JP5557986B2 - Textile treatment composition - Google Patents
Textile treatment composition Download PDFInfo
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- JP5557986B2 JP5557986B2 JP2008104416A JP2008104416A JP5557986B2 JP 5557986 B2 JP5557986 B2 JP 5557986B2 JP 2008104416 A JP2008104416 A JP 2008104416A JP 2008104416 A JP2008104416 A JP 2008104416A JP 5557986 B2 JP5557986 B2 JP 5557986B2
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- Prior art keywords
- component
- fragrance
- mass
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- group
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims description 63
- 239000004753 textile Substances 0.000 title claims description 33
- 239000003205 fragrance Substances 0.000 claims description 75
- 125000004432 carbon atom Chemical group C* 0.000 claims description 34
- 239000003795 chemical substances by application Substances 0.000 claims description 34
- 238000000034 method Methods 0.000 claims description 30
- 239000000835 fiber Substances 0.000 claims description 27
- 150000001875 compounds Chemical class 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 239000000796 flavoring agent Substances 0.000 claims description 14
- 235000019634 flavors Nutrition 0.000 claims description 13
- 238000001179 sorption measurement Methods 0.000 claims description 9
- 125000003545 alkoxy group Chemical group 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 230000001737 promoting effect Effects 0.000 claims description 4
- 125000001424 substituent group Chemical group 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 239000000047 product Substances 0.000 description 52
- -1 silicate compound Chemical class 0.000 description 29
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 21
- 239000000194 fatty acid Substances 0.000 description 15
- 235000014113 dietary fatty acids Nutrition 0.000 description 14
- 229930195729 fatty acid Natural products 0.000 description 14
- 125000000217 alkyl group Chemical group 0.000 description 13
- 239000004205 dimethyl polysiloxane Substances 0.000 description 13
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 13
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 13
- 230000015572 biosynthetic process Effects 0.000 description 10
- 150000004665 fatty acids Chemical class 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 238000003786 synthesis reaction Methods 0.000 description 9
- 239000002253 acid Chemical class 0.000 description 8
- 239000004615 ingredient Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- ZCTQGTTXIYCGGC-UHFFFAOYSA-N Benzyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 125000003342 alkenyl group Chemical group 0.000 description 6
- 150000002430 hydrocarbons Chemical group 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 239000002304 perfume Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- VPKMGDRERYMTJX-CMDGGOBGSA-N 1-(2,6,6-Trimethyl-2-cyclohexen-1-yl)-1-penten-3-one Chemical compound CCC(=O)\C=C\C1C(C)=CCCC1(C)C VPKMGDRERYMTJX-CMDGGOBGSA-N 0.000 description 4
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 4
- ZFMSMUAANRJZFM-UHFFFAOYSA-N Estragole Chemical compound COC1=CC=C(CC=C)C=C1 ZFMSMUAANRJZFM-UHFFFAOYSA-N 0.000 description 4
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000007983 Tris buffer Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 description 4
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000008237 rinsing water Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 3
- HMNKTRSOROOSPP-UHFFFAOYSA-N 3-Ethylphenol Chemical compound CCC1=CC=CC(O)=C1 HMNKTRSOROOSPP-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000012634 fragment Substances 0.000 description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- 230000001953 sensory effect Effects 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000003760 tallow Substances 0.000 description 3
- 150000003512 tertiary amines Chemical class 0.000 description 3
- NOOLISFMXDJSKH-KXUCPTDWSA-N (-)-Menthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-KXUCPTDWSA-N 0.000 description 2
- ULDHMXUKGWMISQ-SECBINFHSA-N (-)-carvone Chemical compound CC(=C)[C@@H]1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-SECBINFHSA-N 0.000 description 2
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- SCCDQYPEOIRVGX-UHFFFAOYSA-N Acetyleugenol Chemical compound COC1=CC(CC=C)=CC=C1OC(C)=O SCCDQYPEOIRVGX-UHFFFAOYSA-N 0.000 description 2
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical class [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 2
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 2
- 239000005770 Eugenol Substances 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- ZYEMGPIYFIJGTP-UHFFFAOYSA-N O-methyleugenol Chemical compound COC1=CC=C(CC=C)C=C1OC ZYEMGPIYFIJGTP-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- MOYAFQVGZZPNRA-UHFFFAOYSA-N Terpinolene Chemical compound CC(C)=C1CCC(C)=CC1 MOYAFQVGZZPNRA-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- HMKKIXGYKWDQSV-KAMYIIQDSA-N alpha-Amylcinnamaldehyde Chemical compound CCCCC\C(C=O)=C\C1=CC=CC=C1 HMKKIXGYKWDQSV-KAMYIIQDSA-N 0.000 description 2
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 description 2
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 235000015278 beef Nutrition 0.000 description 2
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 description 2
- UAHWPYUMFXYFJY-UHFFFAOYSA-N beta-myrcene Chemical compound CC(C)=CCCC(=C)C=C UAHWPYUMFXYFJY-UHFFFAOYSA-N 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- CRPUJAZIXJMDBK-UHFFFAOYSA-N camphene Chemical compound C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 description 2
- 125000001589 carboacyl group Chemical group 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 229940043350 citral Drugs 0.000 description 2
- 229930003633 citronellal Natural products 0.000 description 2
- 235000000983 citronellal Nutrition 0.000 description 2
- 235000000484 citronellol Nutrition 0.000 description 2
- JOZKFWLRHCDGJA-UHFFFAOYSA-N citronellol acetate Chemical compound CC(=O)OCCC(C)CCC=C(C)C JOZKFWLRHCDGJA-UHFFFAOYSA-N 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 229960000956 coumarin Drugs 0.000 description 2
- 235000001671 coumarin Nutrition 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229960002217 eugenol Drugs 0.000 description 2
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 2
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- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 229910017053 inorganic salt Inorganic materials 0.000 description 2
- 229930002839 ionone Natural products 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
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- 229940087305 limonene Drugs 0.000 description 2
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- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004811 liquid chromatography Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
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- 239000002736 nonionic surfactant Substances 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
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- 239000003921 oil Substances 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
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- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 2
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- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
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- 229910000077 silane Inorganic materials 0.000 description 2
- SUBJHSREKVAVAR-UHFFFAOYSA-N sodium;methanol;methanolate Chemical compound [Na+].OC.[O-]C SUBJHSREKVAVAR-UHFFFAOYSA-N 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
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- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 1
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- 239000004215 Carbon black (E152) Substances 0.000 description 1
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- BJIOGJUNALELMI-ARJAWSKDSA-N cis-isoeugenol Chemical compound COC1=CC(\C=C/C)=CC=C1O BJIOGJUNALELMI-ARJAWSKDSA-N 0.000 description 1
- SECPZKHBENQXJG-UHFFFAOYSA-N cis-palmitoleic acid Natural products CCCCCCC=CCCCCCCCC(O)=O SECPZKHBENQXJG-UHFFFAOYSA-N 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
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- 230000006837 decompression Effects 0.000 description 1
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 1
- DENRZWYUOJLTMF-UHFFFAOYSA-N diethyl sulfate Chemical compound CCOS(=O)(=O)OCC DENRZWYUOJLTMF-UHFFFAOYSA-N 0.000 description 1
- 229940008406 diethyl sulfate Drugs 0.000 description 1
- 229930008394 dihydromyrcenol Natural products 0.000 description 1
- XSNQECSCDATQEL-UHFFFAOYSA-N dihydromyrcenol Chemical compound C=CC(C)CCCC(C)(C)O XSNQECSCDATQEL-UHFFFAOYSA-N 0.000 description 1
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- LCWMKIHBLJLORW-UHFFFAOYSA-N gamma-carene Natural products C1CC(=C)CC2C(C)(C)C21 LCWMKIHBLJLORW-UHFFFAOYSA-N 0.000 description 1
- HIGQPQRQIQDZMP-UHFFFAOYSA-N geranil acetate Natural products CC(C)=CCCC(C)=CCOC(C)=O HIGQPQRQIQDZMP-UHFFFAOYSA-N 0.000 description 1
- 229940113087 geraniol Drugs 0.000 description 1
- HIGQPQRQIQDZMP-DHZHZOJOSA-N geranyl acetate Chemical compound CC(C)=CCC\C(C)=C\COC(C)=O HIGQPQRQIQDZMP-DHZHZOJOSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
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- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- SDQFDHOLCGWZPU-UHFFFAOYSA-N lilial Chemical compound O=CC(C)CC1=CC=C(C(C)(C)C)C=C1 SDQFDHOLCGWZPU-UHFFFAOYSA-N 0.000 description 1
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- UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- 229940116837 methyleugenol Drugs 0.000 description 1
- PRHTXAOWJQTLBO-UHFFFAOYSA-N methyleugenol Natural products COC1=CC=C(C(C)=C)C=C1OC PRHTXAOWJQTLBO-UHFFFAOYSA-N 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
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- 238000005192 partition Methods 0.000 description 1
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- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
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- 238000002360 preparation method Methods 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- KWVISVAMQJWJSZ-VKROHFNGSA-N solasodine Chemical compound O([C@@H]1[C@@H]([C@]2(CC[C@@H]3[C@@]4(C)CC[C@H](O)CC4=CC[C@H]3[C@@H]2C1)C)[C@@H]1C)[C@]11CC[C@@H](C)CN1 KWVISVAMQJWJSZ-VKROHFNGSA-N 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
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- 229960000790 thymol Drugs 0.000 description 1
- BJIOGJUNALELMI-UHFFFAOYSA-N trans-isoeugenol Natural products COC1=CC(C=CC)=CC=C1O BJIOGJUNALELMI-UHFFFAOYSA-N 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/005—Compositions containing perfumes; Compositions containing deodorants
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/162—Organic compounds containing Si
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/503—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms without bond between a carbon atom and a metal or a boron, silicon, selenium or tellurium atom
- D06M13/507—Organic silicon compounds without carbon-silicon bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Detergent Compositions (AREA)
Description
本発明は繊維製品処理剤組成物に関する。 The present invention relates to a textile product treating agent composition.
