CN1252220A - Composition with pesticide and miticide property active compound - Google Patents

Composition with pesticide and miticide property active compound Download PDF

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Publication number
CN1252220A
CN1252220A CN99123326A CN99123326A CN1252220A CN 1252220 A CN1252220 A CN 1252220A CN 99123326 A CN99123326 A CN 99123326A CN 99123326 A CN99123326 A CN 99123326A CN 1252220 A CN1252220 A CN 1252220A
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Prior art keywords
general formula
reactive compound
group reactive
active compound
compound
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R·菲舍尔
C·埃德伦
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Bayer AG
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Bayer AG
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/12—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

To obtain an insecticidal and acaricidal composition having good insecticidal and acaricidal characteristics by including a dihydrofuranone derivative and a specific macrolide, an extender and/or a surfactant. This composition is obtained by including an active compound combined formulation comprising (A) a dihydrofuranone derivative represented by formula I, (B) one or more macrolides selected from 17 kinds of compounds such as (i) a phenylhydrazine derivative represented by formula II (bifenazate), (ii) a mcrolide represented by formula III in which common name is abamectin, (iii) a naphthalenedione derivative represented by formula IV (acequinocyl) and (iv) a pyrrole derivative represented by formula V (chlorfenapyr) and (C) an extender and/or a surfactant. Although the ingredient A is a known compound and the ingredient B is a known pest controlling active compound, satisfactory effects are obtained at a low application ratio by combining the ingredients.

Description

Composition with reactive compound of desinsection and acaricidal properties
The present invention relates to the composition of novel reactive compound, it contains a known dihydrofuran ketone derivatives on the one hand, contains other known pesticide activity on the other hand again, and has good desinsection and acaricidal properties.
Know the dihydrofuran ketone derivatives of general formula (I)
Figure A9912332600091
Can be used for preventing and treating the animal pest.For example insect and the evil mite (seeing EP-A 0528156).The activity of this material is good, but can stay some needed things sometimes when hanging down consumption.
And known, many heterocycles, organo-tin compound, benzoyl area kind and pyrethroid have desinsection and acaricidal properties (see WO 93-22297, WO 93-10083, DE-A 2641343, EP-A 0347488, EP-A 0210487, US-A 3264177 and EP-A 0234045), the activity of these materials is also dissatisfied when hanging down consumption.
Find that now the dihydrofuran ketone derivatives of novel general formula (I) and the active compound combinations of following compound have good desinsection and acaricidal properties.
These compounds are
(1) phenylhydrazine derivant (Bifenazate) of general formula (II)
Figure A9912332600101
And/or
(2) has common name abamectin (Olivomitecidin) macrolide (III)
And/or
(3) the naphthalenedione derivative of general formula (IV) (the mite quinone goes out).
And/or
(4) azole derivatives of general formula (V) (fluorine azoles worm is clear)
Figure A9912332600103
And/or
(5) thiourea derivative of general formula (VI) (it is grand to kill mite sulphur)
Figure A9912332600111
And/or
(6) general formula (VII) De oxazoline derivative (Te Ben oxazole)
Figure A9912332600112
And/or
(7) organic tin derivates of general formula (VIII)
Figure A9912332600113
Wherein
The R representative
(VIIIa=azoles ring tin)
Or
R representative-OH
(VIIIb=plictran)
And/or
(8) pyrazole derivatives (tebufenpyrad) of general formula (IX)
And/or
(9) pyrazole derivatives of general formula (X) (azoles mite ester)
Figure A9912332600122
And/or
(10) pyridazinone derivative (pyridaben) of general formula (XI)
And/or
(11) benzoyl urea (flufenoxuron) of general formula (XII)
Figure A9912332600124
And/or
(12) pyrethroid (bifenthrin) of general formula (XIII)
Figure A9912332600131
And/or
(13) tetrazine derivatives of general formula (XIV) (four mite piperazines)
And/or
(14) organic tin derivates (fenbutatin oxide) of general formula (XV)
Figure A9912332600133
And/or
(15) sulfenamide of general formula (XVI) (two first Euparen)
Figure A9912332600134
And/or
(16) general formula of learning from WO 94-02470 and EP 0883991 (XVII) and pyrimidine alcohol ether (XVIII)
Figure A9912332600141
R=Cl (XVII); (4-[(4-chloro-α, α, α-three fluoro-3-tolyl) oxygen]-6-[(α, α, α-4-tetrafluoro-3-tolyl) oxygen] pyrimidine)
R=NO 2(XVIII); 4-[(4-chloro-α, α, α-three fluoro-3-tolyl) oxygen]-6[(α, α, α-three fluoro-4-nitro-3-tolyl) oxygen] pyrimidine
R=Br (XIX); 4-[(4-chloro-α, α, α-three fluoro-3-tolyl) oxygen]-6-[(α, α, α-three fluoro-4-bromo-3-tolyl) oxygen] pyrimidine
And/or
(17) macrolide of general formula (XX) (spinosad SPINOSYN 105)
Figure A9912332600142
Preferred 85% spinosyn A R=H
15% spinosyn B R=CH 3Mixture
Surprised is, more much higher than the active summation of each reactive compound according to the desinsection and the acaricidal activity of active compound combinations of the present invention.So this is unexpected real synergistic effect, be not only active addition.
