CN1635379A - Serum copper, iron and zinc rapid sensitive detection kit and preparing method thereof - Google Patents
Serum copper, iron and zinc rapid sensitive detection kit and preparing method thereof Download PDFInfo
- Publication number
- CN1635379A CN1635379A CN 200410096340 CN200410096340A CN1635379A CN 1635379 A CN1635379 A CN 1635379A CN 200410096340 CN200410096340 CN 200410096340 CN 200410096340 A CN200410096340 A CN 200410096340A CN 1635379 A CN1635379 A CN 1635379A
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- Prior art keywords
- pyridylazo
- bromo
- phenol
- colour developing
- serum
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Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 74
- 210000002966 serum Anatomy 0.000 title claims abstract description 53
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 37
- 239000011701 zinc Substances 0.000 title claims abstract description 36
- 239000010949 copper Substances 0.000 title claims abstract description 34
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 32
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 30
- 238000011896 sensitive detection Methods 0.000 title claims description 21
- 238000000034 method Methods 0.000 title abstract description 19
- 239000007788 liquid Substances 0.000 claims abstract description 50
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 22
- 238000002360 preparation method Methods 0.000 claims description 24
- 239000011550 stock solution Substances 0.000 claims description 24
- 239000004094 surface-active agent Substances 0.000 claims description 21
- 239000003153 chemical reaction reagent Substances 0.000 claims description 19
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 18
- 238000005303 weighing Methods 0.000 claims description 18
- -1 (2) pyridylazo Chemical class 0.000 claims description 16
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 16
- 238000012216 screening Methods 0.000 claims description 16
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 15
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 14
- 239000007864 aqueous solution Substances 0.000 claims description 14
- BHZOKUMUHVTPBX-UHFFFAOYSA-M sodium acetic acid acetate Chemical compound [Na+].CC(O)=O.CC([O-])=O BHZOKUMUHVTPBX-UHFFFAOYSA-M 0.000 claims description 12
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 10
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 claims description 10
- 229920004890 Triton X-100 Polymers 0.000 claims description 8
- 239000013504 Triton X-100 Substances 0.000 claims description 8
- LWZFANDGMFTDAV-BURFUSLBSA-N [(2r)-2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O LWZFANDGMFTDAV-BURFUSLBSA-N 0.000 claims description 8
- LNIGBQNXJNNICD-UHFFFAOYSA-N 2-[(5-bromopyridin-2-yl)diazenyl]-5-(dimethylamino)phenol Chemical compound OC1=CC(N(C)C)=CC=C1N=NC1=CC=C(Br)C=N1 LNIGBQNXJNNICD-UHFFFAOYSA-N 0.000 claims description 7
- ZVZFHCZCIBYFMZ-UHFFFAOYSA-N 6-methylheptoxybenzene Chemical compound CC(C)CCCCCOC1=CC=CC=C1 ZVZFHCZCIBYFMZ-UHFFFAOYSA-N 0.000 claims description 7
- HOBSGKWFTBDQCH-UHFFFAOYSA-N phenol;sodium Chemical compound [Na].[Na].OC1=CC=CC=C1 HOBSGKWFTBDQCH-UHFFFAOYSA-N 0.000 claims description 7
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 7
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 6
- QKNYBSVHEMOAJP-UHFFFAOYSA-N 2-amino-2-(hydroxymethyl)propane-1,3-diol;hydron;chloride Chemical compound Cl.OCC(N)(CO)CO QKNYBSVHEMOAJP-UHFFFAOYSA-N 0.000 claims description 6
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 6
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 239000005642 Oleic acid Substances 0.000 claims description 6
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 6
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 6
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 6
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 6
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 6
