CN103966029A - Effervescent tablet for cleaning tea stains and preparation method of effervescent tablet - Google Patents

Effervescent tablet for cleaning tea stains and preparation method of effervescent tablet Download PDF

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Publication number
CN103966029A
CN103966029A CN201410168830.5A CN201410168830A CN103966029A CN 103966029 A CN103966029 A CN 103966029A CN 201410168830 A CN201410168830 A CN 201410168830A CN 103966029 A CN103966029 A CN 103966029A
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China
Prior art keywords
tea stain
tea
cleaning
agent
sodium
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CN201410168830.5A
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CN103966029B (en
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尹浩
刘亚军
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GUANGZHOU CHEERWIN BIOTECHNOLOGY Co.,Ltd.
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Guangzhou Liby Enterprise Group Co Ltd
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Abstract

The invention relates to an effervescent tablet for cleaning tea stains. The effervescent tablet mainly comprises the following ingredients by mass: 20% to 50% of an oxidation bleaching agent, 10% to 40% of an acid disintegrating agent, 10% to 40% of an alkaline disintegrating agent, 4% to 15% of an agglomerant and 0.1% to 5% of a surfactant. The invention further discloses a preparation method of the effervescent tablet, which comprises the following steps: 1) mixing the dried alkaline disintegrating agent with the oxidation bleaching agent, and stirring the mixture to be uniform to obtain granules A; 2) mixing the dried acid disintegrating agent, the dried agglomerant and the dried surfactant, and stirring the mixture to be uniform to obtain granules B; 3) mixing the granules A and the granules B, stirring the mixture to be uniform, then, carrying out tabletting, extracting a sample, checking the sample according to a quality standard, and packaging the sample if the sample is checked to be qualified. The effervescent tablet is high in tea stain detergency, and can clean a tea set without dead angle; moreover, irritation of the conventional powder product is lowered during use. Therefore, the effervescent tablet is more convenient to carry about and use.

