CN105086536A - Special high-performance emulsion paint for building external wall - Google Patents
Special high-performance emulsion paint for building external wall Download PDFInfo
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- CN105086536A CN105086536A CN201510472911.9A CN201510472911A CN105086536A CN 105086536 A CN105086536 A CN 105086536A CN 201510472911 A CN201510472911 A CN 201510472911A CN 105086536 A CN105086536 A CN 105086536A
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Abstract
The invention discloses special high-performance emulsion paint for a building external wall. Raw materials of the special high-performance emulsion paint include acrylic emulsion, polyurethane emulsion, bisphenol A epoxy resin, o-cresol-formaldehyde epoxy resin, microencapsulated red phosphorus, tri(2,3-dibromopropyl) borate, boric acid, diphenylsilanediol, gamma-aminopropyl triethoxy silane polymers, filler, dodecafluoroheptyl methacrylate, poly(vinylidene fluoride), coalescing agents, sorbitan monopalmitate, lauric acid, amino resin, N-phenyl-N'-cyclohexyl-p-phenylenediamine, triethanolamine, defoaming agents, hydroxyethyl cellulose, potassium citrate, p-hydroxybenzoic acid, propyl p-hydroxybenzoate, sodium lactate and water. The special high-performance emulsion paint has excellent weather resistance, water resistance and fire resistance, the adhesive force between the special high-performance emulsion paint and a substrate is large, and the substrate decoration performance is good.
Description
Technical field
The present invention relates to emulsion paint technical field, particularly relate to a kind of external wall dedicated high performance emulsion paint.
Background technology
Emulsion paint is water-dispersible paint, and it take synthetic resin emulsion as base-material, and filler adds the coating that various auxiliary agent is refined after grinding distribution.Emulsion paint has possessed the many merits different from conventional wall coating materials, and as being easy to brushing, drying is rapid, paint film is water-fast, scrub resistance is good.
The major function of exterior wall latex paint is decoration and architecture protection object plane, makes buildings appearance neat and artistic, thus reaches the object of beautifying urban environment, can play the effect of architecture protection beyond the region of objective existence wall simultaneously, extend its work-ing life.Exterior wall latex paint service requirements following points: good decorative property, require exterior wall latex paint rich color, and select variation, tint retention is good, the long period can keep good decorate properties; Water-tolerant, exterior wall long-term exposure in an atmosphere, often will be subject to rainwash, and thus exterior wall latex paint must possess good water resistance; After dust in air and other materials stain coating, coating can lose original aesthetic, and thus exterior wall latex paint not easily must be stain or stain rear easy cleaning by these materials; Good weatherability, exposes coating in an atmosphere by under the influence and effect of many weather environment factors, and the phenomenons such as general coating there will be cracking, peels off, shedding, variable color, make it lose original ornamental and protectiveness; Good flame resistance, when presence of fire, spreading of the intensity of a fire can the direct security of the lives and property endangering people.
Emulsion paint is of a great variety in the market, and exterior wall latex paint is also varied, but traditional exterior wall latex paint exist poor water resistance, easy to crack, peel off, shedding, variable color, non-easy cleaning, poor fire defect, thus limit its application.
Summary of the invention
Based on the technical problem that background technology exists, the present invention proposes a kind of external wall dedicated high performance emulsion paint, its weathering resistance, water tolerance and excellent fireproof performance, with the strong adhesion of ground, to the good decorative property of ground.
A kind of external wall dedicated high performance emulsion paint that the present invention proposes, its raw material comprises following component by weight: ACRYLIC EMULSION 40-60 part, polyaminoester emulsion 20-35 part, bisphenol A epoxide resin 10-30 part, o-cresol formaldehyde type epoxy resin 12-20 part, microencapsulated powder oil 1-10 part, boric acid three (2, 3-dibromo) propyl ester 1-5 part, boric acid 1-5 part, diphenyl silanodiol 3-10 part, γ-aminopropyl triethoxysilane polymkeric substance 4-15 part, filler 10-35 part, dodecafluoroheptyl methacrylate 2-10 part, polyvinylidene fluoride resin 3-10 part, film coalescence aid 15-35 part, sorbitol anhydride monopalmitate 5-10 part, lauric acid 2-10 part, aminoresin 1-5 part, N-phenyl-N '-cyclohexyl Ursol D 0.3-2 part, trolamine 1-3 part, defoamer 1-3 part, Natvosol 1-2 part, Tripotassium Citrate 1-2 part, P-hydroxybenzoic acid 1-4 part, propylparaben 2-8 part, Sodium.alpha.-hydroxypropionate 1-8 part, water 50-120 part.
