CN103173136B - Esters binder - Google Patents
Esters binder Download PDFInfo
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- CN103173136B CN103173136B CN201310060233.6A CN201310060233A CN103173136B CN 103173136 B CN103173136 B CN 103173136B CN 201310060233 A CN201310060233 A CN 201310060233A CN 103173136 B CN103173136 B CN 103173136B
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- water
- binder
- sodium
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- 239000011230 binding agent Substances 0.000 title claims abstract description 20
- 150000002148 esters Chemical class 0.000 title claims abstract description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 229910001868 water Inorganic materials 0.000 claims abstract description 23
- 229920002472 Starch Polymers 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 239000008107 starch Substances 0.000 claims abstract description 11
- 235000019698 starch Nutrition 0.000 claims abstract description 11
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910021538 borax Inorganic materials 0.000 claims abstract description 7
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 7
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 5
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims abstract description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 4
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 4
- 229920001732 Lignosulfonate Polymers 0.000 claims abstract description 4
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 4
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 4
- 229920001276 ammonium polyphosphate Polymers 0.000 claims abstract description 4
- 239000000839 emulsion Substances 0.000 claims abstract description 4
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 4
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims abstract description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 30
- 239000002956 ash Substances 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 238000012986 modification Methods 0.000 claims description 7
- 230000004048 modification Effects 0.000 claims description 7
- 235000002918 Fraxinus excelsior Nutrition 0.000 claims description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229920002367 Polyisobutene Polymers 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 229940037003 alum Drugs 0.000 claims description 3
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 238000007598 dipping method Methods 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 235000019357 lignosulphonate Nutrition 0.000 claims description 3
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 claims description 3
- 239000002105 nanoparticle Substances 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 3
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 abstract description 3
- 230000006378 damage Effects 0.000 abstract description 2
- 238000005187 foaming Methods 0.000 abstract description 2
- 239000010803 wood ash Substances 0.000 abstract 2
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 abstract 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 abstract 1
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 abstract 1
- 235000011121 sodium hydroxide Nutrition 0.000 abstract 1
- 239000003292 glue Substances 0.000 description 13
- 238000000034 method Methods 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000000123 paper Substances 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 241000272517 Anseriformes Species 0.000 description 1
- 101100002917 Caenorhabditis elegans ash-2 gene Proteins 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses an esters binder. The binder is prepared from the following raw materials: lignosulfonate, modified wood ash, styrene, hydroxyethyl methacrylate, acrylate, acrylic acid, sodium persulfate, 3-allyloxy-2-hydroxy propane sulfonic acid, starch, sodium hydroxide, borax, water 30, water glass, ammonium polyphosphate, pure acrylic emulsion, aluminum hydroxide, and sodium lauryl ether sulfate. The binder disclosed by the invention is stable in product quality, strong in binding force, good in stiffness, fast cured without foaming, and capable of comprehensively improving various performances of a corrugated case; by adding the modified wood ash, the destruction of the binder due to a water molecule can be effectively reduced, so that water resistance of the binder is greatly improved; and as the hydrophilic performance of the binder is reduced, the binder has the characteristic of fast drying so as to facilitate application to a high-speed tile line.
Description
Technical field
The present invention relates generally to a kind of caking agent, relates in particular to a kind of ester class binding agent.
Background technology
At present, watt line produce in the tackiness agent of corrugated cardboard mainly use amylan tackiness agent, we know, the stripping strength standard of existing Starch Adhesive is 5.88n/m2, its production technique is single stage method glue and two step method glue, glue is divided into again cold glue and two kinds of methods of hot glue, facts have proved, adopts the hot adhesive-preparing technology binder performance more made than cold adhesive-preparing technology good.But, existing tackiness agent can not be stablized, glue kinematic viscosity declines very fast, shorter general about 24 hours of shelf-time just started to go bad, body paper is to consist of multiple fiber molecule, starch adhesive is penetrated into fiber and forms the glue nail of root top shape from the surperficial pore of paper, between lining paper and stupefied peak, by glue, is followed closely effectively and is bonded together.High-strength corrugated board papery is better, and tightness is high, and top sizing pore is blocked, and general glue perviousness is poor, easily occurs false stickyly, bubbles, the quality problems such as come unstuck.Address this problem, must guarantee glue stability, the starch thickener that the viscosity high workability through overcuring is poor is accurate, in right amount, spread upon equably on corrugation crest line, meet this processing requirement of high-strength corrugated board bonding mechanism, must manufacture glue performance aspect and be resolved.Dry slow, come unstuck distortion, moisture absorption.
