CN105217802A - A kind of water quality cleansing agent - Google Patents
A kind of water quality cleansing agent Download PDFInfo
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- CN105217802A CN105217802A CN201510733330.6A CN201510733330A CN105217802A CN 105217802 A CN105217802 A CN 105217802A CN 201510733330 A CN201510733330 A CN 201510733330A CN 105217802 A CN105217802 A CN 105217802A
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Abstract
The invention discloses a kind of water quality cleansing agent, its formula comprises each component of following mass fraction: ammonium persulfate-sodium bisulfate 15 ~ 55 parts, thionamic acid 0 ~ 5 part, citric acid 5 ~ 20 parts; 1 ~ 12 part, sodium carbonate, sodium bicarbonate 0 ~ 10 part, 0 ~ 0.5 part, magnesiumcarbonate, Sodium hexametaphosphate 99 0 ~ 9 part, calcium peroxide 15 ~ 30 parts, Sodium dodecylbenzene sulfonate 0 ~ 1 part, sodium lauryl sulphate 0 ~ 2 part, polyoxyethylene glycol 0.05 ~ 0.1 part, Sodium sulfate anhydrous.min(99) 5 ~ 15 parts and complex micro organism fungicide 15 ~ 25 parts.In purification of water quality agent prescription of the present invention, for compound potassium hydrogen persulfate product detoxication technique+beneficial microorganism recovers the sewage disposal technology of microecological balance, instead of and existingly can cause secondary pollution product, there is quick-acting, long-acting advantage, can work in half an hour; And it changes the end, removing toxic substances, sustainable 7 ~ 10 days of antibacterial and water purification effect, the recovery of improvement to water pollution and the eubiosis can be realized in 7 days ~ 1 month.
Description
Technical field
The present invention relates to river course, lake pollution water body treating, landscape water process, aquaculture industry water improvement field, be specially one and be compounded with green chemical and beneficial microorganism water quality cleansing agent.
Background technology
The prior art of administering polluted-water both at home and abroad, can be divided into chemical process, physical method and biological method.Although but these methods existing can purifying water body to a certain extent, has respective shortcoming.
Chemical process generally includes chemicals such as using all kinds of haloid element preparation, tensio-active agent and dioxide peroxide, realize sterilization and the water quality improvement of water body, these products in use all can produce secondary pollution, increase water body viscosity, water bottom is caused to harden, be unfavorable for even being harmful to the foundation of water ecology balance, and to aqueous bio, after cause damage to the animal and human in food chain.
The method of physics is generally and uses the chemical of macromolecular, band polarity and carry out Absorptive complex wave containing the mineral (as zeolite powder) of a large amount of micropore, objectionable impurities is deposited in water bottom, reaches temporary transient water body purification target; But always essentially, objectionable impurities of not degrading, just puts together objectionable impurities, covers in bottom, again can be diffused in water body at any time, cause more serious problem along with the change of water condition.
Conventional biological method is the compounding technology degraded water body ammonia and nitrogen organic with genus bacillus or multiple genus bacillus, by the degraded water body organisms such as milk-acid bacteria, photosynthetic bacterium, nitrobacteria and other objectionable impuritiess containing ammonia nitrogen etc.; The technology relatively environmental protection of microbial treatment water body, but it is long owing to administering the cycle, cost is higher, especially modern water body pollutes because of the pesticide residue in farmland and herbicide residue, because culture fishery and water treatment field use the table such as chlorinated product, the tetrakis hydroxymetyl phosphonium sulfuric series products alive of secondary pollution in a large number, and a large amount of Algae toxins because producing in blue algae growth and death process, cause water body to contain the very strong material of large number of biological toxicity, be difficult to repair by microbial technique.
Develop a kind of green, fundamentally can realize polluting water body disinfection, degraded water body objectionable impurities, transform the superfluous ammonia and nitrogen organic of water body, recovering the water quality cleansing agent of water body microecological balance will be of great advantage to river course, lake pollution water body treating, landscape water process, aquaculture industry water body treating industry.
