CN101300979A - Compounded pesticide composition containing Spirodiclofen - Google Patents

Compounded pesticide composition containing Spirodiclofen Download PDF

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Publication number
CN101300979A
CN101300979A CNA2008101326243A CN200810132624A CN101300979A CN 101300979 A CN101300979 A CN 101300979A CN A2008101326243 A CNA2008101326243 A CN A2008101326243A CN 200810132624 A CN200810132624 A CN 200810132624A CN 101300979 A CN101300979 A CN 101300979A
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China
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spiral shell
mite
weight
mite ester
shell mite
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CNA2008101326243A
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Chinese (zh)
Inventor
洪湖
唐静
徐博
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广西田园生化股份有限公司
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Priority to CNA2008101326243A priority Critical patent/CN101300979A/en
Publication of CN101300979A publication Critical patent/CN101300979A/en

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Abstract

The present invention relates to a compound agricultural chemical composition, characterized in that the composition is prepared by compounding envidor with one selected from avermectin, pyridaben, propargite, clofentezine or azocyclotin, preferably, the ratios by weight of the active ingredients, such as envidor to avermectin, envidor to pyridaben, envidor to propargite, envidor to clofentezine and envidor to azocyclotin, are respectively 250:1-0.4:1, 0.04:1-25:1, 1:125-1:0.2, 1:62.5-1:0.1 and 1:62.5-1:0.1.The compound agricultural chemical composition according to the present invention exhibits the efficacy and vigor levels greater than the active addition of the components, not only reducing dosage each unit of area, but also eliminating the fastness caused by slathering envidor and improving the control efficiency remarkably.

Description

A kind of compound pesticide composition that contains spiral shell mite ester

Technical field

The present invention relates to pesticide field, particularly contain the binary built composition pesticide of spiral shell mite ester, be mainly used in the oranges and tangerines Insecticiding-miticiding.

Background technology

The mite class is commonly called as two spotted spider mite, is arachnoide pest, and common harmful mite belongs to Acariformes and Acarina more, is one of important pests of harm multiple kinds of crops.The leaf of mite class harm plant, stem, flower etc., thorn is inhaled stem leaves of plants, is pest common on fruit tree, cotton, solanaceous vegetable and the ornamental flower, and there is the yellowish-brown point of a large amount of needle point size chlorosis in initial stage leaf front, the a large amount of from the bottom up chlorosis of anaphase blade are crispaturaed and are come off, and cause a large amount of fallen leaves.Sometimes begin to take place from plant middle part blade, blade is flavescence gradually.The mite evil takes place from generation to generation many, and fertility is strong, and under suitable temperature and humidity conditions, acarid quantity can increase rapidly exponentially in the short period, worked the mischief to crops such as fruit trees.And miticide easily developed immunity to drugs, if the evil mite seriously is taken place again less than timely control, the blade of the crop that is injured is understood chlorosis and is turned white, and withering and falling in advance works the mischief to crops such as fruit trees, and acarid is important pest.

Since the eighties in last century, citrus red mite has become topmost insect in the southern citrus production.Be the control citrus red mite, the tangerine farming needs to spray miticide 4~7 times, time-consuming taking a lot of work throughout the year.Because citrus red mite is from generation to generation many, breeding is fast, and miticide is easily developed immunity to drugs, and the good miticide kind of some original control efficiency is through using the obvious variation of miticidal effect for many years for a long time.Therefore, very need new miticide efficient, that the lasting period is long in the citrus production.Just under such background, Bayer Hangzhou crop science company has introduced Chinese market in 2005 with mite 24% suspending agent of endangering.Mite danger is the miticide of a brand-new mechanism of action developing more than ten years consuming time of Bayer Cropscience Co.,Ltd, and its active ingredient is spiral shell mite ester.Mite danger is destroyed the energy metabolism activity of acarid by suppressing the lipogenesis in the evil mite body, finally kills harmful mite.Its mite mechanism of killing is different from existing various miticide fully, so do not have the cross resistance problem with other existing miticide, can be used for preventing and treating multiple resistance tetranychid.

