CN105093689A - 彩色滤光片整合晶体管式液晶面板及其制造方法 - Google Patents
彩色滤光片整合晶体管式液晶面板及其制造方法 Download PDFInfo
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Abstract
本发明公开一种彩色滤光片整合晶体管式(COA)液晶面板及其制造方法,其是通过以紫外线诱导多区域垂直配向(UV2A)的光配向技术形成所述COA液晶面板中的配向膜,以及通过控制所述COA液晶面板中液晶层的液晶分子的介电常数(△ε),来改进现有COA液晶显示器的影像残留的问题。
Description
技术领域
本发明是有关于一种液晶面板及其制造方法,特别是有关于一种彩色滤光片整合晶体管式(ColorfilteronArray,COA)液晶面板及其制造方法。
背景技术
彩色滤光片整合晶体管式(COA)液晶显示器是一种将彩色滤光片与薄膜晶体管阵列设置于同一基板的液晶显示器,其可以有效的提高开口率,还能解决大尺寸面板的对准问题,且同时降低由照光产生的漏电流,因此彩色滤光片整合晶体管技术特别适用于大尺寸面板的显示器。
然而,由于现在很多研究机构为了提高COA液晶显示器的响应时间等光学性能,会将所述COA液晶显示器中的液晶层的液晶分子的介电常数设计的很高(介电常数的提高主要是通过极性液晶单体的比例增加,但是极性液晶单体增加后会导致液晶的稳定性降低),因此容易使得液晶在使用过程中发生劣化,而产生可移动离子,使电压保持率(VHR)等降低,从而导致信赖性(尤其是影像残留)不佳。
因此,有必要提供一种可以改进影像残留的彩色滤光片整合晶体管式液晶面板,来解决现有技术所存在的问题。
发明内容
本发明的主要目的在于提供一种彩色滤光片整合晶体管式(COA)液晶面板及其制造方法。通过以紫外线诱导多区域垂直配向(ultravioletinducedmulti-domainverticalalignment,UV2A)的光配向技术形成所述彩色滤光片整合晶体管式液晶面板中的配向膜,以及通过控制所述彩色滤光片整合晶体管式液晶面板中液晶层的液晶分子的介电常数(△ε),来改进现有彩色滤光片整合晶体管式液晶显示器的影像残留的问题。
为达成本发明的前述目的,本发明提供一种彩色滤光片整合晶体管式液晶面板,包含:
一第一基板,具有一第一配向膜,所述第一基板包含:
一透明基板;
一薄膜晶体管阵列层,设置于所述透明基板上;以及
一彩色滤光层,设置于所述薄膜晶体管阵列层上;
一第二基板,具有一第二配向膜,所述第一基板与第二基板相对设置;以及
一液晶层,夹设于所述第一基板与所述第二基板之间,且所述液晶层接触所述第一配向膜和所述第二配向膜,所述液晶层包含至少一种极性液晶单体和至少一种非极性液晶单体。由一偏振光敏感材料构成的所述第一及第二配向膜是通过紫外线诱导多区域垂直配向(UV2A)的光配向技术而形成的。
在本发明的一实施例中,所述液晶层的液晶分子为负性液晶。
在本发明的一实施例中,所述液晶层的液晶分子的介电常数(△ε)在20℃下是介于-2.1~-2.5之间。
在本发明的一实施例中,所述偏振光敏感材料为聚酰亚胺材料。
在本发明的一实施例中,所述聚酰亚胺材料的反应波长为313nm。
在本发明的一实施例中,所述聚酰亚胺材料的配向基团包含肉桂酸、香豆素。
再者,本发明另提供一种彩色滤光片整合晶体管式液晶面板的制造方法,包括以下步骤:
提供一第一基板,所述第一基板包含一透明基板、一设置于所述透明基板上的薄膜晶体管阵列层及一设置于所述薄膜晶体管阵列层上的彩色滤光层;