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 6
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 239000000243 solution Substances 0.000 claims description 6
- WAVOOWVINKGEHS-UHFFFAOYSA-N 3-(diethylamino)phenol Chemical compound CCN(CC)C1=CC=CC(O)=C1 WAVOOWVINKGEHS-UHFFFAOYSA-N 0.000 claims description 4
- GDEBSAWXIHEMNF-UHFFFAOYSA-O cupferron Chemical compound [NH4+].O=NN([O-])C1=CC=CC=C1 GDEBSAWXIHEMNF-UHFFFAOYSA-O 0.000 claims description 4
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 4
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 4
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 4
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 4
- 235000017858 Laurus nobilis Nutrition 0.000 claims description 3
- 235000005212 Terminalia tomentosa Nutrition 0.000 claims description 3
- 235000013024 sodium fluoride Nutrition 0.000 claims description 3
- 239000011775 sodium fluoride Substances 0.000 claims description 3
- 235000015165 citric acid Nutrition 0.000 claims description 2
- 244000125380 Terminalia tomentosa Species 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 6
- 102000004169 proteins and genes Human genes 0.000 abstract description 3
- 108090000623 proteins and genes Proteins 0.000 abstract description 3
- 238000012360 testing method Methods 0.000 abstract description 2
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
- 239000012153 distilled water Substances 0.000 description 10
- 238000001514 detection method Methods 0.000 description 8
- 238000002835 absorbance Methods 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000003556 assay Methods 0.000 description 6
- 238000006757 chemical reactions by type Methods 0.000 description 6
- 230000003287 optical effect Effects 0.000 description 6
- 238000004321 preservation Methods 0.000 description 6
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 4
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 208000007502 anemia Diseases 0.000 description 3
- 238000004737 colorimetric analysis Methods 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 244000147568 Laurus nobilis Species 0.000 description 2
- 208000031845 Pernicious anaemia Diseases 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 238000003321 atomic absorption spectrophotometry Methods 0.000 description 2
- 201000011510 cancer Diseases 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 238000002798 spectrophotometry method Methods 0.000 description 2
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- 206010018910 Haemolysis Diseases 0.000 description 1
- 208000002972 Hepatolenticular Degeneration Diseases 0.000 description 1
- 208000017604 Hodgkin disease Diseases 0.000 description 1
- 208000010747 Hodgkins lymphoma Diseases 0.000 description 1
- WTDHULULXKLSOZ-UHFFFAOYSA-N Hydroxylamine hydrochloride Chemical compound Cl.ON WTDHULULXKLSOZ-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 208000012641 Pigmentation disease Diseases 0.000 description 1
- 244000061458 Solanum melongena Species 0.000 description 1
- 102000004338 Transferrin Human genes 0.000 description 1
- 108090000901 Transferrin Proteins 0.000 description 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 230000003698 anagen phase Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 230000032823 cell division Effects 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- RNFNDJAIBTYOQL-UHFFFAOYSA-N chloral hydrate Chemical compound OC(O)C(Cl)(Cl)Cl RNFNDJAIBTYOQL-UHFFFAOYSA-N 0.000 description 1
- 229960002327 chloral hydrate Drugs 0.000 description 1
- 230000001684 chronic effect Effects 0.000 description 1
- 238000007398 colorimetric assay Methods 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 230000008588 hemolysis Effects 0.000 description 1