But spiral shell mite ester is to becoming mite effect and quick-acting relatively poor, and the agent of spiral shell mite ester list is used when insect density is high relatively certain limitation.And the agricultural chemicals of a kind of active ingredient of long-term single use will cause the generation of resistance very soon, thereby loses its using value.Itself and other pesticide active ingredient is combined into composite insecticide, is at present in exploitation with develop a kind of mode effectively and efficiently commonly used in the new insecticide pesticide.Main purpose with the composite back use of some single insecticidal constituents, except being its consumption of minimizing, improve insecticidal effect, reduce outside toxic action and the adverse effect the environment generation, another important purpose is exactly in order to solve the pesticide resistance that insect is produced the single component agricultural chemicals, make drug effect descend or be close to invalid agricultural chemicals and recover insecticidal effect again, even can also improve effect.Rule during agriculture chemical compounding is to guarantee that the composition of assembly should lack as far as possible under certain desinsection control efficiency prerequisite.

Summary of the invention

The compound pesticide composition of a composite composition among the present invention in spiral shell mite ester and Avermectin, pyridaben, alkynes mite spy, four mite piperazines, the azacyclotin, effectiveness that is showed and activity level have exceeded the stack of composition activity, and the result of this effect is known as synergistic effect.Not only reduce a mu dosage, can eliminate the mite class simultaneously to because a large amount of uses of spiral shell mite ester may cause the resistance that produces, its control efficiency is obviously improved, laborsaving, economical, minimizing environmental pollution is reduced farmer's burdens.

The objective of the invention is according to above-mentioned situation, provide a kind of by one in Avermectin, pyridaben, alkynes mite spy, four mite piperazines, the azacyclotin with the composite insecticide pesticide mixture preparation that forms of spiral shell mite ester.

Insecticide pesticide mixture preparation of the present invention is in Avermectin, pyridaben, alkynes mite spy, four mite piperazines, the azacyclotin one by active ingredient and forms with spiral shell mite ester, its part by weight is: spiral shell mite ester and Avermectin component ratio are 250: 1-0.4: 1, spiral shell mite ester and pyridaben component ratio are 0.04: 1-25: 1, the special component ratio of spiral shell mite ester and alkynes mite is 1: 125-1: 0.2, spiral shell mite ester and four mite piperazine component ratios are 1: 62.5-1: 0.1, and spiral shell mite ester and azacyclotin component ratio are 1: 62.5-1: 0.1.After adding proper assistant and carrier, make water-dispersible granules, suspending agent, wetting powder, aerosol, sustained release agent, aqueous emulsion, missible oil, microemulsion, effervescent tablet etc.

The present invention carries out composite mix preparation and application thereof by spiral shell mite ester and Avermectin, pyridaben, alkynes mite spy, four mite piperazines, azacyclotin etc., and advantage is:

1, brand new, mechanism of action uniqueness, behind the composite reagents such as spiral shell mite ester and Avermectin, have certain synergistic effect, reduce consumption separately, the adverse effect that reduces toxic action and environment is produced is applicable to be used for preventing and treating the pest mite class that existing miticide is produced resistance

2. the mite spectrum is wide extremely, adaptability is strong, behind the composite reagents such as spiral shell mite ester and Avermectin, not only two spotted spider mite, yellow spider, Xiu Pi lice, yellow tea mite, Tetranychus cinnabarinus and Tetranychus urticae etc. all there are fine preventive effect, in addition, insects such as pear sucker, oystershell scale and leafhopper class are had the well double effect of controlling.And quick-acting and late effect property are preferably arranged, and insecticidal action rapidly and lastingly.

Spiral shell mite ester respectively with composite reagent such as Avermectin after, it is excellent especially to kill the ovum effect, simultaneously to the children if mite also has good action of contace poison.Kill the ovum performance good with kill, the larva composite reagent, the raising control efficiency.

4. low toxicity, low-residual, safety are good, and the high price insecticide and at a low price pesticide compositional use with and reduce cost.

5. solve the pesticide resistance that insect is produced the single component agricultural chemicals, both can improve quick-acting, help the resistance management of mite evil again, even can also improve effect.

Part example of the present invention:

Embodiment:

The present invention carries out mixture preparation by spiral shell mite ester and Avermectin, pyridaben, alkynes mite spy, four mite piperazines, azacyclotin etc., mainly is research object with the citrus red mite, is used for the oranges and tangerines field, is pesticidal preparations.The active ingredient insecticide that the wood invention relates to is respectively:

Spiral shell mite ester Spirodiclofen (C 21H 24Cl 2O 4) 411.32

Avermectin Ivermectin

[B 1aC 48H 72O 14(R=C 2H 5)B 1bC 47H 70O 14(R=CH 3)]B 1a:872B 1b:858

Pyridaben Pyridaben (C 19H 25ClN 2OS) 364.93

Special Propargite (the C of alkynes mite 19H 26O 4S) 350.5

Four mite piperazine Clofentezine (C 14H 8Cl 2N 4) 303.15

Embodiment 1

54% spiral shell mite ester Avermectin water-dispersible granules compound method

Spiral shell mite ester 48% (weight)

Avermectin 6% (weight)

Naphthalene sulfonic acid formaldehyde condensation polymer 10% (weight)

Lauryl sodium sulfate 5% (weight)

Ammonium sulfate 15% (weight)

Potter's clay is supplied

Said mixture is evenly mixed, and comminution by gas stream adds suitable quantity of water and mediates, and the mixture pelleting of gained, is drying to obtain product.

