CN105277540A - On-site rapid detection method for copper ions in water and capable of eliminating reagent blank effects - Google Patents
On-site rapid detection method for copper ions in water and capable of eliminating reagent blank effects Download PDFInfo
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Abstract
The invention discloses an on-site rapid detection method for copper ions in water and capable of eliminating reagent blank effects. The method is as follows: preparation of a liquid-type copper ion detection reagent is carried out; a standard color card in deduction of reagent blank color and with a transparent plastic plate as a support material is made; the blank tube color is overlaid on the standard color card and contrast with a sample tube is carried out during detection. The method is simple, the accuracy is high and operation is easy. The liquid-type copper ion detection reagent is employed for detection and time of the whole detection process can be controlled effectively. The blank tube color is overlaid on the standard color card, then colorimetric contrast with the sample tube is carried out, and thus adverse effects of fluctuation of reagent blank on the detection result accuracy can be eliminated effectively. The detection method is especially suitable for on-site rapid detection of copper ions in water.
Description
Technical field
The invention belongs to field of water quality detection, particularly relate to a kind of eliminate reagent blank impact water in copper ion field fast detection method.
Background technology
Copper (Cu) is the trace element of needed by human, in the body of people, have many-sided physiological function.Research proves, in potable water, the copper of trace is useful to human body, and can supplement the deficiency of copper in human foods, meanwhile, copper can play the effect killing some bacterium in tap water.But, drink the water of copper too high levels, then can bring discomfort to health, cause and have a stomach upset, cause vomiting and diarrhoea.A large amount of absorption copper can impel selenium deficiency, and disturbs the absorption of iron; Feed copper too much not only suppresses zinc-iron alloy solution, and can accelerate zinc excretion, and clinical have throwing copper treatment copper lack and cause the report of scarce zinc disease.
In water, the detection of copper ion adopts atomic absorption spectrophotometry, visible spectrophotometry, inductively coupled plasma atomic emission spectrum/mass spectroscopy, electrochemical methods etc. more, these methods all need water sample to take back special laboratory, chemically examined by the operative technique personnel of specialty, the large-scale instrumentation that major part method also needs price high, quick, easy Site Detection requirement can not be met, some special when and wheres also exist sampling not in time, the situation of sampling location Water quality can not be objectively responded.
The dry-type that existing copper ion Site Detection reagent mostly is based on colourimetry in the market detects reagent, this detection reagent get when measuring a certain amount of water sample and dry-type detect reagent mix, dissolve, react a period of time after produce specific color, directly contrast the concentration drawing water sample test substance with standard color card.These class methods fast, convenient, public participation degree is high, but cannot eliminate the impact of change on measurement result of reagent blank when measuring, and only just has higher accuracy when reagent blank is invariable.But actual detection finds, be no matter the detection reagent of liquid-type or dry-type, in storing process, all inevitably there is reagent blank become situation that is large or that diminish gradually.In addition, when using the detection reagent of dry-type to carry out water sample detection, need first fully to dissolve detecting reagent with water sample to be measured, then carry out reaction with the concrete pollutant in water sample and produce particular color.Because the TWS of Various Seasonal, zones of different collection is not quite similar, during dissolving dry-type detection reagent, required time is also not quite similar, and whole testing process required time is difficult to effective control, also causes adverse effect to the accuracy of testing result.
Therefore, demand is a kind of uses liquid-type to detect reagent, can eliminate reagent blank on testing result impact, use the direct visual colorimetric determination of standard color card quantitative water in the detection method of copper ion, seem particularly important for realizing copper ion field quick detection in water.
