CN106745815A - It is a kind of to improve the water treatment agent that biochemical system goes ammonia nitrogen ability - Google Patents
It is a kind of to improve the water treatment agent that biochemical system goes ammonia nitrogen ability Download PDFInfo
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- CN106745815A CN106745815A CN201710026813.1A CN201710026813A CN106745815A CN 106745815 A CN106745815 A CN 106745815A CN 201710026813 A CN201710026813 A CN 201710026813A CN 106745815 A CN106745815 A CN 106745815A
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- Prior art keywords
- ammonia nitrogen
- treatment agent
- water treatment
- improve
- biochemical system
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Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
- C02F3/342—Biological treatment of water, waste water, or sewage characterised by the microorganisms used characterised by the enzymes used
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/06—Nutrients for stimulating the growth of microorganisms
Abstract
The water treatment agent that biochemical system goes ammonia nitrogen ability, including following components represented with weight portion are improved the invention discloses a kind of:75 100 parts of filler, 22 35 parts of biology enzyme, 33 40 parts of microorganism, 80 100 parts of nutriment;The nutriment includes vitamin, amino acid, sucrose, whey.It is decomposed using biological inoculum to harmful substances such as the ammonia nitrogens in waste water, to improve the biochemical ability of waste water.
Description
Technical field
The present invention relates to a kind of sewage-treating agent, in particular, it is related to a kind of biochemical system that improves to go ammonia nitrogen ability
Water treatment agent.
Background technology
Ammonia nitrogen in waste water is the important substance of body eutrophication and environmental pollution, and unprocessed or treatment is incomplete
Any discharge of nitrogen-containing pollutant can cause the amount reproduction of algae and other microorganisms in water;And ammonia nitrogen can cause drinking water
Peculiar smell, increases waterworks operating load;Increase the chlorine consumption in water disinfection and industrial cycle sterilisation process;Industry should
In, there is corrosivity to some metals, particularly copper;During reusing sewage, ammonia nitrogen can promote aqueduct and use in recycled water
The breeding of microorganism in wetting system, forms biofouling, blocks pipeline and water equipment, and influence heat exchange efficiency.
Water treatment agent common at present mainly includes inorganic flocculating agent and the major class of organic polymer coargulator two.It is wherein every kind of
Chemical products all has stronger specific aim, and failure, and useization are easy for when other chemical substances for having complexity are run into
After learning product, chemical residue can be left in water, side effect is easily brought to water body or even new pollution is caused.Therefore have
The water treatment agent of Biodegradable and security turns into the focus of research.
Most of organic matter and small part inorganic matter in waste water can be used by microorganism as nutriment, make
Microorganism obtains the energy or the new cell of synthesis for needing, the material referred to as substrate that these can be utilized by microorganism.If
Substrate in sewage is degradable, illustrates that the sewage can carry out harmless treatment using biological method.Biological method is by net
Changing principle can be divided into biomembrance process and activated sludge process, and due to activated sludge process research fully, operational management is convenient, financial cost
Suitably, thus in municipal sewage treatment generally it is combined with activated sludge process using Physical.This use activated sludge process
Process the feasibility of sewage, the biodegradability of abbreviation sewage.
To adding strong oxidizer to make the organic matter open loop chain rupture with macromolecular chain in waste water in waste water, will divide greatly
Sub- organic matter is converted into small organic molecule, and the degraded that small organic molecule is more beneficial for microorganism is utilized, to microbial degradation
Play the effect of key, the effective biochemical ability for improving waste water.It is residual in water and most strong oxidizers are used as chemical products
Stay and side effect easily is brought to water body.
The content of the invention
The water treatment agent that biochemical system goes ammonia nitrogen ability is improved it is an object of the invention to provide a kind of, it utilizes biological bacteria
Plant and the harmful substances such as the ammonia nitrogen in waste water are decomposed, to improve the biochemical ability of waste water.
To achieve the above object, the invention provides following technical scheme:
It is a kind of to improve the water treatment agent that biochemical system goes ammonia nitrogen ability, including following components represented with weight portion:
The nutriment includes vitamin, amino acid, sucrose, whey.