In a particular embodiment, a kind of external wall dedicated high performance emulsion paint that the present invention proposes, in its raw material, the weight part of ACRYLIC EMULSION can be 40,42,43,45,46,48,49,49.3,52,53,54,56,57,58.6,59,59.3,60 parts; The weight part of polyaminoester emulsion can be 20,23,25,26,27,28,28.6,29,29.3,31,32,33,33.6,34,34.5,35 parts; The weight part of bisphenol A epoxide resin can be 10,12,13,15,16,17,18,18.6,19,19.3,23,25,26,27,28,28.6,29,29.3,30 parts; The weight part of o-cresol formaldehyde type epoxy resin can be 12,13,15,16,18,19,19.3,20 parts; The weight part of microencapsulated powder oil can be 1,2,3,4,5,6,6.3,7,8,8.6,9,9.3,10 part; The weight part of boric acid three (2,3-dibromo) propyl ester can be 1,1.3,1.5,1.8,2,2.3,2.7,3,3.4,4,4.6,5 part; The weight part of boric acid can be 1,1.3,1.8,2,2.6,3,3.4,4,4.6,5 part; The weight part of diphenyl silanodiol can be 3,4,5,6,6.3,7,8,8.6,9,9.3,10 parts; The weight part of γ-aminopropyl triethoxysilane polymkeric substance can be 4,5,6,7,8,8.6,9,9.3,10,13,13.4,14,14.6,15 parts; The weight part of filler can be 10,13,15,16,18,19,19.3,23,25,26,28,28.6,29,29.4,31,32,34,34.6,35 parts; The weight part of dodecafluoroheptyl methacrylate can be 2,3,4,5,5.6,6,6.4,7,7.8,8,8.6,9,9.4,10 parts; The weight part of polyvinylidene fluoride resin can be 3,4,5,6,6.3,7,7.8,8,8.6,9,9.3,10 parts; The weight part of film coalescence aid can be 15,16,18,19,19.3,21,23,24,25,26,28,29,29.3,31,32,34,34.6,35 parts; The weight part of sorbitol anhydride monopalmitate can be 5,6,7,8,8.6,9,9.3,10 parts; Lauric weight part can be 2,3,4,5,6,6.3,7,8,8.6,9,9.4,10 parts; The weight part of aminoresin can be 1,1.3,1.8,2,2.6,3,3.4,3.8,4,4.6,5 part; The weight part of N-phenyl-N '-cyclohexyl Ursol D can be 0.3,0.5,0.8,0.9,1,1.3,1.8,2 part; The weight part of trolamine can be 1,1.2,1.56,1.8,2,2.3,2.8,3 part; The weight part of defoamer can be 1,1.2,1.5,1.86,2,2.3,2.6,2.68,3 part; The weight part of Natvosol can be 1,1.2,1.5,1.86,1.9,2 part; The weight part of Tripotassium Citrate can be 1,1.2,1.3,1.56,1.8,1.86,1.9,1.94,2 part; The weight part of P-hydroxybenzoic acid can be 1,1.2,1.56,1.6,1.68,2,2.3,2.8,3,3.4,4 part; The weight part of propylparaben can be 2,3,4,5,5.6,6,6.7,7,7.4,8 parts; The weight part of Sodium.alpha.-hydroxypropionate can be 1,1.3,1.8,2,2.6,3,3.4,4,4.6,5,5.3,6,6.7,7,7.8,8 part; The weight part of water can be 50,53,56,58,61,65,68,72,75,78,78.6,79,86,89,94,97,98,103,108,112,116,116.8,119.3,120 parts.
Preferably, in its raw material, the weight ratio of ACRYLIC EMULSION, polyaminoester emulsion, bisphenol A epoxide resin, o-cresol formaldehyde type epoxy resin is 45-56:26-33:17-25:16-20.
Preferably, its raw material comprises following component by weight: ACRYLIC EMULSION 50-54 part, polyaminoester emulsion 28-31 part, bisphenol A epoxide resin 19-23 part, o-cresol formaldehyde type epoxy resin 17-20 part, microencapsulated powder oil 6-10 part, boric acid three (2, 3-dibromo) propyl ester 2-4 part, boric acid 3-4 part, diphenyl silanodiol 6-10 part, γ-aminopropyl triethoxysilane polymkeric substance 8-12 part, filler 20-30 part, dodecafluoroheptyl methacrylate 7-9 part, polyvinylidene fluoride resin 6-8 part, film coalescence aid 26-30 part, sorbitol anhydride monopalmitate 7-9 part, lauric acid 7-8 part, aminoresin 3-4.5 part, N-phenyl-N '-cyclohexyl Ursol D 1-1.4 part, trolamine 2-2.6 part, defoamer 2-2.3 part, Natvosol 1.3-1.7 part, Tripotassium Citrate 1.4-1.7 part, P-hydroxybenzoic acid 2-2.4 part, propylparaben 3-3.8 part, Sodium.alpha.-hydroxypropionate 4-4.6 part, water 89-94 part.