Embodiment 2

35% spiral shell mite ester Damanling suspension agent compound method

Spiral shell mite ester 12% (weight)

Pyridaben 23% (weight)

Sodium lignin sulfonate 8% (weight)

JFC 3% (weight)

Farming newborn 600# 3% (weight)

Water is supplied

Various compositions are mixed, in sand mill, be ground to the active ingredient particle diameter less than 4 μ m.

Embodiment 3

The special wettable powder agent compounding method of 42% spiral shell mite ester alkynes mite

Spiral shell mite ester 6% (weight)

Alkynes mite spy 36% (weight)

Calcium lignosulfonate 12% (weight)

Draw back powder 5% (weight)

Lauryl sodium sulfate 3% (weight)

Kaolin is supplied

Various compositions are mixed, promptly obtain product by 325 mesh sieves through comminution by gas stream.

Embodiment 4

48% spiral shell mite ester, four mite piperazine missible oil compound methods

Spiral shell mite ester 18% (weight)

Four mite piperazines 30% (weight)

Emulsifier 603# 5% (weight)

Emulsifier 500# 5% (weight)

Dimethylbenzene is supplied

Various compositions are mixed, stir missible oil.

Embodiment 5

48% spiral shell mite ester azacyclotin wettable powder agent compounding method

Spiral shell mite ester 18% (weight)

Azacyclotin 30% (weight)

Calcium lignosulfonate 12% (weight)

Draw back powder 5% (weight)

Lauryl sodium sulfate 3% (weight)

Kaolin is supplied

Various compositions are mixed, promptly obtain product by 325 mesh sieves through comminution by gas stream.

Embodiment 6

18% spiral shell mite ester Avermectin suspending agent compound method

Spiral shell mite ester 16% (weight)

Avermectin 2% (weight)

Calcium lignosulfonate 5% (weight)

JFC 3% (weight)

Farming newborn 603# 2% (weight)

Thickener 5% (weight)

Water is supplied

Various compositions are mixed, in sand mill, be ground to the active ingredient particle diameter less than 4 μ m.

Embodiment 7

27% spiral shell mite ester Avermectin sustained release agent compound method

Spiral shell mite ester 24% (weight)

Avermectin 3% (weight)

SOPA 10% (weight)

Polyvinyl alcohol 5% (weight)

Water 28% (weight)

Active carbon 30% (weight)

Various compositions are mixed, in sand mill, be ground to the active ingredient particle diameter, be loaded on and make sustained release agent in the active carbon less than 4 μ m.

Embodiment 8

46% spiral shell mite ester pyridaben dry suspending agent compound method

Spiral shell mite ester 16% (weight)

Pyridaben 30% (weight)

Sodium lignin sulfonate 8% (weight)

Sodium phosphate trimer 3% (weight)

Kaolin 32% (weight)

Disintegrant 12% (weight)

Various compositions are mixed, pulverize, mix suitable water spray granulating and drying and get dry suspending agent.

Embodiment 9

32% spiral shell mite ester, four mite piperazine missible oil compound methods

Spiral shell mite ester 12% (weight)

Four mite piperazines 20% (weight)

Emulsifier 602# 8% (weight)

Emulsifier 500# 5% (weight)

Dimethylbenzene is supplied

Various compositions are mixed, stir missible oil.

Embodiment 10

30% spiral shell mite ester pyridaben missible oil compound method

Spiral shell mite ester 10% (weight)

Pyridaben 20% (weight)

Emulsifier 603# 7% (weight)

Emulsifier 500# 5% (weight)

Dimethylbenzene is supplied

Various compositions are mixed, stir missible oil.

Embodiment 11

24% spiral shell mite ester, four mite piperazine aqueous emulsion compound methods

Spiral shell mite ester 10% (weight)

Four mite piperazines 14% (weight)

Isopropyl alcohol 10% (weight)

Dimethylbenzene 5% (weight)

Emulsifier 600 # 10% (weight)

Water is supplied

Various compositions are mixed, in shearing still, be trimmed to the active ingredient particle diameter less than 3 μ m.

