CN107021562B - Environment-friendly ammonia nitrogen removal water treatment agent - Google Patents
Environment-friendly ammonia nitrogen removal water treatment agent Download PDFInfo
- Publication number
- CN107021562B CN107021562B CN201710296211.8A CN201710296211A CN107021562B CN 107021562 B CN107021562 B CN 107021562B CN 201710296211 A CN201710296211 A CN 201710296211A CN 107021562 B CN107021562 B CN 107021562B
- Authority
- CN
- China
- Prior art keywords
- ammonia nitrogen
- sodium
- stirrer
- hydroxide
- water treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 58
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 title claims abstract description 46
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 25
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 48
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 34
- 238000003756 stirring Methods 0.000 claims abstract description 29
- 238000000034 method Methods 0.000 claims abstract description 27
- 241000894006 Bacteria Species 0.000 claims abstract description 22
- 229920002401 polyacrylamide Polymers 0.000 claims abstract description 19
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract description 18
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims abstract description 18
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 17
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 17
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 17
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 17
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 17
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 17
- QQFLQYOOQVLGTQ-UHFFFAOYSA-L magnesium;dihydrogen phosphate Chemical compound [Mg+2].OP(O)([O-])=O.OP(O)([O-])=O QQFLQYOOQVLGTQ-UHFFFAOYSA-L 0.000 claims abstract description 17
- 229910000401 monomagnesium phosphate Inorganic materials 0.000 claims abstract description 17
- 235000019785 monomagnesium phosphate Nutrition 0.000 claims abstract description 17
- 239000010457 zeolite Substances 0.000 claims abstract description 17
- LWEAHXKXKDCSIE-UHFFFAOYSA-M 2,3-di(propan-2-yl)naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S([O-])(=O)=O)=C(C(C)C)C(C(C)C)=CC2=C1 LWEAHXKXKDCSIE-UHFFFAOYSA-M 0.000 claims abstract description 16
- 239000005708 Sodium hypochlorite Substances 0.000 claims abstract description 16
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 16
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims abstract description 16
- LKCUKVWRIAZXDU-UHFFFAOYSA-L zinc;hydron;phosphate Chemical compound [Zn+2].OP([O-])([O-])=O LKCUKVWRIAZXDU-UHFFFAOYSA-L 0.000 claims abstract description 16
- 229940077386 sodium benzenesulfonate Drugs 0.000 claims abstract description 13
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 239000008367 deionised water Substances 0.000 claims abstract description 6
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 6
- 238000005303 weighing Methods 0.000 claims abstract description 5
- XRGVGHCBGYMWDJ-UHFFFAOYSA-M sodium 2,3,4,5-tetrakis(prop-1-enyl)benzenesulfonate Chemical compound C(=CC)C=1C(=C(C(=C(C=1)S(=O)(=O)[O-])C=CC)C=CC)C=CC.[Na+] XRGVGHCBGYMWDJ-UHFFFAOYSA-M 0.000 claims abstract description 3
- 238000002360 preparation method Methods 0.000 abstract description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 12
- 239000003651 drinking water Substances 0.000 description 10
- 235000020188 drinking water Nutrition 0.000 description 10
- 230000000694 effects Effects 0.000 description 8
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 7
- 238000001179 sorption measurement Methods 0.000 description 7
- 229910021529 ammonia Inorganic materials 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 241000108664 Nitrobacteria Species 0.000 description 5
- 238000010170 biological method Methods 0.000 description 4
- 239000003344 environmental pollutant Substances 0.000 description 4
- 238000005189 flocculation Methods 0.000 description 4
- 230000016615 flocculation Effects 0.000 description 4
- 231100000719 pollutant Toxicity 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000000701 coagulant Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000012851 eutrophication Methods 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000011573 trace mineral Substances 0.000 description 2
- 235000013619 trace mineral Nutrition 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- CKMXBZGNNVIXHC-UHFFFAOYSA-L ammonium magnesium phosphate hexahydrate Chemical compound [NH4+].O.O.O.O.O.O.[Mg+2].[O-]P([O-])([O-])=O CKMXBZGNNVIXHC-UHFFFAOYSA-L 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 231100000481 chemical toxicant Toxicity 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 229920000592 inorganic polymer Polymers 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 230000001546 nitrifying effect Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 229910052567 struvite Inorganic materials 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Microbiology (AREA)
- Biodiversity & Conservation Biology (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Water Treatment By Sorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