近年、香りに対する意識の高まりから、衣料用洗浄剤や仕上げ剤などの繊維製品処理剤に残香性のある香料を用いて、洗濯終了後にも繊維製品に香りが持続する技術が開発されている。これらは、親油性の高い揮発蒸散しにくい香料成分を用いる技術が一般的であるが、このような香料成分は匂い立ちが悪く、重厚な香りの香料成分が多いため、残る香調はこれらの香りで決定されてしまう。一方、親水性の高い香料、或いは比較的親水性の香料成分は匂い立ちに優れ、親油性の香料成分に比べ素材数が多くあることから、さまざまな香りの設計が可能である。しかし、繊維製品への吸着性が乏しいため、処理された繊維製品の香りが弱く、更に持続性も弱くなってしまう事から、親水性の高い香料、或いは比較的親水性の香料成分の吸着性を改善し、繊維製品に残留する香調のバリエーションを広げる技術が強く求められている。 In recent years, with the growing awareness of fragrance, a technique has been developed in which a fragrance is maintained in a textile product even after washing is finished by using a fragrance having a residual scent in a textile treatment agent such as a cleaning agent for clothes and a finishing agent. These techniques generally use a fragrance component that is highly lipophilic and difficult to evaporate, but such a fragrance component has a bad smell and a lot of fragrance components with a heavy fragrance, so the remaining fragrance is It is determined by the scent. On the other hand, a highly hydrophilic fragrance or a relatively hydrophilic fragrance component is excellent in smell and has a larger number of materials than an oleophilic fragrance component, so various fragrances can be designed. However, since the adsorptivity to fiber products is poor, the scent of the processed fiber products is weak and the sustainability is also weakened. Therefore, the adsorptivity of highly hydrophilic fragrances or relatively hydrophilic fragrance components There is a strong demand for a technology that improves the fragrance and expands the variation of the scent that remains in textile products.
一方、ケイ酸エステル化合物は残香性を付与する技術として知られている。ケイ酸エステルを含有する繊維製品処理剤は、特許文献1、特許文献2、特許文献3、特許文献4等に開示されており、特に特許文献4には香料組成物との併用が記載されている。
特許文献1〜4に記載されている技術は、ケイ酸エステルの加水分解物が香料成分として用いられ、繊維製品に付着したケイ酸エステルが徐々に加水分解することで香りの持続性を向上させる技術であるため、アルコール系の香料成分に限られる点や、水が存在しなければ香りがしないなどの課題がある。ケイ酸エステルの賦香技術で用いられるアルコール系の香料は種類に限りがあり、衣類に残る香りのバリエーションを広げることはケイ酸エステルの賦香技術だけでは対応できない。また、特定のケイ酸エステルが比較的親水性の香料成分の繊維製品への吸着性を向上させる点については示唆するものではない。特許文献4は他の香料成分との併用が具体的に例示されているが、これらは香料の一部としてケイ酸エステル化合物を用いる技術であり、比較的親水性の香料成分とケイ酸エステルを特定の比率で含有させた場合の効果については示唆するものではない。 In the techniques described in Patent Documents 1 to 4, the hydrolyzate of silicate ester is used as a fragrance component, and the silicate ester attached to the fiber product is gradually hydrolyzed to improve the fragrance sustainability. Since it is a technique, there are problems such as being limited to alcohol-based fragrance ingredients and not having a scent unless water is present. Alcohol-based fragrances used in the silicate aroma technology are limited in kind, and it is not possible to expand the variation of the fragrance remaining in clothing by using the silicate aroma technology alone. Moreover, it does not suggest that the specific silicate ester improves the adsorptivity of the relatively hydrophilic fragrance component to the fiber product. Patent Document 4 specifically illustrates the combined use with other fragrance components, but these are techniques using a silicate ester compound as a part of the fragrance, and a relatively hydrophilic fragrance component and a silicate ester are used. There is no suggestion of the effect when it is contained in a specific ratio.
従って本発明の課題は、衣料用洗浄剤や仕上げ剤等の繊維製品処理剤を用いて繊維製品を処理した場合に香料の吸着性、特に比較的親水性の香料の吸着性を高めることができ、繊維製品に残存する香調のバリエーションを広げ、さまざまな香りを長時間にわたり強く賦香する事ができる繊維製品処理剤組成物を提供することにある。 Therefore, the object of the present invention is to improve the adsorptivity of fragrances, in particular, the adsorptivity of relatively hydrophilic fragrances, when textile products are treated with a textile product treating agent such as a cleaning agent for clothes and a finishing agent. An object of the present invention is to provide a textile product treating agent composition capable of widening a variety of fragrances remaining in textile products and capable of strongly perfusing various fragrances over a long period of time.
本発明は、下記(a)成分及び(b1)成分を、(a)成分/(b1)成分=98/2〜20/80の質量比で含有する繊維製品処理剤組成物、並びにこの繊維製品処理剤組成物を、水を媒体として繊維製品に接触させる、(b1)成分の繊維製品への吸着を促進させる方法を提供する。
(a):一般式(1)で表される化合物
The present invention provides a fiber product treating agent composition containing the following component (a) and component (b1) at a mass ratio of (a) component / (b1) component = 98/2 to 20/80, and the fiber product. Provided is a method for promoting adsorption of the component (b1) to a fiber product, wherein the treating agent composition is brought into contact with the fiber product using water as a medium.
(A): Compound represented by the general formula (1)
〔式中、Xは−OH、−R1(R1は置換基としてフェニル基、水酸基又はアルコキシ基を有していても良い総炭素数1〜22の脂肪族炭化水素基)又は−OR2(R2は炭素数6〜22の炭化水素基)、YはX又は−OSi(X)3、nは平均値を示す0〜15の数である。複数個のX及びYはそれぞれ同一でも異なっていても良いが、一分子中に−OR2を少なくとも1つ有する。〕
(b1):logPowが3.0以上、5.0以下の香料。
[Wherein, X is —OH, —R 1 (R 1 is an aliphatic hydrocarbon group having 1 to 22 carbon atoms in total which may have a phenyl group, a hydroxyl group or an alkoxy group as a substituent) or —OR 2. (R 2 is a hydrocarbon group having 6 to 22 carbon atoms), Y is X or —OSi (X) 3 , and n is a number of 0 to 15 indicating an average value. A plurality of X and Y may be the same or different, but have at least one —OR 2 in one molecule. ]
(B1): A fragrance having a log Pow of 3.0 or more and 5.0 or less.
本発明により、香料の吸着性、特に比較的親水性の香料の繊維製品への吸着性を高めることができ、繊維製品に残る香りのバリエーションを広げ、さらにその香りを長時間にわたり強く賦香する事ができる。 By this invention, the adsorptivity of a fragrance | flavor, especially the adsorptivity to the fiber product of a comparatively hydrophilic fragrance | flavor can be improved, the variation of the fragrance which remains in a fiber product is expanded, and also the fragrance is strongly scented for a long time. I can do things.
[(a)成分]
本発明の(a)成分は、上記一般式(1)で表される化合物である。
[(A) component]
The component (a) of the present invention is a compound represented by the above general formula (1).
一般式(1)において、Xは−OH、−R1又は−OR2、YはX又は−OSi(X)3、nは平均値を示す0〜15の数であり、複数個のX及びYはそれぞれ同一でも異なっていても良いが、一分子中に−OR2を少なくとも1つ有する。 In the general formula (1), X is —OH, —R 1 or —OR 2 , Y is X or —OSi (X) 3 , n is a number of 0 to 15 indicating an average value, and a plurality of X and Y may be the same or different, but has at least one —OR 2 in one molecule.
R1は置換基としてフェニル基、水酸基又はアルコキシ基を有していても良い総炭素数1〜22の脂肪族炭化水素基を示すが、置換基としてフェニル基、水酸基又はアルコキシ基を有していても良い総炭素数1〜22の直鎖又は分岐鎖のアルキル基又はアルケニル基が好ましく、nが0の場合には、炭素数6〜18の直鎖又は分岐鎖のアルキル基がより好ましく、n−ヘキシル基、n−オクチル基、n−デシル基、n−ドデシル基、n−ヘキサデシル基、n−オクタデシル基等の炭素数6〜18の直鎖アルキル基が更に好ましく、炭素数10〜18の直鎖アルキル基が更により好ましい。 R 1 represents an aliphatic hydrocarbon group having 1 to 22 carbon atoms which may have a phenyl group, a hydroxyl group or an alkoxy group as a substituent, but has a phenyl group, a hydroxyl group or an alkoxy group as a substituent. A linear or branched alkyl group or alkenyl group having 1 to 22 total carbon atoms may be preferable, and when n is 0, a linear or branched alkyl group having 6 to 18 carbon atoms is more preferable, Straight chain alkyl groups having 6 to 18 carbon atoms such as n-hexyl group, n-octyl group, n-decyl group, n-dodecyl group, n-hexadecyl group and n-octadecyl group are more preferable, and the number of carbon atoms is 10 to 18 Are even more preferred.