By above-mentioned technical proposal, microorganism with the organic substance of sewage as food, while to the pollutant in water body
Degraded, when the organic substance of itself is not enough in sewage, nutriment continues as microorganism and subsists as food, enters
One step promotes the growth of microorganism, improves the clean-up effect of water body, and after pollutant is purified, these microbes are with dirt
Contaminate the reduction of thing and nutriment and reduce until extinction, is converted into harmless carbohydrate, it is not easy to water body is produced secondary
Effect, reduces the situation that secondary pollution occurs and occurs;And using the combination of biology enzyme and microorganism, enzyme be by plant, animal,
The protein that bacterium, fungi and all life entities are produced and depended on for existence naturally, it is to promote chemical reaction without changing itself
Catalyst, biology enzyme by by larger molecular organicses in sewage and inorganic materialization it is small into convenient microbe absorb small molecule thing
Matter, substantially increases purification efficiency.
Preferably, the nutriment also includes sodium chloride.The microorganism include Halophiles, allotrophic nitrobacteria,
Denitrifying bacteria.
By above-mentioned technical proposal, Halophiles still has activity higher thin so as to make up heterotrophic nitrification under high salt concn
Bacterium and denitrifying bacteria active relatively low defect under high salt concn, and sodium chloride is added in nutriment for Halophiles is provided
The environment of activity is improved, while making allotrophic nitrobacteria and denitrifying bacteria that first there is relatively low activity, Halophiles is first played
Effect, Halophiles is by long-chain organic pollutant degradation for biodegradability is higher and the easy short chain small molecule being absorbed by the micro-organisms
Material, while the phagocytosis by Halophiles to short chain small-molecule substance and ammonia nitrogen, to organic pollution and ammonia in sewage
Nitrogen plays catharsis;After Halophiles plays a role, allotrophic nitrobacteria and denitrifying bacteria continue to play a role, and absorb thermophilic
The short chain small-molecule substance that salt bacterium is degraded out, and nitrification and denitrification effect is carried out to the ammonia nitrogen in water body, reduce ammonia nitrogen dense
Degree, accelerates purification efficiency and extends the clarification time, further improves the biodegradability of the pollutant in water body.
Preferably, described filler includes sludge.The filler of going back includes diatomite and nano titanium oxide.
In above-mentioned technical proposal, sludge, diatomite and nano titanium oxide be with larger specific surface area it is non-from
Subbase material, the skin effect of nano titanium oxide is conducive to making biology enzyme and microbial profile uniform, and is the life of microorganism
It is long that more sufficient carrier space is provided.Diatomite has loose structure and can be used as nano titanium oxide and the load of microorganism
Body, nano-titanium dioxide stability is high, and nontoxic pollution-free is not easy to produce secondary pollution to water body, and it is under light illumination
Easily produce with strong oxidation Superoxide anion free radical, hydroxyl radical free radical, super oxygen hydroxyl radical free radical, can by formaldehyde, benzene,
The majority harmful organic substance such as toluene, dimethylbenzene, ammonia resolves into the small-molecule substance of short chain or even resolves into harmless water and dioxy
Change carbon, the metabolism of biology enzyme and microorganism can be accelerated, improve the efficiency for increasing biodegradability.
Preferably, the biology enzyme includes protease, amylase, cellulase, lipase.
It is an advantage of the invention that:
1st, microbes are reduced up to withering away with the reduction of pollutant and nutriment, are converted into harmless carbohydrate,
It is not easy to produce side effect to water body, reduces the situation that secondary pollution occurs and occur;
2nd, the combination of biology enzyme, microorganism and the nutriment for enhancing metabolism, greatly improves and harmful substance is divided
Solution efficiency, extends the resolving time, is conducive to improving the biodegradability of pollutant;
3rd, the combination of biology enzyme, microorganism and the nutriment for enhancing metabolism, reduces microorganism and life condition is wanted
Ask, and use Halophiles, enhancing can also play a role to the adaptability of varying environment in more varying environments.