Summary of the invention
The object of the invention is exactly for a kind of ester class binding agent is provided.
The present invention is achieved by the following technical solutions:
An ester class binding agent, it is comprised of A, B, tri-kinds of material of C:
Described A material is comprised of the raw material of following weight parts: sulfonated lignin 1-2, modification trees ash 1-2, vinylbenzene, hydroxyethyl methylacrylate 1-2, acrylate 1-2, vinylformic acid 7-10, Sodium Persulfate 1-2, allyloxy hydroxypropyl azochlorosulfonate acid sodium 1-2,
The preparation method of described modification trees ash is:
(1) 10-15% hydrogen peroxide dipping 3-4 hour for trees ashes, deionized water wash, then soak 3-4 hour with 10-12% sodium hydroxide solution, more extremely neutral with deionized water wash, dry;
(2) in trees ashes, add and be equivalent to the sodium laurylsulfate of its weight 2-3%, the polyisobutene of the nano-sized carbon of 1-2%, 2-3%, 3-5% alum powder, high speed 1200-1500 rev/min of stirring, ovendry power is broken into ultrafine powder;
Described B material is comprised of the raw material of following weight parts: starch 18-20, sodium hydroxide 1-2, borax 0.8-1, water 25-30;
Described C material is comprised of the raw material of following weight parts: water glass 1-2, ammonium polyphosphate 1-2, pure-acrylic emulsion 1-2, aluminium hydroxide 1-2, sodium lauryl tri(oxyethyl) sulfate 1-2, water 125-130;
The preparation method of described ester class binding agent is:
(1) take A material, first vinylbenzene is put into reactor, be heated to 70-75 ℃, then add other material, stir, then be warming up to 110-125 ℃, reaction 2-3 hour, discharging;
(2) take B material, heat water to 80-90 ℃, sodium hydroxide, borax is soluble in water, mix, then add starch, stir reaction 30-45 minute;
(3) take C material, heat water to 90-100 ℃, other material and A, B reacting rear material are added to the water successively, limit edged stirs, insulated and stirred reaction 1-2 hour at 90-100 ℃, and before reaction finishes, tune PH is 6.8-7.2, discharging and get final product.
Advantage of the present invention is:
Formulating of recipe of the present invention is reasonable, and raw material is easy to get, and production technique is simple, coordinative composition of equipments is easy, constant product quality, cohesive force is strong, very power is good, quick-drying is non-foaming, comprehensively improves the various performances of Corrugated Box, add modification trees ash, effectively reduce the destruction of water molecules to binding agent, the water resisting property of binding agent is improved a lot, due to the hydrophilicity decline of glue, make its characteristic with good quick-drying, thereby be conducive on watt line, using at a high speed.
