JP4879654B2 - Liquid detergent composition - Google Patents
Liquid detergent composition Download PDFInfo
- Publication number
- JP4879654B2 JP4879654B2 JP2006146967A JP2006146967A JP4879654B2 JP 4879654 B2 JP4879654 B2 JP 4879654B2 JP 2006146967 A JP2006146967 A JP 2006146967A JP 2006146967 A JP2006146967 A JP 2006146967A JP 4879654 B2 JP4879654 B2 JP 4879654B2
- Authority
- JP
- Japan
- Prior art keywords
- component
- mass
- group
- fragrance
- liquid detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims description 59
- 239000007788 liquid Substances 0.000 title claims description 48
- 239000003599 detergent Substances 0.000 title claims description 46
- 239000003205 fragrance Substances 0.000 claims description 55
- -1 Amine compound Chemical class 0.000 claims description 41
- 125000004432 carbon atom Chemical group C* 0.000 claims description 37
- 125000000217 alkyl group Chemical group 0.000 claims description 33
- 230000001953 sensory effect Effects 0.000 claims description 25
- 239000000463 material Substances 0.000 claims description 22
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 claims description 16
- 229940043350 citral Drugs 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 16
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
- VAMXMNNIEUEQDV-UHFFFAOYSA-N methyl anthranilate Chemical compound COC(=O)C1=CC=CC=C1N VAMXMNNIEUEQDV-UHFFFAOYSA-N 0.000 claims description 12
- 239000003945 anionic surfactant Substances 0.000 claims description 10
- KSMVZQYAVGTKIV-UHFFFAOYSA-N decanal Chemical compound CCCCCCCCCC=O KSMVZQYAVGTKIV-UHFFFAOYSA-N 0.000 claims description 10
- FKUPPRZPSYCDRS-UHFFFAOYSA-N Cyclopentadecanolide Chemical compound O=C1CCCCCCCCCCCCCCO1 FKUPPRZPSYCDRS-UHFFFAOYSA-N 0.000 claims description 9
- 239000002736 nonionic surfactant Substances 0.000 claims description 8
- 125000003342 alkenyl group Chemical group 0.000 claims description 7
- IGODOXYLBBXFDW-UHFFFAOYSA-N alpha-Terpinyl acetate Chemical compound CC(=O)OC(C)(C)C1CCC(C)=CC1 IGODOXYLBBXFDW-UHFFFAOYSA-N 0.000 claims description 7
- HFJRKMMYBMWEAD-UHFFFAOYSA-N dodecanal Chemical compound CCCCCCCCCCCC=O HFJRKMMYBMWEAD-UHFFFAOYSA-N 0.000 claims description 7
- 239000000835 fiber Substances 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 7
- 239000004753 textile Substances 0.000 claims description 7
- PHXATPHONSXBIL-UHFFFAOYSA-N xi-gamma-Undecalactone Chemical compound CCCCCCCC1CCC(=O)O1 PHXATPHONSXBIL-UHFFFAOYSA-N 0.000 claims description 7
- 239000002262 Schiff base Substances 0.000 claims description 6
- 150000004753 Schiff bases Chemical class 0.000 claims description 6
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 claims description 6
- OSOIQJGOYGSIMF-UHFFFAOYSA-N cyclopentadecanone Chemical compound O=C1CCCCCCCCCCCCCC1 OSOIQJGOYGSIMF-UHFFFAOYSA-N 0.000 claims description 6
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims description 6
- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 claims description 6
- 229940102398 methyl anthranilate Drugs 0.000 claims description 6
- PSQYTAPXSHCGMF-BQYQJAHWSA-N β-ionone Chemical compound CC(=O)\C=C\C1=C(C)CCCC1(C)C PSQYTAPXSHCGMF-BQYQJAHWSA-N 0.000 claims description 6
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 5
- 125000002947 alkylene group Chemical group 0.000 claims description 5
- 229960005323 phenoxyethanol Drugs 0.000 claims description 5
- PANBRUWVURLWGY-UHFFFAOYSA-N 2-undecenal Chemical compound CCCCCCCCC=CC=O PANBRUWVURLWGY-UHFFFAOYSA-N 0.000 claims description 4
- DZNVIZQPWLDQHI-UHFFFAOYSA-N Citronellyl formate Chemical compound O=COCCC(C)CCC=C(C)C DZNVIZQPWLDQHI-UHFFFAOYSA-N 0.000 claims description 4
- ZFMSMUAANRJZFM-UHFFFAOYSA-N Estragole Chemical compound COC1=CC=C(CC=C)C=C1 ZFMSMUAANRJZFM-UHFFFAOYSA-N 0.000 claims description 4
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 claims description 4
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 claims description 4
- PQLMXFQTAMDXIZ-UHFFFAOYSA-N isoamyl butyrate Chemical compound CCCC(=O)OCCC(C)C PQLMXFQTAMDXIZ-UHFFFAOYSA-N 0.000 claims description 4
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 claims description 4
- GYHFUZHODSMOHU-UHFFFAOYSA-N nonanal Chemical compound CCCCCCCCC=O GYHFUZHODSMOHU-UHFFFAOYSA-N 0.000 claims description 4
- GJQIMXVRFNLMTB-UHFFFAOYSA-N nonyl acetate Chemical compound CCCCCCCCCOC(C)=O GJQIMXVRFNLMTB-UHFFFAOYSA-N 0.000 claims description 4
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 claims description 4
- 239000002304 perfume Substances 0.000 claims description 4
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 claims description 4
- KMPQYAYAQWNLME-UHFFFAOYSA-N undecanal Chemical compound CCCCCCCCCCC=O KMPQYAYAQWNLME-UHFFFAOYSA-N 0.000 claims description 4
- SFEOKXHPFMOVRM-UHFFFAOYSA-N (+)-(S)-gamma-ionone Natural products CC(=O)C=CC1C(=C)CCCC1(C)C SFEOKXHPFMOVRM-UHFFFAOYSA-N 0.000 claims description 3
- HLCSDJLATUNSSI-JXMROGBWSA-N (2e)-3,7-dimethylocta-2,6-dienenitrile Chemical compound CC(C)=CCC\C(C)=C\C#N HLCSDJLATUNSSI-JXMROGBWSA-N 0.000 claims description 3
- XEJGJTYRUWUFFD-FNORWQNLSA-N (e)-1-(2,6,6-trimethyl-1-cyclohex-3-enyl)but-2-en-1-one Chemical compound C\C=C\C(=O)C1C(C)C=CCC1(C)C XEJGJTYRUWUFFD-FNORWQNLSA-N 0.000 claims description 3
- YYMCVDNIIFNDJK-XFQWXJFMSA-N (z)-1-(3-fluorophenyl)-n-[(z)-(3-fluorophenyl)methylideneamino]methanimine Chemical compound FC1=CC=CC(\C=N/N=C\C=2C=C(F)C=CC=2)=C1 YYMCVDNIIFNDJK-XFQWXJFMSA-N 0.000 claims description 3
- GJJSUPSPZIZYPM-UHFFFAOYSA-N 1,4-dioxacyclohexadecane-5,16-dione Chemical compound O=C1CCCCCCCCCCC(=O)OCCO1 GJJSUPSPZIZYPM-UHFFFAOYSA-N 0.000 claims description 3
- CRIGTVCBMUKRSL-FNORWQNLSA-N 1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-enone Chemical compound C\C=C\C(=O)C1C(C)=CCCC1(C)C CRIGTVCBMUKRSL-FNORWQNLSA-N 0.000 claims description 3
- OEVIJAZJVZDBQL-UHFFFAOYSA-N 1-(5,5-dimethylcyclohexen-1-yl)pent-4-en-1-one Chemical compound CC1(C)CCC=C(C(=O)CCC=C)C1 OEVIJAZJVZDBQL-UHFFFAOYSA-N 0.000 claims description 3
- YBUIAJZFOGJGLJ-SWRJLBSHSA-N 1-cedr-8-en-9-ylethanone Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@@H]1C(C)=C(C(C)=O)C2 YBUIAJZFOGJGLJ-SWRJLBSHSA-N 0.000 claims description 3
- DNRJTBAOUJJKDY-UHFFFAOYSA-N 2-Acetyl-3,5,5,6,8,8-hexamethyl-5,6,7,8- tetrahydronaphthalene Chemical compound CC(=O)C1=C(C)C=C2C(C)(C)C(C)CC(C)(C)C2=C1 DNRJTBAOUJJKDY-UHFFFAOYSA-N 0.000 claims description 3
- LUZDYPLAQQGJEA-UHFFFAOYSA-N 2-Methoxynaphthalene Chemical compound C1=CC=CC2=CC(OC)=CC=C21 LUZDYPLAQQGJEA-UHFFFAOYSA-N 0.000 claims description 3
- SJWKGDGUQTWDRV-UHFFFAOYSA-N 2-Propenyl heptanoate Chemical compound CCCCCCC(=O)OCC=C SJWKGDGUQTWDRV-UHFFFAOYSA-N 0.000 claims description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
- NFAVNWJJYQAGNB-UHFFFAOYSA-N 2-methylundecanal Chemical compound CCCCCCCCCC(C)C=O NFAVNWJJYQAGNB-UHFFFAOYSA-N 0.000 claims description 3
- OXYRENDGHPGWKV-UHFFFAOYSA-N 3-methyl-5-phenylpentan-1-ol Chemical compound OCCC(C)CCC1=CC=CC=C1 OXYRENDGHPGWKV-UHFFFAOYSA-N 0.000 claims description 3
- PCFHYANYPQEMPU-UHFFFAOYSA-N 4-(2,2,3-trimethyl-5-bicyclo[2.2.1]heptanyl)cyclohexan-1-ol Chemical compound CC1(C)C(C)C2CC1CC2C1CCC(O)CC1 PCFHYANYPQEMPU-UHFFFAOYSA-N 0.000 claims description 3
- MGQPKOBPXHENPO-UHFFFAOYSA-N 80657-64-3 Chemical compound C1C2CCC1C1(C(=O)OCC)C2CCC1 MGQPKOBPXHENPO-UHFFFAOYSA-N 0.000 claims description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 239000005977 Ethylene Substances 0.000 claims description 3
- LMETVDMCIJNNKH-UHFFFAOYSA-N [(3,7-Dimethyl-6-octenyl)oxy]acetaldehyde Chemical compound CC(C)=CCCC(C)CCOCC=O LMETVDMCIJNNKH-UHFFFAOYSA-N 0.000 claims description 3
- HMKKIXGYKWDQSV-KAMYIIQDSA-N alpha-Amylcinnamaldehyde Chemical compound CCCCC\C(C=O)=C\C1=CC=CC=C1 HMKKIXGYKWDQSV-KAMYIIQDSA-N 0.000 claims description 3
- CRIGTVCBMUKRSL-UHFFFAOYSA-N alpha-Damascone Natural products CC=CC(=O)C1C(C)=CCCC1(C)C CRIGTVCBMUKRSL-UHFFFAOYSA-N 0.000 claims description 3
- 229940062909 amyl salicylate Drugs 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 125000006297 carbonyl amino group Chemical group [H]N([*:2])C([*:1])=O 0.000 claims description 3
- 229930003633 citronellal Natural products 0.000 claims description 3
- 235000000983 citronellal Nutrition 0.000 claims description 3
- 229940019836 cyclamen aldehyde Drugs 0.000 claims description 3
- MCNKZOMTVSVVSJ-UHFFFAOYSA-N cyclooctyl methyl carbonate Chemical compound COC(=O)OC1CCCCCCC1 MCNKZOMTVSVVSJ-UHFFFAOYSA-N 0.000 claims description 3
- NYNCZOLNVTXTTP-UHFFFAOYSA-N ethyl 2-(1,3-dioxoisoindol-2-yl)acetate Chemical compound C1=CC=C2C(=O)N(CC(=O)OCC)C(=O)C2=C1 NYNCZOLNVTXTTP-UHFFFAOYSA-N 0.000 claims description 3
- PZUDDXJZNSJESK-UHFFFAOYSA-N ethyl 2-cyclohexylpropanoate Chemical compound CCOC(=O)C(C)C1CCCCC1 PZUDDXJZNSJESK-UHFFFAOYSA-N 0.000 claims description 3
- PHXATPHONSXBIL-JTQLQIEISA-N gamma-Undecalactone Natural products CCCCCCC[C@H]1CCC(=O)O1 PHXATPHONSXBIL-JTQLQIEISA-N 0.000 claims description 3
- 229940020436 gamma-undecalactone Drugs 0.000 claims description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 3
- 235000001510 limonene Nutrition 0.000 claims description 3
- 229940087305 limonene Drugs 0.000 claims description 3
- UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 claims description 3
- ZFNVDHOSLNRHNN-UHFFFAOYSA-N xi-3-(4-Isopropylphenyl)-2-methylpropanal Chemical compound O=CC(C)CC1=CC=C(C(C)C)C=C1 ZFNVDHOSLNRHNN-UHFFFAOYSA-N 0.000 claims description 3
- FQTLCLSUCSAZDY-UHFFFAOYSA-N (+) E(S) nerolidol Natural products CC(C)=CCCC(C)=CCCC(C)(O)C=C FQTLCLSUCSAZDY-UHFFFAOYSA-N 0.000 claims description 2
- NOOLISFMXDJSKH-KXUCPTDWSA-N (-)-Menthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-KXUCPTDWSA-N 0.000 claims description 2
- 239000001306 (7E,9E,11E,13E)-pentadeca-7,9,11,13-tetraen-1-ol Substances 0.000 claims description 2
- 239000001674 (E)-1-(2,6,6-trimethyl-1-cyclohexenyl)but-2-en-1-one Substances 0.000 claims description 2
- WSTQLNQRVZNEDV-CSKARUKUSA-N (e)-4-methyldec-3-en-5-ol Chemical compound CCCCCC(O)C(\C)=C\CC WSTQLNQRVZNEDV-CSKARUKUSA-N 0.000 claims description 2
- FXCYGAGBPZQRJE-ZHACJKMWSA-N 1-(2,6,6-Trimethyl-2-cyclohexen-1-yl)-1,6-heptadien-3-one Chemical compound CC1=CCCC(C)(C)C1\C=C\C(=O)CCC=C FXCYGAGBPZQRJE-ZHACJKMWSA-N 0.000 claims description 2
- BGTBFNDXYDYBEY-UHFFFAOYSA-N 1-(2,6,6-trimethylcyclohexen-1-yl)but-2-en-1-one Chemical compound CC=CC(=O)C1=C(C)CCCC1(C)C BGTBFNDXYDYBEY-UHFFFAOYSA-N 0.000 claims description 2
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims description 2
- AKCXZPYDVPYOMQ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol;propane-1,2-diol Chemical compound CC(O)CO.CCCCOCCOCCO AKCXZPYDVPYOMQ-UHFFFAOYSA-N 0.000 claims description 2
- VVUMWAHNKOLVSN-UHFFFAOYSA-N 2-(4-ethoxyanilino)-n-propylpropanamide Chemical compound CCCNC(=O)C(C)NC1=CC=C(OCC)C=C1 VVUMWAHNKOLVSN-UHFFFAOYSA-N 0.000 claims description 2
- HBNHCGDYYBMKJN-UHFFFAOYSA-N 2-(4-methylcyclohexyl)propan-2-yl acetate Chemical compound CC1CCC(C(C)(C)OC(C)=O)CC1 HBNHCGDYYBMKJN-UHFFFAOYSA-N 0.000 claims description 2
- KSJKLZBZCWUZEI-UHFFFAOYSA-N 2-butoxyethanol;2-(2-hydroxypropoxy)propan-1-ol Chemical compound CCCCOCCO.CC(O)COC(C)CO KSJKLZBZCWUZEI-UHFFFAOYSA-N 0.000 claims description 2
- PRNCMAKCNVRZFX-UHFFFAOYSA-N 3,7-dimethyloctan-1-ol Chemical compound CC(C)CCCC(C)CCO PRNCMAKCNVRZFX-UHFFFAOYSA-N 0.000 claims description 2
- INIOTLARNNSXAE-UHFFFAOYSA-N 4,8-dimethyl-2-propan-2-ylidene-3,3a,4,5,6,8a-hexahydro-1h-azulen-6-ol Chemical compound CC1CC(O)C=C(C)C2CC(=C(C)C)CC12 INIOTLARNNSXAE-UHFFFAOYSA-N 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 claims description 2
- FQTLCLSUCSAZDY-ATGUSINASA-N Nerolidol Chemical compound CC(C)=CCC\C(C)=C\CC[C@](C)(O)C=C FQTLCLSUCSAZDY-ATGUSINASA-N 0.000 claims description 2
- 239000005844 Thymol Substances 0.000 claims description 2