提供一第二基板;
分别涂布一偏振光敏感材料在所述第一基板及所述第二基板上,而后通过紫外线诱导多区域垂直配向(UV2A)的光配向技术来相应地形成一第一配向膜及一第二配向膜;以及
提供至少一种极性液晶单体和至少一种非极性液晶单体,且混合所述极性液晶单体及所述非极性液晶单体,而后填充在所述第一基板及所述第二基板之间,形成一液晶层,所述液晶层接触所述第一配向膜和所述第二配向膜。
在本发明的一实施例中,所述液晶层的液晶分子为负性液晶。
在本发明的一实施例中,所述液晶层的液晶分子的介电常数(△ε)在20℃下是介于-2.1~-2.5之间。
在本发明的一实施例中,所述偏振光敏感材料为聚酰亚胺材料。
在本发明的一实施例中,所述聚酰亚胺材料的反应波长为313nm。
在本发明的一实施例中,所述聚酰亚胺材料的配向基团包含肉桂酸、香豆素。
本发明与现有技术相比具有明显的优点和有益的效果。通过上述技术方案,本发明彩色滤光片整合晶体管式液晶面板及其制造方法至少具有下列优点及有益效果:通过以紫外线诱导多区域垂直配向(UV2A)的光配向技术形成所述彩色滤光片整合晶体管式液晶面板中的配向膜,以及通过控制所述彩色滤光片整合晶体管式液晶面板中液晶层的液晶分子的介电常数(△ε),来改进现有彩色滤光片整合晶体管式液晶显示器的影像残留的问题。
附图说明
图1是本发明一实施例中彩色滤光片整合晶体管式液晶面板的构造示意图。
图2是本发明一实施例中彩色滤光片整合晶体管式液晶面板的制造方法的步骤流程图。
图3是紫外线诱导多区域垂直配向(UV2A)的光配向技术的示意图。
图4是表4的不同液晶配方的影像残留表现。
1COA液晶面板202黑色矩阵层
10第一基板203第二透明导电膜
20第二基板1021Mo/Al
30液晶层1022G-SiNx
40间隙柱1023a-Si
50框胶1024MoN/Al/Mo
101第一透明基板、透明基板R红色子像素
102薄膜晶体管阵列层G绿色子像素
103第一保护层B蓝色子像素
104彩色滤光层D1段差
105第二保护层D2间隙柱差
106第一透明导电膜D3B&RG膜厚差
201第二透明基板S11-S14步骤
具体实施方式
为更进一步阐述本发明为达成预订发明目的所采取的技术手段及功效,以下结合附图及较佳实施例,对依据本发明提出的彩色滤光片整合晶体管式液晶面板及其制造方法其具体实施方式、结构、特征及其功效,详细说明如后。
请参照图1,其为本发明一实施例中彩色滤光片整合晶体管式液晶面板1的构造示意图。所述彩色滤光片整合晶体管式液晶面板1包含一第一基板10、一第二基板20、一液晶层30及若干间隙柱40。所述第一基板10与第二基板20相对设置,且所述液晶层30夹设于所述第一基板10与第二基板20之间。所述第一基板10的内表面上具有一第一配向膜(图中未示出),所述第二基板20的内表面上具有一第二配向膜(图中未示出)。所述液晶层30接触所述第一配向膜及所述第二配向膜。
所述第一基板10包括一第一透明基板101、一薄膜晶体管阵列层102、一第一保护层103、一彩色滤光层104、一第二保护层105及若干第一透明导电膜106。所述薄膜晶体管阵列层102是设置于所述第一透明基板101的内表面上。所述第一保护层103是设置于所述薄膜晶体管阵列层102上。所述彩色滤光层104是设置于所述第一保护层103上。所述第二保护层105是设置于所述彩色滤光层104上。所述若干第一透明导电膜106是设置于所述第二保护层105上。