The dihydrofuran ketone derivatives of general formula (I) is known (seeing EP-A 0528156).
General formula (VIII) comprises general formula (VIIIa) (azoles ring tin) And general formula (VIIIb) (plictran)
Figure A9912332600152
Desinsection and the acaricidal activity component considered in active compound combinations according to the present invention except the dihydrofuran ketone derivatives of general formula (I), also all are known.These reactive compounds have particularly been done introduction in following publication:
(1) phenylhydrazine derivant of general formula (II)
WO?93-10?083
(2) macrolide of common name abamectin (III) (Olivomitecidin)
DE-A?2717040
(3) the naphthalenedione derivative of general formula (IV)
DE-A?2641?343
(4) azole derivatives of general formula (V)
EP-A?0347?488
(5) thiourea derivative of general formula (VI)
EP-A?0210?487
(6) general formula (VII) De oxazoline derivative
WO?93-22297
(7) organic tin derivates of general formula (VIIIa)
The agricultural chemicals handbook, 9 editions (The Pesticide Manual) general formulas (VIIIb) p.48
US-A?3?264?177
(8) azole derivatives of general formula (IX)
Farm chemicals handbook, 1998, C 328 (Farm ChemicalsHandbook)
(9) azole derivatives of general formula (X)
EP-A?0234045
(10) pyridazinone derivative of general formula (XI)
EP-A?0134439
(11) benzoyl urea of general formula (XII)
EP-A?0161019
(12) pyrethroid of general formula (XIII)
EP-A?0049977
(13) tetrazine derivatives of general formula (XIV)
EP-A?0?005?912
(14) organic tin derivates of general formula (XV)
DE-A?2115?666
(15) sulfenamide of general formula (XVI)
The agricultural chemicals handbook, 11 editions, 1997, p.1208
(16) the pyrimidine alcohol ether of general formula (XVII)～(XIX)
WO 94-02470 and EP-A 883 991 Hes
(17) SPINOSYN 105 of general formula (XX)
EP-A?0375?316。
Except the reactive compound of general formula (I), contain a kind of reactive compound the compound from (1) to (17) at least according to active compound combinations of the present invention.In addition, their activity that also can contain other desinsection and/or kill mite component altogether.
If in active compound combinations according to the present invention, reactive compound is to exist with the weight ratio of determining, synergistic effect is significant especially., the weight ratio of reactive compound can change in wide relatively scope in active compound combinations.Generally,
From the reactive compound of (1) group, from 0.1～5 part, the weight meter, preferably from 0.2～3 part, the weight meter,
From the reactive compound of (2) group, from 0.01～2 part, the weight meter, preferably from 0.05～1 part, the weight meter,
From the reactive compound of (3) group, from 0.1～5 part, the weight meter, preferably from 0.2～3 part, the weight meter,
From the reactive compound of (4) group, from 0.1～10 part, the weight meter, preferably from 0.5～5 part, the weight meter,
From the reactive compound of (5) group, from 1～10 part, the weight meter, preferably from 2～5 parts, the weight meter,
From the reactive compound of (6) group, from 0.1～5 part, the weight meter, preferred 0.2～3 part, the weight meter,
From the reactive compound of (7) group, from 0.5～10 part, the weight meter, preferably from 1～5 part, the weight meter,
From the reactive compound of (8) group, from 0.1～5 part, the weight meter, preferably from 0.2～3 part, the weight meter,
From the reactive compound of (9) group, from 0.1～5 part, the weight meter, preferably from 0.2～3 part, the weight meter,
From the reactive compound of (10) group, from 0.1～5 part, the weight meter, preferably from 0.2～3 part, the weight meter,
From the reactive compound of (11) group, from 0.05～5 part, the weight meter, preferably from 0.1～3 part, the weight meter,
From the reactive compound of (12) group, from 0.01～2 part, the weight meter, preferred 0.05～1 part, the weight meter,
From the reactive compound of (13) group, from 0.5～10 part, the weight meter, preferably from 2～5 parts, the weight meter,
From the reactive compound of (14) group, from 0.5～10 part, the weight meter, preferably from 1～5 part, the weight meter,
From the reactive compound of (15) group, from 0.5～10 part, the weight meter, preferably from 1～5 part, the weight meter,
From the reactive compound of (16) group, from 0.05～5 part, the weight meter, preferably from 0.2～3 part, the weight meter, and/or
From the reactive compound of (17) group, from 0.05～5 part, the weight meter, preferably from 0.2～3 part, the weight meter, more than all be equipped with general formula (I) reactive compound of per 1 part of weight meter.