An environment-friendly water treatment agent for removing ammonia nitrogen is prepared from the following raw materials: nitrite bacteria, polyacrylamide, tetrapropenyl sodium benzenesulfonate, nekal, polyferric chloride, sodium hydroxide, sodium hypochlorite, zeolite, zinc hydrogen phosphate, magnesium dihydrogen phosphate, aluminum hydroxide, magnesium hydroxide and phosphoric acid. The preparation method of the environment-friendly water treatment agent for removing ammonia nitrogen comprises the following steps: the method comprises the following steps: a. weighing polyacrylamide, sodium tetrapropenylbenzenesulfonate, nekal, polyferric chloride and deionized water, adding into a stirrer, and stirring uniformly. b. Sequentially adding sodium hydroxide, sodium hypochlorite, zeolite, zinc hydrogen phosphate, magnesium dihydrogen phosphate, aluminum hydroxide and magnesium hydroxide into a stirrer, and uniformly stirring. c. Adding nitrite bacteria into a stirrer, and stirring uniformly. d. Adding phosphoric acid into a stirrer, and uniformly stirring to obtain the treating agent. The water treatment agent for removing ammonia nitrogen provided by the invention has the advantages of low cost and high ammonia nitrogen removal efficiency, and is suitable for wide popularization.
Description
Technical Field
The invention belongs to the technical field of water treatment, and particularly relates to an environment-friendly water treatment agent for removing ammonia nitrogen.
background
In recent years, the aggravation of water pollution of water sources, the improvement of water quality standards of drinking water and the enhancement of environmental awareness of people bring severe challenges to the field of drinking water treatment in China. Ammonia nitrogen pollutants generally exist in water source water in China, and are difficult to remove by a conventional water treatment process, so that the ammonia nitrogen pollutants become one of main pollutants for drinking water treatment, and particularly, the ammonia nitrogen in a low-temperature stage is difficult to treat.
at present, the methods for removing ammonia nitrogen in the drinking water treatment process mainly comprise a physical chemical method and a biological method. (1) The breakpoint chlorination method is one of the main methods for removing ammonia nitrogen in drinking water production, has the characteristics of no influence of temperature, quick reaction and high efficiency, but has the problems of large dosage of liquid chlorine, high control requirement and easy generation of toxic and harmful byproducts. (2) The adsorption method for removing ammonia nitrogen is to remove ammonia nitrogen by physical and chemical methods such as adsorption or ion exchange by using an adsorbent, such as zeolite, a nano molecular sieve and the like. Although the adsorption method can achieve a relatively ideal effect on the removal of ammonia nitrogen, the removal rate is influenced by various factors such as the characteristics of an adsorbent, contact time, background components in water and the like, and the adsorption method also has the defects of limited adsorption capacity, frequent regeneration and the like. (3) The biological method for removing ammonia nitrogen is one of the most common methods for controlling ammonia nitrogen in drinking water, the principle is that the ammonia nitrogen in the water is removed by means of the metabolic activity of microorganisms attached to a filler, and the method has the characteristics of economy and simplicity in operation, and has a wide application space in the aspect of drinking water ammonia nitrogen control. However, the drinking water biological method ammonia nitrogen removal process is influenced by various factors such as temperature, water quality and the like, and particularly, the biological activity is inhibited in a low-temperature environment (such as half-year low-temperature stage of Harbin source water), so that the ammonia nitrogen removal efficiency is obviously reduced. Therefore, research and development of a water treatment technology for efficiently, economically and simply removing ammonia nitrogen and ensuring the water quality safety of drinking water become a difficult task for water treatment researchers.
Pollution treatment, energy conservation and emission reduction become important subjects for implementing sustainable development strategies in China, and ammonia nitrogen wastewater as an important pollutant of water eutrophication becomes the key point of treatment. After ammonia nitrogen wastewater is discharged into water bodies such as lakes, reservoirs, estuaries, gulfs and the like, eutrophication of the water bodies is caused, aquatic organisms, particularly algae, propagate in large quantities, the ecological balance of the water bodies is destroyed, and water quality deterioration and fish death are caused. Therefore, the ammonia nitrogen removal technology is becoming a hotspot for research, development and application in the field of wastewater treatment. Therefore, ammonia nitrogen in the wastewater must be treated.