Summary of the invention
The technical problem to be solved in the present invention overcomes during existing polluted-water is administered to eradicate pollutent or cycle longer defect, provide a kind of green, fundamentally can realize water quality cleansing agent that water body disinfection, degraded water body objectionable impurities are polluted, transformed the superfluous ammonia and nitrogen organic of water body, recover water body microecological balance.
In order to solve the problems of the technologies described above, the invention provides following technical scheme:
A kind of water quality cleansing agent, its formula comprises each component of following mass fraction:
Ammonium persulfate-sodium bisulfate 15 ~ 55 parts, thionamic acid 0 ~ 5 part, citric acid 5 ~ 20 parts; 1 ~ 12 part, sodium carbonate, sodium bicarbonate 0 ~ 10 part, 0 ~ 0.5 part, magnesiumcarbonate, Sodium hexametaphosphate 99 0 ~ 9 part, calcium peroxide 15 ~ 30 parts, Sodium dodecylbenzene sulfonate 0 ~ 1 part, sodium lauryl sulphate 0 ~ 2 part, polyoxyethylene glycol 0.05 ~ 0.1 part, Sodium sulfate anhydrous.min(99) 5 ~ 15 parts and complex micro organism fungicide 15 ~ 25 parts.
Preferably, its formula comprises each component of following mass fraction:
Ammonium persulfate-sodium bisulfate 35 parts, thionamic acid 3 parts, citric acid 12 parts; 5 parts, sodium carbonate, 0.5 part, magnesiumcarbonate, Sodium hexametaphosphate 99 3 parts, calcium peroxide 20 parts; Sodium dodecylbenzene sulfonate 0.5 part, sodium lauryl sulphate 0.92 part, polyoxyethylene glycol 0.08 part, Sodium sulfate anhydrous.min(99) 10 parts and complex micro organism fungicide 20 parts.
Further, the number containing Bacillus subtillis in described complex micro organism fungicide is 15 ~ 5,000,000,000/g, Bacillus licheniformis 0 ~ 3,000,000,000/g, actinomycetes 0 ~ 100,000,000/g, denitrifying bacterium 0 ~ 500,000,000/g and milk-acid bacteria 0 ~ 3,000,000,000/g.
Preferably, the number containing Bacillus subtillis in described complex micro organism fungicide is 2,000,000,000/g, Bacillus licheniformis 1,000,000,000/g, actinomycetes 0.25 hundred million/g, denitrifying bacterium 100,000,000/g and milk-acid bacteria 1,500,000,000/g.
Preferably, described polyoxyethylene glycol is one or several in Macrogol 4000, polyethylene glycol 6000 and PEG 8000.
