CN107683325A - Dress material liquid ceanser compositions - Google Patents
Dress material liquid ceanser compositions Download PDFInfo
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- CN107683325A CN107683325A CN201680033884.8A CN201680033884A CN107683325A CN 107683325 A CN107683325 A CN 107683325A CN 201680033884 A CN201680033884 A CN 201680033884A CN 107683325 A CN107683325 A CN 107683325A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/08—Liquid soap, e.g. for dispensers; capsuled
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
Abstract
The present invention relates to a kind of dress material liquid ceanser compositions, its contain the specific anion surfactant as (A) composition, as (B) composition specific structure quaternary ammonium salt, the polybasic carboxylic acid as (C) composition or its salt, the nonionic surfactant and water with the specific averagely oxirane of addition molal quantity as (D) composition, [content of (D) composition]/[content of the content of (A) composition+(B) composition] (mass ratio) is less than more than 0.1 0.4.
Description
Technical field
The present invention relates to a kind of dress material liquid ceanser compositions.
Background technology
With the rise of the health consciousness of raw reviver, the care of stink or bacterium to dress material also begins to raise.It is known to have
Adhere to skin resident bacteria or the various bacteriums being present in environment on dress material and bred.It is dried due to after washing
The dress material worn when the undried dress material of journey or sweating more contains moisture, it is therefore contemplated that in bacterium with propagation and
The discharge quantitative change of metabolin is more, it is easier to produces stink.
As the method for the propagation for the bacterium for suppressing to be attached on dress material, such as such as Japanese Unexamined Patent Publication 2011-246585 public affairs
Report is such, discloses containing the nonionic surfactant as main wash composition and as display for undried smelly eliminating
The liquid ceanser compositions of the quaternary ammonium salt of the alkyl with a carbon number 6~22 of main dose of effect.In addition, in day
In this Unexamined Patent 11-43405 publications, disclose and used containing the low irritant fiber using organic carboxyl acid as the quaternary ammonium salt to ion
Antibacterial working process agent.
On the other hand, in the case where cleaning is attached with the dress material of dirt, according to utilizing dress material cleansing composition
In contained surfactant, after dirt departs from from dress material, dirt is attached to the problem of the recontamination of dress material again again, deposits
It is being not likely to produce the problem of cleaning.It is known to have in surfactant, compared with nonionic surfactant, anionic surface
One side of activating agent, the problem of recontamination are few.
However, it is known that there is bactericidal action caused by the cationic surfactants such as quaternary ammonium salt with anion surfactant
To be reduced in the composition of principal component.In Japanese Unexamined Patent Publication 7-53995 publications, a kind of sterilizing cleaning agent combination is disclosed
Thing, it contains cation system bactericide, more than 0.5 times mole of metal-chelator of the bactericide and non-ionic surface
Activating agent and/or amphoteric surfactant, in the composition containing anion surfactant, bactericidal effect does not reduce.
There is a kind of structuring heavy-filth liquid washing detergent composition disclosed in Japanese Kohyo 11-512768 publications, it contains alkyl
The anion surfactants such as polyethoxy sulfuric ester, quaternary surfactant, the anion surfactant and quaternary ammonium salt
Surfactant forms liquid crystal particle.
The content of the invention
In the presence of following problem：Even if the dress material that the dirts such as sebum dirt are attached with after dress is washed, clothing is attached to
Dirt or bacterium on material are also not exclusively fallen.
The dirts such as the sebum residued on dress material are metabolized by the bacterium residued on dress material, discharge smelly metabolin
And stink is produced, thus, the problem that stink is produced by the dress material after wearing 1 day also be present.In order to suppress to be present on dress material
The propagation of bacterium, even if using quaternary ammonium salt, the leeway improved yet be present.
In addition, the present inventor etc. has found：In the dress material liquid ceanser compositions containing anion surfactant
During using cationic surfactant and specific chelating agent, storage stability be present reduces, especially by the guarantor under high temperature
Deposit and produce the separation of composition or fuzzy problem.
From the aspect of easy to use, form is the ratio of the dress material liquid ceanser compositions of liquid in cleaning agent
Market in increase.Therefore, in fluid composition, it is expected solve described problem.
The present invention provides a kind of dress material to dress material endowing antibacterial, excellent storage stability and combined with liquid ceanser
Thing.
The present invention relates to a kind of dress material liquid ceanser compositions, wherein, contain following more than mass % of (A) composition 10
Below 16 mass %, below the mass % of more than the mass % of (B) composition 13, below the mass % of more than the mass % of (C) composition 28, (D)
Composition and water,
The mass ratio of [content of (D) composition]/[content of the content of (A) composition+(B) composition] be more than 0.1 0.4 with
Under.
(A) composition：Anion surfactant represented by following formulas (1),
RO-(C2H4O)mSO3 -·M+ (1)
[in formula, R is alkyl of the carbon number below more than 10 16, and m represents average addition molal quantity, and is more than 14
Following number, M+For cation.]
(B) composition：Quaternary ammonium compound represented by following formulas (2),
[in formula, R1For aliphatic alkyl of the carbon number below more than 12 16, R2、R3And R4It is separately selected from first
Group in base, ethyl and hydroxyethyl, X-For anion.]
(C) composition：Carbon number is below more than 46 and less than more than 2 yuan 4 yuan of polybasic carboxylic acid or its salt,
(D) composition：Nonionic surfactant represented by following formulas (3),
R5O-(C2H4O)nH (3)
[in formula, R5For alkyl of the carbon number below more than 12 16, n represents average addition molal quantity, and is more than 10
Less than 40 number.]
According to the present invention, there is provided a kind of to dress material endowing antibacterial, the dress material liquid ceanser of excellent storage stability
Composition.
According to the present invention, there is provided a kind of dress material liquid ceanser compositions, its cleaning and antibacterial by assigning dress material
Property two kinds of functions, the dress material for being attached with dirt is washed, not only can effectively suppress in drying caused by it is not dry
Saturating stink, and can effectively suppress the caused stink during dress material after dress is dried.
Embodiment
Dress material liquid ceanser compositions of the present invention can be by the anion surfactant of (A) composition and (B) composition
Quaternary ammonium compound coexist, therefore, cleaning performance and anti-microbial property can be had both.In addition, in order to show sufficient antibacterial
The concentration of effect stably coordinates the quaternary ammonium compound of (B) composition etc, it is necessary to which storage stability develops skill.In the present invention
In, find：By coordinate (D) composition ethyleneoxy average addition molal quantity more than nonionic surfactant, Ke Yishi
The raising of existing storage stability.
Dress material of the present invention is to include the anion surfactant as (A) composition, conduct by the use of liquid ceanser compositions
(B) cationic surfactant of composition, the polybasic carboxylic acid as (C) composition, the oxirane as (D) composition have specific
The nonionic surfactant of average addition molal quantity and the composition of water.In general, in water (A) composition and (B) into
When point coexisting, complex is formed, cleaning, antibiotic property can be lost.But as the present invention in (B) composition and (C) composition
Coexisting under, (B) composition compared with (A) composition, easily with (C) composition formed complex, it is therefore contemplated that suppress (A) composition and
(B) formation of the complex of composition, cleaning action caused by (A) composition can be maintained and assigned caused by (B) composition to dress material
Antibacterial effect effect.Shown in its embodiment as be described hereinafter, from the aspect of anti-microbial property rise, (C) composition is also supported
Use level is more.