- UZFLPKAIBPNNCA-UHFFFAOYSA-N alpha-ionone Natural products CC(=O)C=CC1C(C)=CCCC1(C)C UZFLPKAIBPNNCA-UHFFFAOYSA-N 0.000 claims description 2
- UZFLPKAIBPNNCA-BQYQJAHWSA-N alpha-ionone Chemical compound CC(=O)\C=C\C1C(C)=CCCC1(C)C UZFLPKAIBPNNCA-BQYQJAHWSA-N 0.000 claims description 2
- WLJVXDMOQOGPHL-UHFFFAOYSA-N benzyl-alpha-carboxylic acid Natural products OC(=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-UHFFFAOYSA-N 0.000 claims description 2
- POIARNZEYGURDG-UHFFFAOYSA-N beta-damascenone Natural products CC=CC(=O)C1=C(C)C=CCC1(C)C POIARNZEYGURDG-UHFFFAOYSA-N 0.000 claims description 2
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 claims description 2
- ZANQMOGWQBCGBN-UHFFFAOYSA-N ethyl 2,6,6-trimethylcyclohexa-2,4-diene-1-carboxylate Chemical compound CCOC(=O)C1C(C)=CC=CC1(C)C ZANQMOGWQBCGBN-UHFFFAOYSA-N 0.000 claims description 2
- FQMZVFJYMPNUCT-UHFFFAOYSA-N geraniol formate Natural products CC(C)=CCCC(C)=CCOC=O FQMZVFJYMPNUCT-UHFFFAOYSA-N 0.000 claims description 2
- 229940094941 isoamyl butyrate Drugs 0.000 claims description 2
- WASNIKZYIWZQIP-AWEZNQCLSA-N nerolidol Natural products CC(=CCCC(=CCC[C@@H](O)C=C)C)C WASNIKZYIWZQIP-AWEZNQCLSA-N 0.000 claims description 2
- 229960003424 phenylacetic acid Drugs 0.000 claims description 2
- 239000003279 phenylacetic acid Substances 0.000 claims description 2
- 229960000790 thymol Drugs 0.000 claims description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims 2
- KHWTYGFHPHRQMP-UHFFFAOYSA-N (4-propan-2-ylcyclohexyl)methanol Chemical compound CC(C)C1CCC(CO)CC1 KHWTYGFHPHRQMP-UHFFFAOYSA-N 0.000 claims 1
- 239000005968 1-Decanol Substances 0.000 claims 1
- SDQFDHOLCGWZPU-UHFFFAOYSA-N lilial Chemical compound O=CC(C)CC1=CC=C(C(C)(C)C)C=C1 SDQFDHOLCGWZPU-UHFFFAOYSA-N 0.000 claims 1
- GHZRKQCHJFHJPX-UHFFFAOYSA-N oxacycloundecan-2-one Chemical compound O=C1CCCCCCCCCO1 GHZRKQCHJFHJPX-UHFFFAOYSA-N 0.000 claims 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims 1
- 229960004889 salicylic acid Drugs 0.000 claims 1
- 229910000077 silane Inorganic materials 0.000 claims 1
- 238000004140 cleaning Methods 0.000 description 27
- 239000004744 fabric Substances 0.000 description 26
- 239000000126 substance Substances 0.000 description 15
- 238000012360 testing method Methods 0.000 description 15
- 238000005406 washing Methods 0.000 description 15
- 238000011156 evaluation Methods 0.000 description 13
- 230000002265 prevention Effects 0.000 description 10
- 235000002639 sodium chloride Nutrition 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 8
- 229920000742 Cotton Polymers 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 150000003138 primary alcohols Chemical class 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 6
- 239000003093 cationic surfactant Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 230000035943 smell Effects 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 5
- 239000007844 bleaching agent Substances 0.000 description 5
- 238000011109 contamination Methods 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 239000003112 inhibitor Substances 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 5
- 150000003333 secondary alcohols Chemical class 0.000 description 5
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 4
- 102000004190 Enzymes Human genes 0.000 description 4
- 108090000790 Enzymes Proteins 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 4
- 239000004902 Softening Agent Substances 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 239000012190 activator Substances 0.000 description 4
- 150000005215 alkyl ethers Chemical class 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000000796 flavoring agent Substances 0.000 description 4
- 235000019634 flavors Nutrition 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- JIRHAGAOHOYLNO-UHFFFAOYSA-N (3-cyclopentyloxy-4-methoxyphenyl)methanol Chemical compound COC1=CC=C(CO)C=C1OC1CCCC1 JIRHAGAOHOYLNO-UHFFFAOYSA-N 0.000 description 3
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 229940007550 benzyl acetate Drugs 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000007850 fluorescent dye Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- MTVBNJVZZAQKRV-BJMVGYQFSA-N (e)-2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol Chemical compound OCC(/C)=C/CC1CC=C(C)C1(C)C MTVBNJVZZAQKRV-BJMVGYQFSA-N 0.000 description 2
- IOFYRNMXFRRJPS-UHFFFAOYSA-N 1-(3,3-dimethylcyclohexen-1-yl)pent-4-en-1-one Chemical compound CC1(C)CCCC(C(=O)CCC=C)=C1 IOFYRNMXFRRJPS-UHFFFAOYSA-N 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- IDHKBOHEOJFNNS-UHFFFAOYSA-N 2-[2-(2-phenoxyethoxy)ethoxy]ethanol Chemical compound OCCOCCOCCOC1=CC=CC=C1 IDHKBOHEOJFNNS-UHFFFAOYSA-N 0.000 description 2
- GTNCESCYZPMXCJ-UHFFFAOYSA-N 3-Phenylpropyl propanoate Chemical compound CCC(=O)OCCCC1=CC=CC=C1 GTNCESCYZPMXCJ-UHFFFAOYSA-N 0.000 description 2
- CVLHGLWXLDOELD-UHFFFAOYSA-N 4-(Propan-2-yl)benzenesulfonic acid Chemical compound CC(C)C1=CC=C(S(O)(=O)=O)C=C1 CVLHGLWXLDOELD-UHFFFAOYSA-N 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- JKRWZLOCPLZZEI-UHFFFAOYSA-N alpha-Trichloromethylbenzyl acetate Chemical compound CC(=O)OC(C(Cl)(Cl)Cl)C1=CC=CC=C1 JKRWZLOCPLZZEI-UHFFFAOYSA-N 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 239000002734 clay mineral Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 235000019645 odor Nutrition 0.000 description 2
- 125000006353 oxyethylene group Chemical group 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229940067107 phenylethyl alcohol Drugs 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920001444 polymaleic acid Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 239000004034 viscosity adjusting agent Substances 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- RAEOEMDZDMCHJA-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-[2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]ethyl]amino]acetic acid Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CCN(CC(O)=O)CC(O)=O)CC(O)=O RAEOEMDZDMCHJA-UHFFFAOYSA-N 0.000 description 1
- ZMPRRFPMMJQXPP-UHFFFAOYSA-N 2-sulfobenzoic acid Chemical compound OC(=O)C1=CC=CC=C1S(O)(=O)=O ZMPRRFPMMJQXPP-UHFFFAOYSA-N 0.000 description 1
- SDGNNLQZAPXALR-UHFFFAOYSA-N 3-sulfophthalic acid Chemical compound OC(=O)C1=CC=CC(S(O)(=O)=O)=C1C(O)=O SDGNNLQZAPXALR-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- WSTQLNQRVZNEDV-UHFFFAOYSA-N 4-methyldec-3-en-5-ol Chemical compound CCCCCC(O)C(C)=CCC WSTQLNQRVZNEDV-UHFFFAOYSA-N 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- QEVGZEDELICMKH-UHFFFAOYSA-N Diglycolic acid Chemical compound OC(=O)COCC(O)=O QEVGZEDELICMKH-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical class OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 239000005792 Geraniol Substances 0.000 description 1
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 1
- GLZPCOQZEFWAFX-JXMROGBWSA-N Nerol Natural products CC(C)=CCC\C(C)=C\CO GLZPCOQZEFWAFX-JXMROGBWSA-N 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 108010082455 Sebelipase alfa Proteins 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- DUJHUESDNVWCBZ-UHFFFAOYSA-N [acetyloxy(2-hydroxyethyl)amino] acetate Chemical compound CC(=O)ON(CCO)OC(C)=O DUJHUESDNVWCBZ-UHFFFAOYSA-N 0.000 description 1
- 229940022663 acetate Drugs 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 150000001639 boron compounds Chemical class 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 229940125782 compound 2 Drugs 0.000 description 1
- 229940126214 compound 3 Drugs 0.000 description 1
- 229940125898 compound 5 Drugs 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 150000001896 cresols Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- MHDVGSVTJDSBDK-UHFFFAOYSA-N dibenzyl ether Chemical compound C=1C=CC=CC=1COCC1=CC=CC=C1 MHDVGSVTJDSBDK-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000010413 gardening Methods 0.000 description 1
- 229940113087 geraniol Drugs 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000011086 high cleaning Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 235000019562 intensity of smell Nutrition 0.000 description 1
- 229940041615 kanuma Drugs 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- ZUHZZVMEUAUWHY-UHFFFAOYSA-N n,n-dimethylpropan-1-amine Chemical compound CCCN(C)C ZUHZZVMEUAUWHY-UHFFFAOYSA-N 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- HGASFNYMVGEKTF-UHFFFAOYSA-N octan-1-ol;hydrate Chemical compound O.CCCCCCCCO HGASFNYMVGEKTF-UHFFFAOYSA-N 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- 229940113162 oleylamide Drugs 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- VWMVAQHMFFZQGD-UHFFFAOYSA-N p-Hydroxybenzyl acetone Natural products CC(=O)CC1=CC=C(O)C=C1 VWMVAQHMFFZQGD-UHFFFAOYSA-N 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- SATCULPHIDQDRE-UHFFFAOYSA-N piperonal Chemical compound O=CC1=CC=C2OCOC2=C1 SATCULPHIDQDRE-UHFFFAOYSA-N 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 235000019419 proteases Nutrition 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- NJGBTKGETPDVIK-UHFFFAOYSA-N raspberry ketone Chemical compound CC(=O)CCC1=CC=C(O)C=C1 NJGBTKGETPDVIK-UHFFFAOYSA-N 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 229940077386 sodium benzenesulfonate Drugs 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 229920003176 water-insoluble polymer Polymers 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Fats And Perfumes (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
本発明は、液体洗浄剤組成物に関する。 The present invention relates to a liquid detergent composition.
従来から、洗浄後の繊維製品が、繊維処理剤の脱落や塩類の付着等によって、柔らかさを失い、ごわごわした感触になるのを防止するために、洗浄剤に柔軟化剤を配合することが検討されてきた。繊維表面に沈着して、繊維製品の風合いに柔軟性を付与する柔軟化剤として、従来、スメクタイト等の粘土鉱物（例えば特許文献１参照）、ジアルキル型第４級アンモニウム塩や長鎖アミン等の陽イオン界面活性剤（例えば特許文献２、３参照）、ポリ（ジメチルシロキサン）等のシリコーン（例えば特許文献４参照）等が提案されてきた。 Conventionally, a softening agent has been added to the cleaning agent to prevent the fiber product after washing from losing its softness due to dropping off of the fiber treatment agent or adhesion of salts, etc. Has been studied. As a softening agent that is deposited on the fiber surface and imparts flexibility to the texture of the fiber product, conventionally, clay minerals such as smectite (see, for example, Patent Document 1), dialkyl type quaternary ammonium salts, long chain amines, etc. Cationic surfactants (see, for example, Patent Documents 2 and 3), silicones such as poly (dimethylsiloxane) (see, for example, Patent Document 4), and the like have been proposed.
最近、消費者の要求に伴って、柔軟化に加え、香りを訴求（特に香料の持続性と残香性）した衣料用洗剤が上市され、香料組成物の高配合が検討課題の一つになってきている。 Recently, in response to consumer demand, in addition to softening, detergents for garments that appeal to fragrance (especially fragrance sustainability and residual fragrance) have been put on the market, and high blending of fragrance compositions has become one of the issues to be studied. It is coming.
液体洗浄剤は粉末洗浄剤に比べ、粉立ちによる咽がない、汚れ部分に直接塗布できるといった使いやすさの点で優れている。また、液状やペースト状の成分は粉末洗浄剤には多量に配合できないが、液体洗浄剤には比較的多量に配合できるといった使いやすさの点で優れている。しかし、粘土鉱物のような固体粒子や、シリコーンのような水不溶性の高分子化合物は液体洗浄剤組成物中で沈降・分離等が起こり易く、安定性の点で配合検討において注意が必要であった。このため、液体洗浄剤には柔軟化剤として陽イオン界面活性剤を用いることが一般的であった。 Liquid detergents are superior to powder detergents in terms of ease of use, such as no throat caused by dusting and direct application to dirt. In addition, liquid or paste-like components cannot be blended in a large amount with a powder detergent, but are excellent in terms of ease of use such that a relatively large amount can be blended with a liquid detergent. However, solid particles such as clay minerals and water-insoluble polymer compounds such as silicone are likely to settle and separate in the liquid detergent composition, and caution must be exercised in formulation studies in terms of stability. It was. For this reason, it is common to use a cationic surfactant as a softening agent in a liquid detergent.
