CN107311592A - A kind of toughening type fire-proof plate and preparation method thereof - Google Patents
A kind of toughening type fire-proof plate and preparation method thereof Download PDFInfo
- Publication number
- CN107311592A CN107311592A CN201710644696.5A CN201710644696A CN107311592A CN 107311592 A CN107311592 A CN 107311592A CN 201710644696 A CN201710644696 A CN 201710644696A CN 107311592 A CN107311592 A CN 107311592A
- Authority
- CN
- China
- Prior art keywords
- parts
- proof plate
- raw material
- counted
- type fire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 62
- 239000002994 raw material Substances 0.000 claims abstract description 45
- 239000000835 fiber Substances 0.000 claims abstract description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000002245 particle Substances 0.000 claims abstract description 33
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Inorganic materials [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims abstract description 17
- ZOMBKNNSYQHRCA-UHFFFAOYSA-J calcium sulfate hemihydrate Chemical compound O.[Ca+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZOMBKNNSYQHRCA-UHFFFAOYSA-J 0.000 claims abstract description 17
- 239000003063 flame retardant Substances 0.000 claims abstract description 17
- 239000011507 gypsum plaster Substances 0.000 claims abstract description 17
- 239000004568 cement Substances 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims description 30
- 239000003638 reducing agent Substances 0.000 claims description 21
- 239000000945 filler Substances 0.000 claims description 19
- 239000000779 smoke Substances 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 13
- 229910052799 carbon Inorganic materials 0.000 claims description 13
- 239000000839 emulsion Substances 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 13
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims description 13
- 239000004088 foaming agent Substances 0.000 claims description 12
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical group O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims description 12
- QUOZWMJFTQUXON-UXXRCYHCSA-N Androsin Natural products COC1=CC(C(C)=O)=CC=C1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 QUOZWMJFTQUXON-UXXRCYHCSA-N 0.000 claims description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 10
- HWKQNAWCHQMZHK-UHFFFAOYSA-N Trolnitrate Chemical class [O-][N+](=O)OCCN(CCO[N+]([O-])=O)CCO[N+]([O-])=O HWKQNAWCHQMZHK-UHFFFAOYSA-N 0.000 claims description 10
- 239000000243 solution Substances 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 8
- 239000010440 gypsum Substances 0.000 claims description 7
- 229910052602 gypsum Inorganic materials 0.000 claims description 7
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- JCDWFXSLSFYVDM-UHFFFAOYSA-N [hydroxy-[hydroxy-[hydroxy(oxoboranyloxy)boranyl]oxyboranyl]oxyboranyl]oxy-oxoboranyloxyborinic acid;zinc Chemical compound [Zn].[Zn].O=BOB(O)OB(O)OB(O)OB(O)OB=O JCDWFXSLSFYVDM-UHFFFAOYSA-N 0.000 claims description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- WNROFYMDJYEPJX-UHFFFAOYSA-K Aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 5
- KGBXLFKZBHKPEV-UHFFFAOYSA-N Boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 5
- 229940044172 CALCIUM FORMATE Drugs 0.000 claims description 5
- CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 claims description 5
- VTHJTEIRLNZDEV-UHFFFAOYSA-L Magnesium hydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 5
- JOXIMZWYDAKGHI-UHFFFAOYSA-N P-Toluenesulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 5
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical group [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 5
- 230000032683 aging Effects 0.000 claims description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N al2o3 Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 239000000440 bentonite Substances 0.000 claims description 5
- 229910000278 bentonite Inorganic materials 0.000 claims description 5
- 239000004327 boric acid Substances 0.000 claims description 5
- 239000004281 calcium formate Substances 0.000 claims description 5
- 235000019255 calcium formate Nutrition 0.000 claims description 5
- 239000010881 fly ash Substances 0.000 claims description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 5
- 235000011187 glycerol Nutrition 0.000 claims description 5
- 238000005469 granulation Methods 0.000 claims description 5
- 230000003179 granulation Effects 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- 239000000347 magnesium hydroxide Substances 0.000 claims description 5
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 5
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 5
- 229920000137 polyphosphoric acid Polymers 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 238000005507 spraying Methods 0.000 claims description 5
- 239000000454 talc Substances 0.000 claims description 5
- 229910052623 talc Inorganic materials 0.000 claims description 5
- 235000012222 talc Nutrition 0.000 claims description 5
- 210000003135 Vibrissae Anatomy 0.000 claims description 4
- MYOXMAQGEINAEF-UHFFFAOYSA-N [C].N1=NN=CC=C1 Chemical compound [C].N1=NN=CC=C1 MYOXMAQGEINAEF-UHFFFAOYSA-N 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- 240000000218 Cannabis sativa Species 0.000 claims description 3
- 240000000491 Corchorus aestuans Species 0.000 claims description 3
- 235000011777 Corchorus aestuans Nutrition 0.000 claims description 3
- 235000010862 Corchorus capsularis Nutrition 0.000 claims description 3