R2は炭素数6〜22、好ましくは6〜15、より好ましくは8〜15の炭化水素基を示すが、炭化水素基としてはアルキル基、アルケニル基又はアルキルアリール基が好ましく、特に分岐構造を有するアルキル基及びアルケニル基から選ばれる基が、繊維製品への(b1)成分の吸着性を向上させる観点から好適である。 R 2 represents a hydrocarbon group having 6 to 22 carbon atoms, preferably 6 to 15 carbon atoms, more preferably 8 to 15 carbon atoms, and the hydrocarbon group is preferably an alkyl group, an alkenyl group or an alkylaryl group, particularly having a branched structure. A group selected from an alkyl group and an alkenyl group is preferable from the viewpoint of improving the adsorptivity of the component (b1) to the fiber product.
一般式(1)において、nが0の場合には、4個のXのうち2〜4個、好ましくは3又は4個が−OR2であり、残りが−R1である化合物が好適である。 In the general formula (1), when n is 0, a compound in which 2 to 4 of 4 X, preferably 3 or 4 is —OR 2 and the rest is —R 1 is suitable. is there.
n=0の場合の好ましい化合物としては、下記式(1−1)又は(1−2)で表される化合物が挙げられる。 A preferable compound in the case of n = 0 includes a compound represented by the following formula (1-1) or (1-2).
〔式中、R1及びR2は前記と同じ意味を示す。〕
一般式(1)において、nが1〜15の場合には、nは平均値を示し、全てのX及びYに対して、1/10以上、好ましくは1/8以上が−OR2であり、残りが−R1である化合物が好適であり、全てのX及びYが−OR2である化合物が特に好ましい。nとしては、1〜10が好ましく、1〜5がより好ましい。
[Wherein, R 1 and R 2 have the same meaning as described above. ]
In the general formula (1), when n is 1 to 15, n represents an average value, and for all X and Y, 1/10 or more, preferably 1/8 or more is -OR 2 . A compound in which the remainder is —R 1 is preferred, and a compound in which all X and Y are —OR 2 is particularly preferred. As n, 1-10 are preferable and 1-5 are more preferable.
nが1〜15の場合の好ましい化合物としては、下記式(1−3)又は(1−4)で表される化合物が挙げられる。 Preferred compounds when n is 1 to 15 include compounds represented by the following formula (1-3) or (1-4).
〔式中、R1及びR2は前記と同じ意味を示す。mは1〜15の数を示し、Tは、−OR2又は−R1を示す。〕
一般式(1)で表される化合物は、特許文献1や特許文献4などに記載されている方法で入手することができる。
[Wherein, R 1 and R 2 have the same meaning as described above. m represents a number of 1 to 15, T represents the -OR 2 or -R 1. ]
The compound represented by the general formula (1) can be obtained by the methods described in Patent Document 1, Patent Document 4, and the like.
[(b1)成分及びその他の香料成分]
本発明の(b1)成分はlogPowが3.0以上、5.0以下の香料である。(b1)成分は一般的には香り立ちに優れ、素材数が多くあることから、さまざまな香りを繊維製品に付与できるが、繊維製品処理時に繊維製品に吸着し難く、これら香料成分の吸着性を向上させることが重要である。本発明は(b1)成分の吸着性を向上させる技術として特に優れるものである。
[(B1) component and other perfume ingredients]
The component (b1) of the present invention is a fragrance having a log Pow of 3.0 or more and 5.0 or less. The component (b1) is generally excellent in fragrance and has a large number of materials, so that various fragrances can be imparted to the fiber product, but it is difficult to adsorb to the fiber product during the fiber product treatment, and the absorptivity of these fragrance components It is important to improve. The present invention is particularly excellent as a technique for improving the adsorptivity of the component (b1).
ここでlogPowとは、化学物質の1−オクタノール/水分配係数で、f値法(疎水性フラグメント定数法)により計算で求められた値をいう。具体的には、化合物の化学構造を、その構成要素に分解し、各フラグメントの有する疎水性フラグメント定数(f値)を積算して求めることができ、CLOGP3 Reference Manual Daylight Software 4.34, Albert Leo, David Weininger, Version 1, March 1994を参考にすることができる。 Here, logPow is a 1-octanol / water partition coefficient of a chemical substance, which is a value obtained by calculation by the f-value method (hydrophobic fragment constant method). Specifically, the chemical structure of a compound can be determined by decomposing the chemical structure into its constituent components and integrating the hydrophobic fragment constants (f values) of each fragment. CLOGP3 Reference Manual Daylight Software 4.34, Albert Leo, David You can refer to Weininger, Version 1, March 1994.
(b1)成分としては、i)α−ピネン(4.18)、β−ピネン(4.18)、カンフェン(4.18)、リモネン(4.35)、テルピノーレン(4.35)、ミルセン(4.33)、p−サイメン(4.07)から選ばれる炭化水素系香料、ii)サンダルマイソールコア(3.9)、サンタロール(3.9)、l−メントール(3.2)、シトロネロール(3.25)、ジヒドロミルセノール(3.03)、エチルリナルール(3.08)、ムゴール(3.03)、ネロリドール(4.58)から選ばれるアルコール系香料、iii)アルデヒドC−111(4.05)、グリーナール(3.13)、マンダリンアルデヒド(4.99)、シトラール(3.12)、シトロネラール(3.26)、アミルシンナミックアルデヒド(4.32)、ヘキシルシンナミックアルデヒド(4.85)、リリアール(3.86)、ジヒドロジャスモン(3.13)、l−カルボン、イオノンα(3.71)、メチルイオノンα(4.24)、メチルイオノンG(4.02)から選ばれるアルデヒド、ケトン系香料、iv)ヘプチルアセテート(3.36)、シトロネリルアセテート(4.20)、ゲラニルアセテート(3.72)、リナリルアセテート(3.50)、エチルシンナメート(3.0)、ベンジルサリシレート(4.2)、イソブチルサリシレート(3.92)から選ばれるエステル系香料、v)チモール(3.40)、バニトロープ(3.11)から選ばれるフェノール系香料、vi)セドロキサイド(4.58)、シトロネリルエチルエーテル(4.36)、アネトール(3.31)、ネロリンヤラヤラ(3.24)、エステラゴール(3.1)、メチルイソオイゲノール(3.0)から選ばれるエーテル系香料を挙げることができる。なお、( )内はlogPow値である。 As component (b1), i) α-pinene (4.18), β-pinene (4.18), camphene (4.18), limonene (4.35), terpinolene (4.35), myrcene (4.33), p-cymene (4.07) Selected hydrocarbon fragrances, ii) Sandal Mysore Core (3.9), Santalol (3.9), l-Menthol (3.2), Citronellol (3.25), Dihydromyrcenol (3.03), Ethyllinarool (3.08), Mugor (3.03), alcoholic fragrance selected from nerolidol (4.58), iii) aldehyde C-111 (4.05), greenal (3.13), mandarin aldehyde (4.99), citral (3.12), citronellal (3.26), amylcinnamic Aldehyde (4.32), Hexylcinnamic aldehyde (4.85), Lilyal (3.86), Dihydrojasmon (3.13), l-carvone, Ionone Aldehyde selected from (3.71), methylionone α (4.24), methylionone G (4.02), ketone-based fragrance, iv) heptyl acetate (3.36), citronellyl acetate (4.20), geranyl acetate (3.72), linalyl acetate (3.50) , Ester fragrance selected from ethyl cinnamate (3.0), benzyl salicylate (4.2), isobutyl salicylate (3.92), v) phenolic fragrance selected from thymol (3.40) and banitrop (3.11), vi) cedroxide (4.58) And citronellyl ethyl ether (4.36), anethole (3.31), neroline yarayara (3.24), estellagol (3.1), and methyl isoeugenol (3.0). The values in parentheses are logPow values.
特に(b1)成分として、リモネン(4.35)、エストラゴール(3.1)、l−メントール(3.2)、シトロネロール(3.25)、シトラール(3.12)、シトロネラール(3.26)、イソブチルサリシレート(3.8)、アミルシンナミックアルデヒド(4.32)、ジヒドロジャスモン(3.13)、イオノンα(3.71)、メチルイオノンα(4.24)、メチルイオノンG(4.02)、ベンジルサリシレート(4.2)が香り立ちがよいため、また爽やかな香りを繊維製品に付与できるため好適である。 In particular, as component (b1), limonene (4.35), estragole (3.1), l-menthol (3.2), citronellol (3.25), citral (3.12), citronellal (3.26), isobutyl salicylate (3.8), amylcinnamic aldehyde (4.32), Dihydrojasmon (3.13), Ionone α (3.71), Methyl ionone α (4.24), Methyl ionone G (4.02), Benzyl salicylate (4.2) are fragrant and can give a fresh fragrance to textiles. Therefore, it is preferable.
本発明では、(b1)成分以外の香料成分を含有する香料組成物として使用することが出来る。比較的親油性の高いlogPowが5を超える香料成分〔以下(b2)成分という〕としては、β−カリオフィレン(6.45)、トリメチルウンデセナール(5.16)、ヘキシルサリシレート(5.09)、アンブロキサン(5.27)、テンタローム(5.7)、パールライド(5.7)等を挙げることができる。 In this invention, it can be used as a fragrance composition containing a fragrance component other than the component (b1). Perfume ingredients [hereinafter referred to as component (b2)] having a relatively high lipophilic log Pow of more than 5 include β-caryophyllene (6.45), trimethylundecenal (5.16), hexyl salicylate (5.09), ambroxan (5.27) , Tentarom (5.7), pearl ride (5.7) and the like.
