CN105176160A - Water-borne coating with high oxidation resistance and preparation method thereof - Google Patents
Water-borne coating with high oxidation resistance and preparation method thereof Download PDFInfo
- Publication number
- CN105176160A CN105176160A CN201510682457.XA CN201510682457A CN105176160A CN 105176160 A CN105176160 A CN 105176160A CN 201510682457 A CN201510682457 A CN 201510682457A CN 105176160 A CN105176160 A CN 105176160A
- Authority
- CN
- China
- Prior art keywords
- parts
- water
- borne coatings
- antioxidant property
- auxiliary agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a water-borne coating with high oxidation resistance and a preparation method thereof. The water-borne coating with high oxidation resistance is prepared from following raw materials in parts by weight: 85 to 88 parts of epoxy-modified organic silicon resin, 30 to 38 parts of hydroxypropyl bromic acid resin, 11 to 13 parts of lecithin, 18 to 24 parts of dodecyl acrylate, 15 to 18 parts of diethyl malonate, 12 to 16 parts of calcite, 2 to 4 parts of silicone oil, 50 to 55 parts of deionized water, 7 to 9 parts of crylic acid and 5 to 8 parts of additive. The invention also provides the preparation method of the coating. The coating not only has high oxidation resistance and high abrasion resistance, but also has good adhesion, and therefore cannot easily shed; the surface friction coefficient of the coating is small, so the coating can resist abrasion; moreover, colors are diversified, the service life is long, toxicity is low, the surface tension is small, the surface activity is high, and the cost is low; the coating does not blister, fade and shed for a long time; furthermore, the adhesion property of the coating to various materials is good.
Description
Technical field
The present invention relates to a kind of coating, water-borne coatings that a kind of antioxidant property is high specifically and preparation method thereof.
Background technology
At present, the water-borne coatings that antioxidant property is high can be widely used in the industries such as electrical equipment, metallurgy, oil, aviation field, chemical industry, medicine, food various in, because equipment is in the process of life-time service, after a variety of causes causes coating surface breakage, thus cause the inner rapid oxidation of coating, damage its structure, reduce its work-ing life, damage equipment, causes huge loss.
Summary of the invention
Technical problem to be solved by this invention is, for the shortcoming of above prior art, propose high water-borne coatings of a kind of antioxidant property and preparation method thereof, this water-borne coatings not only antioxidant property is high, crocking resistance is strong, and adhesivity is good, difficult drop-off, this water-borne coatings skin friction coefficient is little, rub resistance, manufacture simple, cost is low, long service life.
In order to solve the problems of the technologies described above, technical scheme of the present invention is achieved in the following ways: the water-borne coatings that a kind of antioxidant property is high, and following raw material counted by weight by the water-borne coatings that antioxidant property is high:
Epoxy modified silicone resin: 85-88 part
Hydroxyl third bromic acid resin: 30-38 part
Yelkin TTS: 11-13 part
Dodecyl acrylate: 18-24 part
Diethyl malonate: 15-18 part
Calcite: 12-16 part
Silicone oil: 2-4 part
Deionized water: 50-55 part
Vinylformic acid: 7-9 part
Auxiliary agent: 5-8 part;
The component of auxiliary agent is counted by weight: zircon: 7-9 part, talcum powder: 3-5 part, deionized water: 10-15 part, titanium dioxide: 2-4 part, Graphite Powder 99: 0.5-0.8 part;
The preparation method of auxiliary agent is: by zircon and talcum powder co-grinding, cross 120 mesh sieves, obtain powders A, then titanium dioxide and Graphite Powder 99 co-grinding, cross 40 mesh sieves, obtain powder B, powders A and powder B are uniformly mixed with the ratio of 1:3, stir 5-8 minute, then add deionized water and stirring reaction 15-20 minute, then filter, dry, pulverize, cross 120 mesh sieves, under nitrogen protection, after calcining 2-3 hour at being heated to 860-880 DEG C, air cooling, to room temperature, is then pulverized, cross 100 mesh sieves, can auxiliary agent be obtained; And use following method to obtain the high water-borne coatings of this antioxidant property:
Step (1): by raw material: epoxy modified silicone resin, hydroxyl third bromic acid resin are first put into stirring tank with Yelkin TTS and mixed, temperature in control stirring tank is at 45-50 DEG C, setting stirring velocity 676-680r/min, churning time 30-35min, then mix putting into dodecyl acrylate, diethyl malonate, calcite and silicone oil successively, stirring velocity is 820-830r/min, keeps 40-45min;
Step (2): then by raw material: deionized water, vinylformic acid and auxiliary agent are put into stirring tank and mixed, setting stirring velocity is 850-860r/min, churning time is 52-70min, and modulation water-borne coatings pH value is 8-9, can obtain the water-borne coatings that described antioxidant property is high.