- 235000004431 Linum usitatissimum Nutrition 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Tris Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 235000009120 camo Nutrition 0.000 claims description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 3
- 235000005607 chanvre indien Nutrition 0.000 claims description 3
- 239000011487 hemp Substances 0.000 claims description 3
- 235000012765 hemp Nutrition 0.000 claims description 3
- 235000012766 marijuana Nutrition 0.000 claims description 3
- 239000011780 sodium chloride Substances 0.000 claims description 3
- 239000010456 wollastonite Substances 0.000 claims description 3
- 229910052882 wollastonite Inorganic materials 0.000 claims description 3
- 240000008564 Boehmeria nivea Species 0.000 claims description 2
- 239000004113 Sepiolite Substances 0.000 claims description 2
- 229910052599 brucite Inorganic materials 0.000 claims description 2
- 238000001354 calcination Methods 0.000 claims description 2
- TUKQLEWOUPCTOS-UHFFFAOYSA-N dimagnesium;dioxido(oxo)silane;hydroxy-oxido-oxosilane;hydrate Chemical compound O.[Mg+2].[Mg+2].O[Si]([O-])=O.O[Si]([O-])=O.[O-][Si]([O-])=O TUKQLEWOUPCTOS-UHFFFAOYSA-N 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 229910052624 sepiolite Inorganic materials 0.000 claims description 2
- 235000019355 sepiolite Nutrition 0.000 claims description 2
- 240000006240 Linum usitatissimum Species 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- 235000019504 cigarettes Nutrition 0.000 abstract description 6
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- KWKXNDCHNDYVRT-UHFFFAOYSA-N Dodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1 KWKXNDCHNDYVRT-UHFFFAOYSA-N 0.000 description 3
- 231100000614 Poison Toxicity 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000002574 poison Substances 0.000 description 3
- 241000208202 Linaceae Species 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L Sulphite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 239000011528 polyamide (building material) Substances 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 1
- 230000003712 anti-aging Effects 0.000 description 1
- 150000008107 benzenesulfonic acids Chemical class 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006011 modification reaction Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000002195 synergetic Effects 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- BSUNTQCMCCQSQH-UHFFFAOYSA-N triazine Chemical compound C1=CN=NN=C1.C1=CN=NN=C1 BSUNTQCMCCQSQH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/52—Producing shaped prefabricated articles from the material specially adapted for producing articles from mixtures containing fibres, e.g. asbestos cement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/52—Producing shaped prefabricated articles from the material specially adapted for producing articles from mixtures containing fibres, e.g. asbestos cement
- B28B1/525—Producing shaped prefabricated articles from the material specially adapted for producing articles from mixtures containing fibres, e.g. asbestos cement containing organic fibres, e.g. wood fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B3/00—Producing shaped articles from the material by using presses; Presses specially adapted therefor
- B28B3/02—Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein a ram exerts pressure on the material in a moulding space; Ram heads of special form
- B28B3/025—Hot pressing, e.g. of ceramic materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
- C04B28/16—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing anhydrite, e.g. Keene's cement
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/08—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding porous substances
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/10—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by using foaming agents or by using mechanical means, e.g. adding preformed foam
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
- C04B2111/285—Intumescent materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/40—Porous or lightweight materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/76—Use at unusual temperatures, e.g. sub-zero
Abstract
The invention discloses a kind of toughening type fire-proof plate and preparation method thereof, it is related to fire-proof plate technical field, includes the raw material of following part meter：55 ~ 65 parts of 55 ~ 65 parts of cement, 40 ~ 42 parts of plaster of Paris, 35 ~ 40 parts of fiber reinforced particle, 15 ~ 20 parts of auxiliary agent and water.The present invention has good toughness and other mechanical properties, and not easy to crack, heat is unlikely to deform, and meeting fire has the features such as fire-retardant, low cigarette and nonhazardous.
Description
Technical field
The present invention relates to thermal insulation mortar technical field, and in particular to a kind of toughening type fire-proof plate and preparation method thereof.
Background technology
Fire-proof plate also known as refractory slab, scientific name are thermosetting resin-impregnated paper high-pressure laminated board, are that incrustation is built with fire resisting
Material, is widely used in the fields such as interior decoration, furniture, kitchen cabinet, laboratory table face, exterior wall.There is matter in fire-proof plate in the market
Crisp, poor toughness and easily it is scaling-off the problems such as.
The content of the invention
It is an object of the invention to provide a kind of toughening type fire-proof plate and preparation method thereof, with good toughness and other power
Performance is learned, not easy to crack, heat is unlikely to deform, meeting fire has the features such as fire-retardant, low cigarette and nonhazardous.
