CN105238405A - 一种提高稀土离子共掺上转换纳米材料发光强度的方法 - Google Patents
一种提高稀土离子共掺上转换纳米材料发光强度的方法 Download PDFInfo
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- CN105238405A CN105238405A CN201510727909.1A CN201510727909A CN105238405A CN 105238405 A CN105238405 A CN 105238405A CN 201510727909 A CN201510727909 A CN 201510727909A CN 105238405 A CN105238405 A CN 105238405A
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- trifluoroacetate
- rare earth
- doped
- scandium
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- 238000006243 chemical reaction Methods 0.000 title claims abstract description 47
- 238000000034 method Methods 0.000 title claims abstract description 32
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- -1 rare earth ion Chemical class 0.000 claims abstract description 76
- 239000011159 matrix material Substances 0.000 claims abstract description 30
- 238000002360 preparation method Methods 0.000 claims abstract description 13
- 238000006862 quantum yield reaction Methods 0.000 claims abstract description 7
- 238000012546 transfer Methods 0.000 claims abstract description 6
- 239000002243 precursor Substances 0.000 claims description 41
- 229910052775 Thulium Inorganic materials 0.000 claims description 31
- 229910052691 Erbium Inorganic materials 0.000 claims description 30
- 239000002073 nanorod Substances 0.000 claims description 30
- CUNPJFGIODEJLQ-UHFFFAOYSA-M potassium;2,2,2-trifluoroacetate Chemical compound [K+].[O-]C(=O)C(F)(F)F CUNPJFGIODEJLQ-UHFFFAOYSA-M 0.000 claims description 28
- GUBFQUUXGNHDPZ-UHFFFAOYSA-K scandium(3+);2,2,2-trifluoroacetate Chemical compound [Sc+3].[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F GUBFQUUXGNHDPZ-UHFFFAOYSA-K 0.000 claims description 28
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 27
- 239000002994 raw material Substances 0.000 claims description 27
- 239000002904 solvent Substances 0.000 claims description 27
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 25
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 claims description 25
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 25
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 25
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 25
- 239000005642 Oleic acid Substances 0.000 claims description 25
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 25
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 25
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 25
- 229910052700 potassium Inorganic materials 0.000 claims description 25
- 239000011591 potassium Substances 0.000 claims description 25
- 229910052706 scandium Inorganic materials 0.000 claims description 25
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims description 25
- 239000000243 solution Substances 0.000 claims description 25
- VTUCCXROZBIRRC-UHFFFAOYSA-K 2,2,2-trifluoroacetate;ytterbium(3+) Chemical compound [Yb+3].[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F VTUCCXROZBIRRC-UHFFFAOYSA-K 0.000 claims description 20
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadecene Natural products CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 claims description 20
- DTQVDTLACAAQTR-UHFFFAOYSA-M Trifluoroacetate Chemical compound [O-]C(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-M 0.000 claims description 18
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 claims description 16
- ASVJFTFEDFWVRJ-UHFFFAOYSA-K thulium(3+);2,2,2-trifluoroacetate Chemical compound [Tm+3].[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F ASVJFTFEDFWVRJ-UHFFFAOYSA-K 0.000 claims description 14
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 claims description 14
- FAOLWJARFWBHJV-UHFFFAOYSA-K erbium(3+);2,2,2-trifluoroacetate Chemical compound [Er+3].[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F FAOLWJARFWBHJV-UHFFFAOYSA-K 0.000 claims description 13
- 229910052689 Holmium Inorganic materials 0.000 claims description 11
- 238000004020 luminiscence type Methods 0.000 claims description 11
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical class OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 claims description 9