柔軟化剤として陽イオン界面活性剤を用いる場合、陰イオン界面活性剤と陽イオン界面活性剤との水不溶性のコンプレックスが生成し液体洗浄剤組成物が白濁・分離する恐れがあり、安定性の点で配合検討において注意が必要であった。このため、洗浄剤として用いる界面活性剤としては非イオン界面活性剤が一般的であり、陰イオン界面活性剤は用いたとしても少量であった。非イオン界面活性剤は、他の界面活性剤に比べ脱脂力が高いために、皮脂汚れ等に有効であるが、繊維製品の風合いを硬くする傾向があり十分な柔軟効果が得られ難いという問題があった。 When a cationic surfactant is used as a softening agent, a water-insoluble complex of an anionic surfactant and a cationic surfactant may be generated, and the liquid detergent composition may become cloudy or separate, which is stable. In that respect, attention was necessary in the formulation study. For this reason, nonionic surfactants are common as surfactants used as cleaning agents, and a small amount of anionic surfactant is used even when used. Nonionic surfactants are more effective for sebum stains due to their higher degreasing power than other surfactants, but they tend to harden the texture of textile products and are difficult to obtain sufficient flexibility. was there.
また、陰イオン界面活性剤を高配合した場合、香料（油性成分）を高配合すると分離する恐れがあり、安定性の点で配合検討において注意が必要であった。 In addition, when an anionic surfactant is highly blended, there is a risk of separation when a perfume (oil-based component) is blended at a high level, and caution is required in the formulation study in terms of stability.
また洗浄工程において、固体粒子汚れの再汚染防止は重要な課題の一つである。この再汚染を防止するために、カルボキシメチルセルロース等のセルロース系の再汚染防止剤（例えば特許文献５参照）や、ポリエチレングリコール等のノニオン性高分子再汚染防止剤の配合検討が行われているが、十分な効果が得られず、液体洗浄剤に配合すると系の粘度上昇が見られるといった問題点があった。 In the cleaning process, prevention of recontamination of solid particle dirt is one of the important issues. In order to prevent this re-contamination, studies have been made on the combination of a cellulose-based re-contamination inhibitor such as carboxymethyl cellulose (see, for example, Patent Document 5) and a nonionic polymer re-contamination inhibitor such as polyethylene glycol. However, a sufficient effect cannot be obtained, and there is a problem in that an increase in the viscosity of the system is observed when blended with a liquid detergent.
一方、固体粒子汚れや繊維は水中において負の電荷を持っており、陰イオン界面活性剤を用いた場合、これらの負の電荷量が増大し、固体粒子汚れは繊維から落ちやすく、再付着し難くなる（例えば非特許文献１参照）。こういった点で、洗浄剤に用いる界面活性剤として、陰イオン界面活性剤は好適である。
本発明の課題は、特に固体粒子汚れに対して優れた洗浄性能及び再汚染防止性能を有し、更に良好な柔軟性を有し、保存安定が良好で、香料を高配合できる液体洗浄剤組成物を提供することにある。 An object of the present invention is to provide a liquid detergent composition that has excellent cleaning performance and re-contamination prevention performance, particularly for solid particle soils, and has good flexibility, good storage stability, and high blending of fragrances. To provide things.
本発明者等は、固体粒子汚れの洗浄性能、再汚染防止性能が高い陰イオン界面活性剤と、柔軟効果の高い長鎖アミン系化合物、及び香料を液体洗浄剤組成物中に安定に高配合することで、上記課題が解決できることを見出した。 The inventors of the present invention stably and highly blended an anionic surfactant having a high cleaning performance for solid particle soil and a high anti-recontamination performance, a long-chain amine compound having a high softening effect, and a fragrance into a liquid cleaning composition. As a result, the present inventors have found that the above problems can be solved.
即ち、本発明は、下記（ａ）成分、（ｂ）成分、（ｃ）成分、（ｄ）成分及び（ｅ）成分を含有し、組成物中の（ａ）成分の含有量が５〜２０質量％、（ｂ）成分の含有量が０．５〜１０質量％、（ｃ）成分の含有量が５〜２５質量％、（ｄ）成分の含有量が０．５〜３質量％、（ｅ）成分の含有量が１〜２０質量％であり、（ａ）成分と（ｂ）成分の質量比（ａ）／（ｂ）が１／１〜１０／１、（ａ）成分と（ｂ）成分との合計量と（ｃ）成分の質量比［（ａ）＋（ｂ）］／（ｃ）が２／３〜３／１、（ｄ）成分と（ｅ）成分の質量比（ｄ）／（ｅ）が１／２〜１／２０である液体洗浄剤組成物を提供する。
（ａ）陰イオン界面活性剤
（ｂ）一般式（Ｉ）で表されるアミン化合物
That is, this invention contains the following (a) component, (b) component, (c) component, (d) component, and (e) component, and the content of (a) component in a composition is 5-20. The content of the component (b) is 0.5 to 10% by mass, the content of the component (c) is 5 to 25% by mass, the content of the component (d) is 0.5 to 3% by mass, ( e) The content of the component is 1 to 20% by mass, the mass ratio (a) / (b) of the component (a) to the component (b) is 1/1 to 10/1, the component (a) and the component (b) ) Component and mass ratio of component (c) [(a) + (b)] / (c) is 2/3 to 3/1, mass ratio of component (d) to component (e) (d ) / (E) is 1/2 to 1/20.
(A) Anionic surfactant (b) Amine compound represented by formula (I)
〔式中、Ｒ1は炭素数１３〜２１のアルキル基又はアルケニル基、Ｒ2及びＲ3はそれぞれ独立に、炭素数１〜６のアルキル基又はヒドロキシアルキル基、ＸはＮＨ、ＣＯＮＨ、ＣＯＯ及びＯから選ばれる基、Ｒ4は炭素数２〜６のアルキレン基を示す。〕
（ｃ）非イオン界面活性剤
（ｄ）香料
（ｅ）一般式（II）で表される化合物
Ｒ5Ｏ｛(Ｃ2Ｈ4Ｏ)m（Ｃ3Ｈ6Ｏ)p｝Ｈ （II）
〔式中、Ｒ5は炭素数１〜８のアルキル基又はフェニル基、ｍ及びｐは各々０〜６の数であり、両者が同時に０になることはなく、｛ ｝内はｍ及びｐが０より大きいときに、オキシエチレン基とオキシプロピレン基がランダム状及び／又はブロック状に結合しているポリオキシアルキレン鎖である。〕
本発明は、更に（ｆ）成分として、分子中に４〜１０個の炭素原子を含み、且つ芳香族基を有するスルホン酸又はその塩を含有する上記液体洗浄剤組成物を提供する。
[Wherein, R 1 is an alkyl group or alkenyl group having 13 to 21 carbon atoms, R 2 and R 3 are each independently an alkyl group or hydroxyalkyl group having 1 to 6 carbon atoms, X is NH, CONH, COO and A group selected from O, R 4 represents an alkylene group having 2 to 6 carbon atoms. ]
(C) Nonionic surfactant (d) Perfume (e) Compound represented by general formula (II) R 5 O {(C 2 H 4 O) m (C 3 H 6 O) p } H (II)
[In the formula, R 5 is an alkyl group having 1 to 8 carbon atoms or a phenyl group, m and p are each a number of 0 to 6, and both of them are not 0 at the same time. When it is larger than 0, it is a polyoxyalkylene chain in which oxyethylene groups and oxypropylene groups are bonded in a random and / or block form. ]
The present invention further provides the above liquid detergent composition containing, as component (f), a sulfonic acid or a salt thereof containing 4 to 10 carbon atoms in the molecule and having an aromatic group.
本発明は、更に（ｇ）成分として、炭素数１〜４の１価のアルコールを含有する上記液体洗浄剤組成物を提供する。 The present invention further provides the above liquid cleaning composition containing a monohydric alcohol having 1 to 4 carbon atoms as component (g).
本発明の液体洗浄剤組成物は、安定性、洗浄性能、再汚染防止性能、柔軟性能の何れもが優れ、更に香料を高配合できるという効果を有する。 The liquid detergent composition of the present invention is excellent in stability, cleaning performance, recontamination prevention performance, and softness performance, and has an effect that a fragrance can be blended at a high level.
［（ａ）成分］
本発明の（ａ）成分である陰イオン界面活性剤としては、下記（ａ１）〜（ａ４）に示す化合物が挙げられる。
（ａ１）平均炭素数１０〜２０のアルキル基を有するアルキルベンゼンスルホン酸塩。
（ａ２）アルキル基の平均炭素数が１０〜２０、エチレンオキサイド（以下、ＥＯと表記することもある）平均付加モル数が０．５〜６のポリオキシエチレンアルキルエーテル硫酸塩。
（ａ３）平均炭素数１０〜２０のアルキル基又はアルケニル基を有するアルキル又はアルケニル硫酸エステル塩。
（ａ４）平均炭素数８〜２０の脂肪酸塩。
[(A) component]
Examples of the anionic surfactant that is the component (a) of the present invention include the compounds shown in the following (a1) to (a4).
(A1) Alkylbenzenesulfonate having an alkyl group having an average carbon number of 10 to 20.
(A2) Polyoxyethylene alkyl ether sulfates having an alkyl group with an average carbon number of 10 to 20, an ethylene oxide (hereinafter sometimes referred to as EO) average added mole number of 0.5 to 6.
(A3) Alkyl or alkenyl sulfate ester salt having an average alkyl group or alkenyl group having 10 to 20 carbon atoms.
(A4) Fatty acid salt having an average carbon number of 8 to 20.
これら陰イオン界面活性剤の対イオンとしては、ナトリウム、カリウム等のアルカリ金属イオン、マグネシウム、カルシウム等のアルカリ土類金属イオン、モノエタノールアミン、ジエタノールアミン、トリエタノールアミン等のアルカノールアミン、モノメチルジエタノールアミン、ジメチルモノエタノールアミン等のアルキルアルカノールアミンなどの陽イオンからなる群から選択される少なくとも１種が挙げられる。 Counterions of these anionic surfactants include alkali metal ions such as sodium and potassium, alkaline earth metal ions such as magnesium and calcium, alkanolamines such as monoethanolamine, diethanolamine and triethanolamine, monomethyldiethanolamine, dimethyl Examples thereof include at least one selected from the group consisting of cations such as alkyl alkanolamines such as monoethanolamine.
（ａ）成分は、特に、保存安定性向上の点で（ａ１）を含有することが好ましく、また、すすぎ性改善の点で（ａ４）を含有することが好ましい。 The component (a) particularly preferably contains (a1) from the viewpoint of improving storage stability, and preferably contains (a4) from the viewpoint of improving rinsing properties.
（ａ）成分は、１種又は２種以上を混合して用いても良く、更に中和物として液体洗浄剤組成物中に配合しても、酸形態で液体洗浄剤組成物中に配合した後中和してもよい。 The component (a) may be used singly or in combination of two or more types, and further blended in the liquid detergent composition as a neutralized product, or blended in the liquid detergent composition in the acid form. It may be post-neutralized.
［（ｂ）成分］
本発明の（ｂ）成分である一般式（Ｉ）で表されるアミン化合物において、一般式（Ｉ）中のＲ1は炭素数１５〜２１、更に炭素数１５〜１９のアルキル基又はアルケニル基が好ましく、特にアルキル基が好ましい。また、Ｒ2及びＲ3はそれぞれ独立に、炭素数１〜３、更に炭素数１のアルキル基又はヒドロキシアルキル基が好ましく、特にアルキル基が好ましい。また、Ｒ2及びＲ3は同一であることが好ましい。ＸはＣＯＮＨが好ましい。Ｒ4は炭素数２〜４、更に３のアルキレン基が好ましく、直鎖アルキレン基がより好ましい。
[Component (b)]
In the amine compound represented by the general formula (I) as the component (b) of the present invention, R 1 in the general formula (I) is an alkyl group or an alkenyl group having 15 to 21 carbon atoms, and further having 15 to 19 carbon atoms. Are preferable, and an alkyl group is particularly preferable. R 2 and R 3 are each independently preferably an alkyl group or a hydroxyalkyl group having 1 to 3 carbon atoms and further 1 carbon atom, and particularly preferably an alkyl group. R 2 and R 3 are preferably the same. X is preferably CONH. R 4 is preferably an alkylene group having 2 to 4 carbon atoms and more preferably 3 and more preferably a linear alkylene group.
（ｂ）成分としては、一般式(III)で表されるアミン化合物から選ばれる少なくとも１種が好ましい。 Component (b) is preferably at least one selected from amine compounds represented by general formula (III).
〔式中、Ｒ1、Ｒ2及びＲ3は前記と同じ意味を示し、ｎは２〜６、好ましくは２〜４、更に好ましくは３の整数を示す。〕
一般式(III)で表されるアミン化合物の具体例としては、ラウリルアミドプロピルジメチルアミン、ミリスチルアミドプロピルジメチルアミン、パルミチルアミドプロピルジメチルアミン、ステアリルアミドプロピルジメチルアミン、ベヘニルアミドプロピルジメチルアミン、オレイルアミドプロピルジメチルアミン等が挙げられる。
（ｂ）成分は、１種又は２種以上を混合して用いることができる。
[Wherein R 1 , R 2 and R 3 represent the same meaning as described above, and n represents an integer of 2 to 6, preferably 2 to 4, and more preferably 3. ]
Specific examples of the amine compound represented by the general formula (III) include laurylamidopropyldimethylamine, myristylamidopropyldimethylamine, palmitylamidopropyldimethylamine, stearylamidopropyldimethylamine, behenylamidopropyldimethylamine, oleylamide. And propyldimethylamine.
(B) A component can be used 1 type or in mixture of 2 or more types.
［（ｃ）成分］
本発明の（ｃ）成分である非イオン界面活性剤としては、下記（ｃ１）〜（ｃ５）に示す化合物が挙げられる。
（ｃ１）一般式(IV)で表されるポリオキシエチレン／オキシプロピレンアルキルエーテル
Ｒ6Ｏ［(ＥＯ)s／(ＰＯ)t］Ｈ (IV)
（式中、Ｒ6は炭素数９〜２０のアルキル基を示し、ＥＯはオキシエチレン基、ＰＯはオキシプロピレン基を示し、ｓ、ｔは各々ＥＯ、ＰＯの平均付加モル数で、ｓは４〜１６、ｔは１〜５の数を示す。ＥＯ、ＰＯはランダム付加又はブロック付加でもよい。）
（ｃ２）平均炭素数が９〜２０の１級アルコール又は２級アルコール由来のアルキル基又はアルケニル基を有し、エチレンオキサイドの平均付加モル数が１〜２０モルであるポリオキシエチレンアルキル又はアルケニルエーテル
（ｃ３）一般式（Ｖ）で表されるアルキルグリコシド
Ｒ7−(ＯＲ8)xＧy （Ｖ）
（式中、Ｒ7は直鎖又は分岐鎖の炭素数８〜１８のアルキル基、アルケニル基、又はアルキルフェニル基、Ｒ8は炭素数２〜４のアルキレン基、Ｇは炭素数５又は６の還元糖に由来する残基、ｘは平均値０〜６の数、ｙは平均値１〜１０の数を示す。）
（ｃ４）脂肪酸アルカノールアミド
（ｃ５）ポリヒドロキシ脂肪酸アミド
（ｃ）成分の中では、（ｃ２）のポリオキシエチレンアルキル又はアルケニルエーテルが好ましい。特に安定性の観点から、エチレンオキサイドの平均付加モル数は３〜１８が好ましく、５〜１５がより好ましい。また、（ｃ２）中のアルキル基又はアルケニル基は、１級アルコール由来のアルキル基と２級アルコール由来のアルキル基の両方であることが、安定性の観点から好ましく、１級アルコール由来のポリオキシエチレンアルキル又はアルケニルエーテル／２級アルコール由来のポリオキシエチレンアルキル又はアルケニルエーテルの質量比が１／１〜１０／１であるものが好ましく、２／１〜８／１であるものがより好ましく、３／１〜７／１であるものが更に好ましい。また、１級アルコール、２級アルコールはそれぞれ直鎖のものが好ましい。
[Component (c)]
Examples of the nonionic surfactant which is the component (c) of the present invention include compounds shown in the following (c1) to (c5).
