CN101999018A - Textile treatment agent composition - Google Patents
Textile treatment agent composition Download PDFInfo
- Publication number
- CN101999018A CN101999018A CN2009801129248A CN200980112924A CN101999018A CN 101999018 A CN101999018 A CN 101999018A CN 2009801129248 A CN2009801129248 A CN 2009801129248A CN 200980112924 A CN200980112924 A CN 200980112924A CN 101999018 A CN101999018 A CN 101999018A
- Authority
- CN
- China
- Prior art keywords
- composition
- fibre
- treating agent
- fragrance
- fabric treating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 220
- 239000004753 textile Substances 0.000 title abstract 5
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 58
- 238000000034 method Methods 0.000 claims abstract description 51
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 37
- 150000001875 compounds Chemical class 0.000 claims abstract description 24
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 6
- 125000003545 alkoxy group Chemical group 0.000 claims abstract description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 5
- 239000000835 fiber Substances 0.000 claims description 67
- 239000003205 fragrance Substances 0.000 claims description 55
- 239000004744 fabric Substances 0.000 claims description 52
- 229910052799 carbon Inorganic materials 0.000 claims description 42
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 38
- 235000013599 spices Nutrition 0.000 claims description 27
- 125000000217 alkyl group Chemical group 0.000 claims description 23
- 238000003672 processing method Methods 0.000 claims description 12
- 238000010521 absorption reaction Methods 0.000 claims description 6
- 150000001721 carbon Chemical group 0.000 claims description 4
- 125000001424 substituent group Chemical group 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 abstract description 7
- 238000001179 sorption measurement Methods 0.000 abstract description 7
- 239000002304 perfume Substances 0.000 abstract description 3
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 2
- -1 silicate ester compound Chemical class 0.000 description 28
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 25
- 239000004205 dimethyl polysiloxane Substances 0.000 description 15
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 15
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 15
- 238000005406 washing Methods 0.000 description 15
- 238000005516 engineering process Methods 0.000 description 14
- 238000003756 stirring Methods 0.000 description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 239000002253 acid Substances 0.000 description 12
- 150000002148 esters Chemical class 0.000 description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 11
- 238000010438 heat treatment Methods 0.000 description 11
- 229920000742 Cotton Polymers 0.000 description 10
- 238000001035 drying Methods 0.000 description 10
- 238000011156 evaluation Methods 0.000 description 10
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- 238000012986 modification Methods 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
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- 230000015572 biosynthetic process Effects 0.000 description 8
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- 239000010703 silicon Substances 0.000 description 8
- 238000003786 synthesis reaction Methods 0.000 description 8
- 241001502050 Acis Species 0.000 description 7
- 239000000194 fatty acid Substances 0.000 description 7
- 239000000796 flavoring agent Substances 0.000 description 7
- 235000019634 flavors Nutrition 0.000 description 7
- 238000005342 ion exchange Methods 0.000 description 7
- 230000014759 maintenance of location Effects 0.000 description 7
- ZCTQGTTXIYCGGC-UHFFFAOYSA-N Benzyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 description 6
- ZFMSMUAANRJZFM-UHFFFAOYSA-N Estragole Chemical compound COC1=CC=C(CC=C)C=C1 ZFMSMUAANRJZFM-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 125000003342 alkenyl group Chemical group 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 239000012298 atmosphere Substances 0.000 description 6
- 238000009835 boiling Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 238000004821 distillation Methods 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
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- 239000000243 solution Substances 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
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- 238000002203 pretreatment Methods 0.000 description 5
- 230000001953 sensory effect Effects 0.000 description 5
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- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 4
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 4
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 description 4
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- 230000006837 decompression Effects 0.000 description 4
- 230000018044 dehydration Effects 0.000 description 4
- 238000006297 dehydration reaction Methods 0.000 description 4
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 239000003755 preservative agent Substances 0.000 description 4
- 230000002335 preservative effect Effects 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- UFLHIIWVXFIJGU-ARJAWSKDSA-N (Z)-hex-3-en-1-ol Chemical compound CC\C=C/CCO UFLHIIWVXFIJGU-ARJAWSKDSA-N 0.000 description 3
- DNRJTBAOUJJKDY-UHFFFAOYSA-N 2-Acetyl-3,5,5,6,8,8-hexamethyl-5,6,7,8- tetrahydronaphthalene Chemical compound CC(=O)C1=C(C)C=C2C(C)(C)C(C)CC(C)(C)C2=C1 DNRJTBAOUJJKDY-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000005792 Geraniol Substances 0.000 description 3
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- 125000001118 alkylidene group Chemical group 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 125000001589 carboacyl group Chemical group 0.000 description 3
- 229940043350 citral Drugs 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
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- 229940113087 geraniol Drugs 0.000 description 3
- UFLHIIWVXFIJGU-UHFFFAOYSA-N hex-3-en-1-ol Natural products CCC=CCCO UFLHIIWVXFIJGU-UHFFFAOYSA-N 0.000 description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 150000003961 organosilicon compounds Chemical class 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- 229920002545 silicone oil Polymers 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000003760 tallow Substances 0.000 description 3
- 150000003512 tertiary amines Chemical class 0.000 description 3
- 230000010148 water-pollination Effects 0.000 description 3
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 2
- NOOLISFMXDJSKH-KXUCPTDWSA-N (-)-Menthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-KXUCPTDWSA-N 0.000 description 2
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 2
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- HEVGGTGPGPKZHF-UHFFFAOYSA-N 1-(1,2-dimethyl-3-methylidenecyclopentyl)-4-methylbenzene Chemical compound CC1C(=C)CCC1(C)C1=CC=C(C)C=C1 HEVGGTGPGPKZHF-UHFFFAOYSA-N 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- YCIXWYOBMVNGTB-UHFFFAOYSA-N 3-methyl-2-pentylcyclopent-2-en-1-one Chemical compound CCCCCC1=C(C)CCC1=O YCIXWYOBMVNGTB-UHFFFAOYSA-N 0.000 description 2
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- 239000005844 Thymol Substances 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- VHSXAHUANQIENY-UHFFFAOYSA-N [O]CCc1ccccc1 Chemical compound [O]CCc1ccccc1 VHSXAHUANQIENY-UHFFFAOYSA-N 0.000 description 1
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- 150000007513 acids Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 239000002168 alkylating agent Substances 0.000 description 1
- 229940100198 alkylating agent Drugs 0.000 description 1
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 1
- YPZUZOLGGMJZJO-LQKXBSAESA-N ambroxan Chemical compound CC([C@@H]1CC2)(C)CCC[C@]1(C)[C@@H]1[C@]2(C)OCC1 YPZUZOLGGMJZJO-LQKXBSAESA-N 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
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- 230000001143 conditioned effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 229930008394 dihydromyrcenol Natural products 0.000 description 1
- XSNQECSCDATQEL-UHFFFAOYSA-N dihydromyrcenol Chemical compound C=CC(C)CCCC(C)(C)O XSNQECSCDATQEL-UHFFFAOYSA-N 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- JZZIHCLFHIXETF-UHFFFAOYSA-N dimethylsilicon Chemical compound C[Si]C JZZIHCLFHIXETF-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 150000002240 furans Chemical class 0.000 description 1