Active compound combinations according to the present invention is applicable to control circuitous animal pest that arrives aspect the protection of agricultural, forest, storage product and material and health, preferred arthropods and nematode, particularly insect and evil mite.They all have activity to common sensitive strain and resistant strain and the insect of all developmental stage or some developmental stage.Above-mentioned pest comprises:
Isopoda, ball pillworm for example, armadillidum vulgare and pillworm (Porcellio scaber)
Believe sufficient guiding principle, for example have a zebra land
Chilopoda, for example food fruit DIWUGONG and common house centipede.
Symphyla, for example flower garden common house centipede
Thysanoptera, for example silverfiss
Collembola is for example equiped with arms Onychiurus arcticus
Blattaria, oriental cockroach for example, American cockroach, Ma Dela blattaria and Groton bug.
Orthoptera, acheta domestica for example, Gryllotalpa spp, African migratory locust, different black locust and desert locust.
Dermaptera, for example European earwig.
Isoptera, for example Reticulitermes.
Anoplura, grape phylloxera for example, the goitre woolly aphid belongs to, body louse, Haematopinus, Linognathus.
Mallophaga, for example Trichodectes and Damalinia.
Thrips, Frankliniella occidentalis for example, greenhouse Hercinothrips spp, palm thrips and onion thrips.
Semiptera, for example Eurygasterspp belongs to, red cotton bug, square butt stinkbug, bed bug, phodnius prolixus and vertebra Reduvius.
Homoptera, for example wild cabbage aleyrodid, cassava aleyrodid, greenhouse whitefly, cotten aphid, cabbage aphid, the tea sugarcane conceals knurl aphid, beans winged euonymus aphid, apple aphid, wooly aphis, mealy plum aphid, English grain aphid, tumor aphid genus, phorodon aphid, rhopalosiphum padi, Empoasca spp belongs to, the line leafhopper, rice leafhopper, the hard ball a red-spotted lizard of Europe fruit, olive black bourch, small brown rice planthopper, brown planthopper, red kidney Aspidiotus, the ivy Aspidiotus, mealybug belongs to and Psylla spp.
Lepidoptera, Pectinophora gossypiella for example, loose looper, the orchard autumn geometrid moth, the thin moth of apple, apple ermine moth, diamond-back moth, malacosoma neustria, the pornography and drug moth, Euproctis, cotton lyonetid, citrus leaf lyonetid, the ground Noctua is cut Noctua, Noctua, earias insulana, Heliothis, greedy noctuid, tomato moth, small noctuid, the nearly looper noctuid of tobacco, greedy Noctua, cabbage looper, codling moth, Pier, straw borer spp, corn borer, Anagasta kuehniella, galleria mellonella waxmoth, curtain rain moth, bag rain moth, brownly knit moth, yellow tail leaf roller, cigarette moth, the dragon spruce Choristoneura spp, grape codling moth (Clysia ambiguella), the green volume of tea long paper moth and oak moth.