Specific embodiment
Below by embodiment, the invention will be further described.It should be understood that being prepared described in the embodiment of the present invention
Method is only used for the explanation present invention, rather than limitation of the present invention, the present invention is made under concept thereof of the invention
The simple modifications of Preparation Method belong to the scope of protection of present invention.
Involved all substances are commercially available in the embodiment of the present invention.
Embodiment one:
1st, weigh
Filler:Sludge 20g, diatomite 45g, nano titanium oxide 10g;
Biology enzyme:Protease 5g, amylase 6g, cellulase 7g, lipase 8g;
Microorganism:Halophiles 15g, allotrophic nitrobacteria 10g, denitrifying bacteria 10g;
Nutriment:Vitamin 10g, amino acid 20g, sucrose 20g, whey 20g, sodium chloride 15g;
2nd, microculture
By load weighted Halophiles, allotrophic nitrobacteria, denitrifying bacteria in step 1, grow in the medium, by detection
Afterwards, the inoculum of the first generation is transferred in 250 liters of biological fermentation devices through aseptic process and carries out twenty four hours at room temperature
Growth, be then made bacterium solution standby;
3rd, mix
Obtained bacterium solution in step 2 is mixed in a reservoir with load weighted biology enzyme in step 1, will battalion after being sufficiently mixed
Support in material and filler addition said vesse, be obtained after mixing again and improve the water treatment agent that biochemical system goes ammonia nitrogen ability.
Sewage is processed in certain sewage treatment plant using the water treatment agent in the present embodiment, by water treatment agent input
In processing pond, foundation《Integrated wastewater discharge standard》(GB8978-1996) water inlet and effluent quality detection to processing pond, detection
Result is represented:Ammonia nitrogen concentration is 450mg/L in water inlet, and ammonia nitrogen concentration is 15mg/L in water outlet, is met《Integrated wastewater discharge mark
It is accurate》(GB8978-1996) first discharge standard.
Embodiment two:
1st, weigh
Filler:Sludge 25g, diatomite 50g, nano titanium oxide 20g;
Biology enzyme:Protease 7g, amylase 5g, cellulase 6g, lipase 4g;
Microorganism:Halophiles 14g, allotrophic nitrobacteria 15g, denitrifying bacteria 11g;
Nutriment:Vitamin 9g, amino acid/11 8g, sucrose 20g, whey 19g, sodium chloride 14g;
2nd, microculture
By load weighted Halophiles, allotrophic nitrobacteria, denitrifying bacteria in step 1, grow in the medium, by detection
Afterwards, the inoculum of the first generation is transferred in 250 liters of biological fermentation devices through aseptic process and carries out twenty four hours at room temperature
Growth, be then made bacterium solution standby;
3rd, mix
Obtained bacterium solution in step 2 is mixed in a reservoir with load weighted biology enzyme in step 1, will battalion after being sufficiently mixed
Support in material and filler addition said vesse, be obtained after mixing again and improve the water treatment agent that biochemical system goes ammonia nitrogen ability.
Sewage is processed in certain sewage treatment plant using the water treatment agent in the present embodiment, by water treatment agent input
In processing pond, foundation《Integrated wastewater discharge standard》(GB8978-1996) water inlet and effluent quality detection to processing pond, detection
Result is represented:Ammonia nitrogen concentration is 500mg/L in water inlet, and ammonia nitrogen concentration is 15mg/L in water outlet, is met《Integrated wastewater discharge mark
It is accurate》(GB8978-1996) first discharge standard.
Embodiment three:
1st, weigh
Filler:Sludge 35g, diatomite 58g, nano titanium oxide 20g;
Biology enzyme:Protease 11g, amylase 9g, cellulase 8g, lipase 7g;
Microorganism:Halophiles 17g, allotrophic nitrobacteria 8g, denitrifying bacteria 8g;
Nutriment:Vitamin 7g, amino acid 30g, sucrose 25g, whey 28g, sodium chloride 10g;
2nd, microculture
By load weighted Halophiles, allotrophic nitrobacteria, denitrifying bacteria in step 1, grow in the medium, by detection
Afterwards, the inoculum of the first generation is transferred in 250 liters of biological fermentation devices through aseptic process and carries out twenty four hours at room temperature
Growth, be then made bacterium solution standby;
3rd, mix
Obtained bacterium solution in step 2 is mixed in a reservoir with load weighted biology enzyme in step 1, will battalion after being sufficiently mixed
Support in material and filler addition said vesse, be obtained after mixing again and improve the water treatment agent that biochemical system goes ammonia nitrogen ability.
