CN105296198B - A kind of environmental protection repairing type shoe washing liquid and preparation method thereof - Google Patents
A kind of environmental protection repairing type shoe washing liquid and preparation method thereof Download PDFInfo
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- CN105296198B CN105296198B CN201510629807.6A CN201510629807A CN105296198B CN 105296198 B CN105296198 B CN 105296198B CN 201510629807 A CN201510629807 A CN 201510629807A CN 105296198 B CN105296198 B CN 105296198B
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Abstract
The invention discloses a kind of environmentally friendly repairing type shoe washing liquids comprising renovation agent, at least one surfactant and water.The invention also discloses the methods for preparing the environmentally friendly repairing type shoe washing liquid.
Description
Technical field
The present invention relates to detergent applications, more particularly it relates to a kind of shoe washing liquid and preparation method thereof.
Background technology
Currently, the personal cleansing liquid for shoes product is also seldom, since the fiber of shoes product or the microcosmic surface of leather itself have
Many tiny bumps or wrinkle so that dirt is combined more secured with fiber or leather surface, goes dirt more difficult, because
More stringent requirements are proposed for dirt-removing power of this people to shoe washing liquid.In addition, since shoes product and skin contact can adsorb sweat, skin
The metabolites such as fat and dirt, in addition the environment that closing is moist, make in shoes as microbial reproduction, fermentation, corruption place, it
Be catalyzed metabolite and decomposite the volatile compound frowzy such as various lower fatty acids and Ammonia, in addition bacterium itself
The smell that secretion and the dead bones of the body rot causes to generate unpleasant stink in shoes, influences personal lifestyle and environmental sanitation, therefore, disappear
More stringent requirements are proposed for sterilizing and anti-foul of the person of expense to shoe washing liquid.Furthermore it due to the long-term dress of shoes product, inevitably causes
The abrasion of vamp makes filament or leather slight crack or defective wool occur on microcosmic, and in the light for macroscopically then showing shoes product
Property lose, affect shoes product service life and beauty, therefore, consumer expect have repair failed fibers, covering fiber defective wool, make shoes
Product reappear the appearance of the shoe washing liquid of bright property.In addition to this, the attention with people to environmental protection, exploitation and performance are excellent
More, have become the substantial responsibility of manufacturer to the cleaning solution of eco-friendly.
Therefore, being highly desirable to prepare a kind of has that cleaning capacity is strong, has reparation and bright effect and environment to shoes product
Friendly multi-functional shoe washing liquid.
Invention content
In view of the above demand, one aspect of the present invention provides a kind of environmentally friendly repairing type shoe washing liquid, by weight percentage, packet
Contain：
Organic siliconresin 0.01%-1%；
At least one surfactant 0.1%-10%；
Water surplus.
In one embodiment, the number-average molecular weight of the organic siliconresin is 20,000 or more, it is preferable that described to have
The number-average molecular weight of machine silicones is 70,000 or more.
In one embodiment, the shoe washing liquid further includes the modified organic silicon of 0.1%-5%.
In one embodiment, the modified organic silicon is water-soluble modified organosilicon.
In one embodiment, the water-soluble modified organosilicon is organic silicon modified by polyether, epoxy-modified organic
Silicon, alcohol modified organic silicon, fatty acid modified organosilicon, fatty acid alcohol modified organic silicon, one kind in amino-modified silicone or
It is several.
In one embodiment, the modified organic silicon is organic silicon modified by polyether, alcohol modified organic silicon, amino change
One or more of property organosilicon.
In one embodiment, the shoe washing liquid further includes the small molecule polycarboxylic acid and/or its salt of 0.01%-7%.
In one embodiment, the small molecule polycarboxylic acid and/or its salt are to have 2-4 carboxyl in molecule and divide
Aliphatic carboxylic acid and/or its salt of the son amount less than or equal to 500.