Ammonium persulfate-sodium bisulfate in purification of water quality agent prescription of the present invention is dissolved in after in water, a large amount of nascent oxygen can be produced, harmful microbial cell wall can be penetrated, with the protein generation crosslinking reaction in the body such as bacterium, virus, and destroy the genetic material such as DNA, RNA, thus kill and suppress harmful microorganism; Organic acid is too high except reducing the PH that too much causes because of ammonia content of water body, simultaneously and carbonate form effervesce reaction, expedite product in the diffusion of water body, increase reaction efficiency; The Trisodium Citrate etc. that effervesce reaction generates, can also active adsorption water body detrimental impurity except as sterilization auxiliary agent, comprises heavy metal etc.; Sodium dodecylbenzene sulfonate and sodium lauryl sulphate itself can reduce water surface tension force, accelerate oxygen in air and, in the dissolving of water body, strengthen the infiltration power to bacteriophage surface simultaneously, strengthen sterilisation effect; Transition metal ion containing sub-valence state in water body, as ferrous ion, divalent manganesetion, divalent cobalt ion etc., these transition metal ions can promote that potassium hydrogen persulfate forms sulphuric acid free radical, the redox potential of sulphuric acid free radical is 2.5 ~ 3.1v, and sulphuric acid free radical is deposited in case at large quantity of moisture, is partially converted to the hydroxy radical qiao of redox potential 2.8v; No matter be sulphuric acid free radical or hydroxy radical qiao, have very high redox potential, can effective degrading pesticide residues, herbicide residue, organic pigment residual, Algae toxins, chloramines class hazard residue etc.; Calcium peroxide composition at water body slow releasing oxygen, can reach 24 ~ 36 hours, except the end detoxifying effect that changes consolidating compound potassium hydrogen persulfate formula (mainly controls the generation of the material such as nitrite and hydrogen sulfide.When the dissolved oxygen of water body reaches 5ppm and is above, enough oxygen is had as electron acceptor(EA) in water, utilize nitrate ion etc. as electron acceptor(EA) when instead of fermentable, now nitrite can not be produced, hydrogen sulfide, ferrous ion, the objectionable impuritiess such as divalent manganesetion, only have when Dissolved Oxygen in Water is lower than 3ppm, nitrobacteria just starts to utilize nitrate ion as electron acceptor(EA), produce harmful nitrite ion, and along with the further reduction of dissolved oxygen and water body redox potential, microbiological anaerobic ferments, just can produce hydrogen sulfide successively, the material of the polluted-water environment that ferrous ion etc. is harmful), constantly supplement water body dissolved oxygen simultaneously, for the beneficial microorganism starting growth and breeding after activation provides oxygen as electron acceptor(EA), promote that microorganism is to the conversion of water body ammonia and nitrogen organic matter.
Compared with prior art, the present invention has following beneficial effect:
One, water quality cleansing agent of the present invention, can to degrade all kinds of noxious pollutant of water body, both general objectionable impurities had been comprised as reducing substanceses such as nitrite, sulfide, ferrous ions, comprise again the objectionable impurities that the various bio-toxicities such as degradation of polychlorinated biphenyl, polycyclic aromatic hydrocarbons, Algae toxins, organic pigment are large, these noxious pollutants are all the problems that current water purification technology is difficult to solve;
Two, water quality cleansing agent of the present invention can control harmful microorganism in water body fast, comprise vibrios, fungi and because playing all kinds of unwanted bacteria of fishes and shrimps common disease and virus, also harmful blue-green algae, Euglena and dinoflagellate is comprised, and by improving the environmental improvement that water body redox potential grows applicable harmful microorganism;
Three, water quality cleansing agent of the present invention solves the suspension recycling problem of water bottom precipitating organic matters: water quality cleansing agent of the present invention can make sediment become fluffy, solve substrate to harden problem, can suspend being formed after the detoxicating organic matter being deposited in sediment small-particle simultaneously, after adsorbing the supplementary carbon source of this product, form a large amount of organic floc sedimentations, become the hotbed of next step beneficial microorganism growth and breeding;
Four, water quality cleansing agent of the present invention can make full use of legion's fighting technique of different bacterium, composite several bacterium promote mutually, Each performs its own functions, organic substance superfluous in further decomposition water body and substrate, they are converted into algae, all kinds of protozoic nutrition source, form optimum Tiny ecosystem circulation;
Five, the compound potassium hydrogen persulfate removing toxic substances that in purification of water quality agent prescription of the present invention, first works and disinfection technology, take into full account subtilis, the impact of actinomycetes and denitrifying bacterium, can not to the subtilis of resting stage and reactivation process, actinomycetes and denitrifying bacterium produce and suppress and kill and wound, its effect is after two hours, disinfection composition runs out of in the environment, subtilis, normal bacterial propagule is formed after actinomycetes and denitrifying bacterium activation, just effectively utilize through removing toxic substances, environment after sterilization and redox potential improve, and be adsorbed on the organic floc sedimentation after removing toxic substances in a large number, form the normal Tiny ecosystem of water body,
Six, water quality cleansing agent of the present invention has quick-acting, long-acting advantage, can work in half an hour; And it changes the end, removing toxic substances, sustainable 7 ~ 10 days of antibacterial and water purification effect, the recovery of improvement to water pollution and the eubiosis can be realized in 7 days ~ 1 month.
