CN105186292A - Method for manufacturing sparkle plug of internal combustion engine and sparkle plug of internal combustion engine - Google Patents

Method for manufacturing sparkle plug of internal combustion engine and sparkle plug of internal combustion engine Download PDF

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Publication number
CN105186292A
CN105186292A CN201510309282.8A CN201510309282A CN105186292A CN 105186292 A CN105186292 A CN 105186292A CN 201510309282 A CN201510309282 A CN 201510309282A CN 105186292 A CN105186292 A CN 105186292A
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China
Prior art keywords
spark plug
head zone
oxide
coating
slurry
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Granted
Application number
CN201510309282.8A
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Chinese (zh)
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CN105186292B (en
Inventor
奥利弗·贝克迈尔
克莱门斯·玛丽亚·瓦普特
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Ford Global Technologies LLC
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Ford Global Technologies LLC
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23DENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
    • C23D5/00Coating with enamels or vitreous layers
    • C23D5/02Coating with enamels or vitreous layers by wet methods
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01TSPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
    • H01T13/00Sparking plugs
    • H01T13/02Details
    • H01T13/14Means for self-cleaning
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01TSPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
    • H01T21/00Apparatus or processes specially adapted for the manufacture or maintenance of spark gaps or sparking plugs
    • H01T21/02Apparatus or processes specially adapted for the manufacture or maintenance of spark gaps or sparking plugs of sparking plugs
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23DENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
    • C23D7/00Treating the coatings, e.g. drying before burning

Abstract

The invention discloses a method for manufacturing a sparkle plug of an internal combustion engine and a sparkle plug of an internal combustion engine.Spark plug (1) contains a header (8) of the main body (2) and head region (8) to be assigned to the internal combustion engine combustion chamber. And, at least at least partially coating formed through the following steps to set on the head region (8) : - the header area (8) at least part of the roughness, and the slurry coating to the roughness of the head region (8), - dry coating slurry, heat - coated to the roughness of the head region (8) the slurry to form a porcelain glaze layer (10). The invention also relates to especially flux produced by the method of the internal combustion engine spark plug (1).