Another aspect provides the preparation methods of the environmentally friendly repairing type shoe washing liquid, including：
Small molecule polycarboxylic acid and/or its salt are added to the water and stirred to dissolving,
Surfactant is added, 10-60 min are stirred with the rotating speed of 5-60 r/min, and
Organic siliconresin is added and modified organic silicon stirs to clarify to obtain the final product.
Specific implementation mode
The detailed description for preferred implementation method of the invention below of participating in the election of and including embodiment this public affairs can be more easily understood
Open content.A large amount of terms can be referred in following description and claims, these terms are defined as following meanings.
Unless otherwise specified, whole temperature are indicated with degree Celsius herein, unless specifically stated otherwise, all polymer point
For son amount based on number-average molecular weight, the test method of number average molecular weight is vapor pressure method.
" optionally " or refer to " optionally " that the item described thereafter or event may or may not occur, and this is retouched
State the situation that the situation occurred including event and event do not occur.
Approximate term in specification and claims is used for modifying quantity, and it is specific to indicate that the present invention is not limited to this
Quantity further includes the modified part of the acceptable change without lead to related basic function close to the quantity.Phase
It answers, modifies a numerical value with " about ", " about " etc., mean that the present invention is not limited to the exact numericals.In some examples, approximate
Term likely corresponds to the precision of the instrument of measured value.In present specification and claims, range limits can be with
Combination and/or exchange, these ranges include all subranges contained therebetween if not stated otherwise.
The first aspect of the application provides a kind of environment-friendly type sterilization shoe washing liquid, weight percent, including following component：
Organic siliconresin 0.01%-1%；
At least one surfactant 0.1%-10%；
Water surplus.
It is 0.01 at%-1 at% that organic siliconresin used herein, which has space structure, addition, it is preferable that
The addition of the organic siliconresin is 0.2 at%.
Herein described organic siliconresin is by formula（1）Shown performed polymer is crosslinked to obtain
（1）
Wherein：R is the aliphatic hydrocarbyl of 1 to 24 carbon atom, and in different repetitive units, R can be identical, can not also
It is identical；R ' is the functional groups such as hydroxyl, alkoxy, hydrogen or halogenated hydrocarbons, and in different repetitive units, R ' can be identical, can also
It differs；The integer that n is 0,1,2, in different repetitive units, n may be the same or different；X is to make the organosilicon
The number-average molecular weight of resin reaches 20,000 or more integer, it is preferable that x is that the number-average molecular weight of the organic siliconresin is made to reach
70000 or more integer, it is highly preferred that x is the integer for making the number-average molecular weight of the organic siliconresin reach 100,000 or more；
In the repetitive unit for forming the organic siliconresin, contain R ' at least one repetitive unit.
The netted organosilicon has good adhesive force with leather or fiber, can fill up the slight crack in leather or fiber
Place, plays repair, can also be attached to leather or fiber surface, cover the defective wool position of leather or fiber, make leather
Or fiber shows bright characteristic, therefore constitute beneficial effects of the present invention.
In one embodiment, further include the modification of 0.1at%-5 at% for the environmentally friendly repairing type shoe washing liquid of the application
Organosilicon, number-average molecular weight is between 1000-10000.Preferably, the environmentally friendly repairing type shoe washing liquid includes changing for 1 at%
Property organosilicon, number-average molecular weight is between 2000-5000.
The modified organic silicon is water-soluble modified organosilicon, specifically includes organic silicon modified by polyether, epoxy-modified organic
Silicon, alcohol modified organic silicon, fatty acid modified organosilicon, fatty acid alcohol modified organic silicon, one kind in amino-modified silicone or
It is several, it is preferable that the water-soluble modified organosilicon is organic silicon modified by polyether, alcohol modified organic silicon, amino-modified silicone
One or more of.
Water-soluble modified organosilicon for the application is linear structure, and linear structure described herein refers to modified base
Group can be located at the organosilicon both ends and form linear chain structure, can also graft on formation side chain knot on the silicone backbone
Structure.