Summary of the invention
The object of the embodiment of the present invention is that providing a kind of eliminates copper ion field fast detection method in the water of reagent blank impact, to realize in water, copper ion is on-the-spot fast, Accurate Determining, overcomes prior art and being difficult to effectively to control detection time when using dry-type to detect reagent because of the difference of dissolution time, testing result accuracy being caused to the shortcoming of adverse effect because of fluctuation when using and do not deduct standard color card, the colorimetric of reagent blank this standard color card directly being contrasted reagent blank of obtaining a result, cannot eliminate with sample hose.。
The present invention be achieved in that a kind of eliminate reagent blank impact water in copper ion field fast detection method comprise:
Step one, obtaining liq type copper ion detect reagent, it to be pH containing 2-(5-Bromo-2-pyridylazo)-5-diethylamino phenol, Tween-80, hydrogen peroxide, sodium fluoride, ethylene glycol be 3.5 Acetic acid-sodium acetate damping fluid;
Step 2, get 7 10ml glass color comparison tubes, arrange that the 1st color comparison tube is blank tube, 2-7 root color comparison tube is standard pipe, the copper ion standard solution of deionized water and variable concentrations is added respectively in blank tube and standard pipe, the liquid-type copper ion added again described in step one detects reagent, reaction a period of time;
Step 3, by bottom color comparison tube to the color that each tube reaction in photographs step 2 produces, with mapping software photoshop7.0 by after each standard pipe color deduction blank tube color, the concentration of the copper ion standard solution of the color of gained and correspondence is printed on water white transparency PVC plastic flitch, obtains the copper ion standard color card after deducting reagent blank;
Step 4, separately get 2 10ml glass color comparison tubes, arrange that the 1st color comparison tube is blank tube, the 2nd color comparison tube is sample hose, in blank tube and sample hose, add deionized water and water sample to be measured respectively, then add the liquid-type copper ion detection reagent described in step one, reaction a period of time;
Step 5, the standard color card described in step 3 is placed in step 4 blank tube bottom, by upwards observe bottom color comparison tube blank tube superpose with standard color card after color, and with sample hose color comparator, when the color after blank tube superposes with standard color card and sample hose solid colour, read the copper ion concentration corresponding to standard color card within a certain period of time, be Determined Copper in Aqueous Solution concentration.
Further, in step, described liquid-type copper ion detects reagent to be the pH of 60mmol/L be 3.5 Acetic acid-sodium acetate damping fluid, the concentration of 2-(5-the Bromo-2-pyridylazo)-5-diethylamino phenol contained is 0.04-0.10g/L, the concentration of Tween-80 is 0.02-0.08ml/L, the concentration of hydrogen peroxide is 3-10ml/L, the concentration of sodium fluoride is 5-25g/L, the concentration of ethylene glycol is 10-30ml/L, compound method is: take 0.04-0.10g2-(5-Bromo-2-pyridylazo)-5-diethylamino phenol, 5-25g sodium fluoride, add 800ml60mmol/LpH3.5 Acetic acid-sodium acetate damping fluid stirring and dissolving, add 0.02-0.08ml Tween-80 again, 3-10ml hydrogen peroxide, 10-30ml ethylene glycol, 1000ml is settled to 60mmol/LpH3.5 Acetic acid-sodium acetate damping fluid after stirring and dissolving.
Further, in step 2, the concentration of described copper ion standard solution is respectively 0.04mg/L, 0.08mg/L, 0.12mg/L, 0.16mg/L, 0.20mg/L, 0.24mg/L, compound method is: precision takes the metallic copper that 0.1000g content is 99.99%, 1000ml is settled to after the nitric acid dissolve of 10ml50%, obtain the copper ion storing solution that concentration is 100mg/L, with deionized water, copper ion storing solution is diluted to the copper ion standard solution that concentration is 0.04mg/L, 0.08mg/L, 0.12mg/L, 0.16mg/L, 0.20mg/L, 0.24mg/L.
Further, in step 2 and step 4, the described volume adding the copper ion standard solution of deionized water and variable concentrations is 10ml.
Further, in step 2 and step 4, described to add the volume that liquid-type copper ion detects reagent be 0.2ml.
Further, in step 2 and step 4, preferred reaction conditions for react 5-15 minute in 5-40 DEG C of environment.
Further, in step 3, the thickness of described water white transparency PVC plastic flitch is 1-2mm.
Further, in step 5, described certain hour is 5-10 minute.
The copper ion field fast detection method eliminating reagent blank impact of the present invention has the advantage that method is simple, accuracy is high, be easy to operation; Use liquid-type copper ion to detect reagent to detect, effectively can control whole testing process required time; By blank tube color addition is carried out the method for colorimetric control with sample hose again on standard color card, effectively can eliminate the impact of reagent blank on testing result, be particularly suitable for copper ion field quick detection in water.
Accompanying drawing explanation
Fig. 1 is copper ion field fast detection method process flow diagram in the water of the reagent blank the eliminated impact that the embodiment of the present invention provides.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with embodiment, this present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain this present invention, be not intended to limit the present invention.
Below in conjunction with drawings and the specific embodiments, application principle of the present invention is further described.
