CN105345902A - Silk fibroin-silica sol skin-close enhanced pretreating agent for wicker for wickerwork and preparation method of silk fibroin-silica sol skin-close enhanced pretreating agent - Google Patents
Silk fibroin-silica sol skin-close enhanced pretreating agent for wicker for wickerwork and preparation method of silk fibroin-silica sol skin-close enhanced pretreating agent Download PDFInfo
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- CN105345902A CN105345902A CN201510739042.1A CN201510739042A CN105345902A CN 105345902 A CN105345902 A CN 105345902A CN 201510739042 A CN201510739042 A CN 201510739042A CN 105345902 A CN105345902 A CN 105345902A
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- wicker
- silk fibroin
- pretreating agent
- silica sol
- skin
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Abstract
The invention relates to the technical field of modified treatment of wicker for wickerwork, in particular to a silk fibroin-silica sol skin-close enhanced pretreating agent for wicker for wickerwork and a preparation method of the silk fibroin-silica sol skin-close enhanced pretreating agent. The silk fibroin-silica sol skin-close enhanced pretreating agent is prepared from, by weight, 0.01-0.02 part of lactic acid, 6-8 parts of silk fibroin water solution, 0.01-0.02 part of zinc acetate, 10-12 parts of silica sol with the solid content of 20% to 25%, 1-2 parts of polyoxyethylene, 0.2-0.3 part of alkyl sodium sulfonate and 40-50 parts of water. After the pretreating agent permeates into wicker fibers through high pressure, a silk fibroin and silica sol composite carrier in the pretreating agent adheres to the wicker fibers, and the effects of increasing strength and toughness, improving the hand feeling and the like are achieved. The treated wicker is better in air and water vapor permeability, corrosion and mould prevention is achieved, the wicker is smooth and flexible, and weaving and forming are easy. A product woven from the pretreated wicker is longer in service life, bearing force is increased, and the use range is further widened.
Description
Technical field
The present invention relates to wicker plaiting article wicker modification treatment technology field, be specifically related to a kind of fibroin albumen for wicker plaiting article wicker-Ludox pro-skin and strengthen pretreating agent and preparation method thereof.
Background technology
Wicker plaiting article is one of folks of china traditional handicraft product, people are just as common daily utility in ancient times, until after 20th century decades just rise gradually, the also project becoming selected areas of China foreign exchange earning gradually, Anhui Province has become one of three large wicker plaiting article production bases, the whole nation.
Wicker is as the material of wicker plaiting article, and it is by novel design, can be woven into that various honesty is natural, handsome in appearance, the practical art product of Portable durable.Along with industry development, product is constantly brought forth new ideas, and the willow having more Nover practical attractive in appearance is presented in face of client.But, because wicker is pure natural plant fiber, not humidity and drying, causes mechanical property to reduce, fracture of easily going mouldy, and bearing capacity is poor, govern further developing of product, if carry out pretreatment to wicker before establishment, improve the adaptability of its environment to external world, improve mechanical property, obtaining wicker plaiting article product quality like this will significantly be improved.
Summary of the invention
The object of the invention is to provide a kind of fibroin albumen for wicker plaiting article wicker-Ludox pro-skin to strengthen pretreating agent and preparation method thereof, in order to improve the serviceability of wicker, reach the object improving knitting quality, to achieve these goals, the technical solution used in the present invention is as follows:
A kind of fibroin albumen for wicker plaiting article wicker-Ludox pro-skin strengthens pretreating agent, it is characterized in that, this inorganic agent is made up of the raw material of following weight portion: lactic acid 0.01-0.02, silk fibroin water solution 6-8, zinc acetate 0.01-0.02, solid content are Ludox 10-12, polyethylene glycol oxide 1-2, SAS 0.2-0.3, the water 40-50 of 20-25%.
Fibroin albumen-Ludox pro-skin for wicker plaiting article wicker strengthens a preparation method for pretreating agent, and it is characterized in that, the preparation method of this inorganic agent is:
(1) first lactic acid, zinc acetate, SAS are dropped in water, stir after material is dissolved completely, mixed solution is heated to 40-50 DEG C, then adds polyethylene glycol oxide, be uniformly mixed 30-40min, gained solution for standby;
(2) silk fibroin water solution is dropwise added in Ludox slowly, and constantly stir, after dropwising, the solution of mixed solution with step (1) gained is mixed completely, obtain wicker pretreating agent.
