CN105309452A - Efficacy-enhanced mite killing pesticide composition - Google Patents
Efficacy-enhanced mite killing pesticide composition Download PDFInfo
- Publication number
- CN105309452A CN105309452A CN201510675481.0A CN201510675481A CN105309452A CN 105309452 A CN105309452 A CN 105309452A CN 201510675481 A CN201510675481 A CN 201510675481A CN 105309452 A CN105309452 A CN 105309452A
- Authority
- CN
- China
- Prior art keywords
- mite killing
- composition pesticide
- synergistic
- killing composition
- dispersant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an efficacy-enhanced mite killing pesticide composition. The efficacy-enhanced mite killing pesticide composition is prepared from, by weight, 5-50% of effective ingredients, 1-10% of spirodiclofen, 0.5-5% of surface active agents, 1-5% of dispersing agents, 1-5% of anti-freezing agents, 0.5-5% of thickening agents, 0.05-0.5% of anti-corrosion agent and the balance water. The effective ingredients are prepared from abamectin and spirodiclofen with the mass ratio of 1 to 0.1-10. The composition has a remarkable prevention and control effect on all pest mites such as tetranychus cinnabarinus, panonychus citri and tetranychus urticae koch on crops such as flowers, fruit trees, vegetables, grains and cotton. The effective ingredients have an obvious synergistic effect, the pesticide effect of abamectin and spirodiclofen is improved through spirodiclofen in the composition, the field use amount and the pesticide use cost are decreased, and meanwhile the waterborne dosage form is the environment-friendly dosage form so that pollution to the environment can be reduced.
Description
Technical field
The invention belongs to agrochemical applications field, be specifically related to a kind of Synergistic mite killing composition pesticide.
Background technology
Avermectin, English name Avermectins, first the class developed by Japanese North university large village intelligence etc. and Merck company of the U.S. has desinsection, kills mite, ten hexa-atomic Macrocyclic lactone compounds of eelworm-killing activity, is fermented produce by streptomyces griseus Streptomycesavermitilis in streptomycete.Containing 8 components in natural A vermectins, mainly contain 4 kinds of i.e. A1a, A2a, B1a and B2a, its total content >=80%; The homologue that 4 corresponding ratios are less is A1b, A2b, B1b and B2b, its total content≤20%.After harmful Avermectin (abamectin) in 1991 enters China's pesticide market, Avermectis agricultural chemicals occupies more important status in the control of insect system of China.Avermectin is a kind of antibiotics insecticidal/acaricidal agent of efficient, wide spectrum, has stomach toxicity and action of contace poison to mite class and insect.Spray leaf surface and can decompose dissipation rapidly, the active ingredient infiltrated in plant parenchyma can be present in tissue and to have conduction the long period, has long residual effect to the insect taking food harm in evil mite and plant tissue.Be mainly used in poultry, domestic animal endoparasite and ectoparasite and crop pests, worm as red in parasitism, diptera, coleoptera, Lepidoptera and pest mite etc.
Spiral shell mite ester, also known as mite danger Envidor, Bayer Bitterfeld GmbH is researched and developed, tetronic acid class miticide.The mode of action: have the brand-new mechanism of action, tool action of contace poison, does not have interior absorption.The Fatty synthesis of main suppression mite, blocks the energy metabolism of mite, and each developmental stage of mite is all effective, comprises ovum.Kill mite and compose wide, strong adaptability: mite danger all has fine preventive effect to two spotted spider mite, yellow spider, Xiu Pi lice, yellow tea mite, Tetranychus cinnabarinus and Tetranychus urticae etc., the mite evil that can be used for the solanaceous crops such as the fruit tree such as citrus, grape and eggplant, capsicum, tomato is administered.In addition mite danger has insects such as pear sucker, oystershell scale and leafhopper classes and well doublely controls effect.Lasting period is long: the lasting period of mite danger is long, can control citrus red mite (crm) harm and reach 40 ~ 50 days on producing.Mite danger executes resistance of rainwater washing against after on crop leaf, and the normal performance that moderate rain does not affect drug effect met by spray medicine after 2 hours.Low toxicity, low-residual, safety are good.Very safe to crop under different temperature condition, to people and animals and crop safety, low toxicity.Without transreactance: mixedly now can to use with most of agricultural chemicals (strong basicity agricultural chemicals and copper agent except) is existing.Mixed with existing miticide, both can improve the quick-acting of mite danger, be conducive to again the resistance management of mite evil.