As shown in Figure 1, the present invention be achieved in that a kind of eliminate reagent blank impact water in copper ion field fast detection method comprise:
S101, obtaining liq type copper ion detect reagent, it to be pH containing 2-(5-Bromo-2-pyridylazo)-5-diethylamino phenol, Tween-80, hydrogen peroxide, sodium fluoride, ethylene glycol be 3.5 Acetic acid-sodium acetate damping fluid;
S102, get 7 10ml glass color comparison tubes, arrange that the 1st color comparison tube is blank tube, 2-7 root color comparison tube is standard pipe, the copper ion standard solution of deionized water and variable concentrations is added respectively in blank tube and standard pipe, the liquid-type copper ion added again described in step S101 detects reagent, reaction a period of time;
S103, by bottom color comparison tube to the color that each tube reaction in photographs step S102 produces, with mapping software photoshop7.0 by after each standard pipe color deduction blank tube color, the concentration of the copper ion standard solution of the color of gained and correspondence is printed on water white transparency PVC plastic flitch, obtains the copper ion standard color card after deducting reagent blank;
S104, separately get 2 10ml glass color comparison tubes, arrange that the 1st color comparison tube is blank tube, the 2nd color comparison tube is sample hose, in blank tube and sample hose, add deionized water and water sample to be measured respectively, then add the liquid-type copper ion detection reagent described in step S101, reaction a period of time;
S105, the standard color card described in step S103 is placed in step S104 blank tube bottom, by upwards observe bottom color comparison tube blank tube superpose with standard color card after color, and with sample hose color comparator, when the color after blank tube superposes with standard color card and sample hose solid colour, read the copper ion concentration corresponding to standard color card within a certain period of time, be Determined Copper in Aqueous Solution concentration.
Further, in step S101, described liquid-type copper ion detects reagent to be the pH of 60mmol/L be 3.5 Acetic acid-sodium acetate damping fluid, the concentration of 2-(5-the Bromo-2-pyridylazo)-5-diethylamino phenol contained is 0.04-0.10g/L, the concentration of Tween-80 is 0.02-0.08ml/L, the concentration of hydrogen peroxide is 3-10ml/L, the concentration of sodium fluoride is 5-25g/L, the concentration of ethylene glycol is 10-30ml/L, compound method is: take 0.04-0.10g2-(5-Bromo-2-pyridylazo)-5-diethylamino phenol, 5-25g sodium fluoride, add 800ml60mmol/LpH3.5 Acetic acid-sodium acetate damping fluid stirring and dissolving, add 0.02-0.08ml Tween-80 again, 3-10ml hydrogen peroxide, 10-30ml ethylene glycol, 1000ml is settled to 60mmol/LpH3.5 Acetic acid-sodium acetate damping fluid after stirring and dissolving.
Further, in step S102, the concentration of described copper ion standard solution is respectively 0.04mg/L, 0.08mg/L, 0.12mg/L, 0.16mg/L, 0.20mg/L, 0.24mg/L, compound method is: precision takes the metallic copper that 0.1000g content is 99.99%, 1000ml is settled to after the nitric acid dissolve of 10ml50%, obtain the copper ion storing solution that concentration is 100mg/L, with deionized water, copper ion storing solution is diluted to the copper ion standard solution that concentration is 0.04mg/L, 0.08mg/L, 0.12mg/L, 0.16mg/L, 0.20mg/L, 0.24mg/L.
Further, in step S102 and step S104, the described volume adding the copper ion standard solution of deionized water and variable concentrations is 10ml.
Further, in step S102 and step S104, the described volume adding liquid-type copper ion detection reagent is 0.2ml.
Further, in step S102 and step S104, preferred reaction conditions for react 5-15 minute in 5-40 DEG C of environment.
Further, in step S103, the thickness of described water white transparency PVC plastic flitch is 1-2mm.
Further, in step S105, described certain hour is 5-10 minute.