さらに、親水性の高いlogPowが3未満の香料成分〔以下(b3)という〕としては、テルピネオール(2.6)、ゲラニオール(2.77)、リナロール(2.55)、ミルセノール(2.61)、ネロール(2.77)、シス−ジャスモン(2.64)、フェニルエチルアセテート(2.13)、アリルアミルグリコレート(2.51)、リファローム(2.26)、シス−3−ヘキシルアセテート(2.34)、スチラリルアセテート(2.27)、o−t−ブチルシクロヘキサノン(2.27)、p−t−ブチルシクロヘキサノン(2.27)、アセチルオイゲノール(2.83)、シンナミルアセテート(2.35)、オイゲノール(2.40)、イソオイゲノール(2.58)、モスシンス(2.94)、アニソール(2.06)、メチルオイゲノール(2.78)、クマリン(1.4)等を挙げることができる。 Further, as perfume ingredients having a high log Pow of less than 3 (hereinafter referred to as (b3)), terpineol (2.6), geraniol (2.77), linalool (2.55), myrsenol (2.61), nerol (2.77), cis- Jasmon (2.64), phenylethyl acetate (2.13), allyl amyl glycolate (2.51), rifarom (2.26), cis-3-hexyl acetate (2.34), styryl acetate (2.27), ot-butylcyclohexanone (2.27) ), Pt-butylcyclohexanone (2.27), acetyl eugenol (2.83), cinnamyl acetate (2.35), eugenol (2.40), isoeugenol (2.58), mussynth (2.94), anisole (2.06), methyl eugenol (2.78) ) And coumarin (1.4).
本発明の(b1)成分を含有する香料としては、少なくとも(b1)成分と(b2)成分を含有するものが好ましく、(b2)成分の香りと、(b1)成分の香りが相まって、種々な香りを繊維製品に残香させることが可能となる。全香料中の香料成分(b1)の含有量は、30質量%以上が好ましく、50質量%以上が更に好ましい。また、全香料中の(b2)成分の含有量は、10〜50質量%が好ましく、20〜30質量%がより好ましく、残りが(b3)成分である香料が最も好適である。(b1)成分と(b1)+(b2)成分の質量比は、10/90〜100/0が好ましく、20/80〜100/0がより好ましく、30/70〜100/0が更に好ましい。以下、(b1)、(b2)および(b3)成分の混合物を(b)成分という。 As the fragrance containing the component (b1) of the present invention, those containing at least the component (b1) and the component (b2) are preferable, and the scent of the component (b2) and the scent of the component (b1) It is possible to leave the scent on the textile product. 30 mass% or more is preferable and, as for content of the fragrance | flavor component (b1) in all the fragrance | flavors, 50 mass% or more is still more preferable. Moreover, 10-50 mass% is preferable, as for content of (b2) component in all the fragrance | flavors, 20-30 mass% is more preferable, and the fragrance | flavor whose remainder is (b3) component is the most suitable. The mass ratio of the component (b1) and the component (b1) + (b2) is preferably 10/90 to 100/0, more preferably 20/80 to 100/0, and still more preferably 30/70 to 100/0. Hereinafter, the mixture of the components (b1), (b2) and (b3) is referred to as the component (b).
[繊維製品処理剤組成物]
本発明の繊維製品処理剤組成物は、(b1)成分の繊維製品への吸着性を向上させ、香り立ちに優れ、バリエーションの広い香りを持続させる観点から、(a)成分と(b1)成分とを、(a)成分/(b1)成分=98/2〜20/80の質量比で含有する。(a)成分/(b1)成分の質量比は、90/10〜30/70が好ましく、85/15〜40/60がより好ましい。
[Fiber product treatment composition]
From the viewpoint of improving the adsorptivity of the component (b1) to the fiber product, excellent fragrance formation, and maintaining a wide variety of fragrances, the fiber product treating agent composition of the present invention includes the components (a) and (b1). Are contained in a mass ratio of (a) component / (b1) component = 98/2 to 20/80. 90 / 10-30 / 70 is preferable and, as for mass ratio of (a) component / (b1) component, 85 / 15-40 / 60 is more preferable.
本発明の繊維製品処理剤組成物は香料の希釈剤や保留剤を含有することが出来る。希釈剤、保留剤の好適な例としては、ジプロピレングリコール、パルミチン酸イソプロピルエステル、ジエチルフタレート、ペンジルベンゾエート、流動パラフィン,イソパラフィン、油脂等を挙げることができる。(b)成分と保留剤の合計に対する保留剤の割合は0〜20質量%が好ましい。 The textile product treating agent composition of the present invention can contain a fragrance diluent and a retention agent. Preferable examples of the diluent and the retentive agent include dipropylene glycol, palmitic acid isopropyl ester, diethyl phthalate, pendyl benzoate, liquid paraffin, isoparaffin, and oil. (B) As for the ratio of the retention agent with respect to the sum total of a component and a retention agent, 0-20 mass% is preferable.
本発明の繊維製品処理剤組成物は、柔軟剤、賦香剤、糊剤、スタイルケア剤等に香りのコントロールを目的として応用することが出来る。 The textile product treating agent composition of the present invention can be applied to softeners, flavoring agents, glues, style care agents and the like for the purpose of controlling the scent.
本発明の繊維製品処理剤組成物は、一般家庭における洗濯工程のすすぎの段階で濯ぎ水に添加される繊維製品処理剤として用いられるのが好ましく、具体的には柔軟剤組成物に応用することが好ましい。 The textile product treating agent composition of the present invention is preferably used as a textile product treating agent to be added to rinsing water at the stage of rinsing in a general household laundry process. Specifically, it is applied to a softener composition. Is preferred.
本発明を柔軟剤組成物に応用する場合には、(c)成分として柔軟基剤を含有することが好ましい。柔軟基剤としては、炭素数10〜22の炭化水素基を1〜3個有する3級アミン又はその酸塩もしくはその4級化物〔以下(c1)成分という〕、及び(a)成分以外のシリコーン化合物〔以下(c2)成分という〕から選ばれる化合物が好ましい。 When applying this invention to a softening agent composition, it is preferable to contain a softening base as (c) component. As the soft base, a tertiary amine having 1 to 3 hydrocarbon groups having 10 to 22 carbon atoms, or an acid salt thereof or a quaternized product thereof (hereinafter referred to as (c1) component), and silicones other than (a) component A compound selected from compounds [hereinafter referred to as component (c2)] is preferred.
(c1)成分としては、エステル結合又はアミド結合を有していても良い炭素数12〜22の炭化水素基を1〜3個と残りが炭素数1〜3のアルキル基及び/又はヒドロキシアルキル基である3級アミン又はその酸塩もしくはその4級化物が好ましい。(c1)成分の具体例としては、下記(c11)〜(c13)の化合物を挙げることができる。 As the component (c1), 1 to 3 hydrocarbon groups having 12 to 22 carbon atoms which may have an ester bond or an amide bond, and the remaining alkyl groups and / or hydroxyalkyl groups having 1 to 3 carbon atoms. A tertiary amine or an acid salt thereof or a quaternized product thereof is preferred. Specific examples of the component (c1) include the following compounds (c11) to (c13).
(c11)炭素数12〜22、好ましくは炭素数14〜20、より好ましくは炭素数16〜18のアルキル基又はアルケニル基を2個と残りが炭素数1〜3のアルキル基又はヒドロキシアルキル基である4級アンモニウム塩(塩としてはクロル塩、炭素数1〜12の脂肪酸塩、炭素数1〜3のアルキル硫酸エステル塩)
(c12)アルカノイル基又はアルケノイル基の炭素数11〜21、好ましくは13〜19、より好ましくは15から17であるアルカノイル(アルケノイル)オキシエチル基、もしくはアルカノイル(アルケノイル)アミノプロピル基を1又は2個と残りが炭素数1〜3のアルキル基又はヒドロキシアルキル基である3級アミン又はその酸塩(酸塩としては塩酸塩、硫酸塩、リン酸塩、炭素数1〜12の脂肪酸塩)
(c13)トリエタノールアミンと、炭素数12〜22、好ましくは14〜20、特に好ましくは16〜18の脂肪酸、又は脂肪酸低級アルキルエステル、脂肪酸クロリドから選ばれる脂肪酸誘導体、好ましくは脂肪酸とのエステル化反応生成物をアルキル化剤、好ましくはメチルクロリド、ジメチル硫酸又はジエチル硫酸により4級化した4級アンモニウム塩(塩としてはクロル塩、炭素数1〜12の脂肪酸塩、炭素数1〜3のアルキル硫酸エステル塩)。
(C11) Two alkyl groups or alkenyl groups having 12 to 22 carbon atoms, preferably 14 to 20 carbon atoms, more preferably 16 to 18 carbon atoms, and the remaining alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms. A certain quaternary ammonium salt (as a salt, a chlor salt, a C1-C12 fatty acid salt, a C1-C3 alkyl sulfate ester salt)
(C12) 1 or 2 alkanoyl (alkenoyl) oxyethyl group or alkanoyl (alkenoyl) aminopropyl group having 11 to 21, preferably 13 to 19, more preferably 15 to 17, carbon atoms of the alkanoyl group or alkenoyl group, and Tertiary amine or its acid salt whose remaining is an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group (acid salts such as hydrochloride, sulfate, phosphate, fatty acid salt having 1 to 12 carbon atoms)
(C13) Esterification of triethanolamine with a fatty acid derivative selected from fatty acids having 12 to 22 carbon atoms, preferably 14 to 20 carbon atoms, particularly preferably 16 to 18 carbon atoms, or fatty acid lower alkyl esters, and fatty acid chlorides, preferably fatty acids. A quaternary ammonium salt obtained by quaternizing the reaction product with an alkylating agent, preferably methyl chloride, dimethyl sulfate or diethyl sulfate (a chlor salt as a salt, a fatty acid salt having 1 to 12 carbon atoms, an alkyl having 1 to 3 carbon atoms) Sulfate ester).