At present, a plurality of processes for removing ammonia nitrogen are applied to water treatment engineering, such as an ozone activated carbon method, a breakpoint chlorine adding method, a biological method, a stripping method, an ammonia steaming method, a gas-water separation membrane method and the like. However, the above processes for removing ammonia nitrogen all have certain disadvantages, such as generation of triple pollution, secondary pollution to air, large equipment investment, high treatment cost and limited removal rate of ammonia nitrogen.
Disclosure of Invention
aiming at the problems in the prior art, the invention aims to provide the environment-friendly ammonia nitrogen removing water treatment agent which is low in cost and high in ammonia nitrogen removing efficiency.
in order to achieve the effect, the invention is realized by the following technical scheme:
An environment-friendly water treatment agent for removing ammonia nitrogen is prepared from the following raw materials: nitrite bacteria, polyacrylamide, tetrapropenyl sodium benzenesulfonate, nekal, polyferric chloride, sodium hydroxide, sodium hypochlorite, zeolite, zinc hydrogen phosphate, magnesium dihydrogen phosphate, aluminum hydroxide, magnesium hydroxide and phosphoric acid.
the raw materials comprise, by weight, 180 ~ 220g of nitrite bacteria, 6 ~ 10g of polyacrylamide, 45 ~ 55g of tetrapropenyl sodium benzenesulfonate, 25 ~ 35g of nekal, 75 ~ 85g of polyferric chloride, 15 ~ 25g of sodium hydroxide, 20 ~ 30g of sodium hypochlorite, 15 ~ 25g of zeolite, 6 ~ 10g of zinc hydrogen phosphate, 8 ~ 12g of magnesium dihydrogen phosphate, 12 ~ 18g of aluminum hydroxide, 18 ~ 22g of magnesium hydroxide and 18 ~ 22g of phosphoric acid.
Part of the components of the environment-friendly ammonia nitrogen removal water treatment agent have the following functions:
Tetrapropenyl sodium benzenesulfonate is sensitive to water hardness, not easy to oxidize, strong in foaming power, high in detergency, easy to be compounded with various assistants, low in cost and very excellent in anionic surfactant.
Polyacrylamide (PAM) -is a linear organic high molecular polymer and is a high molecular water treatment flocculant product, can adsorb suspended particles in water, plays a role in bridging among the particles, enables fine particles to form larger flocs, and accelerates the speed of precipitation. This process is called flocculation, and PAM is widely used as a flocculant for water treatment because of its good flocculation effect.
Polyferric chloride, a novel high-efficiency inorganic polymer coagulant, has good flocculation effect and low price, and has better water purification effect than the traditional aluminum sulfate, iron salt and other common inorganic salt coagulants. The polyaluminum ferric chloride is very soluble in water, and can be used for treating drinking water, industrial wastewater and domestic sewage. The coagulation effect is characterized by reduced residual turbidity chroma, floc forming blocks, high adsorption performance, good sludge filtration and dehydration performance and the like, and particularly, the treatment effect is better than that of alum, polyaluminium chloride, polyferric sulfate and ferric trioxide when high-turbidity water and low-temperature low-turbidity water are treated. Wherein, the effect of the purification treatment of low-temperature and low-turbidity water is particularly obvious.
zinc phosphate, inorganic nitrogen and phosphorus and trace elements necessary for the growth of nitrobacteria, and also contains growth-promoting substances, so that the growth speed of the nitrobacteria can be increased.