Description

Produce the method for spark plug and the spark plug of explosive motor of explosive motor
The present invention relates to the method for the spark plug according to claim 1 preamble of the explosive motor producing especially motor vehicles.The invention still further relates to the spark plug for explosive motor according to claim 7 preamble.
Application ignited internal combustion engine needs pilot spark, and object is the fuel-air mixture of the compression of lighting in its combustion chamber.For this purpose, the automatically controlled spark plug of the pilot spark being used as controllably to provide respective is used.In their running, pilot spark forms open arc between the central electrode and at least one grounding electrode of spark plug.Spark plug has the main body with connecting portion usually, and connecting portion such as can have external screw thread.Such spark plug can be screwed into the corresponding opening of the cylinder cover of explosive motor.
Connected by the conduction to connecting portion, when spark plug is placed in cylinder cover, grounding electrode is in ground connection by vehicle ground portion.By contrast, central electrode can be connected with ignition coil by such as firing cable.Central electrode can stand by ignition coil the ignition voltage that is applicable to.For this purpose, central electrode and grounding electrode are electrically insulated from each other, because the electric arc of ignition voltage should only produce between two electrodes by the insulator be applicable to.Electrode spacing represents the standard of the burning for obtaining required fuel-air mixture that can pre-set in this.
In the layout of spark plug, it has the combustion chamber of end face to corresponding explosive motor of electrode spacing.For the purposes of the present invention, described end is considered to the head zone of spark plug.
In the process running spark plug, known possible deposit can be formed in its head zone.Deposit is oil carbon normally.These oil carbon deposits are owing to the combustion process of respective fuel.In this case, such deposit mainly concentrates on and is positioned on the SI semi-insulation body of head zone.Depend on running time, these deposits can realize the loose structure with thickness of several millimetres.
The problem produced is owing to the conductivity of the latter.Especially rely on the deposit that formed between the metallic region of the head zone of spark plug, occur the most at last misfiring and the example of uncontrollable pilot spark.And deposit shows at the end of burn cycle with the trend that uncontrollable mode burns away; This and glow plug are similar.Weakening or even imperfect combustion then due to fuel-air mixture, this finally causes the volatile organic matter (discharge of hydrocarbon) in waste gas with undesirable high level.
The spark plug of the known various configuration of prior art.Except they are only used as except igniter, prior art have also been disclosed avoids above-mentioned sedimental technical scheme.
Therefore, EP1557918A1 discloses the spark plug of explosive motor, allegedly because conductive deposit permanently can avoid the generation of shunting.For this reason, suggestion is the layer of precious metal of the catalysis formed on the point foot of the insulator of the head zone being positioned at spark plug.Layer of precious metal can be platinum (Pt), palladium (Pd) or rhodium (Rh).
The noble coatings of suggestion is intended to reduce the temperature needed for combustion deposit.Especially the cold-start phase of explosive motor is interesting, does not wherein also reach optimum operation temperature.Therefore, the reduction of attainable ignition temperature should the sedimental oxidation of final corresponding acceleration.About the position of noble coatings, this is confined to the inner surface of the insulated hole at the central electrode towards spark plug.Conventional insulated hole exposes the insulator inner opening of central electrode to the open air, and central electrode surrounds, so that described central electrode can interact with grounding electrode at other position insulated bodys.
DE4222137B4 discloses the fuel injection nozzle for diesel internal combustion engine.This comprises the nozzle body with spray-hole, and spray-hole penetrates described nozzle body, and until the wall of the nozzle body of applying coating.Coating is thickening towards the opening of spray-hole, so that nozzle bore is tapered towards their opening.Coating itself is by hard material such as chromium, nickel, nickel-phosphorus, nickel-boron, nickel-cobalt-boron, Al 2o 3, Cr 2o 3, TiO 2, Cr 3c 2, SiO 2, AlSi, NiCr, WTi or WC formed.
DE19951014A1 discloses the Fuelinjection nozzle of the coating equally with the region at least broadened around floss hole opening.This coating be the oxide of Co or Ni or cobalt oxide or nickel oxide or cobalt alloy or nickel alloy or Ru or Rh or Pd or Os or Ir or Pt or these metals each other or the catalytic active layer of alloy with other metal.
JP2007-309167A discloses the combustion chamber purging system of explosive motor.For this reason, by the surface of titanium dioxide-coated to the injection opening of injector.
JP2005-155618A discloses the technique forming the coating be made up of titanium oxide on the nozzle of injection valve.
Although the layout that result is noble coatings can accelerate the sedimental burning existed, such as its performance and local are arranged result also in and are uncontrollablely lighted and glow.Generally speaking, the technique of therefore following the trail of physics or chemical vapour deposition (CVD) (PVD/CVD) up to now and the technique relating to plating measure generation all can not be made to be applicable to for reliably stoping the coating of sedimental formation and relevant inferior position to become possibility.