(c2)成分としては、水不溶性のシリコーン化合物が好適である。ここで水不溶性化合物とは20℃のイオン交換水1Lに溶解する量が1g以下の化合物である。具体的にはジメチルポリシロキサン、4級アンモニウム変性ジメチルポリシロキサン、アミノ変性ジメチルポリシロキサン、アミド変性ジメチルポリシロキサン、エポキシ変性ジメチルポリシロキサン、カルボキシ変性ジメチルポリシロキサン、ポリオキシアルキレン変性ジメチルポリシロキサン、フッ素変性ジメチルポリシロキサン等のシリコーン化合物が挙げられる。 As the component (c2), a water-insoluble silicone compound is suitable. Here, the water-insoluble compound is a compound having an amount of 1 g or less dissolved in 1 L of ion-exchanged water at 20 ° C. Specifically, dimethylpolysiloxane, quaternary ammonium modified dimethylpolysiloxane, amino modified dimethylpolysiloxane, amide modified dimethylpolysiloxane, epoxy modified dimethylpolysiloxane, carboxy modified dimethylpolysiloxane, polyoxyalkylene modified dimethylpolysiloxane, fluorine modified Examples include silicone compounds such as dimethylpolysiloxane.
本発明では特に分子量千〜100万、好ましくは3千〜100万、特に好ましくは5千〜100万、25℃における粘度が2〜100万mm2/s、好ましくは500〜100万mm2/s、特に好ましくは1千〜100万mm2/sのジメチルポリシロキサン、アミノ変性ジメチルポリシロキサン、アミド変性ジメチルポリシロキサン、ポリオキシアルキレン(ポリオキシエチレン及び/又はポリオキシプロピレン、好ましくはポリオキシエチレン)変性ジメチルポリシロキサンから選ばれる1種以上が好ましい。アミノ変性ジメチルポリシロキサンのアミノ当量(アミノ当量とは窒素原子1個当たりの分子量)は、1,500〜40,000g/molが好ましく、2,500〜20,000g/molがより好ましく、3,000〜10,000g/molが更に好ましい。 In the present invention, the molecular weight is 1,000 to 1,000,000, preferably 3,000 to 1,000,000, particularly preferably 5,000 to 1,000,000, and the viscosity at 25 ° C. is 2 to 1,000,000 mm 2 / s, preferably 500 to 1,000,000 mm 2 /. s, particularly preferably 1,000 to 1,000,000 mm 2 / s dimethylpolysiloxane, amino-modified dimethylpolysiloxane, amide-modified dimethylpolysiloxane, polyoxyalkylene (polyoxyethylene and / or polyoxypropylene, preferably polyoxyethylene 1) One or more selected from modified dimethylpolysiloxane is preferred. The amino equivalent of amino-modified dimethylpolysiloxane (amino equivalent is the molecular weight per nitrogen atom) is preferably 1,500 to 40,000 g / mol, more preferably 2,500 to 20,000 g / mol, 000 to 10,000 g / mol is more preferable.
本発明では特に(c1)成分と(c2)成分を併用することが好ましく(c1)成分/(c2)成分を質量比で60/1〜1/50、好ましくは60/1〜1/20、更に好ましくは50/1〜1/10で含有することが好適である。 In the present invention, it is particularly preferable to use the component (c1) and the component (c2) in combination, and the component (c1) / (c2) component is 60/1 to 1/50, preferably 60/1 to 1/20 in mass ratio. More preferably, it is contained at 50/1 to 1/10.
本発明の(a)成分、(b)成分、及び任意ではあるが柔軟剤組成物に応用する場合には必要な成分である(c)成分は水に対して不溶な化合物であるため、水性の組成物の形態として用いる場合には、組成物中に安定に溶解、分散、乳化させる目的から非イオン界面活性剤〔以下(d)成分という〕を含有することが好適である。 Component (a), component (b), and optional component (c), which is a necessary component when applied to a softener composition, is a compound that is insoluble in water. When used in the form of the composition, it is preferable to contain a nonionic surfactant [hereinafter referred to as component (d)] for the purpose of stably dissolving, dispersing, and emulsifying the composition.
(d)成分としては、炭素数8〜20のアルキル基又はアルケニル基を有するポリオキシエチレンアルキルエーテルが好ましく、下記一般式(2)で表される非イオン界面活性剤がより好ましい。 (D) As a component, the polyoxyethylene alkyl ether which has a C8-C20 alkyl group or an alkenyl group is preferable, and the nonionic surfactant represented by following General formula (2) is more preferable.
R2a−A−〔(R2bO)p−R2c〕q (2)
〔式中、R2aは、炭素数8〜18、好ましくは炭素数10〜16のアルキル基又はアルケニル基であり、R2bは、炭素数2又は3のアルキレン基、好ましくはエチレン基であり、R2cは、炭素数1〜3のアルキル基又は水素原子であり、pは2〜100、好ましくは5〜80、より好ましくは5〜60、更に好ましくは10〜60の数であり、Aは−O−、−COO−,−CON−又は−N−であり、Aが−O−又は−COO−の場合qは1であり、Aが−CON−又は−N−の場合qは1又は2である。〕
一般式(2)の化合物の具体例としては、以下の式(2−1)〜(2−3)で表される化合物を挙げることができる。
R 2a -A - [(R 2b O) p -R 2c] q (2)
[Wherein R 2a is an alkyl group or alkenyl group having 8 to 18 carbon atoms, preferably 10 to 16 carbon atoms, R 2b is an alkylene group having 2 or 3 carbon atoms, preferably an ethylene group, R 2c is an alkyl group having 1 to 3 carbon atoms or a hydrogen atom, p is 2 to 100, preferably 5 to 80, more preferably 5 to 60, still more preferably 10 to 60, and A is -O-, -COO-, -CON- or -N-, q is 1 when A is -O- or -COO-, and q is 1 when A is -CON- or -N-. 2. ]
Specific examples of the compound of the general formula (2) include compounds represented by the following formulas (2-1) to (2-3).
R2a−O−(C2H4O)r−H (2−1)
〔式中、R2aは前記の意味を示す。rは8〜100、好ましくは10〜60の数である。〕
R2a−O−(C2H4O)s−(C3H6O)t−H (2−2)
〔式中、R2aは前記の意味を示す。s及びtはそれぞれ独立に2〜40、好ましくは5〜40の数であり、(C2H4O)と(C3H6O)はランダム又はブロック付加体であってもよい。〕
R 2a -O- (C 2 H 4 O) r -H (2-1)
[Wherein R 2a has the above-mentioned meaning. r is a number of 8 to 100, preferably 10 to 60. ]
R 2a -O- (C 2 H 4 O) s - (C 3 H 6 O) t -H (2-2)
[Wherein R 2a has the above-mentioned meaning. s and t are each independently a number of 2 to 40, preferably 5 to 40, and (C 2 H 4 O) and (C 3 H 6 O) may be random or block adducts. ]
〔式中、R2aは前記の意味を示す。Aは−N<又は−CON<であり、u及びvはそれぞれ独立に0〜40の数であり、u+vは5〜60、好ましくは5〜40の数である。R2d、R2eはそれぞれ独立に水素原子又は炭素数1〜3のアルキル基である。〕
本発明の繊維製品処理剤組成物を柔軟剤組成物に応用する場合には柔軟効果を向上させる目的から脂肪酸〔以下(e1)成分という〕を含有することが好適であり、具体的にはラウリン酸、ミリスチン酸、パルミチン酸、パルミトレイン酸、ステアリン酸、オレイン酸、リノール酸、エルカ酸、ベヘニン酸等の炭素数12〜22の飽和又は不飽和脂肪酸が好ましく、特にパルミチン酸、ステアリン酸、オレイン酸、リノール酸が好適である。
[Wherein R 2a has the above-mentioned meaning. A is -N <or -CON <, u and v are each independently a number of 0 to 40, and u + v is a number of 5 to 60, preferably 5 to 40. R 2d and R 2e are each independently a hydrogen atom or an alkyl group having 1 to 3 carbon atoms. ]
When the textile product treating agent composition of the present invention is applied to a softener composition, it is preferable to contain a fatty acid [hereinafter referred to as (e1) component] for the purpose of improving the softening effect. Saturated or unsaturated fatty acids having 12 to 22 carbon atoms such as acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, oleic acid, linoleic acid, erucic acid, behenic acid, etc. are preferred, especially palmitic acid, stearic acid, oleic acid Linoleic acid is preferred.
本発明の組成物は、貯蔵安定性を向上させる目的から必要に応じて(f)成分として無機塩を含有することができる。無機塩としては、塩化ナトリウム、塩化カルシウム、及び塩化マグネシウムが貯蔵安定性の点から好ましい。 The composition of the present invention can contain an inorganic salt as the component (f) as needed for the purpose of improving storage stability. As the inorganic salt, sodium chloride, calcium chloride, and magnesium chloride are preferable from the viewpoint of storage stability.
本発明の組成物は、貯蔵安定性を改善する目的で(g)成分として炭素数8〜22の飽和又は不飽和脂肪酸と多価アルコールとのエステル化合物を含有してもよい。配合できる(g)成分としては、トリグリセライド、ジグリセライド、モノグリセライド、ペンタエリスリトールのモノ、ジ、トリ脂肪酸エステル、ソルビタン脂肪酸エステルを挙げることができる。 The composition of the present invention may contain an ester compound of a saturated or unsaturated fatty acid having 8 to 22 carbon atoms and a polyhydric alcohol as the component (g) for the purpose of improving storage stability. Examples of the component (g) that can be blended include triglycerides, diglycerides, monoglycerides, mono-, di-, tri-fatty acid esters, and sorbitan fatty acid esters of pentaerythritol.