Embodiment 12

45% spiral shell mite ester abamectin emulsifiable concentrate compound method

Spiral shell mite ester 40% (weight)

Avermectin 5% (weight)

Emulsifier 602# 5% (weight)

Emulsifier 500# 5% (weight)

Dimethylbenzene is supplied

Various compositions are mixed, stir missible oil.

Embodiment 13

10% spiral shell mite ester avermectin micro-emulsion compound method

Spiral shell mite ester 9% (weight)

Avermectin 1% (weight)

Emulsifier 16% (weight)

Auxiliary agent 12% (weight)

Water is supplied

Various compositions are mixed, stir microemulsion.

Embodiment 14

The special effervescent tablet compound method of 30% spiral shell mite ester alkynes mite

Spiral shell mite ester 4% (weight)

Alkynes mite spy 26% (weight)

Calcium lignosulfonate 10% (weight)

Draw back powder 4% (weight)

Lauryl sodium sulfate 2% (weight)

Leafing agent is supplied

Various compositions are mixed, promptly obtain product by 325 mesh sieve compressing tablets through comminution by gas stream.

Embodiment 15

15% spiral shell mite ester pyridaben aerosol compound method

Spiral shell mite ester 5% (weight)

Pyridaben 10% (weight)

Calcium lignosulfonate 12% (weight)

JFC 4% (weight)

Farming newborn 603# 5% (weight)

Antifreezing agent 1% (weight)

Propane diols 10

Thinner is supplied

Behind former medicine and solid surfactant comminution by gas stream, add thinner and liquid surfactant then and grind to form the active ingredient particle diameter less than 3 μ m oily suspension, pack product.

Embodiment 16

Avermectin and spiral shell mite ester are to the control efficiency (embodiment 1,6,7,12,13) of citrus red mite

For clear and definite Avermectin and spiral shell mite ester list with and when using with to the control efficiency of citrus red mite, the applicant had carried out drug effect test of field zone and Toxicity Determination in 2007.

Field trial:

Handle 3000 times of 1:240 grams per liter spiral shell mite ester suspending agents,

Handle 2000 times of 2:1% abamectin emulsifiable concentrates

Handle 1500 times of 3:240 grams per liter spiral shell mite ester suspending agent 4500 times+1% abamectin emulsifiable concentrates

Handle 4: blank

As shown in Table 1,1500 times of 240 grams per liter spiral shell mite ester suspending agents, 4500 times+1% abamectin emulsifiable concentrates have good control efficiency to citrus red mite, and quick-acting and lasting effect all are better than single agent.

The effect of table 1 different disposal control citrus red mite

Toxicity Determination:

Selecting the resistance citrus red mite is target pest, and every processing repeats 4 times, and every concentration is handled 40, uses LC 50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient.

By data in the table as seen, the co-toxicity coefficient of spiral shell mite ester, 5 different proportioning antagonism citrus red mites of Avermectin illustrates that all greater than 100 two composite reagents have synergistic effect to citrus red mite.Spiral shell mite ester wherein: Avermectin active ingredient ratio is 10: 1 o'clock, and co-toxicity coefficient is the highest, is 149.8.Illustrate that two composite reagents are used to prevent and treat citrus red mite and have certain synergistic effect, can use in practice.

Table 2: spiral shell mite ester, Avermectin and 5 different proportionings are to citrus red mite toxicity test result

Embodiment 17

Pyridaben and spiral shell mite ester are to the control efficiency (embodiment 2,8,10) of citrus red mite

For clear and definite pyridaben and spiral shell mite ester list with and when using with to the control efficiency of citrus red mite, the applicant had carried out drug effect test of field zone and Toxicity Determination in 2007.

Field trial:

Handle 3000 times of 1:240 grams per liter spiral shell mite ester suspending agents,

Handle 1000 times of 2:15% pyridaben missible oil

Handle 1500 times of 3:240 grams per liter spiral shell mite ester suspending agent 4500 times+15% pyridaben missible oil

Handle 4: blank

As shown in Table 3,1500 times of 240 grams per liter spiral shell mite ester suspending agents, 4500 times+15% pyridaben missible oil have good control efficiency to citrus red mite, and quick-acting and lasting effect all are better than single agent.

The effect of table 3 different disposal control citrus red mite

Toxicity Determination:

Selecting the resistance citrus red mite is target pest, and every processing repeats 4 times, and every concentration is handled 40, uses LC 50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient.