Preferably, described ACRYLIC EMULSION is one or more the combination in pure-acrylic emulsion, benzene emulsion, organosilicon crylic acid latex, acrylate and vinyl acetate emulsion.
Preferably, described filler is mixed by the magnesium hydroxide of 10-20 weight part, the aluminium hydroxide of 4-15 weight part, the pearlstone of 5-15 weight part, the Nano silica sol of 2-10 weight part, the asbestos powder of 3-15 weight part, the nano titanium oxide of 10-25 weight part, the red iron oxide of 2-10 weight part; Magnesium hydroxide and aluminium hydroxide join in system, have synergistic flame retardant resistance; Nano silica sol has the ultraviolet performance of absorption, add in system, coordinate according to the above ratio with pearlstone, asbestos powder, nano titanium oxide, red iron oxide, magnesium hydroxide and aluminium hydroxide, the sticking power of emulsion paint can be improved, and make emulsion paint have characteristic that is water-fast, resistant, the weathering resistance of emulsion paint can also be improved.
Preferably, described filler is mixed by the magnesium hydroxide of 16 weight parts, the aluminium hydroxide of 8 weight parts, the pearlstone of 7 weight parts, the Nano silica sol of 6 weight parts, the asbestos powder of 10 weight parts, the nano titanium oxide of 16 weight parts, the red iron oxide of 5 weight parts.
Preferably, described aluminium hydroxide is nano-aluminum hydroxide, and the median size of described nano-aluminum hydroxide is 15-25nm; The median size of described Nano silica sol is 10-20nm; The median size of described nano titanium oxide is 15-35nm.
Preferably, described film coalescence aid is one or more the combination in ethylene glycol, propylene glycol, hexylene glycol, lauric acid alcohol, glycol ether, propylene-glycol ethyl ether, butyl glycol ether, propandiol butyl ether, ethylene glycol phenyl ether, turps, kautschin, perhydronaphthalene, phenylcarbinol, di-isopropyl succinate, butyl carbitol acetate.
Preferably, described film coalescence aid is mixed by the ethylene glycol of 1-3 weight part, the lauric acid alcohol of 1-3 weight part, the glycol ether of 3-8 weight part, the propylene-glycol ethyl ether of 1-4 weight part, the butyl glycol ether of 2-6 weight part, the ethylene glycol phenyl ether of 3-10 weight part, the kautschin of 1-4 weight part, the perhydronaphthalene of 4-10 weight part, the di-isopropyl succinate of 1-3 weight part, the butyl carbitol acetate of 2-5 weight part; Each film coalescence aid coordinates according to the above ratio, join in emulsion paint, consistency is good, and performance is worked in coordination with, and has suitable evaporation rate in emulsion paint, reduce the second-order transition temperature of system on the one hand, emulsion particle is out of shape easier, improves the cohesion degree of emulsion particle, soaking between emulsion polymer and each raw material, improve the film-forming properties of emulsion paint, improve the density of film, improve the scrub resistance of emulsion film; Impel latex particle to form complete film on the one hand, decrease the migration of water and corrosive ions, improve the Corrosion Protection of emulsion paint; On the other hand, improve the frost resistance of film.
Preferably, described film coalescence aid is mixed by the ethylene glycol of 1.7 weight parts, the lauric acid alcohol of 2 weight parts, the glycol ether of 5 weight parts, the propylene-glycol ethyl ether of 1 weight part, the butyl glycol ether of 3 weight parts, the ethylene glycol phenyl ether of 5 weight parts, the kautschin of 4 weight parts, the perhydronaphthalene of 8 weight parts, the di-isopropyl succinate of 2 weight parts, the butyl carbitol acetate of 3.7 weight parts.
External wall dedicated high performance emulsion paint of the present invention can emulsion paint preparation technology conveniently be prepared from.