It is wide that agricultural phytophagy evil mite has damaging range, and generation is many, and reproduction speed is fast, and mostly occurs in the hidden place of vacuum side of blade, therefore prevents and treats very difficult.Miticide abuse causes evil mite pesticide resistance constantly to increase for a long time, and control efficiency reduces year by year.Therefore user be badly in need of efficiently, low toxicity, non-harmful Pesticidal products.The miticide of the different mechanism of action is carried out combine the mode effectively efficiently that synergy is the mite of control evil at present.In addition add the synergist that can reduce medical liquid surface tension, improve wet spreading ability, medicinal liquid osmosis ability in the formulation, become raising control efficiency, reduce dosage, reduce cost accounting, expanding prevention is composed, the effective means of the generation of delaying drug resistance.If publication number is CN101543213A, publication date is a kind of Insecticidal and acaricidal agent of 2009-9-30, its with spiral shell mite ester and Avermectin by weight carrying out composite for 60:1 ~ 1:10, active ingredient weight percent content is 0.1 ~ 80%, auxiliary material comprises organic solvent, emulsifier, surfactant, inert filler etc., but actual use finds, the control efficiency of such composition pesticide is still poor.
At present, Ye You peasant household, in order to improve the control efficiency of agricultural chemicals, adds pesticide synergistic agent in agricultural chemicals, but, pesticide synergistic agent of a great variety, and not often kind of pesticide synergistic agent is all applicable to all breeding times of crop, some pesticide synergistic agent can cause the generation of chemical injury of crops.
Summary of the invention
Technical problem to be solved by this invention is to provide the good Synergistic mite killing composition of a kind of control efficiency.
In order to solve the problems of the technologies described above, the present invention adopts following technical scheme:
A kind of Synergistic mite killing composition pesticide, by weight, the composition of raw materials of described Synergistic mite killing composition pesticide is as follows: active ingredient 5% ~ 50%, synergist 1% ~ 10%, surfactant 0.5% ~ 5%, dispersant 1% ~ 5%, antifreezing agent 1% ~ 5%, thickener 0.5% ~ 5%, preservative 0.05% ~ 0.5%, surplus is water; Wherein, Avermectin and the spiral shell mite ester of described active ingredient to be mass ratio be 1:0.1 ~ 10.
Preferably, the mass ratio that feeds intake of described Avermectin and described spiral shell mite ester is 1:4 ~ 8.
Further preferably, the mass ratio that feeds intake of described Avermectin and described spiral shell mite ester is 1:5 ~ 7.
Preferably, by weight, the composition of raw materials of described Synergistic mite killing composition pesticide is as follows: active ingredient 5% ~ 50%, synergist 3% ~ 8%, surfactant 0.5% ~ 5%, dispersant 1% ~ 5%, antifreezing agent 1% ~ 5%, thickener 0.5% ~ 5%, preservative 0.05% ~ 0.5%, surplus is water.
Further preferably, by weight, the composition of raw materials of described Synergistic mite killing composition pesticide is as follows: active ingredient 10% ~ 20%, synergist 3% ~ 8%, surfactant 0.5% ~ 5%, dispersant 1% ~ 5%, antifreezing agent 1% ~ 5%, thickener 0.5% ~ 5%, preservative 0.05% ~ 0.5%, surplus is water.
Still more preferably, by weight, the composition of raw materials of described Synergistic mite killing composition pesticide is as follows: active ingredient 10% ~ 20%, synergist 4% ~ 6%, surfactant 0.5% ~ 5%, dispersant 1% ~ 5%, antifreezing agent 1% ~ 5%, thickener 0.5% ~ 5%, preservative 0.05% ~ 0.5%, surplus is water.
Most preferably, by weight, the composition of raw materials of described Synergistic mite killing composition pesticide is as follows: active ingredient 10% ~ 20%, synergist 4% ~ 6%, surfactant 0.5% ~ 2%, dispersant 3% ~ 5%, antifreezing agent 3% ~ 5%, thickener 0.5% ~ 2%, preservative 0.1% ~ 0.2%, surplus is water.