Specific embodiments of the invention:
Embodiment 1
Step one, take 0.04g2-(5-Bromo-2-pyridylazo)-5-diethylamino phenol, 5g sodium fluoride, add 800ml60mmol/LpH3.5 Acetic acid-sodium acetate damping fluid stirring and dissolving, add 0.02ml Tween-80 again, 3ml hydrogen peroxide, 10ml ethylene glycol, 1000ml is settled to 60mmol/LpH3.5 Acetic acid-sodium acetate damping fluid after stirring and dissolving, obtain 1000ml and contain 0.04g/L2-(5-Bromo-2-pyridylazo)-5-diethylamino phenol, 0.02ml/L Tween-80, 3ml/L hydrogen peroxide, 5g/L sodium fluoride, the 60mmol/LpH3.5 Acetic acid-sodium acetate damping fluid of 10ml/L ethylene glycol is that liquid-type copper ion detects reagent,
Step 2, get 7 10ml glass color comparison tubes, arrange that the 1st color comparison tube is blank tube, 2-7 root color comparison tube is standard pipe, the copper ion standard solution that 10ml deionized water and 10ml concentration are 0.04mg/L, 0.08mg/L, 0.12mg/L, 0.16mg/L, 0.20mg/L, 0.24mg/L is added respectively in blank tube and standard pipe, the liquid-type copper ion added again described in step one detects reagent 0.2ml, reacts 15 minutes in 5 DEG C of environment;
Step 3, by bottom color comparison tube to the color that each tube reaction in photographs step 2 produces, with mapping software photoshop7.0 by after each standard pipe color deduction blank tube color, the concentration of the copper ion standard solution of the color of gained and correspondence is printed on the water white transparency PVC plastic flitch that thickness is 1mm, obtains each concentration copper ion standard color card after deducting reagent blank;
Step 4, separately get 2 10ml glass color comparison tubes, arrange that the 1st color comparison tube is blank tube, the 2nd color comparison tube is sample hose, 10ml deionized water and 10ml water sample to be measured is added respectively in blank tube and sample hose, add the liquid-type copper ion described in step one again and detect reagent, react 15 minutes in 5 DEG C of environment;
Step 5, the standard color card described in step 3 is placed in step 4 blank tube bottom, by upwards observe bottom color comparison tube blank tube superpose with standard color card after color, and with sample hose color comparator, when both solid colours, in 5 minutes, read the copper ion concentration corresponding to standard color card, show that Determined Copper in Aqueous Solution concentration is 0.04mg/L.
Detect the copper ion concentration of water sample described in the present embodiment step 4 with national standard method atomic absorption method, result is 0.042mg/L, can find out, the testing result of method described in the present embodiment and atomic absorption method has good consistance.
Embodiment 2
Step one, take 0.07g2-(5-Bromo-2-pyridylazo)-5-diethylamino phenol, 15g sodium fluoride, add 800ml60mmol/LpH3.5 Acetic acid-sodium acetate damping fluid stirring and dissolving, add 0.05ml Tween-80 again, 6.5ml hydrogen peroxide, 20ml ethylene glycol, 1000ml is settled to 60mmol/LpH3.5 Acetic acid-sodium acetate damping fluid after stirring and dissolving, obtain 1000ml and contain 0.07g/L2-(5-Bromo-2-pyridylazo)-5-diethylamino phenol, 0.05ml/L Tween-80, 6.5ml/L hydrogen peroxide, 15g/L sodium fluoride, the 60mmol/LpH3.5 Acetic acid-sodium acetate damping fluid of 20ml/L ethylene glycol is that liquid-type copper ion detects reagent,
Step 2, get 7 10ml glass color comparison tubes, arrange that the 1st color comparison tube is blank tube, 2-7 root color comparison tube is standard pipe, the copper ion standard solution that 10ml deionized water and 10ml concentration are 0.04mg/L, 0.08mg/L, 0.12mg/L, 0.16mg/L, 0.20mg/L, 0.24mg/L is added respectively in blank tube and standard pipe, the liquid-type copper ion added again described in step one detects reagent 0.2ml, reacts 10 minutes in 20 DEG C of environment;
Step 3, by bottom color comparison tube to the color that each tube reaction in photographs step 2 produces, with mapping software photoshop7.0 by after each standard pipe color deduction blank tube color, the concentration of the copper ion standard solution of the color of gained and correspondence is printed on the water white transparency PVC plastic flitch that thickness is 1.5mm, obtains each concentration copper ion standard color card after deducting reagent blank;
Step 4, separately get 2 10ml glass color comparison tubes, arrange that the 1st color comparison tube is blank tube, the 2nd color comparison tube is sample hose, 10ml deionized water and 10ml water sample to be measured is added respectively in blank tube and sample hose, add the liquid-type copper ion described in step one again and detect reagent, react 10 minutes in 20 DEG C of environment;
Step 5, the standard color card described in step 3 is placed in step 4 blank tube bottom, by upwards observe bottom color comparison tube blank tube superpose with standard color card after color, and with sample hose color comparator, when both solid colours, in 7.5 minutes, read the copper ion concentration corresponding to standard color card, show that Determined Copper in Aqueous Solution concentration is 0.12mg/L.