The technical scheme that the present invention limits further is:
The water-borne coatings that aforesaid antioxidant property is high, following raw material counted by weight by the water-borne coatings that antioxidant property is high: epoxy modified silicone resin: 85 parts, hydroxyl third bromic acid resin: 30 parts, Yelkin TTS: 11 parts, dodecyl acrylate: 18 parts, diethyl malonate: 15 parts, calcite: 12 parts, silicone oil: 2 parts, deionized water: 50 parts, vinylformic acid: 7 parts, auxiliary agent: 5 parts.
The water-borne coatings that aforesaid antioxidant property is high, following raw material counted by weight by the water-borne coatings that antioxidant property is high: epoxy modified silicone resin: 88 parts, hydroxyl third bromic acid resin: 38 parts, Yelkin TTS: 13 parts, dodecyl acrylate: 24 parts, diethyl malonate: 18 parts, calcite: 16 parts, silicone oil: 4 parts, deionized water: 55 parts, vinylformic acid: 9 parts, auxiliary agent: 8 parts.
The water-borne coatings that aforesaid antioxidant property is high, following raw material counted by weight by the water-borne coatings that antioxidant property is high: epoxy modified silicone resin: 87 parts, hydroxyl third bromic acid resin: 34 parts, Yelkin TTS: 12 parts, dodecyl acrylate: 19 parts, diethyl malonate: 17 parts, calcite: 14 parts, silicone oil: 3 parts, deionized water: 52 parts, vinylformic acid: 8 parts, auxiliary agent: 7 parts.
The invention has the beneficial effects as follows: not only antioxidant property is high for the high water-borne coatings of this antioxidant property, crocking resistance is strong, and adhesivity is good, difficult drop-off, this coating surface frictional coefficient is little, rub resistance, and color is various, long service life, not only toxicity is little, surface tension is little, and surfactivity is high, and cost is low; The water-borne coatings that this antioxidant property is high can keep for a long time non-foaming, colour-fast, not mildew spot, do not come off; And all have good adhesion property to various material, smooth, outward appearance is beautiful.
Embodiment
The present invention is described in further detail below:
embodiment 1
The water-borne coatings that a kind of antioxidant property that the present embodiment provides is high, following raw material counted by weight by the water-borne coatings that antioxidant property is high: epoxy modified silicone resin: 85 parts, hydroxyl third bromic acid resin: 30 parts, Yelkin TTS: 11 parts, dodecyl acrylate: 18 parts, diethyl malonate: 15 parts, calcite: 12 parts, silicone oil: 2 parts, deionized water: 50 parts, vinylformic acid: 7 parts, auxiliary agent: 5 parts;
The component of auxiliary agent is counted by weight: zircon: 7 parts, talcum powder: 3 parts, deionized water: 10 parts, titanium dioxide: 2 parts, Graphite Powder 99: 0.5 part;
The preparation method of auxiliary agent is: by zircon and talcum powder co-grinding, crosses 120 mesh sieves, obtains powders A, then titanium dioxide and Graphite Powder 99 co-grinding, cross 40 mesh sieves, obtain powder B, powders A and powder B are uniformly mixed with the ratio of 1:3, stir 5 minutes, then add deionized water and stirring and react 15 minutes, then filter, dry, pulverize, cross 120 mesh sieves, under nitrogen protection, calcine after 2 hours at being heated to 860 DEG C, air cooling is to room temperature, then pulverize, cross 100 mesh sieves, can auxiliary agent be obtained; And use following method to obtain the high water-borne coatings of this antioxidant property:
Step (1): by raw material: epoxy modified silicone resin, hydroxyl third bromic acid resin are first put into stirring tank with Yelkin TTS and mixed, temperature in control stirring tank is at 45 DEG C, setting stirring velocity 676r/min, churning time 30min, then mix putting into dodecyl acrylate, diethyl malonate, calcite and silicone oil successively, stirring velocity is 820r/min, keeps 40min;
Step (2): then by raw material: deionized water, vinylformic acid and auxiliary agent are put into stirring tank and mixed, setting stirring velocity is 850r/min, churning time is 52min, and modulation water-borne coatings pH value is 8, can obtain the water-borne coatings that described antioxidant property is high.