本発明の組成物は、必要に応じて(h)成分として溶剤を含有してもよい。溶剤としては、エタノール、イソプロパノール、グリセリン、エチレングリコール、プロピレングリコールから選ばれる溶剤が好ましく、特にエタノールが匂いの点から好ましい。 The composition of this invention may contain a solvent as (h) component as needed. As the solvent, a solvent selected from ethanol, isopropanol, glycerin, ethylene glycol, and propylene glycol is preferable, and ethanol is particularly preferable from the point of smell.
本発明の繊維製品処理剤組成物を柔軟剤組成物に応用することができる。この場合には、組成物中の(a)成分の含有量は、0.1〜6.0質量%が好ましく、0.2〜3.0質量%がより好ましく、0.3〜1.0質量%が更に好ましい。また、組成物中の(b1)成分の含有量は、0.02〜1.5質量%が好ましく、0.05〜1質量%がより好ましく、0.08〜0.8質量%が更に好ましい。また、組成物中の(b)成分の含有量は、0.1〜1.5質量%が好ましく、0.2〜1質量%がより好ましく、0.3〜0.8質量%が更に好ましい。また、(a)成分と(b)成分の割合は、(a)成分/(b)成分の質量比で20/80〜90/10が好ましく、30/70〜90/10がより好ましく、40/60〜90/10が更に好ましい。さらに組成物中の(c1)成分の含有量は、3〜30質量%がより好ましく、3〜25質量%がより好ましく、3〜20質量%が更に好ましい。また、組成物中の(c2)成分の含有量は、0.3〜15質量%が好ましく、0.3〜10質量%がより好ましく、0.5〜8質量%が更に好ましい。組成物中の(d)成分の含有量は、0.1〜10質量%が好ましく、0.2〜9質量%がより好ましく、0.5〜8質量%が更に好ましい。保存安定性の観点から(a)成分と(d)成分の割合は、(a)成分/(d)成分の質量比で3/97〜90/10が好ましく、5/95〜50/50がより好ましく、10/90〜30/70が更に好ましい。また、組成物中の(e)成分の含有量は、0.2〜10質量%が好ましく、0.2〜5質量%がより好ましく、0.3〜4質量%が更に好ましい。組成物中の(f)成分の含有量は、0.0005〜5質量%が好ましく、0.001〜4質量%がより好ましく、0.005〜3質量%が更に好ましい。組成物中の(g)成分の含有量は、0.01〜15質量%が好ましく、0.05〜10質量%がより好ましく、0.1〜5質量%が更に好ましい。組成物中の(h)成分の含有量は、0.2〜25質量%が好ましく、0.3〜10質量%がより好ましく、0.3〜5質量%が更に好ましい。 The textile product treating agent composition of the present invention can be applied to a softener composition. In this case, the content of the component (a) in the composition is preferably 0.1 to 6.0% by mass, more preferably 0.2 to 3.0% by mass, and 0.3 to 1.0. More preferred is mass%. Moreover, 0.02-1.5 mass% is preferable, as for content of (b1) component in a composition, 0.05-1 mass% is more preferable, and 0.08-0.8 mass% is still more preferable. . Moreover, 0.1-1.5 mass% is preferable, as for content of (b) component in a composition, 0.2-1 mass% is more preferable, and 0.3-0.8 mass% is still more preferable. . Further, the ratio of the component (a) to the component (b) is preferably 20/80 to 90/10, more preferably 30/70 to 90/10 in terms of the mass ratio of the component (a) / (b). / 60 to 90/10 is more preferable. Furthermore, 3-30 mass% is more preferable, as for content of (c1) component in a composition, 3-25 mass% is more preferable, and 3-20 mass% is still more preferable. Moreover, 0.3-15 mass% is preferable, as for content of (c2) component in a composition, 0.3-10 mass% is more preferable, and 0.5-8 mass% is still more preferable. The content of the component (d) in the composition is preferably 0.1 to 10% by mass, more preferably 0.2 to 9% by mass, and still more preferably 0.5 to 8% by mass. From the viewpoint of storage stability, the ratio of the component (a) to the component (d) is preferably 3/97 to 90/10 in terms of the mass ratio of the component (a) / (d), and preferably 5/95 to 50/50. More preferred is 10/90 to 30/70. Moreover, 0.2-10 mass% is preferable, as for content of (e) component in a composition, 0.2-5 mass% is more preferable, and 0.3-4 mass% is still more preferable. The content of the component (f) in the composition is preferably 0.0005 to 5% by mass, more preferably 0.001 to 4% by mass, and still more preferably 0.005 to 3% by mass. 0.01-15 mass% is preferable, as for content of the (g) component in a composition, 0.05-10 mass% is more preferable, and 0.1-5 mass% is still more preferable. The content of the component (h) in the composition is preferably 0.2 to 25% by mass, more preferably 0.3 to 10% by mass, and still more preferably 0.3 to 5% by mass.
[(b1)成分の繊維製品への吸着を促進させる方法]
本発明における(b1)成分の繊維製品への吸着を促進させる方法は、本発明の繊維製品処理剤組成物を、水を媒体として繊維製品に接触させる方法である。
[Method for Promoting Adsorption of (b1) Component to Textile Product]
The method for promoting the adsorption of the component (b1) to the fiber product in the present invention is a method of bringing the fiber product treating agent composition of the present invention into contact with the fiber product using water as a medium.
本発明の繊維製品処理剤組成物を繊維製品に接触させる工程としては、一般家庭の洗濯工程のすすぎの段階が好ましく、繊維製品1kgに対して、(a)成分及び(b1)成分の合計が0.01〜0.5g、更に0.02〜0.3g、特に0.03〜0.2gになるように濯ぎ水に添加することが好ましい。 As the process of bringing the textile product treating agent composition of the present invention into contact with the textile product, a rinsing stage of a general household washing process is preferable, and the total of the (a) component and the (b1) ingredient is 1 kg of the textile product. It is preferable to add to rinse water so that it may become 0.01-0.5g, 0.02-0.3g, especially 0.03-0.2g.
一般に(a)成分、及び(b1)成分を含む(b)成分は水に不溶の化合物であるため、濯ぎ水に添加する場合には、(a)成分及び(b)成分を濯ぎ水に均一に溶解、分散、乳化させることが好適であり、そのためには(d)成分が重要な役割を果たす。本発明では(d)成分を(a)成分と(b)成分の合計に対して好ましくは1/20〜20/1の質量比、より好ましくは1/15〜15/1の質量比、特に好ましくは1/10〜10/1の質量比で濯ぎ水に共存させることが好ましい。洗濯工程のすすぎの段階で繊維製品に接触させた後は通常の脱水/乾燥を行う。 In general, the component (a) and the component (b1) including the component (b1) are insoluble in water. Therefore, when added to the rinsing water, the components (a) and (b) are uniform in the rinsing water. It is preferable to dissolve, disperse and emulsify in (4), and the component (d) plays an important role. In the present invention, the component (d) is preferably a mass ratio of 1/20 to 20/1, more preferably a mass ratio of 1/15 to 15/1, with respect to the sum of the components (a) and (b). It is preferable to coexist in the rinsing water at a mass ratio of 1/10 to 10/1. Ordinary dehydration / drying is performed after contact with the textile product in the rinsing stage of the washing process.
これ以外の方法としては、一般家庭の洗濯において洗剤と共に添加する方法、スプレーにより繊維製品に直接噴霧する方法、ローラー等で塗布する方法等が挙げられる。 Examples of methods other than this include a method of adding together with a detergent in washing at home, a method of spraying directly on a textile product by spraying, a method of applying with a roller, and the like.
実施例及び比較例で用いた各配合成分をまとめて以下に示す。 Each compounding component used in Examples and Comparative Examples is shown below.
(a)成分
(a−1):下記合成例1で得られたオクチルケイ酸トリス(2−フェニルエチル)エステル
(a−2):下記合成例2で得られたテトラキス(cis−3−ヘキセニルオキシ)シラン
(a−3):下記合成例3で得られたポリ(4−メトキシフェニルメトキシ)シロキサン
(b)成分
(b1−1):エストラゴール(logPow=3.1)
(b1−2):イソブチルサリシレート(logPow=3.8)
(b1−3):ベンジルサリシレート(logPow=4.2)
(b2−1):パールライド(logPow=5.7)
(b2−2):テンタローム(logPow=5.7)
(b3−1):クマリン(logPow=1.4)
(b3−2):オイゲノール(logPow=2.4)
(c)成分
(c1−1): N−(3−アミノプロピル)−N−(2−ヒドロキシエチル)−N−メチルアミンと硬化牛脂脂肪酸を1/1.9のモル比で公知の方法に従って脱水縮合させ、反応物中の脂肪酸含量が5質量%になった時点で反応を終了させて得られた反応生成物であり、下記式(3)で表されるアミンを95質量%含有するもの。
(A) Component (a-1): Octylsilicic acid tris (2-phenylethyl) ester obtained in Synthesis Example 1 below (a-2): Tetrakis (cis-3-hexenyl) obtained in Synthesis Example 2 below Oxy) silane (a-3): poly (4-methoxyphenylmethoxy) siloxane obtained in Synthesis Example 3 below (b) Component (b1-1): Estragole (logPow = 3.1)
(B1-2): Isobutyl salicylate (logPow = 3.8)
(B1-3): benzyl salicylate (logPow = 4.2)
(B2-1): Pearl Ride (logPow = 5.7)
(B2-2): Tentarom (logPow = 5.7)
(B3-1): Coumarin (logPow = 1.4)
(B3-2): Eugenol (logPow = 2.4)
(C) Component (c1-1): N- (3-aminopropyl) -N- (2-hydroxyethyl) -N-methylamine and hardened tallow fatty acid in a molar ratio of 1 / 1.9 according to a known method. A reaction product obtained by dehydrating condensation and terminating the reaction when the fatty acid content in the reaction product reaches 5% by mass, containing 95% by mass of an amine represented by the following formula (3) .