(C1) Polyoxyethylene / oxypropylene alkyl ether represented by the general formula (IV) R 6 O [(EO) s / (PO) t ] H (IV)
(Wherein R 6 represents an alkyl group having 9 to 20 carbon atoms, EO represents an oxyethylene group, PO represents an oxypropylene group, s and t are average addition moles of EO and PO, respectively, and s is 4 -16, t represents a number from 1 to 5. EO and PO may be random addition or block addition.
(C2) A polyoxyethylene alkyl or alkenyl ether having an alkyl group or an alkenyl group derived from a primary alcohol or a secondary alcohol having an average carbon number of 9 to 20 and an average added mole number of ethylene oxide of 1 to 20 mol (c3) the general formula alkylglycoside R 7 represented by (V) - (OR 8) x G y (V)
(In the formula, R 7 is a linear or branched alkyl group having 8 to 18 carbon atoms, an alkenyl group, or an alkylphenyl group, R 8 is an alkylene group having 2 to 4 carbon atoms, and G is a carbon atom having 5 or 6 carbon atoms. Residues derived from reducing sugars, x is the number of average values 0-6, y is the number of average values 1-10.)
(C4) Fatty acid alkanolamide (c5) Polyhydroxy fatty acid amide Among the components (c), polyoxyethylene alkyl or alkenyl ether of (c2) is preferable. In particular, from the viewpoint of stability, the average added mole number of ethylene oxide is preferably from 3 to 18, and more preferably from 5 to 15. The alkyl group or alkenyl group in (c2) is preferably both an alkyl group derived from a primary alcohol and an alkyl group derived from a secondary alcohol, from the viewpoint of stability, and the polyoxy derived from the primary alcohol The mass ratio of ethyleneoxy or alkenyl ether / secondary alcohol-derived polyoxyethylene alkyl or alkenyl ether is preferably 1/1 to 10/1, more preferably 2/1 to 8/1. More preferably, 1/1 to 7/1. Further, the primary alcohol and the secondary alcohol are preferably straight chain.
［（ｄ）成分］
本発明の（ｄ）成分である香料としては、液体洗浄剤容器の開口時の香りが経時的に変化したり弱くなるのを抑制し、かつ衣類への残香性にも優れる観点から、感覚強度が４以上かつＣｌｏｇＰが３以上の香料素材（以下、香料素材ＡＢという）を（ｄ）成分中に４０質量％以上含有するものが好ましい。
[Component (d)]
As the fragrance which is the component (d) of the present invention, from the viewpoint of suppressing the fragrance at the time of opening the liquid detergent container from changing or weakening with time and being excellent in residual fragrance to clothing, the sensory strength Is preferably 40% by mass or more in the component (d) of a fragrance material (hereinafter referred to as fragrance material AB) having 4 or more and ClogP of 3 or more.
ここで、「感覚強度」とは、Physical Foundations in Perfumery(American Perfumer and Cosmetics，1970年12月発行）中、第５章、Absolute Intensity of 0dor, 0lfactory Equilibrium、第４３〜４７頁に記載の方法により求められる匂いの感覚強度である。 Here, “sensory intensity” is defined by the method described in Chapter 5, Absolute Intensity of 0dor, 0lfactory Equilibrium, pages 43 to 47 in Physical Foundations in Perfumery (American Perfumer and Cosmetics, issued in December 1970). This is the required intensity of smell.
感覚強度はWeber-Fechner則に従うものであって、シトラールを標準香料として物質の匂いの感覚強度を評価するものであり、シトラールの１００質量％の匂いの感覚強度を「５」とする。 The sensory intensity follows the Weber-Fechner rule and evaluates the sensory intensity of the odor of a substance using citral as a standard fragrance. The sensory intensity of the odor of 100% by mass of citral is set to “5”.
即ち、シトラールの１００質量％と、例えば、物質（イ）の１００質量％が同じ強さであった場合、その感覚強度は「５」である。次に、感覚強度４、３、２、１、０のサンプルを得るため、シトラールを無臭溶剤であるフタル酸ジエチルで希釈して、シトラールの４０質量％、１６質量％、６．３質量％、２．５質量及び１質量％の各希釈液（以下、シトラールの標準希釈液という）を調製する。例えば、物質（ロ）の１００質量％と、シトラールの４０質量％標準希釈液が同じ強さであった場合、その感覚強度は「４」で、物質（ハ）の１００質量％と、シトラールの１６質量％標準希釈液が同じ強さであった場合、その感覚強度は「３」である。 That is, when 100% by mass of citral and, for example, 100% by mass of the substance (I) have the same strength, the sensory intensity is “5”. Next, in order to obtain samples having a sensory intensity of 4, 3, 2, 1, 0, citral was diluted with diethyl phthalate, which is an odorless solvent, and 40% by weight, 16% by weight, 6.3% by weight of citral, Prepare 2.5% and 1% by weight of each dilution (hereinafter referred to as citral standard dilution). For example, if 100% by mass of substance (b) and 40% by mass standard dilution of citral have the same strength, the sensory strength is “4”, 100% by mass of substance (c), and citral When the 16% by mass standard diluted solution has the same strength, the sensory intensity is “3”.
感覚強度が６以上の強い物質の強さを決めるには匂い物質の４０質量％、１６質量％、６．３質量、２．５質量％等の希釈液を用意して、シトラールの１００質量％と比較する必要がある。例えば、物質（ニ）の４０質量％希釈液がシトラールの１００質量％の強さと同じであった場合、その感覚強度は「６」であり、物質（ホ）の１６質量％希釈液がシトラールの１００質量％の強さと同じであった場合、その感覚強度は「７」であり、物質（ヘ）の６．３質量％希釈液がシトラールの１００質量％の強さと同じであった場合、その感覚強度は「８」であり、物質（ト）の２．５質量％希釈液がシトラールの１００質量％の強さと同じであった場合、その感覚強度は「９」である。 To determine the strength of a strong substance with a sensory intensity of 6 or more, prepare diluted solutions of 40%, 16%, 6.3%, 2.5% by weight of odorous substance, and 100% by weight of citral. It is necessary to compare with. For example, when the 40% by weight diluted solution of the substance (d) is the same as the 100% by weight strength of citral, the sensory strength is “6” and the 16% by weight diluted solution of the substance (e) is citral. When the strength is 100% by mass, the sensory intensity is “7”. When the 6.3% by weight dilution of the substance (f) is the same as 100% by mass of citral, The sensory intensity is “8”, and when the 2.5 mass% diluted solution of the substance (g) is the same as the 100 mass% strength of citral, the sensory intensity is “9”.
前記文献“Physical Foundations in Perfumery”には、感覚強度１の化合物の例としてローズフェノン（Rosacetol, Rose crystal）、感覚強度２の化合物の例として酢酸ベンジル、フェニルエチルアルコール等が挙げられている。 The above-mentioned document “Physical Foundations in Perfumery” includes rosephenone (Rosacetol, Rose crystal) as an example of a compound having a sensory intensity 1, and benzyl acetate, phenylethyl alcohol and the like as examples of a compound having a sensory intensity 2.
次に、「ＣｌｏｇＰ」とは、有機化合物の水と１−オクタノールに対する親和性を示す係数である。Daylight Chemical Information System, Inc. から入手できるプログラム“ＣＬＯＧＰ”で計算される。このプログラムは、実測のＬｏｇＰ値がある場合にはそれと共に、Hansch，Leo のフラグメントアプローチにより算出される“計算ＬｏｇＰ”の値である。フラグメントアプローチは化合物の化学構造に基づいており、原子の数及び化学結合のタイプを考慮している（cf. A. Leo, Comprehensive Medicinal Chemistry, Vol.4, C. Hansch, P. G. Sammnens, J. B. Taylor and C. A. Ramsden, Eds., p.295, Pergamon Press, 1990）。本発明では、プログラムＣＬＯＧＰ ｖ4.01により計算したＣｌｏｇＰ値を用いた。 Next, “ClogP” is a coefficient indicating the affinity of an organic compound for water and 1-octanol. Calculated with the program “CLOGP” available from Daylight Chemical Information System, Inc. This program is the value of “calculated LogP” calculated by Hansch, Leo's fragment approach together with the measured LogP value, if any. The fragment approach is based on the chemical structure of the compound and takes into account the number of atoms and the type of chemical bond (cf. A. Leo, Comprehensive Medicinal Chemistry, Vol. 4, C. Hansch, PG Sammnens, JB Taylor and CA Ramsden, Eds., P.295, Pergamon Press, 1990). In the present invention, the ClogP value calculated by the program CLOGP v4.01 is used.
本発明に使用される香料素材ＡＢとして、下記香料素材Ａ群及び香料素材Ｂ群からなる群より選ばれる少なくとも１種を用いることができる。
・香料素材Ａ群
感覚強度が４であって、かつＣｌｏｇＰが３以上の化合物からなる群である。具体例として、アセチルセドレン（Ａ１）、α−ダマスコン（Ａ２）、１−デカナールとアンスラニル酸メチルとのシッフベース（Ａ３）、アミルシンナミックアルデヒド（Ａ４）、サリチル酸アミル（Ａ５）、β−ダマスコン（Ａ６）、シクラメンアルデヒド（Ａ７）、ダマセノン（Ａ８）、δ−ダマスコン（Ａ９）、ゲラニルニトリル（Ａ１０）、α−ヨノン（Ａ１１）、β−ヨノン（Ａ１２）、メチルシクロオクチルカーボネート（Ａ１３）、リリアール（Ａ１４）、リリアールとアンスラニル酸メチルとのシッフベース（Ａ１５）、リモネン（Ａ１６）、酢酸リナリル（Ａ１７）、リラールとアンスラニル酸メチルとのシッフベース（Ａ１８）、酢酸ジヒドロテルピニル（Ａ１９）、エチレンドデカンジオエート（Ａ２０）、マイラックアルデヒド（Ａ２１）、ネロリドール（Ａ２２）、フェニル酢酸 ｐ−クレジル（Ａ２３）、３−メチル−５−フェニルペンタン−１−オール（Ａ２４）、イソカンフィルシクロヘキサノール（Ａ２５）、２−メチル−４−（２，２，３−トリメチル−３−シクロペンテン−１−イル）−２−ブテン−１−オール（Ａ２６）、６−アセチル−１，１，２，４，４，７−ヘキサメチル−テトラリン（Ａ２７）、酢酸テルピニル（Ａ２８）及びエチレンドデカンジオエート（Ａ２９）が例示される。
・香料素材Ｂ群
感覚強度５以上であって、かつＣｌｏｇＰが３以上の化合物からなる群である。具体例として、シトラール（Ｂ１）、シクロペンタデカノン（Ｂ２）、ジフェニルメタン（Ｂ３）、エチルトリシクロ［５．２．１．０2,6］デカン−２−イルカーボキシレート（Ｂ４）、ｐ−イソプロピルシクロヘキシルメタノール（Ｂ５）、エチル−２−シクロヘキシルプロピオネート（Ｂ６）、サンタロール（Ｂ７）、ジメチルオクタノール（Ｂ８）、テトラヒドロリナロール（Ｂ９）、ベチベロール（Ｂ１０）、酢酸ベチベリル（Ｂ１１）、アリルヨノン（Ｂ１２）、アンブレットリド（Ｂ１３）、オーランチオール（Ｂ１４）、サリチル酸 ｃｉｓ−３−ヘキセニル（Ｂ１５）、ギ酸シトロネリル（Ｂ１６）、エストラゴール（Ｂ１７）、エチレンブラシレート（Ｂ１８）、ギ酸ゲラニル（Ｂ１９）、β−ナフトールメチルエーテル（Ｂ２０）、シクロヘキシルプロピオン酸アリル（Ｂ２１）、シトロネラール（Ｂ２２）、１−（３，３−ジメチル−６−シクロヘキセン−１−イル）−ペンタ−４−エン−１−オンと１−（３，３−ジメチル−１−シクロヘキセン−１−イル）−ペンタ−４−エン−１−オンの混合物（Ｂ２３）、エチルデハイドロシクロゲラネート（Ｂ２４）、ｌ−メントール（Ｂ２５）、シクロペンタデカノリド（Ｂ２６）、チモール（Ｂ２７）、４−メチル−３−デセン−５−オール（Ｂ２８）、デカノール（Ｂ２９）、１−ノナノール（Ｂ３０）、デカナール（Ｂ３１）、ウンデカナール（Ｂ３２）、ドデカナール（Ｂ３３）、２−メチルウンデカナール（Ｂ３４）、γ−ウンデカラクトン（Ｂ３５）、酪酸イソアミル（Ｂ３６）、酢酸ノニル（Ｂ３７）、ウンデセナール（Ｂ３８）、ｎ−ノナナール（Ｂ３９）、ヘプタン酸アリル（Ｂ４０）、シトロネリルオキシアセトアルデヒド（Ｂ４１）及びシクロペンタデカノリド（Ｂ４２）が例示される。
As the fragrance material AB used in the present invention, at least one selected from the group consisting of the following fragrance material A group and fragrance material B group can be used.
-Fragrance | flavor raw material A group The sensory intensity is 4 and ClogP is a group which consists of 3 or more compounds. Specific examples include acetyl cedrene (A1), α-damascone (A2), Schiff base of 1-decanal and methyl anthranilate (A3), amylcinnamic aldehyde (A4), amyl salicylate (A5), β-damascone ( A6), cyclamenaldehyde (A7), damasenone (A8), δ-damascone (A9), geranylnitrile (A10), α-ionone (A11), β-ionone (A12), methylcyclooctyl carbonate (A13), lyial (A14), Schiff base of lyial and methyl anthranilate (A15), limonene (A16), linalyl acetate (A17), Schiff base of rilal and methyl anthranilate (A18), dihydroterpinyl acetate (A19), ethylenedodecane Geoate (A20), Myrak Aldehyde (A21), nerolidol (A22), phenylacetic acid p-cresyl (A23), 3-methyl-5-phenylpentan-1-ol (A24), isocamphylcyclohexanol (A25), 2-methyl-4 -(2,2,3-trimethyl-3-cyclopenten-1-yl) -2-buten-1-ol (A26), 6-acetyl-1,1,2,4,4,7-hexamethyl-tetralin ( A27), terpinyl acetate (A28) and ethylenedodecanedioate (A29).
