CN105538454A - Nano-carbon sol-silica sol composite enhancement pretreating agent for wickers for wickerwork and preparing method of nano-carbon sol-silica sol composite enhancement pretreating agent - Google Patents

Nano-carbon sol-silica sol composite enhancement pretreating agent for wickers for wickerwork and preparing method of nano-carbon sol-silica sol composite enhancement pretreating agent Download PDF

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Publication number
CN105538454A
CN105538454A CN201510981645.2A CN201510981645A CN105538454A CN 105538454 A CN105538454 A CN 105538454A CN 201510981645 A CN201510981645 A CN 201510981645A CN 105538454 A CN105538454 A CN 105538454A
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CN
China
Prior art keywords
nano
pretreating agent
sol
carbon
wicker
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510981645.2A
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Chinese (zh)
Inventor
刘金玲
梁加地
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Funan County Jindi Willow Crafts Co Ltd
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Funan County Jindi Willow Crafts Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Funan County Jindi Willow Crafts Co Ltd filed Critical Funan County Jindi Willow Crafts Co Ltd
Priority to CN201510981645.2A priority Critical patent/CN105538454A/en
Publication of CN105538454A publication Critical patent/CN105538454A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K9/00Chemical or physical treatment of reed, straw, or similar material
    • B27K9/002Cane, bamboo
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/007Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process employing compositions comprising nanoparticles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/52Impregnating agents containing mixtures of inorganic and organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2240/00Purpose of the treatment
    • B27K2240/20Removing fungi, molds or insects

Abstract

The invention relates to the technical field of modified treatment of wickers for wickerwork, in particular to a nano-carbon sol-silica sol composite enhancement pretreating agent for the wickers for wickerwork and a preparing method of the nano-carbon sol-silica sol composite enhancement pretreating agent. The nano-carbon sol-silica sol composite enhancement pretreating agent comprises, by weight, 8-10 parts of nano-carbon sol with the solid content ranging from 10% to 15%, 0.1-0.2 part of sodium polyacrylate, 0.01-0.02 part of potassium sorbate, 1-1.5 parts of polyoxyethylene, 6-8 parts of clarification whitewash, 10-12 parts of silica sol with the solid content ranging from 20% to 25% and 40-50 parts of water. The pretreating agent permeates into wicker fibers at a high pressure, nano-carbon, nanometer silicon and the like can be well attracted to the fibers, and the effects of improving the fiber structures, strengthening, toughening, protecting and the like are achieved; the resistivity of the treated wickers to the outside is strengthened, the molding durability is good, and cracking is not prone to occurrence; and a product knitted by the wickers treated in the manner is longer in service life, the bearing force of the product is improved, and the using scope is further expanded.

Description

A kind of nano carbon sol for wicker plaiting article wicker-Ludox composite strengthening pretreating agent and preparation method thereof
Technical field
The present invention relates to wicker plaiting article wicker modification treatment technology field, be specifically related to a kind of nano carbon sol for wicker plaiting article wicker-Ludox composite strengthening pretreating agent and preparation method thereof.
Background technology
Wicker plaiting article is one of folks of china traditional handicraft product, people are just as common daily utility in ancient times, until after 20th century decades just rise gradually, the also project becoming selected areas of China foreign exchange earning gradually, Anhui Province has become one of three large wicker plaiting article production bases, the whole nation.
Wicker is as the material of wicker plaiting article, and it is by novel design, can be woven into that various honesty is natural, handsome in appearance, the practical art product of Portable durable.Along with industry development, product is constantly brought forth new ideas, and the willow having more Nover practical attractive in appearance is presented in face of client.But, because wicker is pure natural plant fiber, not humidity and drying, causes mechanical property to reduce, fracture of easily going mouldy, and bearing capacity is poor, govern further developing of product, if carry out pretreatment to wicker before establishment, improve the adaptability of its environment to external world, improve mechanical property, obtaining wicker plaiting article product quality like this will significantly be improved.
Summary of the invention
The object of the invention is to provide a kind of nano carbon sol for wicker plaiting article wicker-Ludox composite strengthening pretreating agent and preparation method thereof, in order to improve the serviceability of wicker, reach the object improving knitting quality, to achieve these goals, the technical solution used in the present invention is as follows:
A kind of nano carbon sol for wicker plaiting article wicker-Ludox composite strengthening pretreating agent, it is characterized in that, this inorganic agent is made up of the raw material of following weight portion: solid content is nano carbon sol 8-10, the Sodium Polyacrylate 0.1-0.2 of 10-15%, potassium sorbate 0.01-0.02, polyethylene glycol oxide 1-1.5, clarification limewash 6-8, solid content are 20-25% Ludox 10-12, water 40-50.
For a preparation method for the nano carbon sol-Ludox composite strengthening pretreating agent of wicker plaiting article wicker, it is characterized in that, the preparation method of this inorganic agent is:
(1) first potassium sorbate, Sodium Polyacrylate are dropped in water, stir after material is dissolved completely, mixed solution is heated to 40-50 DEG C, then adds polyethylene glycol oxide, be uniformly mixed 30-40min, gained solution for standby;
(2) clarification limewash is dropwise added in Ludox slowly, and constantly stir, add nano carbon sol again after dropwising, continue to be uniformly mixed, finally the solution of gained mixed solution with step (1) gained is mixed completely, obtain wicker pretreating agent.
Pretreating agent advantage prepared by the present invention is: preparation method is simple, composition environment-protecting asepsis, it has good permeability, high pressure is utilized to be penetrated into after in wicker fiber during use, nano-sized carbon wherein, the complex carriers such as nano-silicon enter in fiber, absorption that can be good is attached to it, reach and improve fibre structure, strengthen, toughness reinforcing, the effects such as protection, wicker after process resistivity to external world strengthens, shaping persistence is good, not easy to crack, the life of product be woven into through pretreated like this wicker is longer, bearing capacity increases, widen the scope of application further.
Detailed description of the invention
Embodiment
The pretreating agent of the present embodiment is obtained by the raw material of following weight portion (kilogram): Ludox 11, water 45 that the nano carbon sol 8 that solid content is 15%, Sodium Polyacrylate 0.1, potassium sorbate 0.02, polyethylene glycol oxide 1.2, clarification limewash 7, solid content are 25%.
The preparation method of the present embodiment inorganic agent is:
(1) first potassium sorbate, Sodium Polyacrylate are dropped in water, stir after material is dissolved completely, mixed solution is heated to 40-50 DEG C, then adds polyethylene glycol oxide, be uniformly mixed 35min, gained solution for standby;
(2) clarification limewash is dropwise added in Ludox slowly, and constantly stir, add nano carbon sol again after dropwising, continue to be uniformly mixed, finally the solution of gained mixed solution with step (1) gained is mixed completely, obtain wicker pretreating agent.
The compression strength of passing through the untreated wicker of comparatively same batch of the wicker that this pre-treatment treatment is crossed on average improves 44%, and bending strength on average improves 50%, and the product bearing capacity be woven on average improves 55%, and Long-Time Service is indeformable.