- ONKNPOPIGWHAQC-UHFFFAOYSA-N galaxolide Chemical compound C1OCC(C)C2=C1C=C1C(C)(C)C(C)C(C)(C)C1=C2 ONKNPOPIGWHAQC-UHFFFAOYSA-N 0.000 description 1
- HIGQPQRQIQDZMP-UHFFFAOYSA-N geranil acetate Natural products CC(C)=CCCC(C)=CCOC(C)=O HIGQPQRQIQDZMP-UHFFFAOYSA-N 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- JPXGPRBLTIYFQG-UHFFFAOYSA-N heptan-4-yl acetate Chemical compound CCCC(CCC)OC(C)=O JPXGPRBLTIYFQG-UHFFFAOYSA-N 0.000 description 1
- 239000000413 hydrolysate Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- SDQFDHOLCGWZPU-UHFFFAOYSA-N lilial Chemical compound O=CC(C)CC1=CC=C(C(C)(C)C)C=C1 SDQFDHOLCGWZPU-UHFFFAOYSA-N 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- CXHHBNMLPJOKQD-UHFFFAOYSA-M methyl carbonate Chemical compound COC([O-])=O CXHHBNMLPJOKQD-UHFFFAOYSA-M 0.000 description 1
- SBENKNZHVXGNTP-UHFFFAOYSA-N methylconiferyl ether Natural products COCC=CC1=CC=C(O)C(OC)=C1 SBENKNZHVXGNTP-UHFFFAOYSA-N 0.000 description 1
- 229940116837 methyleugenol Drugs 0.000 description 1
- PRHTXAOWJQTLBO-UHFFFAOYSA-N methyleugenol Natural products COC1=CC=C(C(C)=C)C=C1OC PRHTXAOWJQTLBO-UHFFFAOYSA-N 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229930008383 myrcenol Natural products 0.000 description 1
- DUNCVNHORHNONW-UHFFFAOYSA-N myrcenol Chemical compound CC(C)(O)CCCC(=C)C=C DUNCVNHORHNONW-UHFFFAOYSA-N 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- WASNIKZYIWZQIP-AWEZNQCLSA-N nerolidol Natural products CC(=CCCC(=CCC[C@@H](O)C=C)C)C WASNIKZYIWZQIP-AWEZNQCLSA-N 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 description 1
- 229960003493 octyltriethoxysilane Drugs 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- 125000000963 oxybis(methylene) group Chemical group [H]C([H])(*)OC([H])([H])* 0.000 description 1
- RUVINXPYWBROJD-UHFFFAOYSA-N para-methoxyphenyl Natural products COC1=CC=C(C=CC)C=C1 RUVINXPYWBROJD-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920003216 poly(methylphenylsiloxane) Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 210000003296 saliva Anatomy 0.000 description 1
- 230000001835 salubrious effect Effects 0.000 description 1
- 210000000697 sensory organ Anatomy 0.000 description 1
- 150000003376 silicon Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- KWVISVAMQJWJSZ-VKROHFNGSA-N solasodine Chemical compound O([C@@H]1[C@@H]([C@]2(CC[C@@H]3[C@@]4(C)CC[C@H](O)CC4=CC[C@H]3[C@@H]2C1)C)[C@@H]1C)[C@]11CC[C@@H](C)CN1 KWVISVAMQJWJSZ-VKROHFNGSA-N 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 229960000790 thymol Drugs 0.000 description 1
- BJIOGJUNALELMI-UHFFFAOYSA-N trans-isoeugenol Natural products COC1=CC(C=CC)=CC=C1O BJIOGJUNALELMI-UHFFFAOYSA-N 0.000 description 1
- XMLSXPIVAXONDL-UHFFFAOYSA-N trans-jasmone Natural products CCC=CCC1=C(C)CCC1=O XMLSXPIVAXONDL-UHFFFAOYSA-N 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- WTARULDDTDQWMU-UHFFFAOYSA-N β-pinene Chemical compound C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/005—Compositions containing perfumes; Compositions containing deodorants
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/162—Organic compounds containing Si
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/503—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms without bond between a carbon atom and a metal or a boron, silicon, selenium or tellurium atom
- D06M13/507—Organic silicon compounds without carbon-silicon bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Detergent Compositions (AREA)
Abstract
Provided are a textile treatment agent composition containing (a) compound represented by general formula (1) and (b1) perfume of log Pow at least 3.0 and not more than 5.0 in a ratio by mass of component (a)/component (b1) from 98/2 to 20/80, and a method wherein this textile treatment agent composition is brought into contact with textile products with water as the medium and the adsorption of the component (b1) on the textile product is accelerated. (1) [In this formula, X is -OH, -R1 (where R1 is an aliphatic hydrocarbyl group having a total of from 1 to 22 carbon atoms optionally substituted with a phenyl group, hydroxyl group or alkoxy group) or -OR2 (where R2 is a hydrocarbyl group having from 6 to 22 carbon atoms); Y is X or -OSi(X)3, and n is a number from 0 to 15 indicating the average value; and the plurality of X or Y may be the same or different, but there is at least one -OR2 in the molecule].
Description
Technical field
The present invention relates to fabric treating agent composition.
Background technology
In recent years, because people to the raising of the consciousness of fragrance, are developing at clothing uses spices with fragrance retention in fabric treating agents such as remover or retouching agent, finishes still to keep aromatic technology in the fibre of back in washing.These typically use high being difficult to of the lipophile technology of rising fragrance component of volatilizing, but because the odor dispersion of these fragrance components is poor, mostly are the heavy thick fragrance component of fragrance greatly, and therefore, residual fragrance is decided by their fragrance.On the other hand, because the fragrance emissions excellence of the fragrance component of strong spices of hydrophily or comparison possess hydrophilic property, to compare raw material types many with oil loving fragrance component, therefore, can design various fragrance.But, because it is poor to the adsorptivity of fibre, therefore a little less than the fragrance of fibre after treatment, and continuation is also poor, therefore, tight demand improves the adsorptivity of the fragrance component of strong spices of hydrophily or comparison possess hydrophilic property, the technology that expansion remains in the flavor change in the fibre.
On the other hand, as the technology of giving fragrance retention, known have a silicate ester compound.In JP-A54-59498, JP-A 54-93006, JP-A 55-127314, JP-A 2003-526644 etc., disclose the fabric treating agent that contains esters of silicon acis, particularly in JP-A 2003-526644, put down in writing also usefulness with flavor compositions.
Summary of the invention
The invention provides a kind of fabric treating agent composition, it contains following (a) composition and (b1) composition with the mass ratio of composition=98/2～20/80 of (a) composition/(b1), wherein,
(a) be the compound shown in the general formula (1),
[in the formula, X is-OH ,-R1 (R1 be can have phenyl, hydroxyl or alkoxyl be 1～22 aliphatic alkyl as substituent total carbon atom number) or-OR2 (R2 is that carbon number is 6～22 alkyl), Y be X or-OSi (X) 3, n is 0～15 a number of expression mean value.A plurality of X and Y can be the same or different respectively, but have 1-OR2 at least in a molecule.]
(b1) be that logPow is the spices more than 3.0, below 5.0.
The invention provides a kind of by being that medium makes above-mentioned composition contact fibre promote the method for (b1) composition to fibre absorption with water.
The invention provides a kind of fiber product processing method, give fibre with fragrance by after carrying out the following A operation, carrying out the B operation, perhaps by carrying out the A operation simultaneously and the B operation is given fibre with fragrance,
The A operation: the operation of using above-mentioned composition that fibre is handled,
B operation: the operation of fibre being carried out heat treated.
The specific embodiment
The hydrolysate that the technology of putting down in writing in JP-A 54-59498, JP-A 54-93006, JP-A 55-127314, JP-A2003-526644 is to use esters of silicon acis as fragrance component, by make attached to the esters of silicon acis on the fibre slowly hydrolysis improve the technology of the continuation of fragrance, therefore, be confined to the fragrance component aspect of alcohols and do not have water then do not have problem such as fragrance if exist.The kind of the alcohols spices that uses in the fragrant technology of the tax of esters of silicon acis is limited, and expansion residues in the variation of the fragrance on the clothing and can't tackle only according to the fragrant technology of the tax of esters of silicon acis.In addition, the fragrance component of possess hydrophilic property enlightens without any technology to the adsorptivity this point of fibre improving relatively about specific esters of silicon acis.