The invention provides following technical scheme：A kind of toughening type fire-proof plate, includes the raw material of following part meter：Cement 55
55 ~ 65 parts of ~ 65 parts, 40 ~ 42 parts of plaster of Paris, 35 ~ 40 parts of fiber reinforced particle, 15 ~ 20 parts of auxiliary agent and water；
Fiber reinforced particle includes the raw material that following part is counted：10 ~ 12 parts of styrene-acrylic emulsion, 8 ~ 10 parts of inorfil, string 6 ~ 8
3 ~ 4 parts of part, 4 ~ 6 parts of filler and toughener；
The auxiliary agent includes the raw material that following part is counted：2 ~ 3 parts of curing agent, 2 ~ 3 parts of fire retardant, 1 ~ 2 part of carbon forming agent, smoke suppressant 1 ~ 2
0.4 ~ 0.6 part of part, 0.6 ~ 0.8 part of water reducer, 0.6 ~ 0.8 part of foaming agent and early strength agent.
Wherein, the raw material of following part meter is included：60 parts of cement, 41 parts of plaster of Paris, 37.5 parts of fiber reinforced particle, auxiliary agent
17.5 parts and 60 parts of water；
Fiber reinforced particle includes the raw material that following part is counted：11 parts of styrene-acrylic emulsion, 9 parts of inorfil, 7 parts of string, filler 5
3.5 parts of part and toughener；
The auxiliary agent includes the raw material that following part is counted：2.5 parts of curing agent, 2.5 parts of fire retardant, 1.5 parts of carbon forming agent, smoke suppressant 1.5
Part, 0.7 part of water reducer, 0.7 part of foaming agent and 0.5 part of early strength agent.
Wherein, the preparation method of the plaster of Paris is：Ardealite is weighed, by wherein 1/4 ardealite at 160 ~ 180 DEG C
Temperature conditionss under calcining 1 ~ 2h, ageing obtain β semi-hydrated gypsums within 2~3 days；By the ardealite of residue 3/4 at 340~360 DEG C
1 ~ 2h is calcined under temperature conditionss and obtains II type anhydrous gypsums；β semi-hydrated gypsums and II type anhydrous gypsums are mixed to get the building
Gypsum.
Wherein, the toughener includes the raw material that following part is counted：0.8 ~ 1.2 part of aluminum oxide, 0.6 ~ 0.8 part of calcium formate, ten
0.2 ~ 0.4 part of 0.6 ~ 0.8 part of dialkyl benzene sulfonic acids sodium, 0.4 ~ 0.6 part of glycerine, 0.2 ~ 0.4 part of ethanol and rosin.
Wherein, the string is the one or more in flax, jute, gombo hemp and ramie, and the inorfil is
One or more in wollastonite fibre, crystal whisker of gypsum, brucite fiber and sepiolite fibre.
Wherein, the filler includes the raw material that following part is counted：14 ~ 16 parts of modified alta-mud, 10 ~ 12 parts of diatomite, talcum
4 ~ 5 parts of 5 ~ 7 parts of powder and flyash.
Wherein, the method for preparing modified bentonite is：Bentonite is put into boric acid aqueous solution, with 200 ~ 300r/
Min rotating speed mixes 1 ~ 2h, filters, and it is 7 to retain filter residue and be washed to pH value, 100 ~ 300 after then filter residue is dried
20 ~ 40min is calcined under the conditions of DEG C and obtains the modified alta-mud.
Wherein, the curing agent includes the raw material that following part is counted：40 ~ 60% 7 ~ 9 parts of p-methyl benzenesulfonic acid solution, phosphoric acid 3 ~ 5
Part and 40 ~ 60% 20 ~ 30 parts of sulfuric acid solution, aforementioned base materials are mixed, curing agent is obtained.
Wherein, the smoke suppressant is molybdenum trioxide and Firebrake ZB according to 1 ~ 3：1 ratio is mixed, the fire retardant bag
Include the raw material of following part meter：1 ~ 2 part of polyphosphoric acid, 0.6 ~ 0.8 part of magnesium hydroxide and 0.1 ~ 0.3 part of aluminium hydroxide, the carbon forming agent
For triazine carbon forming agent, the water reducer be poly carboxylic acid series water reducer, polyamide-based water reducer and one kind in naphthalene water reducer or
Several, the foaming agent is lauryl sodium sulfate, and the early strength agent is one kind in triethanolamine, sodium chloride and natrium nitrosum
Or it is several.
The present invention provides a kind of preparation method of toughening type fire-proof plate, comprises the following steps：
（1）, prepare fiber reinforced particle
Inorfil, string and filler are weighed according to proportioning, co-grinding simultaneously crosses 200 ~ 300 mesh sieves, obtains powder, Xiang Fen
Styrene-acrylic emulsion and toughener are added in material, to stir 20 ~ 30min under 200 ~ 350r/min speed conditions, material A is obtained；Will
Granulation of spraying water is put into comminutor after mixed material A drying process, fiber reinforced particle is obtained；
（2）, raw material mixing
According to proportioning surplus stock with by step（1）Obtained fiber reinforced particle mixing, it is mixed with 100 ~ 200r/min rotating speed
30 ~ 50min of stirring is closed, is uniformly dispersed and obtains base-material；
（3）, it is compressing
By step（2）Obtained base-material is put into mould, and high temperature is compressing, and press temperature is 400 ~ 600 DEG C, after the completion of compacting
Room temperature is cooled to, the toughening type fire-proof plate is obtained.
