CN105415467A - Nano-microcrystalline cellulose-silica sol reinforced pretreating agent for willow weaving wickers and preparation method thereof - Google Patents

Nano-microcrystalline cellulose-silica sol reinforced pretreating agent for willow weaving wickers and preparation method thereof Download PDF

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Publication number
CN105415467A
CN105415467A CN201510739097.2A CN201510739097A CN105415467A CN 105415467 A CN105415467 A CN 105415467A CN 201510739097 A CN201510739097 A CN 201510739097A CN 105415467 A CN105415467 A CN 105415467A
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CN
China
Prior art keywords
wicker
pretreating agent
wickers
nano
microcrystalline cellulose
Prior art date
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Pending
Application number
CN201510739097.2A
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Chinese (zh)
Inventor
王丽琼
杨东跃
杨思懿
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Anhui Meijing Arts And Crafts Co Ltd
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Anhui Meijing Arts And Crafts Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Meijing Arts And Crafts Co Ltd filed Critical Anhui Meijing Arts And Crafts Co Ltd
Priority to CN201510739097.2A priority Critical patent/CN105415467A/en
Publication of CN105415467A publication Critical patent/CN105415467A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/52Impregnating agents containing mixtures of inorganic and organic compounds

Abstract

The invention relates to the technical field of wicker modified treatment, in particular to a nano-microcrystalline cellulose-silica sol reinforced pretreating agent for willow weaving wickers and a preparation method thereof. The nano-microcrystalline cellulose-silica sol reinforced pretreating agent is composed of, by weight, 0.1-0.2 part of hydrophilic silicone oil, 0.1-0.2 part of secondary alkane sulphonate sodium, 0.2-0.4 part of nano-microcrystalline cellulose, 10-12 parts of silica sol with the solid content being 20-25%, 0.01-0.02 part of sodium ascorbate, 6-8 part of clear limewater, 1-2 parts of polyoxyethylene and 40-50 parts of water. After the pretreating agent permeates into the wickers, the functions of strengthening, toughening, plasticity improvement and the like are achieved; the clear limewater has the functions of assisting materials to be attached and bonded to fibers and the like; the modified wickers are better in weaving performance, smooth, pliable, tough and capable of achieving more high temperature resistance; products woven by the pretreated wickers are longer in service life, increase weight capacity and further widen the service range.

Description

A kind of nano micro crystal cellulose for wicker plaiting article wicker-Ludox strengthens pretreating agent and preparation method thereof
Technical field
The present invention relates to wicker plaiting article wicker modification treatment technology field, be specifically related to a kind of nano micro crystal cellulose for wicker plaiting article wicker-Ludox and strengthen pretreating agent and preparation method thereof.
Background technology
Wicker plaiting article is one of folks of china traditional handicraft product, people are just as common daily utility in ancient times, until after 20th century decades just rise gradually, the also project becoming selected areas of China foreign exchange earning gradually, Anhui Province has become one of three large wicker plaiting article production bases, the whole nation.
Wicker is as the material of wicker plaiting article, and it is by novel design, can be woven into that various honesty is natural, handsome in appearance, the practical art product of Portable durable.Along with industry development, product is constantly brought forth new ideas, and the willow having more Nover practical attractive in appearance is presented in face of client.But, because wicker is pure natural plant fiber, not humidity and drying, causes mechanical property to reduce, fracture of easily going mouldy, and bearing capacity is poor, govern further developing of product, if carry out pretreatment to wicker before establishment, improve the adaptability of its environment to external world, improve mechanical property, obtaining wicker plaiting article product quality like this will significantly be improved.
Summary of the invention
The object of the invention is to provide a kind of nano micro crystal cellulose for wicker plaiting article wicker-Ludox to strengthen pretreating agent and preparation method thereof, in order to improve the serviceability of wicker, reach the object improving knitting quality, to achieve these goals, the technical solution used in the present invention is as follows:
A kind of nano micro crystal cellulose for wicker plaiting article wicker-Ludox strengthens pretreating agent, it is characterized in that, this inorganic agent is made up of the raw material of following weight portion: hydrophilic silicone oil 0.1-0.2, SAS 0.1-0.2, nano micro crystal cellulose 0.2-0.4, solid content are Ludox 10-12, the sodium ascorbate 0.01-0.02 of 20-25%, clarification limewash 6-8, polyethylene glycol oxide 1-2, water 40-50.
Nano micro crystal cellulose-Ludox for wicker plaiting article wicker strengthens a preparation method for pretreating agent, and it is characterized in that, the preparation method of this inorganic agent is:
(1) first SAS, sodium ascorbate are dropped in water, stir after material is dissolved completely, mixed solution is heated to 40-50 DEG C, then adds polyethylene glycol oxide, be uniformly mixed 30-40min, gained solution for standby;
(2) clarification limewash is dropwise added in Ludox slowly, and constantly stir, after dropwising, nano micro crystal cellulose is added in mixed solution, ultrasonic make it dispersed after, mix completely with the solution of step (1) gained and other leftover materials again, obtain wicker pretreating agent.
Pretreating agent advantage prepared by the present invention is: preparation method is simple, composition environment-protecting asepsis, it has good permeability, high pressure is utilized to be penetrated in wicker fiber during use, nano micro crystal cellulose wherein, Ludox, polyethylene glycol oxide infiltrates through after in fiber can reach enhancing, toughness reinforcing, improve the effects such as plasticity, clarification limewash has auxiliary material to adhere to the effects such as bonding on fiber, modified wicker knitting property is better, smooth pliable and tough, more high temperature resistant, the life of product be woven into through pretreated like this wicker is longer, bearing capacity increases, widen the scope of application further.
Detailed description of the invention
Embodiment
The pretreating agent of the present embodiment is obtained by the raw material of following weight portion (kilogram): hydrophilic silicone oil 0.1, SAS 0.2, nano micro crystal cellulose 0.3, solid content be 20% Ludox 12, sodium ascorbate 0.01, clarification limewash 7, polyethylene glycol oxide 1.5, water 45.
The preparation method of the present embodiment inorganic agent is:
(1) first SAS, sodium ascorbate are dropped in water, stir after material is dissolved completely, mixed solution is heated to 40-50 DEG C, then adds polyethylene glycol oxide, be uniformly mixed 35min, gained solution for standby;
(2) clarification limewash is dropwise added in Ludox slowly, and constantly stir, after dropwising, nano micro crystal cellulose is added in mixed solution, ultrasonic make it dispersed after, mix completely with the solution of step (1) gained and other leftover materials again, obtain wicker pretreating agent.
The compression strength of passing through the untreated wicker of comparatively same batch of the wicker that this pre-treatment treatment is crossed on average improves 35%, and bending strength on average improves 42%, and the product bearing capacity be woven on average improves 46%.