-Fragrance | flavor raw material B group It is the group which consists of a compound with sensory intensity 5 or more and ClogP of 3 or more. Specific examples include citral (B1), cyclopentadecanone (B2), diphenylmethane (B3), ethyltricyclo [5.2.1.0 2,6 ] decan-2-ylcarboxylate (B4), p. -Isopropylcyclohexylmethanol (B5), ethyl-2-cyclohexylpropionate (B6), santalol (B7), dimethyloctanol (B8), tetrahydrolinalol (B9), vetiverol (B10), vetiberyl acetate (B11), allyl ionone (B12), ambridolide (B13), auranthiol (B14), cis-3-hexenyl salicylate (B15), citronellyl formate (B16), estragole (B17), ethylene brushate (B18), geranyl formate ( B19), β-naphthol methyl ether B20), allyl cyclohexylpropionate (B21), citronellal (B22), 1- (3,3-dimethyl-6-cyclohexen-1-yl) -pent-4-en-1-one and 1- (3,3 -Dimethyl-1-cyclohexen-1-yl) -pent-4-en-1-one (B23), ethyl dehydrocyclogeranate (B24), l-menthol (B25), cyclopentadecanolide ( B26), thymol (B27), 4-methyl-3-decen-5-ol (B28), decanol (B29), 1-nonanol (B30), decanal (B31), undecanal (B32), dodecanal (B33) 2-methylundecanal (B34), γ-undecalactone (B35), isoamyl butyrate (B36), nonyl acetate (B3) ), Undecenal (B38), n-nonanal (B39), allyl heptanoate (B40), citronellyloxyacetaldehyde (B41) and cyclopentadecanolide (B42) are exemplified.
これらの中でも、好ましい香料素材ＡＢとして、安定性や、少量の配合でも分かりやすい香りが創作できるという観点より、アセチルセドレン（Ａ１）、α−ダマスコン（Ａ２）、アミルシンナミックアルデヒド（Ａ４）、サリチル酸アミル（Ａ５）、シクラメンアルデヒド（Ａ７）、ダマセノン（Ａ８）、δ−ダマスコン（Ａ９）、ゲラニルニトリル（Ａ１０）、β−ヨノン（Ａ１２）、メチルシクロオクチルカーボネート（Ａ１３）、リリアール（Ａ１４）、リモネン（Ａ１６）、酢酸リナリル（Ａ１７）、マイラックアルデヒド（Ａ２１）、３−メチル−５−フェニルペンタン−１−オール（Ａ２４）、イソカンフィルシクロヘキサノール（Ａ２５）、２−メチル−４−（２，２，３−トリメチル−３−シクロペンテン−１−イル）−２−ブテン−１−オール（Ａ２６）、６−アセチル−１，１，２，４，４，７−ヘキサメチル−テトラリン（Ａ２７）、酢酸テルピニル（Ａ２８）、シクロペンタデカノン（Ｂ２）、ｐ−イソプロピルシクロヘキシルメタノール（Ｂ５）、サリチル酸 ｃｉｓ−３−ヘキセニル（Ｂ１５）、デカナール（Ｂ３１）、２−メチルウンデカナール（Ｂ３４）及びヘプタン酸アリル（Ｂ４０）が例示される。 Among these, as a preferable fragrance material AB, acetyl cedrene (A1), α-damascone (A2), amylcinnamic aldehyde (A4), from the viewpoint that stability and an easy-to-understand fragrance can be created even with a small amount of blending, Amyl salicylate (A5), cyclamenaldehyde (A7), damacenone (A8), δ-damascone (A9), geranylnitrile (A10), β-ionone (A12), methylcyclooctyl carbonate (A13), lyial (A14), Limonene (A16), linalyl acetate (A17), mylacaldehyde (A21), 3-methyl-5-phenylpentan-1-ol (A24), isocamphylcyclohexanol (A25), 2-methyl-4- ( 2,2,3-trimethyl-3-cyclopenten-1-yl) -2 Buten-1-ol (A26), 6-acetyl-1,1,2,4,4,7-hexamethyl-tetralin (A27), terpinyl acetate (A28), cyclopentadecanone (B2), p-isopropylcyclohexyl Examples include methanol (B5), cis-3-hexenyl salicylate (B15), decanal (B31), 2-methylundecanal (B34), and allyl heptanoate (B40).
本発明において、香りの持続性、残香性の観点から、香料素材ＡＢの合計含有量は、本発明の（ｄ）成分中４０質量％以上が好ましく、より好ましくは５０質量％以上、更に好ましくは６０質量％以上である。 In the present invention, from the viewpoint of fragrance persistence and residual fragrance, the total content of the fragrance material AB is preferably 40% by mass or more, more preferably 50% by mass or more, and still more preferably in the component (d) of the present invention. 60% by mass or more.
本発明の（ｄ）成分は、感覚強度が５以上かつＣｌｏｇＰが３以上の香料素材を、（ｄ）成分中１０質量％以上含むことが好ましく、更には１５質量％以上、特に２０質量％以上含むことが好ましい。感覚強度が５以上かつＣｌｏｇＰが３以上の香料素材として、前述の香料素材Ｂ群として挙げたものが例示される。この中でも香りの経時安定性や少量の配合でも分かりやすい香りが創作できるという観点より、シトラール（Ｂ１）、エチルトリシクロ［５．２．１．０2,6］デカン−２−イルカーボキシレート（Ｂ４）、エチル−２−シクロヘキシルプロピオネート（Ｂ６）、テトラヒドロリナロール（Ｂ９）、オーランチオール（Ｂ１４）、エチレンブラシレート（Ｂ１８）、β−ナフトールメチルエーテル（Ｂ２０）、シクロヘキシルプロピオン酸アリル（Ｂ２１）、シトロネラール（Ｂ２２）、１−（３，３−ジメチル−６−シクロヘキセン−１−イル）−ペンタ−４−エン−１−オンと１−（３，３−ジメチル−１−シクロヘキセン−１−イル）−ペンタ−４−エン−１−オンの混合物（Ｂ２３）、シクロペンタデカノリド（Ｂ２６）、４−メチル−３−デセン−５−オール（Ｂ２８）、ドデカナール（Ｂ３３）、γ−ウンデカラクトン（Ｂ３５）及びウンデセナール（Ｂ３８）が好ましいものとして例示される。 The component (d) of the present invention preferably contains a fragrance material having a sensory intensity of 5 or more and a ClogP of 3 or more in the component (d) of 10% by mass or more, more preferably 15% by mass or more, especially 20% by mass or more. It is preferable to include. Examples of the fragrance material having a sensory intensity of 5 or more and ClogP of 3 or more include those listed as the fragrance material group B described above. Among these, citral (B1), ethyltricyclo [5.2.1.0 2,6 ] decan-2-ylcarboxylate, from the viewpoint that the fragrance is stable over time and a simple scent can be created even with a small amount of formulation. (B4), ethyl-2-cyclohexylpropionate (B6), tetrahydrolinalol (B9), auranthiol (B14), ethylene brushate (B18), β-naphthol methyl ether (B20), allyl cyclohexylpropionate ( B21), citronellal (B22), 1- (3,3-dimethyl-6-cyclohexen-1-yl) -pent-4-en-1-one and 1- (3,3-dimethyl-1-cyclohexene-1 -Yl) -pent-4-en-1-one mixture (B23), cyclopentadecanolide (B26), 4-methyl -3-Decene-5-ol (B28), dodecanal (B33), γ-undecalactone (B35) and undecenal (B38) are preferred examples.
本発明の（ｄ）成分は、香料素材ＡＢ以外の香料を含有していても良い。香料素材ＡＢ以外の香料として、フェニルエチルアルコール、酢酸ベンジル、ゲラニオール、ネロール、酢酸ベンジル、４−（４−ヒドロキシフェニル）−２−ブタノン、ヘリオトロピン、リラール等が例示される。 The component (d) of the present invention may contain a fragrance other than the fragrance material AB. Examples of the fragrance other than the fragrance material AB include phenylethyl alcohol, benzyl acetate, geraniol, nerol, benzyl acetate, 4- (4-hydroxyphenyl) -2-butanone, heliotropin, laral and the like.
［（ｅ）成分］
本発明の（ｅ）成分である一般式（II）で表される化合物としては、エチレングリコールモノブチルエーテル、ジエチレングリコールモノブチルエーテル（ブチルカルビトール）、プロピレングリコールジエチレングリコールモノブチルエーテル、ジプロピレングリコールエチレングリコールモノブチルエーテル、エチレングリコールモノフェニルエーテル、トリエチレングリコールモノフェニルエーテル等を挙げることができる。中でも、安定性の観点から一般式（II−１）又は（II−２）で表される化合物が好ましい。
[(E) component]
Examples of the compound represented by the general formula (II) as the component (e) of the present invention include ethylene glycol monobutyl ether, diethylene glycol monobutyl ether (butyl carbitol), propylene glycol diethylene glycol monobutyl ether, dipropylene glycol ethylene glycol monobutyl ether, Examples thereof include ethylene glycol monophenyl ether and triethylene glycol monophenyl ether. Especially, the compound represented by general formula (II-1) or (II-2) from a stability viewpoint is preferable.
Ｒ5-1Ｏ(Ｃ2Ｈ4Ｏ)m1Ｈ （II−１）
〔式中、Ｒ5-1は炭素数１〜８、好ましくは２〜６のアルキル基、ｍ１は１〜６、好ましくは１〜３の数である。〕
Ｒ5-2Ｏ(Ｃ2Ｈ4Ｏ)m2Ｈ （II−２）
〔式中、Ｒ5-2はフェニル基、ｍ２は１〜６、好ましくは１〜３の数である。〕
一般式（II−１）で表される化合物としては、エチレングリコールモノブチルエーテル、ジエチレングリコールモノブチルエーテル等が、一般式（II−２）で表される化合物としては、エチレングリコールモノフェニルエーテル、トリエチレングリコールモノフェニルエーテル等が挙げられる。
R 5-1 O (C 2 H 4 O) m1 H (II-1)
[Wherein R 5-1 represents an alkyl group having 1 to 8 carbon atoms, preferably 2 to 6 carbon atoms, and m1 represents a number of 1 to 6, preferably 1 to 3 carbon atoms. ]
R 5-2 O (C 2 H 4 O) m 2 H (II-2)
[Wherein R 5-2 is a phenyl group, and m2 is a number of 1 to 6, preferably 1 to 3. ]
Examples of the compound represented by the general formula (II-1) include ethylene glycol monobutyl ether and diethylene glycol monobutyl ether. Examples of the compound represented by the general formula (II-2) include ethylene glycol monophenyl ether and triethylene glycol. And monophenyl ether.
（ｅ）成分としては、特に、一般式（II−１）で表される化合物及一般式（II−２）で表される化合物を含有することが好ましく、（II−１）／（II−２）の質量比が１／１０〜１０／１がより好ましく、１／５〜５／１が更に好ましく、１／２〜２／１が特に好ましい。 As the component (e), it is particularly preferable to contain a compound represented by the general formula (II-1) and a compound represented by the general formula (II-2), and (II-1) / (II- The mass ratio of 2) is more preferably 1/10 to 10/1, further preferably 1/5 to 5/1, and particularly preferably 1/2 to 2/1.
［液体洗浄剤組成物］
本発明の液体洗浄剤組成物は、必須成分として、上記のような（ａ）成分、（ｂ）成分、（ｃ）成分、（ｄ）成分及び（ｅ）成分を含有する。本発明の組成物中の（ａ）成分の含有量は、安定性、洗浄性能、再汚染防止性能の観点より、５〜２０質量％であり、８〜１８質量％が好ましく、１０〜１６質量％がより好ましく、１２〜１５質量％が更に好ましい。
[Liquid detergent composition]
The liquid detergent composition of the present invention contains the above components (a), (b), (c), (d) and (e) as essential components. Content of (a) component in the composition of this invention is 5-20 mass% from a viewpoint of stability, washing | cleaning performance, and recontamination prevention performance, 8-18 mass% is preferable, and 10-16 mass % Is more preferable, and 12 to 15% by mass is still more preferable.
また本発明の液体洗浄剤組成物は、洗浄性能、すすぎ性改善の観点から、（ａ）成分として、上記（ａ４）の平均炭素数８〜２０の脂肪酸塩を含有することが好ましく、組成物中の（ａ４）の含有量は０．１〜５質量％が好ましく、０．３〜３質量％がより好ましい。 Moreover, it is preferable that the liquid detergent composition of this invention contains the fatty acid salt of the said C8-20 average carbon number of said (a4) as a (a) component from a viewpoint of washing | cleaning performance and a rinse improvement. The content of (a4) is preferably 0.1 to 5% by mass, more preferably 0.3 to 3% by mass.
本発明の液体洗浄剤組成物中の（ｂ）成分の含有量は、安定性、洗浄性能、柔軟性能の観点より、０．５〜１０質量％であり、１〜８質量％が好ましく、２〜６質量％がより好ましく、３〜５質量％が更に好ましい。 The content of the component (b) in the liquid detergent composition of the present invention is 0.5 to 10% by mass, preferably 1 to 8% by mass, from the viewpoints of stability, cleaning performance, and flexibility. -6 mass% is more preferable, and 3-5 mass% is still more preferable.
本発明の液体洗浄剤組成物中の（ｃ）成分の含有量は、安定性、洗浄性能、柔軟性能、香料高配合性の観点より、５〜２５質量％であり、８〜２０質量％が好ましく、１０〜１８質量％がより好ましく、１２〜１６質量％が更に好ましい。 Content of (c) component in the liquid cleaning composition of this invention is 5-25 mass% from a viewpoint of stability, washing | cleaning performance, a softness | flexibility performance, and a high fragrance | flavor compounding property, and 8-20 mass% is. Preferably, 10-18 mass% is more preferable, and 12-16 mass% is still more preferable.
本発明の液体洗浄剤組成物中の（ｄ）成分の含有量は、安定性、香料の持続性、残香性の観点より、０．５〜３質量％であり、０．６〜２．５質量％が好ましく、０．７〜２質量％がより好ましく、０．８〜１．５質量％が更に好ましい。 The content of the component (d) in the liquid detergent composition of the present invention is 0.5 to 3% by mass, and 0.6 to 2.5 from the viewpoints of stability, perfume durability, and residual fragrance. % By mass is preferred, 0.7-2% by mass is more preferred, and 0.8-1.5% by mass is still more preferred.