Beneficial effects of the present invention：With good toughness and other mechanical properties, not easy to crack, heat is unlikely to deform,
Meeting fire has the features such as fire-retardant, low cigarette and nonhazardous, specific as follows：
（1）, the present invention add fiber reinforced particle in the feed, using styrene-acrylic emulsion, inorfil, string, filler and
Toughener compounding is made, and rich in toughness, fibre strength is good, improves overall resistance to compression and tensile strength, also has resistance to height in addition
The features such as temperature, resist chemical, improvement anti-contracility and freeze-thaw resistance；
（2）, the filler that adds in fiber reinforced particle of the invention, it is light weight, porous and with good heat insulation effect；The nothing of addition
Machine fiber and string, can improve overall surface strength, prevent from being molded, construct and use during occur cracking and fall
Slag, is increased the service life long and can be unlikely to deform with anti-aging, not easy to crack, heat；
（3）, the present invention in the feed addition Firebrake ZB and molybdenum trioxide mixture as smoke suppressant, can obviously reduce the present invention
Cigarette poison release during burning, in addition, smoke suppressant and refractory particle can reach more preferable flame-retardant smoke inhibition synergistic effect, makes cigarette poison enter one
Step is reduced so that the present invention, which meets fire, has the features such as fire-retardant, low cigarette and nonhazardous, when running into indoor generation fire, Ke Yiyou
Effect barrier propagation of flame, can be that escape and fire extinguishing provide the time, it is possible to reduce casualties；
（4）, the present invention in addition carbon forming agent, it is expanded foamed under the heated situation of burning, improve the quality of layer of charcoal, improve
Fire endurance；
（5）, preparation method of the present invention it is simple, solidification is fast and hardness is good, it is heated after will not split, crush, meet high temperature or naked light, no
Smog and other organic poisons can be produced.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments be merely to illustrate the present invention and without
In limitation the scope of the present invention.
Embodiment 1
A kind of toughening type fire-proof plate, includes the raw material of following part meter：55 parts of cement, 40 parts of plaster of Paris, fiber reinforced particle 35
55 parts of part, 15 parts of auxiliary agent and water；
Fiber reinforced particle includes the raw material that following part is counted：10 parts of styrene-acrylic emulsion, 8 parts of inorfil, 6 parts of string, filler 4
3 parts of part and toughener；
The auxiliary agent includes the raw material that following part is counted：2 parts of curing agent, 2 parts of fire retardant, 1 part of carbon forming agent, 1 part of smoke suppressant, water reducer
0.4 part of 0.6 part, 0.6 part of foaming agent and early strength agent.
Wherein, the preparation method of the plaster of Paris is：Ardealite is weighed, the temperature by wherein 1/4 ardealite at 160 DEG C
1h, ageing are calcined under the conditions of degree and obtains β semi-hydrated gypsums within 2 days；The ardealite of residue 3/4 is calcined under 340 DEG C of temperature conditionss
1h obtains II type anhydrous gypsums；β semi-hydrated gypsums and II type anhydrous gypsums are mixed to get the plaster of Paris.
Wherein, the toughener includes the raw material that following part is counted：0.8 part of aluminum oxide, 0.6 part of calcium formate, detergent alkylate
0.2 part of 0.6 part of sodium sulfonate, 0.4 part of glycerine, 0.2 part of ethanol and rosin.
Wherein, the string is flax, and the inorfil is wollastonite fibre.
Wherein, the filler includes the raw material that following part is counted：14 parts of modified alta-mud, 10 parts of diatomite, 5 parts of talcum powder and
4 parts of flyash.
Wherein, the method for preparing modified bentonite is：Bentonite is put into boric acid aqueous solution, with 200r/min's
Rotating speed mixes 1h, filters, and it is 7 to retain filter residue and be washed to pH value, is calcined after then filter residue is dried under the conditions of 100 DEG C
20min obtains the modified alta-mud.
Wherein, the curing agent includes the raw material that following part is counted：40% 7 parts of p-methyl benzenesulfonic acid solution, 3 parts of phosphoric acid and 40
20 parts of ~ % sulfuric acid solution, aforementioned base materials are mixed, curing agent is obtained.
Wherein, the smoke suppressant is molybdenum trioxide and Firebrake ZB according to 1：1 ratio is mixed, and the fire retardant includes
The raw material of following part meter：0.1 part of 1 part of polyphosphoric acid, 0.6 part of magnesium hydroxide and aluminium hydroxide, the carbon forming agent are triazine carbon forming agent,
The water reducer is poly carboxylic acid series water reducer, and the foaming agent is lauryl sodium sulfate, and the early strength agent is triethanolamine.
A kind of preparation method of toughening type fire-proof plate is provided in the present embodiment, comprised the following steps：
（1）, prepare fiber reinforced particle
Inorfil, string and filler are weighed according to proportioning, co-grinding simultaneously crosses 200 mesh sieves, powder obtained, into powder
Styrene-acrylic emulsion and toughener are added, to stir 20min under 200r/min speed conditions, material A is obtained；Mixed material A is done
Granulation of spraying water is put into comminutor after dry processing, fiber reinforced particle is obtained；
（2）, raw material mixing
According to proportioning surplus stock with by step（1）Obtained fiber reinforced particle mixing, is stirred with 100r/min rotating speed mixing
30min is mixed, is uniformly dispersed and obtains base-material；
（3）, it is compressing
By step（2）Obtained base-material is put into mould, and high temperature is compressing, and press temperature is 400 DEG C, is cooled down after the completion of compacting
To room temperature, the toughening type fire-proof plate is obtained.
Embodiment 2
A kind of toughening type fire-proof plate, includes the raw material of following part meter：65 parts of cement, 42 parts of plaster of Paris, fiber reinforced particle 40
65 parts of part, 20 parts of auxiliary agent and water；
Fiber reinforced particle includes the raw material that following part is counted：12 parts of styrene-acrylic emulsion, 10 parts of inorfil, 8 parts of string, filler
6 parts and 4 parts of toughener；
The auxiliary agent includes the raw material that following part is counted：3 parts of curing agent, 3 parts of fire retardant, 2 parts of carbon forming agent, 2 parts of smoke suppressant, water reducer
0.6 part of 0.8 part, 0.8 part of foaming agent and early strength agent.
Wherein, the preparation method of the plaster of Paris is：Ardealite is weighed, the temperature by wherein 1/4 ardealite at 180 DEG C
2h, ageing are calcined under the conditions of degree and obtains β semi-hydrated gypsums within 3 days；The ardealite of residue 3/4 is calcined under 360 DEG C of temperature conditionss
2h obtains II type anhydrous gypsums；β semi-hydrated gypsums and II type anhydrous gypsums are mixed to get the plaster of Paris.
Wherein, the toughener includes the raw material that following part is counted：1.2 parts of aluminum oxide, 0.8 part of calcium formate, detergent alkylate
0.4 part of 0.8 part of sodium sulfonate, 0.6 part of glycerine, 0.4 part of ethanol and rosin.
Wherein, the string is jute, and the inorfil is crystal whisker of gypsum.
Wherein, the filler includes the raw material that following part is counted：16 parts of modified alta-mud, 12 parts of diatomite, 7 parts of talcum powder and
5 parts of flyash.
Wherein, the method for preparing modified bentonite is：Bentonite is put into boric acid aqueous solution, with 300r/min's
Rotating speed mixes 2h, filters, and it is 7 to retain filter residue and be washed to pH value, is calcined after then filter residue is dried under the conditions of 300 DEG C
40min obtains the modified alta-mud.
Wherein, the curing agent includes the raw material that following part is counted：60% 9 parts of p-methyl benzenesulfonic acid solution, 5 parts of phosphoric acid and
30 parts of 60% sulfuric acid solution, aforementioned base materials are mixed, curing agent is obtained.
Wherein, the smoke suppressant is molybdenum trioxide and Firebrake ZB according to 3：1 ratio is mixed, and the fire retardant includes
The raw material of following part meter：0.3 part of 2 parts of polyphosphoric acid, 0.8 part of magnesium hydroxide and aluminium hydroxide, the carbon forming agent are triazine carbon forming agent,
The water reducer is polyamide-based water reducer, and the foaming agent is lauryl sodium sulfate, and the early strength agent is sodium chloride.
A kind of preparation method of toughening type fire-proof plate is provided in the present embodiment, comprised the following steps：
（1）, prepare fiber reinforced particle
Inorfil, string and filler are weighed according to proportioning, co-grinding simultaneously crosses 300 mesh sieves, powder obtained, into powder
Styrene-acrylic emulsion and toughener are added, to stir 30min under 350r/min speed conditions, material A is obtained；Mixed material A is done
Granulation of spraying water is put into comminutor after dry processing, fiber reinforced particle is obtained；
（2）, raw material mixing
According to proportioning surplus stock with by step（1）Obtained fiber reinforced particle mixing, is stirred with 200r/min rotating speed mixing
50min is mixed, is uniformly dispersed and obtains base-material；
（3）, it is compressing
By step（2）Obtained base-material is put into mould, and high temperature is compressing, and press temperature is 600 DEG C, is cooled down after the completion of compacting
To room temperature, the toughening type fire-proof plate is obtained.
Embodiment 3
A kind of toughening type fire-proof plate, includes the raw material of following part meter：60 parts of cement, 41 parts of plaster of Paris, fiber reinforced particle 37
60 parts of part, 17 parts of auxiliary agent and water；
Fiber reinforced particle includes the raw material that following part is counted：11 parts of styrene-acrylic emulsion, 9 parts of inorfil, 7 parts of string, filler 5
3.5 parts of part and toughener；
The auxiliary agent includes the raw material that following part is counted：2.5 parts of curing agent, 2.5 parts of fire retardant, 1.5 parts of carbon forming agent, smoke suppressant 1.5
Part, 0.7 part of water reducer, 0.7 part of foaming agent and 0.5 part of early strength agent.
Wherein, the preparation method of the plaster of Paris is：Ardealite is weighed, the temperature by wherein 1/4 ardealite at 170 DEG C
1.5h, ageing are calcined under the conditions of degree and obtains β semi-hydrated gypsums within 3 days；The ardealite of residue 3/4 is forged under 350 DEG C of temperature conditionss
Burn 1.5h and obtain II type anhydrous gypsums；β semi-hydrated gypsums and II type anhydrous gypsums are mixed to get the plaster of Paris.
Wherein, the toughener includes the raw material that following part is counted：1 part of aluminum oxide, 0.7 part of calcium formate, detergent alkylate sulphur
0.3 part of sour 0.7 part of sodium, 0.5 part of glycerine, 0.3 part of ethanol and rosin.
Wherein, the string is gombo hemp, and the inorfil is crystal whisker of gypsum.
Wherein, the filler includes the raw material that following part is counted：15 parts of modified alta-mud, 11 parts of diatomite, 6 parts of talcum powder and
4.5 parts of flyash.
Wherein, the method for preparing modified bentonite is：Bentonite is put into boric acid aqueous solution, with 250r/min's
Rotating speed mixes 1.5h, filters, and it is 7 to retain filter residue and be washed to pH value, is forged after then filter residue is dried under the conditions of 200 DEG C
Burn 30min and obtain the modified alta-mud.
Wherein, the curing agent includes the raw material that following part is counted：50% 8 parts of p-methyl benzenesulfonic acid solution, phosphatase 24 part and 50%
25 parts of sulfuric acid solution, aforementioned base materials are mixed, curing agent is obtained.
Wherein, the smoke suppressant is molybdenum trioxide and Firebrake ZB according to 2：1 ratio is mixed, and the fire retardant includes
The raw material of following part meter：0.2 part of 1.5 parts of polyphosphoric acid, 0.7 part of magnesium hydroxide and aluminium hydroxide, the carbon forming agent are triazine into charcoal
Agent, the water reducer is naphthalene water reducer, and the foaming agent is lauryl sodium sulfate, and the early strength agent is natrium nitrosum.
A kind of preparation method of toughening type fire-proof plate is provided in the present embodiment, comprised the following steps：
（1）, prepare fiber reinforced particle
Inorfil, string and filler are weighed according to proportioning, co-grinding simultaneously crosses 250 mesh sieves, powder obtained, into powder
Styrene-acrylic emulsion and toughener are added, to stir 25min under 300r/min speed conditions, material A is obtained；Mixed material A is done
Granulation of spraying water is put into comminutor after dry processing, fiber reinforced particle is obtained；
（2）, raw material mixing
According to proportioning surplus stock with by step（1）Obtained fiber reinforced particle mixing, is stirred with 150r/min rotating speed mixing
40min is mixed, is uniformly dispersed and obtains base-material；
（3）, it is compressing
By step（2）Obtained base-material is put into mould, and high temperature is compressing, and press temperature is 5600 DEG C, cold after the completion of compacting
But to room temperature, the toughening type fire-proof plate is obtained.
The present invention is described in detail with reference to the foregoing embodiments, for those skilled in the art, its according to
The technical scheme described in foregoing embodiments can so be modified, or which part technical characteristic is equally replaced
Change.Within the spirit and principles of the invention, any modification, equivalent substitution and improvements made etc., should be included in the present invention
Protection domain within.
Claims (10)
1. a kind of toughening type fire-proof plate, it is characterised in that the raw material counted including following part：55 ~ 65 parts of cement, plaster of Paris 40 ~
55 ~ 65 parts of 42 parts, 35 ~ 40 parts of fiber reinforced particle, 15 ~ 20 parts of auxiliary agent and water；
Fiber reinforced particle includes the raw material that following part is counted：10 ~ 12 parts of styrene-acrylic emulsion, 8 ~ 10 parts of inorfil, string 6 ~ 8
3 ~ 4 parts of part, 4 ~ 6 parts of filler and toughener；
The auxiliary agent includes the raw material that following part is counted：2 ~ 3 parts of curing agent, 2 ~ 3 parts of fire retardant, 1 ~ 2 part of carbon forming agent, smoke suppressant 1 ~ 2
0.4 ~ 0.6 part of part, 0.6 ~ 0.8 part of water reducer, 0.6 ~ 0.8 part of foaming agent and early strength agent.
2. toughening type fire-proof plate according to claim 1, it is characterised in that the raw material counted including following part：60 parts of cement,
60 parts of 41 parts of plaster of Paris, 37.5 parts of fiber reinforced particle, 17.5 parts of auxiliary agent and water；
Fiber reinforced particle includes the raw material that following part is counted：11 parts of styrene-acrylic emulsion, 9 parts of inorfil, 7 parts of string, filler 5
3.5 parts of part and toughener；
The auxiliary agent includes the raw material that following part is counted：2.5 parts of curing agent, 2.5 parts of fire retardant, 1.5 parts of carbon forming agent, smoke suppressant 1.5
Part, 0.7 part of water reducer, 0.7 part of foaming agent and 0.5 part of early strength agent.
3. toughening type fire-proof plate according to claim 1, it is characterised in that the preparation method of the plaster of Paris is：Claim
Ardealite is taken, wherein 1/4 ardealite is calcined into 1 ~ 2h, ageing under 160 ~ 180 DEG C of temperature conditionss obtains the water of β half for 2~3 days
Gypsum；The ardealite of residue 3/4 is calcined into 1 ~ 2h under 340~360 DEG C of temperature conditionss and obtains II type anhydrous gypsums；By β half
Water gypsum and II type anhydrous gypsums are mixed to get the plaster of Paris.
4. toughening type fire-proof plate according to claim 1, it is characterised in that the toughener includes the original that following part is counted
Material：0.8 ~ 1.2 part of aluminum oxide, 0.6 ~ 0.8 part of calcium formate, 0.6 ~ 0.8 part of neopelex, 0.4 ~ 0.6 part of glycerine, second
0.2 ~ 0.4 part of 0.2 ~ 0.4 part of alcohol and rosin.
5. toughening type fire-proof plate according to claim 1, it is characterised in that the string is flax, jute, gombo hemp
With the one or more in ramie, the inorfil is wollastonite fibre, crystal whisker of gypsum, brucite fiber and sepiolite fibre
In one or more.
6. toughening type fire-proof plate according to claim 1, it is characterised in that the filler includes the raw material that following part is counted：
4 ~ 5 parts of 14 ~ 16 parts of modified alta-mud, 10 ~ 12 parts of diatomite, 5 ~ 7 parts of talcum powder and flyash.
7. toughening type fire-proof plate according to claim 6, it is characterised in that the method for preparing modified bentonite is：
Bentonite is put into boric acid aqueous solution, 1 ~ 2h is mixed with 200 ~ 300r/min rotating speed, filtering retains filter residue and washed
It is 7 to pH value, calcining 20 ~ 40min under the conditions of 100 ~ 300 DEG C after then filter residue is dried obtains the modified alta-mud.
8. toughening type fire-proof plate according to claim 1, it is characterised in that the curing agent includes the original that following part is counted
Material：40 ~ 60% 7 ~ 9 parts of p-methyl benzenesulfonic acid solution, 3 ~ 5 parts of phosphoric acid and 40 ~ 60% 20 ~ 30 parts of sulfuric acid solution, by aforementioned base materials
Mixing, obtains curing agent.
9. toughening type fire-proof plate according to claim 1, it is characterised in that the smoke suppressant is molybdenum trioxide and Firebrake ZB
According to 1 ~ 3：1 ratio is mixed, and the fire retardant includes the raw material that following part is counted：1 ~ 2 part of polyphosphoric acid, magnesium hydroxide 0.6 ~
0.8 part and 0.1 ~ 0.3 part of aluminium hydroxide, the carbon forming agent are triazine carbon forming agent, and the water reducer is poly carboxylic acid series water reducer, gathered
One or more in acid amides based water reducer and naphthalene water reducer, the foaming agent is lauryl sodium sulfate, the early strength agent
For the one or more in triethanolamine, sodium chloride and natrium nitrosum.
10. a kind of preparation method of toughening type fire-proof plate according to any one of claim 1 ~ 9, it is characterised in that including
Following steps：
（1）, prepare fiber reinforced particle
Inorfil, string and filler are weighed according to proportioning, co-grinding simultaneously crosses 200 ~ 300 mesh sieves, obtains powder, Xiang Fen
Styrene-acrylic emulsion and toughener are added in material, to stir 20 ~ 30min under 200 ~ 350r/min speed conditions, material A is obtained；Will
Granulation of spraying water is put into comminutor after mixed material A drying process, fiber reinforced particle is obtained；
（2）, raw material mixing
According to proportioning surplus stock with by step（1）Obtained fiber reinforced particle mixing, it is mixed with 100 ~ 200r/min rotating speed
30 ~ 50min of stirring is closed, is uniformly dispersed and obtains base-material；
（3）, it is compressing
By step（2）Obtained base-material is put into mould, and high temperature is compressing, and press temperature is 400 ~ 600 DEG C, after the completion of compacting
Room temperature is cooled to, the toughening type fire-proof plate is obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710644696.5A CN107311592A (en) | 2017-08-01 | 2017-08-01 | A kind of toughening type fire-proof plate and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710644696.5A CN107311592A (en) | 2017-08-01 | 2017-08-01 | A kind of toughening type fire-proof plate and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107311592A true CN107311592A (en) | 2017-11-03 |
Family
ID=60171734
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710644696.5A Pending CN107311592A (en) | 2017-08-01 | 2017-08-01 | A kind of toughening type fire-proof plate and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107311592A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108285359A (en) * | 2018-03-29 | 2018-07-17 | 合肥市闵葵电力工程有限公司 | A kind of repairing cement special based polyalcohol mortar and preparation method thereof |
| CN111848207A (en) * | 2020-07-23 | 2020-10-30 | 湖州巨旺墙体材料有限公司 | Nano-material modified heat-insulation building block suitable for low-temperature environment |
| WO2021012309A1 (en) * | 2019-07-19 | 2021-01-28 | 广东特耐石新材料科技有限公司 | Inorganic fiber toughened inorganic composite artificial stone panel and preparation method therefor |
| CN113072331A (en) * | 2021-04-17 | 2021-07-06 | 菏泽永民新型建筑材料股份有限公司 | Energy-saving building material and preparation method thereof |
| CN113754367A (en) * | 2021-08-02 | 2021-12-07 | 廊坊傲天节能科技有限公司 | High-temperature-resistant high-strength fireproof door core plate and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102584155A (en) * | 2011-12-22 | 2012-07-18 | 东莞市恒和节能科技有限公司 | Inorganic heat-insulating fireproof plate and manufacturing method thereof |
| CN104761272A (en) * | 2015-05-04 | 2015-07-08 | 李孟平 | Carbon filer heat insulating material preparing method |
| CN106431129A (en) * | 2016-08-31 | 2017-02-22 | 周飞燕 | Fireproof material based on modified bentonite and preparation method of modified bentonite |
-
2017
- 2017-08-01 CN CN201710644696.5A patent/CN107311592A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102584155A (en) * | 2011-12-22 | 2012-07-18 | 东莞市恒和节能科技有限公司 | Inorganic heat-insulating fireproof plate and manufacturing method thereof |
| CN104761272A (en) * | 2015-05-04 | 2015-07-08 | 李孟平 | Carbon filer heat insulating material preparing method |
| CN106431129A (en) * | 2016-08-31 | 2017-02-22 | 周飞燕 | Fireproof material based on modified bentonite and preparation method of modified bentonite |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108285359A (en) * | 2018-03-29 | 2018-07-17 | 合肥市闵葵电力工程有限公司 | A kind of repairing cement special based polyalcohol mortar and preparation method thereof |
| WO2021012309A1 (en) * | 2019-07-19 | 2021-01-28 | 广东特耐石新材料科技有限公司 | Inorganic fiber toughened inorganic composite artificial stone panel and preparation method therefor |
| US11485685B2 (en) | 2019-07-19 | 2022-11-01 | GuangDong TopNice New Materials Technology CO., LTD. | Inorganic fiber toughened inorganic composite artificial stone panel and preparation method thereof |
| CN111848207A (en) * | 2020-07-23 | 2020-10-30 | 湖州巨旺墙体材料有限公司 | Nano-material modified heat-insulation building block suitable for low-temperature environment |
| CN113072331A (en) * | 2021-04-17 | 2021-07-06 | 菏泽永民新型建筑材料股份有限公司 | Energy-saving building material and preparation method thereof |
| CN113754367A (en) * | 2021-08-02 | 2021-12-07 | 廊坊傲天节能科技有限公司 | High-temperature-resistant high-strength fireproof door core plate and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107311592A (en) | A kind of toughening type fire-proof plate and preparation method thereof | |
| CN102320808B (en) | Fireproof insulation board and preparation process thereof | |
| CN109879654B (en) | Insulation board raw material composition and insulation board | |
| CN107986720A (en) | A kind of insulated fire environment-friendly composite material and preparation method thereof | |
| CN107117929A (en) | A kind of external wall insulation and preparation method thereof | |
| CN107188509A (en) | A kind of lightweight water-resistant gypsum board and preparation method thereof | |
| CN104761233A (en) | Fireproof insulation board and manufacturing method thereof | |
| CN107382193A (en) | A kind of preparation method of fireproofing and heat resistant light cellular partition board | |
| CN107337416A (en) | A kind of preparation method of environmentally friendly plasterboard | |
| CN106082884B (en) | A kind of insulating light wall slab and preparation process containing solid waste cinder | |
| CN107216105A (en) | A kind of lightweight water-resistant gypsum board and preparation method thereof | |
| CN103880376B (en) | A kind of lightweight inorganic fireproof heat preservation plate material | |
| CN107382256A (en) | A kind of fire-proof plate and preparation method thereof | |
| CN102659385A (en) | Refractory wall plate material and production method thereof | |
| CN110002821B (en) | Fireproof heat-insulating energy-saving door leaf and preparation method thereof | |
| CN109133834B (en) | High-strength gypsum partition board and preparation method thereof | |
| CN102152523B (en) | Fireproof flame-resistant core board material and production method thereof | |
| CN103880375B (en) | A kind of preparation method of lightweight inorganic fireproof heat preservation plate material | |
| CN107186861A (en) | A kind of preparation method of fire-proof light partition plate | |
| KR100548963B1 (en) | Method of producing a porous building materials by using pearlite | |
| CN107337417A (en) | A kind of lightweight water-resistant gypsum board and preparation method thereof | |
| CN103086683A (en) | Environmentally-friendly light cloth-adhering plate base plate and manufacturing method thereof | |
| CN112521116A (en) | Green environment-friendly plate and production method thereof | |
| CN105924123A (en) | Cement-based modified expanded perlite insulation board and production method thereof | |
| CN108358590A (en) | A kind of compression-resistant fire plate and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171103 |