In addition, the inventors discovered that：By cooperation (D) composition, the storage stability under storage stability, special high temperature carries
It is high.Whether it is speculated because even if forming the complex of (A) composition and (B) composition, being also ingested in (A) composition and (D) composition
Mixed micelle, thus carry out solubilising.
[(A) composition]
(A) composition is the anion surfactant represented by following formulas (1).(A) there is composition cleaning to be attached to clothing
The effect of dirt or various bacterium on material.
RO-(C2H4O)mSO3 -·M+ (1)
[in formula, R is that alkyl, m of the carbon number below more than 10 16 represent average addition molal quantity, and is more than 14
Following number, M+For cation.]
In formula (1), R is alkyl of the carbon number below more than 10 16, in terms of further the cleaning of dress material is improved
Consider, preferably comprise alkyl of the carbon number below more than 12 14.From the cleaning and storage stability side that can maintain dress material
Face considers, the ratio of alkyl of the carbon number in total R that (A) composition has below more than 12 14 be preferably 60 mass % with
On, more preferably more than 70 mass %, also, it is preferred that being below 100 mass %.The ratio can be 100 mass %.That is, (A)
In composition, from the aspect of the cleaning and storage stability that can maintain dress material, R is hydrocarbon of the carbon number below more than 12 14
The ratio of the anion surfactant of base is preferably more than 60 mass %, more preferably more than 70 mass %, also, it is preferred that being
Below 100 mass %.The ratio can be 100 mass %.
As R alkyl, alkyl, alkenyl, preferably alkyl, more preferably primary alkyl can be enumerated, it is more preferably straight
Chain primary alkyl.
In formula (1), from the aspect of the difficulty of complex is formed with (B) composition, m average addition molal quantity for 1 with
On, preferably more than 1.2, more preferably more than 1.4, more preferably more than 1.6.From the viewpoint of cleaning, m's is flat
Equal addition molal quantity is less than 4, preferably less than 3, more preferably less than 2.5.
In formula (1), M+For cation, the metal ion of 1 valency, the metal ion of divalent and carbon number 2 are preferably selected from
More than a kind of ion in alkanolammonium of the above below 6.
As the metal ion of 1 valency, such as potassium ion, sodium ion can be enumerated.As the metal ion of divalent, example can be enumerated
Such as magnesium ion.As alkanolammonium of the carbon number below more than 26, can enumerate monoethanol ammonium ion, diethanol ammonium from
Son, N- methyl ethanols ammonium ion, N- methyl diethanols ammonium ion, triethanol ammonium ion.
[(B) composition]
(B) composition is the quaternary ammonium compound represented by following formulas (2).Dress material liquid of the present invention containing (B) composition
Cleansing composition can be to dress material endowing antibacterial.
[in formula, R1For aliphatic alkyl of the carbon number below more than 12 16, R2、R3And R4It is separately selected from first
Group in base, ethyl and hydroxyethyl, X-For anion.]
From the outward appearance of dress material liquid ceanser compositions of the present invention easily becomes transparent, storage stability is also excellent in addition
From the viewpoint of, R1The carbon number of aliphatic alkyl be carbon number below 16, preferably less than 14, more preferably 12.
From the viewpoint of residual from (B) composition to cloth, R1For carbon number more than 12, preferably more than 14, more preferably 16.
R1Aliphatic alkyl can enumerate alkyl, alkenyl, preferably alkyl, more preferably primary alkyl, more preferably
Straight chain primary alkyl.
As the aliphatic alkyl of carbon number 12, lauryl can be enumerated., can as the aliphatic alkyl of carbon number 14
Enumerate myristyl.As the aliphatic alkyl of carbon number 16, palmityl or palm oil-base (palmitoleyl) can be enumerated.
Storage stability at a high temperature of dress material liquid ceanser compositions of the present invention becomes better aspect, this hair
Bright dress material preferably comprises following (b1) compositions by the use of liquid ceanser compositions and (b2) composition is used as (B) composition.
(b1) composition：R in formula (2)1For the quaternary ammonium compound of the aliphatic alkyl of carbon number 12.
(b2) composition：R in formula (2)1For the quaternary ammonium compound and formula of the aliphatic alkyl of carbon number 14
(2) R in1For more than a kind of compound in the quaternary ammonium compound of the aliphatic alkyl of carbon number 16.
Maintaining to become good aspect to the storage stability under the effect and high temperature of dress material endowing antibacterial, (b2)
The preferred R of composition1For the quaternary ammonium compound of the aliphatic alkyl of carbon number 16.
Dress material liquid ceanser compositions of the present invention contain (b1) composition and (b2) composition as the situation of (b) composition
Under, maintain good aspect is become to the storage stability under the effect and high temperature of dress material endowing antibacterial, (b1) composition and
(b2) content ratio of composition is in terms of the mass ratio of [content of (b2) composition]/[content of (b1) composition], preferably 1/99 with
Upper less than 90/10.Storage stability at high temperature becomes better aspect, and the mass ratio is more preferably more than 2/98, entered
One step is preferably more than 3/97, is still more preferably more than 4/96, is still more preferably more than 5/95, still more preferably
It is still more preferably more than 15/85 for more than 10/90, moreover, more preferably less than 85/15, it is still more preferably 80/
Less than 20.
In formula (2), R2、R3And R4It is separately the group in methyl, ethyl and hydroxyethyl.R2、R3And
R4It is respectively preferably methyl.
In formula (2), X-For anion, from the aspect of the easiness obtained of raw material, can enumerate selected from halogen ion and
More than a kind of anion in alkyl sulfate ion of the carbon number below more than 13.As halogen ion, can enumerate selected from chlorine
More than a kind of anion in compound ion and bromide ion.As alkyl sulfate of the carbon number below more than 13 from
Son, more than a kind of the anion that can be enumerated in methyl sulfate and ethyl sulfuric acid radical ion.(B) composition of the invention
One kind or two or more quaternary ammonium compound can be used together and use.
[(C) composition]
(C) composition is carbon number below more than 46 and less than more than 2 yuan 4 yuan of polybasic carboxylic acid or its salt.In the present invention,
Think preferentially to form complex with (B) composition in water by (C) composition, suppress the compound bodily form of (A) composition and (B) composition
Into maintaining showing for the cleaning from (A) composition and antibiotic property from (B) composition.
From the viewpoint of it can maintain the antibacterial effect caused by (B) composition to dress material, (C) composition is preferably 3 yuan
Polybasic carboxylic acid or its salt.
(C) composition is preferably selected from the more of more than a kind in butanedioic acid, malic acid, tartaric acid, citric acid and their salt
First carboxylic acid or its salt.
(C) composition is more preferably citric acid or its salt.
(C) salt of the polybasic carboxylic acid of composition can enumerate the alkali metal such as sodium salt, sylvite.
(C) composition can be with the carboxylic acid group of less than more than 24 be the compound of acid type and be salt form compound
Coexist.
[(D) composition]
(D) composition is the nonionic surfactant represented by following formulas (3).
R5O-(C2H4O)nH (3)
[in formula, R5For alkyl of the carbon number below more than 12 16, n represents average addition molal quantity, and is more than 10
Less than 40 number.]