Since organic siliconresin is hydrophobic polymer polymer, the long-time stability in liquid detergent are always
One problem.The modified organic silicon is added in the shoe washing liquid, on the one hand can make the reparation being attached on leather or fiber
Agent is more uniform, and enhancing is using the bright property of leather or fiber after the shoe washing liquid, and on the other hand, applicant is found surprisingly that,
It is used in compounding by water-soluble modified organosilicon and netted organic siliconresin, can significantly improve netted organosilicon in aqueous solution
In stability, make the shoe washing liquid can be with stable for extended periods of time, therefore constitute beneficial effects of the present invention.
At least one surfactant used herein includes the betaines surface-active of 0.1 at%-5 at%
Agent.Preferably, at least one surfactant used includes the betaines surfactant of 1.9 at%.
In one embodiment, the betaines surfactant includes alkyl betaine, alkylamidoalkyl sweet tea
Dish alkali and azochlorosulfonate propyl lycine and its derivative, specifically include：Lauryl betaine, myristyl betaine, coconut oil base sweet tea
Dish alkali, oil-based betaine, stearyl betaine, dodecyldimethylammonium hydroxide inner salt, dodecyldimethylamine base glycine betaine, hexadecane
Base dimethyl betaine, octodecyl betaine, lauroyl amido propyl betaine, myristyl amido propyl beet
Alkali, palmityl amido propyl betaine, cocoamidopropyl betaine, oleamide glycine betaine, stearamide propyl glycine betaine,
Stearamide base propyl betaine, myristyl azochlorosulfonate propyl lycine, cetyl azochlorosulfonate propyl lycine, octadecyl sulfopropyl
Glycine betaine, trimethylglycine glycine betaine, decyl sulfonic group glycine betaine, dodecyl dihydroxy ethyl glycine betaine, octadecyl two
The combination of one or more of ethoxy glycine betaine.Preferably, the betaines surfactant is coconut oleamide third
Base glycine betaine.
At least one of the application surfactant further includes the alkyl glycosides of 0.1 at%-5 at%；Preferably, described
At least one surfactant includes the alkyl glycosides of 2.0 at%.
In one embodiment, the alkyl glycosides is not particularly limited, and can be cocoyl glucoside, bay
Base glucoside, Plantacare 818, myristyl glucoside, palmityl glucoside, stearyl glucoside and cocoyl glucoside
It is in one or several.
At least one surfactant for the application can only include betaines surfactant, can also be sweet tea
Dish bases surfactant and alkyl glycosides are used in compounding.
In one embodiment, further include killing for 0.1 at%-1 at% for the environmentally friendly repairing type shoe washing liquid of the application
Microbial inoculum；Preferably, the environmentally friendly repairing type shoe washing liquid includes the fungicide of 0.1 at%.
In one embodiment, the fungicide is one kind in phenol, quaternary ammonium salt, chitosan and its derivative
Or it is several, it specifically includes：Phenol, cresol and soap solution, hexachlorophene, parachlorometaxylenol, benzylalkyl ammonium chloride, benzyl
Ethyl ammonium chloride, cetyl pyridinium ammonium chloride, gluconic acid chlorohexidene, chlorhexidine acetate and chlorhexidine hydrochloride, triclosan, three
It is a kind of or several in chlorine card class, piroctone olamine, DMDM hydantoin, Climbazole, isopropyl cresols, chitosan, organosilicon
Kind.Preferably, the fungicide is parachlorometaxylenol.
Term " small molecule polycarboxylic acid and/or its salt " used herein refers to having 2-4 carboxyl, molecule in molecule
Aliphatic carboxylic acid and/or its salt of the amount less than or equal to 500.
In one embodiment, further include the small of 0.01at%-7 at% for the environmentally friendly repairing type shoe washing liquid of the application
Molecule polycarboxylic acid and/or its salt.