Sewage is processed in certain sewage treatment plant using the water treatment agent in the present embodiment, by water treatment agent input
In processing pond, foundation《Integrated wastewater discharge standard》(GB8978-1996) water inlet and effluent quality detection to processing pond, detection
Result is represented:Ammonia nitrogen concentration is 400mg/L in water inlet, and ammonia nitrogen concentration is 15mg/L in water outlet, is met《Integrated wastewater discharge mark
It is accurate》(GB8978-1996) first discharge standard.
Example IV:
1st, weigh
Filler:Sludge 35g, diatomite 35g, nano titanium oxide 10g;
Biology enzyme:Protease 5g, amylase 9g, cellulase 8g, lipase 7g;
Microorganism:Halophiles 15g, allotrophic nitrobacteria 11g, denitrifying bacteria 11g;
Nutriment:Vitamin 10g, amino acid 20g, sucrose 20g, whey 28g, sodium chloride 14g;
2nd, microculture
By load weighted Halophiles, allotrophic nitrobacteria, denitrifying bacteria in step 1, grow in the medium, by detection
Afterwards, the inoculum of the first generation is transferred in 250 liters of biological fermentation devices through aseptic process and carries out twenty four hours at room temperature
Growth, be then made bacterium solution standby;
3rd, mix
Obtained bacterium solution in step 2 is mixed in a reservoir with load weighted biology enzyme in step 1, will battalion after being sufficiently mixed
Support in material and filler addition said vesse, be obtained after mixing again and improve the water treatment agent that biochemical system goes ammonia nitrogen ability.
Sewage is processed in certain sewage treatment plant using the water treatment agent in the present embodiment, by water treatment agent input
In processing pond, foundation《Integrated wastewater discharge standard》(GB8978-1996) water inlet and effluent quality detection to processing pond, detection
Result is represented:Ammonia nitrogen concentration is 480mg/L in water inlet, and ammonia nitrogen concentration is 15mg/L in water outlet, is met《Integrated wastewater discharge mark
It is accurate》(GB8978-1996) first discharge standard.
Embodiment five:
1st, weigh
Filler:Sludge 25g, diatomite 40g, nano titanium oxide 20g;
Biology enzyme:Protease 11g, amylase 9g, cellulase 6g, lipase 4g;
Microorganism:Halophiles 14g, allotrophic nitrobacteria 8g, denitrifying bacteria 15g;
Nutriment:Vitamin 9g, amino acid 30g, sucrose 20g, whey 19g, sodium chloride 10g;
2nd, microculture
By load weighted Halophiles, allotrophic nitrobacteria, denitrifying bacteria in step 1, grow in the medium, by detection
Afterwards, the inoculum of the first generation is transferred in 250 liters of biological fermentation devices through aseptic process and carries out twenty four hours at room temperature
Growth, be then made bacterium solution standby;
3rd, mix
Obtained bacterium solution in step 2 is mixed in a reservoir with load weighted biology enzyme in step 1, will battalion after being sufficiently mixed
Support in material and filler addition said vesse, be obtained after mixing again and improve the water treatment agent that biochemical system goes ammonia nitrogen ability.
Sewage is processed in certain sewage treatment plant using the water treatment agent in the present embodiment, by water treatment agent input
In processing pond, foundation《Integrated wastewater discharge standard》(GB8978-1996) water inlet and effluent quality detection to processing pond, detection
Result is represented:Ammonia nitrogen concentration is 420mg/L in water inlet, and ammonia nitrogen concentration is 15mg/L in water outlet, is met《Integrated wastewater discharge mark
It is accurate》(GB8978-1996) first discharge standard.