Nitrite bacteria, a class of bacteria that eliminate (via oxidation) ammonia in aquatic ecosystems and produce nitrous acid, the bacterium of the genus nitrite, commonly referred to as the "oxidator of ammonia," is sufficiently viable because its food source is ammonia, and the chemical energy generated by the combination of ammonia and oxygen. Bacteria capable of oxidizing nitrous acid molecules and converting the nitrous acid molecules into nitric acid molecules. Bacteria of the genus nitrobacteria, commonly referred to as "oxidators of nitrous acid", are capable of generating nitric acid by combination with oxygen, as their food source is nitrous acid (although this is not necessarily nitrous acid, other organic matter is possible), and the chemical energy generated is sufficient to enable them to survive. The nitrifying bacteria can decompose and remove toxic chemicals (ammonia and nitrous acid) in water, so that the water quality can be purified.
Magnesium dihydrogen phosphate, which is inorganic nitrogen phosphorus and trace elements necessary for the growth of nitrobacteria, also comprises a growth-promoting substance, and can accelerate the growth of the nitrobacteria.
Magnesium hydroxide: reacting with ammonia nitrogen particles in water together with phosphoric acid to generate MgNH4PO4.6H2O (struvite) precipitate, and granulating the precipitate to obtain the compound fertilizer.
The preparation method of the environment-friendly water treatment agent for removing ammonia nitrogen comprises the following steps:
a. Weighing polyacrylamide, sodium tetrapropenylbenzenesulfonate, nekal, polyferric chloride and deionized water, adding into a stirrer, and stirring uniformly;
b. Sequentially adding sodium hydroxide, sodium hypochlorite, zeolite, zinc hydrogen phosphate, magnesium dihydrogen phosphate, aluminum hydroxide and magnesium hydroxide into a stirrer, and uniformly stirring;
c. adding nitrite bacteria into a stirrer, and uniformly stirring;
d. Adding phosphoric acid into a stirrer, and uniformly stirring to obtain the treating agent.
The invention has the beneficial effects that: the water treatment agent for removing ammonia nitrogen provided by the invention has low cost, can quickly remove ammonia nitrogen in water by adopting a microorganism ammonia nitrogen removal method and a precipitation method, better plays roles of oxidation, adsorption, flocculation, precipitation, sterilization, disinfection and the like, has high ammonia nitrogen removal efficiency, and is suitable for wide popularization.
Detailed Description
For easy understanding, the technical solution of the present invention is further described in detail by examples:
Example 1:
an environment-friendly water treatment agent for removing ammonia nitrogen is prepared from the following raw materials: nitrite bacteria, polyacrylamide, tetrapropenyl sodium benzenesulfonate, nekal, polyferric chloride, sodium hydroxide, sodium hypochlorite, zeolite, zinc hydrogen phosphate, magnesium dihydrogen phosphate, aluminum hydroxide, magnesium hydroxide and phosphoric acid.
The raw materials comprise the following components in parts by weight:
200g of nitrite bacteria, 8g of polyacrylamide, 50g of tetrapropenyl sodium benzenesulfonate, 30g of nekal, 80g of polyferric chloride, 20g of sodium hydroxide, 25g of sodium hypochlorite, 20g of zeolite, 8g of zinc hydrogen phosphate, 10g of magnesium dihydrogen phosphate, 15g of aluminum hydroxide, 20g of magnesium hydroxide and 20g of phosphoric acid.
the preparation process of the environment-friendly water treatment agent for removing ammonia nitrogen comprises the following steps:
a. Weighing 8g of polyacrylamide, 50g of tetrapropenyl sodium benzenesulfonate, 30g of nekal, 80g of polyferric chloride and 0.1 ton of deionized water, adding into a stirrer, and stirring uniformly.
b. and (b) sequentially adding 20g of sodium hydroxide, 25g of sodium hypochlorite, 20g of zeolite, 8g of zinc hydrogen phosphate, 10g of magnesium dihydrogen phosphate, 15g of aluminum hydroxide and 20g of magnesium hydroxide into the stirrer in the step a, and stirring for thirty minutes.
c. and (b) adding 200g of nitrite bacteria into the stirrer in the step (b), stirring for ten minutes, and uniformly stirring.
d. And (c) adding 20g of phosphoric acid into the stirrer in the step (c), stirring for ten minutes, and uniformly stirring to obtain the treating agent.