(式中、Rは硬化牛脂脂肪酸からカルボキシル基を除いた残基を示す。)
その他の成分
(d−1):炭素数12の飽和アルコールにエチレンオキシドを平均20モル付加させたもの
(f−1):塩化カルシウム
(g−1):硬化牛脂脂肪酸1.7モルとグリセリン1モルの脱水縮合物(脱水縮合物中の未反応脂肪酸含有量は3質量%)
(h−1):エタノール
合成例1:オクチルケイ酸トリス(2−フェニルエチル)エステル[トリス(2−フェニルエチルオキシ)オクチルシラン]の合成
300mLの四つ口フラスコにオクチルトリエトキシシラン83.01g(0.30mol)、フェニルエチルアルコール127.76g(0.83mol)、2.8%ナトリウムメトキシドメタノール溶液0.857mLを入れ、窒素気流下エタノールを留出させながら110〜115℃で2.5時間攪拌した。2.5時間後、槽内の圧力を徐々に8kPaまで下げ、エタノールを留出させながら110〜119℃でさらに3時間攪拌した。3時間後、冷却、減圧を解除した後、濾過を行い、オクチルケイ酸トリス(2−フェニルエチル)エステルを含む173.61gの淡黄色油状物を得た。
(In the formula, R represents a residue obtained by removing a carboxyl group from hardened beef tallow fatty acid.)
Other components (d-1): 20 alcohols added with an average of 20 moles of saturated alcohol having 12 carbon atoms (f-1): calcium chloride (g-1): 1.7 moles of cured beef tallow fatty acid and 1 mole of glycerin Dehydration condensate (content of unreacted fatty acid in the dehydration condensate is 3% by mass)
(H-1): Ethanol Synthesis Example 1: Synthesis of octylsilicic acid tris (2-phenylethyl) ester [tris (2-phenylethyloxy) octylsilane] 83.01 g of octyltriethoxysilane in a 300 mL four-necked flask (0.30 mol), 127.76 g (0.83 mol) of phenylethyl alcohol, 0.857 mL of a 2.8% sodium methoxide methanol solution, and 2.5 at 110 to 115 ° C. while distilling ethanol under a nitrogen stream. Stir for hours. After 2.5 hours, the pressure in the tank was gradually lowered to 8 kPa, and the mixture was further stirred at 110 to 119 ° C. for 3 hours while distilling ethanol. Three hours later, after cooling and releasing the reduced pressure, filtration was carried out to obtain 173.61 g of a pale yellow oily substance containing octylsilicic acid tris (2-phenylethyl) ester.
合成例2:ケイ酸テトラキス(cis−3−ヘキセニル)エステル[テトラキス(cis−3−ヘキセニルオキシ)シラン]の合成
200mLの四つ口フラスコにテトラエトキシシラン35.45g(0.17mol)、cis−3−ヘキセノール64.74g(0.65mol)、2.8%ナトリウムメトキシドメタノール溶液1.34mLを入れ、窒素気流下エタノールを留出させながら118〜120℃で約2時間攪拌した。2時間後、槽内の圧力を徐々に8kPaまで下げ、エタノールを留出させながら112〜119℃でさらに3時間攪拌した。3時間後、冷却、減圧を解除した後、濾過を行い、テトラキス(cis−3−ヘキセニルオキシ)シランを含む66.17gの薄茶色油状物を得た。
Synthesis Example 2: Synthesis of tetrakis (cis-3-hexenyl) silicate [tetrakis (cis-3-hexenyloxy) silane] In a 200 mL four-necked flask, 35.45 g (0.17 mol) of tetraethoxysilane, cis- 3-Hexenol 64.74 g (0.65 mol), 2.8% sodium methoxide methanol solution 1.34 mL was added, and the mixture was stirred at 118 to 120 ° C. for about 2 hours while distilling ethanol under a nitrogen stream. After 2 hours, the pressure in the tank was gradually lowered to 8 kPa, and the mixture was further stirred at 112 to 119 ° C. for 3 hours while distilling ethanol. Three hours later, after cooling and releasing the reduced pressure, filtration was performed to obtain 66.17 g of a light brown oily substance containing tetrakis (cis-3-hexenyloxy) silane.
合成例3:ポリ(4−メトキシフェニルメトキシ)シロキサンの合成
100mLの四つ口フラスコにテトラエトキシシラン72.96gと水酸化カリウム0.24g、イオン交換水0.4mLを入れ、窒素気流下120〜125℃、33kPa〜101kPa(常圧)で約37時間反応を行った。この間イオン交換水を0.4mL追加した。反応後、33kPaで更に2時間反応させた後、冷却、濾過を行い、67.29gのエトキシシランの縮合物を淡黄色液体として得た。
Synthesis Example 3: Synthesis of poly (4-methoxyphenylmethoxy) siloxane 72.96 g of tetraethoxysilane, 0.24 g of potassium hydroxide and 0.4 mL of ion-exchanged water were placed in a 100 mL four-necked flask, and a nitrogen flow of 120- The reaction was performed at 125 ° C. and 33 kPa to 101 kPa (normal pressure) for about 37 hours. During this time, 0.4 mL of ion-exchanged water was added. After the reaction, the reaction was further continued at 33 kPa for 2 hours, followed by cooling and filtration to obtain 67.29 g of an ethoxysilane condensate as a pale yellow liquid.
続いて、100mLの四つ口フラスコに先のテトラエトキシシラン縮合物25.00gと4−メトキシフェニルメタノール56.39g、4.8%水酸化ナトリウム水溶液0.17gを入れ、エタノールを留出させながら95〜119℃でさらに2時間攪拌した。2時間後、槽内の圧力を徐々に8kPaまで下げ、エタノールを留出させながら116〜119℃でさらに3時間攪拌した。3時間後、冷却、減圧を解除した後、濾過を行い、58.83gのポリ(4−メトキシフェニルメトキシ)シロキサンを淡黄色油状物として得た。 Subsequently, 25.00 g of the above tetraethoxysilane condensate and 56.39 g of 4-methoxyphenylmethanol and 0.17 g of 4.8% aqueous sodium hydroxide solution were placed in a 100 mL four-necked flask, and ethanol was distilled off. The mixture was further stirred at 95 to 119 ° C. for 2 hours. After 2 hours, the pressure in the tank was gradually lowered to 8 kPa, and the mixture was further stirred at 116 to 119 ° C. for 3 hours while distilling ethanol. After 3 hours, cooling and decompression were released, followed by filtration to obtain 58.83 g of poly (4-methoxyphenylmethoxy) siloxane as a pale yellow oil.
実施例1〜3及び比較例1〜4
最終の繊維製品処理剤組成物が300gになるように、表1に示す配合成分を表1に示す割合で用い、下記方法により表1に示す組成の繊維製品処理剤組成物1〜4を調製した。
Examples 1-3 and Comparative Examples 1-4
Using the compounding ingredients shown in Table 1 in the proportions shown in Table 1 so that the final textile product treating agent composition is 300 g, the fiber product treating compositions 1 to 4 having the composition shown in Table 1 are prepared by the following method. did.
<繊維製品処理剤組成物の調製法>
一枚の長さが2.5cmのタービン型羽根が3枚ついた攪拌羽根をビーカー底面より1cm上部に設置した、500mLのガラスビーカーに必要量の95質量%イオン交換水を入れ、ウォーターバスで62℃まで昇温した。500rpmで攪拌しながら、融解した(d)成分を添加した。次に(c)成分と、(g)成分及び(h)成分を予め予備混合し、70℃で溶融させた予備混合物を添加した。次に所定のpHにするのに必要な量の35%塩酸水溶液及び/又は48%水酸化ナトリウム水溶液を添加し、5分間攪拌した後、5℃のウォーターバスで30℃まで冷却し、(f)成分を添加し更に5分間混合した。更に、(a)成分および(b)成分を攪拌しながら添加し、最後に再度pHを確認し、必要に応じて35%塩酸水溶液及び/又は48%水酸化ナトリウム水溶液を用いてpHを調整した。表1の組成においては、(c1−1)は、ほぼすべて塩酸塩の状態で組成物に存在する。なお、表1中、(c1−1)の数値はそれ自体(有効分)の配合量である。
<Method for Preparing Textile Treatment Agent Composition>
A 500 mL glass beaker in which a stirring blade with three turbine-type blades each having a length of 2.5 cm is installed 1 cm above the bottom of the beaker is charged with a necessary amount of 95% by mass ion-exchanged water. The temperature was raised to 62 ° C. While stirring at 500 rpm, the melted component (d) was added. Next, the (c) component, the (g) component, and the (h) component were premixed in advance, and a premixed mixture melted at 70 ° C. was added. Next, an amount of 35% hydrochloric acid aqueous solution and / or 48% sodium hydroxide aqueous solution necessary for obtaining a predetermined pH is added, stirred for 5 minutes, and then cooled to 30 ° C. with a 5 ° C. water bath (f ) Ingredients were added and mixed for another 5 minutes. Further, the components (a) and (b) were added with stirring, and finally the pH was confirmed again, and the pH was adjusted using a 35% aqueous hydrochloric acid solution and / or a 48% aqueous sodium hydroxide solution as necessary. . In the composition of Table 1, (c1-1) is almost entirely present in the composition in the form of hydrochloride. In Table 1, the numerical value of (c1-1) is the blending amount of itself (effective amount).
上記方法で得られた繊維製品処理剤組成物を用い、下記方法で繊維製品に処理し、香料吸着率を測定した。結果を表2に示す。 The fiber product treating agent composition obtained by the above method was used to treat the fiber product by the following method, and the perfume adsorption rate was measured. The results are shown in Table 2.