In one embodiment, the small molecule polycarboxylic acid and/or its salt include：Along canopy ammonium citrate-hydroxyacetic acid
And/or its salt, hydroxyacetic acid and/or its salt, citric acid and/or its salt, oxalic acid and/or its salt, 1,3,6- hexanes tricarboxylic acids and/
Or its salt, adipic acid and/or its salt, 3- carboxymethyls -1,5- pentanes dioctyl phthalate and/or its salt, triethyl ethylenediamine tetraacetic acid (EDTA) and/or
Its salt, glucose and/or its salt, tartaric acid and/or its salt, D-sorbite and/or its salt, 1,3- malonic acid and/or its salt, 1,
4- succinic acid and/or its salt, 1,5- glutaric acids and/or its salt, ethylenediamine tetra-acetic acid and/or its salt, aminotriacetic acid and/or its
Salt, diethylene-triamine pentaacetic acid and/or its salt, hydroxyethylethylene diamine tri-acetic acid and/or its salt, bicine N- and/
Or its salt, polyacrylic acid, polymethylacrylic acid, hydrolysis of polymaleic anhydride, butene dioic acid, one kind or several in polybutene diacid
Kind.Preferably, the small molecule polycarboxylic acid and/or its salt be citric acid and/or its salt, oxalic acid and/or its salt, tartaric acid and/
Or one or more of its salt.
The small molecule polycarboxylic acid and/or its salt can loosely be attached to the soil on shoes product surface, make soil be easier from
It falls off on vamp, enhances the cleaning force of the shoe washing liquid.In addition, the surfactant in the shoe washing liquid can be emulsified and be fallen off
Soil afterwards prevents its secondary settlement, further enhances the cleaning performance of the shoe washing liquid.
The another aspect of the application provides a kind of method preparing the environment-friendly type sterilization shoe washing liquid, including：
Small molecule polycarboxylic acid and/or its salt are added to the water and stirred to dissolving,
Surfactant is added, 10-60 min are stirred with the rotating speed of 5-60 r/min, and
Net high-polymer polymer is added and organic silicon modified by polyether stirs to clarify to obtain the final product.
Herein described shoe washing liquid can be used for the cleaning of clothing after the dilution of proper proportion, and remain to protect
Hold its strong cleaning capacity, sterilization, reparation and bright effect.
The application method of herein described shoe washing liquid includes：
Method one：It dips a small amount of shoe washing liquid and is applied to dirty place, wiping.
Method two：The shoe washing liquid is directly cleaned into shoes product or clothing after proper proportion dilutes.
Herein described environmental protection repairing type shoe washing liquid, raw material environmental sound, waste liquid will not after flowing into natural water
Water pollution and eutrophication are caused, is a environment-friendly type cleaning products.
In order to make technical problems, technical solutions and advantageous effects to be solved by the present invention be more clearly understood, below in conjunction with
Embodiment, the present invention will be described in further detail.It should be appreciated that following embodiment is served only for doing furtherly the present invention
It is bright, it should not be understood as limiting the scope of the invention, professional and technical personnel in the field is according to the content of aforementioned present invention
Some the nonessential modifications and adjustment made, still fall within protection scope of the present invention.
In addition, if illustrated without other, it is raw materials used to be all commercially available.
Raw material:
A1：Organic siliconresin (number-average molecular weight is 20,000 or more)
A2：Organic siliconresin (number-average molecular weight is 70,000 or more)
A3：Organic siliconresin (number-average molecular weight is 100,000 or more)
B1：Organic silicon modified by polyether resin
B2：Alcohol modified organic silicon
B3：Amino-modified silicone resin
C1：Potassium oxalate
D1：Sodium citrate
E1：Cocoamidopropyl betaine
F1：Alkyl glycosides
G1：To chlorine isophthalic dimethlbenzene
H1：Water
Embodiment 1
The D1 of the C1 of 0.01 parts by weight and 0.1 parts by weight are added to stirring in the H1 of 99.57 parts by weight to be added to dissolving
The G1 of 0.01 parts by weight, stirs evenly, and the F1 of the E1 and 0.1 parts by weight of 0.1 parts by weight is added, is stirred with the rotating speed of 5-60 r/min
It mixes 10-60min, is eventually adding the B1 of the A1 and 0.1 parts by weight of 0.01 parts by weight, stirs to clarify to obtain the final product.