所述第二基板20包括一第二透明基板201、一黑色矩阵层202及一第二透明导电膜203。所述黑色矩阵层202是设置于所述第二透明基板201的内表面上。所述第二透明导电膜203是设置于所述黑色矩阵层202上。所述若干间隙柱40是设置于所述彩色滤光层104及所述黑色矩阵层202之间。
所述液晶层30包含至少一种极性液晶单体和至少一种非极性液晶单体。所述液晶层30的液晶分子为负性液晶,并且所述液晶层30的液晶分子的介电常数(△ε)在20℃下是介于-2.1~-2.5之间。
由一偏振光敏感材料构成的所述第一及第二配向膜是通过紫外线诱导多区域垂直配向(UV2A)的光配向技术而形成的。所述偏振光敏感材料是一反应波长为313nm的聚酰亚胺材料,且所述聚酰亚胺材料的配向基团包含肉桂酸、香豆素。
请参照图2,其为本发明一实施例中彩色滤光片整合晶体管式液晶面板1的制造方法的步骤流程图,该制造方法包括下述步骤S11至S14。
在步骤S11中,提供一第一基板10。所述第一基板10包含一透明基板101、一设置于所述透明基板101上的薄膜晶体管阵列层102及一设置于所述薄膜晶体管阵列层102上的彩色滤光层104。
在步骤S12中,提供一第二基板20。
在步骤S13中,分别涂布一偏振光敏感材料在所述第一基板10及所述第二基板20上,而后通过紫外线诱导多区域垂直配向(UV2A)的光配向技术来相应地形成一第一配向膜及一第二配向膜(图中未示出)。所述偏振光敏感材料是一反应波长为313nm的聚酰亚胺材料,且所述聚酰亚胺材料的配向基团包含肉桂酸、香豆素。所述紫外线诱导多区域垂直配向(UV2A)的光配向技术的具体特征为,紫外偏振光为倾斜入射至一配向膜,然后所述配向膜会沿着所述紫外偏振光的入射方向而倾倒,亦即,可以通过控制不同的入射光的方向,来控制配向膜的配向方向,从而控制液晶的倒向,如图3所示。
在步骤S14中,提供至少一种极性液晶单体和至少一种非极性液晶单体,且混合所述极性液晶单体及所述非极性液晶单体,而后填充在所述第一基板10及所述第二基板20之间,形成一液晶层30。所述液晶层30接触所述第一配向膜和所述第二配向膜。所述液晶层30的液晶分子为负性液晶,且所述液晶层的液晶分子的介电常数(△ε)在20℃下是介于-2.1~-2.5之间。
通过执行上述步骤S11至S14,即可制作出本发明的彩色滤光片整合晶体管式液晶面板。
请参照表1,其是本发明的具体实例中不同液晶配方的介电常数(△ε)。具有单体A~C和单体a~d的液晶混合物LC-1的介电常数(△ε)为-3.5。具有单体A~E和单体a~b的液晶混合物LC-2的介电常数(△ε)为-2.7。具有单体A~C及E和单体a~b及d的液晶混合物LC-3的介电常数(△ε)为-2.1。因此,可以得知,通过液晶配方的调整(亦即,不同的极性液晶单体和不同的非极性液晶单体的选取),可以获得不同的介电常数(△ε)。另外,也可通过调整单体的含量来控制其介电常数(△ε)。
[表1]
接着,请参照图4,其是表4的不同液晶配方的影像残留表现。在此,以不同时间的JND表示。JND无时以1.7表示,其是最佳。JND数值越大,影像残留表现越差。从图4中可以看出随着介电常数(△ε)变大,影像残留表现越来越好。因此,可以得知,通过控制液晶的介电常数(△ε)可以改善液晶的影像残留表现。
如上所述,本发明的彩色滤光片整合晶体管式液晶面板及其制造方法是通过以紫外线诱导多区域垂直配向(UV2A)的光配向技术形成所述彩色滤光片整合晶体管式液晶面板中的配向膜,以及通过控制所述彩色滤光片整合晶体管式液晶面板中液晶层的液晶分子的介电常数(△ε),来改进现有彩色滤光片整合晶体管式液晶显示器的影像残留的问题。