Coleoptera, furniture death watch beetle for example, lesser grain borer, tea bean weevil, the North America house longhorn beetle, the willow Huang is chrysomelid, colorado potato beetles, the horseradish ape is chrysomelid, the chrysomelid genus of bar, rape golden head flea beetle, the big Epilachna spp of Mexico, latent food first belongs to, saw-toothed grain beetle, Anthonomus spp belongs to, Sitophilus, black grape ear image, the banana collar resembles, and seed resembles, and alfalfa leaf resembles, khapra beetle belongs to, and the spot khapra beetle belongs to, Anthrenus, fur is moth-eaten to be belonged to, and powder is moth-eaten to be belonged to, and the cauliflower nitidulid belongs to (Meligethes aeneus), Ptinus, golden spider beetle, globose spider beetle, Tribolium, bloom first, Agriotes spp, wide chest click beetle belongs to, May gill cockchafer, potato gill cockchafer and the brown New Zealand rib wing melolonthid.
Hymenoptera, for example pine sawfoy belongs to, real tenthredinidae, march fly belongs to, MonomoriumMayr and Vespa.
Diptera, Aedes for example, Anopheles, Culex, black-tailed fruit flies, Musca, Fannia, calliphora erythrocephala, Lucilia, Carysomyia, cuterbrid belongs to, Gasterophilus, Hippobosca, liriomyza bryoniae belongs to, Genus Stomoxys, Oestrus, Hypoderma, Gadfly, a smaller kind of cicada cicada belongs to (Tannia spp.), march fly, Oscinella frit, the grass Hylemyia, spinach spring fly, Mediterranean fruitfly, big trypetid of olive and European daddy-longlegs.
Siphonaptera, for example Xanthopsyllacheopis and Ceratophyllus.
Younger sister's shape guiding principle, for example scorpion and robber spider, erythema spider.
Acarina, Acarus siro for example, Argas, Ornithodoros, the perverse mite of cock skin, tea sugarcane goitre mite, citrus elephant skin thorn goitre mite, Boophilus, Rh, Amblyomma, Hyalomma, hard tick belongs to, the scabies mite belongs to, Psoroptes, and itch mite belongs to, and tarsonemid belongs to, Bryobia praetiosa, Panonychus citri belongs to and Tetranychus.
Can be successfully used to prevent and treat insect and the evil mite of harm plant especially according to active compound combinations of the present invention, Tetranychus for example, Panonychus citri belongs to, and half tarsonemid belongs to, and tarsonemid belongs to, short whisker Acarapis, elephant skin thorn Eriophyes, acupuncture Eriophyes and Eriophyes.
Under the pest control concentration required with doing harm to mite, plant is handled the stem of breeding and seed treatment and soil treatment to the acrial part that active compound combinations has the good chemical sproof fact to allow to do plant.Can pass through foliage applying according to active compound combinations of the present invention, also can do seed soaking and handle.
Can change various general formulations into according to active compound combinations of the present invention, solution for example, emulsion, suspending agent pulvis, foam, paste, granule, aerosol and the microcapsule formulations in polymer, the coated composition that seed is used, and ultra-low-volume formulation.
These formulations are produced by known method, for example, mix mutually with spreading agent by reactive compound or active compound combinations, spreading agent is a liquid flux, add liquefied gas and/or the solid carrier depressed, the optional surfactant that uses comprises emulsifier and/or dispersant, and/or blowing agent.If used spreading agent is a water, for example also may use organic solvent as cosolvent.Suitable liquid flux comprises substantially: aromatic hydrocarbons, dimethylbenzene for example, toluene or Fluhyzon, chlorinated aromatic hydrocarbons, or chlorinated aliphatic hydrocarbon, for example chlorobenzene, vinyl chloride or carrene, aliphatic hydrocarbon, for example cyclohexane or paraffin, petroleum cuts for example, alcohols, for example butanols or ethylene glycol and their ether and ester, ketone, acetone for example, MEK, methyl iso-butyl ketone (MIBK) or cyclohexanone, intensive polar solvent be dimethyl formamide and dimethyl sulfoxide (DMSO) for example, or water.Liquefied gas spreading agent or carrier can be regarded as nominal liquid, and it is a gas under room temperature and atmospheric pressure, for example aerosol propellant such as butane, propane, nitrogen or carbonic acid gas.Suitable solid carrier is the natural minerals that for example grinds, as kaolin, and clay, talcum, chalk, quartz, Attagel, montmorillonite or diatomite, and the synthetic mineral that grinds, as fine silicon dioxide, aluminium oxide and silicate, the suitable solid carrier that granule is used is: the natural rock that for example pulverizes and sieved, as calcite, marble, float stone, sepiolite and dolomite, or the particle of other synthetic inorganic and organic meal, organic particle is as sawdust, cocoa shell, corncob and tobacco rods.Suitable emulsifier and/or blowing agent are: for example nonionic and anion emulsifier, and as polyoxyethylene fatty acid ester, polyoxyethylene aliphatic alcohol ether, as alkylaryl polyglycol ether, alkylsulfonate, alkyl sulfate, arylsulphonate, or other protolysate.Suitable dispersant is: for example lignin-sulfite waste liquor and methylcellulose.