Observe according to this, therefore the spark plug of the explosive motor especially explosive motor of motor vehicles certainly still has the space of improvement.
For background technology, the present invention is based on the technique and a kind of spark plug for explosive motor developed further for the production of spark plug, so that the target of the method for the coating providing possible cost-efficient formation to be applicable to, this coating to can be incorporated in existing production sequence and guarantees to improve the reliable effect of the waste gas value formed in running.
The solution of the part that the technique of described target is correlated with is the content of the method for the feature with claim 1.The part that the product of described target is correlated with realizes according to the spark plug of the feature with claim 7.The particularly advantageous improvement of the present invention is open by respective dependent claims further.
It should be noted that and can be combined with each other the method and feature that describe in detail separately in following specification in the technical significant mode of any needs, because further disclosed herein improvement of the present invention.
Accordingly, technique according to the present invention comprises the spark plug producing explosive motor.Particularly preferably, explosive motor is the engine of motor vehicles.
The spark plug that will produce has the main body comprising head zone.Coating is at least partially disposed on head zone.Head zone is designed at least one combustion chamber when spark plug is arranged in explosive motor towards explosive motor.This respect, head zone is placed in relevant combustion chamber at least in part.This respect, head zone is intended to the combustion chamber being assigned to explosive motor.
Preferably spark plug itself has standard design.It comprises central electrode and at least one grounding electrode, grounding electrode and central electrode separate and by least part of combination of insulator relative to central electrode electric insulation.
According to the present invention, by following steps, coating is arranged on the head zone of spark plug:
-make at least part of roughening of head zone,
-will the head zone being coated to roughening be starched,
The slurry of-dry coating,
-heating is coated to the slurry of the head zone of roughening to form enamel layer.
In this regard, be form enamel layer in the head zone of the main body of spark plug according to the essence of technique of the present invention.Compared to providing layer of precious metal, this advantage produced is the deposition having stoped oil carbon according to enamel layer of the present invention to a great extent.At this on the one hand, enamel layer does not play the effect reducing the such temperature needed for deposit of burn off, but stops or at least reduce and formed from the beginning.
---being such as drops---deposits and dries up on enamel layer to cause this knowledge to be in fact do not have the fluid composition of fuel.This has been considered to be in main cause spark plug being formed the lamella as coal tar.So prevent or reduce such deposit to mean that possible its glows be no longer possible at least in a large number.
In addition, enamel layer according to the present invention plays the effect of extra insulator, thus reliably prevents the interruption of possible pilot spark.Deposit is if possible in fact along with the time is formed in head zone, and this is especially correlated with.Because deposit is conductivity, from prior art, if provide the layer of precious metal equally with conductivity that pilot spark that is uncontrollable and that damage so may occur, the present invention can avoid this.
Due to enamel layer according to the present invention, will there is duplicate protection effectively in the operation thus for reliable spark plug, and the result as this correspondingly improves the waste gas value formed in explosive motor running.This reason is caused to be anti-adhesive according to the enamel layer at least in the head zone of relevant spark plug of the present invention and electrical insulation capability.
Can advantageously be readily incorporated in the existing technique of producing spark plug according to the layout of enamel layer of the present invention.Due to the heat resistanceheat resistant performance of enamel layer, this proves that for its operating position and the relevant heat load acted on it be very durable.
Especially preferred, enamel layer can be oxidation and be also level and smooth and be the enamel layer of catalytic activity.Alternatively or in addition, enamel layer also can be the form of " clean enamel ".Such as, such enamel layer is well-known with the lining of household electrical appliance such as baking box.If baking box runs at than usually higher temperature, these comprise self-cleaning effect.Then this relates to purification annealing, and the deposit such as oil lamella of any attachment wherein can by complete catalytic decomposition without the need to mechanism.
For the purposes of the present invention, should be understood that the initial basis of starching the enamel layer be to provide.This is preferably the dough of the form of mineral mixture, exists, and be coated to the part of the roughening of head zone in a suitable manner with the fluid of pasty state to the denseness of viscous.
About the use of painting method, such as contact process or no-contact can be expected for coating.Therefore, such as can by means of feeding rod or feeding brush coating materials.In addition, such as coating can be completed particularly by airless spraying by flooding or spraying.