本発明の液体洗浄剤組成物中の（ｅ）成分の含有量は、安定性、洗浄性能、柔軟性能、香料高配合性の観点より、１〜２０質量％であり、２〜１５質量％が好ましく、３〜１２質量％がより好ましく、５〜１０質量％が更に好ましい。 Content of (e) component in the liquid cleaning composition of this invention is 1-20 mass% from a viewpoint of stability, washing | cleaning performance, softness | flexibility performance, and a high fragrance | flavor compounding property, and 2-15 mass% is. Preferably, 3-12 mass% is more preferable, and 5-10 mass% is still more preferable.
本発明の液体洗浄剤組成物中の（ａ）成分と（ｂ）成分の質量比（ａ）／（ｂ）は、安定性、柔軟性能の観点より、１／１〜１０／１であり、３／２〜８／１が好ましく、２／１〜７／１がより好ましく、３／１〜６／１が更に好ましい。 The mass ratio (a) / (b) of the component (a) and the component (b) in the liquid detergent composition of the present invention is 1/1 to 10/1 from the viewpoint of stability and flexibility performance. 3/2 to 8/1 are preferable, 2/1 to 7/1 are more preferable, and 3/1 to 6/1 are still more preferable.
本発明の液体洗浄剤組成物中の（ａ）成分と（ｂ）成分との合計量と（ｃ）成分の質量比［（ａ）＋（ｂ）］／（ｃ）は、安定性、洗浄性能の観点より、２／３〜３／１であり、３／４〜５／２が好ましく、５／６〜２／１がより好ましく、１／１〜３／２が更に好ましい。 In the liquid detergent composition of the present invention, the total amount of the component (a) and the component (b) and the mass ratio of the component (c) [(a) + (b)] / (c) indicate stability, cleaning. From the viewpoint of performance, it is 2/3 to 3/1, preferably 3/4 to 5/2, more preferably 5/6 to 2/1, and still more preferably 1/1 to 3/2.
本発明の液体洗浄剤組成物中の（ｄ）成分と（ｅ）成分の質量比（ｄ）／（ｅ）は、安定性、香料高配合性の観点より、１／２〜１／２０であり、１／４〜１／１８が好ましく、１／６〜１／１６がより好ましく、１／８〜１／１４が更に好ましい。 The mass ratio (d) / (e) of the component (d) and the component (e) in the liquid detergent composition of the present invention is 1/2 to 1/20 from the viewpoint of stability and high blendability of fragrances. Yes, 1/4 to 1/18 is preferable, 1/6 to 1/16 is more preferable, and 1/8 to 1/14 is still more preferable.
本発明の液体洗浄剤組成物は、安定性の観点から（ｆ）成分として、分子中に４〜１０個の炭素原子を含み、且つ芳香族基を有するスルホン酸又はその塩を含有することが好ましい。本発明の組成物中の（ｆ）成分の含有量は、０．１〜１０質量％が好ましく、０．２〜５質量％がより好ましく、０．３〜３質量％が更に好ましい。 From the viewpoint of stability, the liquid detergent composition of the present invention may contain, as component (f), a sulfonic acid or a salt thereof containing 4 to 10 carbon atoms in the molecule and having an aromatic group. preferable. 0.1-10 mass% is preferable, as for content of (f) component in the composition of this invention, 0.2-5 mass% is more preferable, 0.3-3 mass% is still more preferable.
（ｆ）成分としては、例えばベンゼンスルホン酸、トルエンスルホン酸、キシレンスルホン酸、クメンスルホン酸、スルホ安息香酸、スルホフタル酸、ナフタレンスルホン酸及びそれらのナトリウム塩、カリウム塩、ジエタノールアミン塩などが挙げられる。これらの中でも、トルエンスルホン酸、キシレンスルホン酸、クメンスルホン酸及びそれらのナトリウム塩、カリウム塩、ジエタノールアミン塩などが好ましい。また、これらは随意に１種単独で用いても２種以上を併用してもよい。 Examples of the component (f) include benzenesulfonic acid, toluenesulfonic acid, xylenesulfonic acid, cumenesulfonic acid, sulfobenzoic acid, sulfophthalic acid, naphthalenesulfonic acid, and sodium salts, potassium salts, diethanolamine salts thereof, and the like. Among these, toluene sulfonic acid, xylene sulfonic acid, cumene sulfonic acid and their sodium salt, potassium salt, diethanolamine salt and the like are preferable. In addition, these may optionally be used alone or in combination of two or more.
本発明の液体洗浄剤組成物は、安定性の観点から（ｇ）成分として、炭素数１〜４の１価のアルコールを含有することが好ましい。本発明の組成物中の（ｇ）成分の含有量は、０．１〜１０質量％が好ましく、０．５〜５質量％がより好ましく、１〜３質量％が更に好ましい。 The liquid detergent composition of the present invention preferably contains a monohydric alcohol having 1 to 4 carbon atoms as the component (g) from the viewpoint of stability. 0.1-10 mass% is preferable, as for content of the (g) component in the composition of this invention, 0.5-5 mass% is more preferable, and 1-3 mass% is still more preferable.
（ｇ）成分としては、メタノール、エタノール、プロパノール、ブタノール等が挙げられるが、特にエタノールが好ましい。 Examples of the component (g) include methanol, ethanol, propanol, butanol and the like, and ethanol is particularly preferable.
更に本発明の液体洗浄剤組成物には、次の（ｉ）〜(xiii)に示す成分を配合することができる。
（ｉ）アルカリ金属の水酸化物、ケイ酸塩、炭酸ナトリウム等の炭酸塩、及びアルカノールアミンなどのアルカリ剤
（ii）エチレングリコール及びプロピレングリコール等のグリコール類、安息香酸塩（防腐剤としての効果もある）、並びに尿素などの減粘剤及び可溶化剤
（iii）ポリオキシアルキレンベンジルエーテル、ポリオキシアルキレンフェニルエーテルなどの相調整剤及び洗浄力向上剤
（iv）ニトリロ三酢酸塩、エチレンジアミン四酢酸塩、イミノ二酢酸塩、ジエチレントリアミン五酢酸塩、グリコールエーテルジアミン四酢酸塩、ヒドロキシエチルイミノ二酢酸塩及びトリエチレンテトラミン六酢酸塩等のアミノポリ酢酸塩、マロン酸、コハク酸、リンゴ酸、ジグリコール酸、酒石酸及びクエン酸などの金属イオン捕捉剤
（ｖ）ポリアクリル酸、ポリマレイン酸、カルボキシメチルセルロース、重量平均分子量５０００以上のポリエチレングリコール、無水マレイン酸−ジイソブチレン共重合体、無水マレイン酸−メチルビニルエーテル共重合体、無水マレイン酸−酢酸ビニル共重合体、ナフタレンスルホン酸塩ホルマリン縮合物、及び特開昭５９−６２６１４号公報の請求項１〜２１（１頁３欄５行〜３頁４欄１４行）記載のポリマーなどの再汚染防止剤及び分散剤
（vi）ポリビニルピロリドン等の色移り防止剤
（vii）過炭酸ナトリウムまたは過硼酸ナトリウム等の漂白剤
（viii）テトラアセチルエチレンジアミン、特開平６−３１６７００号の一般式（Ｉ−２）〜（Ｉ−７）で表される漂白活性化剤等の漂白活性化剤
（ix）アミラーゼ、プロテアーゼ、リパーゼ及びセルラーゼ等の酵素
（ｘ）塩化カルシウム、硫酸カルシウム、ギ酸、ホウ酸（ホウ素化合物）等の酵素安定化剤
（xi）チノパールＣＢＳ（チバスペシャリティケミカルズ製）やホワイテックスＳＡ（住友化学社製）等の蛍光染料
（xii）シリカ、シリコーン等の消泡剤
（xiii）ブチルヒドロキシトルエン、ジスチレン化クレゾール、亜硫酸ナトリウム及び亜硫酸水素ナトリウム等の酸化防止剤
本発明の液体洗浄剤組成物中、（ｉ）のアルカリ剤の含有量は０．０１〜１０質量％が好ましい。(ii)の減粘剤及び可溶化剤の含有量は０．０１〜３０質量％が好ましい。（iii）の相調整剤及び洗浄力向上剤の含有量は０．０１〜１０質量％が好ましい。（iv）の金属イオン捕捉剤の含有量は０．１〜２０質量％が好ましい。（ｖ）の再汚染防止剤及び分散剤の含有量は０．０１〜１０質量％が好ましい。(vi)の色移り防止剤の含有量は０．０１〜１０質量％が好ましい。（vii）の漂白剤の含有量は０．０１〜１０質量％が好ましい。（viii）の漂白活性化剤の含有量は０．０１〜１０質量％が好ましい。（ix）の酵素の含有量は０．００１〜２質量％が好ましい。（ｘ）の酵素安定化剤の含有量は０．００１〜２質量％が好ましい。（xi）の蛍光染料の含有量は０．００１〜１質量％が好ましい。（xii）の消泡剤の含有量は０．０１〜２質量％が好ましい。（xiii）の酸化防止剤の含有量は０．０１〜２質量％が好ましい。
Furthermore, the components shown in the following (i) to (xiii) can be blended in the liquid detergent composition of the present invention.
(I) Alkali metal hydroxides, silicates, carbonates such as sodium carbonate, and alkali agents such as alkanolamines (ii) glycols such as ethylene glycol and propylene glycol, benzoates (effects as preservatives) And) thickeners and solubilizers such as urea (iii) phase modifiers and detergency improvers such as polyoxyalkylene benzyl ether and polyoxyalkylene phenyl ether (iv) nitrilotriacetate, ethylenediaminetetraacetic acid Salts, aminopolyacetates such as iminodiacetate, diethylenetriaminepentaacetate, glycol etherdiaminetetraacetate, hydroxyethyliminodiacetate and triethylenetetramine hexaacetate, malonic acid, succinic acid, malic acid, diglycolic acid , Metal ion scavengers such as tartaric acid and citric acid (v) poly Acrylic acid, polymaleic acid, carboxymethyl cellulose, polyethylene glycol having a weight average molecular weight of 5000 or more, maleic anhydride-diisobutylene copolymer, maleic anhydride-methyl vinyl ether copolymer, maleic anhydride-vinyl acetate copolymer, naphthalene sulfone Recontamination preventives and dispersants such as acid salt formalin condensate and polymers described in claims 1 to 21 of JP-A-59-62614 (page 1, column 3, line 5 to page 3, column 4, line 14) ) Color transfer inhibitor such as polyvinylpyrrolidone (vii) Bleaching agent such as sodium percarbonate or sodium perborate (viii) Tetraacetylethylenediamine, general formulas (I-2) to (I-7) of JP-A-6-316700 Bleach activators such as bleach activators represented by (ix) Amylase, protease, lipase and cell Enzymes (x) Enzyme stabilizers such as calcium chloride, calcium sulfate, formic acid, boric acid (boron compounds) (xi) Chino Pearl CBS (manufactured by Ciba Specialty Chemicals), Whitetex SA (manufactured by Sumitomo Chemical Co., Ltd.), etc. Fluorescent dyes (xii) Antifoaming agents such as silica and silicone (xiii) Antioxidants such as butylhydroxytoluene, distyrenated cresol, sodium sulfite and sodium bisulfite In the liquid detergent composition of the present invention, (i) The content of the alkaline agent is preferably 0.01 to 10% by mass. The content of the thickening agent and the solubilizing agent (ii) is preferably 0.01 to 30% by mass. The content of the phase adjusting agent and the detergency improving agent (iii) is preferably 0.01 to 10% by mass. The content of the metal ion scavenger (iv) is preferably 0.1 to 20% by mass. The content of the recontamination inhibitor and the dispersant in (v) is preferably from 0.01 to 10% by mass. The content of the color transfer inhibitor (vi) is preferably 0.01 to 10% by mass. The content of the bleaching agent (vii) is preferably 0.01 to 10% by mass. The content of the bleach activator (viii) is preferably 0.01 to 10% by mass. The content of the enzyme (ix) is preferably 0.001 to 2% by mass. The content of the enzyme stabilizer (x) is preferably 0.001 to 2% by mass. The content of the fluorescent dye (xi) is preferably 0.001 to 1% by mass. The content of the antifoaming agent (xii) is preferably 0.01 to 2% by mass. The content of the antioxidant (xiii) is preferably 0.01 to 2% by mass.
本発明の液体洗浄剤組成物は、その他、青味付け剤、抗菌防腐剤、（ｂ）成分以外の陽イオン界面活性剤、両性界面活性剤等を含有することができる。 In addition, the liquid detergent composition of the present invention can contain a bluing agent, an antibacterial preservative, a cationic surfactant other than the component (b), an amphoteric surfactant, and the like.
本発明の液体洗浄剤組成物の２０℃における粘度は、取り扱いの容易さの点で１０〜４００ｍＰａ・ｓが好ましく、３０〜３００ｍＰａ・ｓがより好ましく、５０〜２００ｍＰａ・ｓが更に好ましい。粘度調整剤によりこのような範囲になるように調製することが好ましい。 The viscosity at 20 ° C. of the liquid detergent composition of the present invention is preferably 10 to 400 mPa · s, more preferably 30 to 300 mPa · s, and even more preferably 50 to 200 mPa · s in terms of ease of handling. It is preferable to prepare so that it may become such a range with a viscosity modifier.
なお、これらの粘度は、Ｂ型粘度計（（株）東京計器製、ＶＩＳＣＯＭＥＴＥＲ ＭＯＤＥＬ ＤＶＭ−Ｂ）を用い、ローター３又は４、回転数６０ｒ／ｍｉｎ、測定時間６０秒の条件で測定されたものである。 These viscosities were measured using a B-type viscometer (manufactured by Tokyo Keiki Co., Ltd., VISCOMETER MODEL DVM-B) under the conditions of rotor 3 or 4, rotation speed 60 r / min, measurement time 60 seconds. It is.
粘度調整剤として、減粘剤としてはエタノール、メタノール、プロパノール、グリセリン、エチレングリコール、プロピレングリコール等の炭素数１〜４の低級アルコール、トルエンスルホン酸（塩）、キシレンスルホン酸（塩）等を用いることができ、増粘剤としては水溶性高分子、無機電解質を用いることができる。水溶性高分子としては、ポリマレイン酸、ポリイタコン酸、ビニルメチルエーテル−無水マレイン酸共重合物等が挙げられる。無機電解質としては、硫酸ナトリウム、塩化ナトリウム、塩化カリウム等が挙げられる。 As a viscosity modifier, as a viscosity reducer, a lower alcohol having 1 to 4 carbon atoms such as ethanol, methanol, propanol, glycerin, ethylene glycol, propylene glycol, toluenesulfonic acid (salt), xylenesulfonic acid (salt), or the like is used. As the thickener, a water-soluble polymer or an inorganic electrolyte can be used. Examples of the water-soluble polymer include polymaleic acid, polyitaconic acid, vinyl methyl ether-maleic anhydride copolymer, and the like. Examples of the inorganic electrolyte include sodium sulfate, sodium chloride, potassium chloride and the like.