Example 2:
an environment-friendly water treatment agent for removing ammonia nitrogen is prepared from the following raw materials: nitrite bacteria, polyacrylamide, tetrapropenyl sodium benzenesulfonate, nekal, polyferric chloride, sodium hydroxide, sodium hypochlorite, zeolite, zinc hydrogen phosphate, magnesium dihydrogen phosphate, aluminum hydroxide, magnesium hydroxide and phosphoric acid.
the raw materials comprise the following components in parts by weight: 180g of nitrite bacteria, 6g of polyacrylamide, 45g of tetrapropenyl sodium benzenesulfonate, 25g of nekal, 75g of polyferric chloride, 15g of sodium hydroxide, 20g of sodium hypochlorite, 15g of zeolite, 6g of zinc hydrogen phosphate, 8g of magnesium dihydrogen phosphate, 12g of aluminum hydroxide, 18g of magnesium hydroxide and 18g of phosphoric acid.
The preparation process of the environment-friendly water treatment agent for removing ammonia nitrogen comprises the following steps:
a. 6g of polyacrylamide, 45g of tetrapropenyl sodium benzenesulfonate, 25g of nekal, 75g of polyferric chloride and 0.1 ton of deionized water are weighed and added into a stirrer to be uniformly stirred.
b. And (b) sequentially adding 15g of sodium hydroxide, 20g of sodium hypochlorite, 15g of zeolite, 6g of zinc hydrogen phosphate, 8g of magnesium dihydrogen phosphate, 12g of aluminum hydroxide and 18g of magnesium hydroxide into the stirrer in the step a, and stirring for thirty minutes.
c. And (b) adding 180g of nitrite bacteria into the stirrer in the step (b), stirring for ten minutes, and uniformly stirring.
d. And (c) adding 18g of phosphoric acid into the stirrer in the step (c), stirring for ten minutes, and uniformly stirring to obtain the treating agent.
example 3:
An environment-friendly water treatment agent for removing ammonia nitrogen is prepared from the following raw materials: nitrite bacteria, polyacrylamide, tetrapropenyl sodium benzenesulfonate, nekal, polyferric chloride, sodium hydroxide, sodium hypochlorite, zeolite, zinc hydrogen phosphate, magnesium dihydrogen phosphate, aluminum hydroxide, magnesium hydroxide and phosphoric acid.
The raw materials comprise the following components in parts by weight: 220g of nitrite bacteria, 10g of polyacrylamide, 55g of tetrapropenyl sodium benzenesulfonate, 35g of nekal, 85g of polyferric chloride, 25g of sodium hydroxide, 30g of sodium hypochlorite, 25g of zeolite, 10g of zinc hydrogen phosphate, 12g of magnesium dihydrogen phosphate, 18g of aluminum hydroxide, 22g of magnesium hydroxide and 22g of phosphoric acid.
The preparation process of the environment-friendly water treatment agent for removing ammonia nitrogen comprises the following steps:
a. Weighing 10g of polyacrylamide, 55g of tetrapropenylsodium benzenesulfonate, 35g of nekal, 85g of polyferric chloride and 0.1 ton of deionized water, adding into a stirrer, and stirring uniformly.
b. And (b) sequentially adding 25g of sodium hydroxide, 30g of sodium hypochlorite, 25g of zeolite, 10g of zinc hydrogen phosphate, 12g of magnesium dihydrogen phosphate, 18g of aluminum hydroxide and 22g of magnesium hydroxide into the stirrer in the step a, and stirring for thirty minutes.
c. And (b) adding 220g of nitrite bacteria into the stirrer in the step (b), stirring for ten minutes, and uniformly stirring.
d. And (c) adding 22g of phosphoric acid into the stirrer in the step (c), stirring for ten minutes, and uniformly stirring to obtain the treating agent.
the above embodiments are merely illustrative or explanatory of the technical solution of the present invention and should not be construed as limiting the technical solution of the present invention, and it is apparent that various modifications and variations can be made by those skilled in the art without departing from the spirit and scope of the present invention. The present invention also encompasses these modifications and variations provided they come within the scope of the claims and their equivalents.