Among the JP-A 2003-526644 particular instantiation with other fragrance component and use, but these are to use the technology of silicate ester compound as the part of spices, and the effect during to the fragrance component that contains the comparison possess hydrophilic property with specific ratio and esters of silicon acis does not provide the technology enlightenment.
Therefore, the invention provides a kind of fabric treating agent composition, when using clothing fibre to be handled with fabric treating agents such as remover or retouching agent, can improve the adsorptivity of spices, particularly improve the relatively adsorptivity of the spices of possess hydrophilic property, and can expand the variation that remains in the fragrance in the fibre, can give stronger various fragrance for a long time.
According to the present invention, can improve the adsorptivity of spices, particularly the adsorptivity of the spices of possess hydrophilic property to fibre compared in raising, and can expand the variation that remains in the fragrance in the fibre, and can give stronger fragrance for a long time.
[(a) composition]
(a) of the present invention composition is the compound by above-mentioned general formula (1) expression.
In the general formula (1), X is-OH ,-R1 or-OR2, Y be X or-OSi (X) 3, n is 0～15 a number of expression mean value.A plurality of X and Y can be the same or different respectively, but have 1-OR2 at least in a molecule.
It is 1～22 aliphatic alkyl as substituent total carbon atom number that R1 represents to have phenyl, hydroxyl or alkoxyl, preferably can have phenyl, hydroxyl or alkoxyl and be the alkyl or the alkenyl of 1～22 straight or branched as substituent total carbon atom number, n is 0 o'clock, more preferably carbon number is the alkyl of 6～18 straight or branched, carbon numbers such as further preferred n-hexyl, n-octyl, positive decyl, dodecyl, n-hexadecyl, n-octadecane base are 6～18 straight chained alkyl, and further preferred carbon number is 10～18 straight chained alkyl.
R2 represents that carbon number is 6～22 alkyl, and preferred carbon number is 6～15 alkyl, and more preferably carbon number is 8～15 alkyl.As alkyl, preferred alkyl, alkenyl or alkylaryl are considered to the viewpoint of the adsorptivity of fibre from improving (b1) composition, are preferably selected from the alkyl with branched structure and the group of alkenyl especially.
In the general formula (1), be 0 o'clock at n, 2～4, preferred 3 or 4 among preferred 4 X are-OR2, all the other are-and the compound of R1.
Preferred compound during as n=0, can enumerate following formula (1-1) or (1-2) shown in compound.
[in the formula, R1 and R2 represent implication same as described above.]
In the preferred formula (1) n be 1～15 o'clock n represent mean value, with respect to whole X and Y 1/10 or more preferred 1/8 or more for-OR2, all the other are-compound of R1, especially preferably whole X and Y is-compound of OR2.As n, be preferably 1～10, more preferably 1～5.
As n is 1～15 o'clock preferred compound, can enumerate following formula (1-3) or (1-4) shown in compound.
[in the formula, R1 and R2 represent implication same as described above.M represents 1～15 number, T represents-OR2 or-R1.]
Compound shown in the general formula (1) can obtain by the method for record among JP-A 54-59498 and the JP-A 2003-526644 etc.
[(b1) composition and other fragrance component]
(b1) of the present invention composition is that logPow is at the spices more than 3.0, below 5.0.Because (b1) the common fragrance emissions excellence of composition, raw material are many, thereby can give fibre with various fragrance, but are difficult to be adsorbed on the fibre when fibre is handled, the adsorptivity that improves these fragrance components is most important.The present invention is outstanding especially technology as the technology of the adsorptivity that improves (b1) composition.
At this, logPow is meant the 1-octanol/water distribution coefficient that utilizes chemical substance, calculates the value of obtaining by f value method (hydrophobicity fragment constant method).Particularly, can resolve into its inscape by chemical constitution with compound, accumulative total hydrophobicity fragment constant (f value) that each fragment had and obtaining, can be with reference to CLOGP3 Reference Manual Daylight Software 4.34, Albert Leo, David Weininger, Version 1, and March 1994.
As (b1) composition, can enumerate: the hydro carbons spices that i) is selected from australene (4.18), nopinene (4.18), amphene (4.18), citrene (4.35), terpinolene (4.35), laurene (4.33), p-cymene (4.07); Ii) be selected from the alcohols spices of Sandalmysore Core (3.9), santalol (3.9), 1-menthol (3.2), citronellol (3.25), dihydromyrcenol (3.03), ethyl linalool (3.08), alloocimenol (3.03), nerolidol (4.58); Iii) be selected from aldehydes spices, the ketone fragrance of aldehyde C-111 (4.05), greenal (グ リ one Na one Le) (3.13), citral (mandarin aldehyde) (4.99), citral (3.12), citronellal (3.26), amyl cinnamic aldehyde (4.32), jasminolene (4.85), lilial (3.86), dihydro jasmone (3.13), 1-carvol, ionone α (3.71), methyl ionone α (4.24), methyl ionone G (4.02); Iv) be selected from the ester perfume of heptyl acetate (3.36), geraniol acetate (4.20), Mang geranyl acetate (3.72), acetate linalool ester (3.50), ethyl cinnamate (3.0), benzyl salicylate (4.2), isonefolia (3.92); V) be selected from the phenols spices of thymol (3.40), vanitrope (3.11); Vi) be selected from the ethers spices of cedroxyde (4.58), citronellyl ethyl ether (4.36), anethole (3.31), naphthyl methyl ether (nerolin yara yara) (3.24), estragole (3.1), isoeugenol methyl ether (3.0).Wherein, in the bracket be the value of logPow.
As (b1) composition, because the fragrance emissions excellence of citrene (4.35), estragole (3.1), 1-menthol (3.2), citronellol (3.25), citral (3.12), citronellal (3.26), isonefolia (3.8), amyl cinnamic aldehyde (4.32), dihydro jasmone (3.13), ionone α (3.71), methyl ionone α (4.24), methyl ionone G (4.02), benzyl salicylate (4.2), and it is can give fibre, thereby preferred especially with salubrious fragrance.
In the present invention, can use the flavor compositions that contains (b1) composition fragrance component in addition., can enumerate: β-carypohyllene (6.45), trimethyl undecenal (5.16), 1-Hexyl salicylate (5.09), imperial saliva furans (ambroxan) (5.27), tonalid (tentarome) (5.7), Jiale muskiness (pearlide) (5.7) etc. than the fragrance component (hereinafter referred to as (b2) composition) that higher logPow surpasses 5 as lipophile.
And, as the fragrance component (hereinafter referred to as (b3) composition) of the strong logPow less than 3 of hydrophily, can enumerate: terpineol (2.6), Mang geraniol (2.77), linalool (2.55), myrcenol (2.61), nerol (2.77), cis-jasmone (2.64), phenethyl acetate (2.13), allyl amyl glycolate (2.51), cis-3-hexenol methyl carbonate (liffarome) (2.26), suitable-3-hexyl acetate (2.34), methyl phenyl carbinyl acetate (2.27), verdone (2.27), to tert-butyl group cyclohexanone (2.27), acetyl eugenol (2.83), cinnamyl acetate (2.35), eugenol (2.40), isoeugenol (2.58), MOSS SYNTH (2.94), anisole (2.06), methyleugenol (2.78), cumarin (1.4) etc.