(D) composition in the present invention not only improves cleaning force, moreover, improving dress material liquid ceanser compositions of the present invention
At a high temperature of storage stability.(A) guarantor of the complex that composition and (B) composition are formed in preservation, especially at high temperature
In depositing, have the tendency of to separate out and separate in the composition.But in the present invention, by using (D) composition in (A) composition
And in the mixed micelle of (D) composition, the complex that (A) composition and (B) composition are formed is ingested, and thus speculates the preservation of composition
Stability be able to should improve.
In formula (3), R5For alkyl of the carbon number below more than 12 16.
R5Alkyl can enumerate alkyl, alkenyl, preferably alkyl, more preferably primary alkyl, more preferably linear primary
Alkyl.In addition, R5Alkyl can enumerate the aliphatic of the aliphatic alkyl of straight chain or the aliphatic alkyl of side chain, preferably straight chain
Alkyl.
In terms of the imparting for maintaining the antibacterial effect caused by (B) composition to clothing and more improving storage stability,
R5Preferably straight chained alkyl, more than a kind of the group more preferably in lauryl and myristyl.
From the aspect of the raising of the storage stability at a high temperature of dress material liquid ceanser compositions of the present invention, (D)
Total R that composition has5In the ratio of alkyl of the carbon number below more than 12 14 be preferably more than 60 mass %, more preferably
More than 70 mass %, it is still more preferably more than 80 mass %, also, it is preferred that being below 100 mass %.The ratio can be
100 mass %.That is, in (D) composition, from the storage stability at a high temperature of dress material liquid ceanser compositions of the present invention
From the aspect of raising, R5Ratio for the nonionic surfactant of alkyl of the carbon number below more than 12 14 is preferably 60 matter
More than % is measured, is still more preferably more than 80 mass % more preferably more than 70 mass %, also, it is preferred that being 100 mass %
Below.The ratio can be 100 mass %.
Dress material of the present invention is preferably comprised selected from R with liquid ceanser compositions5For the nonionic of the alkyl of carbon number 12
Surfactant and R5Lived for more than a kind of non-ionic surface in the nonionic surfactant of the alkyl of carbon number 14
Property agent be used as (D) composition.
Dress material of the present invention preferably comprises R with liquid ceanser compositions5For the non-ionic surface of the alkyl of carbon number 12
Activating agent and R5Nonionic surfactant for the alkyl of carbon number 14 is used as (D) composition.In this case, (R5It is former for carbon
The content of the nonionic surfactant of the alkyl of subnumber 12)/(R5For the nonionic surfactant of the alkyl of carbon number 14
Content) mass ratio be preferably more than 40/60, more preferably more than 50/50, be still more preferably more than 55/45, and
And preferably less than 100, i.e. less than 100/1, more preferably less than 98/2.
In formula (3), n represents the average addition molal quantity of oxirane, is less than more than 10 40 number.From further carrying
From the viewpoint of high storage stability, n is preferably more than 12, more preferably more than 13, more preferably more than 15, more enters one
Step is preferably more than 16, is still more preferably more than 18, is still more preferably more than 20, also, it is preferred that being less than 35.
[water]
Water can enumerate ion exchange water, the ion exchange water containing below hypochlorite 0.1mg/kg above 5mg/kg, from
Water etc..
[composition, any condition etc.]
Dress material liquid ceanser compositions of the present invention contain described (A) composition, (B) composition, (C) composition, (D) composition
And water.
From the viewpoint of the viewpoint for the cleaning for improving the dirt being attached on dress material or bacterium and storage stability, this
Invention dress material liquid ceanser compositions contain more than the mass % of (A) composition 10 below 16 mass %.The just content of (A) composition
For, from it is described it is same from the viewpoint of, in the composition, preferably more than 11 mass %.Moreover, the content with regard to (A) composition
For, from the viewpoint of it can maintain the antibacterial effect of dress material caused by (B) composition, in the composition, preferably 15 matter
Below % is measured, more preferably below 14 mass %.
In the present invention, the content of (A) composition is set to by by M+Cation be scaled Na+Quality and the value that calculates.That is,
(A) content of composition is set to the value by being scaled the quality of sodium salt and calculating.
Dress material cleansing composition of the present invention contains more than the mass % of (B) composition 1 below 3 mass %.With regard to (B) composition
For content, from the aspect of the further imparting ability improved to the antibiotic property of dress material, in the composition, preferably 1.5 matter
More than % is measured, more preferably more than 2 mass %.Moreover, for the content of (B) composition, from raising dress material liquid ceanser
From the aspect of the storage stability of composition, in the composition, preferably below 2.9 mass %, more preferably 2.8 mass % with
Under, it is still more preferably below 2.6 mass % more preferably below 2.7 mass %.
Dress material cleansing composition of the present invention contains more than the mass % of (C) composition 2 below 8 mass %.With regard to (C) composition
For content, formed from the complex for suppressing (A) composition in water and (B) composition, can more improve the antibiotic property of dress material
From the aspect of, in the composition, preferably more than 2.5 mass %, more preferably more than 3 mass %, more preferably 3.5 matter
More than % is measured, is still more preferably more than 4 mass %, is still more preferably more than 4.5 mass %, also, it is preferred that being 7 matter
Below % is measured, is still more preferably 5.5 matter more preferably below 6 mass % more preferably below 6.5 mass %
Measure below %.
For dress material cleansing composition of the present invention, as the content of (D) composition and the content and (B) of (A) composition
The mass ratio of the total amount of the content of composition, [content of (D) composition]/[content of the content of (A) composition+(B) composition] are
Less than more than 0.1 0.4.
By by (A) composition and (B) composition dress material with the complex formed in liquid ceanser compositions take in
(D) in the micella that composition is formed and in terms of can more improving storage stability, [content of (D) composition]/[(A) composition contains
The content of amount+(B) composition] mass ratio be preferably more than 0.11, more preferably more than 0.12, and preferably less than 0.35,
More preferably less than 0.3, more preferably less than 0.25, it is still more preferably less than 0.2.
For dress material liquid ceanser compositions, from assigning higher antibiotic property to dress material and can more improve
From the viewpoint of storage stability, as (B) composition content and (A) composition content it is mass ratio, [(B) composition contains
Amount]/[content of (A) composition] be preferably less than more than 0.05 0.3.
From the viewpoint of can assign higher antibiotic property to dress material, [content of (B) composition]/[(A) composition contains
Amount] mass ratio be preferably more than 0.06, more preferably more than 0.07, be still more preferably more than 0.08, more enter one
Step is preferably more than 0.09, is still more preferably more than 1.0.Moreover, go out from the viewpoint that can more improve storage stability
Hair, the mass ratio of [content of (B) composition]/[content of (A) composition] is preferably less than 0.25, and more preferably less than 0.23, enter
One step is preferably less than 0.2, is still more preferably less than 0.19, is still more preferably less than 0.18.
The content of water is total amount as 100 mass % of the content of (A)~(D) composition and any condition.Handling
Easiness in terms of, in the composition, the content of water is preferably more than 60 mass %, more preferably more than 65 mass %, is more entered
One step is preferably more than 70 mass %.
For dress material liquid ceanser compositions of the present invention, from by the dress material liquid ceanser containing (B) composition
From the viewpoint of stink caused by composition suppresses, the pH at preferably 20 DEG C is less than more than 27.
From the viewpoint of the easiness of pH regulations for utilizing (C) composition, the pH is preferably less than 6.8, and more preferably 6.5
Hereinafter, more preferably less than 6, also, it is preferred that be more than 3, more preferably more than 3.5, more preferably more than 4.
