CN105133813B - Environmental friendly, wear resistant and sound-absorbing double-layer-structure waterproof wood-plastic floor - Google Patents
Environmental friendly, wear resistant and sound-absorbing double-layer-structure waterproof wood-plastic floor Download PDFInfo
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- CN105133813B CN105133813B CN201510395003.4A CN201510395003A CN105133813B CN 105133813 B CN105133813 B CN 105133813B CN 201510395003 A CN201510395003 A CN 201510395003A CN 105133813 B CN105133813 B CN 105133813B
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Abstract
The invention discloses an environmental friendly, wear resistant and sound-absorbing double-layer-structure waterproof wood-plastic floor, and relates to the technical field of wood-plastic floor production. The environmental friendly, wear resistant and sound-absorbing double-layer-structure waterproof wood-plastic floor comprises a base material layer and a decorative layer. The base material layer is made from the following raw materials, by mass, 50 to 55 parts of straw powder, 35 to 40 parts of hard resin, 12 to 15 parts of amino resin, 10 to 13 parts of modified bamboo powder, 5 to 8 parts of calcium carbonate, 4 to 6 parts of chlorinated paraffin, 3 to 5 parts of polyvinyl alcohol, 3 to 4 parts of polyester fiber, 2 to 4 parts of magnesium hydroxide, 2 to 3 parts of nanometer sponge, 1 to 2 parts of triethanolamine, 8 to 11 parts of glycerol and 10 to 13 parts of ethanol. The decorative layer is made through steps of immersing color or texture decorative paper in an adhesive, and paving the dried and solidified decorative paper on the base material layer, wherein the adhesive is made from the following raw material by mass. The environmental friendly, wear resistant and sound-absorbing double-layer-structure waterproof wood-plastic floor has a double-layer structure which is a structure of a wood-plastic floor, the surface of the decorative layer is flat and smooth, so the wood-plastic floor is easy to maintain and clean, good in wear resistance and corrosion resistance. The base material layer can stop moisture, so defects that a present floor easily bents, deforms, shrinks in dry conditions and expands in wet conditions.
Description
Technical field:
The present invention relates to Wood-plastic floor production technical field, and in particular to a kind of environmentally friendly, wear-resisting and sound-absorbing double-decker
Formula waterproof Wood-plastic floor.
Background technology:
At present, family is used on market, the floor that office occupancy is decorated generally to adopt wood floors or compoiste wood floor.Wood
The feel of quality plate is pleasant, but easily imbibition or drying distortions, often occurs contraction, expansion in use and becomes
Shape, warp, problems of crack, and need to expend a large amount of timber, the production cycle is longer, relatively costly.And compoiste wood floor master
If a kind of floor formed using the blended extruding of wood flour and binding agent and other additives, its surface color and polish is abundant, into
This is low, but there are problems that hygroscopic, and the subject matter on this floor is release formaldehyde, and serious harm human body is good for
Health, the feature of environmental protection are poor.
A kind of a kind of floor of the Wood-plastic floor technique productions such as to be utilization plastics extruded with sponge, has wood concurrently
The performance and feature of material and plastics, can replace the environmentally friendly hitech materials of timber and plastics.With excellent physical property, environmental protection
Property, appearance tactile impression is good, and the secondary workability with timber, by routine work mode, can be processed into various facilities and system
Product.General Wood-plastic floor includes four-layer structure, is from top to bottom followed successively by wearing layer, decorative layer, substrate layer and balance layer, needs
This four-layer structure is processed respectively, then is combined together by adhesive or pressing process.There is life in this production technology
The characteristics of producing complicated link, more control technology point and larger Productive statistics cost, and it is chemical substance that adhesive is most, it is long
The phenomenon that chemical reaction occurs with other materials in use environment occurs when phase uses, generates volatility and human body is had
Harmful material, so as to threaten health.
The content of the invention:
The technical problem to be solved be provide that a kind of production process is simple, that input cost is low is environmentally friendly, resistance to
The double-layer structural waterproof Wood-plastic floor of mill and sound-absorbing.
The technical problem to be solved is realized using following technical scheme:
A kind of environmentally friendly, wear-resisting and sound-absorbing double-layer structural waterproof Wood-plastic floor, including substrate layer and decorative layer, the base
Material layer is made up of the raw material of following mass fraction:
Powder of straw 50-55 part, animi resin 35-40 parts, amino resins 12-15 parts, modified bamboo powder 10-13 parts, Calcium Carbonate 5-8
Part, chlorinated paraffin 4-6 parts, polyvinyl alcohol 3-5 parts, polyester fiber 3-4 parts, magnesium hydroxide 2-4 parts, nanosponges 2-3 parts, three second
Hydramine 1-2 parts, glycerol 8-11 parts, ethanol 10-13 parts;
The decorative layer is that the facing paper with color or texture is put in adhesive to soak, and is spread after its dry solidification
It is attached on substrate layer, the adhesive is made up of the raw material of following mass fraction:
Tripolycyanamide 20-25 parts, nano aluminium oxide 8-10 parts, nano tin dioxide 5-8 parts, carboxymethyl cellulose 2-3 parts, water
12-15 parts, glycerol 18-20 parts.
The production method of the powder of straw is first to wash harvested straw three times, and then dry in the sun is less than to moisture
10%, Jing pulverizers are crushed, are sieved after roguing, and the powder for taking 40 mesh soaks 5-8h in 5% dilute hydrochloric acid solution, filter, finally
Jing oven dryings to moisture can be used less than 5%.
The straw is in rice straw, wheat stalk, corn straw, soybean stalk, broomcorn straw, Caulis Sacchari sinensis straw
One or more.
The preparation method of the modified bamboo powder is first bamboo powder to be soaked into 3-5h in 3-5% dilute nitric acid solutions, then at ultrasound
Supersound process 15-20min under frequency 22kHz, power 50-100W, then stirs lower addition equivalent sodium polyacrylate, is warming up to
75-80 DEG C reaction 30-60min, reaction terminate after filter, filter cake wash three times, most after Jing oven dryings be less than to moisture
5% can use.
The production method of environmentally friendly, wear-resisting and sound-absorbing the double-layer structural waterproof Wood-plastic floor comprises the following steps:
(1) amino resins, polyvinyl alcohol and ethanol are added in high-speed mixer, is warming up to 110-120 DEG C of insulation mixing
15-20min, adds chlorinated paraffin and triethanolamine after then natural cooling is cooled to 30-40 DEG C, continue to mix 5-10min, then
Material is added in ball mill, granularity is milled to less than 50 μm, coating liquid is obtained final product;
(2) first powder of straw is scattered in glycerol, adds animi resin, be warming up to 120-125 DEG C of insulation reaction 1-2h,
Reaction stands cooling after terminating, and obtains final product material I;
(3) material I is added in high-speed mixer, and adds modified bamboo powder, Calcium Carbonate and magnesium hydroxide, mix 15-
Polyester fiber and nanosponges, material are added to be warming up to 80-90 DEG C of mixing 10-15min, be finally cooled to 30-40 DEG C after 20min
After add pigment, after 5-10min stop mixing, obtain final product material II;
(4) material II is added in ball mill, extrusion molding in extruder is added to after ball milling 2-3h, extrusion temperature is
160-180 DEG C, the thick coating liquids of one layer of 2-3mm are then coated on sheet material after the cooling period, substrate layer is obtained final product after spontaneous curing;
(5) facing paper with color or texture is put in adhesive and soaks 20-30min, then taken out, treat its drying
Mat formation after solidification on substrate layer, finally carry out hot pressing under temperature 140-180 DEG C, pressure 50-115MPa, obtain final product wood moulding ground
Plate.
The invention has the beneficial effects as follows:
(1) designed using double-layer structural;
(2) immersion of facing paper is carried out using the adhesive without formaldehyde, the feature of environmental protection is strong, does not result in secondary pollution;And
And add transparent wear-resistant component in adhesive, make decorative layer that there is stronger wearability;
(3) decor surface is smooth bright and clean, easy maintenance clean, and with very strong wear-resisting and corrosion resistance;
(4) in substrate layer polyester fiber and nanosponges addition, have can Wood-plastic floor that produce stronger
Sound absorption properties;
(5) substrate layer adopts extrusion technology, makes the internal stress on floor more balanced, eliminates the anisotropy on floor, gram
The easy warping deformation in floor, the shortcoming of drying shrinkage bulking are taken, and there is substrate layer and intercepted through coating operation after extrusion molding
The ability of moisture and moisture, remains intact straight state;
(6) decorative layer is mated formation on substrate layer by heat pressing process, it is to avoid because the safety that existed using adhesive it is hidden
Suffer from problem;
(7) recycling of agricultural crop straw, is conducive to environmental protection and reduces production cost.
Specific embodiment:
In order that technological means, creation characteristic, reached purpose and effect that the present invention is realized are easy to understand, tie below
Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
A kind of environmentally friendly, wear-resisting and sound-absorbing double-layer structural waterproof Wood-plastic floor, including substrate layer and decorative layer, the base
Material layer is made up of the raw material of following quality:
Wheat stalk powder 50kg, animi resin 35kg, amino resins 13kg, modified bamboo powder 11kg, Calcium Carbonate 6kg, chlorination stone
Wax 4kg, polyvinyl alcohol 3kg, polyester fiber 3kg, magnesium hydroxide 2kg, nanosponges 2kg, triethanolamine 1kg, glycerol 10kg,
Ethanol 12kg;
The decorative layer is that the facing paper with color or texture is put in adhesive to soak, and is spread after its dry solidification
It is attached on substrate layer, the adhesive is made up of the raw material of following quality:
Tripolycyanamide 20kg, nano aluminium oxide 8kg, nano tin dioxide 6kg, carboxymethyl cellulose 2kg, water 12kg, the third three
Alcohol 18kg.
Wherein, the production method of powder of straw is first to wash harvested straw three times, and then dry in the sun is low to moisture
In 10%, Jing pulverizers are crushed, are sieved after roguing, and the powder for taking 40 mesh soaks 5h in 5% dilute hydrochloric acid solution, filter, finally
Jing oven dryings to moisture can be used less than 5%.
The preparation method of modified bamboo powder is first bamboo powder to be soaked into 3h in 3-5% dilute nitric acid solutions, then at supersonic frequency
Supersound process 20min under 22kHz, power 100W, then stirs lower addition equivalent sodium polyacrylate, is warming up to 75-80 DEG C of reaction
45min, reaction is filtered after terminating, and filter cake washes three times, most after Jing oven dryings can use less than 5% to moisture.
The production of Wood-plastic floor is carried out according to above-mentioned raw materials formula, is comprised the following steps:
(1) amino resins, polyvinyl alcohol and ethanol are added in high-speed mixer, is warming up to 110-120 DEG C of insulation mixing
20min, adds chlorinated paraffin and triethanolamine after then natural cooling is cooled to 30-40 DEG C, continue to mix 10min, then by thing
Material is added in ball mill, is milled to granularity less than 50 μm, obtains final product coating liquid;
(2) first powder of straw is scattered in glycerol, adds animi resin, be warming up to 120-125 DEG C of insulation reaction 1h, instead
Cooling is stood after should terminating, material I is obtained final product;
(3) material I is added in high-speed mixer, and adds modified bamboo powder, Calcium Carbonate and magnesium hydroxide, mixing
Polyester fiber and nanosponges are added after 15min, material is warming up to 80-90 DEG C of mixing 10min, after being finally cooled to 30-40 DEG C
Pigment is added, mixing is stopped after 5min, obtain final product material II;
(4) material II is added in ball mill, extrusion molding in extruder is added to after ball milling 3h, extrusion temperature is 160-
180 DEG C, the thick coating liquids of one layer of 2-3mm are then coated on sheet material after the cooling period, substrate layer is obtained final product after spontaneous curing;
(5) facing paper with color or texture is put in adhesive and soaks 30min, then taken out, treat that it is dried solid
Mat formation after change on substrate layer, finally carry out hot pressing under temperature 140-180 DEG C, pressure 50-115MPa, obtain final product Wood-plastic floor.
Embodiment 2
A kind of environmentally friendly, wear-resisting and sound-absorbing double-layer structural waterproof Wood-plastic floor, including substrate layer and decorative layer, the base
Material layer is made up of the raw material of following quality:
Corn stalk powder 50kg, animi resin 40kg, amino resins 12kg, modified bamboo powder 11kg, Calcium Carbonate 6kg, chlorination stone
Wax 5kg, polyvinyl alcohol 3kg, polyester fiber 3kg, magnesium hydroxide 2kg, nanosponges 3kg, triethanolamine 1kg, glycerol 10kg,
Ethanol 12kg;
The decorative layer is that the facing paper with color or texture is put in adhesive to soak, and is spread after its dry solidification
It is attached on substrate layer, the adhesive is made up of the raw material of following quality:
Tripolycyanamide 22kg, nano aluminium oxide 9kg, nano tin dioxide 6kg, carboxymethyl cellulose 2kg, water 15kg, the third three
Alcohol 18kg.
The production method of the present embodiment Wood-plastic floor is with embodiment 1.
Embodiment 3
A kind of environmentally friendly, wear-resisting and sound-absorbing double-layer structural waterproof Wood-plastic floor, including substrate layer and decorative layer, the base
Material layer is made up of the raw material of following quality:
Rice straw powder 50kg, animi resin 40kg, amino resins 15kg, modified bamboo powder 10kg, Calcium Carbonate 7kg, chlorination stone
Wax 5kg, polyvinyl alcohol 4kg, polyester fiber 3kg, magnesium hydroxide 3kg, nanosponges 2kg, triethanolamine 1kg, glycerol 10kg,
Ethanol 12kg;
The decorative layer is that the facing paper with color or texture is put in adhesive to soak, and is spread after its dry solidification
It is attached on substrate layer, the adhesive is made up of the raw material of following quality:
Tripolycyanamide 25kg, nano aluminium oxide 10kg, nano tin dioxide 8kg, carboxymethyl cellulose 2kg, water 15kg, the third three
Alcohol 18kg.
The production method of the present embodiment Wood-plastic floor is with embodiment 1.
The ultimate principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel it should be appreciated that the present invention is not restricted to the described embodiments, the simply explanation described in above-described embodiment and description this
The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, these changes
Change and improvement is both fallen within scope of the claimed invention.The claimed scope of the invention by appending claims and its
Equivalent thereof.
Claims (4)
1. a kind of environmentally friendly, wear-resisting and sound-absorbing double-layer structural waterproof Wood-plastic floor, it is characterised in that:Including substrate layer and decoration
Layer, the substrate layer is made up of the raw material of following mass fraction:
Powder of straw 50-55 part, animi resin 35-40 parts, amino resins 12-15 parts, modified bamboo powder 10-13 parts, Calcium Carbonate 5-8 part,
Chlorinated paraffin 4-6 parts, polyvinyl alcohol 3-5 parts, polyester fiber 3-4 parts, magnesium hydroxide 2-4 parts, nanosponges 2-3 parts, three ethanol
Amine 1-2 parts, glycerol 8-11 parts, ethanol 10-13 parts;
The decorative layer is that the facing paper with color or texture is put in adhesive to soak, mat formation after its dry solidification to
On substrate layer, the adhesive is made up of the raw material of following mass fraction:
Tripolycyanamide 20-25 parts, nano aluminium oxide 8-10 parts, nano tin dioxide 5-8 parts, carboxymethyl cellulose 2-3 parts, water 12-
15 parts, glycerol 18-20 parts.
2. environmentally friendly, wear-resisting and sound-absorbing double-layer structural waterproof Wood-plastic floor according to claim 1, it is characterised in that:
The production method of the powder of straw is first to wash harvested straw three times, and then dry in the sun is less than 10% to moisture, goes
After miscellaneous Jing pulverizers crush, sieve, the powder for taking 40 mesh soaks 5-8h in 5% dilute hydrochloric acid solution, filter, most after Jing baking ovens do
It is dry to moisture can use less than 5%.
3. environmentally friendly, wear-resisting and sound-absorbing double-layer structural waterproof Wood-plastic floor according to claim 1, it is characterised in that:
The preparation method of the modified bamboo powder is first bamboo powder to be soaked into 3-5h in 3-5% dilute nitric acid solutions, then at supersonic frequency
Supersound process 15-20min under 22kHz, power 50-100W, then stirs lower addition equivalent sodium polyacrylate, is warming up to 75-80
DEG C reaction 30-60min, reaction terminate after filter, filter cake wash three times, most after Jing oven dryings be less than 5% to moisture
Can use.
4. environmentally friendly, wear-resisting and sound-absorbing double-layer structural waterproof Wood-plastic floor according to claim 1, it is characterised in that
Its production method comprises the following steps:
(1) amino resins, polyvinyl alcohol and ethanol are added in high-speed mixer, is warming up to 110-120 DEG C of insulation mixing 15-
20min, adds chlorinated paraffin and triethanolamine after then natural cooling is cooled to 30-40 DEG C, continue to mix 5-10min, then will
Material is added in ball mill, is milled to granularity less than 50 μm, obtains final product coating liquid;
(2) first powder of straw is scattered in glycerol, adds animi resin, be warming up to 120-125 DEG C of insulation reaction 1-2h, reacted
Cooling is stood after end, material I is obtained final product;
(3) material I is added in high-speed mixer, and adds modified bamboo powder, Calcium Carbonate and magnesium hydroxide, mix 15-20min
Polyester fiber and nanosponges, material are added to be warming up to 80-90 DEG C of mixing 10-15min, add after being finally cooled to 30-40 DEG C afterwards
Enter pigment, mixing is stopped after 5-10min, obtain final product material II;
(4) material II is added in ball mill, extrusion molding in extruder is added to after ball milling 2-3h, extrusion temperature is 160-
180 DEG C, the thick coating liquids of one layer of 2-3mm are then coated on sheet material after the cooling period, substrate layer is obtained final product after spontaneous curing;
(5) facing paper with color or texture is put in adhesive and soaks 20-30min, then taken out, treat its dry solidification
After mat formation on substrate layer, finally carry out hot pressing under temperature 140-180 DEG C, pressure 50-115MPa, obtain final product Wood-plastic floor.
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