CN105926275A - Antibacterial and mildew-resistant finishing method of wool cotton fabric - Google Patents

Antibacterial and mildew-resistant finishing method of wool cotton fabric Download PDF

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Publication number
CN105926275A
CN105926275A CN201610329134.7A CN201610329134A CN105926275A CN 105926275 A CN105926275 A CN 105926275A CN 201610329134 A CN201610329134 A CN 201610329134A CN 105926275 A CN105926275 A CN 105926275A
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China
Prior art keywords
fabric
antibacterial
mouldproof
parts
mildew
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Pending
Application number
CN201610329134.7A
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Chinese (zh)
Inventor
何良
周建玉
刘晨
潘万里
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Jiangsu Sunshine Group Co Ltd
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Jiangsu Sunshine Group Co Ltd
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Priority to CN201610329134.7A priority Critical patent/CN105926275A/en
Publication of CN105926275A publication Critical patent/CN105926275A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/10Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/10Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
    • D06B3/18Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/30Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with oxides of halogens, oxyacids of halogens or their salts, e.g. with perchlorates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/10Animal fibres
    • D06M2101/12Keratin fibres or silk
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/35Abrasion, pilling or fibrillation resistance

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The invention discloses an antibacterial and mildew-resistant finishing method of a wool cotton fabric. The method comprises the steps of wet steaming, wherein wet steaming treatment is firstly conducted on the wool cotton fabric, therefore, the hydrophilicity of the wool fabric is enhanced, and the fiber structure is loosen; cotton fiber oxidizing, wherein selective oxidizing is conducted on cotton fibers in yarn through a sodium periodate solution, and selective oxidizing is beneficial for improving bonding of the cotton fibers and functional components in antibacterial and mildew-resistant finishing liquor; antibacterial and mildew-resistant finishing and the like. According to the fabric treated through the process steps, the bonding force between an antibacterial and mildew-resistant functional membrane layer and the fibers is high, and the water washing resistance and friction resistance are high.

Description

A kind of antibacterial and mouldproof method for sorting of velvet apple fabric
Technical field
The present invention relates to textile production technical field, be specifically related to the antibacterial and mouldproof method for sorting of a kind of velvet apple fabric.
Background technology
Owing to the wool fiber in velvet apple fabric and cotton fiber are natural fiber, in the environment that air humidity is bigger, velvet apple fabric is easier to mould growth, mycete vitality is the strongest, general temperature 25 DEG C~30 DEG C, humidity is more than 80%, and has the oxygen of abundance, will growth and breeding.Sultry rainy weather, tinea antibacterial and fungus are easier to breeding, if skin perspiration is not smooth, are easy for the dermatosiss such as raw tinea cruris, tinea manus and pedis, miliaria, acne, pompholyx.In prior art, the means of antimildew and antibacterial mainly have following two: the first, anti-biotic material is made anti-bacterial fibre, or using the natural fiber such as flaxen fiber with anti-microbial property etc. as raw fibre blending to fabric in;Second, use antibiotic finishing solution that fabric is carried out Final finishing.Above two method respectively has the membership that adds of synthetic antimicrobial fiber or natural antibacterial fiber in pluses and minuses, specially former approach affects the fiber composition of fabric, does not reaches predetermined feel and pliability;Antibiotic substance can be loaded to fiber surface by Final finishing, but owing to water-wash resistance is poor, therefore anti-microbial property tends not to last longer.Therefore, it is necessary to anti-bacterial finish technique of the prior art is optimized.
Summary of the invention
It is an object of the invention to overcome defect present in prior art, it is provided that the antibacterial and mouldproof method for sorting of a kind of velvet apple fabric, the fabric anti-microbial property after above-mentioned PROCESS FOR TREATMENT is lasting.
For realizing above-mentioned technique effect, the technical scheme is that the antibacterial and mouldproof method for sorting of a kind of velvet apple fabric, it is characterised in that comprise the following steps:
S1: velvet apple fabric treatment fluid two is soaked two and rolls process, is subsequently placed in wet steaming in the steamer that vapor (steam) temperature is 110~130 DEG C and processes 8~14min, and wherein the relative humidity in steamer controls 55~65%, takes out fabric cleaning, drying;
S2: S1 gained fabric is placed in the sodium periodate solution of 1.2~2g/L, lucifuge reaction 2~3h it is incubated after being heated to 32~36 DEG C, reacted spun fibers is placed in the glycerin solution of 0.02~0.05mol/L and soaks half an hour, more fully wash with deionized water;
S3: S2 gained fabric is placed in two leachings two in antibacterial and mouldproof dressing liquid and rolls, dry through preliminary drying, washing, obtain velvet apple fabric finished product;Antibacterial and mouldproof dressing liquid is counted by weight and is included Ludox 0.5~3 parts, silver-carrying nano powder body 0.3~2 parts, ethanol 5~15 parts and deionized water 65~75 parts.
Preferably technical scheme is that the nano-powder of described silver-carrying nano powder body is to have at least one in the zeolite of nanoporous structure, Maifanitum, silicon dioxide, wollastonite, montmorillonite.
Preferably technical scheme is that described treatment fluid is distilled water or ethanol solution.
Preferably technical scheme is that in described ethanol solution, the percentage by weight of ethanol is 20~50%.
Preferably technical scheme is that padding platen pressure in process in S3 is 400~420kPa, and speed is 15~18m/min, overfeeding 12~15%.
Preferably technical scheme is that in S2, the dioxide-containing silica in Ludox is 60~70%.
Advantages of the present invention and having the beneficial effects that:
First velvet apple fabric is carried out wet steaming process by the present invention, the hydrophilic making wool fabric strengthens, fibre structure loosens, and sodium periodate solution is to the cotton fiber selective oxidation in yarn, and selective oxidation is conducive to improving cotton fiber and combines with the function ingredients in antibacterial and mouldproof dressing liquid.The adhesion between fabric antibacterial and antimildew function film layer and fiber after above-mentioned processing step processes is strong, water-fastness strong with frictional behaviour.
Detailed description of the invention
Below in conjunction with embodiment, the detailed description of the invention of the present invention is further described.Following example are only used for clearly illustrating technical scheme, and can not limit the scope of the invention with this.
Embodiment 1
For realizing above-mentioned technique effect, in embodiment 1, the antibacterial and mouldproof method for sorting of velvet apple fabric comprises the following steps:
S1: velvet apple fabric treatment fluid two is soaked two and rolls process, is subsequently placed in wet steaming in the steamer that vapor (steam) temperature is 110 DEG C and processes 8min, and wherein the relative humidity in steamer controls 55%, takes out fabric cleaning, drying;
S2: be placed in the sodium periodate solution of 1.2g/L by S1 gained fabric, is incubated lucifuge reaction 2h, reacted spun fibers is placed in the glycerin solution of 0.02mol/L and soaks half an hour, more fully wash with deionized water after being heated to 32 DEG C;
S3: S2 gained fabric is placed in two leachings two in antibacterial and mouldproof dressing liquid and rolls, dry through preliminary drying, washing, obtain velvet apple fabric finished product;Antibacterial and mouldproof dressing liquid is counted by weight and is included Ludox 0.5 part, silver-carrying nano powder body 0.3 part, ethanol 5 parts and deionized water 65 parts.
The nano-powder of silver-carrying nano powder body is the zeolite with nanoporous structure.
Treatment fluid is distilled water;Padding platen pressure in process in S3 is 400kPa, and speed is 15m/min, overfeeding 12%.
In S2, the dioxide-containing silica in Ludox is 60%.
Embodiment 2
Embodiment 2 is distinguished as with embodiment 1:
S1: vapor (steam) temperature is that in the steamer of 130 DEG C, wet steaming processes 14min, and wherein the relative humidity in steamer controls 65%;
S2: be placed in the sodium periodate solution of 2g/L by S1 gained fabric, is incubated lucifuge reaction 3h, reacted spun fibers is placed in the glycerin solution of 0.05mol/L and soaks half an hour after being heated to 36 DEG C;
S3: antibacterial and mouldproof dressing liquid is counted by weight and is included Ludox 3 parts, silver-carrying nano powder body 2 parts, ethanol 15 parts and deionized water 75 parts.
The nano-powder of silver-carrying nano powder body is the Maifanitum with nanoporous structure.
Treatment fluid is ethanol solution.In ethanol solution, the percentage by weight of ethanol is 20%.
Padding platen pressure in process in S3 is 420kPa, and speed is 18m/min, overfeeding 15%.
In S2, the dioxide-containing silica in Ludox is 70%.
Embodiment 3
Embodiment 3 is distinguished as with embodiment 1:
S1: vapor (steam) temperature is that in the steamer of 120 DEG C, wet steaming processes 11min, and wherein the relative humidity in steamer controls 60%;
S2: be placed in the sodium periodate solution of 1.6g/L by S1 gained fabric, is incubated lucifuge reaction 2.5h, reacted spun fibers is placed in the glycerin solution of 0.035mol/L and soaks half an hour after being heated to 34 DEG C;
S3: antibacterial and mouldproof dressing liquid is counted by weight and is included Ludox 1.7 parts, silver-carrying nano powder body 1.7 parts, ethanol 10 parts and deionized water 70 parts.
The nano-powder of silver-carrying nano powder body is the montmorillonite with nanoporous structure.
Treatment fluid is ethanol solution;In ethanol solution, the percentage by weight of ethanol is 50%.
Padding platen pressure in process in S3 is 410kPa, and speed is 16m/min, overfeeding 13%.
In S2, the dioxide-containing silica in Ludox is 65%.
Comparative example
Not comprising S1 in comparative example 1, remaining technological parameter is with embodiment 3;
Not comprising S2 in comparative example 2, remaining technological parameter is with embodiment 3;
Comparative example 1,2 forms controlled trial with embodiment 1-3.Detect through antibacterial and mouldproof and washing, the sample antibacterial and mouldproof performance of comparative example 1-2 is all worse than embodiment 1-3, mainly show as the water-wash resistance of antibacterial and mouldproof performance and increase decline substantially along with washing times, additionally, the antibacterial and mouldproof wash durability of embodiment 4 is better than comparative example 3, and the antibacterial and mouldproof ability of embodiment 4 is better than raw wool cotton face fabric, thus prove that technical scheme applies also for other antibacterial and mouldproof finishing agents.
The above is only the preferred embodiment of the present invention; it should be pointed out that, for those skilled in the art, on the premise of without departing from the technology of the present invention principle; can also make some improvements and modifications, these improvements and modifications also should be regarded as protection scope of the present invention.

Claims (6)

1. the antibacterial and mouldproof method for sorting of a velvet apple fabric, it is characterised in that comprise the following steps:
S1: velvet apple fabric treatment fluid two is soaked two and rolls process, is subsequently placed in wet steaming in the steamer that vapor (steam) temperature is 110~130 DEG C and processes 8~14min, and wherein the relative humidity in steamer controls 55~65%, takes out fabric cleaning, drying;
S2: S1 gained fabric is placed in the sodium periodate solution of 1.2~2g/L, lucifuge reaction 2~3h it is incubated after being heated to 32~36 DEG C, reacted spun fibers is placed in the glycerin solution of 0.02~0.05mol/L and soaks half an hour, more fully wash with deionized water;
S3: S2 gained fabric is placed in two leachings two in antibacterial and mouldproof dressing liquid and rolls, dry through preliminary drying, washing, obtain velvet apple fabric finished product;Antibacterial and mouldproof dressing liquid is counted by weight and is included Ludox 0.5~3 parts, silver-carrying nano powder body 0.3~2 parts, ethanol 5~15 parts and deionized water 65~75 parts.
The antibacterial and mouldproof method for sorting of velvet apple fabric the most according to claim 2, it is characterised in that the nano-powder of described silver-carrying nano powder body is to have at least one in the zeolite of nanoporous structure, Maifanitum, silicon dioxide, wollastonite, montmorillonite.
The antibacterial and mouldproof method for sorting of velvet apple fabric the most according to claim 1, it is characterised in that described treatment fluid is distilled water or ethanol solution.
The wet steaming colouring method of whole-wool worsted face fabric the most according to claim 3, it is characterised in that in described ethanol solution, the percentage by weight of ethanol is 20~50%.
The wet steaming colouring method of whole-wool worsted face fabric the most according to claim 1, it is characterised in that padding platen pressure in process in S3 is 400~420kPa, and speed is 15~18m/min, overfeeding 12~15%.
The wet steaming colouring method of whole-wool worsted face fabric the most according to claim 1, it is characterised in that in S2, the dioxide-containing silica in Ludox is 60~70%.
CN201610329134.7A 2016-05-18 2016-05-18 Antibacterial and mildew-resistant finishing method of wool cotton fabric Pending CN105926275A (en)

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Application Number Priority Date Filing Date Title
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108505243A (en) * 2018-03-26 2018-09-07 相里海霞 A kind of antibacterial treatment process of wool worsted fabric
CN108642707A (en) * 2018-06-22 2018-10-12 合肥洁诺医疗用品有限公司 A kind of preparation method of operating cap non-woven fabrics
CN109914101A (en) * 2019-02-25 2019-06-21 邹平舫汇针织有限公司 A kind of preparation process of the fabric with the anti-mosquito function of the anti-mite of antibacterial
CN110055747A (en) * 2019-05-15 2019-07-26 中国农业科学院麻类研究所 A kind of nano-antibacterial bast-fibre and its preparation method and application
CN115821588A (en) * 2022-12-13 2023-03-21 周权有 Fabric finishing agent for modal fabric and finishing method
CN116918831A (en) * 2023-07-25 2023-10-24 山东鑫永恒新材料有限公司 Silver-loaded antibacterial slow-release material and preparation method thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108505243A (en) * 2018-03-26 2018-09-07 相里海霞 A kind of antibacterial treatment process of wool worsted fabric
CN108642707A (en) * 2018-06-22 2018-10-12 合肥洁诺医疗用品有限公司 A kind of preparation method of operating cap non-woven fabrics
CN109914101A (en) * 2019-02-25 2019-06-21 邹平舫汇针织有限公司 A kind of preparation process of the fabric with the anti-mosquito function of the anti-mite of antibacterial
CN110055747A (en) * 2019-05-15 2019-07-26 中国农业科学院麻类研究所 A kind of nano-antibacterial bast-fibre and its preparation method and application
CN115821588A (en) * 2022-12-13 2023-03-21 周权有 Fabric finishing agent for modal fabric and finishing method
CN116918831A (en) * 2023-07-25 2023-10-24 山东鑫永恒新材料有限公司 Silver-loaded antibacterial slow-release material and preparation method thereof
CN116918831B (en) * 2023-07-25 2024-03-12 山东鑫永恒新材料有限公司 Silver-loaded antibacterial slow-release material and preparation method thereof

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Application publication date: 20160907