In the present invention, have selected ACRYLIC EMULSION, polyaminoester emulsion, bisphenol A epoxide resin and o-cresol formaldehyde type epoxy resin and coordinate filmogen as emulsion paint according to a certain percentage, give weathering resistance, water tolerance, the erosion resistance of coating excellence, and improve the cohesive force of film, reduce the shrinking percentage of film; Microencapsulated powder oil, boric acid three (2,3-dibromo) propyl ester, boric acid, γ-aminopropyl triethoxysilane polymkeric substance joins in coating has synergistic effect, flame retarding efficiency is high, and water-wash resistance is strong, avoid the shortcoming of single fire retardant poor water resistance, improve flame retardant resistance and the water tolerance of emulsion paint; Diphenyl silanodiol joins in coating, has mating reaction with bisphenol A epoxide resin and o-cresol formaldehyde type epoxy resin, can form the epoxy resin containing element silicon, add in system, further increase the flame retardant resistance of emulsion paint; Dodecafluoroheptyl methacrylate and polyvinylidene fluoride resin complex join in system, good with the consistency of raw material each in system, owing to introducing fluorine element, improve the water tolerance of emulsion paint; N-phenyl-N '-cyclohexyl Ursol D joins in emulsion paint, coordinate with aminoresin and trolamine, while making emulsion paint solidify, improve ageing resistance and the weathering resistance of emulsion paint, and between trolamine and boric acid, there is interaction, further improve the flame retardant resistance of emulsion paint; The cooperation of P-hydroxybenzoic acid, propylparaben, Sodium.alpha.-hydroxypropionate joins in emulsion paint, coordinates, improve germ resistance and the resistance to soiling of emulsion paint, improve the weathering resistance of emulsion paint with filler.
Carry out Performance Detection to external wall dedicated high performance emulsion paint of the present invention, detected result is as follows: surface drying time is 1-3h; The time of doing solid work is 10-13h; Sticking power is 1-2 level; Snappiness is 2-3mm; Impact strength is 28-32kg.cm; 24h water tolerance, peels off without wrinkling, nothing; 48h humidity resistance, peels off without wrinkling, nothing; Resistance to combustion time 22-35min; Flame propagation ratio is 11-15; Mass loss is 2-3.5g; Char volume is 19-21cm
3; Scrub for resistance to 3000-3500 time; Artificial weathering ageing resistance 900-1000h passes through.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
A kind of external wall dedicated high performance emulsion paint that the present invention proposes, its raw material comprises following component by weight: ACRYLIC EMULSION 40 parts, polyaminoester emulsion 35 parts, bisphenol A epoxide resin 10 parts, o-cresol formaldehyde type epoxy resin 20 parts, microencapsulated powder oil 1 part, boric acid three (2, 3-dibromo) propyl ester 5 parts, boric acid 1 part, diphenyl silanodiol 10 parts, 15 parts, γ-aminopropyl triethoxysilane polymkeric substance, filler 10 parts, dodecafluoroheptyl methacrylate 10 parts, polyvinylidene fluoride resin 3 parts, film coalescence aid 35 parts, sorbitol anhydride monopalmitate 5 parts, lauric acid 10 parts, 1 part, aminoresin, N-phenyl-N '-cyclohexyl Ursol D 2 parts, trolamine 1 part, defoamer 1 part, Natvosol 1 part, Tripotassium Citrate 2 parts, P-hydroxybenzoic acid 1 part, propylparaben 8 parts, Sodium.alpha.-hydroxypropionate 1 part, 120 parts, water,
Wherein, described film coalescence aid is mixed by the ethylene glycol of 1 weight part, the lauric acid alcohol of 1 weight part, the glycol ether of 8 weight parts, the propylene-glycol ethyl ether of 1 weight part, the butyl glycol ether of 6 weight parts, the ethylene glycol phenyl ether of 3 weight parts, the kautschin of 4 weight parts, the perhydronaphthalene of 4 weight parts, the di-isopropyl succinate of 3 weight parts, the butyl carbitol acetate of 2 weight parts.
Embodiment 2
A kind of external wall dedicated high performance emulsion paint that the present invention proposes, its raw material comprises following component by weight: pure-acrylic emulsion 60 parts, polyaminoester emulsion 20 parts, bisphenol A epoxide resin 30 parts, o-cresol formaldehyde type epoxy resin 12 parts, microencapsulated powder oil 10 parts, boric acid three (2, 3-dibromo) propyl ester 1 part, boric acid 5 parts, diphenyl silanodiol 3 parts, 4 parts, γ-aminopropyl triethoxysilane polymkeric substance, filler 35 parts, dodecafluoroheptyl methacrylate 2 parts, polyvinylidene fluoride resin 10 parts, film coalescence aid 15 parts, sorbitol anhydride monopalmitate 10 parts, lauric acid 2 parts, 5 parts, aminoresin, N-phenyl-N '-cyclohexyl Ursol D 0.3 part, trolamine 3 parts, defoamer 3 parts, Natvosol 2 parts, Tripotassium Citrate 1 part, P-hydroxybenzoic acid 4 parts, propylparaben 2 parts, Sodium.alpha.-hydroxypropionate 8 parts, 50 parts, water,
Wherein, described film coalescence aid is mixed by the ethylene glycol of 3 weight parts, the lauric acid alcohol of 3 weight parts, the glycol ether of 3 weight parts, the propylene-glycol ethyl ether of 4 weight parts, the butyl glycol ether of 2 weight parts, the ethylene glycol phenyl ether of 10 weight parts, the kautschin of 1 weight part, the perhydronaphthalene of 10 weight parts, the di-isopropyl succinate of 1 weight part, the butyl carbitol acetate of 5 weight parts.