In purification of water quality agent prescription of the present invention, for compound potassium hydrogen persulfate product detoxication technique+beneficial microorganism recovers the sewage disposal technology of microecological balance, instead of chlorinated product, dioxide peroxide, tetrakis hydroxymetyl phosphonium sulfuric etc. and have secondary pollution product, water pollution can be eradicated and recover water body Tiny ecosystem.After using this product to carry out maintenance to water body, in the substrate of water body, organism forms normal Conversion of energy, for aqueous bio utilizes, decrease the trouble of the desiltings such as aquaculture water, river course, lake, achieve the preventive management of aquaculture, reduce the chance that disease occurs, reduce antibiotic use, not only make culture fishery go on green cultivation pattern, and avoid current aquaculture industry to the pollution at regional water source.
Embodiment
Below the preferred embodiments of the present invention are described, should be appreciated that preferred embodiment described herein is only for instruction and explanation of the present invention, is not intended to limit the present invention.
Embodiment 1
A kind of water quality cleansing agent, its formula comprises each component of following mass fraction:
Ammonium persulfate-sodium bisulfate 15 parts, citric acid 5 parts; 1 part, sodium carbonate, calcium peroxide 15 parts, Macrogol 4000 0.05 part, Sodium sulfate anhydrous.min(99) 5 parts and complex micro organism fungicide 15 parts.Number containing Bacillus subtillis in complex micro organism fungicide is 1,500,000,000/g
The water quality cleansing agent of this formula can be used for processing and pollute lighter river course, lake pollution water body treating, landscape water process, aquaculture industry water improvement field, there is quick-acting, long-acting advantage, the recovery of improvement to water pollution and the eubiosis can be realized the soonest in 7 days.
Embodiment 2
A kind of water quality cleansing agent, its formula comprises each component of following mass fraction:
Ammonium persulfate-sodium bisulfate 35 parts, thionamic acid 3 parts, citric acid 12 parts; 5 parts, sodium carbonate, 0.5 part, magnesiumcarbonate, Sodium hexametaphosphate 99 3 parts, calcium peroxide 20 parts; Sodium dodecylbenzene sulfonate 0.5 part, sodium lauryl sulphate 0.92 part, polyethylene glycol 6000 0.08 part, Sodium sulfate anhydrous.min(99) 10 parts and complex micro organism fungicide 20 parts.Wherein, the number containing Bacillus subtillis in complex micro organism fungicide is 2,000,000,000/g, Bacillus licheniformis 1,000,000,000/g, actinomycetes 0.25 hundred million/g, denitrifying bacterium 100,000,000/g and milk-acid bacteria 5,000,000,000/g.
The water quality cleansing agent of this formula is more representative formula, alignment degree and serious pollution, all can realize the recovery of improvement to water pollution and the eubiosis in 7 days ~ 1 month.
Embodiment 3
A kind of water quality cleansing agent, its formula comprises each component of following mass fraction:
Ammonium persulfate-sodium bisulfate 55 parts, thionamic acid 5 parts, citric acid 20 parts; 12 parts, sodium carbonate, sodium bicarbonate 10 parts, 0.5 part, magnesiumcarbonate, Sodium hexametaphosphate 99 9 parts, calcium peroxide 30 parts, Sodium dodecylbenzene sulfonate 1 part, sodium lauryl sulphate 2 parts, Macrogol 4000 and PEG 8000 totally 0.1 part, Sodium sulfate anhydrous.min(99) 15 parts and complex micro organism fungicide 25 parts.Number containing Bacillus subtillis in complex micro organism fungicide is 1,500,000,000/g, Bacillus licheniformis 3,000,000,000/g, actinomycetes 100,000,000/g, denitrifying bacterium 500,000,000/g and milk-acid bacteria 3,000,000,000/g.