Pretreating agent advantage prepared by the present invention is: preparation method is simple, composition environment-protecting asepsis, it has good permeability, high pressure is utilized to be penetrated into after in wicker fiber during use, fibroin albumen wherein, Ludox complex carrier enters in fiber, can be good attached to it, reach enhancing, toughness reinforcing, improve the effects such as feel, wicker breathable moisture permeability after process is better, again in conjunction with other composition, make modified wicker anticorrosive mildewproof, smooth pliable and tough, be easy to knitting forming, the life of product be woven into through pretreated like this wicker is longer, bearing capacity increases, widen the scope of application further.
Detailed description of the invention
Embodiment
The pretreating agent of the present embodiment is obtained by the raw material of following weight portion (kilogram): lactic acid 0.01, silk fibroin water solution 6, zinc acetate 0.01, solid content are Ludox 10, polyethylene glycol oxide 1.5, SAS 0.2, the water 45 of 25%.
The preparation method of the present embodiment inorganic agent is:
(1) first lactic acid, zinc acetate, SAS are dropped in water, stir after material is dissolved completely, mixed solution is heated to 40-50 DEG C, then adds polyethylene glycol oxide, be uniformly mixed 35min, gained solution for standby;
(2) silk fibroin water solution is dropwise added in Ludox slowly, and constantly stir, after dropwising, the solution of mixed solution with step (1) gained is mixed completely, obtain wicker pretreating agent.
The compression strength of passing through the untreated wicker of comparatively same batch of the wicker that this pre-treatment treatment is crossed on average improves 32%, and bending strength on average improves 35%, and the product bearing capacity be woven on average improves 42%, and product sense of touch is good.
Claims (2)
1. the fibroin albumen for wicker plaiting article wicker-Ludox pro-skin strengthens pretreating agent, it is characterized in that, this inorganic agent is made up of the raw material of following weight portion: lactic acid 0.01-0.02, silk fibroin water solution 6-8, zinc acetate 0.01-0.02, solid content are Ludox 10-12, polyethylene glycol oxide 1-2, SAS 0.2-0.3, the water 40-50 of 20-25%.
2. a kind of fibroin albumen for wicker plaiting article wicker-Ludox pro-skin strengthens the preparation method of pretreating agent as claimed in claim 1, and it is characterized in that, described preparation method is:
(1) first lactic acid, zinc acetate, SAS are dropped in water, stir after material is dissolved completely, mixed solution is heated to 40-50 DEG C, then adds polyethylene glycol oxide, be uniformly mixed 30-40min, gained solution for standby;
(2) silk fibroin water solution is dropwise added in Ludox slowly, and constantly stir, after dropwising, the solution of mixed solution with step (1) gained is mixed completely, obtain wicker pretreating agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510739042.1A CN105345902A (en) | 2015-11-04 | 2015-11-04 | Silk fibroin-silica sol skin-close enhanced pretreating agent for wicker for wickerwork and preparation method of silk fibroin-silica sol skin-close enhanced pretreating agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510739042.1A CN105345902A (en) | 2015-11-04 | 2015-11-04 | Silk fibroin-silica sol skin-close enhanced pretreating agent for wicker for wickerwork and preparation method of silk fibroin-silica sol skin-close enhanced pretreating agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105345902A true CN105345902A (en) | 2016-02-24 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510739042.1A Pending CN105345902A (en) | 2015-11-04 | 2015-11-04 | Silk fibroin-silica sol skin-close enhanced pretreating agent for wicker for wickerwork and preparation method of silk fibroin-silica sol skin-close enhanced pretreating agent |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104786332A (en) * | 2015-04-30 | 2015-07-22 | 青岛克立克信息技术有限公司 | Multi-effect timber modifier |
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- 2015-11-04 CN CN201510739042.1A patent/CN105345902A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104786332A (en) * | 2015-04-30 | 2015-07-22 | 青岛克立克信息技术有限公司 | Multi-effect timber modifier |
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| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160224 |