Claims (2)

1. the nano carbon sol for wicker plaiting article wicker-Ludox composite strengthening pretreating agent, it is characterized in that, this inorganic agent is made up of the raw material of following weight portion: solid content is nano carbon sol 8-10, the Sodium Polyacrylate 0.1-0.2 of 10-15%, potassium sorbate 0.01-0.02, polyethylene glycol oxide 1-1.5, clarification limewash 6-8, solid content are 20-25% Ludox 10-12, water 40-50.
2. the preparation method of a kind of nano carbon sol for wicker plaiting article wicker-Ludox composite strengthening pretreating agent as claimed in claim 1, it is characterized in that, described preparation method is:
(1) first potassium sorbate, Sodium Polyacrylate are dropped in water, stir after material is dissolved completely, mixed solution is heated to 40-50 DEG C, then adds polyethylene glycol oxide, be uniformly mixed 30-40min, gained solution for standby;
(2) clarification limewash is dropwise added in Ludox slowly, and constantly stir, add nano carbon sol again after dropwising, continue to be uniformly mixed, finally the solution of gained mixed solution with step (1) gained is mixed completely, obtain wicker pretreating agent.
CN201510981645.2A 2015-12-24 2015-12-24 Nano-carbon sol-silica sol composite enhancement pretreating agent for wickers for wickerwork and preparing method of nano-carbon sol-silica sol composite enhancement pretreating agent Pending CN105538454A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510981645.2A CN105538454A (en) 2015-12-24 2015-12-24 Nano-carbon sol-silica sol composite enhancement pretreating agent for wickers for wickerwork and preparing method of nano-carbon sol-silica sol composite enhancement pretreating agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510981645.2A CN105538454A (en) 2015-12-24 2015-12-24 Nano-carbon sol-silica sol composite enhancement pretreating agent for wickers for wickerwork and preparing method of nano-carbon sol-silica sol composite enhancement pretreating agent

Publications (1)

Publication Number Publication Date
CN105538454A true CN105538454A (en) 2016-05-04

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510981645.2A Pending CN105538454A (en) 2015-12-24 2015-12-24 Nano-carbon sol-silica sol composite enhancement pretreating agent for wickers for wickerwork and preparing method of nano-carbon sol-silica sol composite enhancement pretreating agent

Country Status (1)

Country Link
CN (1) CN105538454A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1492480A (en) * 2002-10-21 2004-04-28 台湾积体电路制造股份有限公司 Method for producing wafer with strain channel layer
CN102092068A (en) * 2010-11-23 2011-06-15 孟祥荣 Willow weaving raw material wicker and oak bark dip treating agent and using method thereof
CN103935036A (en) * 2014-04-02 2014-07-23 西安交通大学 Powder 3D (Three Dimensional) printing method using photosensitive sol binding agent

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1492480A (en) * 2002-10-21 2004-04-28 台湾积体电路制造股份有限公司 Method for producing wafer with strain channel layer
CN102092068A (en) * 2010-11-23 2011-06-15 孟祥荣 Willow weaving raw material wicker and oak bark dip treating agent and using method thereof
CN103935036A (en) * 2014-04-02 2014-07-23 西安交通大学 Powder 3D (Three Dimensional) printing method using photosensitive sol binding agent

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Application publication date: 20160504