Detect the copper ion concentration of water sample described in the present embodiment step 4 with national standard method atomic absorption method, result is 0.124mg/L, can find out, the testing result of method described in the present embodiment and atomic absorption method has good consistance.
Embodiment 3
Step one, take 0.10g2-(5-Bromo-2-pyridylazo)-5-diethylamino phenol, 25g sodium fluoride, add 800ml60mmol/LpH3.5 Acetic acid-sodium acetate damping fluid stirring and dissolving, add 0.08ml Tween-80 again, 10ml hydrogen peroxide, 30ml ethylene glycol, 1000ml is settled to 60mmol/LpH3.5 Acetic acid-sodium acetate damping fluid after stirring and dissolving, obtain 1000ml and contain 0.10g/L2-(5-Bromo-2-pyridylazo)-5-diethylamino phenol, 0.08ml/L Tween-80, 10ml/L hydrogen peroxide, 25g/L sodium fluoride, the 60mmol/LpH3.5 Acetic acid-sodium acetate damping fluid of 30ml/L ethylene glycol is that liquid-type copper ion detects reagent,
Step 2, get 7 10ml glass color comparison tubes, arrange that the 1st color comparison tube is blank tube, 2-7 root color comparison tube is standard pipe, the copper ion standard solution that 10ml deionized water and 10ml concentration are 0.04mg/L, 0.08mg/L, 0.12mg/L, 0.16mg/L, 0.20mg/L, 0.24mg/L is added respectively in blank tube and standard pipe, the liquid-type copper ion added again described in step one detects reagent 0.2ml, reacts 5 minutes in 40 DEG C of environment;
Step 3, by bottom color comparison tube to the color that each tube reaction in photographs step 2 produces, with mapping software photoshop7.0 by after each standard pipe color deduction blank tube color, the concentration of the copper ion standard solution of the color of gained and correspondence is printed on the water white transparency PVC plastic flitch that thickness is 2mm, obtains each concentration copper ion standard color card after deducting reagent blank;
Step 4, separately get 2 10ml glass color comparison tubes, arrange that the 1st color comparison tube is blank tube, the 2nd color comparison tube is sample hose, 10ml deionized water and 10ml water sample to be measured is added respectively in blank tube and sample hose, add the liquid-type copper ion described in step one again and detect reagent, react 5 minutes in 40 DEG C of environment;
Step 5, the standard color card described in step 3 is placed in step 4 blank tube bottom, by upwards observe bottom color comparison tube blank tube superpose with standard color card after color, and with sample hose color comparator, when both solid colours, in 10 minutes, read the copper ion concentration corresponding to standard color card, show that Determined Copper in Aqueous Solution concentration is 0.24mg/L.
Detect the copper ion concentration of water sample described in the present embodiment step 4 with national standard method atomic absorption method, result is 0.236mg/L, can find out, the testing result of method described in the present embodiment and atomic absorption method has good consistance.
Embodiment 4
In order to prove creativeness of the present invention further, invention has been following contrast test, investigating the change of reagent blank to the impact of measurement result accuracy.Detecting reagent by the method obtaining liq type copper ion described in this law embodiment 1 step one is test group, not deduct reagent blank, the detection reagent adopting standard color card direct color comparison is control group, two group reagents are put respectively 4 DEG C of refrigerators and 37 water-baths store 7 days, and measure with the water sample that aas determination copper ion concentration is 0.04mg/L with a, replace water sample to carry out reagent blank test with deionized water simultaneously, by 721 spectrophotometer record reagent blank values, during test, cuvette optical path is 1cm, test wavelength is 560nm, reference solution is deionized water, the results are shown in Table 1.
Table 1
As can be seen from Table 1, under identical experiment condition, along with the increase gradually of reagent blank, the measurement result of test group remains unchanged, but the measurement result of control group obviously becomes large, show that method of the present invention effectively can remove the change of reagent blank to the impact of copper ion test result.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any amendments done within the spirit and principles in the present invention, equivalent replacement and improvement etc., all should be included within protection scope of the present invention.