Tackifier are carboxymethyl cellulose and the natural and synthetic polymer that exists with powder, particle or emulsion form for example; as gum Arabic; polyvinyl alcohol and polyvinylacetate, or other natural phosphatide such as lecithin and cephalin and synthetic phosphatide all can use in prescription.Other additive can be mineral oil and rape oil.
Use for example inorganic pigment of pigment, as iron oxide, titanium oxide and Prussia orchid, and organic dyestuff, as alizarin dyes, azo dyes and metal phthalocyanine dyestuff, and the nutrient of trace for example iron, manganese, boron, copper, cobalt, molybdenum and zinc salt all are possible.
Various formulations generally contain the reactive compound of between 0.1 and 95% (weight meter), preferably between 0.5 and 90%.
In various formulations, active compound combinations according to the present invention can be used as and other reactive compound bactericide for example, insecticide, and the mixture of miticide and weed killer herbicide, and exist as the mixture with fertilizer or plant growth regulator.
Active compound combinations can they formulation form or thus the preparation type of service, as the solution that can directly use, missible oil, emulsion, suspension, wetting powder, soluble powder or granule go to use, and they are applied with usual way, for example by irrigating, spraying, dense fog, spreading, scatter, and the powder of handling as dry seeds, the water soluble powder of the solution seed treatment of seed treatment, the water soluble powder that slurries are handled, or use by dressing.
When using according to active compound combinations of the present invention, amount of application depends on the kind of using, and can change in wide relatively scope.When handling plant part, the amount of application of active compound combinations is generally 0.1 and 10, between the 000g/ha, preferred 10 and 1000g/ha between.
Good desinsection and acaricidal activity according to active compound combinations of the present invention can be confirmed from following example.And the weak activity of single reactive compound demonstration, the activity of composition has surpassed and has simply added and activity.
When the activity of active compound combinations surpasses the active summation of each reactive compound when using separately, there have been insecticide and acaricidal synergistic effect.
Prediction activity for the composition of determining of two kinds of reactive compounds can be calculated as follows (see S.R., Colby, Weeds 15 (1967), 20-22):
If
X is to be mg/ha at amount of application, the drug effect when using reactive compound A,
Y is to be ng/ha at amount of application, the drug effect when using reactive compound B,
E is to be m and ng/ha at amount of application, the drug effect when using reactive compound A and B,
So E = X + Y - X &CenterDot; Y 100
Drug effect is in %, and the 0%th, corresponding to the drug effect of contrast, and 100% drug effect means and does not see influence.
If actual activity has surpassed calculated value, the activity of composition adds so, that is to say, has synergistic effect.In this case, the drug effect that arrives of actual observation must be greater than the prediction drug effect of calculating from following formula (E).
Following example explanation the present invention.
Example A
Tetranychid test (OP-resistance/spraying is handled)
Solvent: 3 parts of dimethyl formamides, weight meter
Emulsifier: 1 part of alkylaryl polyglycol ether, weight meter
In order to prepare the appropriate formulations of reactive compound, the reactive compound or the active compound combinations of 1 part of weight meter mixed mutually with the solvent of said amount and the emulsifier of said amount, and water with the dope dilution agent to desired concn.
Spray on the Kidney bean that the greenhouse Tetranychus urticae of each vegetative stage seriously infects with the preparation of the reactive compound of desired concn.
Through behind the required time, to measure and kill %, 100% all Tetranychus urticaes of expression are killed; 0% expression does not have Tetranychus urticae to be killed.
Reactive compound, activity compound concentration and result of the test are shown in following table.
Table A
The mite of harm plant
Tetranychid test (OP-resistance/spraying is handled) Found=surveys active Calc.=according to Colby formula activity calculated

Claims (5)

1. desinsection and miticide composition is characterized in that they contain a kind of active compound combinations, and it consists of the dihydrofuran ketone derivatives of general formula (I)
Figure A9912332600021
With
(1) phenylhydrazine derivant (Bifenazate) of general formula (II)
Figure A9912332600022
And/or
(2) has common name Olivomitecidin (III) macrolide (abamectin)
And/or
(3) the naphthalenedione derivative of general formula (IV) (the mite quinone goes out).