Preferably, described synergist is polyether-modified trisiloxanes.
Preferably, described surfactant is one or more in styrylphenol polyoxyethylene ether, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether; Described dispersant is polycarboxylic acid salt's dispersant; Described antifreezing agent be selected from glycerine, propane diols, ethylene glycol one or more; Described thickener be selected from xanthans, aluminium-magnesium silicate, white carbon one or more; One or more for being selected from 1,2-benzisothiazole-3-ketone (BIT), methylisothiazolinone (MIT), Sodium Benzoate of described preservative.
Described styrylphenol polyoxyethylene ether is purchased from Beijing Zhi Jiefangyuan Science and Technology Ltd., described alkylphenol polyoxyethylene is purchased from Guangzhou Hong Dou Chemical Co., Ltd., described aliphatic amine polyoxyethylene ether is purchased from Boxing County, Shandong Province Da Chang oil and fat chemical Co., Ltd, described polycarboxylic acid salt's dispersant is purchased from Zibo Hua Tian Trade Co., Ltd., described glycerine, propane diols, ethylene glycol is purchased from Nanjing Yangzi petrochemical industry Co., Ltd, described xanthans is purchased from Shanghai Chemical Co., Ltd. of Hang Seng, aluminium-magnesium silicate and white carbon are purchased from Yongtai, Jinan Chemical Co., Ltd., described 1, 2-benzisothiazole-3-ketone (BIT) is purchased from Jinan ten thousand Duo Xin Chemical Co., Ltd., methylisothiazolinone (MIT) is purchased from Changzhou Run Yang Chemical Co., Ltd., purchased from same Tai Weirun Chemical Co., Ltd. in described Sodium Benzoate.
The preparation method of Synergistic mite killing composition pesticide of the present invention is: be mixed into mixture by above-mentioned active ingredient, synergist, surfactant, dispersant, antifreezing agent, thickener, preservative and water, after clipper tentatively shears mixing, add in sand mill and grind about 3h under 2000r/min rotating speed, measure particle diameter 90%<3 μm stop grinding, cross filter sanding media obtain.
Described Synergistic mite killing composition pesticide all has better control efficiency to all plant evils such as the Tetranychus cinnabarinus on agriculturally flowers, fruit tree, vegetables, grain and cotton wet goods crop, full pawl tetranychid, Tetranychus urticae, yellow tea mite mite.
Due to the enforcement of above technical scheme, the present invention compared with prior art tool has the following advantages:
The formula of Synergistic mite killing composition pesticide of the present invention is reasonable, preparation is novel, easy to use, significantly improve the control efficiency to plant evil mite, and can not chemical injury of crops be caused, can significantly reduce weeding cost, save manpower and reduce dispenser labour intensity, water base formulation is environmental protection formulation simultaneously, decreases the pollution to environment.
Embodiment
Below in conjunction with specific embodiment, technical scheme of the present invention is further described, but the present invention should not be limited to these embodiments, below described content be mass content.
Embodiment one, Toxicity Determination
First by Avermectin, the former medicine of spiral shell mite ester according to certain mass ratio machining experiment aqueous suspension agent, experiment is that field gathers apple full pawl tetranychid with worm, if through the first generation mite of indoor propagation hatching, select the female one-tenth mite of physiological status suppression.
Test method is with reference to farm-chemical indoor determination experiment criterion " NY/T1154.12-2008, tetranychid slide infusion process ".Double faced adhesive tape is cut into 2cm long, is affixed on one end of slide, then choose healthy female one-tenth mite, stick on glue by its back, every sheet 30, puts into and is lined with wet sponge container, cover lid, under being placed in 25 DEG C of conditions.Microscopy after 2h, rejects dead and injured individuality, supplies every sheet 30.5-7 series mass concentration is configured according to the method for geometric ratio or equal difference.Slide is dipped in after shaking 5S gently in liquid and takes out, suck unnecessary liquid with blotting paper, be placed in the ceramic whiteware dish being lined with wet sponge, use the covered rearing with plastic film that light transmission is good.