Description

Tea stain effervescent table for cleaning and preparation method thereof
Technical field
The present invention relates to a kind of tea stain sanitising agent, belong to daily chemical product field, specifically relate to a kind of tea stain effervescent table for cleaning and preparation method thereof.
Background technology
China is the native place of tea, and tea is also a Sinitic part.China people just have the custom of drinking tea since ancient times.Kind of tea, tea making, the history of having tea are of long standing and well established especially.In tea, contain theophylline, after tea set length duration of service, theophylline is easy to be attached to tea set surface.The tea dirt that tea set inwall is detained, is called for short tea stain or tea stain.Tea stain is to produce because oxidizing reaction occurs in air for the tea-polyphenol in tealeaves and the metallics in tea stain, wherein the insalubrious material such as the various metals such as cadmium, lead, iron, arsenic, mercury and nitrite.Everybody drinks tea and generally the cleaning of tea set is not taken much count of, and some area even thinks that thick tea stain is a treasured, is the identity symbol of old tea people identity.Nowadays science is verified, and tea stain is harmful to HUMAN HEALTH.Tea stain is brought health into when drinking tea, and with the nutrition chemical combination such as protein, fat and VITAMIN in food, generates the precipitation of indissoluble, hinders the absorption of nutrition.Meanwhile, these oxide compounds enter that health also can cause nerve, digestion, uropoiesis hematopoietic disorder and dysfunction, especially arsenic, cadmium can be carcinogenic, causes fetal anomaly, health risk.Therefore have tea drinking habit person, should often clean in time the tea stain of tea set inwall.
As you know, tea stain is to be difficult to clean.The daily tea set of a lot of people cleans with drift ice, scrubbing powder, liquid detergent etc.Purging method is also varied: with vinegar, soak and remove tea stain; Or soak and remove tea stain by SYNTHETIC OPTICAL WHITNER; Or with sponge, dip in salt friction and remove tea stain; Or remove tea stain with cleaning powder; Or clean de-sludging with toothpaste.Although these clean tea stains tips play to a certain extent the effect of dispelling tea stain, do not consider security or suitability.Using drift ice, scrubbing powder is not the sanitising agent of professional cleaning tea stain, its security needs assessment.Use sponge or toothpaste etc. to remove tea stain by rubbing effect, in irregular tea set, clean, use inconvenient.
Chinese patent CN101851565A discloses a kind of tea set cleaning agent and preparation method thereof, and it adopts calcium carbonate, zeolite etc. as decontamination composition, utilizes frictional behaviour to clean tea stain, but a lot of tea set is irregular, and cleaning can leave a lot of dead angles, uses inconvenient.Chinese patent CN102559416A discloses a kind of preparation method of tea residue detergent, in embodiment, having adopted sodium carbonate peroxide and sodium carbonate is main cleansing, tea stain spot is had to good removal effect, but the shortcoming existing is apparent, powder composition easily floats in product use procedure, and the dust of kicking up has pungency.
Summary of the invention
In order to overcome the above-mentioned deficiency of existing tea stain sanitising agent, the object of the present invention is to provide a kind of tea stain effervescent table for cleaning, to tea stain dirt strong detergency, realize the decontamination of tea set without dead angle, reduce traditional powder product pungency in use simultaneously, carry and use convenient.
The present invention is achieved by the following technical solutions.
A kind of tea stain effervescent table for cleaning of the present invention, each feed composition that it comprises following weight percent: oxidative bleaching agent 20-50%, acid disintegrating agent 10-40%, alkaline disintegrating agent 10-40%, binding agent 4-15%, tensio-active agent 0.1-5%.
Furthermore, a kind of tea stain effervescent table for cleaning of the present invention, each feed composition that it comprises following weight percent: oxidative bleaching agent 30~40%; Acid disintegrating agent 20~35%; Alkalescence disintegrating agent 20~35%; Binding agent 6~12%; Tensio-active agent 0.5~4%.