本発明の液体洗浄剤組成物は、安定性、洗浄性能、損傷性の観点から、ＪＩＳ Ｋ ３３６２：１９９８記載の２０℃で測定するｐＨは６〜９が好ましく、６．５〜８がより好ましい。 In the liquid detergent composition of the present invention, the pH measured at 20 ° C. described in JIS K 3362: 1998 is preferably 6-9, more preferably 6.5-8, from the viewpoints of stability, cleaning performance, and damage. .
実施例１
下記（ａ）成分、（ｂ）成分、（ｃ）成分、（ｄ）成分、（ｅ）成分、更に（ｂ）成分の比較品である（ｂ’）成分を用い、表２〜表４に示す組成の液体洗浄剤組成物を調製した。得られた液体洗浄剤組成物について、その洗浄力、保存安定性、再汚染防止性、柔軟性を下記の方法により評価した。結果を表２〜表４に示す。
Example 1
The following (a) component, (b) component, (c) component, (d) component, (e) component, and (b ') component which is a comparative product of (b) component are further used in Tables 2 to 4 A liquid detergent composition having the composition shown was prepared. About the obtained liquid cleaning composition, the cleaning power, storage stability, recontamination prevention property, and the softness | flexibility were evaluated by the following method. The results are shown in Tables 2-4.
＜配合成分＞
（ａ）成分
・ＬＡＳ：直鎖アルキル（炭素数１０〜１４）ベンゼンスルホン酸ナトリウム、商品名 ネオペレックスＧ−６５（花王株式会社製）（有効分換算して配合した）
・ＥＳ：ポリオキシエチレンアルキルエーテル硫酸ナトリウム、商品名 エマール２７０Ｊ（花王株式会社製）（有効分換算して配合した）
・脂肪酸：商品名 ルナックＬ−５５（花王株式会社製）
（ｂ）成分
・アミン化合物１：ＲＣＯＮＨ(ＣＨ2)3Ｎ(ＣＨ3)2（Ｒ：炭素数１７のアルキル基）
・アミン化合物２：ＲＣＯＯ(ＣＨ2)3Ｎ(ＣＨ3)2（Ｒ：炭素数１７のアルキル基）
・アミン化合物３：ＲＯ(ＣＨ2)3Ｎ(ＣＨ3)2（Ｒ：炭素数１８のアルキル基）
・アミン化合物４：ＲＮＨ(ＣＨ2)3Ｎ(ＣＨ3)2（Ｒ：炭素数１８のアルキル基）
（ｂ’）成分（（ｂ）成分の比較品）
・アミン化合物５：ＲＣＯＮＨ(ＣＨ2)3Ｎ(ＣＨ3)2（Ｒ：炭素数１２のアルキル基）
・アミン化合物６：ＲＣＯＮＨ(ＣＨ2)3Ｎ(ＣＨ3)2（Ｒ：炭素数２２のアルキル基）
・アミン化合物７：ＲＣＯＮＨＣＨ2Ｎ(ＣＨ3)2（Ｒ：炭素数１７のアルキル基）
・アミン化合物８：ＲＣＯＮＨ(ＣＨ2)7Ｎ(ＣＨ3)2（Ｒ：炭素数１７のアルキル基）
（ｃ）成分
・非イオン界面活性剤１：エマルゲン１２０（花王株式会社製）（炭素数１２〜１４の１級アルコールにＥＯを平均１２モル付加させたポリオキシエチレンアルキルエーテル）
・非イオン界面活性剤２：炭素数１２〜１４の直鎖第１級アルコール（商品名 カルコール２４７４（花王株式会社製））にＥＯを平均５モル付加させたポリオキシエチレンアルキルエーテル
・非イオン界面活性剤３：ソフタノール７０（（株）日本触媒製）（炭素数１２〜１４の２級アルコールにＥＯを平均７モル付加させたポリオキシエチレンアルキルエーテル）
・非イオン界面活性剤４：炭素数１２〜１４の直鎖第１級アルコール（商品名 カルコール２４７４（花王株式会社製））にＥＯを平均５モル、ＰＯを平均２モル、ＥＯを平均３モルの順にブロック付加させたポリオキシアルキレンアルキルエーテル
（ｄ）成分
表１に示す香料組成物１〜５
<Blending ingredients>
(A) Component / LAS: straight chain alkyl (10 to 14 carbon atoms) sodium benzenesulfonate, trade name Neoperex G-65 (manufactured by Kao Corporation)
・ ES: Sodium polyoxyethylene alkyl ether sulfate, trade name EMAL 270J (manufactured by Kao Corporation)
・ Fatty acid: Product name LUNAC L-55 (manufactured by Kao Corporation)
(B) Component / Amine compound 1: RCONH (CH 2 ) 3 N (CH 3 ) 2 (R: alkyl group having 17 carbon atoms)
Amine compound 2: RCOO (CH 2 ) 3 N (CH 3 ) 2 (R: an alkyl group having 17 carbon atoms)
Amine compound 3: RO (CH 2 ) 3 N (CH 3 ) 2 (R: an alkyl group having 18 carbon atoms)
Amine compound 4: RNH (CH 2 ) 3 N (CH 3 ) 2 (R: an alkyl group having 18 carbon atoms)
Component (b ′) (Comparative product of component (b))
Amine compound 5: RCONH (CH 2 ) 3 N (CH 3 ) 2 (R: alkyl group having 12 carbon atoms)
Amine compound 6: RCONH (CH 2 ) 3 N (CH 3 ) 2 (R: an alkyl group having 22 carbon atoms)
Amine compound 7: RCONHCH 2 N (CH 3 ) 2 (R: alkyl group having 17 carbon atoms)
Amine compound 8: RCONH (CH 2 ) 7 N (CH 3 ) 2 (R: an alkyl group having 17 carbon atoms)
(C) Component / Nonionic Surfactant 1: Emulgen 120 (manufactured by Kao Corporation) (Polyoxyethylene alkyl ether obtained by adding 12 mol of EO to primary alcohol having 12 to 14 carbon atoms)
Nonionic surfactant 2: Polyoxyethylene alkyl ether obtained by adding 5 mol of EO on average to a linear primary alcohol having 12 to 14 carbon atoms (trade name: Calcoal 2474 (manufactured by Kao Corporation)) Nonionic interface Activator 3: Softanol 70 (manufactured by Nippon Shokubai Co., Ltd.) (polyoxyethylene alkyl ether obtained by adding 7 mol of EO to secondary alcohol having 12 to 14 carbon atoms on average)
・ Nonionic surfactant 4: 12 to 14 carbon linear primary alcohol (trade name Calcoal 2474 (manufactured by Kao Corporation)) with an average of 5 mol of EO, an average of 2 mol of PO, and an average of 3 mol of EO Polyoxyalkylene alkyl ether block-added in this order (d) component Fragrance compositions 1 to 5 shown in Table 1
（ｅ）成分
・ｅ−１：ジエチレングリコールモノブチルエーテル
・ｅ−２：エチレングリコールモノフェニルエーテル
・ｅ−３：トリエチレングリコールモノフェニルエーテル
＜洗浄力の評価法＞
まず、特開平１０−１６８４８５号公報第１４欄第６行に記載の方法に従い、人工汚染布を調製した。次いで、評価用洗浄剤組成物の水溶液１Ｌに１０ｃｍ×１０ｃｍの人工汚染布を５枚入れ、ターゴトメータにて１００ｒｐｍで洗浄した（洗浄条件：洗浄時間５分間、洗浄剤組成物濃度０．０６６７質量％、水の硬度４°ＤＨ、水温２０℃、水道水にてすすぎ５分間）。
(E) Component e-1: Diethylene glycol monobutyl ether e-2: Ethylene glycol monophenyl ether e-3: Triethylene glycol monophenyl ether <Detergency evaluation method>
First, an artificially contaminated cloth was prepared according to the method described in JP-A-10-168485, column 14, line 6. Next, 5 pieces of 10 cm × 10 cm artificially contaminated cloths were placed in 1 L of the aqueous cleaning composition solution for evaluation, and washed with a tartometer at 100 rpm (cleaning conditions: cleaning time 5 minutes, cleaning composition concentration 0.0667 mass%). Water hardness 4 ° DH, water temperature 20 ° C., rinse with tap water for 5 minutes).
洗浄力は汚染前の原布及び洗浄前後の汚染布の５５０ｎｍにおける反射率を自記色彩計（島津製作所製）にて測定し、次式によって洗浄率（％）を求め、５枚の測定平均値を洗浄力とした。洗浄力が４０％以上であれば、洗浄力に優れると判断される。 Detergency measures the reflectance at 550 nm of the raw cloth before contamination and before and after cleaning with a self-recording colorimeter (manufactured by Shimadzu Corporation). Was used as a detergency. If the cleaning power is 40% or more, it is judged that the cleaning power is excellent.
＜保存安定性の評価法＞
５０ｍＬのサンプルビン（Ｎｏ．６広口規格ビン、ガラス製、直径４０ｍｍ、高さ８０ｍｍの円筒形）に、液体洗浄剤組成物を４０ｍＬ充填し、蓋をした後、５℃の恒温室で３０日間静置した。液体の安定性は目視で外観を下記の基準で判定した。
○；均一液体相であり、液安定性に優れる。
△；やや分離又は析出しているように見えるが気にならない程度である。
×；分離又は析出が認められる。
<Method for evaluating storage stability>
A 50 mL sample bottle (No. 6 wide-mouth standard bottle, glass, cylindrical shape with a diameter of 40 mm and a height of 80 mm) was filled with 40 mL of the liquid detergent composition, capped, and then kept in a thermostatic chamber at 5 ° C. for 30 days. Left to stand. The stability of the liquid was visually determined based on the following criteria.
○: A uniform liquid phase and excellent liquid stability.
Δ: Somewhat separated or precipitated, but not so much.
X: Separation or precipitation is observed.
＜再汚染防止性の評価法＞
木綿の白布（金巾２００３布）を１０ｃｍ×１０ｃｍに裁断し、５枚１組とした。評価用洗浄剤組成物の水溶液１Ｌに園芸用鹿沼赤土を加え、ターゴトメーターにて次の条件で洗浄試験を行った。洗浄条件は、洗浄時間：１０分、洗浄剤組成物濃度：０．０８質量％、水の硬度：４°、水の温度：２０℃、すすぎ：２０℃水道水にて５分間流水すすぎである。
<Evaluation method for recontamination prevention>
A white cotton cloth (gold cloth 2003 cloth) was cut into 10 cm × 10 cm to form a set of five sheets. Kanuma red soil for gardening was added to 1 L of an aqueous cleaning composition composition for evaluation, and a cleaning test was conducted with a turgotometer under the following conditions. The washing conditions are: washing time: 10 minutes, detergent composition concentration: 0.08% by mass, water hardness: 4 °, water temperature: 20 ° C., rinse: 20 ° C., running water for 5 minutes in tap water. .
再汚染防止能は、洗浄前の原布（白布）及び試験後の汚染布の４６０ｎｍにおける反射率を自記色彩計（島津製作所製）にて測定し、次式によって再汚染防止率を求め、５枚の測定平均値を下記の基準で評価した。再汚染防止率が６０％以上であれば、再汚染防止能に優れると判断される。 The anti-recontamination ability is determined by measuring the reflectance at 460 nm of the uncleaned cloth (white cloth) and the contaminated cloth after the test with a self-recording colorimeter (manufactured by Shimadzu Corporation), and obtaining the recontamination prevention rate by the following equation: 5 The measurement average value of the sheet was evaluated according to the following criteria. If the recontamination prevention rate is 60% or more, it is judged that the recontamination prevention ability is excellent.
再汚染防止率（％）＝（試験後の反射率／原布の反射率）×１００
＜柔軟性の評価法＞
・標準試験布の調製
全自動洗濯機（松下社製ＮＡ−Ｆ５０Ｋ１）を用いて、木綿タオル、木綿メリヤス未着用肌着、アクリルジャージを入れ、ＪＩＳ Ｋ ３３６２：１９９８記載の洗浄力判定用指標洗剤を標準使用量に従い投入し、標準コースで洗濯を行った。この洗浄サイクルを５回繰り返し、乾燥機で乾燥した処理布を標準試験布として用いた。
・試験布の調製
上記洗濯機を用いて、木綿タオル２枚、木綿未着用肌着２枚、アクリルジャージ２枚を入れ、表２〜４に示した液体洗浄剤組成物を４０ｍＬ入れ、標準コースで洗濯を行った。洗濯終了後、室内（２５℃、４５％ＲＨ）で１昼夜乾燥を行い、各試験布を得た。
・判定
各試験布について、標準試験布を基準として、パネラー５名の官能評価により下記基準で判定した。各パネラーが判定した衣類計６枚の合計点の平均値を求め、柔軟性評価点とした。柔軟性評価点が８点以上の場合、柔軟性に優れると判断される。
Recontamination prevention rate (%) = (reflectance after test / reflectance of base fabric) × 100
<Flexibility evaluation method>
-Preparation of standard test cloth Using a fully automatic washing machine (NA-F50K1 manufactured by Matsushita Co., Ltd.), put cotton towel, cotton knitted underwear, acrylic jersey, and use the detergent for determining the cleaning power described in JIS K 3362: 1998. It was charged according to the standard usage and was washed in the standard course. This washing cycle was repeated 5 times, and a treated cloth dried with a dryer was used as a standard test cloth.
・ Preparation of test cloth Using the washing machine, put 2 cotton towels, 2 cotton underwear, 2 acrylic jerseys, and put 40 mL of the liquid detergent composition shown in Tables 2-4. Laundry was done. After completion of washing, drying was performed for one day in the room (25 ° C., 45% RH) to obtain test cloths.
-Determination About each test cloth, the following reference | standard determined by sensory evaluation of five panelists on the basis of the standard test cloth. The average value of the total score of 6 clothing items determined by each panel was determined and used as the flexibility evaluation score. When the flexibility evaluation score is 8 or more, it is determined that the flexibility is excellent.
標準試験布に比べて明らかに柔らかい：＋２点
標準試験布に比べてやや柔らかい ：＋１点
標準試験布と同等 ： ０点
標準試験布に比べてやや硬い ：−１点
標準試験布に比べて明らかに硬い ：−２点
＜脱水布の香り立ち評価＞
全自動洗濯機（松下社製ＮＡ−Ｆ５０Ｋ１）を用いて、木綿タオル２kg、アクリルジャージ１kgを入れ、ＪＩＳ Ｋ ３３６２：１９９８記載の洗浄力判定用指標洗剤を標準使用量に従い投入し、標準コースで洗濯を行った。この洗浄サイクルを５回繰り返し、乾燥機で乾燥した処理布を標準試験布として用いた。上記洗濯機を用いて、木綿タオル１０枚、アクリルジャージ（３００ｇ）を入れ、表２〜４に示した液体洗浄剤組成物を４０ｍＬ入れ、標準コースで洗濯を行った。この方法で処理した布の香り立ちの評価を10人のパネラーで行った。香りの強さに関する官能評価は次の６段階で行い、平均値を算出した。
Clearly softer than standard test cloth: +2 points Slightly softer than standard test cloth: +1 point Equivalent to standard test cloth: 0 points Slightly harder than standard test cloth: -1 point Clearer than standard test cloth Hard: -2 <Evaluation of fragrance of dehydrated cloth>
Using a fully automatic washing machine (NA-F50K1 manufactured by Matsushita), put 2 kg of cotton towel and 1 kg of acrylic jersey, and inject the index detergent for determining cleaning power described in JIS K 3362: 1998 according to the standard usage amount. Laundry was done. This washing cycle was repeated 5 times, and a treated cloth dried with a dryer was used as a standard test cloth. Using the washing machine, 10 cotton towels and acrylic jersey (300 g) were placed, 40 mL of the liquid detergent composition shown in Tables 2 to 4 was placed, and washing was performed on a standard course. The evaluation of the scent of the fabric treated by this method was carried out by 10 panelists. Sensory evaluation regarding the intensity of fragrance was performed in the following six stages, and the average value was calculated.