Often process and repeat for 4 times, and establish the process not containing medicament not make blank.After process, 48h checks examination worm death condition, records total borer population and death toll respectively.According to test requirements document and medicament feature, can shorten or extend the review time.
According to survey data, calculate the corrected mortality of each process.Calculate by formula (1) and (2), result of calculation all remains into 2 significant digits.
(1)P＝K/N*100
In formula: P-lethality, unit is percentage (%),
K-represents dead borer population, and unit is head;
N-represents the total borer population of process, and unit is head.
(2)P1＝(Pt-P0)/(1-P0)*100
In formula: P1-corrected mortality, unit is percentage (%); Pt-process lethality, unit is percentage (%); P0-blank lethality, unit is percentage (%).
If contrast lethality <5%, without the need to correcting; Contrast lethality, between 5%-20%, should correct by formula (2); Contrast lethality > 20%, test need be reformed.
Computational methods: analyze test data with DPS statistical analysis software, calculate the LC50 of each medicament, assess the insecticidal activity of each medicament.The co-toxicity coefficient (CTC value) of mixture is calculated according to the abundant method of Sun Yun.
Actual measurement toxicity index (ATI)=(standard agent standard agent LC50/ reagent agent LC50) × 100.
In theoretical toxicity index (TTI)=A medicament toxicity index × mixture, the percentage composition+B medicament virulence of A refers to
The percentage composition of B in number × mixture.
Co-toxicity coefficient (CTC)=[the theoretical toxicity index (TTI) of mixture actual measurement toxicity index (ATI)/mixture] × 100.
According to the NY/T1154.13-2008 insecticide combination effect criteria for classifying: co-toxicity coefficient (CTC) >=120 shows as synergistic effect; Co-toxicity coefficient (CTC)≤80 shows as antagonism; 80 < co-toxicity coefficient (CTC) < 120 show as summation action.Result of the test: refer to table 1.
Table 1
Toxicity Determination result shows: in said composition, the mass ratio of Avermectin and spiral shell mite ester is within the scope of 1:10-2:1, and co-toxicity coefficient is all greater than 120, and namely the biologically active of said composition to the full pawl tetranychid of apple shows synergistic effect.Wherein the mass ratio of Avermectin and spiral shell mite ester is when 1:4 and 1:6, and synergistic effect is more obvious, and co-toxicity coefficient is all greater than 140.
Prepared by embodiment two, complex composition suspending agent
In above-mentioned experimental basis, choose synergy the most obviously ratio Avermectin: spiral shell mite ester=1:6, add the polyether-modified trisiloxanes compound (TSS) of different content synergist, preparation aqueous suspension agent.
The composition of raw materials of embodiment 1 to 10 respectively see table 2 to 11 (for mass percent).
Table 2
| Composition | Ratio (%) |
| Avermectin | 2 |
| Spiral shell mite ester | 12 |
| TSS | 1 |
| Styrylphenol polyoxyethylene ether | 1 |
| Polycarboxylic acid salt's dispersant | 3 |
| Glycerine | 4 |
| Xanthans | 0.5 |
| BIT | 0.1 |
| Water | Supply 100 |
Table 3
Table 4
| Composition | Ratio (%) |
| Avermectin | 2 |
| Spiral shell mite ester | 12 |
| TSS | 3 |
| Styrylphenol polyoxyethylene ether | 1 |
| Polycarboxylic acid salt's dispersant | 3 |
| Propane diols | 4 |
| Xanthans | 0.5 |
| Sodium Benzoate | 0.1 |
| Water | Supply 100 |
Table 5
| Composition | Ratio (%) |
| Avermectin | 2 |
| Spiral shell mite ester | 12 |
| TSS | 4 |
| Alkylphenol polyoxyethylene | 1 |
| Polycarboxylic acid salt's dispersant | 3 |
| Propane diols | 4 |
| Xanthans | 0.5 |
| Aluminium-magnesium silicate | 1.0 |