embodiment 2
The water-borne coatings that a kind of antioxidant property that the present embodiment provides is high, following raw material counted by weight by the water-borne coatings that antioxidant property is high: epoxy modified silicone resin: 88 parts, hydroxyl third bromic acid resin: 38 parts, Yelkin TTS: 13 parts, dodecyl acrylate: 24 parts, diethyl malonate: 18 parts, calcite: 16 parts, silicone oil: 4 parts, deionized water: 55 parts, vinylformic acid: 9 parts, auxiliary agent: 8 parts;
The component of auxiliary agent is counted by weight: zircon: 9 parts, talcum powder: 5 parts, deionized water: 15 parts, titanium dioxide: 4 parts, Graphite Powder 99: 0.8 part;
The preparation method of auxiliary agent is: by zircon and talcum powder co-grinding, crosses 120 mesh sieves, obtains powders A, then titanium dioxide and Graphite Powder 99 co-grinding, cross 40 mesh sieves, obtain powder B, powders A and powder B are uniformly mixed with the ratio of 1:3, stir 8 minutes, then add deionized water and stirring and react 20 minutes, then filter, dry, pulverize, cross 120 mesh sieves, under nitrogen protection, calcine after 3 hours at being heated to 880 DEG C, air cooling is to room temperature, then pulverize, cross 100 mesh sieves, can auxiliary agent be obtained; And use following method to obtain the high water-borne coatings of this antioxidant property:
Step (1): by raw material: epoxy modified silicone resin, hydroxyl third bromic acid resin are first put into stirring tank with Yelkin TTS and mixed, temperature in control stirring tank is at 50 DEG C, setting stirring velocity 680r/min, churning time 35min, then mix putting into dodecyl acrylate, diethyl malonate, calcite and silicone oil successively, stirring velocity is 830r/min, keeps 45min;
Step (2): then by raw material: deionized water, vinylformic acid and auxiliary agent are put into stirring tank and mixed, setting stirring velocity is 860r/min, churning time is 70min, and modulation water-borne coatings pH value is 9, can obtain the water-borne coatings that described antioxidant property is high.
embodiment 3
The water-borne coatings that a kind of antioxidant property that the present embodiment provides is high, following raw material counted by weight by the water-borne coatings that antioxidant property is high: epoxy modified silicone resin: 87 parts, hydroxyl third bromic acid resin: 34 parts, Yelkin TTS: 12 parts, dodecyl acrylate: 19 parts, diethyl malonate: 17 parts, calcite: 14 parts, silicone oil: 3 parts, deionized water: 52 parts, vinylformic acid: 8 parts, auxiliary agent: 7 parts;
The component of auxiliary agent is counted by weight: zircon: 8 parts, talcum powder: 4 parts, deionized water: 12 parts, titanium dioxide: 3 parts, Graphite Powder 99: 0.7 part;
The preparation method of auxiliary agent is: by zircon and talcum powder co-grinding, crosses 120 mesh sieves, obtains powders A, then titanium dioxide and Graphite Powder 99 co-grinding, cross 40 mesh sieves, obtain powder B, powders A and powder B are uniformly mixed with the ratio of 1:3, stir 7 minutes, then add deionized water and stirring and react 18 minutes, then filter, dry, pulverize, cross 120 mesh sieves, under nitrogen protection, calcine after 3 hours at being heated to 870 DEG C, air cooling is to room temperature, then pulverize, cross 100 mesh sieves, can auxiliary agent be obtained; And use following method to obtain the high water-borne coatings of this antioxidant property:
Step (1): by raw material: epoxy modified silicone resin, hydroxyl third bromic acid resin are first put into stirring tank with Yelkin TTS and mixed, temperature in control stirring tank is at 48 DEG C, setting stirring velocity 678r/min, churning time 33min, then mix putting into dodecyl acrylate, diethyl malonate, calcite and silicone oil successively, stirring velocity is 828r/min, keeps 42min;
Step (2): then by raw material: deionized water, vinylformic acid and auxiliary agent are put into stirring tank and mixed, setting stirring velocity is 855r/min, churning time is 60min, and modulation water-borne coatings pH value is 8, can obtain the water-borne coatings that described antioxidant property is high.
Like this by technical scheme of the present invention, this water-borne coatings not only antioxidant property is high, and crocking resistance is strong, and adhesivity is good, difficult drop-off, this coating surface frictional coefficient is little, rub resistance, and color is various, long service life, not only toxicity is little, and surface tension is little, surfactivity is high, and cost is low; This coating can keep for a long time non-foaming, colour-fast, not mildew spot, do not come off; And all have good adhesion property to various material, smooth, outward appearance is beautiful.