<繊維製品処理剤組成物による処理および香料吸着率の測定方法>
(1) 前処理
あらかじめ、市販の弱アルカリ性洗剤(花王(株)製 アタック)を用いて、木綿タオル24枚を日立全自動洗濯機NW-6CYで5回洗浄を繰り返し、室内乾燥することによって、過分の薬剤を除去した(洗剤濃度0.0667質量%、水道水47L使用、水温20℃、洗浄10分、ため濯ぎ2回)。
(2) 繊維製品への組成物の処理
National 電気バケツN-BK2-Aに、5Lの水道水を注水し、繊維製品処理剤組成物を10g/衣料1.0kgとなるように溶解(処理浴の調製)させ、上述の方法で前処理を行った2枚の木綿タオルを5分間浸漬し、処理した。
<Treatment with textile product treating agent composition and method for measuring perfume adsorption rate>
(1) Pretreatment In advance, using a commercially available weak alkaline detergent (attack made by Kao Corporation), 24 cotton towels were washed 5 times with Hitachi fully automatic washing machine NW-6CY and dried indoors. Excess drug was removed (detergent concentration 0.0667% by weight, using 47 L of tap water, water temperature 20 ° C., washing 10 minutes, twice for rinsing).
(2) Treatment of composition to textile products
Inject 5L of tap water into National Electric Bucket N-BK2-A, dissolve the fiber product treating agent composition to 10g / 1.0kg of clothing (preparation of treatment bath), and pre-treat with the above method The two cotton towels subjected to the above were immersed and treated for 5 minutes.
香料の吸着率は、処理前の処理浴中の香料含有量(x)と処理後の香料含有量(y)の差分〔(x)−(y)〕をタオルに吸着している量として、処理前の香料含有量(x)に対する割合(百分率)、すなわち、〔(x)−(y)〕/(x)×100を香料の吸着率とする。その結果を表2に示す。なお、処理前後の試験用処理液中の香料の含有量は、下記の液体クロマトグラフィー装置を用いて測定した。 The adsorption rate of the fragrance is defined as the amount of the difference between the fragrance content (x) in the treatment bath before the treatment and the fragrance content (y) after the treatment [(x) − (y)] adsorbed on the towel, The ratio (percentage) to the fragrance content (x) before treatment, that is, [(x) − (y)] / (x) × 100 is defined as the fragrance adsorption rate. The results are shown in Table 2. In addition, content of the fragrance | flavor in the test processing liquid before and behind a process was measured using the following liquid chromatography apparatus.
液体クロマトグラフィー装置:HITACHI L−6000
カラム:Lichrospher 100 RP−18(e) 5μm 125mm×4φ
カラム温度:40℃
溶離剤:アセトニトリル/水=7/3(質量比)の混合溶液
流速:1.0mL/min
検出器:UV(220nm)
Liquid chromatography device: HITACHI L-6000
Column: Lichlorosphere 100 RP-18 (e) 5 μm 125 mm × 4φ
Column temperature: 40 ° C
Eluent: A mixed solution of acetonitrile / water = 7/3 (mass ratio) Flow rate: 1.0 mL / min
Detector: UV (220 nm)
実施例4
表3に示す組成の香料1〜3を用いて、表4〜6に示す組成の繊維製品処理剤組成物を調製した。得られた繊維製品処理剤組成物を用い、実施例1と同様の方法で前処理をした木綿タオルについて同様に柔軟処理を行った。処理後の木綿タオルを、25℃、40%RHにて24時間乾燥させ、残香性の比較官能評価を行った。官能評価結果は、(a)成分を配合していない組成物(ブランク1)と比較して香り強度が強いと答えたパネラーの人数(/10人)で示した。なお、表4では、(a)成分の代わりに、(a−1)成分を合成する際に使用した香料であるフェニルエチルアルコールを加えた組成物(ブランク2)に対しても、同様の香り強度の評価を行った結果を示した。
Example 4
Using the fragrances 1 to 3 having the compositions shown in Table 3, fiber product treating agent compositions having the compositions shown in Tables 4 to 6 were prepared. Using the obtained textile product treating agent composition, a cotton towel pretreated by the same method as in Example 1 was similarly subjected to softening treatment. The treated cotton towel was dried at 25 ° C. and 40% RH for 24 hours, and a comparative sensory evaluation of the remaining fragrance was performed. The sensory evaluation result was shown by the number of panelists (/ 10 people) who answered that the fragrance strength was stronger than that of the composition (blank 1) not containing the component (a). In addition, in Table 4, it is the same fragrance also with respect to the composition (blank 2) which added the phenylethyl alcohol which is the fragrance | flavor used when synthesize | combining (a-1) component instead of (a) component. The results of strength evaluation are shown.
以上の結果より、(a)成分を配合することにより、(b1)成分の吸着率が向上し、その残香性は官能評価においても認識されることが明らかになった。 From the above results, it has been clarified that by blending the component (a), the adsorption rate of the component (b1) is improved, and the residual fragrance is recognized also in sensory evaluation.
Claims (4)
(a):下記式(1−1)又は(1−2)で表される化合物
〔式中、R1は置換基としてフェニル基、水酸基又はアルコキシ基を有していても良い総炭素数1〜22の脂肪族炭化水素基、R2は炭素数6〜22の炭化水素基である。〕
(b1):logPowが3.0以上、5.0以下の香料 A fiber product treating agent composition comprising the following component (a) and component (b1) at a mass ratio of (a) component / (b1) component = 98/2 to 20/80.
(A): Compound represented by the following formula (1-1) or (1-2)
Wherein, R 1 represents a phenyl group as a substituent, a hydroxyl group or an aliphatic hydrocarbon group having 1 to 22 carbon good total carbon may have an alkoxy group, R 2 represents a hydrocarbon group having 6 to 22 carbon atoms There is . ]
(B1): Fragrance with a log Pow of 3.0 or more and 5.0 or less
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US20130139327A1 (en) * | 2010-08-03 | 2013-06-06 | Henkel Ag & Co. Kgaa | Textile treatment composition for removal of deodorant stains |
JP5604220B2 (en) * | 2010-08-19 | 2014-10-08 | 花王株式会社 | Textile treatment composition |
JP5714450B2 (en) * | 2011-08-26 | 2015-05-07 | 花王株式会社 | Liquid air freshener composition for spraying |
JP5792562B2 (en) * | 2011-08-26 | 2015-10-14 | 花王株式会社 | Liquid air freshener composition for spraying |
US9951303B2 (en) * | 2012-10-02 | 2018-04-24 | Robertet, Inc. | Compositions for grafting fragrance substances |
JP6131042B2 (en) * | 2012-12-21 | 2017-05-17 | 花王株式会社 | Silicate ester composition |
US20140335033A1 (en) * | 2013-05-10 | 2014-11-13 | The Procter & Gamble Company | Consumer Products Comprising Silane-Modified Oils |
JP6656245B2 (en) | 2014-11-14 | 2020-03-04 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | Silicone compound |
JP7326047B2 (en) * | 2018-08-07 | 2023-08-15 | 花王株式会社 | Liquid softener composition |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1100671B (en) | 1977-10-15 | 1985-09-28 | Dow Corning Ltd | DETERGENT COMPOSITIONS |
NL8000387A (en) | 1979-02-01 | 1980-08-05 | Dow Corning | PREPARATION WITH ANTI-TRANSPIRATION AND / OR DEODORANT PROPERTIES. |
JP3274940B2 (en) * | 1994-10-12 | 2002-04-15 | 花王株式会社 | Liquid softener composition |
DE10012949A1 (en) * | 2000-03-16 | 2001-09-27 | Henkel Kgaa | Mixtures of cyclic and linear silicic esters of lower alcohols and fragrance and/or biocide alcohols are used as fragrance and/or biocide in liquid or solid laundry and other detergents and in skin and hair cosmetics |
US6670317B2 (en) * | 2000-06-05 | 2003-12-30 | Procter & Gamble Company | Fabric care compositions and systems for delivering clean, fresh scent in a lipophilic fluid treatment process |
CA2408936A1 (en) * | 2000-06-05 | 2001-12-13 | The Procter & Gamble Company | Fabric care compositions and systems for delivering clean, fresh scent in a lipophilic fluid treatment process |
JP4602229B2 (en) * | 2005-10-31 | 2010-12-22 | 花王株式会社 | Textile treatment composition |
JP4647483B2 (en) * | 2005-12-27 | 2011-03-09 | 花王株式会社 | Softener composition |
JP4879654B2 (en) * | 2006-05-26 | 2012-02-22 | 花王株式会社 | Liquid detergent composition |
JP5036254B2 (en) * | 2006-09-06 | 2012-09-26 | ライオン株式会社 | Emulsion type liquid softener composition |
-
2008
- 2008-04-14 JP JP2008104416A patent/JP5557986B2/en active Active
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2009
- 2009-04-13 EP EP09731996A patent/EP2267217A4/en not_active Withdrawn
- 2009-04-13 MX MX2010011127A patent/MX2010011127A/en unknown
- 2009-04-13 US US12/933,798 patent/US20110016636A1/en not_active Abandoned
- 2009-04-13 CN CN200980112924.8A patent/CN101999018B/en not_active Expired - Fee Related
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WO2009128549A1 (en) | 2009-10-22 |
EP2267217A4 (en) | 2013-01-23 |
CN101999018B (en) | 2013-02-13 |
JP2009256818A (en) | 2009-11-05 |
EP2267217A1 (en) | 2010-12-29 |
CN101999018A (en) | 2011-03-30 |
US20110016636A1 (en) | 2011-01-27 |
MX2010011127A (en) | 2010-11-12 |
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