| MIT | 0.1 |
| BIT | 0.1 |
| Water | Supply 100 |
Table 6
| Composition | Ratio (%) |
| Avermectin | 2 |
| Spiral shell mite ester | 12 |
| TSS | 5 |
| Alkylphenol polyoxyethylene | 1.5 |
| Polycarboxylic acid salt's dispersant | 3 |
| Propane diols | 4 |
| Xanthans | 0.5 |
| Sodium Benzoate | 0.1 |
| Water | Supply 100 |
Table 7
Table 8
| Composition | Ratio (%) |
| Avermectin | 2 |
| Spiral shell mite ester | 12 |
| TSS | 7 |
| Styrylphenol polyoxyethylene ether | 1 |
| Polycarboxylic acid salt's dispersant | 3 |
| Glycerine | 4 |
| Xanthans | 0.5 |
| Aluminium-magnesium silicate | 1 |
| BIT | 0.1 |
| Water | Supply 100 |
Table 9
| Composition | Ratio (%) |
| Avermectin | 2 |
| Spiral shell mite ester | 12 |
| TSS | 8 |
| Aliphatic amine polyoxyethylene ether | 1.5 |
| Polycarboxylic acid salt's dispersant | 4 |
| Propane diols | 4 |
| Aluminium-magnesium silicate | 0.8 |
| Xanthans | 0.5 |
| MIT | 0.1 |
| Water | Supply 100 |
Table 10
| Composition | Ratio (%) |
| Avermectin | 2 |
| Spiral shell mite ester | 12 |
| TSS | 9 |
| Aliphatic amine polyoxyethylene ether | 1.5 |
| Polycarboxylic acid salt's dispersant | 4 |
| Propane diols | 4 |
| Xanthans | 0.5 |
| Aluminium-magnesium silicate | 1.2 |
| Sodium Benzoate | 0.1 |
| Water | Supply 100 |
Table 11
| Composition | Ratio (%) |
| Avermectin | 2 |
| Spiral shell mite ester | 12 |
| TSS | 10 |
| Aliphatic amine polyoxyethylene ether | 1.5 |
| Polycarboxylic acid salt's dispersant | 4 |
| Propane diols | 4 |
| Xanthans | 0.5 |
| MIT | 0.1 |
| Water | Supply 100 |
Embodiment three
Polyether-modified trisiloxanes compound and Avermectin, spiral shell mite ester composition are to apple full pawl tetranychid field control effectiveness test.By aqueous suspension agent obtained for the embodiment 1 to 10 in embodiment two, carry out the field control effectiveness test to apple Tetranychus cinnabarinus.Method is with reference to national standard pesticide field efficacy medicine test criterion (one) miticide control apple tetranychus GB/T17980.7-2000.Experimental result is in table 13, and wherein the composition of raw materials of comparative example is see table 12.
Table 12
| Composition | Ratio (%) |
| Avermectin | 2 |
| Spiral shell mite ester | 12 |
| Alkylphenol polyoxyethylene | 1.5 |
| Polycarboxylic acid salt's dispersant | 3 |
| Propane diols | 4 |
| Xanthans | 0.5 |
| Sodium Benzoate | 0.1 |
| Water | Supply 100 |
Table 13
As seen from the above table, after adding synergist, field efficacy is improved, and wherein addition 3%-8% is preferred addition, and addition is 5%, and drug effect improves the most obvious.
Above-described embodiment is just for illustrating technical conceive of the present invention and feature; its object is to person skilled in the art can be understood content of the present invention and implement according to this; can not limit the scope of the invention with this; all equivalences done according to Spirit Essence of the present invention change or modify, and all should be encompassed within protection scope of the present invention.
Claims (10)
1. a Synergistic mite killing composition pesticide, it is characterized in that: by weight, the composition of raw materials of described Synergistic mite killing composition pesticide is as follows: active ingredient 5% ~ 50%, synergist 1% ~ 10%, surfactant 0.5% ~ 5%, dispersant 1% ~ 5%, antifreezing agent 1% ~ 5%, thickener 0.5% ~ 5%, preservative 0.05% ~ 0.5%, surplus is water; Wherein, Avermectin and the spiral shell mite ester of described active ingredient to be mass ratio be 1:0.1 ~ 10.
2. Synergistic mite killing composition pesticide according to claim 1, is characterized in that: the mass ratio that feeds intake of described Avermectin and described spiral shell mite ester is 1:4 ~ 8.