Claims (2)

1. the nano micro crystal cellulose for wicker plaiting article wicker-Ludox strengthens pretreating agent, it is characterized in that, this inorganic agent is made up of the raw material of following weight portion: hydrophilic silicone oil 0.1-0.2, SAS 0.1-0.2, nano micro crystal cellulose 0.2-0.4, solid content are Ludox 10-12, the sodium ascorbate 0.01-0.02 of 20-25%, clarification limewash 6-8, polyethylene glycol oxide 1-2, water 40-50.
2. a kind of nano micro crystal cellulose for wicker plaiting article wicker-Ludox strengthens the preparation method of pretreating agent as claimed in claim 1, and it is characterized in that, described preparation method is:
(1) first SAS, sodium ascorbate are dropped in water, stir after material is dissolved completely, mixed solution is heated to 40-50 DEG C, then adds polyethylene glycol oxide, be uniformly mixed 30-40min, gained solution for standby;
(2) clarification limewash is dropwise added in Ludox slowly, and constantly stir, after dropwising, nano micro crystal cellulose is added in mixed solution, ultrasonic make it dispersed after, mix completely with the solution of step (1) gained and other leftover materials again, obtain wicker pretreating agent.
CN201510739097.2A 2015-11-04 2015-11-04 Nano-microcrystalline cellulose-silica sol reinforced pretreating agent for willow weaving wickers and preparation method thereof Pending CN105415467A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510739097.2A CN105415467A (en) 2015-11-04 2015-11-04 Nano-microcrystalline cellulose-silica sol reinforced pretreating agent for willow weaving wickers and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510739097.2A CN105415467A (en) 2015-11-04 2015-11-04 Nano-microcrystalline cellulose-silica sol reinforced pretreating agent for willow weaving wickers and preparation method thereof

Publications (1)

Publication Number Publication Date
CN105415467A true CN105415467A (en) 2016-03-23

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CN (1) CN105415467A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108293987A (en) * 2017-01-11 2018-07-20 北京赛特超润界面科技有限公司 A kind of composition preventing drop rebound and sputtering on super hydrophobic surface and its application in pesticide
CN111303775A (en) * 2020-03-30 2020-06-19 山东建筑大学 Anti-cracking inorganic adhesive for bamboo and wood structure and preparation method thereof
CN111393130A (en) * 2020-03-30 2020-07-10 山东建筑大学 Inorganic glue for anti-cracking bamboo structure, preparation method of inorganic glue and preparation method of recombined bamboo
CN112226112A (en) * 2020-10-15 2021-01-15 中国石油化工股份有限公司 Preparation method of filter material modifier for oily sewage treatment

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104816366A (en) * 2015-04-30 2015-08-05 青岛百千川海洋生态科技有限公司 Anticorrosion wood modifier
CN104859011A (en) * 2014-12-25 2015-08-26 王玉燕 Nano alumina-containing modified wood production method

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104859011A (en) * 2014-12-25 2015-08-26 王玉燕 Nano alumina-containing modified wood production method
CN104816366A (en) * 2015-04-30 2015-08-05 青岛百千川海洋生态科技有限公司 Anticorrosion wood modifier

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108293987A (en) * 2017-01-11 2018-07-20 北京赛特超润界面科技有限公司 A kind of composition preventing drop rebound and sputtering on super hydrophobic surface and its application in pesticide
CN111303775A (en) * 2020-03-30 2020-06-19 山东建筑大学 Anti-cracking inorganic adhesive for bamboo and wood structure and preparation method thereof
CN111393130A (en) * 2020-03-30 2020-07-10 山东建筑大学 Inorganic glue for anti-cracking bamboo structure, preparation method of inorganic glue and preparation method of recombined bamboo
CN112226112A (en) * 2020-10-15 2021-01-15 中国石油化工股份有限公司 Preparation method of filter material modifier for oily sewage treatment
CN112226112B (en) * 2020-10-15 2022-02-15 中国石油化工股份有限公司 Preparation method of filter material modifier for oily sewage treatment

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Application publication date: 20160323

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