Claims (2)
1. An environment-friendly water treatment agent for removing ammonia nitrogen is characterized in that: the health-care food is prepared from the following raw materials in parts by weight: 180-220 g of nitrite bacteria, 6-10 g of polyacrylamide, 45-55 g of tetrapropenyl sodium benzenesulfonate, 25-35 g of nekal, 75-85 g of polyferric chloride, 15-25 g of sodium hydroxide, 20-30 g of sodium hypochlorite, 15-25 g of zeolite, 6-10 g of zinc hydrogen phosphate, 8-12 g of magnesium dihydrogen phosphate, 12-18 g of aluminum hydroxide, 18-22 g of magnesium hydroxide and 18-22 g of phosphoric acid.
2. The method for preparing the environment-friendly ammonia nitrogen removing water treatment agent according to claim 1: the method is characterized in that: the method comprises the following steps:
a. weighing polyacrylamide, sodium tetrapropenylbenzenesulfonate, nekal, polyferric chloride and deionized water, adding into a stirrer, and stirring uniformly;
b. Sequentially adding sodium hydroxide, sodium hypochlorite, zeolite, zinc hydrogen phosphate, magnesium dihydrogen phosphate, aluminum hydroxide and magnesium hydroxide into a stirrer, and uniformly stirring;
c. Adding nitrite bacteria into a stirrer, and uniformly stirring;
d. Adding phosphoric acid into a stirrer, and uniformly stirring to obtain the treating agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710296211.8A CN107021562B (en) | 2017-04-28 | 2017-04-28 | Environment-friendly ammonia nitrogen removal water treatment agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710296211.8A CN107021562B (en) | 2017-04-28 | 2017-04-28 | Environment-friendly ammonia nitrogen removal water treatment agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107021562A CN107021562A (en) | 2017-08-08 |
| CN107021562B true CN107021562B (en) | 2019-12-13 |
Family
ID=59528227
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710296211.8A Active CN107021562B (en) | 2017-04-28 | 2017-04-28 | Environment-friendly ammonia nitrogen removal water treatment agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107021562B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111115846A (en) * | 2019-12-30 | 2020-05-08 | 漳州傲农现代农业开发有限公司 | Sewage treatment agent for aquaculture wastewater and preparation method and application thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011107984A3 (en) * | 2010-03-01 | 2011-11-10 | Technion- Research And Development Foundation Ltd. | System and process for the treatment of wastewater comprising organic materials, phosphate and ammonium |
| CN102952765A (en) * | 2011-08-31 | 2013-03-06 | 中国石油化工股份有限公司 | Enrichment culture method of salt-tolerant efficient nitrosobacteria |
| CN105016494A (en) * | 2015-07-30 | 2015-11-04 | 陈朝民 | Composite water treatment agent |
| CN105217802A (en) * | 2015-10-29 | 2016-01-06 | 余姜 | A kind of water quality cleansing agent |
| CN106186235A (en) * | 2016-08-22 | 2016-12-07 | 陈永桥 | A kind of high-efficiency sewage ammonia nitrogen removal agent |
| CN106497846A (en) * | 2016-12-14 | 2017-03-15 | 钦州学院 | A kind of wastewater treatment microbial microbial inoculum and preparation method thereof |
-
2017
- 2017-04-28 CN CN201710296211.8A patent/CN107021562B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011107984A3 (en) * | 2010-03-01 | 2011-11-10 | Technion- Research And Development Foundation Ltd. | System and process for the treatment of wastewater comprising organic materials, phosphate and ammonium |
| CN102952765A (en) * | 2011-08-31 | 2013-03-06 | 中国石油化工股份有限公司 | Enrichment culture method of salt-tolerant efficient nitrosobacteria |
| CN105016494A (en) * | 2015-07-30 | 2015-11-04 | 陈朝民 | Composite water treatment agent |
| CN105217802A (en) * | 2015-10-29 | 2016-01-06 | 余姜 | A kind of water quality cleansing agent |
| CN106186235A (en) * | 2016-08-22 | 2016-12-07 | 陈永桥 | A kind of high-efficiency sewage ammonia nitrogen removal agent |
| CN106497846A (en) * | 2016-12-14 | 2017-03-15 | 钦州学院 | A kind of wastewater treatment microbial microbial inoculum and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107021562A (en) | 2017-08-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN112374705B (en) | High-salinity wastewater treatment process for iron and steel enterprises | |