The pH is specifically measured with following method.The pH electrodes of following method are glass electrode.
＜ pH assay method ＞
The pH electrodes (model 6367) that hole field is made to made pH meter D-52 use phthalate buffer in advance
(pH4.01), phosphate standard liquid (pH6.84), borate titer (pH9.18) correction, are fully rinsed with ion exchange water.
In the dress material liquid ceanser compositions for being 20 DEG C by temperature adjustment, it is put into and correction, the pH of cleaning has been made as above
Electrode, using the AUTO HOLD patterns of pH meter, determining to measured value turns into certain.
The outward appearance of dress material liquid ceanser compositions of the present invention is also excellent.Dress material liquid ceanser compositions of the present invention
There can be transparent outward appearance.Here, transparent can be to observe not seeing fuzzy state by visual observation.It is and then just transparent
For, in ultraviolet-uisible spectrophotometer, dress material liquid rinse of the present invention is put into a length of 1cm of light path glass system groove
Agent composition, in compareing side channel using the transmitance in when having ion exchange water, 660nm wavelength can be set to 90% with
On.A digital high side for transmitance is more transparent, for more preferably outward appearance.If by (A)~(D) composition of the invention and water with into
For present invention provide that the mode of content mixed, then can obtain the composition of appearance transparent.
In fluid present invention cleansing composition, as (E) composition, pH adjusting agent can be contained.As (E) composition,
More than a kind of the pH regulations that can be enumerated in alkanolamine below more than 26 of sodium hydroxide, potassium hydroxide and carbon number
Agent.As alkanolamine of the carbon number below more than 26, MEA, diethanol amine, methyl diethanolamine, diformazan can be enumerated
Ethylethanolamine, triethanolamine.The content of pH adjusting agent can use the amount as described pH.
, can be with order to distribute preferable fragrance from composition for dress material liquid ceanser compositions of the present invention
Contain spices and be used as (F) composition.(F) composition can enumerate the known combinations of perfumes for being matched with dress material liquid ceanser compositions
Thing.It is, for example, possible to use " spices and the rudimentary knowledge of blending ", middle island base it is expensive write, nineteen ninety-five, industry books Co., Ltd. hair
The composition containing spices described in row, the 4th printing.
In the composition, the content of (F) composition is preferably more than 0.1 mass %, more preferably more than 0.2 mass %, is entered
One step is preferably more than 0.4 mass %, also, it is preferred that being below 1 mass %, more preferably below 0.8 mass %.
Dress material of the present invention can contain preservative, such as 1,2- benzisoxas by the use of liquid ceanser compositions as (G) composition
Thiazoline -3- ketone, hexamethylene etc..In the composition, the content of (G) composition is preferably 0.001 mass %
More than, more preferably more than 0.05 mass %, also, it is preferred that being below 0.5 mass %, more preferably below 0.3 mass %.
For dress material liquid ceanser compositions of the present invention, even if typically in order to easily make the outward appearance of fluid composition
The content of organic solvent that is transparent and using, have more than one hydroxyl is few, and excellent outer such as appearance transparent can also be presented
See.Specifically, for dress material liquid ceanser compositions of the present invention, even if the organic solvent with more than one hydroxyl
Content for 0 mass % less than 10 mass %, excellent outward appearance can also be presented.
As the organic solvent, less than more than 1 yuan 6 yuan of alcohol of the carbon number below more than 26 can be enumerated.As carbon
1 yuan of alcohol of the atomicity below more than 26, can enumerate such as ethanol.As 2 yuan of alcohol of the carbon number below more than 26, can arrange
Citing such as ethylene glycol, propane diols.As 3 yuan of alcohol of the carbon number below more than 26, such as glycerine can be enumerated.
In the composition, the content of the organic solvent is preferably below 9 mass %, more preferably below 8 mass %, is entered
One step is preferably below 7 mass %, furthermore, it is possible to be 0 mass %.
Dress material liquid ceanser compositions of the present invention can be to dress material endowing antibacterial.
The reason for dress material liquid ceanser compositions of the present invention can be by producing stink substance bacterium more effectively resists
Bacterium property is given to dress material, such as can be to the bacterium of the moraxella described in Japanese Unexamined Patent Publication 2013-18971 publications, big
Enterobacteria or acinetobacter calcoaceticus assign more effective antibiotic property.More than a kind in Moraxella osloensis and catarrhalis SP
Bacterium is as object of the present invention, more preferably.These bacteriums are more present on the dress material used, as after cleaning or de-
Known to the reason for producing the stink substance for making dress material smelly between drying after water bacterium.Dress material of the present invention is combined with liquid ceanser
Thing shows excellent antibiotic property to these bacteriums.
Dress material of the present invention can be used with liquid ceanser compositions in the purposes to dress material endowing antibacterial.
Dress material liquid ceanser compositions of the present invention can by produce stink substance the reason for bacterium antibiotic property assign
Give in the purposes to dress material and using.As bacterium the reason for producing stink substance, bacterium, the large intestine bar of moraxella can be enumerated
Bacterium or acinetobacter calcoaceticus.
Dress material of the present invention can be used with liquid ceanser compositions in the purposes for assigning odor-resistant result to dress material.
Dress material liquid ceanser compositions of the present invention can dress material is assigned after cleaning or after dehydration to drying
Between dress material be difficult to use in the purposes of smelly odor-resistant result.
As the example of embodiment of the present invention, dress material liquid ceanser compositions of the present invention can be enumerated for clothing
Expect the purposes in endowing antibacterial.
As other examples of embodiment of the present invention, dress material liquid ceanser compositions of the present invention can be enumerated will be right
The antibiotic property of the reason for producing stink substance bacterium is given to the purposes in dress material.
As other examples of embodiment of the present invention, can enumerate dress material liquid ceanser compositions of the present invention for
The purposes in odor-resistant result is assigned to dress material.
As other examples of embodiment of the present invention, can enumerate dress material liquid ceanser compositions of the present invention for
Dress material is assigned in the purposes being difficult to after cleaning or after dehydration to dress material between drying in smelly odor-resistant result.
Dress material of the present invention with liquid ceanser compositions be used for clothing, towel, bedding, bedding fibre (sheet,
Pillowcase etc.) etc. dress material cleaning.The fibre of the washing beyond these, which can be carried out, can also be set to object.
The present invention more specifically embodiment is shown in following.In the following embodiments, this hair can be suitably applicable
Bright dress material is with the item described in liquid ceanser compositions.
A kind of dress material liquid ceanser compositions of the ＞ of ＜ 1, wherein, contain：16 matter of following more than mass % of (A) composition 10
Measure below %, below the mass % of more than the mass % of (B) composition 13, below the mass % of more than the mass % of (C) composition 28, (D) composition
And water, wherein,
The mass ratio of [content of (D) composition]/[content of the content of (A) composition+(B) composition] be more than 0.1 0.4 with
Under,
(A) composition：Anion surfactant represented by following formulas (1),
RO-(C2H4O)mSO3 -·M+ (1)
[in formula, R is alkyl of the carbon number below more than 10 16, and m represents average addition molal quantity, and is more than 14
Following number, M+For cation ,]
(B) composition：Quaternary ammonium compound represented by following formulas (2),
[in formula, R1For aliphatic alkyl of the carbon number below more than 12 16, R2、R3And R4It is separately selected from first
Group in base, ethyl and hydroxyethyl, X-For anion ,]
(C) composition：Carbon number is below more than 46 and less than more than 2 yuan 4 yuan of polybasic carboxylic acid or its salt,
(D) composition：Nonionic surfactant represented by following formulas (3),
R5O-(C2H4O)nH (3)
[in formula, R5For alkyl of the carbon number below more than 12 16, n represents average addition molal quantity, and is more than 10
Less than 40 number.]