Figure A9912332600023
And/or
(4) azole derivatives of general formula (V) (fluorine azoles worm is clear)
Figure A9912332600031
And/or
(5) thiourea derivative of general formula (VI) (it is grand to kill mite sulphur)
Figure A9912332600032
And/or
(6) general formula (VII) De oxazoline derivative (Te Ben oxazole)
And/or
(7) organic tin derivates of general formula (VIII) Wherein
The R representative
Figure A9912332600042
(VIIIa=azoles ring tin)
R representative-OH
(VIIIb=plictran)
And/or
(8) azole derivatives (tebufenpyrad) of general formula (IX)
Figure A9912332600043
And/or
(9) azole derivatives of general formula (X) (azoles mite ester)
Figure A9912332600044
And/or
(10) pyridazinone derivative (pyridaben) of general formula (XI)
Figure A9912332600051
And/or
(11) benzoyl urea (flufenoxuron) of general formula (XII)
Figure A9912332600052
And/or
(12) pyrethroid (bifenthrin) of general formula (XIII)
Figure A9912332600053
And/or
(13) tetrazine derivatives of general formula (XIV) (four mite piperazines)
Figure A9912332600054
And/or
(14) organo-tin compound (fenbutatin oxide) of general formula (XV)
Figure A9912332600061
And/or
(15) sulfenamide of general formula (XVI) (two first Euparen)
And/or
(16) general formula (XVII) and pyrimidine alcohol ether (XVIII)
Figure A9912332600063
R=Cl (XVII); (4-[(4-chloro-α, α, α-three fluoro-3-tolyl) oxygen]-6-[(α, α, α-4-tetrafluoro-3-tolyl) oxygen] pyrimidine)
R=NO 2(XVIII); 4-[(4-chloro-α, α, α-three fluoro-3-tolyl) oxygen]-6-[(α, α, α-three fluoro-4-nitro-3-tolyl) oxygen] pyrimidine
R=Br (XIX); 4-[(4-chloro-α, α, α-three fluoro-3-tolyl) oxygen]-6-[(α, α, α-three fluoro-4-bromo-3-tolyl) oxygen] pyrimidine
And/or
(17) macrolide of general formula (XX) (spinosad SPINOSYN 105)
Preferred 85% spinosyn A R=H
15% spinosyn B R=CH 3Mixture and spreading agent and/or surfactant.
2. the composition of claim 1 is characterized in that in active compound combinations, and the reactive compound of general formula (I) and the weight ratio of following reactive compound are:
With (1) group reactive compound, between 1: 0.1 and 1: 5,
With (2) group reactive compound, between 1: 0.01 and 1: 2,
With (3) group reactive compound, between 1: 0.1 and 1: 5,
With (4) group reactive compound, between 1: 0.1 and 1: 10,
With (5) group reactive compound, between 1: 1 and 1: 10,
With (6) group reactive compound, between 1: 0.1 and 1: 5,
With (7) group reactive compound, between 1: 0.5 and 1: 10,
With (8) group reactive compound, between 1: 0.1 and 1: 5,
With (9) group reactive compound, between 1: 0.1 and 1: 5,
With (10) group reactive compound, between 1: 0.1 and 1: 5,
With (11) group reactive compound, between 1: 0.05 and 1: 5,
With (12) group reactive compound, between 1: 0.01 and 1: 2,
With (13) group reactive compound, between 1: 0.5 and 1: 10,
With (14) group reactive compound, between 1: 0.5 and 1: 10,
With (15) group reactive compound, between 1: 0.5 and 1: 10,
With (16) group reactive compound, between 1: 0.05 and 1: 5,
With (17) group reactive compound, between 1: 0.05 and 1: 5.
3. the method for pest control and evil mite is characterized in that the active compound combinations of claim 1 is applied to pest and/or their habitat.
4. the application of the active compound combinations of claim 1 aspect pest control and evil mite.
5. the method for preparing desinsection and miticide composition is characterized in that the active compound combinations of claim 1 is mixed mutually with spreading agent and/or surfactant.
CN99123326A 1998-10-23 1999-10-22 Composition with pesticide and miticide property active compound Pending CN1252220A (en)

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