By data in the table as seen, spiral shell mite ester, 5 different proportionings of pyridaben all greater than 100, illustrate that two composite reagents have synergistic effect to citrus red mite to the co-toxicity coefficient of citrus red mite.Spiral shell mite ester wherein: pyridaben active ingredient ratio is 1: 1 o'clock, and co-toxicity coefficient is the highest, is 158.5.Illustrate that two composite reagents are used to prevent and treat citrus red mite and have certain synergistic effect, can use in practice.

Table 4: spiral shell mite ester, pyridaben and 5 different proportionings are to citrus red mite toxicity test result

Embodiment 18

Alkynes mite spy and spiral shell mite ester are to the control efficiency (embodiment 3,14) of citrus red mite

For clear and definite alkynes mite special and spiral shell mite ester list usefulness and when using with to the control efficiency of citrus red mite, the applicant had carried out drug effect test of field zone and Toxicity Determination in 2007.

Field trial:

Handle 3000 times of 1:240 grams per liter spiral shell mite ester suspending agents,

Handle 1500 times of the special missible oil of 2:73% alkynes mite

Handle 2500 times of the special missible oil of 3:240 grams per liter spiral shell mite ester suspending agent 5000 times+73% alkynes mite

Handle 4: blank

As shown in Table 5,2500 times of special missible oil of 240 grams per liter spiral shell mite ester suspending agents, 5000 times+73% alkynes mite have good control efficiency to citrus red mite, and quick-acting and lasting effect all are better than single agent.

The effect of table 5 different disposal control citrus red mite

Toxicity Determination:

Selecting the resistance citrus red mite is target pest, and every processing repeats 4 times, and every concentration is handled 40, uses LC 50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient.

By data in the table as seen, special 5 the different proportionings of spiral shell mite ester, alkynes mite all greater than 100, illustrate that two composite reagents have synergistic effect to citrus red mite to the co-toxicity coefficient of citrus red mite.Spiral shell mite ester wherein: the peculiar effect component ratio of alkynes mite is 1: 25 o'clock, and co-toxicity coefficient is the highest, is 171.7.Illustrate that two composite reagents are used to prevent and treat citrus red mite and have certain synergistic effect, can use in practice.

Table 6: spiral shell mite ester, alkynes mite spy and 5 different proportionings are to citrus red mite toxicity test result

Embodiment 19

Four mite piperazines and spiral shell mite ester are to the control efficiency (embodiment 4,9,11) of citrus red mite

For clear and definite four mite piperazines and spiral shell mite ester list with and when using with to the control efficiency of citrus red mite, the applicant had carried out drug effect test of field zone and Toxicity Determination in 2007.

Field trial:

Handle 3000 times of 1:240 grams per liter spiral shell mite ester suspending agents,

Handle 1500 times of 2:20% clofentezine suspension agents

Handle 2500 times of 3:240 grams per liter spiral shell mite ester suspending agent 5000 times+20% clofentezine suspension agents

Handle 4: blank

As shown in Table 7,2500 times of 240 grams per liter spiral shell mite ester suspending agents, 5000 times+20% clofentezine suspension agents have good control efficiency to citrus red mite, and quick-acting and lasting effect all are better than single agent.

The effect of table 7 different disposal control citrus red mite

Toxicity Determination:

Selecting the resistance citrus red mite is a day mark insect, and every processing repeats 4 times, and every concentration is handled 40, uses LC 50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient.

By data in the table as seen, spiral shell mite ester, 5 different proportionings of four mite piperazines all greater than 100, illustrate that two composite reagents have synergistic effect to citrus red mite to the co-toxicity coefficient of citrus red mite.Spiral shell mite ester wherein: four mite piperazine active ingredient ratios are 1: 2.5 o'clock, and co-toxicity coefficient is the highest, is 169.9.Illustrate that two composite reagents are used to prevent and treat citrus red mite and have certain synergistic effect, can use in practice.

Table 8: spiral shell mite ester, four mite piperazines and 5 different proportionings are to citrus red mite toxicity test result

Embodiment 20

Azacyclotin and spiral shell mite ester are to the control efficiency (embodiment 5,15) of citrus red mite

For clear and definite azacyclotin and spiral shell mite ester list with and when using with to the control efficiency of citrus red mite, the applicant had carried out drug effect test of field zone and Toxicity Determination in 2007.

