CN106752005A - A kind of waterproof flame-retardant type biomass board of composite type high temperature resistant and preparation method thereof - Google Patents
A kind of waterproof flame-retardant type biomass board of composite type high temperature resistant and preparation method thereof Download PDFInfo
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- CN106752005A CN106752005A CN201611190329.4A CN201611190329A CN106752005A CN 106752005 A CN106752005 A CN 106752005A CN 201611190329 A CN201611190329 A CN 201611190329A CN 106752005 A CN106752005 A CN 106752005A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
Waterproof flame-retardant type biomass board the invention discloses a kind of composite type high temperature resistant and preparation method thereof, characterized in that, with rice straw, sulfate wood pulp, Carboxyl Modified Polydimethylsiloxane, gelatin, nano imvite, polyoxyethylene nonylphenol ether 10, atoleine, rosin, polyacrylic acid, melamine phosphate, boric acid, hydrotalcite, pine tar, alumina silicate fibre, quartz fibre, high silica fiber etc. as raw material.The present invention adds Carboxyl Modified Polydimethylsiloxane to carry out enhancing modification to sulfate wood pulp wire-dividing broom purification is added in rice straw；, used as filler, high temperature melting can be used as adhesive for rosin powder；It is nano montmorillonite modified to process the mechanical property and dimensional stability for significantly improving sheet material；Microcapsules waterproofing agent is prepared using Simple coacervation；Melamine phosphate polypropylene salt borate fire retardant is prepared for, with hydrotalcite synergy, flame retardant effect is more preferably；Obtain a kind of waterproof flame-retardant type biomass board of composite type high temperature resistant.
Description
Technical field
The present invention relates to a kind of preparation method of biomass board, and in particular to a kind of water proof fire retardant of composite type high temperature resistant
Type biomass board and preparation method thereof.
Background technology
China is Rice Production big country, and rice straw aboundresources can make biomass board, alleviate timber and supply with it
The pressure answered, instead of part woodwork and plastic products, while reducing pollution of the plastics to environment, also makes rice straw resource
More effective utilization is obtained.
Zhang Jin is in its Master dissertation《Using rice straw make can be degradable biomass board》In, with water
Rice straw is raw material, a kind of preparation method of environmentally friendly material-biomass board that can be degradable is elaborated, using pure
Physical method, by the technique such as chopping, immersion, grinding, hot-forming after, be made the biological scutum with some strength
Material.Without the addition of any chemical reagent during panel, saved cost, and it is discarded after degradable can be inhaled by soil
Receive, reused as fertilizer, do not result in any environmental pollution.But it is not enough to there is performance in sheet material.
The present invention adds reinforcing agent Carboxyl Modified Polydimethylsiloxane to be increased to sulfate wood pulp wire-dividing broom purification is added in rice straw
Strong modification, adds foaming agent pine tar；Rosin powder contributes to the compacting of sheet material as filler, it is ensured that the densification of sheet material
Degree, high temperature melting can be water insoluble as adhesive, and addition can improve the water resistance of sheet material；Nano montmorillonite modified treatment can
The mechanical property and dimensional stability of sheet material are significantly improved, in montmorillonite and biomass mixed process, reaction is crosslinked, increased
Interact；It is core with the atoleine for emulsifying, the gelatin with abundant dissolving is wall material, adds coagulant ethanol, is used
Simple coacervation prepares microcapsules waterproofing agent；Melamine phosphate-polypropylene salt-borate fire retardant is prepared for, is assisted with hydrotalcite
Same-action, flame retardant effect is more preferably；Obtain a kind of waterproof flame-retardant type biomass board of composite type high temperature resistant.
The content of the invention
The present invention solves the technical problem of a kind of modified waterproof flame-retardant type biomass of composite type high temperature resistant of offer
Sheet material and preparation method thereof, according to the technique prepare biomass board mechanical property is good, high temperature resistant, good waterproof performance, anti-flammability
By force.
The technical problems to be solved by the invention are realized using following technical scheme：
Rice straw 40-47, sulfate wood pulp 3-5, Carboxyl Modified Polydimethylsiloxane 2-4, gelatin 4-8, nano imvite 5-9, emulsifying agent
OP-10 1-3, atoleine 2-4, rosin 2-4, polyacrylic acid 3-5, melamine phosphate 2-4, boric acid 3-5, hydrotalcite 4-6,
Pine tar 1-2, tetraethyl orthosilicate 2-4, alumina silicate fibre 3-5, quartz fibre 3-6, high silica fiber 2-5, DBSA
Sodium 0.3-0.6, ethanol, distillation appropriate amount of water.
Waterproof flame-retardant type biomass board of a kind of composite type high temperature resistant and preparation method thereof, it is characterised in that by following
Step is carried out：
A. the fragment of 10-20mm is cut to after rice straw is dried with pulverizer, be soaked in water 2-4d at room temperature,
Mechanical grinding adds sulfate wood pulp into fibre length 1-5mm, is well mixed, and injects beater, and wire-dividing broom purification makes beating
Degree is in 25-350SR, is slowly stirred addition Carboxyl Modified Polydimethylsiloxane, and tune pH is 4-5；
B. gelatin, nano imvite are mixed with distilled water, 40-50 DEG C of water-bath, stirring and dissolving obtains A liquid；Will
Emulsifier op-10, atoleine mix with rosin, and stirring and emulsifying 1-2h obtains B liquid；A, B liquid are mixed, is stirred, plus
Enter ethanol, continue to stir 1-2h, tune pH value of solution is 8-9, and 1-2h is solidified in ice-water bath, through vacuum drying, crushes to obtain microcapsule powder
End；
C. in polyacrylic acid 1:3-5 adds distilled water, is heated to 70-90 DEG C, and stirring is lower to add melamine phosphate, boric acid,
Ultrasonic disperse, reacts 3-4h, and cooling, suction filtration are washed 3-5 times, dried to constant weight in 80-90 DEG C of baking oven, then mixed with hydrotalcite
Grinding is closed, composite flame-retardant agent is obtained；
D. by tetraethyl orthosilicate, second alcohol and water according to 3:5-8:The mass ratio mixing of 7-10, tune pH is 1-3, magnetic agitation 1-
2h, obtains concentration for the Ludox of 10wt%-20wt% is high-temperature agglomerant；
E. alumina silicate fibre, quartz fibre, high silica fiber are mixed, is smashed with beater, it is 100-300's to obtain draw ratio
Chopped strand, itself and neopelex are added in d in gained Ludox, then are mixed with resulting material in a, b, c,
Pine tar is added, 1-2h is stirred, mould is injected, compressing 2-4h at 2-8MPa, 110-160 DEG C with hot press is molded, obtain a kind of multiple
The resistant to elevated temperatures waterproof flame-retardant type biomass board of mould assembly.
Reaction mechanism of the invention is as follows：
（1）Strengthened by adding sulfate wood pulp wire-dividing broom purification, addition reinforcing agent Carboxyl Modified Polydimethylsiloxane in rice straw
Modification, adds foaming agent pine tar, and a kind of imvite modified waterproof flame-retardant type biomass board is obtained.
（2）Rosin powder contributes to the compacting of sheet material as filler, it is ensured that the consistency of sheet material；Rosin high temperature melting
Can be used as adhesive；Rosin has water insoluble characteristic, and addition can improve the water resistance of sheet material；Rosin molecule have double bond and
Carboxyl-reactive group, can participate in high temperature polymerization as monomer, form firm chemical bond, whole process environmental protection, low energy consumption, and system
Sheet material good mechanical properties, water-resistant type it is excellent.
It is nano montmorillonite modified to process the mechanical property and dimensional stability for being remarkably improved sheet material, montmorillonite and biomass
In mixed process, reaction is crosslinked, increased interaction, the water imbibition of the montmorillonite-composite biomass board after treatment
Can reduce, its dimensional stability is improved.
It is core with the atoleine for emulsifying, the gelatin with abundant dissolving is wall material, coagulant ethanol is added, using Dan Ning
Poly- method prepares microcapsules waterproofing agent；
（3）Melamine phosphate-polypropylene salt-borate fire retardant is prepared for, with hydrotalcite synergy, flame retardant effect is more
It is good；Phosphorous, nitrogen, not halogen in melamine phosphate molecule, and P- N cooperative effects can occur, and flame retarding efficiency is high, and heat endurance is good；
Boron is a kind of environment-friendly type raw material, there is flame retardant synergistic effect between boron-phosphorus-nitrogen；Intermediary water, carbonate are lost when hydrotalcite is heated
And hydroxyl, a large amount of heat absorptions, fire retardation is played, sour gas and smog can be absorbed, play a part of suppression cigarette, eliminate smoke.
（4）High-temperature agglomerant-Ludox is prepared for tetraethyl orthosilicate, with polymolecularity, preferable wearability, good
Translucency etc., the present invention, as high-temperature agglomerant, improves the temperature in use of sheet material using acidic silicasol；Add resistant to elevated temperatures
Alumina silicate fibre, quartz fibre, high silica fiber.
Specific embodiment
In order that technological means, creation characteristic, reached purpose and effect that the present invention is realized are easy to understand, tie below
Specific embodiment is closed, the present invention is expanded on further.
Embodiment
Waterproof flame-retardant type biomass board of a kind of composite type high temperature resistant and preparation method thereof, by following weight parts (g)
Raw material is obtained：
Rice straw 47, sulfate wood pulp 5, Carboxyl Modified Polydimethylsiloxane 4, gelatin 8, nano imvite 9, emulsifier op-10 3, liquid
Paraffin 4, rosin 4, polyacrylic acid 5, melamine phosphate 4, boric acid 3, hydrotalcite 6, pine tar 1, tetraethyl orthosilicate 4, aluminium silicate fiber
Dimension 5, quartz fibre 6, high silica fiber 5, neopelex 0.3, ethanol, distillation appropriate amount of water.
Waterproof flame-retardant type biomass board of a kind of composite type high temperature resistant and preparation method thereof, it is characterised in that by following
Step is carried out：
A. the fragment of 10-20mm is cut to after rice straw is dried with pulverizer, be soaked in water 2d at room temperature,
Mechanical grinding adds sulfate wood pulp into fibre length 1-5mm, is well mixed, and injects beater, and wire-dividing broom purification makes beating
Degree is in 25-350SR, is slowly stirred addition Carboxyl Modified Polydimethylsiloxane, and tune pH is 4-5；
B. gelatin, nano imvite are mixed with distilled water, 40-50 DEG C of water-bath, stirring and dissolving obtains A liquid；Breast
Agent OP-10, atoleine mix with rosin, and stirring and emulsifying 1h obtains B liquid；A, B liquid are mixed, is stirred, add second
Alcohol, continues to stir 1h, and tune pH value of solution is 8-9, and 1h is solidified in ice-water bath, through vacuum drying, crushes to obtain microscapsule powder；
C. in polyacrylic acid 1:3 add distilled water, are heated to 70-80 DEG C, and stirring is lower to add melamine phosphate, boric acid, surpasses
Sound disperse, react 3h, cooling, suction filtration, wash 3 times, in 80-90 DEG C of baking oven dry to constant weight, then with hydrotalcite mixed grinding,
Obtain composite flame-retardant agent；
D. by tetraethyl orthosilicate, second alcohol and water according to 3:8:10 mass ratio mixing, tune pH is 2-3, magnetic agitation 1h, is obtained
Concentration is high-temperature agglomerant for the Ludox of 10wt%-20wt%；
E. alumina silicate fibre, quartz fibre, high silica fiber are mixed, is smashed with beater, it is 100-200's to obtain draw ratio
Chopped strand, itself and neopelex are added in d in gained Ludox, then are mixed with resulting material in a, b, c,
Pine tar is added, 1h is stirred, mould is injected, compressing 2h at 6-8MPa, 140-160 DEG C with hot press is molded, obtain a kind of compound
Resistant to elevated temperatures waterproof flame-retardant type biomass board.
A kind of following institute of waterproof flame-retardant type biomass board performance test results of composite type high temperature resistant prepared by above-described embodiment
Show：
MOR >=21.8MPa, elastic modelling quantity >=2015MPa, internal bond strength >=0.54 MPa, water sucting thickness expansion
Rate≤7.2%, moisture content 4.3-8.3%, limited oxygen index is 34%, and up to UL 94V-0 grades, environmental protection grade reaches flame retardant rating
E1 grades.
Claims (2)
1. waterproof flame-retardant type biomass board of a kind of composite type high temperature resistant and preparation method thereof, it is characterised in that by following heavy
The raw material for measuring part is obtained：
Rice straw 40-47, sulfate wood pulp 3-5, Carboxyl Modified Polydimethylsiloxane 2-4, gelatin 4-8, nano imvite 5-9, emulsifying agent
OP-10 1-3, atoleine 2-4, rosin 2-4, polyacrylic acid 3-5, melamine phosphate 2-4, boric acid 3-5, hydrotalcite 4-6,
Pine tar 1-2, tetraethyl orthosilicate 2-4, alumina silicate fibre 3-5, quartz fibre 3-6, high silica fiber 2-5, DBSA
Sodium 0.3-0.6, ethanol, distillation appropriate amount of water.
2. waterproof flame-retardant type biomass board of a kind of composite type high temperature resistant according to claim 1 and preparation method thereof,
Characterized in that, carrying out according to the following steps：
A. the fragment of 10-20mm is cut to after rice straw is dried with pulverizer, be soaked in water 2-4d at room temperature, mechanical grinding into
Fibre length 1-5mm, adds sulfate wood pulp, is well mixed, and injects beater, and wire-dividing broom purification makes beating degree in 25-350SR,
Addition Carboxyl Modified Polydimethylsiloxane is slowly stirred, tune pH is 4-5；
B. gelatin, nano imvite are mixed with distilled water, 40-50 DEG C of water-bath, stirring and dissolving obtains A liquid；By emulsifier op-10,
Atoleine mixes with rosin, and stirring and emulsifying 1-2h obtains B liquid；A, B liquid are mixed, is stirred, add ethanol, continue to stir 1-
2h, tune pH value of solution is 8-9, and 1-2h is solidified in ice-water bath, through vacuum drying, crushes to obtain microscapsule powder；
C. in polyacrylic acid 1:3-5 adds distilled water, is heated to 70-90 DEG C, and stirring is lower to add melamine phosphate, boric acid,
Ultrasonic disperse, reacts 3-4h, and cooling, suction filtration are washed 3-5 times, dried to constant weight in 80-90 DEG C of baking oven, then mixed with hydrotalcite
Grinding is closed, composite flame-retardant agent is obtained；
D. by tetraethyl orthosilicate, second alcohol and water according to 3:5-8:The mass ratio mixing of 7-10, tune pH is 1-3, magnetic agitation 1-
2h, obtains concentration for the Ludox of 10wt%-20wt% is high-temperature agglomerant；
E. alumina silicate fibre, quartz fibre, high silica fiber are mixed, is smashed with beater, obtain draw ratio for 100-300
Chopped strand, itself and neopelex are added in d in gained Ludox, then mixed with resulting material in a, b, c
Close, add pine tar, stir 1-2h, inject mould, compressing 2-4h at 2-8MPa, 110-160 DEG C with hot press is molded, and obtains one kind
The waterproof flame-retardant type biomass board of composite type high temperature resistant.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106752004A (en) * | 2016-12-21 | 2017-05-31 | 凤台县双利生物科技有限公司 | A kind of waterproof flame-retardant type biomass board of multi-walled carbon nano-tubes activeness and quietness and preparation method thereof |
| CN106752002A (en) * | 2016-12-21 | 2017-05-31 | 凤台县双利生物科技有限公司 | Enhanced waterproof flame-retardant type biomass board of a kind of composite antibacterial film and preparation method thereof |
| CN106752003A (en) * | 2016-12-21 | 2017-05-31 | 凤台县双利生物科技有限公司 | Modified waterproof flame-retardant type biomass board of the compound woodcare paint enhancing of a kind of nano silicon/polyurethane and preparation method thereof |
| CN107189473A (en) * | 2017-06-29 | 2017-09-22 | 合肥达户电线电缆科技有限公司 | A kind of environment-friendly materials water proof fire retardant sheet material and preparation method thereof |
Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101747550A (en) * | 2009-12-17 | 2010-06-23 | 谢德芳 | Compression molding fibre-reinforced straw plastic combined cabinet slab and preparation method thereof |
| CN101786852A (en) * | 2010-01-29 | 2010-07-28 | 王春莉 | Novel environment-friendly and fireproof composite biomass board |
| CN103351481A (en) * | 2013-06-28 | 2013-10-16 | 青岛共好检测技术有限公司 | Natural degradable packaging material |
| CN105058545A (en) * | 2015-07-29 | 2015-11-18 | 安徽鑫润新型材料有限公司 | Oil-proof antifouling health-care fiber composite board and manufacturing method thereof |
| CN105133813A (en) * | 2015-07-06 | 2015-12-09 | 安徽以诺木塑板材科技有限公司 | Environmental friendly, wear resistant and sound-absorbing double-layer-structure waterproof wood-plastic floor |
| CN105885296A (en) * | 2016-06-17 | 2016-08-24 | 叶伟然 | Novel high-strength flame-retardant polyvinyl chloride plastic-wood composite plate |
| CN105936699A (en) * | 2016-06-06 | 2016-09-14 | 浙江乔兴建设集团湖州智能科技有限公司 | Environment-friendly and antibacterial polypropylene plastic-wood composite board for buildings |
| CN106675063A (en) * | 2016-12-21 | 2017-05-17 | 凤台县双利生物科技有限公司 | Lignocellulose-acrylic acid reinforced waterproof flame-retardant biomass board and preparation method thereof |
| CN106675064A (en) * | 2016-12-21 | 2017-05-17 | 凤台县双利生物科技有限公司 | Carbon fiber reinforced and modified waterproof anti-flaming type biomass plate and preparation method thereof |
| CN106752001A (en) * | 2016-12-21 | 2017-05-31 | 凤台县双利生物科技有限公司 | A kind of imvite modified waterproof flame-retardant type biomass board and preparation method thereof |
| CN106752004A (en) * | 2016-12-21 | 2017-05-31 | 凤台县双利生物科技有限公司 | A kind of waterproof flame-retardant type biomass board of multi-walled carbon nano-tubes activeness and quietness and preparation method thereof |
| CN106752002A (en) * | 2016-12-21 | 2017-05-31 | 凤台县双利生物科技有限公司 | Enhanced waterproof flame-retardant type biomass board of a kind of composite antibacterial film and preparation method thereof |
| CN106752003A (en) * | 2016-12-21 | 2017-05-31 | 凤台县双利生物科技有限公司 | Modified waterproof flame-retardant type biomass board of the compound woodcare paint enhancing of a kind of nano silicon/polyurethane and preparation method thereof |
-
2016
- 2016-12-21 CN CN201611190329.4A patent/CN106752005A/en active Pending
Patent Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101747550A (en) * | 2009-12-17 | 2010-06-23 | 谢德芳 | Compression molding fibre-reinforced straw plastic combined cabinet slab and preparation method thereof |
| CN101786852A (en) * | 2010-01-29 | 2010-07-28 | 王春莉 | Novel environment-friendly and fireproof composite biomass board |
| CN103351481A (en) * | 2013-06-28 | 2013-10-16 | 青岛共好检测技术有限公司 | Natural degradable packaging material |
| CN105133813A (en) * | 2015-07-06 | 2015-12-09 | 安徽以诺木塑板材科技有限公司 | Environmental friendly, wear resistant and sound-absorbing double-layer-structure waterproof wood-plastic floor |
| CN105058545A (en) * | 2015-07-29 | 2015-11-18 | 安徽鑫润新型材料有限公司 | Oil-proof antifouling health-care fiber composite board and manufacturing method thereof |
| CN105936699A (en) * | 2016-06-06 | 2016-09-14 | 浙江乔兴建设集团湖州智能科技有限公司 | Environment-friendly and antibacterial polypropylene plastic-wood composite board for buildings |
| CN105885296A (en) * | 2016-06-17 | 2016-08-24 | 叶伟然 | Novel high-strength flame-retardant polyvinyl chloride plastic-wood composite plate |
| CN106675063A (en) * | 2016-12-21 | 2017-05-17 | 凤台县双利生物科技有限公司 | Lignocellulose-acrylic acid reinforced waterproof flame-retardant biomass board and preparation method thereof |
| CN106675064A (en) * | 2016-12-21 | 2017-05-17 | 凤台县双利生物科技有限公司 | Carbon fiber reinforced and modified waterproof anti-flaming type biomass plate and preparation method thereof |
| CN106752001A (en) * | 2016-12-21 | 2017-05-31 | 凤台县双利生物科技有限公司 | A kind of imvite modified waterproof flame-retardant type biomass board and preparation method thereof |
| CN106752004A (en) * | 2016-12-21 | 2017-05-31 | 凤台县双利生物科技有限公司 | A kind of waterproof flame-retardant type biomass board of multi-walled carbon nano-tubes activeness and quietness and preparation method thereof |
| CN106752002A (en) * | 2016-12-21 | 2017-05-31 | 凤台县双利生物科技有限公司 | Enhanced waterproof flame-retardant type biomass board of a kind of composite antibacterial film and preparation method thereof |
| CN106752003A (en) * | 2016-12-21 | 2017-05-31 | 凤台县双利生物科技有限公司 | Modified waterproof flame-retardant type biomass board of the compound woodcare paint enhancing of a kind of nano silicon/polyurethane and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106752004A (en) * | 2016-12-21 | 2017-05-31 | 凤台县双利生物科技有限公司 | A kind of waterproof flame-retardant type biomass board of multi-walled carbon nano-tubes activeness and quietness and preparation method thereof |
| CN106752002A (en) * | 2016-12-21 | 2017-05-31 | 凤台县双利生物科技有限公司 | Enhanced waterproof flame-retardant type biomass board of a kind of composite antibacterial film and preparation method thereof |
| CN106752003A (en) * | 2016-12-21 | 2017-05-31 | 凤台县双利生物科技有限公司 | Modified waterproof flame-retardant type biomass board of the compound woodcare paint enhancing of a kind of nano silicon/polyurethane and preparation method thereof |
| CN107189473A (en) * | 2017-06-29 | 2017-09-22 | 合肥达户电线电缆科技有限公司 | A kind of environment-friendly materials water proof fire retardant sheet material and preparation method thereof |
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Application publication date: 20170531 |