Dress material liquid ceanser compositions of the ＞ of ＜ 2 according to the ＞ of ＜ 1, wherein, in total R that (A) composition has
The ratio of alkyl of the carbon number below more than 12 14 is more than 60 mass %, is further more than 70 mass %, moreover, being
Below 100 mass %, it is further below 95 mass %, further for below 90 mass % or be 100 mass %.
Dress material liquid ceanser compositions of the ＞ of ＜ 3 according to the ＞ of ＜ 1, wherein, in (A) composition, R is carbon number
The ratio of the anion surfactant of less than more than 12 14 alkyl is more than 60 mass %, further for 70 mass % with
On, and be below 100 mass %, it is further below 95 mass %, is further below 90 mass %, or is 100 matter
Measure %.
Dress material liquid ceanser compositions of the ＞ of ＜ 4 according to any one of the ＞ of 1 ＞ of ＜~＜ 3, wherein, as
(A) [content of (B) composition]/[content of (A) composition] of the mass ratio of the content of the content of composition and (B) composition for 0.05 with
On, it is further more than 0.06, is further more than 0.07, be further more than 0.08, is further more than 0.09, further
For more than 1.0, moreover, being less than 0.3, it is further less than 0.25, is further less than 0.23, be further less than 0.2, enter
One step is less than 0.19, is further less than 0.18.
Dress material liquid ceanser compositions of the ＞ of ＜ 5 according to any one of the ＞ of 1 ＞ of ＜~＜ 4, wherein, as
(B) composition, containing following (b1) compositions and (b2) composition,
(b1) composition：R in formula (2)1For the quaternary ammonium compound of the aliphatic alkyl of carbon number 12.
(b2) composition：R in formula (2)1For the quaternary ammonium compound and formula of the aliphatic alkyl of carbon number 14
(2) R in1For more than a kind of compound in the quaternary ammonium compound of the aliphatic alkyl of carbon number 16.
Dress material liquid ceanser compositions of the ＞ of ＜ 6 according to the ＞ of ＜ 5, wherein, dress material is combined with liquid ceanser
The content ratio of (b2) composition and (b1) composition in thing is with the mass ratio of [content of (b2) composition]/[content of (b1) composition]
Meter, it is more than 1/99, is further more than 2/98, is further more than 3/97, be further more than 4/96, be further 5/95
More than, it is further more than 10/90, moreover, being less than 90/10, is further less than 85/15, is further less than 80/20.
Dress material liquid ceanser compositions of the ＞ of ＜ 7 according to the ＞ of ＜ 5 or the ＞ of ＜ 6, wherein, (b2) composition is R1For
The quaternary ammonium compound of the aliphatic alkyl of carbon number 16.
Dress material liquid ceanser compositions of the ＞ of ＜ 8 according to any one of the ＞ of 5 ＞ of ＜~＜ 7, wherein, carbon atom
The aliphatic alkyl of number 12 is lauryl, and the aliphatic alkyl of carbon number 14 is myristyl, the aliphatic of carbon number 16
Alkyl is palmityl or palm oil-base.
Dress material liquid ceanser compositions of the ＞ of ＜ 9 according to any one of the ＞ of 1 ＞ of ＜~＜ 8, wherein, formula
(2) R in2、R3And R4Respectively methyl.
Dress material liquid ceanser compositions of the ＞ of ＜ 10 according to any one of the ＞ of 1 ＞ of ＜~＜ 9, wherein, (C) into
It is divided into more than a kind of polybasic carboxylic acid or its salt in butanedioic acid, malic acid, tartaric acid, citric acid and their salt.
Dress material liquid ceanser compositions of the ＞ of ＜ 11 according to the ＞ of ＜ 10, wherein, (C) composition is selected from citric acid
And its more than a kind of polybasic carboxylic acid or its salt in salt.
Dress material liquid ceanser compositions of the ＞ of ＜ 12 according to any one of the ＞ of 1 ＞ of ＜~＜ 11, wherein, (D)
Total R that composition has5In the ratio of alkyl of the carbon number below more than 12 14 be more than 60 mass %, be further 70 matter
More than % is measured, is further more than 80 mass %, moreover, being below 100 mass %, or is 100 mass %.
Dress material liquid ceanser compositions of the ＞ of ＜ 13 according to any one of the ＞ of 1 ＞ of ＜~＜ 11, wherein, (D)
In composition, R5Ratio for the nonionic surfactant of alkyl of the carbon number below more than 12 14 is more than 60 mass %,
It is further more than 70 mass %, is further more than 80 mass %, moreover, being below 100 mass %, or is 100 mass %.
Dress material liquid ceanser compositions of the ＞ of ＜ 14 according to any one of the ＞ of 1 ＞ of ＜~＜ 13, wherein, formula
(3) in, R5Alkyl for straight chain aliphatic alkyl or side chain aliphatic alkyl, be further the aliphatic alkyl of straight chain.
Dress material liquid ceanser compositions of the ＞ of ＜ 15 according to the ＞ of 1 ＞ of ＜~＜ 14, wherein, in formula (3), R5
Alkyl be alkyl or alkenyl.
Dress material liquid ceanser compositions of the ＞ of ＜ 16 according to the ＞ of ＜ 15, wherein, alkyl is primary alkyl, further
For straight chain primary alkyl.
Dress material liquid ceanser compositions of the ＞ of ＜ 17 according to any one of the ＞ of 1 ＞ of ＜~＜ 16, wherein, formula
(3) in, n is more than 12, is further more than 13, is further more than 15, be further more than 16, is further more than 18,
It is further more than 20, moreover, being less than 35.
Dress material liquid ceanser compositions of the ＞ of ＜ 18 according to any one of the ＞ of 1 ＞ of ＜~＜ 17, wherein, (A)
The content of composition is more than 11 mass % in the composition, is further below 14 mass % moreover, being below 15 mass %.
Dress material liquid ceanser compositions of the ＞ of ＜ 19 according to any one of the ＞ of 1 ＞ of ＜~＜ 18, wherein, (B)
The content of composition is more than 1.5 mass % in the composition, is further more than 2 mass %, moreover, be below 2.9 mass %,
It is further below 2.8 mass %, is further below 2.7 mass %, is further below 2.6 mass %.
Dress material liquid ceanser compositions of the ＞ of ＜ 20 according to any one of the ＞ of 1 ＞ of ＜~＜ 18, wherein, (C)
The content of composition is more than 2.5 mass % in the composition, is further more than 3 mass %, further for 3.5 mass % with
On, it is further more than 4 mass %, is further more than 4.5 mass %, is further 6.5 matter moreover, being below 7 mass %
Below % is measured, is further below 6 mass %, is further below 5.5 mass %.