Above embodiment is only and technological thought of the present invention is described, can not limit protection scope of the present invention with this, and every technological thought proposed according to the present invention, any change that technical scheme basis is done, all falls within scope.
Claims (5)
1. the water-borne coatings that antioxidant property is high, is characterized in that: following raw material counted by weight by the water-borne coatings that described antioxidant property is high:
Epoxy modified silicone resin: 85-88 part
Hydroxyl third bromic acid resin: 30-38 part
Yelkin TTS: 11-13 part
Dodecyl acrylate: 18-24 part
Diethyl malonate: 15-18 part
Calcite: 12-16 part
Silicone oil: 2-4 part
Deionized water: 50-55 part
Vinylformic acid: 7-9 part
Auxiliary agent: 5-8 part;
The component of described auxiliary agent is counted by weight: zircon: 7-9 part, talcum powder: 3-5 part, deionized water: 10-15 part, titanium dioxide: 2-4 part, Graphite Powder 99: 0.5-0.8 part;
The preparation method of described auxiliary agent is: by zircon and talcum powder co-grinding; cross 120 mesh sieves; obtain powders A, then titanium dioxide and Graphite Powder 99 co-grinding, cross 40 mesh sieves; obtain powder B; powders A and powder B are uniformly mixed with the ratio of 1:3, stir 5-8 minute, then add deionized water and stirring reaction 15-20 minute; then filter; dry, pulverize, cross 120 mesh sieves; under nitrogen protection; after calcining 2-3 hour at being heated to 860-880 DEG C, air cooling, to room temperature, is then pulverized; cross 100 mesh sieves, can auxiliary agent be obtained.
2. the water-borne coatings that antioxidant property according to claim 1 is high, is characterized in that: following raw material counted by weight by the water-borne coatings that described antioxidant property is high:
Epoxy modified silicone resin: 85 parts
Hydroxyl third bromic acid resin: 30 parts
Yelkin TTS: 11 parts
Dodecyl acrylate: 18 parts
Diethyl malonate: 15 parts
Calcite: 12 parts
Silicone oil: 2 parts
Deionized water: 50 parts
Vinylformic acid: 7 parts
Auxiliary agent: 5 parts.
3. the water-borne coatings that antioxidant property according to claim 1 is high, is characterized in that: following raw material counted by weight by the water-borne coatings that described antioxidant property is high:
Epoxy modified silicone resin: 88 parts
Hydroxyl third bromic acid resin: 38 parts
Yelkin TTS: 13 parts
Dodecyl acrylate: 24 parts
Diethyl malonate: 18 parts
Calcite: 16 parts
Silicone oil: 4 parts
Deionized water: 55 parts
Vinylformic acid: 9 parts
Auxiliary agent: 8 parts.
4. the water-borne coatings that antioxidant property according to claim 1 is high, is characterized in that: following raw material counted by weight by the water-borne coatings that described antioxidant property is high:
Epoxy modified silicone resin: 87 parts
Hydroxyl third bromic acid resin: 34 parts
Yelkin TTS: 12 parts
Dodecyl acrylate: 19 parts
Diethyl malonate: 17 parts
Calcite: 14 parts
Silicone oil: 3 parts
Deionized water: 52 parts
Vinylformic acid: 8 parts
Auxiliary agent: 7 parts.