- VCEVUFUPSZAPDQ-UHFFFAOYSA-K holmium(3+) 2,2,2-trifluoroacetate Chemical compound [Ho+3].[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F VCEVUFUPSZAPDQ-UHFFFAOYSA-K 0.000 claims description 8
- 239000012046 mixed solvent Substances 0.000 claims description 8
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 claims description 7
- 150000002500 ions Chemical class 0.000 claims description 6
- KUQIWULJSBTNPX-HWKANZROSA-N (e)-octadec-2-ene Chemical compound CCCCCCCCCCCCCCC\C=C\C KUQIWULJSBTNPX-HWKANZROSA-N 0.000 claims description 4
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- 150000002910 rare earth metals Chemical class 0.000 claims description 2
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- 150000003839 salts Chemical class 0.000 claims 1
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- 239000002159 nanocrystal Substances 0.000 description 8
- 230000005284 excitation Effects 0.000 description 7
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- FRNOGLGSGLTDKL-UHFFFAOYSA-N thulium atom Chemical compound [Tm] FRNOGLGSGLTDKL-UHFFFAOYSA-N 0.000 description 3
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- 238000010438 heat treatment Methods 0.000 description 2
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- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- PAAZCQANMCYGAW-UHFFFAOYSA-N acetic acid;2,2,2-trifluoroacetic acid Chemical compound CC(O)=O.OC(=O)C(F)(F)F PAAZCQANMCYGAW-UHFFFAOYSA-N 0.000 description 1
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- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105885844A (zh) * | 2016-04-18 | 2016-08-24 | 中国科学院上海光学精密机械研究所 | 提高稀土离子掺杂无机氟化物上转换发光强度的方法 |
CN110204209A (zh) * | 2019-05-08 | 2019-09-06 | 杭州电子科技大学 | 一种选择性稀土掺杂钪基氟化纳米晶的上转换玻璃陶瓷复合材料 |
CN116023944A (zh) * | 2021-10-26 | 2023-04-28 | 中国科学院福建物质结构研究所 | 一种h+离子掺杂增强发光的稀土无机纳米发光材料及其制备方法和应用 |
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EP0762570A2 (en) * | 1995-09-06 | 1997-03-12 | Hewlett-Packard Company | Laser for the generation of blue light |
RU2295495C1 (ru) * | 2005-11-01 | 2007-03-20 | Государственное образовательное учреждение высшего профессионального образования "Московский государственный институт стали и сплавов" (технологический университет) | СПОСОБ ПОЛУЧЕНИЯ СОЕДИНЕНИЯ KSc2F7 |
CN102086396A (zh) * | 2010-11-25 | 2011-06-08 | 华北电力大学 | 一种CuInS2-ZnS/ZnSe/ZnS核壳结构半导体量子点的制备方法及其在发光器件中的应用 |
CN102268259A (zh) * | 2011-06-14 | 2011-12-07 | 中国科学院长春光学精密机械与物理研究所 | 发光中心分区域掺杂稀土上转换荧光材料及其制备方法 |
CN103305222A (zh) * | 2013-06-18 | 2013-09-18 | 南京大学 | KSc2F7:Yb,Er 上转换荧光纳米棒的制法和用途 |
CN104498039A (zh) * | 2014-12-23 | 2015-04-08 | 湖北大学 | 一种酸辅助制备CdSe/CdS/ZnS核壳结构量子点的合成方法 |
-
2015
- 2015-10-30 CN CN201510727909.1A patent/CN105238405B/zh active Active
Patent Citations (6)
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EP0762570A2 (en) * | 1995-09-06 | 1997-03-12 | Hewlett-Packard Company | Laser for the generation of blue light |
RU2295495C1 (ru) * | 2005-11-01 | 2007-03-20 | Государственное образовательное учреждение высшего профессионального образования "Московский государственный институт стали и сплавов" (технологический университет) | СПОСОБ ПОЛУЧЕНИЯ СОЕДИНЕНИЯ KSc2F7 |
CN102086396A (zh) * | 2010-11-25 | 2011-06-08 | 华北电力大学 | 一种CuInS2-ZnS/ZnSe/ZnS核壳结构半导体量子点的制备方法及其在发光器件中的应用 |
CN102268259A (zh) * | 2011-06-14 | 2011-12-07 | 中国科学院长春光学精密机械与物理研究所 | 发光中心分区域掺杂稀土上转换荧光材料及其制备方法 |
CN103305222A (zh) * | 2013-06-18 | 2013-09-18 | 南京大学 | KSc2F7:Yb,Er 上转换荧光纳米棒的制法和用途 |
CN104498039A (zh) * | 2014-12-23 | 2015-04-08 | 湖北大学 | 一种酸辅助制备CdSe/CdS/ZnS核壳结构量子点的合成方法 |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105885844A (zh) * | 2016-04-18 | 2016-08-24 | 中国科学院上海光学精密机械研究所 | 提高稀土离子掺杂无机氟化物上转换发光强度的方法 |
CN105885844B (zh) * | 2016-04-18 | 2018-04-17 | 中国科学院上海光学精密机械研究所 | 提高稀土离子掺杂无机氟化物上转换发光强度的方法 |
CN110204209A (zh) * | 2019-05-08 | 2019-09-06 | 杭州电子科技大学 | 一种选择性稀土掺杂钪基氟化纳米晶的上转换玻璃陶瓷复合材料 |
CN110204209B (zh) * | 2019-05-08 | 2022-01-04 | 杭州电子科技大学 | 一种选择性稀土掺杂钪基氟化纳米晶的上转换玻璃陶瓷复合材料 |
CN116023944A (zh) * | 2021-10-26 | 2023-04-28 | 中国科学院福建物质结构研究所 | 一种h+离子掺杂增强发光的稀土无机纳米发光材料及其制备方法和应用 |
CN116023944B (zh) * | 2021-10-26 | 2024-11-19 | 中科稀土纳米科技(河北)有限公司 | 一种h+离子掺杂增强发光的稀土无机纳米发光材料及其制备方法和应用 |
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