Dress material liquid ceanser compositions of the ＞ of ＜ 21 according to any one of the ＞ of 1 ＞ of ＜~＜ 20, wherein, as
(D) total amount of the content of the content of composition and (A) composition and the content of (B) composition it is mass ratio, [(D) composition contains
Amount]/[content of the content of (A) composition+(B) composition] be more than 0.11, it is further more than 0.12, moreover, for less than 0.35,
It is further less than 0.3, is further less than 0.25, is further less than 0.2.
Dress material liquid ceanser compositions of the ＞ of ＜ 22 according to any one of the ＞ of 1 ＞ of ＜~＜ 21, wherein, 20 DEG C
Under pH be more than 2, be further more than 3, be further more than 3.5, be further more than 4, moreover, for less than 7, further
For less than 6.8, it is further less than 6.5, is further less than 6.
Dress material liquid ceanser compositions of the ＞ of ＜ 23 according to any one of the ＞ of 1 ＞ of ＜~＜ 22, wherein, have
The content of the organic solvent of more than one hydroxyl be 0 mass % less than 10 mass %, be further below 9 mass %,
It is further below 8 mass %, is further below 7 mass %, or is 0 mass %.
Dress material liquid ceanser compositions of the ＞ of ＜ 24 according to any one of the ＞ of ＜ 23, wherein, have one with
The organic solvent of upper hydroxyl is less than more than 1 yuan 6 yuan of alcohol of the carbon number below more than 26.
Dress material liquid ceanser compositions any one of a kind of ＞ of 1 ＞ of ＜~＜ 24 of the ＞ of ＜ 25 are for will be right
The antibiotic property of the reason for producing stink substance bacterium is given to the purposes in dress material.
Dress material liquid ceanser compositions any one of a kind of ＞ of 1 ＞ of ＜~＜ 24 of the ＞ of ＜ 26 are for clothing
Material assigns the purposes in odor-resistant result.
What the composition any one of a kind of ＞ of 1 ＞ of ＜~＜ 24 of the ＞ of ＜ 27 was used as dress material with liquid ceanser
Purposes.
The purposes that composition any one of a kind of ＞ of 1 ＞ of ＜~＜ 24 of the ＞ of ＜ 28 uses in the cleaning of dress material.
Dress material liquid ceanser compositions any one of a kind of ＞ of 1 ＞ of ＜~＜ 24 of the ＞ of ＜ 29 are for will be right
The antibiotic property of the reason for producing stink substance bacterium is given to the purposes used in dress material.
Dress material liquid ceanser compositions any one of a kind of ＞ of 1 ＞ of ＜~＜ 24 of the ＞ of ＜ 30 are for clothing
Material assigns the purposes used in odor-resistant result.
Embodiment
＜ gradation compositions ＞
Hereinafter, the composition used in embodiment, comparative example is shown.
[(A) composition]
(a-1)：In formula (1), R is that lauryl and myristyl are lauryl/myristyl=7/3 by quality ratio
The mixed alkyl of (mass ratio), m 2.0, M+For Na+Anion surfactant
(a-2)：In formula (1), R is that lauryl and myristyl are lauryl/myristyl=7/3 by quality ratio
The mixed alkyl of (mass ratio), m 1.5, M+For Na+Anion surfactant
[(B) composition]
(b1-1)：N- lauryls-N, N, N- the trimethyl ammonium chloride [R in formula (2)1For lauryl, R2、R3And R4Respectively
For methyl, X-For Cl-Quaternary ammonium compound]
(b2-1)：N- palmityls-N, N, N- the trimethyl ammonium chloride [R in formula (2)1For palmityl, R2、R3And R4Respectively
For methyl, X-For Cl-Quaternary ammonium compound]
[(B ') composition：(B) comparative compound of composition]
(b’-1)：N, N- didecyl-N, N- alkyl dimethyl ammonium chloride [when the representation of formula (2) is used for the sake of convenient, formula
(2) R in1And R2Respectively decyl, R3And R4Respectively methyl, X-For Cl-Quaternary ammonium compound]
(b’-2)：N- stearyls-N, N, N- trimethyl ammonium chloride [when the representation of formula (2) is used for the sake of convenient, formula
(2) R in1For octyl group, R2、R3And R4Respectively methyl, X-For Cl-Quaternary ammonium compound]
[(C) composition]
(c-1)：Citric acid
[(D) composition]
(d-1)：In formula (3), R5For lauryl and myristyl lauryl/myristyl=9/1 by quality ratio
Mixed alkyl, the nonionic surfactant that n is 21
(d-2)：In formula (3), R5For lauryl and myristyl lauryl/myristyl=9/1 by quality ratio
Mixed alkyl, the nonionic surfactant that n is 18
(d-3)：In formula (3), R5For lauryl and myristyl lauryl/myristyl=9/1 by quality ratio
Mixed alkyl, the nonionic surfactant that n is 15
(d-4)：In formula (3), R5For lauryl and myristyl lauryl/myristyl=9/1 by quality ratio
Mixed alkyl, the nonionic surfactant that n is 12
(d-5)：In formula (3), R5For lauryl and myristyl lauryl/myristyl=9/1 by quality ratio
Mixed alkyl, the nonionic surfactant that n is 10
[(D ') composition：(D) comparative compound of composition]
(d’-1)：When the representation of formula (3) is used for the sake of convenient, in formula (3), R5For lauryl and myristyl with
The nonionic surfactant that mass ratio is calculated as the mixed alkyl of lauryl/myristyl=9/1, n is 8
(d’-2)：When the representation of formula (3) is used for the sake of convenient, in formula (3), R5For lauryl and myristyl with
The mixed alkyl of mass ratio meter lauryl/myristyl=9/1, the nonionic surfactant that n is 6
(d’-3)：When the representation of formula (3) is used for the sake of convenient, in formula (3), R5For stearyl base, n be 20 it is non-
Ionic surface active agent
[water]
Ion exchange water containing sodium hypochlorite 1mg/kg
[(E) composition]
(e-1)：Sodium hydroxide (uses as 22 mass % sodium hydrate aqueous solutions.)
[(F) composition]
(f-1)：Flavor compositions containing following fragrance components.Numeral in () is mass parts.
Benzyl carbinol (10), camphor (20), citronellal (10), l-menthol (20), aldehyde C-9 (10), nerol (10), hexichol
Ether (20)
[(G) composition]
(g-1)：Preservative, hexamethylene
The preparation method ＞ of ＜ dress material liquid ceanser compositions
Hereinafter, the preparation method of dress material liquid ceanser compositions used in embodiment, comparative example is shown.
In the embodiment of table 1~4 or each composition of comparative example, relative to completion quality as 30 DEG C required for 100g
Ion exchange water, added with each composition and prepare dress material liquid ceanser compositions.The dress material liquid ceanser of embodiment
Composition has transparent outward appearance after firm prepare.
＜ pH assay method ＞
Hereinafter, show embodiment, comparative example dress material liquid ceanser compositions pH assay method.
The pH electrodes (model 6367) that hole field is made to made pH meter D-52 use phthalate buffer in advance
(pH4.01), phosphate standard liquid (pH6.84), borate titer (pH9.18) correction, are fully rinsed with ion exchange water.
In the dress material liquid ceanser compositions for being 20 DEG C by temperature adjustment, as described above, being put into the pH electricity for having carried out correction, cleaning
Pole, using the AUTO HOLD patterns of pH meter, determining to measured value turns into certain.
＜ embodiments 1~7, the ＞ of comparative example 1~4
Using the dress material liquid ceanser compositions described in table 1, the antibiotic property with following method evaluation to dress material
Imparting effect.In addition, evaluate storage stability with following method.Show the result in table 1.