| CN102701345B (en) | Preoxidation-coagulation algae removing method based on in-situ generation of double coagulants | |
| CN102616980B (en) | Treatment method of chromium-containing high concentration organic wastewater | |
| CN101618919A (en) | Method for processing waste water produced by caprolactam ammoximation process | |
| CN110357347B (en) | Method for treating wastewater by persulfate advanced oxidation coupling biological sulfate reduction | |
| CN107352743B (en) | Method for treating folic acid waste mother liquor water | |
| KR101543551B1 (en) | Wastewater treatment system using electrolysis | |
| CN115448534A (en) | Treatment method and system for lithium iron phosphate wastewater | |
| CN112194282A (en) | Method for chemically removing chloride ions | |
| CN107021562B (en) | Environment-friendly ammonia nitrogen removal water treatment agent | |
| CN103896457A (en) | Fine chemical wastewater treatment process | |
| CN114409196B (en) | Treatment method of antibiotic pharmaceutical wastewater | |
| CN102126813A (en) | System and process for treating oxytetracycline waste water by anaerobic bio-treatment method | |
| CN108101297B (en) | Method for treating pesticide wastewater containing dithioformate | |
| CN107188378A (en) | Pyrazolone production wastewater treatment device and its handling process | |
| CN114133097A (en) | Treatment process of pharmaceutical intermediate production wastewater | |
| CN105621576A (en) | Composite aluminum-iron water purifier and production method thereof | |
| CN113526778A (en) | Treatment process of high-concentration industrial wastewater | |
| CN102701542B (en) | Method for treating sewage containing cyanogen, nickel and fluorine | |
| CN110627300A (en) | Hospital sewage environmental protection processing system | |
| CN106830246B (en) | Aluminum-based composite polymer coagulant for treating micro-polluted source water and preparation method thereof | |
| CN103113004B (en) | Biochemical treatment technology for high-concentration tert-butyl alcohol wastewater | |
| CN109534539B (en) | Physicochemical combination process based on chlorella aging liquid recycling treatment | |
| CN102139944B (en) | Method for treating high-concentration ammonia nitrogen waste water by utilizing ferric sulfate | |
| CN117003327A (en) | Efficient sewage organic matter remover and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20191120 Address after: Yixing City, Xu Yifeng village 214241 Jiangsu city of Wuxi Province Applicant after: JIANGSU YIJING WATER TREATMENT CHEMICAL Co.,Ltd. Address before: 510000 Guangzhou High-tech Industrial Development Zone Science Avenue 231, 233 Skirt Building B1B2, 1st, 2nd, 3rd and 4th floors Applicant before: BOAO ZONGHENG NETWORK TECHNOLOGY Co.,Ltd. Effective date of registration: 20191120 Address after: 510000 Guangzhou High-tech Industrial Development Zone Science Avenue 231, 233 Skirt Building B1B2, 1st, 2nd, 3rd and 4th floors Applicant after: BOAO ZONGHENG NETWORK TECHNOLOGY Co.,Ltd. Address before: Room 607, Building 9, Tiantai Financial Plaza, 333 Macau Road, Jiaozhou City, Qingdao City, Shandong Province Applicant before: QINGDAO GAOZHI HIGH-TECH TECHNOLOGY CO.,LTD. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: An environmentally friendly water treatment agent for ammonia nitrogen removal Effective date of registration: 20201021 Granted publication date: 20191213 Pledgee: Wuxi rural commercial bank Limited by Share Ltd. Yixing branch Pledgor: JIANGSU YIJING WATER TREATMENT CHEMICAL Co.,Ltd. Registration number: Y2020990001240 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20210826 Granted publication date: 20191213 Pledgee: Wuxi rural commercial bank Limited by Share Ltd. Yixing branch Pledgor: JIANGSU YIJING WATER TREATMENT CHEMICAL Co.,Ltd. Registration number: Y2020990001240 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A water treatment agent for environmental protection and ammonia nitrogen removal Effective date of registration: 20210830 Granted publication date: 20191213 Pledgee: Wuxi rural commercial bank Limited by Share Ltd. Yixing branch Pledgor: JIANGSU YIJING WATER TREATMENT CHEMICAL Co.,Ltd. Registration number: Y2021320010334 |