Field trial:

Handle 3000 times of 1:240 grams per liter spiral shell mite ester suspending agents,

Handle 1500 times of 2:20% azacyclotin suspending agents

Handle 2500 times of 3:240 grams per liter spiral shell mite ester suspending agent 5000 times+20% azacyclotin suspending agents

Handle 4: blank

As shown in Table 9,2500 times of 240 grams per liter spiral shell mite ester suspending agents, 5000 times+20% azacyclotin suspending agents have good control efficiency to citrus red mite, and quick-acting and lasting effect all are better than single agent.

The effect of table 9 different disposal control citrus red mite

Toxicity Determination:

Selecting the resistance citrus red mite is target pest, and every processing repeats 4 times, and every concentration is handled 40, uses LC 50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient.

By data in the table as seen, spiral shell mite ester, 5 different proportionings of azacyclotin all greater than 100, illustrate that two composite reagents have synergistic effect to citrus red mite to the co-toxicity coefficient of citrus red mite.Spiral shell mite ester wherein: azacyclotin active ingredient ratio is 1: 2.5 o'clock, and co-toxicity coefficient is the highest, is 189.1.Illustrate that two composite reagents are used to prevent and treat citrus red mite and have certain synergistic effect, can use in practice.

Table 10: spiral shell mite ester, azacyclotin and 5 different proportionings are to citrus red mite toxicity test result

Claims (7)

1. a compound pesticide composition is characterized in that, it is by composite forming in spiral shell mite ester and Avermectin, pyridaben, alkynes mite spy, four mite piperazines or the azacyclotin.
2. according to the compound pesticide composition of claim 1, it is characterized in that spiral shell mite ester and Avermectin component ratio are 250: 1-0.4: 1.
3. according to the compound pesticide composition of claim 1, it is characterized in that spiral shell mite ester and pyridaben component ratio are 0.04: 1-25: 1.
4. according to the compound pesticide composition of claim 1, it is characterized in that the special component ratio of spiral shell mite ester and alkynes mite is 1: 125-1: 0.2.
5. according to the compound pesticide composition of claim 1, it is characterized in that spiral shell mite ester and four mite piperazine component ratios are 1: 62.5-1: 0.1.
6. according to the compound pesticide composition of claim 1, it is characterized in that spiral shell mite ester and azacyclotin component ratio are 1: 62.5-1: 0.1.
7. according to the compound pesticide composition of claim 1, it is characterized in that composite mixture can be processed into water-dispersible granules, suspending agent, wetting powder, aerosol, sustained release agent, dry suspending agent, aqueous emulsion, missible oil etc.
CNA2008101326243A 2008-07-08 2008-07-08 Compounded pesticide composition containing Spirodiclofen CN101300979A (en)

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CN103238605A (en) * 2012-02-11 2013-08-14 张秋芳 Acaricide composition containing spirodiclofen
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CN102657167A (en) * 2012-04-12 2012-09-12 广西田园生化股份有限公司 Ultra low volume liquid formulation containing spirodiclofen
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CN103734151B (en) * 2013-12-28 2016-04-20 上海艳紫化工科技有限公司 Avermectin and spiral shell mite ester compound insecticidal kill mite suspending agent
CN103734151A (en) * 2013-12-28 2014-04-23 上海艳紫化工科技有限公司 Insecticidal and mite-killing suspending agent obtained by compounding abamectin and spirodiclofen
CN103947655B (en) * 2014-04-11 2015-09-16 吴燕妮 A kind of Pesticidal combination comprising ivermectin and spiral shell mite ester
CN103947655A (en) * 2014-04-11 2014-07-30 吴燕妮 Insecticidal composition containing ivermectin and spirodiclofen
CN105557721A (en) * 2014-10-16 2016-05-11 江苏龙灯化学有限公司 Pest killing composition
CN105557721B (en) * 2014-10-16 2019-01-29 江苏龙灯化学有限公司 A kind of Pesticidal combination
CN105309452A (en) * 2015-10-19 2016-02-10 江苏七洲绿色化工股份有限公司 Efficacy-enhanced mite killing pesticide composition
CN108617685A (en) * 2017-03-23 2018-10-09 浙江省化工研究院有限公司 One kind ether compound containing loop coil and the acaricidal composition of organic tin
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CN107018988A (en) * 2017-05-15 2017-08-08 李军民 A kind of Envidor and azacyclotin composite pesticide suspending agent and preparation method thereof
CN107372608A (en) * 2017-06-27 2017-11-24 徐州农丰生物化工有限公司 A kind of mandarin tree acaricide and preparation method thereof

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