[evaluation method of the antibiotic property of dress material]
(1) making of cloth is tested
Each liquid of the 6cm × 6cm kapok flat fabric (cloth of cotton 2003 that will be bought from valley head shop) described in table 1
Cleansing composition cleans, and makes the experiment cloth for antibacterial tests.For water, 120 have been sterilized using being boiled at 100 DEG C
Hardness components are added in a manner of as 5DH ° (Ca/Mg=7/3, mass ratio) in the ion exchange water of minute, are turned into basicity
80mg/L mode adds sodium acid carbonate, and pH is adjusted to 7 water with hydrochloric acid.Water and each liquid ceanser compositions are mixed
Close, the concentration for preparing liquid ceanser compositions is 1g/L cleaning fluid.0.6 liter of cleaning is put into 1 liter of stainless steel beaker
Liquid, the kapok flat fabric 30 for being put into above-mentioned 6cm × 6cm are opened.Capacity (liter) and kapok flat fabric as above-mentioned cleaning fluid
The ratio of quality (g), the quality (g) of capacity (liter)/kapok flat fabric are 50.Entered with Terg-O-Tometer (Terg-O-Tometer)
100 turns of row, the cleaning operation of 10 minutes.Then, give up the cleaning fluid in stainless steel beaker, twist kapok flat fabric with hand, relatively
Dry mass before the cleaning of kapok flat fabric, it is set to 250 mass % or so.Carried out under identical condition 2 times 3 using water
The flushing of minute, it is dehydrated 30 seconds, is spontaneously dried with the dehydration groove of two-tub washing machine.
(2) antibacterial effect
Evaluate the antibacterial effect to Moraxella osloensis.For bacterium, the Moraxella separated from dress material is used
osloensis 41。
Bacterium solution (initial bacterium number 1.0 × 10 is inoculated with cloth 0.4g is tested5CFU/mL) 0.2mL, it is small that 18 are carried out at 37 DEG C
When quiescent culture.Add 20mL LP dilutions (Japanese pharmaceutical (strain) system) irradiation ultrasonic wave 10 minutes, carry out the extraction of bacterium.Enter
The stage dilution of row extract solution, on SCD-LP agar mediums (Japanese pharmaceutical (strain) system) after mixed diluting, enter at 37 DEG C
Row quiescent culture (1 day), measures obtained clump count, will have been subtracted respectively from the common logarithm value of the viable count of the comparative example 1 of table 1
Value (logarithm value) obtained by the common logarithm value of the viable count of embodiment or comparative example is set to quiet bacterium activity value.It is quiet in the evaluation
It more than 2.2 is qualified that bacterium activity value, which is, and quiet bacterium activity value is higher to mean that antibacterial effect is higher.
[evaluation method of storage stability]
The dress material liquid ceanser compositions described in 25g tables are put into No.6 standard jar, are statically placed in 50 DEG C
In thermostat.The outward appearance of dress material liquid ceanser compositions after observing 7 days by visual observation respectively, enters according to following benchmark
Row evaluation.1 and the 2 of following benchmark are qualified level, preferably 1 in the case where considering product form etc..In addition, following bases
2 accurate situation is also that this is preferred in terms of storage stability until it can be seen that fuzzy number of days somewhat is longer.3 is not
Qualified level.In addition, for the 1 of following benchmark or 2 composition, in ultraviolet-uisible spectrophotometer, in optical length
To be put into the dress material liquid ceanser compositions in 1cm glass system groove, when using ion exchange water in compareing side channel
Transmitance in 660nm wavelength turns into more than 90%.
1：Pellucidity is maintained, does not see separation.
2：It is slightly hazy, but it is pellucidity that can be seen, and does not see separation.
3：It can be seen that separation.
[table 1]
In table, (D)/[(A)+(B)] is the matter of [content of (D) composition]/[content of the content of (A) composition+(B) composition]
Amount is than (following same).
In addition, in table, (B)/(A) is the mass ratio (following same) of [content of (B) composition]/[content of (A) composition].
＜ embodiments 8~19, the ＞ of comparative example 5~12
Using the dress material liquid ceanser compositions described in table 2, storage stability is evaluated with following method.Will knot
Fruit is shown in table 2.
[evaluation method of storage stability]
The dress material liquid ceanser compositions described in 25g tables are put into No.6 standard jar, are statically placed in 50 DEG C
In thermostat.The outward appearance of dress material liquid ceanser compositions after observing 7 days by visual observation respectively, after 14 days and after 21 days,
Evaluated with following benchmark.1 and the 2 of following benchmark are qualified level in the case where considering product form etc., preferably
For 1.In addition, 2 situation of following benchmark is also until it can be seen that fuzzy number of days somewhat is longer, this is in storage stability side
Face is preferred.3 be underproof level.In addition, 1 or 2 composition of following benchmark is in ultraviolet-uisible spectrophotometer,
The dress material liquid ceanser compositions are put into a length of 1cm of light path glass system groove, ion exchange is used in side channel is compareed
Transmitance in the wavelength of 660nm during water turns into more than 90%.
1：Pellucidity is maintained, does not see separation.
2：It is slightly hazy, but pellucidity can be seen, do not see separation.
3：It can be seen that separation.
The ＞ of ＜ embodiments 20~27
Using the dress material liquid ceanser compositions described in table 3, the evaluation of stink is carried out with following method.Will knot
Fruit is shown in table 3.
[evaluation method of the stink of dress material liquid ceanser compositions]
The dress material liquid ceanser compositions that are put into No.6 standard jar described in 20g tables 3 simultaneously close the lid, and are put into
It it is 30 DEG C by the temperature adjustment of content in water-bath.On the dress material liquid ceanser group after being maintained 3 hours at 30 DEG C
Compound, evaluation panelist 10 evaluate stink, given a mark according to following benchmark respectively.According to being averaged for the fraction of 10 people
Divide evaluation stink.It is preferred that the side that average mark is high, it is qualified that value of the average mark more than 1.0 is chosen as.
Metewand
0：Feel that the amine equal with embodiment 27 (benchmark) is smelly.
1：Compared with embodiment 27, amine is smelly weak, but somewhat feels that amine is smelly.
2：Almost do not feel that amine is smelly.
[table 3]
＜ embodiments 28,29 ＞
Using the dress material liquid ceanser compositions described in table 4, cleaning force is evaluated with following method.Result is shown
In table 4.
[cleaning force evaluation]
The making ＞ of ＜ artificial contamination's cloth
In 6cm × 6cm wooden cotton polyester wide cut blended cloth (being bought from the valley head shop of wooden cotton polyester ratio=35/65) with
The every 1 model sebum dirt as 100mg mode gravure coating composition consisting of the following, prepare the artificial contamination used
Cloth.
Model sebum dirt
Use the model sebum dirt with following composition.
The mass % of laurate 0.44, the mass % of myristic acid 3.15, the mass % of pentadecanoic acid 2.35, the matter of palmitic acid 6.31
Measure %, the mass % of Heptadecanoic acide 0.44, the mass % of stearic acid 1.6, the mass % of oleic acid 7.91, the mass % of triolein 13.33, palm
The sour mass % of palm ester 2.22, the mass % of squalene 6.66 and the water of surplus (total 100 mass %)
＜ cleaning conditions ＞
As model running water, using in ion exchange water in a manner of as 5DH ° (Ca/Mg=7/3, mass ratio)
Adding has the water of hardness components.The dress material liquid ceanser compositions 0.6g of table 4 is added in 0.6 liter of the model running water,
It is put into 4 artificial contamination's cloth.Cleaned with Terg-O-Tometer under conditions of 100 turns, 10 minutes.