Purification of water quality agent prescription emphasis in the present embodiment, for polluting more serious waters, generally can realize the recovery of improvement to water pollution and the eubiosis, play satisfied recovery effects in 15 days ~ 1 month.
Last it is noted that the foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, although with reference to previous embodiment to invention has been detailed description, for a person skilled in the art, it still can be modified to the technical scheme described in foregoing embodiments, or carries out equivalent replacement to wherein portion of techniques feature.Within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (5)
1. a water quality cleansing agent, is characterized in that, its formula comprises each component of following mass fraction:
Ammonium persulfate-sodium bisulfate 15 ~ 55 parts, thionamic acid 0 ~ 5 part, citric acid 5 ~ 20 parts; 1 ~ 12 part, sodium carbonate, sodium bicarbonate 0 ~ 10 part, 0 ~ 0.5 part, magnesiumcarbonate, Sodium hexametaphosphate 99 0 ~ 9 part, calcium peroxide 15 ~ 30 parts, Sodium dodecylbenzene sulfonate 0 ~ 1 part, sodium lauryl sulphate 0 ~ 2 part, polyoxyethylene glycol 0.05 ~ 0.1 part, Sodium sulfate anhydrous.min(99) 5 ~ 15 parts and complex micro organism fungicide 15 ~ 25 parts.
2. a kind of water quality cleansing agent as described in claim 1, is characterized in that, its formula comprises each component of following mass fraction:
Ammonium persulfate-sodium bisulfate 35 parts, thionamic acid 3 parts, citric acid 12 parts; 5 parts, sodium carbonate, 0.5 part, magnesiumcarbonate, Sodium hexametaphosphate 99 3 parts, calcium peroxide 20 parts, Sodium dodecylbenzene sulfonate 0.5 part, sodium lauryl sulphate 0.92 part, polyoxyethylene glycol 0.08 part, Sodium sulfate anhydrous.min(99) 10 parts and complex micro organism fungicide 20 parts.
3. a kind of water quality cleansing agent as described in claim 1 or 2, it is characterized in that, number containing Bacillus subtillis in described complex micro organism fungicide is 15 ~ 5,000,000,000/g, Bacillus licheniformis 0 ~ 3,000,000,000/g, actinomycetes 0 ~ 100,000,000/g, denitrifying bacterium 0 ~ 500,000,000/g and milk-acid bacteria 0 ~ 3,000,000,000/g.
4. a kind of water quality cleansing agent as described in claim 1 or 2, it is characterized in that, number containing Bacillus subtillis in described complex micro organism fungicide is 2,000,000,000/g, Bacillus licheniformis 1,000,000,000/g, actinomycetes 0.25 hundred million/g, denitrifying bacterium 100,000,000/g and milk-acid bacteria 1,500,000,000/g.
5. a kind of water quality cleansing agent as described in claim 1 or 2, is characterized in that, described polyoxyethylene glycol is one or several in Macrogol 4000, polyethylene glycol 6000 and PEG 8000.
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| CN105601046A (en) * | 2016-03-10 | 2016-05-25 | 蒋安美 | Domestic sewage treatment method |
| CN105941297A (en) * | 2016-05-05 | 2016-09-21 | 广州力必拓生物科技有限公司 | Calcium magnesium salt parallel conditioning agent for cultural water environment and use method and applications |
| CN106241911A (en) * | 2016-08-29 | 2016-12-21 | 连云港永荣生物科技有限公司 | A kind of efficiently water quality cleansing agent |
| CN106335949A (en) * | 2016-11-23 | 2017-01-18 | 郑州源冉生物技术有限公司 | Composite and highly efficient sewage treatment agent from waste plastics and preparation method thereof |
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