０： 匂わない
１： かすかに匂う
２： 匂う
３： 明らかに匂う
４： 強く匂う
５： 非常に強く匂う
＜乾燥布の香り立ち評価＞
脱水布の香り立ち評価を行った後、室内で風乾後、25℃、65％RHの恒温恒湿室で24時間放置した。これらの布を専門パネラー10人により、脱水布の香り立ち評価と同じ基準に従って、残香性の評価を行い、平均値を算出した。
0: Does not smell 1: Smells faintly 2: Smells 3: Clearly smells 4: Smells strongly 5: Smells very strongly <Dry fragrance evaluation>
After the deodorizing cloth was evaluated for fragrance, it was air-dried indoors and left in a constant temperature and humidity room at 25 ° C. and 65% RH for 24 hours. These cloths were evaluated by 10 expert panelists according to the same criteria as the evaluation of fragrance of dehydrated cloth, and the average value was calculated.
*1 蛍光染料：チノパールＣＢＳ−Ｘ（チバスペシャリティケミカルス社製）
*2 ポリマー：特開平１０−６０４７６号公報の４頁段落００２０の合成例１の方法で合成したフェノキシポリエチレングリコール−アクリル酸−マレイン酸共重合体
*3 シリコーン：アミノ変性シリコーン（ＢＹ−１６、東レ・ダウコーニング社製）
*4 陽イオン界面活性剤：コータミン８６Ｗ（花王株式会社製）
* 1 Fluorescent dye: Chino Pearl CBS-X (Ciba Specialty Chemicals)
* 2 Polymer: Phenoxypolyethylene glycol-acrylic acid-maleic acid copolymer synthesized by the method of Synthesis Example 1 on page 4, paragraph 0020 of JP-A-10-60476.
* 3 Silicone: amino-modified silicone (BY-16, manufactured by Toray Dow Corning)
* 4 Cationic surfactant: Cotamin 86W (manufactured by Kao Corporation)
Claims (7)
（ａ）成分と（ｂ）成分の質量比（ａ）／（ｂ）が１／１〜１０／１、
（ａ）成分と（ｂ）成分との合計量と（ｃ）成分の質量比［（ａ）＋（ｂ）］／（ｃ）が２／３〜３／１、
（ｄ）成分と（ｅ）成分の質量比（ｄ）／（ｅ）が１／２〜１／２０である繊維製品用の液体洗浄剤組成物。
（ａ）陰イオン界面活性剤
（ｂ）一般式（Ｉ）で表されるアミン化合物
独立に、炭素数１〜６のアルキル基又はヒドロキシアルキル基、ＸはＮＨ、ＣＯＮＨ、ＣＯＯ及びＯから選ばれる基、Ｒ4は炭素数２〜６のアルキレン基を示す。〕
（ｃ）非イオン界面活性剤
（ｄ）香料
（ｅ）エチレングリコールモノブチルエーテル、ジエチレングリコールモノブチルエーテル（ブチルカルビトール）、プロピレングリコールジエチレングリコールモノブチルエーテル、ジプロピレングリコールエチレングリコールモノブチルエーテル、エチレングリコールモノフェニルエーテル、トリエチレングリコールモノフェニルエーテルから選ばれる化合物を含む成分 Following component (a), (b) component (c) component (d) component and the (e) contains a component, the content of component (a) in the composition is from 10 to 20 wt%, (b) The content of the component is 0.5 to 10% by mass, the content of the (c) component is 5 to 25% by mass, the content of the (d) component is 0.5 to 3% by mass, the content of the (e) component Is 3 to 20% by mass,
The mass ratio (a) / (b) of the component (a) to the component (b) is 1/1 to 10/1,
The total amount of the component (a) and the component (b) and the mass ratio of the component (c) [(a) + (b)] / (c) is 2/3 to 3/1,
A liquid detergent composition for textiles in which the mass ratio (d) / (e) of the component (d) to the component (e) is 1/2 to 1/20.
(A) Anionic surfactant (b) Amine compound represented by formula (I)
(C) Nonionic surfactant (d) Perfume (e) Ethylene glycol monobutyl ether, diethylene glycol monobutyl ether (butyl carbitol), propylene glycol diethylene glycol monobutyl ether, dipropylene glycol ethylene glycol monobutyl ether, ethylene glycol monophenyl ether, tri Components containing a compound selected from ethylene glycol monophenyl ether
・香料素材Ａ群
アセチルセドレン、α−ダマスコン、１−デカナールとアンスラニル酸メチルとのシッフベース、アミルシンナミックアルデヒド、サリチル酸アミル、β−ダマスコン、シクラメンアルデヒド、ダマセノン、δ−ダマスコン、ゲラニルニトリル、α−ヨノン、β−ヨノン、メチルシクロオクチルカーボネート、リリアール、リリアールとアンスラニル酸メチルとのシッフベース、リモネン、酢酸リナリル、リラールとアンスラニル酸メチルとのシッフベース、酢酸ジヒドロテルピニル、エチレンドデカンジオエート、マイラックアルデヒド、ネロリドール、フェニル酢酸 ｐ−クレジル、３−メチル−５−フェニルペンタ ン−１−オール、イソカンフィルシクロヘキサノール、２−メチル−４−（２，２，３−トリメチル−３−シクロペンテン−１−イル）−２−ブテン−１−オール、６−アセチル−１，１，２，４，４，７−ヘキサメチル−テトラリン、酢酸テルピニル及びエチレンドデカンジオエートからなる群。
・香料素材Ｂ群
シトラール、シクロペンタデカノン、ジフェニルメタン、エチルトリシクロ［５．２．１．０2,6］デカン−２−イルカーボキシレート、ｐ−イソプロピルシクロヘキシルメタ
ノール、エチル−２−シクロヘキシルプロピオネート、サンタロール、ジメチルオクタノール、テトラヒドロリナロール、ベチベロール、酢酸ベチベリル、アリルヨノン、アンブレットリド、オーランチオール、サリチル酸 ｃｉｓ−３−ヘキセニル、ギ酸シトロネリル、エストラゴール、エチレンブラシレート、ギ酸ゲラニル、β−ナフトールメチルエーテル、シクロヘキシルプロピオン酸アリル、シトロネラール、１−（３，３−ジメチル−６−シクロヘキセン−１−イル）−ペンタ−４−エン−１−オンと１−（３，３−ジメチル−１−シクロヘキセン−１−イル）−ペンタ−４−エン−１−オンの混合物、エチルデハイドロシクロゲラネート、ｌ−メントール、シクロペンタデカノリド、チモール、４−メチル−３−デセン−５−オール、１−デカノール、１−ノナノール、デカナール、ウンデカナール、ドデカナール、２−メチルウンデカナール、γ−ウンデカラクトン、酪酸イソアミル、酢酸ノニル、ウンデセナール、ｎ−ノナナール、ヘプタン酸アリル、シトロネリルオキシアセトアルデヒド及びシクロペンタデカノリドからなる群。 The liquid detergent composition for textiles according to claim 4, wherein the fragrance material AB is at least one selected from the group consisting of the fragrance material group A and the fragrance material group B shown below.
Fragrance material group A acetyl cedrene, α-damascone, Schiff base of 1-decanal and methyl anthranilate, amylcinnamic aldehyde, amyl salicylate, β-damascone, cyclamenaldehyde, damasenone, δ-damascone, geranylnitrile, α- Ionone, β-ionone, methylcyclooctyl carbonate, lyrial, Schiff base of lilyal and methyl anthranilate, limonene, linalyl acetate, Schiff base of laral and methyl anthranilate, dihydroterpinyl acetate, ethylene dodecanedioate, mylacaldehyde , Nerolidol, phenylacetic acid p-cresyl, 3-methyl-5-phenylpentan-1-ol, isocamphylcyclohexanol, 2-methyl-4- (2,2,3-trimethyl-3-silane Clopenten-1-yl) -2-buten-1-ol, 6-acetyl-1,1,2,4,4,7-hexamethyl-tetralin, terpinyl acetate and ethylenedodecandioate.
Fragrance material group B: Citral, cyclopentadecanone, diphenylmethane, ethyltricyclo [5.2.1.0 2,6 ] decan-2-ylcarboxylate, p-isopropylcyclohexylmethanol, ethyl-2-cyclohexylpro Pionate, Santalol, Dimethyloctanol, Tetrahydrolinalol, Vetiverol, Vetiberyl acetate, Allyl ionone, Ambretlide, Aulanthiol, Salicylic acid cis-3-Hexenyl, Citronellyl formate, Estragol, Ethylene brushate, Geranyl formate, β-naphthol Methyl ether, allyl cyclohexylpropionate, citronellal, 1- (3,3-dimethyl-6-cyclohexen-1-yl) -pent-4-en-1-one and 1- (3,3-dimethyl-1-cyclohexane Sen-1-yl) -pent-4-en-1-one, ethyl dehydrocyclogeranate, l-menthol, cyclopentadecanolide, thymol, 4-methyl-3-decen-5-ol, 1-decanol, 1-nonanol, decanal, undecanal, dodecanal, 2-methylundecanal, γ-undecalactone, isoamyl butyrate, nonyl acetate, undecenal, n-nonanal, allyl heptanoate, citronellyloxyacetaldehyde and cyclopenta A group consisting of decanolide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006146967A JP4879654B2 (en) | 2006-05-26 | 2006-05-26 | Liquid detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006146967A JP4879654B2 (en) | 2006-05-26 | 2006-05-26 | Liquid detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2007314693A JP2007314693A (en) | 2007-12-06 |
| JP4879654B2 true JP4879654B2 (en) | 2012-02-22 |
Family
ID=38848847
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006146967A Active JP4879654B2 (en) | 2006-05-26 | 2006-05-26 | Liquid detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4879654B2 (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5403875B2 (en) * | 2007-03-01 | 2014-01-29 | 小林製薬株式会社 | Fragrance composition |
| JP5419357B2 (en) * | 2008-01-22 | 2014-02-19 | 花王株式会社 | Liquid detergent composition |
| JP5557986B2 (en) * | 2008-04-14 | 2014-07-23 | 花王株式会社 | Textile treatment composition |
| JP5685067B2 (en) * | 2009-12-08 | 2015-03-18 | 花王株式会社 | Method for treating cotton cloth that imparts water diffusion promoting ability to cotton cloth |
| JP5225972B2 (en) * | 2009-12-28 | 2013-07-03 | 花王株式会社 | Liquid softener composition for clothing |
| JP5604221B2 (en) * | 2010-08-19 | 2014-10-08 | 花王株式会社 | How to process clothing |
| JP5852313B2 (en) * | 2011-03-04 | 2016-02-03 | 花王株式会社 | Raw dry odor control agent |
| JP4897933B1 (en) | 2011-04-22 | 2012-03-14 | 花王株式会社 | Liquid detergent composition |
| JP2016199748A (en) * | 2015-04-06 | 2016-12-01 | ライオン株式会社 | Liquid detergent composition |
| JP6716200B2 (en) * | 2015-04-17 | 2020-07-01 | 花王株式会社 | Liquid detergent composition for clothing |
| CN110713863B (en) * | 2018-07-13 | 2022-10-04 | 花王株式会社 | Liquid detergent composition |
| JP6891156B2 (en) * | 2018-11-14 | 2021-06-18 | 花王株式会社 | Soap bubble fragrance |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4663106B2 (en) * | 2000-12-08 | 2011-03-30 | 花王株式会社 | Cleaning composition |
| JP2004143638A (en) * | 2002-10-25 | 2004-05-20 | Kao Corp | Softening agent composition |
| JP2004196857A (en) * | 2002-12-16 | 2004-07-15 | Kao Corp | Production method for liquid detergent composition |
| JP2005029753A (en) * | 2003-07-11 | 2005-02-03 | Kao Corp | Aqueous liquid composition |
| JP4170170B2 (en) * | 2003-07-11 | 2008-10-22 | 花王株式会社 | Aqueous liquid composition |
-
2006
- 2006-05-26 JP JP2006146967A patent/JP4879654B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2007314693A (en) | 2007-12-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4879654B2 (en) | Liquid detergent composition | |
| JP6086957B2 (en) | Liquid cleaning agent | |
| EP3172301B1 (en) | Fabric and home care treatment compositions | |
| EP3172300B1 (en) | Fabric and home care treatment composition | |
| JP6945945B2 (en) | Consumer product composition containing microcapsules | |
| EP3172298B1 (en) | Fabric and home care treatment compositions | |
| EP3172303B1 (en) | Fabric and home care treatment compositions | |
| JP5580166B2 (en) | Liquid detergent composition | |
| JP2019056122A (en) | Cleaning composition containing cationic polymer | |
| JP4829536B2 (en) | Betaine-type compound and detergent composition containing the same | |
| JP2017528534A (en) | Method for preparing a perfumed stable composition | |
| DE102007056525A1 (en) | Polyoxyalkylenamine for improved perfume yield | |
| JP2008519779A (en) | Geranionitrile alternative | |
| JP2019049002A (en) | Detergent composition comprising cationic polymer | |
| AU2012397240A1 (en) | Fabric conditioner containing an amine functional silicone | |
| JP2021181466A (en) | Consumer product compositions comprising microcapsules | |
| AU2011225788A1 (en) | Liquid concentrated fabric softener composition | |
| EP2857579A1 (en) | Treatment agent composition for fiber product | |
| US20090130934A1 (en) | Esterquats Containing OH Groups For Improving Fragrance Effect | |
| JP7359865B2 (en) | Method of using antioxidants in fabric treatment compositions for treating elastane-containing fabrics | |
| JP5990412B2 (en) | Liquid detergent composition for textile products | |
| KR20140130426A (en) | Liquid detergent composition | |
| JP6910199B2 (en) | Fragrance composition for clothing detergent and detergent composition for clothing | |
| JP2023008435A (en) | Liquid detergent and cleaning liquid | |
| JP6089289B2 (en) | Liquid softener composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20101022 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20101102 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20101228 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20111129 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20111130 |
|
| R151 | Written notification of patent or utility model registration |
Ref document number: 4879654 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R151 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20141209 Year of fee payment: 3 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |