CN104293108A - High-adhesive-force wear-resistant modified dicyclopentadiene phenol epoxy resin coating - Google Patents
High-adhesive-force wear-resistant modified dicyclopentadiene phenol epoxy resin coating Download PDFInfo
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- CN104293108A CN104293108A CN201410588271.3A CN201410588271A CN104293108A CN 104293108 A CN104293108 A CN 104293108A CN 201410588271 A CN201410588271 A CN 201410588271A CN 104293108 A CN104293108 A CN 104293108A
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- epoxy resin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Life Sciences & Earth Sciences (AREA)
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- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a high-adhesive-force wear-resistant modified dicyclopentadiene phenol epoxy resin coating, which is prepared by the following raw materials in parts by weight: 67-70 parts of modified dicyclopentadiene phenol epoxy resin, 23-26 parts of ABS resin, 7-10 parts of aldehyde ketone resin KR-80F, 22-26 parts of graphene, 0.3-0.5 part of paraffin, 0.1-0.3 part of zirconium chloride, 0.05-0.08 part of aluminium caprylate, 1.3-1.6 parts of vinyloxytrimethylsilane, 0.3-0.8 part of an antifoaming agent, 0.1-0.4 part of a mould inhibitor, 2.2-2.5 parts of a curing agent, 0.1-0.5 part of a dispersing agent, and 65-70 parts of a dissolvant. The high-adhesive-force wear-resistant modified dicyclopentadiene phenol epoxy resin coating provided by the invention has the advantages that the adhesive force is high, and the wear resistance is excellent.
Description
Technical field
The present invention relates to technical field of coatings, particularly relate to a kind of high adhesive force wear-resisting modification dicyclopentadiene phenol epoxy resin coating.
Background technology
Dicyclopentadiene phenol epoxy resin is a kind of epoxy resin with special skeleton structure, it is not only containing phenyl ring, alicyclic structure also containing dicyclopentadiene, there is excellent thermotolerance, agent of low hygroscopicity ability, the ship housing coating made with it has good temperature use range and chemical stability, but, ship housing surface contacts water throughout the year, organism in water is with chemical bonding, diffusion, the modes such as electrostatic interaction are attached to ship housing surface, to peel off, the modes such as shearing come off from ship housing surface, peel off the coating on ship housing surface simultaneously, the havoc integrity of hull, great safety is brought to safety of navigation, this just has high requirement to the sticking power of ship housing coating, and the wear resisting property of this material is not good, this is just to a kind of high adhesive force of development and the good cyclopentadiene phenol-type epoxy resin coating of wear resisting property proposes clear and definite requirement.
Summary of the invention
The technical problem that basic background technology exists, the present invention proposes a kind of high adhesive force wear-resisting modification dicyclopentadiene phenol epoxy resin coating, sticking power is high, wear resisting property good.
A kind of high adhesive force wear-resisting modification dicyclopentadiene phenol epoxy resin coating that the present invention proposes, its raw material comprises by weight: modification dicyclopentadiene phenol epoxy resin 67-70 part, ABS resin 23-26 part, aldehyde ketone resin KR-80F 7-10 part, Graphene 22-26 part, paraffin 0.3-0.5 part, zirconium chloride 0.1-0.3 part, aluminium octoate 0.05-0.08 part, vinyl three oxygen methyl-monosilane 1.3-1.6 part, defoamer 0.3-0.8 part, mould inhibitor 0.1-0.4 part, solidifying agent 2.2-2.5 part, dispersion agent 0.1-0.5 part, solvent 65-70 part;
Wherein, the preparation method of modification dicyclopentadiene phenol epoxy resin is: 80-85 part dicyclopentadiene phenol epoxy resin and 10-15 part cis-1,4-polybutadiene rubber are mixed by weight, add 55-58 part mixed solvent again to mix, mixed solvent is made up of than 2-3:1-2 with amount of substance 1-Methoxy-2-propyl acetate and propandiol butyl ether, continue to add 1.2-1.5 part peroxidation acetic acid tert-pentyl ester, stir with the stirring velocity of 350-370rpm after 0.5-0.8 part sulphur and 0.1-0.3 part additional crosslinker TAIC, in whipping process, with the average heating speed of 12-15 DEG C/min, temperature is risen to 92-95 DEG C, with the average heating speed of 2.6-2.9 DEG C/min, temperature is risen to 125-128 DEG C again, be cooled to room temperature after insulation 3-5h and obtain modification dicyclopentadiene phenol epoxy resin.
Preferably, the weight ratio of modification dicyclopentadiene phenol epoxy resin, ABS resin, aldehyde ketone resin KR-80F is 68-69:24-25:8-9.
Preferably, the weight ratio of Graphene, paraffin, zirconium chloride, aluminium octoate is 23-24:0.35-0.4:0.16-0.18:0.06-0.07.
Preferably, its raw material comprises by weight: modification dicyclopentadiene phenol epoxy resin 68-69 part, ABS resin 24-25 part, aldehyde ketone resin KR-80F 8-9 part, Graphene 23-24 part, paraffin 0.35-0.4 part, zirconium chloride 0.16-0.18 part, aluminium octoate 0.06-0.07 part, vinyl three oxygen methyl-monosilane 1.4-1.5 part, defoamer 0.4-0.6 part, mould inhibitor 0.2-0.3 part, solidifying agent 2.3-2.4 part, dispersion agent 0.3-0.4 part, solvent 66-68 part.
Preferably, the preparation method of modification dicyclopentadiene phenol epoxy resin is: 82-83 part dicyclopentadiene phenol epoxy resin and 12-14 part cis-1,4-polybutadiene rubber are mixed by weight, add 56-57 part mixed solvent again to mix, mixed solvent is made up of than 2.2-2.5:1.1-1.6 with amount of substance 1-Methoxy-2-propyl acetate and propandiol butyl ether, continue to add 1.3-1.4 part peroxidation acetic acid tert-pentyl ester, stir with the stirring velocity of 360-365rpm after 0.6-0.7 part sulphur and 0.15-0.2 part additional crosslinker TAIC, in whipping process, with the average heating speed of 13-14 DEG C/min, temperature is risen to 93-94 DEG C, with the average heating speed of 2.7-2.8 DEG C/min, temperature is risen to 126-127 DEG C again, be cooled to room temperature after insulation 3.5-4h and obtain modification dicyclopentadiene phenol epoxy resin.
In the present invention, adopt cis-1,4-polybutadiene rubber and the modification of dicyclopentadiene phenol epoxy resin blended cross linking, substantially increase the wear resistance of modification dicyclopentadiene phenol epoxy resin, sticking power and elasticity, and modified epoxy and aldehyde ketone resin KR-80F are as filmogen, significantly improve wear-resisting, impact resistance of the present invention and adhesion property; The interpolation of Graphene, paraffin, zirconium chloride, aluminium octoate, further increases wear resisting property of the present invention and sticking power; In addition, vinyl three oxygen methyl-monosilane can form hydrogen bond with the hydroxyl of metal base surface, thus improves force of cohesion of the present invention and the sticking power to metallic matrix further.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
A kind of high adhesive force wear-resisting modification dicyclopentadiene phenol epoxy resin coating that the present invention proposes, its raw material comprises by weight: modification dicyclopentadiene phenol epoxy resin 70 parts, ABS resin 23 parts, aldehyde ketone resin KR-80F 10 parts, Graphene 22 parts, 0.5 part, paraffin, zirconium chloride 0.1 part, aluminium octoate 0.08 part, vinyl three oxygen methyl-monosilane 1.3 parts, defoamer 0.8 part, mould inhibitor 0.1 part, 2.5 parts, solidifying agent, dispersion agent 0.1 part, solvent 70 parts;
Wherein, the preparation method of modification dicyclopentadiene phenol epoxy resin is: 80 parts of dicyclopentadiene phenol epoxy resin and 15 parts of cis-1,4-polybutadiene rubbers are mixed by weight, add 55 parts of mixed solvents again to mix, mixed solvent is made up of than 2:1 with amount of substance 1-Methoxy-2-propyl acetate and propandiol butyl ether, continue to add 1.2 parts of peroxidation acetic acid tert-pentyl esters, stir with the stirring velocity of 370rpm after 0.8 part of sulphur and 0.1 part of additional crosslinker TAIC, in whipping process, with the average heating speed of 12 DEG C/min, temperature is risen to 95 DEG C, with the average heating speed of 2.6 DEG C/min, temperature is risen to 128 DEG C again, be cooled to room temperature after insulation 3h and obtain modification dicyclopentadiene phenol epoxy resin.
Embodiment 2
A kind of high adhesive force wear-resisting modification dicyclopentadiene phenol epoxy resin coating that the present invention proposes, its raw material comprises by weight: modification dicyclopentadiene phenol epoxy resin 67 parts, ABS resin 26 parts, aldehyde ketone resin KR-80F 7 parts, Graphene 26 parts, 0.3 part, paraffin, zirconium chloride 0.3 part, aluminium octoate 0.05 part, vinyl three oxygen methyl-monosilane 1.6 parts, defoamer 0.3 part, mould inhibitor 0.4 part, 2.2 parts, solidifying agent, dispersion agent 0.5 part, solvent 65 parts;
Wherein, the preparation method of modification dicyclopentadiene phenol epoxy resin is: 85 parts of dicyclopentadiene phenol epoxy resin and 10 parts of cis-1,4-polybutadiene rubbers are mixed by weight, add 58 parts of mixed solvents again to mix, mixed solvent is made up of than 3:2 with amount of substance 1-Methoxy-2-propyl acetate and propandiol butyl ether, continue to add 1.5 parts of peroxidation acetic acid tert-pentyl esters, stir with the stirring velocity of 350rpm after 0.5 part of sulphur and 0.3 part of additional crosslinker TAIC, in whipping process, with the average heating speed of 15 DEG C/min, temperature is risen to 92 DEG C, with the average heating speed of 2.9 DEG C/min, temperature is risen to 125 DEG C again, be cooled to room temperature after insulation 5h and obtain modification dicyclopentadiene phenol epoxy resin.
Embodiment 3
A kind of high adhesive force wear-resisting modification dicyclopentadiene phenol epoxy resin coating that the present invention proposes, its raw material comprises by weight: modification dicyclopentadiene phenol epoxy resin 69 parts, ABS resin 24 parts, aldehyde ketone resin KR-80F 9 parts, Graphene 23 parts, 0.4 part, paraffin, zirconium chloride 0.16 part, aluminium octoate 0.07 part, vinyl three oxygen methyl-monosilane 1.4 parts, defoamer 0.6 part, mould inhibitor 0.2 part, 2.4 parts, solidifying agent, dispersion agent 0.3 part, solvent 68 parts;
Wherein, the preparation method of modification dicyclopentadiene phenol epoxy resin is: 82 parts of dicyclopentadiene phenol epoxy resin and 14 parts of cis-1,4-polybutadiene rubbers are mixed by weight, add 56 parts of mixed solvents again to mix, mixed solvent is made up of than 2.5:1.1 with amount of substance 1-Methoxy-2-propyl acetate and propandiol butyl ether, continue to add 1.3 parts of peroxidation acetic acid tert-pentyl esters, stir with the stirring velocity of 365rpm after 0.7 part of sulphur and 0.15 part of additional crosslinker TAIC, in whipping process, with the average heating speed of 13 DEG C/min, temperature is risen to 94 DEG C, with the average heating speed of 2.7 DEG C/min, temperature is risen to 127 DEG C again, be cooled to room temperature after insulation 3.5h and obtain modification dicyclopentadiene phenol epoxy resin.
Embodiment 4
A kind of high adhesive force wear-resisting modification dicyclopentadiene phenol epoxy resin coating that the present invention proposes, its raw material comprises by weight: modification dicyclopentadiene phenol epoxy resin 68 parts, ABS resin 25 parts, aldehyde ketone resin KR-80F 8 parts, Graphene 24 parts, 0.35 part, paraffin, zirconium chloride 0.18 part, aluminium octoate 0.06 part, vinyl three oxygen methyl-monosilane 1.5 parts, defoamer 0.4 part, mould inhibitor 0.3 part, 2.3 parts, solidifying agent, dispersion agent 0.4 part, solvent 66 parts;
Wherein, the preparation method of modification dicyclopentadiene phenol epoxy resin is: 83 parts of dicyclopentadiene phenol epoxy resin and 12 parts of cis-1,4-polybutadiene rubbers are mixed by weight, add 57 parts of mixed solvents again to mix, mixed solvent is made up of than 2.2:1.6 with amount of substance 1-Methoxy-2-propyl acetate and propandiol butyl ether, continue to add 1.4 parts of peroxidation acetic acid tert-pentyl esters, stir with the stirring velocity of 360rpm after 0.6 part of sulphur and 0.2 part of additional crosslinker TAIC, in whipping process, with the average heating speed of 14 DEG C/min, temperature is risen to 93 DEG C, with the average heating speed of 2.8 DEG C/min, temperature is risen to 126 DEG C again, be cooled to room temperature after insulation 4h and obtain modification dicyclopentadiene phenol epoxy resin.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (5)
1. a high adhesive force wear-resisting modification dicyclopentadiene phenol epoxy resin coating, it is characterized in that, its raw material comprises by weight: modification dicyclopentadiene phenol epoxy resin 67-70 part, ABS resin 23-26 part, aldehyde ketone resin KR-80F 7-10 part, Graphene 22-26 part, paraffin 0.3-0.5 part, zirconium chloride 0.1-0.3 part, aluminium octoate 0.05-0.08 part, vinyl three oxygen methyl-monosilane 1.3-1.6 part, defoamer 0.3-0.8 part, mould inhibitor 0.1-0.4 part, solidifying agent 2.2-2.5 part, dispersion agent 0.1-0.5 part, solvent 65-70 part;
Wherein, the preparation method of modification dicyclopentadiene phenol epoxy resin is: 80-85 part dicyclopentadiene phenol epoxy resin and 10-15 part cis-1,4-polybutadiene rubber are mixed by weight, add 55-58 part mixed solvent again to mix, mixed solvent is made up of than 2-3:1-2 with amount of substance 1-Methoxy-2-propyl acetate and propandiol butyl ether, continue to add 1.2-1.5 part peroxidation acetic acid tert-pentyl ester, stir with the stirring velocity of 350-370rpm after 0.5-0.8 part sulphur and 0.1-0.3 part additional crosslinker TAIC, in whipping process, with the average heating speed of 12-15 DEG C/min, temperature is risen to 92-95 DEG C, with the average heating speed of 2.6-2.9 DEG C/min, temperature is risen to 125-128 DEG C again, be cooled to room temperature after insulation 3-5h and obtain modification dicyclopentadiene phenol epoxy resin.
2. high adhesive force according to claim 1 wear-resisting modification dicyclopentadiene phenol epoxy resin coating, is characterized in that, the weight ratio of modification dicyclopentadiene phenol epoxy resin, ABS resin, aldehyde ketone resin KR-80F is 68-69:24-25:8-9.
3. high adhesive force according to claim 1 and 2 wear-resisting modification dicyclopentadiene phenol epoxy resin coating, is characterized in that, the weight ratio of Graphene, paraffin, zirconium chloride, aluminium octoate is 23-24:0.35-0.4:0.16-0.18:0.06-0.07.
4. the wear-resisting modification dicyclopentadiene phenol epoxy resin of the high adhesive force according to any one of claim 1-3 coating, it is characterized in that, its raw material comprises by weight: modification dicyclopentadiene phenol epoxy resin 68-69 part, ABS resin 24-25 part, aldehyde ketone resin KR-80F 8-9 part, Graphene 23-24 part, paraffin 0.35-0.4 part, zirconium chloride 0.16-0.18 part, aluminium octoate 0.06-0.07 part, vinyl three oxygen methyl-monosilane 1.4-1.5 part, defoamer 0.4-0.6 part, mould inhibitor 0.2-0.3 part, solidifying agent 2.3-2.4 part, dispersion agent 0.3-0.4 part, solvent 66-68 part.
5. the wear-resisting modification dicyclopentadiene phenol epoxy resin of the high adhesive force according to any one of claim 1-4 coating, it is characterized in that, the preparation method of modification dicyclopentadiene phenol epoxy resin is: 82-83 part dicyclopentadiene phenol epoxy resin and 12-14 part cis-1,4-polybutadiene rubber are mixed by weight, add 56-57 part mixed solvent again to mix, mixed solvent is made up of than 2.2-2.5:1.1-1.6 with amount of substance 1-Methoxy-2-propyl acetate and propandiol butyl ether, continue to add 1.3-1.4 part peroxidation acetic acid tert-pentyl ester, stir with the stirring velocity of 360-365rpm after 0.6-0.7 part sulphur and 0.15-0.2 part additional crosslinker TAIC, in whipping process, with the average heating speed of 13-14 DEG C/min, temperature is risen to 93-94 DEG C, with the average heating speed of 2.7-2.8 DEG C/min, temperature is risen to 126-127 DEG C again, be cooled to room temperature after insulation 3.5-4h and obtain modification dicyclopentadiene phenol epoxy resin.
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| CN201410588271.3A CN104293108A (en) | 2014-10-28 | 2014-10-28 | High-adhesive-force wear-resistant modified dicyclopentadiene phenol epoxy resin coating |
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| CN201410588271.3A CN104293108A (en) | 2014-10-28 | 2014-10-28 | High-adhesive-force wear-resistant modified dicyclopentadiene phenol epoxy resin coating |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104861818A (en) * | 2015-04-28 | 2015-08-26 | 桐城市新丰彩印包装有限公司 | High tenacity dicyclopentadiene phenol type epoxy resin decontaminating coating |
| CN104895297A (en) * | 2015-05-29 | 2015-09-09 | 安徽同丰橡塑工业有限公司 | Anti-bacterial, anti-static and anti-corrosive rubber floor |
| CN106589830A (en) * | 2016-12-28 | 2017-04-26 | 滁州品之达电器科技有限公司 | Special plastic for refrigerator shell |
| CN110423536A (en) * | 2019-08-06 | 2019-11-08 | 甘肃泰升化工科技有限公司 | A kind of modified dicyclopentadiene phenol epoxy resin and preparation method thereof |
| CN113441076A (en) * | 2021-06-18 | 2021-09-28 | 上海正宏农牧机械设备有限公司 | TMR mixer material contact surface treatment process |
-
2014
- 2014-10-28 CN CN201410588271.3A patent/CN104293108A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104861818A (en) * | 2015-04-28 | 2015-08-26 | 桐城市新丰彩印包装有限公司 | High tenacity dicyclopentadiene phenol type epoxy resin decontaminating coating |
| CN104895297A (en) * | 2015-05-29 | 2015-09-09 | 安徽同丰橡塑工业有限公司 | Anti-bacterial, anti-static and anti-corrosive rubber floor |
| CN106589830A (en) * | 2016-12-28 | 2017-04-26 | 滁州品之达电器科技有限公司 | Special plastic for refrigerator shell |
| CN110423536A (en) * | 2019-08-06 | 2019-11-08 | 甘肃泰升化工科技有限公司 | A kind of modified dicyclopentadiene phenol epoxy resin and preparation method thereof |
| CN113441076A (en) * | 2021-06-18 | 2021-09-28 | 上海正宏农牧机械设备有限公司 | TMR mixer material contact surface treatment process |
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Application publication date: 20150121 |