For cleaning force, with the former cloth before colour examining colour-difference-metre (Japan electric color Co. Ltd. system Z-300A) measure pollution,
And the reflectivity in the 550nm before and after cleaning, obtain cleaning rate (%) using following formula.Pollution cloth 4 is opened and is measured respectively, is asked
Go out average value.It more than 30% is acceptance line that cleaning rate, which is, and more preferably numerical value is high.
Cleaning rate (%)=100 × [(reflectivity before reflectivity-cleaning after cleaning)/(reflectivity-cleaning of former cloth
Preceding reflectivity)]
[table 4]
Understand：Embodiment 28 is corresponding with embodiment 1, and embodiment 29 is corresponding with embodiment 2.Any dress material liquid
Cleansing composition is respectively provided with good cleaning force.
Claims (7)
1. a kind of dress material liquid ceanser compositions, wherein,
Contain following more than the mass % of (A) composition 10 below 16 mass %, below the mass % of more than the mass % of (B) composition 13, (C)
Below the mass % of more than the mass % of composition 28, (D) composition and water, [content of (D) composition]/[content of (A) composition+(B) composition
Content] mass ratio be less than more than 0.1 0.4,
(A) composition：Anion surfactant represented by following formulas (1)
RO-(C2H4O)mSO3 -·M+ (1)
In formula, R is alkyl of the carbon number below more than 10 16, and m represents average addition molal quantity, and is less than more than 14
Number, M+For cation,
(B) composition：Quaternary ammonium compound represented by following formulas (2)
In formula, R1For aliphatic alkyl of the carbon number below more than 12 16, R2、R3And R4It is separately selected from methyl, second
Group in base and hydroxyethyl, X-For anion,
(C) composition：Carbon number is below more than 46 and less than more than 2 yuan 4 yuan of polybasic carboxylic acid or its salt,
(D) composition：Nonionic surfactant represented by following formulas (3),
R5O-(C2H4O)nH (3)
In formula, R5For alkyl of the carbon number below more than 12 16, n represents average addition molal quantity, and is less than more than 10 40
Number.
2. dress material liquid ceanser compositions according to claim 1, wherein,
As the mass ratio of the content and the content of (B) composition of (A) composition, [content of (B) composition]/[content of (A) composition]
For less than more than 0.05 0.3.
3. dress material liquid ceanser compositions according to claim 1 or 2, wherein,
As (B) composition, containing following (b1) compositions and (b2) composition,
(b1) composition：R in formula (2)1For the quaternary ammonium compound of the aliphatic alkyl of carbon number 12,
(b2) composition：R in formula (2)1In quaternary ammonium compound and formula (2) for the aliphatic alkyl of carbon number 14
R1For more than a kind of compound in the quaternary ammonium compound of the aliphatic alkyl of carbon number 16.
4. according to dress material liquid ceanser compositions according to any one of claims 1 to 3, wherein,
PH at 20 DEG C is less than more than 27.
5. according to dress material liquid ceanser compositions according to any one of claims 1 to 4, wherein,
The content of organic solvent with more than one hydroxyl is 0 mass % less than 10 mass %.
6. a kind of dress material liquid ceanser compositions according to any one of claims 1 to 5 for will to produce stink
The reason for material, the antibiotic property of bacterium was given to purposes in dress material.
7. a kind of dress material liquid ceanser compositions according to any one of claims 1 to 5 are anti-for being assigned to dress material
Purposes in smelly effect.
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| JP2015124168 | 2015-06-19 | ||
| JP2015-124168 | 2015-06-19 | ||
| PCT/JP2016/067191 WO2016204063A1 (en) | 2015-06-19 | 2016-06-09 | Liquid detergent composition for clothing |
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| CN107683325A true CN107683325A (en) | 2018-02-09 |
| CN107683325B CN107683325B (en) | 2020-08-11 |
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| JP (1) | JP6231617B2 (en) |
| CN (1) | CN107683325B (en) |
| WO (1) | WO2016204063A1 (en) |
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| JP2018123210A (en) * | 2017-01-31 | 2018-08-09 | 白元アース株式会社 | Allergen reducing antimicrobial composition |
| JP7190823B2 (en) * | 2017-05-09 | 2022-12-16 | ライオン株式会社 | Liquid detergent composition for clothes |
| JP7245676B2 (en) | 2019-03-11 | 2023-03-24 | 花王株式会社 | mutant protease |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005171008A (en) * | 2003-12-09 | 2005-06-30 | Kao Corp | Liquid detergent composition |
| JP2012087228A (en) * | 2010-10-20 | 2012-05-10 | Kao Corp | Liquid detergent composition |
| CN102575195A (en) * | 2009-10-15 | 2012-07-11 | 狮王株式会社 | Liquid detergent composition |
| WO2012144254A1 (en) * | 2011-04-22 | 2012-10-26 | 花王株式会社 | Liquid detergent composition |
| JP2014141661A (en) * | 2012-12-28 | 2014-08-07 | Kao Corp | Liquid detergent composition for clothing |
| JP2015105270A (en) * | 2013-12-03 | 2015-06-08 | 花王株式会社 | Sterilization method |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3251729B2 (en) * | 1993-08-19 | 2002-01-28 | 花王株式会社 | Disinfectant cleaning composition |
| AR003724A1 (en) * | 1995-09-29 | 1998-09-09 | Procter & Gamble | STRUCTURED LIQUID LAUNDRY DETERGENT COMPOSITION, FOR HARD WORK, COMPRISING ANIONIC AND CATIONIC SURFACTANTS. |
| JP3117937B2 (en) * | 1996-06-25 | 2000-12-18 | 三洋化成工業株式会社 | Antibacterial finishing agent for mild fibers |
| JP5341023B2 (en) * | 2010-05-26 | 2013-11-13 | 花王株式会社 | Liquid detergent composition |
-
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- 2016-06-09 JP JP2016114978A patent/JP6231617B2/en active Active
- 2016-06-09 WO PCT/JP2016/067191 patent/WO2016204063A1/en active Application Filing
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Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005171008A (en) * | 2003-12-09 | 2005-06-30 | Kao Corp | Liquid detergent composition |
| CN102575195A (en) * | 2009-10-15 | 2012-07-11 | 狮王株式会社 | Liquid detergent composition |
| JP2012087228A (en) * | 2010-10-20 | 2012-05-10 | Kao Corp | Liquid detergent composition |
| WO2012144254A1 (en) * | 2011-04-22 | 2012-10-26 | 花王株式会社 | Liquid detergent composition |
| JP2014141661A (en) * | 2012-12-28 | 2014-08-07 | Kao Corp | Liquid detergent composition for clothing |
| JP2015105270A (en) * | 2013-12-03 | 2015-06-08 | 花王株式会社 | Sterilization method |
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| Publication number | Publication date |
|---|---|
| JP2017008303A (en) | 2017-01-12 |
| WO2016204063A1 (en) | 2016-12-22 |
| JP6231617B2 (en) | 2017-11-15 |
| CN107683325B (en) | 2020-08-11 |
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