Embodiment six:
1st, weigh
Filler:Sludge 20g, diatomite 50g, nano titanium oxide 20g;
Biology enzyme:Protease 7g, amylase 6g, cellulase 7g, lipase 8g;
Microorganism:Halophiles 17g, allotrophic nitrobacteria 11g, denitrifying bacteria 11g;
Nutriment:Vitamin 7g, amino acid/11 8g, sucrose 25g, whey 28g, sodium chloride 15g;
2nd, microculture
By load weighted Halophiles, allotrophic nitrobacteria, denitrifying bacteria in step 1, grow in the medium, by detection
Afterwards, the inoculum of the first generation is transferred in 250 liters of biological fermentation devices through aseptic process and carries out twenty four hours at room temperature
Growth, be then made bacterium solution standby;
3rd, mix
Obtained bacterium solution in step 2 is mixed in a reservoir with load weighted biology enzyme in step 1, will battalion after being sufficiently mixed
Support in material and filler addition said vesse, be obtained after mixing again and improve the water treatment agent that biochemical system goes ammonia nitrogen ability.
Sewage is processed in certain sewage treatment plant using the water treatment agent in the present embodiment, by water treatment agent input
In processing pond, foundation《Integrated wastewater discharge standard》(GB8978-1996) water inlet and effluent quality detection to processing pond, detection
Result is represented:Ammonia nitrogen concentration is 440mg/L in water inlet, and ammonia nitrogen concentration is 15mg/L in water outlet, is met《Integrated wastewater discharge mark
It is accurate》(GB8978-1996) first discharge standard.
Claims (6)
1. a kind of biochemical system that improves removes the water treatment agent of ammonia nitrogen ability, it is characterised in that represented with weight portion including following
Component:
The nutriment includes vitamin, amino acid, sucrose, whey.
It is 2. according to claim 1 to improve the water treatment agent that biochemical system goes ammonia nitrogen ability, it is characterised in that:The nutrition
Material also includes sodium chloride.
It is 3. according to claim 2 to improve the water treatment agent that biochemical system goes ammonia nitrogen ability, it is characterised in that:Micro- life
Thing includes Halophiles, allotrophic nitrobacteria, denitrifying bacteria.
It is 4. according to claim 3 to improve the water treatment agent that biochemical system goes ammonia nitrogen ability, it is characterised in that:Described filler
Including sludge.
It is 5. according to claim 4 to improve the water treatment agent that biochemical system goes ammonia nitrogen ability, it is characterised in that:It is described also to fill out
Material includes diatomite and nano titanium oxide.
It is 6. according to claim 1 to improve the water treatment agent that biochemical system goes ammonia nitrogen ability, it is characterised in that:The biology
Enzyme includes protease, amylase, cellulase, lipase.
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Cited By (3)
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CN108238682A (en) * | 2018-02-02 | 2018-07-03 | 广州市真诚环保科技有限公司 | A kind of wastewater biochemical handles denitrifying microorganism complex nutrient preparation |
CN111186902A (en) * | 2018-11-14 | 2020-05-22 | 中国环境科学研究院 | Biological nest water body purification system and method thereof |
CN112194257A (en) * | 2020-09-29 | 2021-01-08 | 南京乐萱生态环境科技有限公司 | Biological regulator for efficiently reducing eutrophication of water body, preparation method and use method |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108238682A (en) * | 2018-02-02 | 2018-07-03 | 广州市真诚环保科技有限公司 | A kind of wastewater biochemical handles denitrifying microorganism complex nutrient preparation |
CN111186902A (en) * | 2018-11-14 | 2020-05-22 | 中国环境科学研究院 | Biological nest water body purification system and method thereof |
CN112194257A (en) * | 2020-09-29 | 2021-01-08 | 南京乐萱生态环境科技有限公司 | Biological regulator for efficiently reducing eutrophication of water body, preparation method and use method |
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Effective date of registration: 20180112 Address after: Yao Chong Street Road in Qixia District of Nanjing city in Jiangsu province 210046 No. 1 Building 2 Room 101 Applicant after: Nanjing Yubao Source Environmental Protection Technology Co., Ltd. Address before: Room 301, No. 32, Dashiqiao 32, Xuanwu District, Jiangsu, Jiangsu Applicant before: Feng Zhixiang |
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Application publication date: 20170531 |