As the spices of (b1) composition of of the present invention containing, preferably contain (b1) composition and (b2) composition at least, (b2) fragrance of composition and (b1) fragrance of composition combine, can make various fragrance lasting in fibre.All the content of fragrance component (b1) is preferably more than the 30 quality % in the spices, more preferably more than the 50 quality %.In addition, most preferably all the content of (b2) composition is preferably 10～50 quality % in the spices, more preferably 20～30 quality % and all the other are the spices of (b3) composition.(b1) composition is preferably 10/90～1/1 with (b1)+(b2) mass ratio of composition, and more preferably 20/80～1/1, more preferably 30/70～1/1.Below, with (b1), (b2) and (b3) mixture of ingredients be called (b) composition.
[fabric treating agent composition]
From improve (b1) composition to adsorptivity, the fragrance emissions excellence of fibre, continue to keep the viewpoint of the wide fragrance of excursion to consider, fabric treating agent composition of the present invention contains (a) composition and (b1) composition with the mass ratio of composition=98/2～20/80 of (a) composition/(b1).(a) composition/(b1) mass ratio of composition is preferably 90/10～30/70, and more preferably 85/15～40/60.
Fabric treating agent composition of the present invention can contain the diluent and the preservative of spices.As the preference of diluent, preservative, can enumerate: dipropylene glycol, isopropyl palmitate, diethyl phthalate, Ergol, atoleine, isomerization alkanes, grease etc.Preservative is preferably 0～20 quality % with respect to the ratio of the total of (b) composition and preservative.
The purpose of using fabric treating agent composition of the present invention in softener, odorant, paste, modeling agent (styling agent) etc. is to control fragrance.
The rinsing of washing step that fabric treating agent composition of the present invention is preferably used as general family makes an addition to the fabric treating agent of rinsing in the wash water in the stage of washing, specifically be preferred for softener composition.
When the present invention is used for softener composition, preferably contain soft base (softening base) as (c) composition.As soft base, be preferably selected from and have tertiary amine that 1～3 carbon number is 10～22 alkyl or its hydrochlorate or its season thing [hereinafter referred to as (c1) composition] and (a) compound of the organo-silicon compound [hereinafter referred to as (c2) composition] beyond the composition.
As (c1) composition, preferably have 1～3 carbon number that can have ester bond or an amido link and be 12～22 alkyl and remainder and be carbon number and be the tertiary amine of 1～3 alkyl and/or hydroxyalkyl or its hydrochlorate or its in season thing.As the concrete example of (c1) composition, can enumerate the compound of following (c11)～(c13).
(c11) have that 2 carbon numbers are 12～22, preferred carbon number is 14～20, more preferably carbon number is 16～18 alkyl or alkenyl, and remainder is that carbon number is the quaternary ammonium salt (as salt, for villaumite, carbon number are that 1～12 soap, carbon number are 1～3 alkyl sulfate salt) of 1～3 alkyl or hydroxyalkyl.
(c12) carbon number with 1 or 2 alkanoyls or alkenoyl (alkenoyl) is 11～21, preferred 13～19, more preferably 15～17 alkanoyl (alkenoyl) oxygen ethyl or alkanoyl (alkenoyl) aminopropyl; and remainder is that carbon number is the tertiary amine of 1～3 alkyl or hydroxyalkyl or its hydrochlorate (as hydrochlorate, being 1～12 soap for hydrochloride, sulfate, phosphate, carbon number).
(c13) utilize the preferred chloromethanes of alkylating agent, dimethyl suflfate or dithyl sulfate, with triethanolamine be selected from that carbon number is 12～22, the derivative of fatty acid of preferred 14～20, preferred especially 16～18 aliphatic acid or fatty acid lower alkyl esters, fatty acid chloride, preferably carry out the quaternary ammonium salt that seasonization generates (as salt, for villaumite, carbon number are that 1～12 soap, carbon number are 1～3 alkyl sulfate salt) with the esterification reaction product of aliphatic acid.
As (c2) composition, the insoluble organo-silicon compound of preferred water.The amount of dissolving in this water-insoluble compound is meant ion exchange water 1L at 20 ℃ is the compound below the 1g.Specifically can enumerate: organo-silicon compound such as dimethyl polysiloxane, quaternary ammonium salt-modified dimethyl polysiloxane, amino modified dimethyl polysiloxane, acid amides modification dimethyl polysiloxane, epoxide modified dimethyl polysiloxane, carboxy-modified dimethyl polysiloxane, polyoxy alkylidene modification dimethyl polysiloxane, fluorine modification dimethyl polysiloxane.In addition, the silicone oil as the finish of any composition in the fabric treating agent of the present invention is enumerated can be used as (c2) composition and uses.
Among the present invention special preferred molecular weight be thousand～1,000,000, preferred 3,000～1,000,000, preferred especially 5,000～1,000,000, the viscosity in the time of 25 ℃ be 2～1,000,000 mm2/s, preferred 500～1,000,000 mm2/s, preferred especially 1,000～1,000,000 mm2/s be selected from dimethyl polysiloxane, amino modified dimethyl polysiloxane, acid amides modification dimethyl polysiloxane, polyoxy alkylidene (polyoxyethylene and/or polyoxypropylene, preferred polyoxyethylene) the modification dimethyl polysiloxane more than a kind.The amino equivalent of amino modified dimethyl polysiloxane (so-called amino equivalent is meant per 1 nitrogen-atoms corresponding molecular weight) is preferably 1500～40000g/mol, more preferably 2500～20000g/mol, more preferably 3000～10000g/mol.
Among the present invention, preferred especially and with (c1) composition and (c2) composition, its content ratio (c1) composition/(c2) composition is 60/1～1/50 by quality ratio, is preferably 60/1～1/20, more preferably 50/1～1/10.
Because (a) of the present invention composition, (b) composition and as composition arbitrarily but be neccessary composition (c) composition when being applied to softener composition, it for water insoluble compound, therefore, when using with the form of waterborne compositions, so that its in composition, stably dissolve, dispersion, emulsification be purpose, preferably contains non-ionic surface active agent [hereinafter referred to as (d) composition].
As (d) composition, preferably has carbon number and is 8～20 the alkyl or the polyoxyethylene alkyl ether of alkenyl, the non-ionic surface active agent shown in the more preferably following general formula (2).
R2a-A-〔(R2bO)p-R2c〕q (2)
[in the formula, R2a is that carbon number is 8～18, preferably carbon number is 10～16 alkyl or alkenyl, R2b is that carbon number is 2 or 3 alkylidene, be preferably ethylidene, R2c is that carbon number is 1～3 alkyl or hydrogen atom, p is 2～100 number, preferred 5～80 number, more preferably 5～60 number, further preferred 10～60 number, A is-O-,-COO-,-CON＜,-CONRx-,-NRx-or-N＜.A for-O-,-COO-,-CONRx ,-q is 1 during NRx-, A for-CON＜or-N＜time q be 2.Rx is that H or carbon number are 1～3 alkyl.]
As the concrete example of the compound of general formula (2), can enumerate the compound shown in the following formula (2-1)～(2-3).
R2a-O-(C2H4O)r-H (2-1)
[in the formula, R2a represents above-mentioned implication.R is 8～100 number, preferred 10～60 number.]
R2a-O-(C2H4O)s/(C3H6O)t-H (2-2)
[in the formula, R2a represents above-mentioned implication.S and t are respectively 2～40 number, preferred 5～40 number independently, and (C2H4O) s/ (C3H6O) t can be random or the block addition product.]
[in the formula, R2a represents above-mentioned implication.A is-N＜or-CON＜, u and v are respectively 0～40 number independently, u+v is 5～60 number, preferred 5～40 number.R2d, R2e are the alkyl of hydrogen atom or carbon number 1～3 respectively independently.]
When fabric treating agent composition of the present invention is applied to softener composition, consider from the purpose that improves soft effect, preferably contain aliphatic acid [hereinafter referred to as (e1) composition], carbon numbers such as concrete preferred laurate, myristic acid, palmitic acid, palmitoleic acid, stearic acid, oleic acid, linoleic acid, erucic acid, mountain Yu acid are 12～22 saturated or unrighted acid, preferred especially palmitic acid, stearic acid, oleic acid, linoleic acid.