Subsequently such as in surrounding air or by the dry slurry applied of heated air jets.The slurry of heat drying is to be used as to form enamel layer subsequently.For the purposes of the present invention, what it is also understood that is that heating refers to annealing, sintering, baking.
According to the Advantageous developments of basic thought of the present invention, before heating, can roughening provide slurry to the metal section of spark plug being positioned at head zone at least in part.In other words, this respect invention provides for enamel layer and can be formed in the metal section of head zone.
The especially preferred enamel layer being can extend to the interior and outside of head zone.This respect, it should be understood that inside refers to mainly towards the region of central electrode.On the contrary, outside is the region away from central electrode.In inside, due to the electric insulation effect of enamel layer, the task of enamel layer is the possible interruption effectively stoping pilot spark on the deposit that existed.On the contrary, provide enamel layer to be mainly used as to stop due to the deposit causing maximum discharge value in addition that glows in outside.
In addition, define at least part of roughening before heating to starch to the SI semi-insulation body being positioned at head zone with providing.In other words, the layout of enamel layer also can extend to the region of insulator.
Another Advantageous developments of the present invention defines, and after starching described in drying and before heating, can mechanical possible the crossing removing the slurry of coating spray at least in part.This mainly comprises central electrode and/or at least one grounding electrode.Object be formed controlled with enough pilot sparks, in order to the corresponding electrode of this object should exist with formation exposed as far as possible.Depend on the technique for coating materials, thus need local to remove the coating of the unwanted slurry being called as spray before heating.
The basis of coating materials is provided by the roughening operation be applicable to of head zone.For this purpose, invention provides for the roughening that such as can be affected initially required partial head region or whole head zone by sandblasting.What self-evidently can also imagine is the technique further making the suitable preparation surface for coating materials separately become possible roughening.This roughening is mainly used as between head zone and the surface of enamel layer, provide durable combination.Result is the surface that the latter can be fixed on head zone preferably.In addition, contact-making surface is expanded by roughening.
The slurry of coating preferably heats in the temperature range of 800 DEG C-900 DEG C.Especially preferred is use protective gas to complete heating.By heating under a shielding gas, incrustation and the variable color of the layer formed on the external screw thread of spark plug especially effectively can be stoped.
The present technique proposing to produce spark plug according to the present invention provides has the possible method that cost-benefit formation can be attached to the coating of the enamel layer form in existing production sequence easily.Stop the sedimental fact by the electric insulation effect of the enamel layer of heatproof in conjunction with the latter, what totally can guarantee is that the reliability service of spark plug is for improvement of the waste gas value formed in running.
The invention still further relates to the spark plug of the explosive motor especially explosive motor of motor vehicles.Preferably according to above-mentioned explained hereafter spark plug of the present invention.
Here, spark plug comprises the main body with head zone, and head zone is intended to the combustion chamber being assigned to explosive motor.In addition, coating is at least partially disposed in head zone.According to the present invention, coating is enamel layer.Alternatively, coating also at least comprises enamel.
More than combine the advantage having explained generation according to the technique of production spark plug of the present invention, and be correspondingly applicable to according to spark plug of the present invention.In addition, the further favourable improvement according to spark plug of the present invention of the following stated is also applicable to.For this reason, now with reference to above said content.
According to the favourable improvement of spark plug according to the present invention, enamel layer is formed by starching.About the component of slurry, define being made up of at least one glass forming oxide except the additional component of at least one and (if necessary) extra at least one opacifiers.
Such as, the group of possible glass forming oxide be at least following in one:
-silicon dioxide (SiO 2)
-diboron trioxide (B 2o 3)
-sodium oxide molybdena (Na 2o)
-potassium oxide (K 2o)
-alundum (Al2O3) (Al 2o 3)
Self-evidently this inventory is not deterministic, thus can also imagine further network former.
About the component that at least one is other, such as, can derive from following group:
-borax
-feldspar
-quartz
-fluoride
-soda
-sodium nitrate
Here situation is that this inventory neither be deterministic, thus can also imagine further component.
If necessary, as at least one opacifiers added, such as, can select from following group:
-titanium (Ti)
-zirconium (Zr)
-molybdenum (Mo)
Similarly this is not deterministic inventory, therefore can also imagine other opacifiers such as tin ash or titanium silicate.
Enamel layer according to the present invention is preferably molten mixture.In glazing temperature, glass forming oxide is melted in together to form glass melt.Substrate enamel comprises the borax of about 23-34% weight, the feldspar of 28-52% weight, the quartz of 5-20% weight, the fluoride of about 5% weight, and remainder is soda and sodium nitrate.As already mentioned, the oxide of Ti, Zr and Mo can be used as opacifiers.