Oxidative bleaching agent of the present invention is sodium carbonate peroxide, peroxide Sodium Tetraborate and peroxosulphuric sodium, wherein more preferred sodium carbonate peroxide.Sodium carbonate peroxide is new and effective bleaching fungicide, has odorless, nontoxic, free of contamination feature, and it decomposes the active oxygen producing in water makes it show very strong decontamination, bactericidal property.
Described acid disintegrating agent has tartrate, citric acid, one or more mixtures of fumaric acid, wherein optimization citric acid more.
Described alkaline disintegrating agent is one or both the mixture in sodium bicarbonate or sodium carbonate, more preferred sodium carbonate wherein,
Binding agent of the present invention has one or more in dextrin, polyoxyethylene glycol, Natvosol, polyvinylpyrrolidone (PVP), sodium starch glycolate, wherein more preferred polyoxyethylene glycol or polyvinylpyrrolidone.
What described polyoxyethylene glycol was PEG-4000 in PEG-6000 0 is any.Wherein more be preferably PEG-4000 or PEG-8 000.
Tensio-active agent of the present invention has one or more in linear alkylbenzene sulphonic acid, sodium lauryl sulphate, methyl sodiosul foaliphatate, α-sodium olefin sulfonate, wherein preferably sodium dodecyl sulfate more.
In addition, the invention allows for a kind of preparation method of above-mentioned tea stain effervescent table for cleaning, comprise following steps:
1) first the alkaline disintegrating agent being dried is mixed with oxidative bleaching agent, A grain stirs to obtain;
2) the acid disintegrating agent being dried, binding agent, tensio-active agent are mixed, B grain stirs to obtain;
3) A grain and B grain are mixed, stir; Then carry out compressing tablet, draw samples is also tested by quality standard, is up to the standards and can packs.
Than prior art, tea stain effervescent table for cleaning of the present invention has following advantage and beneficial effect:
1) the present invention adopts oxygen technology alive, and the active oxygen that product in use discharges has powerful soil removability to tea stain.Utilize effervesce technology, a large amount of bubbles of release can effectively impact tea stain simultaneously, make it to become flexible, accelerate dissolution, thereby have strengthened the detergency ability of product, realize decontamination without dead angle.
2) will in tea set, place 1 tea stain effervescent table for cleaning, add 80 degree hot-water soak 10 minutes, just can reach sparkling clean effect.Use simply, water-saving efficient, safety non-toxic, washes rear noresidue, has again effect antibacterial, taste removal.
3) tea stain effervescent table for cleaning effervescent tablet volume of the present invention is little, is convenient to transportation and carries, easy to use, an a slice, and cost is low, environmental friendliness.
Embodiment
Below, by concrete preferred embodiment, tea stain effervescent table for cleaning of the present invention is described in further detail, but the present invention is not limited in following embodiment.
embodiment 1~3
According to table 1 formulation content, prepare respectively embodiment 1~3 tea stain effervescent table for cleaning, its preparation method is: first the sodium carbonate being dried and sodium carbonate peroxide are mixed, stir.Obtain A grain; The citric acid being dried, sodium lauryl sulphate (K12), PEG-4000, polyvinylpyrrolidone are mixed, stir.Obtain B grain; A grain and B grain are mixed, stir.Then carry out compressing tablet, draw samples is also tested by quality standard, is up to the standards and can be packaged into tea stain effervescent table for cleaning product.
The formula of the tea stain effervescent table for cleaning of table 1 embodiment 1~3 forms
embodiment 4~6
According to table 2 formulation content, prepare respectively embodiment 4~6 tea stain effervescent table for cleaning, its preparation method is: first the sodium carbonate being dried and Sodium Persulfate are mixed, stir.Obtain A grain; The tartrate being dried, α-sodium olefin sulfonate, PEG 8000, sodium starch glycolate are mixed, stir.Obtain B grain; A grain and B grain are mixed, stir.Then carry out compressing tablet, draw samples is also tested by quality standard, and being up to the standards can packaging final prod tea stain effervescent table for cleaning.
The formula of the tea stain effervescent table for cleaning of table 2 embodiment 4~6 forms
embodiment 7~9
According to table 3 formulation content, prepare respectively embodiment 7~9 tea stain effervescent table for cleaning, its preparation method is: first the sodium bicarbonate being dried and Sodium peroxoborate are mixed, stir.Obtain A grain; The fumaric acid being dried, citric acid, Sodium dodecylbenzene sulfonate (LAS), PEG 8000, Natvosol are mixed, stir.Obtain B grain; A grain and B grain are mixed, stir.Then carry out compressing tablet, draw samples is also tested by quality standard, and being up to the standards can packaging final prod tea stain effervescent table for cleaning.
The formula of the tea stain effervescent table for cleaning of table 3 embodiment 7~9 forms
embodiment 10~12
According to table 4 formulation content, prepare respectively embodiment 10~12 tea stain effervescent table for cleaning, its preparation method is: first the sodium carbonate being dried and sodium carbonate peroxide are mixed, stir.Obtain A grain; The tartrate being dried, citric acid, methyl sodiosul foaliphatate (MES), polyethylene glycol 6000, dextrin are mixed, stir.Obtain B grain; A grain and B grain are mixed, stir.Then carry out compressing tablet, draw samples is also tested by quality standard, and being up to the standards can packaging final prod tea stain effervescent table for cleaning.
The formula of the tea stain effervescent table for cleaning of table 4 embodiment 10~12 forms
effects applications test example
The performance test methods of the tea stain effervescent table for cleaning of the embodiment of the present invention is as follows:
1, erosion resistance testing method.
With reference to 2002 editions 2.2.4 sterilizing agents of the < < of Ministry of Health disinfection technology standard > >, the corrosive mensuration of metal (or pottery) is required to measure:
(1) metal (or pottery) sheet is soaked to 10min in having the sanitising agent of surface-active action, fully deoil, clean; With anhydrous propanone or dehydrated alcohol degreasing again.Put dry 1h in 50 ℃ of thermostat containers.M weighs 0.
(2) sample solution concentration of preparation 1.0%, in order to soak test print.During immersion, each metal (or pottery) sheet need be immersed in 200ml experimental liquid.Disposable immersion 1h, was dipped into after the specified time, took out metal (or pottery) sheet, first with tap water, rinse, after cleaning at the dry 1h. of the 50 ℃ of thermostat containers m that weighs 1.
(3) evaluation of result: calculate (R, corrodibility graded index) according to metal (or pottery) erosion rate formula.
The classification of table 5 erosion rate
Erosion rate R (mm/a) Rank
<0.0100 No corrosion
0.0100~<0.100 Mild corrosion
0.100~<1.00 Moderate corrosion
≥1.00 Severe corrosion
2, detersive power evaluation of measuring method
The making of tea stain: experiment is made tea stain with black tea and green tea.Tea immersion, oven dry, immersion repeatedly simulated to formation tea stain.
Detersive power effect evaluation method: selected totally 10 of tested volunteer men and women (22 years old-55 years old age), the teacup cleaning is carried out to sensory evaluation, by following 5 degree, mark to evaluate detersive power effect: 10 minutes, cleaning performance was very clean; 8 minutes, cleaning performance was cleaner; 6 minutes, cleaning performance was general; 4 minutes, cleaning performance was poor; 0 minute, there is no cleaning effect.
By above-described embodiment, contrast commercially available tea stain sanitising agent, carried out detersive power test and erosion resistance test, experimental result is in Table 6.
Table 6 detersive power (green tea tea stain) test-results
Table 7 detersive power (green tea tea stain) test-results
Table 8 detersive power (black tea tea stain) test-results
Table 9 detersive power (black tea tea stain) test-results
Table 10 metal protection experimental result
Consolidated statement 6~table 10 test data can find out, each embodiment is good to tea stain removal effect, and to stainless steel and ceramic material non-corrosiveness, detersive power is higher than commercially available prod.
Tea stain effervescent table for cleaning feature of the present invention is:
The present invention adopts oxygen technology alive, and the active oxygen in use discharging has powerful soil removability to tea stain.Utilize effervesce technology, a large amount of bubbles of release can effectively impact stupid stain tea stain simultaneously, make it to become flexible, accelerate dissolution, realize decontamination without dead angle.
The above, it is only preferred embodiment of the present invention, not the present invention is done to any pro forma restriction, therefore every, do not depart from technical solution of the present invention content, any simple modification, equivalent variations and the modification the above embodiment done according to technical spirit of the present invention, all still belong in the scope of technical solution of the present invention.

Claims (9)

1. a tea stain effervescent table for cleaning, is characterized in that each feed composition that contains following weight percent:
2. tea stain effervescent table for cleaning according to claim 1, is characterized in that each feed composition that contains following weight percent:
3. tea stain effervescent table for cleaning according to claim 1, is characterized in that: described oxidative bleaching agent is any or two or more mixtures in sodium carbonate peroxide, peroxide Sodium Tetraborate, peroxosulphuric sodium.
4. tea stain effervescent table for cleaning according to claim 1, is characterized in that: described acid disintegrating agent is any or two or more mixtures in tartrate, citric acid, fumaric acid.
5. tea stain effervescent table for cleaning according to claim 1, is characterized in that: described alkaline disintegrating agent is one or both the mixing in sodium bicarbonate or sodium carbonate.
6. tea stain effervescent table for cleaning according to claim 1, is characterized in that: described binding agent is one or more the mixture in dextrin, polyoxyethylene glycol, Natvosol, polyvinylpyrrolidone, sodium starch glycolate.
7. tea stain effervescent table for cleaning according to claim 1, is characterized in that: what described polyoxyethylene glycol was PEG-4000 in PEG-6000 0 is any.
8. tea stain effervescent table for cleaning according to claim 1, is characterized in that: described tensio-active agent is one or more the mixture in linear alkylbenzene sulphonic acid, sodium alkyl sulfate, methyl sodiosul foaliphatate, α sodium olefin sulfonate.
9. the preparation method of the tea stain effervescent table for cleaning described in any one in claim 1-8, is characterized in that comprising following steps:
1) first the alkaline disintegrating agent being dried is mixed with oxidative bleaching agent, A grain stirs to obtain;
2) the acid disintegrating agent being dried, binding agent, tensio-active agent are mixed, B grain stirs to obtain;
3) A grain and B grain are mixed, stir; Then carry out compressing tablet, draw samples is also tested by quality standard, is up to the standards and can packs.
CN201410168830.5A 2014-04-24 2014-04-24 Tea stain effervescent table for cleaning and preparation method thereof Active CN103966029B (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105217802A (en) * 2015-10-29 2016-01-06 余姜 A kind of water quality cleansing agent
CN105886159A (en) * 2016-05-08 2016-08-24 杭州氧泡泡生物科技有限公司 Food stage aerobic detergent
CN107384619A (en) * 2017-08-02 2017-11-24 广州立白企业集团有限公司 It is a kind of have remove effervescent table for cleaning of residual, the degerming effect of agriculture and preparation method thereof
CN109504558A (en) * 2018-12-12 2019-03-22 濮阳宏业环保新材料股份有限公司 A kind of Tea stain detergent and preparation method thereof
CN109706006A (en) * 2019-01-21 2019-05-03 厦门格林英日化科技有限公司 Moxa-moxibustion apparatus cleaning agent and preparation method thereof
CN111171967A (en) * 2020-01-09 2020-05-19 广州市日用化学工业研究所有限公司 Effervescent washing product with high disintegration speed and easy rinsing and preparation method thereof
CN116083178A (en) * 2023-03-05 2023-05-09 余姚市德派日用品有限公司 Floor cleaning effervescent tablet and preparation method thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1032642B1 (en) * 1997-11-10 2003-07-02 The Procter & Gamble Company Process for making a detergent tablet
CN101213284A (en) * 2005-06-29 2008-07-02 宝洁公司 Use of an effervescent product to clean soiled dishes by hand washing
CN102001714A (en) * 2009-09-01 2011-04-06 天津瑞普生物技术股份有限公司 Effervescent tablet capable of purifying water quality and preparation method thereof

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105217802A (en) * 2015-10-29 2016-01-06 余姜 A kind of water quality cleansing agent
CN105217802B (en) * 2015-10-29 2018-05-18 上海泰缘生物科技有限公司 A kind of water quality cleansing agent
CN105886159A (en) * 2016-05-08 2016-08-24 杭州氧泡泡生物科技有限公司 Food stage aerobic detergent
CN107384619A (en) * 2017-08-02 2017-11-24 广州立白企业集团有限公司 It is a kind of have remove effervescent table for cleaning of residual, the degerming effect of agriculture and preparation method thereof
CN107384619B (en) * 2017-08-02 2020-09-11 广州立白企业集团有限公司 Cleaning effervescent tablet with pesticide residue removing and bacterium removing effects and preparation method thereof
CN109504558A (en) * 2018-12-12 2019-03-22 濮阳宏业环保新材料股份有限公司 A kind of Tea stain detergent and preparation method thereof
CN109504558B (en) * 2018-12-12 2020-12-01 濮阳宏业环保新材料股份有限公司 Tea dirt cleaning agent and preparation method thereof
CN109706006A (en) * 2019-01-21 2019-05-03 厦门格林英日化科技有限公司 Moxa-moxibustion apparatus cleaning agent and preparation method thereof
CN111171967A (en) * 2020-01-09 2020-05-19 广州市日用化学工业研究所有限公司 Effervescent washing product with high disintegration speed and easy rinsing and preparation method thereof
CN116083178A (en) * 2023-03-05 2023-05-09 余姚市德派日用品有限公司 Floor cleaning effervescent tablet and preparation method thereof

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Effective date of registration: 20190723

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Address before: 510370 Guangdong city of Guangzhou province Liwan District Lu Lu No. two

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