5. a preparation method for the water-borne coatings that antioxidant property is high, is characterized in that: the method is carried out according to the following steps:
Step (1): by raw material: epoxy modified silicone resin, hydroxyl third bromic acid resin are first put into stirring tank with Yelkin TTS and mixed, temperature in control stirring tank is at 45-50 DEG C, setting stirring velocity 676-680r/min, churning time 30-35min, then mix putting into dodecyl acrylate, diethyl malonate, calcite and silicone oil successively, stirring velocity is 820-830r/min, keeps 40-45min;
Step (2): then by raw material: deionized water, vinylformic acid and auxiliary agent are put into stirring tank and mixed, setting stirring velocity is 850-860r/min, churning time is 52-70min, and modulation water-borne coatings pH value is 8-9, can obtain the water-borne coatings that described antioxidant property is high.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510682457.XA CN105176160A (en) | 2015-10-21 | 2015-10-21 | Water-borne coating with high oxidation resistance and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510682457.XA CN105176160A (en) | 2015-10-21 | 2015-10-21 | Water-borne coating with high oxidation resistance and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105176160A true CN105176160A (en) | 2015-12-23 |
Family
ID=54898620
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510682457.XA Pending CN105176160A (en) | 2015-10-21 | 2015-10-21 | Water-borne coating with high oxidation resistance and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105176160A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109593430A (en) * | 2018-11-14 | 2019-04-09 | 江苏海龙核科技股份有限公司 | A kind of anticorrosion, mould proof civil air defense constructions and installations coating |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012036210A1 (en) * | 2010-09-14 | 2012-03-22 | 中国塗料株式会社 | Aqueous coating composition and corrosion prevention method using said aqueous coating composition |
| CN104277687A (en) * | 2014-09-04 | 2015-01-14 | 青岛佳尚创意文化有限公司 | Water-based paint |
| CN104672963A (en) * | 2015-03-12 | 2015-06-03 | 江苏欣安新材料技术有限公司 | Coating used on surface of metal and preparation method for coating |
| CN104672964A (en) * | 2015-03-12 | 2015-06-03 | 江苏欣安新材料技术有限公司 | Coating with high oxidation resistance, and preparation method thereof |
| CN104876538A (en) * | 2015-04-27 | 2015-09-02 | 苏州统明机械有限公司 | Ceramic having rare earth elements and preparation method thereof |
-
2015
- 2015-10-21 CN CN201510682457.XA patent/CN105176160A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012036210A1 (en) * | 2010-09-14 | 2012-03-22 | 中国塗料株式会社 | Aqueous coating composition and corrosion prevention method using said aqueous coating composition |
| CN104277687A (en) * | 2014-09-04 | 2015-01-14 | 青岛佳尚创意文化有限公司 | Water-based paint |
| CN104672963A (en) * | 2015-03-12 | 2015-06-03 | 江苏欣安新材料技术有限公司 | Coating used on surface of metal and preparation method for coating |
| CN104672964A (en) * | 2015-03-12 | 2015-06-03 | 江苏欣安新材料技术有限公司 | Coating with high oxidation resistance, and preparation method thereof |
| CN104876538A (en) * | 2015-04-27 | 2015-09-02 | 苏州统明机械有限公司 | Ceramic having rare earth elements and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109593430A (en) * | 2018-11-14 | 2019-04-09 | 江苏海龙核科技股份有限公司 | A kind of anticorrosion, mould proof civil air defense constructions and installations coating |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106928813B (en) | A kind of preparation method of the cross-linking aqueous epoxy coating of antibacterial colloidal sol | |
| CN104449283B (en) | A kind of aging resistance coating and preparation method thereof | |
| CN103756530A (en) | High-flexibility anti-cracking primer and preparation method thereof | |
| CN109825164A (en) | Solventless epoxy coating suit and its preparation method and application | |
| CN105176160A (en) | Water-borne coating with high oxidation resistance and preparation method thereof | |
| CN104449121A (en) | Antibacterial anticorrosive coating | |
| CN104449119A (en) | Anti-aging rosin coating | |
| CN105176385A (en) | Abrasion-resistant and high-strength water-borne coating and preparation method thereof | |
| CN104293108A (en) | High-adhesive-force wear-resistant modified dicyclopentadiene phenol epoxy resin coating | |
| CN104629618A (en) | High-friction-resistance paint and preparation method thereof | |
| CN104672964A (en) | Coating with high oxidation resistance, and preparation method thereof | |
| CN109251644A (en) | A kind of polyureas floor coatings and its preparation, application method and carbamide resin | |
| CN114933877B (en) | High molecular weight solvent type acrylic ester pressure-sensitive adhesive and preparation method thereof | |
| CN104387857A (en) | Environment-friendly nano paint and preparation method thereof | |
| CN105694670A (en) | Anti-oxidation coating with added zinc oxide and preparation method of anti-oxidation coating | |
| CN103965751B (en) | A kind of super organic solvent-resistant type baked paint and preparation method thereof | |
| CN105176166A (en) | Water-based paint with flame retarding function and preparation method of water-based paint | |
| CN108610973A (en) | A kind of vehicle frame protection paint and preparation method thereof | |
| CN108047786A (en) | A kind of fire resistant anticorrosive paint and preparation method thereof | |
| CN110016280A (en) | A kind of sports equipment anti-decaying paint and preparation method thereof | |
| CN107779094A (en) | A kind of air compressor machine surface-treated metal paint and preparation method thereof | |
| CN105176389A (en) | Metal element-containing high-intensity water-base paint and preparation method thereof | |
| CN104845495A (en) | Exterior-wall fireproof coating and preparation method thereof | |
| CN108373756A (en) | A kind of antifriction metal (AFM) powdery paints | |
| CN103333593B (en) | The powder coating of a kind of oil-proofness bisphenol A polycarbonate and its preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151223 |