And, ceramic paint such as iron oxide, chromium oxide and spinelle can also be there is.
In order to improve the adhesive force especially on metal matrix, also comprise at least one oxide in such as following group in addition according to enamel layer of the present invention:
-cobalt oxide
-manganese oxide
-nickel oxide
In preferred improvement, described matrix be fine grinding with thawing.Melt is quenching, and that is preferably introduce water, therefore granular glass frit produces, in a subsequent step fine grinding again.Such as, the water of 30%-40% and clay and quartz powder are added in grinding operation.Depend on the kind of enamel, also add opacifiers and coloring oxide.
This results in glaze slip, in order to good mixing, before reusing glaze slip, should the regular hour be left standstill, preferred several days.The use of the modifier be applicable to guarantees to have consistent layer thickness.
Make the level and smooth this respect of enamel layer, the latter preferably comprises a high proportion of cerium oxide (CeO).By its catalytic action, concentrate on the fuel droplet evaporation on the surface of enamel layer.As a result, the deposit may subsequently with adverse effect is not formed.And, thus the initial temperature advantageously reducing fuel combustion and the hydrocarbon (HC) burnt incompletely and carbon monoxide (CO).Result similarly reduces the discharge value in explosive motor.
Enamel layer comprises a high proportion of alundum (Al2O3) Al 2o 3, object is the breakdown strength increasing pilot spark.
According to favourable development, enamel layer can have the layer thickness of 100 μm-250 μm.
Further advantage details of the present invention and effect will be explained in more detail based on the exemplary embodiment of exemplary illustration in the following drawings.In figure:
Fig. 1 shows the partial spark plug according to longitudinal section of the present invention;
Fig. 2 shows the partial graph 1 of another form represented in the same manner.
Fig. 1 shows the longitudinal section through spark plug 1 according to the present invention.For the sake of clarity, described longitudinal section is significantly reduced to the connecting portion of the main body 2 of spark plug 1.This generally show the region being designed for the pilot spark (not showing in more detail) producing spark plug 1.
The typical structure of the spark plug 1 be made up of central electrode 3 surrounded with insulated body 4 that the longitudinal section longitudinal direction x shown along spark plug 1 extends.Insulator 4 can be porcelain body.Insulator 4 has and makes the central electrode 3 of pencil shape be arranged on tubular structure in insulating body 4 (not showing in more detail).Insulating body 4 is as the further metallic region electric insulation making central electrode 3 about main body 2.
This respect, insulating body 4 is also as making central electrode 3 about grounding electrode 5 electric insulation arranged on the body 2.Grounding electrode 5 bends to the angle of picture bracket, and first it extend from the front 6 of main body 2 with the direction of longitudinal direction x, then on central electrode 3, bends to angle.Like this, central electrode 3 and grounding electrode 5 are separated from each other and have the electrode spacing of formation.
Can find out, the periphery of main body 2 has external screw thread 7.External screw thread 7 is for being connected spark plug 1 with cylinder cover (the not showing in more detail) hole of explosive motor.For this purpose, hole (not shown) has the internal thread be connected with the external screw thread 7 of the main body 2 of spark plug 1 accordingly.
In Fig. 1, visible partial spark plug 1 comprises the head zone 8 being intended to correspondingly be arranged on or aim at the combustion chamber (invisible) of explosive motor.Can find out that main body 2 has tubular structure in head zone 8, SI semi-insulation body 4 is placed in main body 2 together with the central electrode 3 be arranged on wherein and separates from it.Thus annular gap 9 is formed between the inside region and the exterior lateral area of insulator 4 together with central electrode 3 of main body 2.
Can find out, the coating of the form of porcelain glaze coating 10 is arranged in head zone 8.Here, porcelain glaze coating 10 extends on annular gap 9, thus extends in the inside region of corresponding main body 2 and the exterior lateral area of corresponding insulator 4.Here, and enamel layer 10 also surround main body 2 front 6 upwards until the starting point of the external screw thread 7 of main body 2.In addition, the partial earthing electrode 5 extended with longitudinal direction x is also surrounded by enamel layer 10 substantially.
Fig. 2 again show head zone 8 in simplified form.This respect, do not have to make the otch through insulator 4, therefore the latter covers the central electrode 3 extended wherein in the present circumstance.Compared to the explanation in Fig. 1, enamel layer 10 terminates in the front 6 of main body 2 here.On the contrary, noticeable enamel layer 10, further at grounding electrode 5, especially also extends, so that the latter is only uncoated at free end portion on 3/4ths angle parts of grounding electrode 5.Generally speaking, enamel layer 10 has the enough layer thicknesses for realizing high breakdown strength relative to pilot spark.Layer thickness is 100 μm-250 μm in the present circumstance.
Reference numerals list
1 spark plug
The main body of 21
The central electrode of 31
The insulator of 41
The grounding electrode of 51
The front of 62
The external screw thread of 72
The head zone of 81 and 2
Gap between 92 and 4
The enamel layer of 101
Electrode spacing between a3 and 5
The longitudinal direction of b1