- 208000007475 hemolytic anemia Diseases 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 235000021125 infant nutrition Nutrition 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 208000032839 leukemia Diseases 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000004962 physiological condition Effects 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- NNFCIKHAZHQZJG-UHFFFAOYSA-N potassium cyanide Chemical compound [K+].N#[C-] NNFCIKHAZHQZJG-UHFFFAOYSA-N 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 208000008128 pulmonary tuberculosis Diseases 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 208000011580 syndromic disease Diseases 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 239000012581 transferrin Substances 0.000 description 1
Landscapes
- Investigating Or Analysing Biological Materials (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Abstract
Description
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN 200410096340 CN1261766C (en) | 2004-11-30 | 2004-11-30 | Serum copper, iron and zinc rapid sensitive detection kit and preparing method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN 200410096340 CN1261766C (en) | 2004-11-30 | 2004-11-30 | Serum copper, iron and zinc rapid sensitive detection kit and preparing method thereof |
Publications (2)
Publication Number | Publication Date |
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CN1635379A true CN1635379A (en) | 2005-07-06 |
CN1261766C CN1261766C (en) | 2006-06-28 |
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CN 200410096340 Expired - Fee Related CN1261766C (en) | 2004-11-30 | 2004-11-30 | Serum copper, iron and zinc rapid sensitive detection kit and preparing method thereof |
Country Status (1)
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CN (1) | CN1261766C (en) |
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100501383C (en) * | 2006-09-20 | 2009-06-17 | 浙江大学 | Method for fast determination of iron content in rice seed |
CN102053068A (en) * | 2010-11-02 | 2011-05-11 | 首都医科大学附属北京朝阳医院 | Serum iron content detection method and special standard substance thereof |
CN102175676A (en) * | 2011-01-20 | 2011-09-07 | 东华理工大学 | Novel developing body for measuring copper ions by spectrophotometry and preparation process thereof |
CN102353671A (en) * | 2011-06-27 | 2012-02-15 | 董理 | Method and kit for detecting serium inorganic phosphorus |
CN103364354A (en) * | 2013-06-26 | 2013-10-23 | 斯涛利科技发展(天津)有限公司 | Method for colorimetric detection of hydrogen peroxide by utilizing metal organic complexes |
CN103728228A (en) * | 2012-10-10 | 2014-04-16 | 三星Sdi株式会社 | Method for detecting non-magnetic metal particles contained in secondary battery materials |
EP2784501A1 (en) | 2013-03-26 | 2014-10-01 | Nanomedpharma Ltd | Rapid assay kit for direct photometric determination of copper and zinc levels in fluids |
CN105181692A (en) * | 2015-09-30 | 2015-12-23 | 山东博科生物产业有限公司 | Colorimetry detection kit for IMA (ischemia modified albumin) |
CN105241831A (en) * | 2015-10-12 | 2016-01-13 | 山东博科生物产业有限公司 | Stable good-interference resistance serum zinc detection reagent and detection method |
CN105277540A (en) * | 2015-02-05 | 2016-01-27 | 温州医科大学 | On-site rapid detection method for copper ions in water and capable of eliminating reagent blank effects |
CN105319209A (en) * | 2015-02-05 | 2016-02-10 | 温州医科大学 | On-site rapid detection method for iron ions in water capable of eliminating reagent blank influences |
CN106501244A (en) * | 2016-09-30 | 2017-03-15 | 宁波普瑞柏生物技术股份有限公司 | Serum copper ions quantitative detecting reagent |
CN108458981A (en) * | 2018-04-25 | 2018-08-28 | 信阳师范学院 | A kind of method that methyl hydroximic acid photometry detects iron content in water sample |
CN109358056A (en) * | 2018-12-26 | 2019-02-19 | 西南铝业(集团)有限责任公司 | A method of 7050 zinc in aluminium alloy contents of measurement |
CN109883972A (en) * | 2019-04-11 | 2019-06-14 | 哈尔滨工业大学(威海) | Dissociate Methods For The Determination of Iron in a kind of red blood cell |
CN110849874A (en) * | 2019-12-05 | 2020-02-28 | 深圳市海聚源水产科技有限公司 | Ammonia nitrogen detection reagent formula suitable for high organic matter content culture water body and application |
CN113376153A (en) * | 2021-07-23 | 2021-09-10 | 河南省科学院化学研究所有限公司 | Method for detecting ultra-micro copper ions in water |
CN113720836A (en) * | 2021-09-17 | 2021-11-30 | 北京安图生物工程有限公司 | Kit for detecting serum copper ions and preparation method thereof |
-
2004
- 2004-11-30 CN CN 200410096340 patent/CN1261766C/en not_active Expired - Fee Related
Cited By (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100501383C (en) * | 2006-09-20 | 2009-06-17 | 浙江大学 | Method for fast determination of iron content in rice seed |
CN102053068A (en) * | 2010-11-02 | 2011-05-11 | 首都医科大学附属北京朝阳医院 | Serum iron content detection method and special standard substance thereof |
CN102053068B (en) * | 2010-11-02 | 2012-10-24 | 首都医科大学附属北京朝阳医院 | Serum iron content detection method and special standard substance thereof |
CN102175676A (en) * | 2011-01-20 | 2011-09-07 | 东华理工大学 | Novel developing body for measuring copper ions by spectrophotometry and preparation process thereof |
CN102353671A (en) * | 2011-06-27 | 2012-02-15 | 董理 | Method and kit for detecting serium inorganic phosphorus |
CN103728228A (en) * | 2012-10-10 | 2014-04-16 | 三星Sdi株式会社 | Method for detecting non-magnetic metal particles contained in secondary battery materials |
CN103728228B (en) * | 2012-10-10 | 2020-03-31 | 三星Sdi株式会社 | Method for detecting non-magnetic metal particles contained in secondary battery material |
EP2784501A1 (en) | 2013-03-26 | 2014-10-01 | Nanomedpharma Ltd | Rapid assay kit for direct photometric determination of copper and zinc levels in fluids |
CN103364354A (en) * | 2013-06-26 | 2013-10-23 | 斯涛利科技发展(天津)有限公司 | Method for colorimetric detection of hydrogen peroxide by utilizing metal organic complexes |
CN105277540A (en) * | 2015-02-05 | 2016-01-27 | 温州医科大学 | On-site rapid detection method for copper ions in water and capable of eliminating reagent blank effects |
CN105319209B (en) * | 2015-02-05 | 2018-02-16 | 温州医科大学 | Iron ion field fast detection method in a kind of water for eliminating reagent blank influence |
CN105319209A (en) * | 2015-02-05 | 2016-02-10 | 温州医科大学 | On-site rapid detection method for iron ions in water capable of eliminating reagent blank influences |
CN105277540B (en) * | 2015-02-05 | 2018-03-23 | 温州医科大学 | Copper ion field fast detection method in a kind of water for eliminating reagent blank influence |
CN105181692A (en) * | 2015-09-30 | 2015-12-23 | 山东博科生物产业有限公司 | Colorimetry detection kit for IMA (ischemia modified albumin) |
CN105241831A (en) * | 2015-10-12 | 2016-01-13 | 山东博科生物产业有限公司 | Stable good-interference resistance serum zinc detection reagent and detection method |
CN106501244A (en) * | 2016-09-30 | 2017-03-15 | 宁波普瑞柏生物技术股份有限公司 | Serum copper ions quantitative detecting reagent |
CN108458981A (en) * | 2018-04-25 | 2018-08-28 | 信阳师范学院 | A kind of method that methyl hydroximic acid photometry detects iron content in water sample |
CN109358056A (en) * | 2018-12-26 | 2019-02-19 | 西南铝业(集团)有限责任公司 | A method of 7050 zinc in aluminium alloy contents of measurement |
CN109883972A (en) * | 2019-04-11 | 2019-06-14 | 哈尔滨工业大学(威海) | Dissociate Methods For The Determination of Iron in a kind of red blood cell |
CN110849874A (en) * | 2019-12-05 | 2020-02-28 | 深圳市海聚源水产科技有限公司 | Ammonia nitrogen detection reagent formula suitable for high organic matter content culture water body and application |
CN113376153A (en) * | 2021-07-23 | 2021-09-10 | 河南省科学院化学研究所有限公司 | Method for detecting ultra-micro copper ions in water |
CN113376153B (en) * | 2021-07-23 | 2022-06-03 | 河南省科学院化学研究所有限公司 | Method for detecting ultra-micro copper ions in water |
CN113720836A (en) * | 2021-09-17 | 2021-11-30 | 北京安图生物工程有限公司 | Kit for detecting serum copper ions and preparation method thereof |
Also Published As
Publication number | Publication date |
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CN1261766C (en) | 2006-06-28 |
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