Embodiment 2
The D1 of the C1 of 2 parts by weight and 5 parts by weight are added to stirring in the H1 of 76 parts by weight, 1 parts by weight are added to dissolving
G1, stir evenly, the F1 of the E1 and 5 parts by weight of 5 parts by weight be added, 10-60min is stirred with the rotating speed of 5-60 r/min, most
The B1 of the A1 and 5 parts by weight of 1 parts by weight are added afterwards, stirs to obtain the final product.
Embodiment 3
The D1 of the C1 of 0.5 parts by weight and 1 parts by weight are added to stirring in the H1 of 93.3 parts by weight and are added 0.1 to dissolving
The G1 of parts by weight, stirs evenly, and the F1 of the E1 and 2 parts by weight of 1.9 parts by weight is added, and 10- is stirred with the rotating speed of 5-60 r/min
60min is eventually adding the B3 of the A1 and 1 parts by weight of 0.2 parts by weight, stirs to obtain the final product.
Embodiment 4
The D1 of the C1 of 0.5 parts by weight and 1 parts by weight are added to stirring in the H1 of 93.3 parts by weight and are added 0.1 to dissolving
The G1 of parts by weight, stirs evenly, and the F1 of the E1 and 2 parts by weight of 1.9 parts by weight is added, and 10- is stirred with the rotating speed of 5-60 r/min
60min is eventually adding the B2 of the A2 and 1 parts by weight of 0.2 parts by weight, stirs to obtain the final product.
Embodiment 5
The D1 of the C1 of 0.5 parts by weight and 1 parts by weight are added to stirring in the H1 of 93.3 parts by weight and are added 0.1 to dissolving
The G1 of parts by weight, stirs evenly, and the F1 of the E1 and 2 parts by weight of 1.9 parts by weight is added, and 10- is stirred with the rotating speed of 5-60 r/min
60min is eventually adding the B1 of the A3 and 1 parts by weight of 0.2 parts by weight, stirs to clarify to obtain the final product.
Comparative example 1
The E1 of 1.9 parts by weight is added in the H1 of 97.9 parts by weight the rotating speed with 5-60 r/min and stirs 10-60min,
The A1 that 0.2 parts by weight are added is stirred to obtain the final product.
Comparative example 2
The E1 of 1.9 parts by weight is added in the H1 of 96.9 parts by weight the rotating speed with 5-60 r/min and stirs 10-60min
Afterwards, the B1 of the A1 and 1 parts by weight of 0.2 parts by weight is added, stirs to clarify to obtain the final product.
Comparative example 3
The D1 of 1 parts by weight is added to stirring in the H1 of 95.9 parts by weight and the E1 of 1.9 parts by weight is added, to dissolving with 5-
The rotating speed of 60 r/min stirs 10-60min, is eventually adding the B1 of the A1 and 1 parts by weight of 0.2 parts by weight, stirs to clarify to obtain the final product.
Comparative example 4
The C1 of 0.5 parts by weight is added to stirring in the H1 of 96.4 parts by weight, the E1 of 1.9 parts by weight is added to dissolving, with
The rotating speed of 5-60 r/min stirs 10-60min, is eventually adding the B1 of the A1 and 1 parts by weight of 0.2 parts by weight, stirs to obtain the final product.
Comparative example 5
The D1 of the C1 of 0.5 parts by weight and 1 parts by weight are added to stirring in the H1 of 95.4 parts by weight and are added 1.9 to dissolving
The E1 of parts by weight stirs 10-60min with the rotating speed of 5-60 r/min, is eventually adding the B1 of the A1 and 1 parts by weight of 0.2 parts by weight,
It stirs to clarify to obtain the final product.