Claims (10)
1. can eliminate a copper ion field fast detection method in the water of reagent blank impact, it is characterized in that, in the water of the described reagent blank eliminated impact, copper ion field fast detection method comprises:
Step one, obtaining liq type copper ion detect reagent, it to be pH containing 2-(5-Bromo-2-pyridylazo)-5-diethylamino phenol, Tween-80, hydrogen peroxide, sodium fluoride, ethylene glycol be 3.5 Acetic acid-sodium acetate damping fluid;
Step 2, get 7 10ml glass color comparison tubes, arrange that the 1st color comparison tube is blank tube, 2-7 root color comparison tube is standard pipe, the copper ion standard solution of deionized water and variable concentrations is added respectively in blank tube and standard pipe, the liquid-type copper ion added again described in step one detects reagent, reacts;
Step 3, by bottom color comparison tube to the color that each tube reaction in photographs step 2 produces, with mapping software photoshop7.0 by after each standard pipe color deduction blank tube color, the concentration of the copper ion standard solution of the color of gained and correspondence is printed on water white transparency PVC plastic flitch, obtains the copper ion standard color card after deducting reagent blank;
Step 4, separately get 2 10ml glass color comparison tubes, arrange that the 1st color comparison tube is blank tube, the 2nd color comparison tube is sample hose, in blank tube and sample hose, add deionized water and water sample to be measured respectively, then add the liquid-type copper ion detection reagent described in step one, react;
Step 5, the standard color card described in step 3 is placed in step 4 blank tube bottom, by upwards observe bottom color comparison tube blank tube superpose with standard color card after color, and with sample hose color comparator, when the color after blank tube superposes with standard color card and sample hose solid colour, read the copper ion concentration corresponding to standard color card, be Determined Copper in Aqueous Solution concentration.
2. can eliminate copper ion field fast detection method in the water of reagent blank impact as claimed in claim 1, it is characterized in that, in step, described liquid-type copper ion detects reagent to be the pH of 60mmol/L be 3.5 Acetic acid-sodium acetate damping fluid, the concentration of the 2-contained (5-Bromo-2-pyridylazo)-5-diethylamino phenol is 0.04-0.10g/L, the concentration of Tween-80 is 0.02-0.08ml/L, the concentration of hydrogen peroxide is 3-10ml/L, the concentration of sodium fluoride is 5-25g/L, the concentration of ethylene glycol is 10-30ml/L.
3. can eliminate copper ion field fast detection method in the water of reagent blank impact as claimed in claim 2, it is characterized in that, Acetic acid-sodium acetate buffer method is: take 0.04-0.10g2-(5-Bromo-2-pyridylazo)-5-diethylamino phenol, 5-25g sodium fluoride, add 800ml60mmol/LpH3.5 Acetic acid-sodium acetate damping fluid stirring and dissolving, add 0.02-0.08ml Tween-80,3-10ml hydrogen peroxide, 10-30ml ethylene glycol again, after stirring and dissolving, be settled to 1000ml with 60mmol/LpH3.5 Acetic acid-sodium acetate damping fluid.
4. can eliminate copper ion field fast detection method in the water of reagent blank impact as claimed in claim 1, it is characterized in that, in step 2, the concentration of described copper ion standard solution is respectively 0.04mg/L, 0.08mg/L, 0.12mg/L, 0.16mg/L, 0.20mg/L, 0.24mg/L.
5. can eliminate copper ion field fast detection method in the water of reagent blank impact as claimed in claim 4, it is characterized in that, copper ion standard solution compound method is: take the metallic copper that 0.1000g content is 99.99%, 1000ml is settled to after the nitric acid dissolve of 10ml50%, obtain the copper ion storing solution that concentration is 100mg/L, with deionized water, copper ion storing solution is diluted to the copper ion standard solution that concentration is 0.04mg/L, 0.08mg/L, 0.12mg/L, 0.16mg/L, 0.20mg/L, 0.24mg/L.
6. can eliminate copper ion field fast detection method in the water of reagent blank impact as claimed in claim 1, it is characterized in that, in step 2 and step 4, the described volume adding the copper ion standard solution of deionized water and variable concentrations is 10ml.
7. can eliminate copper ion field fast detection method in the water of reagent blank impact as claimed in claim 1, it is characterized in that, in step 2 and step 4, described to add the volume that liquid-type copper ion detects reagent be 0.2ml.
8. can eliminate copper ion field fast detection method in the water of reagent blank impact as claimed in claim 1, it is characterized in that, in step 2 and step 4, preferred reaction conditions for react 5-15 minute in 5-40 DEG C of environment.
9. can eliminate copper ion field fast detection method in the water of reagent blank impact as claimed in claim 1, it is characterized in that, in step 3, the thickness of described water white transparency PVC plastic flitch is 1-2mm.
10. can eliminate copper ion field fast detection method in the water of reagent blank impact as claimed in claim 1, it is characterized in that, in step 5, react the copper ion concentration read after 5-10 minute corresponding to standard color card.
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