Claims (11)

1. produce the method for the spark plug (1) of the explosive motor of especially motor vehicles for one kind, spark plug (1) comprises the main body (2) with head zone (8), head zone (8) is intended to the combustion chamber being assigned to explosive motor, what coating was at least part of is arranged in head zone (8)
Described method at least has following steps:
-make head zone (8) roughening at least partly,
-will the head zone (8) being coated to roughening be starched,
The slurry of-dry coating,
-heating is coated to the slurry of the head zone (8) of roughening to form enamel layer (10).
2. method according to claim 1,
Wherein
Heat front roughening at least partly and the metal section of starching to the spark plug (1) being positioned at head zone (8) is provided.
3. method according to claim 1 and 2,
Wherein,
Before heating, roughening is starched to the SI semi-insulation body (4) being positioned at head zone (8) with providing at least partly.
4. the method according to aforementioned any one claim,
Wherein
Described in drying slurry after and before heating, at least part of machinery remove the slurry of the coating on central electrode (3) and/or grounding electrode (4) cross spray.
5. the method according to aforementioned any one claim,
Wherein
By blasted rough head zone (8).
6. the method according to aforementioned any one claim,
Wherein
Especially protective gas is used to heat slurry in the temperature range of 800 DEG C-900 DEG C.
7. the method according to aforementioned any one claim,
Wherein
Starch at least one glass forming oxide comprised in following group:
-silicon dioxide (SiO 2)
-diboron trioxide (B 2o 3)
-sodium oxide molybdena (Na 2o)
-potassium oxide (K 2o)
-alundum (Al2O3) (Al 2o 3)
And at least one component also comprised in following group:
-borax
-feldspar
-quartz
-fluoride
-soda
-sodium nitrate
And if necessary, comprise at least one opacifiers in following group
-titanium (Ti)
-zirconium (Zr)
-molybdenum (Mo).
8. the spark plug of the explosive motor produced particularly by the method described in aforementioned any one claim, comprise the main body (2) with head zone (8), head zone (8) is intended to the combustion chamber being assigned to explosive motor, what coating was at least part of is arranged in head zone (8)
Wherein
Coating is enamel layer (10) or at least comprises enamel.
9. spark plug according to claim 8,
Wherein
Enamel layer (1) is formed by slurry, starches at least one glass forming oxide comprised in following group:
-silicon dioxide (SiO 2)
-diboron trioxide (B 2o 3)
-sodium oxide molybdena (Na 2o)
-potassium oxide (K 2o)
-alundum (Al2O3) (Al 2o 3)
And at least one component also comprised in following group:
-borax
-feldspar
-quartz
-fluoride
-soda
-sodium nitrate
And if necessary, comprise at least one opacifiers in following group
-titanium (Ti)
-zirconium (Zr)
-molybdenum (Mo).
10. spark plug according to claim 8 or claim 9,
Wherein
Enamel layer (10) comprises at least one oxide in following group:
-cobalt oxide
-manganese oxide
-nickel oxide.
11. according to Claim 8 to 10 spark plug wherein described in,
Wherein
Enamel layer (10) has the layer thickness of 100 μm-250 μm.
CN201510309282.8A 2014-06-06 2015-06-08 Method for producing spark plug of internal combustion engine and spark plug of internal combustion engine Active CN105186292B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102014210922.1A DE102014210922A1 (en) 2014-06-06 2014-06-06 Method for producing a spark plug for an internal combustion engine and spark plug for an internal combustion engine
DE102014210922.1 2014-06-06

Publications (2)

Publication Number Publication Date
CN105186292A true CN105186292A (en) 2015-12-23
CN105186292B CN105186292B (en) 2020-07-14

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CN (1) CN105186292B (en)
DE (1) DE102014210922A1 (en)
RU (1) RU2703873C2 (en)

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CN109869233A (en) * 2017-12-05 2019-06-11 通用电气公司 Heat product for turbogenerator
CN113544921A (en) * 2019-03-20 2021-10-22 罗伯特·博世有限公司 Spark plug shell with electroplated nickel and zinc containing protective layer and silicon containing sealing layer and spark plug with shell and method for manufacturing shell

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DE102018222460A1 (en) 2018-12-20 2020-06-25 Robert Bosch Gmbh Spark plug with rounded insulator base section
DE102018222468A1 (en) * 2018-12-20 2020-06-25 Robert Bosch Gmbh Spark plug with rounded insulator base section and rounded housing section
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RU2703873C2 (en) 2019-10-22
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EP2953217A1 (en) 2015-12-09
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RU2015121744A3 (en) 2019-01-18
CN105186292B (en) 2020-07-14

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