3. Synergistic mite killing composition pesticide according to claim 2, is characterized in that: the mass ratio that feeds intake of described Avermectin and described spiral shell mite ester is 1:5 ~ 7.
4. Synergistic mite killing composition pesticide according to claim 1, it is characterized in that: by weight, the composition of raw materials of described Synergistic mite killing composition pesticide is as follows: active ingredient 5% ~ 50%, synergist 3% ~ 8%, surfactant 0.5% ~ 5%, dispersant 1% ~ 5%, antifreezing agent 1% ~ 5%, thickener 0.5% ~ 5%, preservative 0.05% ~ 0.5%, surplus is water.
5. Synergistic mite killing composition pesticide according to claim 4, it is characterized in that: by weight, the composition of raw materials of described Synergistic mite killing composition pesticide is as follows: active ingredient 10% ~ 20%, synergist 3% ~ 8%, surfactant 0.5% ~ 5%, dispersant 1% ~ 5%, antifreezing agent 1% ~ 5%, thickener 0.5% ~ 5%, preservative 0.05% ~ 0.5%, surplus is water.
6. Synergistic mite killing composition pesticide according to claim 5, it is characterized in that: by weight, the composition of raw materials of described Synergistic mite killing composition pesticide is as follows: active ingredient 10% ~ 20%, synergist 4% ~ 6%, surfactant 0.5% ~ 5%, dispersant 1% ~ 5%, antifreezing agent 1% ~ 5%, thickener 0.5% ~ 5%, preservative 0.05% ~ 0.5%, surplus is water.
7. Synergistic mite killing composition pesticide according to claim 6, it is characterized in that: by weight, the composition of raw materials of described Synergistic mite killing composition pesticide is as follows: active ingredient 10% ~ 20%, synergist 4% ~ 6%, surfactant 0.5% ~ 2%, dispersant 3% ~ 5%, antifreezing agent 3% ~ 5%, thickener 0.5% ~ 2%, preservative 0.1% ~ 0.2%, surplus is water.
8. Synergistic mite killing composition pesticide according to claim 1, is characterized in that: described synergist is polyether-modified trisiloxanes.
9. Synergistic mite killing composition pesticide according to claim 1, is characterized in that: described surfactant is one or more in styrylphenol polyoxyethylene ether, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether; Described dispersant is polycarboxylic acid salt's dispersant; Described antifreezing agent be selected from glycerine, propane diols, ethylene glycol one or more; Described thickener be selected from xanthans, aluminium-magnesium silicate, white carbon one or more; One or more for being selected from 1,2-benzisothiazole-3-ketone, methylisothiazolinone, Sodium Benzoate of described preservative.
10. the Synergistic mite killing composition pesticide according to any one of claim 1 to 9 is for preventing and treating the purposes of the Agricultural Mites on flowers, fruit tree, vegetables, grain, cotton crop.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510675481.0A CN105309452A (en) | 2015-10-19 | 2015-10-19 | Efficacy-enhanced mite killing pesticide composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510675481.0A CN105309452A (en) | 2015-10-19 | 2015-10-19 | Efficacy-enhanced mite killing pesticide composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105309452A true CN105309452A (en) | 2016-02-10 |
Family
ID=55238551
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510675481.0A Pending CN105309452A (en) | 2015-10-19 | 2015-10-19 | Efficacy-enhanced mite killing pesticide composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105309452A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111109271A (en) * | 2019-12-13 | 2020-05-08 | 广西金穗生态科技股份有限公司 | Dragon fruit root mite killing composition and prevention and control method of dragon fruit root mites |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1252220A (en) * | 1998-10-23 | 2000-05-10 | 拜尔公司 | Composition with pesticide and miticide property active compound |
| CN101300979A (en) * | 2008-07-08 | 2008-11-12 | 广西田园生化股份有限公司 | Compounded pesticide composition containing Spirodiclofen |
| CN101366379A (en) * | 2007-06-29 | 2009-02-18 | 拜尔农作物科学股份公司 | Acaricidal active substance combinations |
| CN101543213A (en) * | 2008-03-25 | 2009-09-30 | 山东京博控股发展有限公司 | Composition of insecticide and acaricide |