Comparative example 6
The D1 of the C1 of 0.5 parts by weight and 1 parts by weight are added to stirring in the H1 of 95.3 parts by weight, 2 weights are added to dissolving
The F1 for measuring part stirs 10-60min with the rotating speed of 5-60 r/min, is eventually adding the B1 of the A1 and 1 parts by weight of 0.2 parts by weight, stirs
It mixes to clarifying to obtain the final product.
Comparative example 7
The D1 of the C1 of 0.5 parts by weight and 1 parts by weight are added to stirring in the H1 of 93.4 parts by weight and are added 1.9 to dissolving
The F1 of the E1 of parts by weight and 2 parts by weight stir 10-60min with the rotating speed of 5-60 r/min, are eventually adding the A1 of 0.2 parts by weight
With the B1 of 1 parts by weight, stir to clarify to obtain the final product.
Table 1 prepares the raw materials and consumption of environmentally friendly repairing type shoe washing liquid（Parts by weight）
Test method
Anti-microbial property：It is measured according to Japanese Industrial Standards JIS Z2801.
The measurement of clarity：
Each component is configured to shoe washing liquid according to amount specified in above-described embodiment and comparative example, with following standard by one
The skilled syndic of name judges the clarity of the shoe washing liquid prepared under different ratio.
Wherein：" 0 " indicates limpid, and "+" indicates muddy, and "+" more multilist shows muddy more serious
Cleaning force standard：
Common wash conditions and application wash conditions under, with following standard by a skilled syndic judge described in wash
Cleaning force of the shoes liquid to shoes product spot.
◎：The more spots of removal more apparent than reference sample.
○：More spots are removed than reference sample.
△：Spot is removed with similar degree compared with reference sample.
×：Less spot is removed than reference sample.
Brightness measures：
It is prepared into shoe washing liquid according to proportioning described in the various embodiments described above and comparative example, under the same conditions, is used respectively
The shoe washing liquid of the different ratio of phase homogenous quantities is judged by a skilled syndic using shoes after the shoe washing liquid with following standard
The bright degree of product.
◎：Compared to keen sensation to bright sense before use.
○：Feel bright sense compared with before use.
△：Feel with preceding light having the same is used.
×：Bright sense is obviously destroyed compared with before use.
Confirm the result of a skilled syndic judgement according to Scheffe ' s paired comparisons methods by 10 syndics can
By property.That is, a skilled syndic represents and judges a set of sneakers spot experiment slice（A set of includes 5）, adjacent result test film
Pairing, for example, by 10 other syndics according to Scheffe ' s paired comparisons methods confirm ◎ and zero, zero and △, △ and
×, prudent limit is judged as 95% time with significant difference by the judging result of a skilled syndic.
Above-mentioned test result is shown in Table 2
The performance test of the shoe washing liquid prepared under 2 different ratio of table
Table 2 statistics indicate that, compared with the shoe washing liquid without using modified organic silicon, use modified organic silicon and organosilicon tree
Fat, which compounds, can be obviously improved the solubility property of organic siliconresin, and can improve the prosthetic after the use shoe washing liquid to shoes product
And bright degree；It is used with surfactant compound using small molecule polycarboxylic acid and/or its salt, the shoe washing liquid can be improved
Cleaning force, therefore constitute beneficial effects of the present invention.
Example above-mentioned is merely illustrative, some features of the feature for explaining the disclosure.The attached claims
It is intended to the range as wide as possible for requiring to be contemplated that, and embodiments as presented herein is only according to all possible embodiment
Combination selection embodiment explanation.Therefore, the purpose of applicant is that the attached claims are not illustrated the present invention
Feature exemplary selectional restriction.And the progress in science and technology will be formed language express inaccuracy due to and not
The possible equivalent or son being presently considered are replaced, and these variations also should in the conceived case be interpreted by appended
Claim covers.