本发明已由上述相关实施例加以描述,然而上述实施例仅为实施本发明的范例。必需指出的是,已公开的实施例并未限制本发明的范围。相反地,包含于权利要求书的精神及范围的修改及均等设置均包括于本发明的范围内。
Claims (12)
1.一种彩色滤光片整合晶体管式(ColorfilteronArray,COA)液晶面板,其特征在于,包含:
一第一基板,具有一第一配向膜,所述第一基板包含:
一透明基板;
一薄膜晶体管阵列层,设置于所述透明基板上;以及
一彩色滤光层,设置于所述薄膜晶体管阵列层上;
一第二基板,具有一第二配向膜,所述第一基板与第二基板相对设置;以及
一液晶层,夹设于所述第一基板与所述第二基板之间,且所述液晶层接触所述第一配向膜和所述第二配向膜,所述液晶层包含至少一种极性液晶单体和至少一种非极性液晶单体,
其中由一偏振光敏感材料构成的所述第一及第二配向膜是通过紫外线诱导多区域垂直配向(ultravioletinducedmulti-domainverticalalignment,UV2A)的光配向技术而形成的。
2.根据权利要求1所述的彩色滤光片整合晶体管式液晶面板,其特征在于,所述液晶层的液晶分子为负性液晶。
3.根据权利要求3所述的彩色滤光片整合晶体管式液晶面板,其特征在于,所述液晶层的液晶分子的介电常数(△ε)在20℃下是介于-2.1~-2.5之间。
4.根据权利要求1所述的彩色滤光片整合晶体管式液晶面板,其特征在于,所述偏振光敏感材料为聚酰亚胺材料。
5.根据权利要求4所述的彩色滤光片整合晶体管式液晶面板,其特征在于,所述聚酰亚胺材料的反应波长为313nm。
6.根据权利要求4所述的彩色滤光片整合晶体管式液晶面板,其特征在于,所述聚酰亚胺材料的配向基团包含肉桂酸、香豆素。
7.一种彩色滤光片整合晶体管式(ColorfilteronArray,COA)液晶面板的制造方法,其特征在于,包括以下步骤:
提供一第一基板,所述第一基板包含一透明基板、一设置于所述透明基板上的薄膜晶体管阵列层及一设置于所述薄膜晶体管阵列层上的彩色滤光层;
提供一第二基板;
分别涂布一偏振光敏感材料在所述第一基板及所述第二基板上,而后通过紫外线诱导多区域垂直配向(ultravioletinducedmulti-domainverticalalignment,UV2A)的光配向技术来相应地形成一第一配向膜及一第二配向膜;以及
提供至少一种极性液晶单体和至少一种非极性液晶单体,且混合所述极性液晶单体及所述非极性液晶单体,而后填充在所述第一基板及所述第二基板之间,形成一液晶层,所述液晶层接触所述第一配向膜和所述第二配向膜。
8.根据权利要求8所述的彩色滤光片整合晶体管式液晶面板的制造方法,其特征在于,所述液晶层的液晶分子为负性液晶。
9.根据权利要求9所述的彩色滤光片整合晶体管式液晶面板的制造方法,其特征在于,所述液晶层的液晶分子的介电常数(△ε)在20℃下是介于-2.1~-2.5之间。
10.根据权利要求8所述的彩色滤光片整合晶体管式液晶面板的制造方法,其特征在于,所述偏振光敏感材料为聚酰亚胺材料。
11.根据权利要求10所述的彩色滤光片整合晶体管式液晶面板的制造方法,其特征在于,所述聚酰亚胺材料的反应波长为313nm。
12.根据权利要求10所述的彩色滤光片整合晶体管式液晶面板的制造方法,其特征在于,所述聚酰亚胺材料的配向基团包含肉桂酸、香豆素。
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