| CN103734151A (en) * | 2013-12-28 | 2014-04-23 | 上海艳紫化工科技有限公司 | Insecticidal and mite-killing suspending agent obtained by compounding abamectin and spirodiclofen |
| US20140212387A1 (en) * | 2011-05-27 | 2014-07-31 | Bayer Intellectual Property Gmbh | Liquid preparation for biological plant protection, method for producing it and use thereof |
-
2015
- 2015-10-19 CN CN201510675481.0A patent/CN105309452A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1252220A (en) * | 1998-10-23 | 2000-05-10 | 拜尔公司 | Composition with pesticide and miticide property active compound |
| CN101366379A (en) * | 2007-06-29 | 2009-02-18 | 拜尔农作物科学股份公司 | Acaricidal active substance combinations |
| CN101543213A (en) * | 2008-03-25 | 2009-09-30 | 山东京博控股发展有限公司 | Composition of insecticide and acaricide |
| CN101300979A (en) * | 2008-07-08 | 2008-11-12 | 广西田园生化股份有限公司 | Compounded pesticide composition containing Spirodiclofen |
| US20140212387A1 (en) * | 2011-05-27 | 2014-07-31 | Bayer Intellectual Property Gmbh | Liquid preparation for biological plant protection, method for producing it and use thereof |
| CN103734151A (en) * | 2013-12-28 | 2014-04-23 | 上海艳紫化工科技有限公司 | Insecticidal and mite-killing suspending agent obtained by compounding abamectin and spirodiclofen |
Non-Patent Citations (1)
| Title |
|---|
| 廖洪流: "有机硅助剂在农业中的应用进展", 《精细与专用化学品》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111109271A (en) * | 2019-12-13 | 2020-05-08 | 广西金穗生态科技股份有限公司 | Dragon fruit root mite killing composition and prevention and control method of dragon fruit root mites |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102113505B (en) | Composition containing acetamiprid for controlling brontispa longissima | |
| CN103355314A (en) | Acaricidal composition containing pyriminostrobin and etoxazole | |
| CN105123699B (en) | A kind of insecticide and acaricide containing thymol and Nylar | |
| CN103947655B (en) | A kind of Pesticidal combination comprising ivermectin and spiral shell mite ester | |
| CN103493831B (en) | A kind of Pesticidal combination containing phonetic mite amine and tetronic acid insecticides | |
| CN106376565B (en) | A kind of Pesticidal combination containing capillary and Celastrus angulatus | |
| CN101642108A (en) | Pesticidal composition with synergistic effect | |
| CN109392942A (en) | A kind of Pesticidal combination containing indoxacarb and bistrifluron | |
| CN103636621A (en) | Pesticide composition containing etoxazole and azadirachtin | |
| CN114916555B (en) | Application of pesticide composition containing bistrifluron in controlling plant pest mites | |
| CN103329905B (en) | Sterilization composition containing penflufen and validamycin | |
| CN105309452A (en) | Efficacy-enhanced mite killing pesticide composition | |
| CN101653129A (en) | Pesticide composition | |
| CN103931649B (en) | The Pesticidal combination of emamectin-benzoate and cholrempenthrin | |
| CN102792972A (en) | Insecticide compound comprising guadipyr and metarrhizium anisopliae | |
| CN102599168A (en) | Pesticide composition containing Tolfenpyrad and Envidor | |
| CN105309441B (en) | Composition pesticide containing nitrile pyrrole mite ester and its purposes in prevention and treatment harmful mite | |
| CN104186529A (en) | Pesticide composition containing imidaclothiz and spirotetramat | |
| CN109380258A (en) | A kind of insecticide composition and its production method with synergistic effect | |
| CN103651444A (en) | Pesticide combination | |
| CN103875700A (en) | Insecticidal composition and applications thereof in controlling insects with piercing-sucking mouthpart | |
| CN109392909A (en) | A kind of miticide composition containing fluorine pyrrole furanone and chlorfenapyr | |
| CN104996434A (en) | Pesticide composition containing tolfenpxrad and etoxazole | |
| CN101856034A (en) | Pesticide composition containing etoxazole and fenpropathrin | |
| CN101971858A (en) | Pesticide composition containing bifenazate and fenpropathrin |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160210 |
|
| RJ01 | Rejection of invention patent application after publication |