Claims (2)
1. a kind of repairing type shoe washing liquid, which is characterized in that by weight percentage, it includes：
Organic siliconresin 0.01%-1%；
At least one surfactant 0.1%-10%；
Modified organic silicon 0.1%-5%；
Small molecule polycarboxylic acid and/or its salt 0.01%-7%；
Water surplus；
The number-average molecular weight of the organic siliconresin is 70,000 or more；The small molecule polycarboxylic acid and/or its salt is in molecule
It is less than or equal to 500 aliphatic carboxylic acid and/or its salt with 2-4 carboxyl and molecular weight；
The modified organic silicon is organic silicon modified by polyether, alcohol modified organic silicon, one kind in amino-modified silicone or several
Kind.
2. a kind of method preparing shoe washing liquid as described in claim 1, specific preparation process are as follows：
Small molecule polycarboxylic acid and/or its salt are added to the water stirring to dissolving, surfactant is added and is turned with 5-60r/min
Speed stirring 10-60min, and addition organic siliconresin and modified organic silicon stir to clarify to obtain the final product；The modified organic silicon is poly-
One or more of ether modified organic silicon, alcohol modified organic silicon, amino-modified silicone.
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| CN201510629807.6A CN105296198B (en) | 2015-09-29 | 2015-09-29 | A kind of environmental protection repairing type shoe washing liquid and preparation method thereof |
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| CN201510629807.6A CN105296198B (en) | 2015-09-29 | 2015-09-29 | A kind of environmental protection repairing type shoe washing liquid and preparation method thereof |
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| CN101735900A (en) * | 2008-11-17 | 2010-06-16 | 北京华美琪科技有限公司 | Application of non-reactive organic silicone oil and derivate thereof in fabric nursing |
| CN101747999A (en) * | 2008-12-07 | 2010-06-23 | 荆门市新科专利技术有限公司 | Shoe washing liquid |
| CN102226135A (en) * | 2011-05-12 | 2011-10-26 | 荆立民 | Sterilizing/decontaminatimg/deodorizing shoe cleaning liquid and preparation method thereof |
| CN103556464A (en) * | 2013-10-29 | 2014-02-05 | 宋子奎 | Fabric function repair agent composition and preparation method of fabric function repair agent composition |
| CN103666881A (en) * | 2013-12-17 | 2014-03-26 | 常熟虞贵人家居用品有限公司 | Leather detergent |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103666781A (en) * | 2012-09-22 | 2014-03-26 | 青岛道合生物科技有限公司 | Special cleaning wet wipe for leather |
| CN103060132A (en) * | 2012-12-05 | 2013-04-24 | 刘聪 | Leather cleaning wet wipe |
| CN103966031A (en) * | 2014-05-30 | 2014-08-06 | 于文 | Environment-friendly leather cleaning care agent and preparation method thereof |
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2015
- 2015-09-29 CN CN201510629807.6A patent/CN105296198B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101735900A (en) * | 2008-11-17 | 2010-06-16 | 北京华美琪科技有限公司 | Application of non-reactive organic silicone oil and derivate thereof in fabric nursing |
| CN101747999A (en) * | 2008-12-07 | 2010-06-23 | 荆门市新科专利技术有限公司 | Shoe washing liquid |
| CN102226135A (en) * | 2011-05-12 | 2011-10-26 | 荆立民 | Sterilizing/decontaminatimg/deodorizing shoe cleaning liquid and preparation method thereof |
| CN103556464A (en) * | 2013-10-29 | 2014-02-05 | 宋子奎 | Fabric function repair agent composition and preparation method of fabric function repair agent composition |
| CN103666881A (en) * | 2013-12-17 | 2014-03-26 | 常熟虞贵人家居用品有限公司 | Leather detergent |
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| CN105296198A (en) | 2016-02-03 |
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