Consider that from the purpose that improves storage-stable composition of the present invention can contain inorganic salts as required as (f) composition.As inorganic salts, consider preferred sodium chloride, calcium chloride and magnesium chloride from the viewpoint of storage-stable.
To improve storage-stable is purpose, and it is that the ester compounds of 8～22 saturated or unrighted acid and polyalcohol is as (g) composition that composition of the present invention also can contain carbon number.As (g) composition that can cooperate, can enumerate single, double, tri-fatty acid ester, the sorbitan fatty acid ester of triglyceride, Diglyceride, simple glyceride, pentaerythrite.
Composition of the present invention can also contain solvent as required as (h) composition.As solvent, be preferably selected from the solvent in ethanol, isopropyl alcohol, glycerol, ethylene glycol, the propylene glycol, consider special preferred alcohol from the viewpoint of smell.
In addition, in fabric treating agent composition of the present invention, can also contain finishes such as hydrocarbon ils, alcohol oil, ester oil, silicone oil as required as (i) composition.As the solubility of (a) composition 20 ℃ the time is finish more than the 5 weight %, preferably the 5 weight % of the solubility less than in 20 ℃ water and (a) composition solubility in the time of 20 ℃ be finish more than the 5 weight %.At this, as above-mentioned finish, the more preferably solubility less than 0.5 weight % in the water in the time of 20 ℃, further preferred less than 0.1 weight %.
As the 5 weight % of the solubility less than in 20 ℃ water and (a) solubility of composition 20 ℃ the time be finish more than the 5 weight %, consider that from volatile viewpoint of finish the vapour pressure in the time of preferred 20 ℃ is below the 2.7kPa, more preferably below the 1kPa.As hydrocarbon ils, can enumerate carbon number and be the saturated or undersaturated hydrocarbon ils more than 8.As ester oil, aliphatic acid and the carbon number that can enumerate carbon number and be more than 14 are the ester oil of the carboxylate of the alcohol more than 1.As silicone oil, can enumerate modified silicon oils such as dimethicone, methyl phenyl silicone oil and phenyl modified, (gathering) ether modification, alkyl-modified, fatty acid ester modification, fluorine modification, amino modified, epoxide modified, carboxy-modified, methyl alcohol modification, phenol modification.
Preferred liquid paraffin, carbon number are that 14～20 aliphatic acid and carbon number are the carboxylate of 1～20 alcohol, the dimethyl-silicon wet goods that viscosity is 1mPas～1000mPas in these finishes.
Fabric treating agent composition of the present invention can be applied in the softener composition.In this case, the content of (a) composition in the composition is preferably 0.1～6.0 quality %, more preferably 0.2～3.0 quality %, more preferably 0.3～1.0 quality %.In addition, the content of (b1) composition in the composition is preferably 0.02～1.5 quality %, more preferably 0.05～1 quality %, more preferably 0.08～0.8 quality %.In addition, the content of (b) composition in the composition is preferably 0.1～1.5 quality %, more preferably 0.2～1 quality %, more preferably 0.3～0.8 quality %.In addition, (a) composition and (b) components in proportions be so that (a) composition/(b) mass ratio of composition is preferably 20/80～90/10, and more preferably 30/70～90/10, more preferably 40/60～90/10.And the content of (c1) composition in the composition is preferably 3～30 quality %, more preferably 3～25 quality %, more preferably 3～20 quality %.In addition, the content of (c2) composition in the composition is preferably 0.3～15 quality %, more preferably 0.3～10 quality %, more preferably 0.5～8 quality %.The content of (d) composition in the composition is preferably 0.1～10 quality %, more preferably 0.2～9 quality %, more preferably 0.5～8 quality %.Consider from the viewpoint that keeps stability, (a) composition and (d) components in proportions so that (a) composition/(d) mass ratio of composition is preferably 3/97～90/10, more preferably 5/95～50/50, more preferably 10/90～30/70.In addition, the content of (e) composition in the composition is preferably 0.2～10 quality %, more preferably 0.2～5 quality %, more preferably 0.3～4 quality %.The content of (f) composition in the composition is preferably 0.0005～5 quality %, more preferably 0.001～4 quality %, more preferably 0.005～3 quality %.The content of (g) composition in the composition is preferably 0.01～15 quality %, more preferably 0.05～10 quality %, more preferably 0.1～5 quality %.The content of (h) composition in the composition is preferably 0.2～25 quality %, more preferably 0.3～10 quality %, more preferably 0.3～5 quality %.
[promoting the method for (b1) composition] to fibre absorption
Promoting (b1) of the present invention composition to the method for fibre absorption to be, is the method that medium makes fabric treating agent composition contact fibre of the present invention with water.
As the step that makes fabric treating agent composition contact fibre of the present invention, rinsing the stage of washing of preferred general home washings step, be added on and rinse in the wash water, make (a) composition and (b1) composition total with respect to fibre 1kg be preferably 0.01～0.5g, more preferably 0.02～0.3g, be preferably 0.03～0.2g especially.
Usually, because (a) composition and comprise that (b) composition of (b1) composition is water-fast compound, therefore, be added on when rinsing in the wash water, preferably make (a) composition and (b) composition in rinsing wash water, dissolve equably, dispersion, emulsification, therefore, (d) composition plays an important role.In the present invention, with respect to (a) composition and (b) total of composition, the mass ratio of (d) composition that coexists in rinsing wash water is preferably 1/20～20/1, more preferably 1/15～15/1, is preferably 1/10～10/1 especially.Rinsing the stage of washing of washing procedure, the common dehydration/drying of behind the contact fibre, carrying out.
As method in addition, can enumerate: the method for in the washing of general family, adding simultaneously, be sprayed directly on to method on the fibre, utilize method that roller etc. applies etc. by spray-on process with remover.
Following method is the processing method of another fibre.
[processing method of fibre]
The processing method of fibre of the present invention is the method for carrying out following A operation and B operation, and the A operation is to promote the operation of above-mentioned (b1) composition to fibre absorption, and the B operation is the operation of carrying out heat treated.That is, the processing method of fibre of the present invention comprises: use and to contain above-mentioned (a) composition and (b1) fabric treating agent composition of composition A operation that fibre is handled and the B operation of fibre being carried out heat treated.Preferable methods is the method for carrying out the method for B operation or carrying out A operation and B operation simultaneously after the A operation.
In the A operation,, can enumerate the method for following (i)～(iii) etc. as the method for using fabric treating agent composition that fibre is handled.
(i) cleaning or rinsing the stage of washing in the washing procedure of fibre is added on fabric treating agent composition and cleans water or rinse method in the wash water.
The sprayer that (ii) use to trigger container etc. sparges method on the fibre with fabric treating agent composition.
(iii) make the carrier contact that comprises fabric treating agent composition method as the fibre of process object.
Consider from aspects such as the absorption that promotes (b1) composition, ease-to-operates,, can enumerate the method for (i) as the processing method of preferred A operation.When using the method for (i), bath raio (mass ratio of water/fibre) is preferably 3～30, and more preferably 4～30.When using drum-type washing machine, their bath raio is usually according to the weight automatic setting of washings.The preferred bath raioes of considering them etc., the selected clean conditioned disjunction that makes fabric treating agent composition be attached to fibre is effectively rinsed the condition of washing.In the method, preferably according to every 1kg fibre, fabric treating agent composition is 0.005～15.0g, more preferably the ratio of 0.05～10.0g is used fabric treating agent composition.In addition, be preferably formed the ratio of 0.001～1000ppm, more preferably form the ratio of 0.01～100ppm with respect to the addition of the fabric treating agent composition of water.
In the B operation preferably, as the fibre that utilizes fabric treating agent composition to handle is carried out methods of heating treatment, have the method (Contact Heating method) that directly contacts or directly do not contact with thermal source and the method (noncontact heating) that fibre heated via media such as air with thermal source.
As the thermal source of Contact Heating method, the hard surface that can use flatiron, garment press etc. to heat.The surface temperature of use face is preferably 80～250 ℃, and more preferably 90～240 ℃, more preferably 100～230 ℃.Also can use shield and the use face of contact.Heat treatment time is different according to the temperature of setting, but be generally 5 seconds～and about 5 minutes.
As the noncontact heating, can enumerate the heating under the heating atmosphere, can use heat drying machine, heated scrub drying machine etc.The temperature of heating atmosphere is preferably 50～120 ℃, and more preferably 50～110 ℃, more preferably 50～100 ℃.According to the function of the temperature etc. of heating atmosphere, heat drying machine, heated scrub drying machine, heat treatment time is longer, is about 5～400 minutes.
Carry out at the same time the A operation (iii) with the B operation time, also can contain comprising (a) composition and (b1) carrier of the fabric treating agent composition of composition put under the high temperature atmosphere with fibre, under the high temperature atmosphere, carry out A operation and B operation simultaneously.In addition, the carrier that comprises above-mentioned fabric treating agent composition is contacted together with fibre under environment, by adding thermosetting high temperature atmosphere, also can carry out A operation and B operation simultaneously thereafter.At this moment, preferably carrier and the fibre that comprises fabric treating agent composition of the present invention stirred, it is contacted with high-frequency.In addition, from being that the viewpoint that medium is adsorbed on the fibre (b1) composition considers that preferably the fibre that contacts with the carrier that comprises fabric treating agent composition of the present invention contains water with water.Water contained in the fibre is preferably 30～300 quality % for fibre, more preferably 30～200 quality %, more preferably 30～150 quality %, most preferably 30～100 quality %.
Embodiment
Following examples are set forth enforcement of the present invention.Embodiment is the example that illustration of the present invention is set forth, and is not used in qualification the present invention.
Gather each gradation composition that uses in embodiment and the comparative example as follows:
(a) composition
(a-1): the octyl group silicic acid three that in following synthesis example 1, obtains (2-phenethyl) ester
(a-2): four (cis-3-hexenyl oxygen) silane that in following synthesis example 2, obtains
(a-3): poly-(the 4-methoxybenzene ylmethoxy) siloxanes that in following synthesis example 3, obtains
(a-4): poly-(the Mang ox oxygen base) siloxanes that in following synthesis example 3, obtains
＜(a ') composition (comparison of (a) composition) 〉
(a '-1): benzyl carbinol
(a '-2): cis-3-hexenol
(a '-4): Mang geraniol
(b) composition
(b1-1): estragole (logPow=3.1)
(b1-2): isonefolia (logPow=3.8)
(b1-3): benzyl salicylate (logPow=4.2)
(b2-1): Jiale muskiness (logPow=5.7)
(b2-2): tonalid (logPow=5.7)
(b3-1): cumarin (logPow=1.4)
(b3-2): eugenol (logPow=2.4)
(c) composition
(c1-1): utilize known method that N-(3-aminopropyl)-N-(2-ethoxy)-N-methylamine and curing tallow acid are carried out dehydrating condensation with 1/1.9 mol ratio, the reaction product that cessation reaction obtained when the content of fatty acid in reactant was 5 quality % is the compound of the amine shown in the following formula (3) that contains quality 95%.
(in the formula, R represents from solidifying the residue that tallow acid removes decarboxylate.)
Other composition
(d-1): at carbon number is the compound of the average 20 moles ethylene oxide of addition in 12 the saturated alcohols
(f-1): calcium chloride
(g-1): the dehydration condensation (content of the unreacted aliphatic acid in the dehydration condensation is 3 quality %) that solidifies 1 mole of 1.7 moles of tallow acids and glycerine
(h-1): ethanol
(i): organic silicon emulsion (Shin-Etsu Chemial Co., Ltd, KM-902 (emulsion of the dimethyl polysiloxane of 500,000 mm2/s))
Synthesis example 1: octyl group silicic acid three (2-phenethyl) ester [three (2-phenethyl oxygen) octyl group silane] synthetic
Add octyltri-ethoxysilane 83.01g (0.30mol), benzyl carbinol 127.76g (0.83mol), 2.8% methanol solution of sodium methylate 0.857mL in the four-hole boiling flask of 300mL, the limit is distilled under nitrogen current and is removed the ethanol limit 110～115 ℃ of stirrings 2.5 hours.2.5 after hour, slowly the groove internal pressure is dropped to 8kPa, the limit distillation is removed the ethanol limit and was further stirred 3 hours at 110～119 ℃.After cooling off, remove decompression after 3 hours, filter, obtain containing the faint yellow oily thing of the 173.61g of octyl group silicic acid three (2-phenethyl) ester.
Synthesis example 2: silicic acid four (cis-3-hexenyl) ester [four (cis-3-hexenyl oxygen) silane] synthetic
Add tetraethoxysilane 35.45g (0.17mol), cis-3-hexenol 64.74g (0.65mol), 2.8% methanol solution of sodium methylate 1.34mL in the four-hole boiling flask of 200mL, the limit is distilled under nitrogen current and is removed the ethanol limit 118～120 ℃ of stir abouts 2 hours.After 2 hours, slowly the pressure in the groove is dropped to 8kPa, the limit distillation is removed the ethanol limit and was further stirred 3 hours at 112～119 ℃.After 3 hours, cool off, remove decompression after, filter, obtain containing the Sandy grease of the 66.17g of four (cis-3-hexenyl oxygen) silane.
Synthesis example 3: gather the synthetic of (4-methoxybenzene ylmethoxy) siloxanes
In the four-hole boiling flask of 100mL, add tetraethoxysilane 72.96g and potassium hydroxide 0.24g, ion exchange water 0.4mL, under nitrogen current, carry out about 37 hours reaction with 120～125 ℃, 33kPa～101kPa (normal pressure).Append ion exchange water 0.4mL therebetween.After the reaction, after 33kPa further reacts 2 hours, cool off, filter, obtain the condensation product of the Ethoxysilane of 67.29g with weak yellow liquid.
Then, add above-mentioned tetraethoxysilane condensation product 25.00g and 4-methoxyphenyl methyl alcohol 56.39g, 4.8% sodium hydrate aqueous solution 0.17g in the four-hole boiling flask of 100mL, the limit distillation is removed the ethanol limit and was further stirred 2 hours at 95～119 ℃.After 2 hours, slowly the pressure in the groove is dropped to 8kPa, the limit distillation is removed the ethanol limit 116～119 ℃ of stirrings of carrying out 3 hours again.After 3 hours, cool off, remove decompression after, filter, obtain poly-(4-methoxybenzene ylmethoxy) siloxanes of 58.83g with faint yellow oily thing.
Synthesis example 4: gather the synthetic of (3,7-dimethyl-trans-2,6-octadienyl oxygen) siloxanes
In the four-hole boiling flask of 100mL, add tetraethoxysilane 72.96g and potassium hydroxide 0.24g, ion exchange water 0.4mL, under nitrogen current, carry out about 37 hours reaction with 120～125 ℃, 33kPa～101kPa (normal pressure).Append ion exchange water 0.4mL therebetween.After the reaction, after 33kPa further carries out reaction in 2 hours, cool off, filter, obtain the condensation product of the Ethoxysilane of 67.29g with weak yellow liquid.Then, in the four-hole boiling flask of 100mL, add tetraethoxysilane condensation product 25.00g and 3,7-dimethyl-trans-2,6-octadiene-1-alcohol (Mang geraniol) 62.95g, 4.8% sodium hydrate aqueous solution 0.17g, the limit distillation is removed the ethanol limit 97～121 ℃ of stirrings of carrying out 2 hours.After 2 hours, slowly the pressure in the groove is dropped to 8kPa, the limit distillation is removed the ethanol limit 118～121 ℃ of stirrings of carrying out 3 hours again.After 3 hours, cool off, remove decompression after, filter, obtain poly-(3,7-dimethyl-trans-2,6-octadienyl oxygen) siloxanes of 65.36g with faint yellow oily thing.
Embodiment 1～3 and comparative example 1～4
Use the gradation composition shown in the table 1 in the ratio shown in the table 1, make that final fabric treating agent composition is 300g, utilize the fabric treating agent composition of forming shown in the following method preparation table 1 1～4.
The compound method of＜fabric treating agent composition 〉
The 95 quality % ion exchange waters that add aequum in glass beaker stirring vane, 500mL of the Scroll-type blade that to be provided with three every leaf length be 2.5cm of the position than the high 1cm in beaker bottom surface utilize warming-in-water to 62 ℃.(d) composition that dissolving is added on the limit is stirred with 500rpm in the limit.Then, with (c) composition, (g) composition and (h) composition carry out premixed, be added on the premix of 70 ℃ of following fusions.Add 35% aqueous hydrochloric acid solution and/or 48% sodium hydrate aqueous solution of the aequum be used to obtain regulation pH then, stirs after 5 minutes, be cooled to 30 ℃ with 5 ℃ water-baths, interpolation (f) composition is gone forward side by side and one is gone on foot the mixing of carrying out 5 minutes.And interpolation (a) composition and (b) composition are while stirring reaffirmed pH at last, use 35% aqueous hydrochloric acid solution and/or 48% sodium hydrate aqueous solution as required, regulate pH.In the composition of table 1, (c1-1) nearly all be present in the composition with the state of hydrochloride.Wherein, the numerical value of (c1-1) is himself use level of (active ingredient) in the table 1.
[table 1]
The fabric treating agent composition that use obtains by said method is handled fibre with following method, measures the spices adsorption rate.The results are shown in table 2.
The processing of＜use fabric treating agent composition and the assay method of spices adsorption rate 〉
(1) pre-treatment
At first, use commercially available alkalescent remover (Kao Corp produces Attack), with the automatic washing machine NW-6CY of Hitachi 24 cotton towels are cleaned 5 times repeatedly, removed unnecessary medicament (remover concentration 0.0667 quality %, use 47L running water, 20 ℃ of water temperatures, clean 10 minutes, rinse and wash 2 times) by indoor seasoning.
(2) composition is to the processing of fibre
In the electronic bucket of National N-BK2-A, inject the 5L running water, with the ratio dissolving fabric treating agent composition (handling the preparation of bathing) of 10g/ clothing 1.0kg, will use said method to carry out 2 cotton towel dippings 5 minutes of pre-treatment and carry out stir process.Afterwards, used home-use double-cylinder type laundry machine dehydration 1 minute.
Adsorption rate about spices, flavour content (x) during processing before handling bathed with handle after poor [(x)-(y)] of flavour content (y) as the amount that is adsorbed on the towel, with its with respect to the ratio (percentage) of handling preceding flavour content (x) promptly [(x)-(y)]/(x) * 100 as the spices adsorption rate.It the results are shown in table 2.Wherein, the test of handling front and back uses following liquid-chromatography apparatus to measure with the flavour content in the treatment fluid.
Liquid-chromatography apparatus: the L-6000 of Hitachi
Post: Lichrospher 100 RP-18 (e) 5 μ m 125mm * 4 Φ
Column temperature: 40 ℃
Eluant, eluent: the mixed solution of acetonitrile/water=7/3 (mass ratio)
Flow velocity: 1.0mL/min
Detector: UV (220nm)
[table 2]
Embodiment 4
Use the spices of forming shown in the table 3 1～3, the fabric treating agent composition of forming shown in preparation table 4～6.The fabric treating agent composition that use obtains carries out soft treatment equally to the cotton towel that uses the method identical with embodiment 1 to carry out after the pre-treatment.With the cotton towel after handling under 25 ℃, the condition of 40%RH dry 24 hours, carry out the sense organ comparative evaluation of fragrance retention.To answer the evaluation member's stronger number (/ 10) expression sensory evaluation result than the fragrance of the composition of mismatching (a) composition (blank 1).In addition, the perfume phenylethanol that uses when synthesizing (a-1) composition for interpolation replaces the composition (blank 2) of (a) composition, carries out same aroma strength evaluation, its result of expression in table 4.
[table 3]
[table 4]
[table 5]
[table 6]
By above result as can be known, by cooperating (a) composition, (b1) adsorption rate of composition is improved, and also can confirm its fragrance retention in the sensory evaluation.
Embodiment 5, comparative example 5
Use the gradation composition shown in the table 7 in the ratio shown in the table 7, make that final fabric treating agent composition is 300g, with the fabric treating agent composition 10 and 11 of embodiment 1～3 and comparative example 1～4 same preparation composition.The fabric treating agent composition that adopts above-mentioned processing method use to obtain is handled fibre, carries out the sensory evaluation of dry and fragrance retention with following method.
＜drying means 〉
Processing method 1: the cotton towel that will use said method to handle is used National scrubbing-and-drying unit NH-D502 (68 ℃ of dry built-in temperatures) heat treated 2 hours, thereafter, is suspended in the thermostatic chamber of 20 ℃/60%RH on the suspension bracket and places 22 hours.
Processing method 2: do not use scrubbing-and-drying unit, the cotton towel that uses said method to handle is suspended in the thermostatic chamber of 20 ℃/60%RH on the suspension bracket placed 24 hours.
The sensory evaluation of＜fragrance retention 〉
To using above-mentioned processing method 1 processing of scrubbing-and-drying unit (use) to carry out the cotton towel after the heat treated and using processing method 2 (without the processing of scrubbing-and-drying unit, air dry) cotton towel after handling, the evaluation group by 10 people carries out sensory evaluation to fragrance retention.Evaluation result is represented with the number of answering the strong evaluation member of aroma strength.The results are shown in table 7.
[table 7]
Embodiment 6 and comparative example 6
Use the gradation composition shown in the table 8 in the ratio shown in the table 8, make that final fabric treating agent composition is 300g, the fabric treating agent composition 12～15 that uses following compound method preparation to form.With the fabric treating agent composition that the vial storage obtains, in 40 ℃ insulating box, preserve after 1 month, use following method to handle fibre, measure the adsorption rate of (b1-3) composition by said method to fibre.The results are shown in table 8.
(1) compound method of fabric treating agent composition
The 95 quality % ion exchange waters that add aequum in glass beaker stirring vane, 500mL of the Scroll-type blade that to be provided with three every leaf length be 2.5cm of the position than the high 1cm in beaker bottom surface utilize warming-in-water to 62 ℃.(d) composition that dissolving is added on the limit is stirred with 500rpm in the limit.Then, with (c) composition, (g) composition and (h) composition carry out premixed, be added on the premix of 70 ℃ of following fusions.Add 35% aqueous hydrochloric acid solution and/or 48% sodium hydrate aqueous solution of the aequum be used to obtain regulation pH then, stirs after 5 minutes, be cooled to 30 ℃ with 5 ℃ water-baths, interpolation (f) composition is gone forward side by side and one is gone on foot the stirring of carrying out 5 minutes.And, add (a) composition (b) composition while stirring, stirred 5 minutes.When containing (i) composition, add and stirred 5 minutes in this in stage.Reaffirm pH at last, use 35% aqueous hydrochloric acid solution and/or 48% sodium hydrate aqueous solution to regulate pH as required.In the composition of table 8, (c1-1) nearly all be present in the composition with the state of hydrochloride.Wherein, the numerical value of (c1-1) is himself use level of (active ingredient) in the table 8.
(2) pre-treatment
At first, use commercially available alkalescent remover (Kao Corp produces Attack), (45cm * 70cm) cleans 5 times repeatedly, removes unnecessary medicament (remover concentration 0.0667 quality %, use 47L running water, 20 ℃ of water temperatures, clean 10 minutes, rinse and wash 2 times) by indoor seasoning with 24 cotton knitwear with the automatic washing machine NW-6CY of Hitachi.
(3) composition is to the processing of fibre
In the electronic bucket of National N-BK2-A, inject the 5L running water, with the ratio of 10g/ clothing 1.0kg dissolving fabric treating agent composition (handling the preparation of bathing), 2 cotton knitwear dippings that use above-mentioned method to carry out after the pre-treatment were handled in 5 minutes.
[table 8]
Claims (3)
1. fabric treating agent composition is characterized in that:
Contain following (a) composition and (b1) composition with the mass ratio of composition=98/2～20/80 of (a) composition/(b1), wherein,
(a) be the compound shown in the general formula (1),
In the formula, X is-OH ,-R1 or-OR2, Y be X or-OSi (X) 3, n is 0～15 a number of expression mean value, and a plurality of X and Y can be the same or different respectively, but have 1-OR2 at least in a molecule, wherein, R1 is that can to have phenyl, hydroxyl or alkoxyl be 1～22 aliphatic alkyl as substituent total carbon atom number, and R2 is that carbon number is 6～22 alkyl
(b1) be that logPow is the spices more than 3.0, below 5.0.
2. one kind by being that medium makes the described fabric treating agent composition of claim 1 contact fibre promote the method for (b1) composition to fibre absorption with water.
3. fiber product processing method is characterized in that:
Give fibre with fragrance by after carrying out the following A operation, carrying out the B operation, perhaps by carrying out the A operation simultaneously and the B operation is given fibre with fragrance,
The A operation: the operation of using the described fabric treating agent composition of claim 1 that fibre is handled,
B operation: the operation of fibre being carried out heat treated.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008104416A JP5557986B2 (en) | 2008-04-14 | 2008-04-14 | Textile treatment composition |
| JP2008-104416 | 2008-04-14 | ||
| PCT/JP2009/057803 WO2009128549A1 (en) | 2008-04-14 | 2009-04-13 | Textile treatment agent composition |
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| CN101999018A true CN101999018A (en) | 2011-03-30 |
| CN101999018B CN101999018B (en) | 2013-02-13 |
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| CN200980112924.8A Expired - Fee Related CN101999018B (en) | 2008-04-14 | 2009-04-13 | Textile treatment agent composition |
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| Country | Link |
|---|---|
| US (1) | US20110016636A1 (en) |
| EP (1) | EP2267217A4 (en) |
| JP (1) | JP5557986B2 (en) |
| CN (1) | CN101999018B (en) |
| MX (1) | MX2010011127A (en) |
| WO (1) | WO2009128549A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105163715A (en) * | 2013-05-10 | 2015-12-16 | 宝洁公司 | Consumer products comprising silane-modified oils |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JP5297978B2 (en) * | 2008-10-30 | 2013-09-25 | 花王株式会社 | Textile treatment composition |
| JP5580027B2 (en) * | 2009-12-11 | 2014-08-27 | 花王株式会社 | Liquid bleach composition |
| JP5455606B2 (en) * | 2009-12-21 | 2014-03-26 | 花王株式会社 | Textile treatment composition |
| JP5502535B2 (en) * | 2010-03-16 | 2014-05-28 | 花王株式会社 | Liquid detergent composition |
| JP5530797B2 (en) * | 2010-05-10 | 2014-06-25 | 花王株式会社 | How to process clothing |
| US20130139327A1 (en) * | 2010-08-03 | 2013-06-06 | Henkel Ag & Co. Kgaa | Textile treatment composition for removal of deodorant stains |
| JP5604220B2 (en) * | 2010-08-19 | 2014-10-08 | 花王株式会社 | Textile treatment composition |
| JP5792562B2 (en) * | 2011-08-26 | 2015-10-14 | 花王株式会社 | Liquid air freshener composition for spraying |
| JP5714450B2 (en) * | 2011-08-26 | 2015-05-07 | 花王株式会社 | Liquid air freshener composition for spraying |
| US9951303B2 (en) * | 2012-10-02 | 2018-04-24 | Robertet, Inc. | Compositions for grafting fragrance substances |
| JP6131042B2 (en) * | 2012-12-21 | 2017-05-17 | 花王株式会社 | Silicate ester composition |
| BR112017009277A2 (en) * | 2014-11-14 | 2017-12-19 | Procter & Gamble | silicone compounds |
| JP7326047B2 (en) * | 2018-08-07 | 2023-08-15 | 花王株式会社 | Liquid softener composition |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
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| IT1100671B (en) | 1977-10-15 | 1985-09-28 | Dow Corning Ltd | DETERGENT COMPOSITIONS |
| NL8000387A (en) | 1979-02-01 | 1980-08-05 | Dow Corning | PREPARATION WITH ANTI-TRANSPIRATION AND / OR DEODORANT PROPERTIES. |
| JP3274940B2 (en) * | 1994-10-12 | 2002-04-15 | 花王株式会社 | Liquid softener composition |
| DE10012949A1 (en) * | 2000-03-16 | 2001-09-27 | Henkel Kgaa | Mixtures of cyclic and linear silicic esters of lower alcohols and fragrance and/or biocide alcohols are used as fragrance and/or biocide in liquid or solid laundry and other detergents and in skin and hair cosmetics |
| WO2001094521A1 (en) * | 2000-06-05 | 2001-12-13 | The Procter & Gamble Company | Fabric care compositions and systems for delivering clean, fresh scent in a lipophilic fluid treatment process |
| US6670317B2 (en) * | 2000-06-05 | 2003-12-30 | Procter & Gamble Company | Fabric care compositions and systems for delivering clean, fresh scent in a lipophilic fluid treatment process |
| JP4602229B2 (en) * | 2005-10-31 | 2010-12-22 | 花王株式会社 | Textile treatment composition |
| JP4647483B2 (en) * | 2005-12-27 | 2011-03-09 | 花王株式会社 | Softener composition |
| JP4879654B2 (en) * | 2006-05-26 | 2012-02-22 | 花王株式会社 | Liquid detergent composition |
| JP5036254B2 (en) * | 2006-09-06 | 2012-09-26 | ライオン株式会社 | Emulsion type liquid softener composition |
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2008
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- 2009-04-13 EP EP09731996A patent/EP2267217A4/en not_active Withdrawn
- 2009-04-13 CN CN200980112924.8A patent/CN101999018B/en not_active Expired - Fee Related
- 2009-04-13 US US12/933,798 patent/US20110016636A1/en not_active Abandoned
- 2009-04-13 WO PCT/JP2009/057803 patent/WO2009128549A1/en active Application Filing
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105163715A (en) * | 2013-05-10 | 2015-12-16 | 宝洁公司 | Consumer products comprising silane-modified oils |
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| JP5557986B2 (en) | 2014-07-23 |
| JP2009256818A (en) | 2009-11-05 |
| MX2010011127A (en) | 2010-11-12 |
| WO2009128549A1 (en) | 2009-10-22 |
| EP2267217A4 (en) | 2013-01-23 |
| EP2267217A1 (en) | 2010-12-29 |
| CN101999018B (en) | 2013-02-13 |
| US20110016636A1 (en) | 2011-01-27 |
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