Embodiment
Embodiment 1
An ester class binding agent, is characterized in that it is comprised of A, B, tri-kinds of material of C:
Described A material is comprised of the raw material of following weight parts: sulfonated lignin 2, modification trees ash 2, vinylbenzene, hydroxyethyl methylacrylate 2, acrylate 2, vinylformic acid 10, Sodium Persulfate 2, allyloxy hydroxypropyl azochlorosulfonate acid sodium 2,
The preparation method of described modification trees ash is:
(1) 15% hydrogen peroxide dipping 4 hours for trees ashes, deionized water wash, then soak 4 hours with 12% sodium hydroxide solution, then with deionized water wash to neutral, dry;
(2) in trees ashes, add and be equivalent to the sodium laurylsulfate of its weight 3%, 2% nano-sized carbon, 3% polyisobutene, 5% alum powder, 1500 revs/min of stirrings at a high speed, ovendry power is broken into ultrafine powder;
Described B material is comprised of the raw material of following weight parts: starch 20, sodium hydroxide 2, borax 1, water 30;
Described C material is comprised of the raw material of following weight parts: water glass 2, ammonium polyphosphate 2, pure-acrylic emulsion 2, aluminium hydroxide 2, sodium lauryl tri(oxyethyl) sulfate 2, water 130;
The preparation method of described ester class binding agent is:
(1) take A material, first vinylbenzene is put into reactor, be heated to 75 ℃, then add other material, stir, then be warming up to 125 ℃, react discharging 3 hours;
(2) take B material, heat water to 90 ℃, sodium hydroxide, borax is soluble in water, mix, then add starch, stir, react 45 minutes;
(3) take C material, heat water to 100 ℃, other material and A, B reacting rear material are added to the water successively, limit edged stirs, and insulated and stirred reaction is 2 hours at 100 ℃, and before reaction finishes, adjusting PH is 7.2, discharging and get final product.
Performance test:
The present invention's formula is through testing throughout the year, and its bond strength reaches 7.61n/cm
2, the physicalies such as side pressure strength surpass common adhesive 20-30% left and right, can deposit summer and autumn and never degenerate for 7 days, can deposit winter in spring and never degenerate for 14 days.Glue consumption: every layer of starch is 3.5g/m
2.Can solve lightweight paper plate and reveal the chop line problems such as trace, and can solve cardboard and come unstuck, bubble, false sticky, the quality problems such as prying, because glue consumption reduces cost-saving 30% left and right.
Atmospheric moisture is greater than in 90% situation, guarantees the quality 60 days, and carton ducks in drink, within 48 hours, do not come unstuck, and after carton is dry, good bonding, mass conservation.
Claims (1)
1. an ester class binding agent, is characterized in that it is comprised of A, B, tri-kinds of material of C:
Described A material is comprised of the raw material of following weight parts: sulfonated lignin 1-2, modification trees ash 1-2, vinylbenzene, hydroxyethyl methylacrylate 1-2, acrylate 1-2, vinylformic acid 7-10, Sodium Persulfate 1-2, allyloxy hydroxypropyl azochlorosulfonate acid sodium 1-2;
The preparation method of described modification trees ash is:
(1) 10-15% hydrogen peroxide dipping 3-4 hour for trees ashes, deionized water wash, then soak 3-4 hour with 10-12% sodium hydroxide solution, more extremely neutral with deionized water wash, dry;
(2) in trees ashes, add and be equivalent to the sodium laurylsulfate of its weight 2-3%, the polyisobutene of the nano-sized carbon of 1-2%, 2-3%, 3-5% alum powder, high speed 1200-1500 rev/min of stirring, ovendry power is broken into ultrafine powder;
Described B material is comprised of the raw material of following weight parts: starch 18-20, sodium hydroxide 1-2, borax 0.8-1, water 25-30;
Described C material is comprised of the raw material of following weight parts: water glass 1-2, ammonium polyphosphate 1-2, pure-acrylic emulsion 1-2, aluminium hydroxide 1-2, sodium lauryl tri(oxyethyl) sulfate 1-2, water 125-130;
The preparation method of described ester class binding agent is:
(1) take A material, first vinylbenzene is put into reactor, be heated to 70-75 ℃, then add other material, stir, then be warming up to 110-125 ℃, reaction 2-3 hour, discharging;
(2) take B material, heat water to 80-90 ℃, sodium hydroxide, borax is soluble in water, mix, then add starch, stir reaction 30-45 minute;
(3) take C material, heat water to 90-100 ℃, other material and A, B reacting rear material are added to the water successively, limit edged stirs, insulated and stirred reaction 1-2 hour at 90-100 ℃, and before reaction finishes, tune pH is 6.8-7.2, discharging and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310060233.6A CN103173136B (en) | 2013-02-26 | 2013-02-26 | Esters binder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310060233.6A CN103173136B (en) | 2013-02-26 | 2013-02-26 | Esters binder |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103173136A CN103173136A (en) | 2013-06-26 |
| CN103173136B true CN103173136B (en) | 2014-12-17 |
Family
ID=48633349
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310060233.6A Active CN103173136B (en) | 2013-02-26 | 2013-02-26 | Esters binder |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103173136B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10017671B2 (en) | 2015-10-30 | 2018-07-10 | CEL Chemical & Supply, Inc. | Additive for a starch adhesive composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102229789A (en) * | 2011-05-17 | 2011-11-02 | 北京高盟新材料股份有限公司 | Aqueous laminating adhesive for gold and silver cards and preparation method thereof |
| JP2012031422A (en) * | 2011-09-30 | 2012-02-16 | Dic Corp | Flame-retarding pressure-sensitive adhesive, and flame-retarding pressure-sensitive adhesive tape |
| CN102898975A (en) * | 2012-09-05 | 2013-01-30 | 蚌埠市比优特包装印务有限责任公司 | Tile mounting glue and preparation method thereof |
-
2013
- 2013-02-26 CN CN201310060233.6A patent/CN103173136B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102229789A (en) * | 2011-05-17 | 2011-11-02 | 北京高盟新材料股份有限公司 | Aqueous laminating adhesive for gold and silver cards and preparation method thereof |
| JP2012031422A (en) * | 2011-09-30 | 2012-02-16 | Dic Corp | Flame-retarding pressure-sensitive adhesive, and flame-retarding pressure-sensitive adhesive tape |
| CN102898975A (en) * | 2012-09-05 | 2013-01-30 | 蚌埠市比优特包装印务有限责任公司 | Tile mounting glue and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 《淀粉基木板胶粘剂的研究进展》;王俊丽;《中国胶粘剂》;20061231;第15卷(第1期);第45-48页 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10017671B2 (en) | 2015-10-30 | 2018-07-10 | CEL Chemical & Supply, Inc. | Additive for a starch adhesive composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103173136A (en) | 2013-06-26 |
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Effective date of registration: 20161216 Address after: 542899 Hezhou the Guangxi Zhuang Autonomous Region Electronic Science and technology park is run on the road No. 1 Patentee after: GUANGXI HUIZHI PRODUCTIVITY PROMOTION CENTER Co.,Ltd. Address before: Wu Song Zhen Tongling County of Anhui province Tongling 244100 Union City Village Patentee before: Anhui Mingzhu Dope Technology Co.,Ltd. |
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Effective date of registration: 20190415 Address after: 523000 No. 688-19 Fumin Middle Road, Dalang Town, Dongguan City, Guangdong Province Patentee after: DONGGUAN HOPEWAY PACKAGING TECHNOLOGY CO.,LTD. Address before: 542899 No. 1 Zhengrun Avenue, Hezhou Electronic Science and Technology Park, Guangxi Zhuang Autonomous Region Patentee before: GUANGXI HUIZHI PRODUCTIVITY PROMOTION CENTER Co.,Ltd. |
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| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: An ester binder Effective date of registration: 20210420 Granted publication date: 20141217 Pledgee: China Co. truction Bank Corp Dongguan branch Pledgor: DONGGUAN HOPEWAY PACKAGING TECHNOLOGY Co.,Ltd. Registration number: Y2021980002831 |
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Date of cancellation: 20230803 Granted publication date: 20141217 Pledgee: China Co. truction Bank Corp Dongguan branch Pledgor: DONGGUAN HOPEWAY PACKAGING TECHNOLOGY CO.,LTD. Registration number: Y2021980002831 |