Embodiment 3
A kind of external wall dedicated high performance emulsion paint that the present invention proposes, its raw material comprises following component by weight: benzene emulsion 30 parts, organosilicon crylic acid latex 24 parts, polyaminoester emulsion 28 parts, bisphenol A epoxide resin 23 parts, o-cresol formaldehyde type epoxy resin 17 parts, microencapsulated powder oil 10 parts, boric acid three (2, 3-dibromo) propyl ester 2 parts, boric acid 4 parts, diphenyl silanodiol 6 parts, 8 parts, γ-aminopropyl triethoxysilane polymkeric substance, filler 30 parts, dodecafluoroheptyl methacrylate 7 parts, polyvinylidene fluoride resin 8 parts, film coalescence aid 26 parts, sorbitol anhydride monopalmitate 9 parts, lauric acid 7 parts, 4.5 parts, aminoresin, N-phenyl-N '-cyclohexyl Ursol D 1 part, trolamine 2.6 parts, defoamer 2 parts, Natvosol 1.7 parts, Tripotassium Citrate 1.4 parts, P-hydroxybenzoic acid 2.4 parts, propylparaben 3 parts, Sodium.alpha.-hydroxypropionate 4.6 parts, 89 parts, water,
Wherein, described filler is mixed by the magnesium hydroxide of 10 weight parts, the aluminium hydroxide of 15 weight parts, the pearlstone of 5 weight parts, the Nano silica sol of 10 weight parts, the asbestos powder of 3 weight parts, the nano titanium oxide of 25 weight parts, the red iron oxide of 2 weight parts;
Described aluminium hydroxide is nano-aluminum hydroxide, and the median size of described nano-aluminum hydroxide is 15nm; The median size of described Nano silica sol is 10nm; The median size of described nano titanium oxide is 35nm;
Described film coalescence aid is mixed by the ethylene glycol of 1.7 weight parts, the lauric acid alcohol of 2 weight parts, the glycol ether of 5 weight parts, the propylene-glycol ethyl ether of 1 weight part, the butyl glycol ether of 3 weight parts, the ethylene glycol phenyl ether of 5 weight parts, the kautschin of 4 weight parts, the perhydronaphthalene of 8 weight parts, the di-isopropyl succinate of 2 weight parts, the butyl carbitol acetate of 3.7 weight parts.
Embodiment 4
A kind of external wall dedicated high performance emulsion paint that the present invention proposes, its raw material comprises following component by weight: pure-acrylic emulsion 20 parts, benzene emulsion 10 parts, organosilicon crylic acid latex 15 parts, acrylate and vinyl acetate emulsion 5 parts, polyaminoester emulsion 31 parts, bisphenol A epoxide resin 19 parts, o-cresol formaldehyde type epoxy resin 20 parts, microencapsulated powder oil 6 parts, boric acid three (2, 3-dibromo) propyl ester 4 parts, boric acid 3 parts, diphenyl silanodiol 10 parts, 12 parts, γ-aminopropyl triethoxysilane polymkeric substance, filler 20 parts, dodecafluoroheptyl methacrylate 9 parts, polyvinylidene fluoride resin 6 parts, perhydronaphthalene 12 parts, phenylcarbinol 8 parts, di-isopropyl succinate 10 parts, sorbitol anhydride monopalmitate 7 parts, lauric acid 8 parts, 3 parts, aminoresin, N-phenyl-N '-cyclohexyl Ursol D 1.4 parts, trolamine 2 parts, defoamer 2.3 parts, Natvosol 1.3 parts, Tripotassium Citrate 1.7 parts, P-hydroxybenzoic acid 2 parts, propylparaben 3.8 parts, Sodium.alpha.-hydroxypropionate 4 parts, 94 parts, water,
Wherein, described filler is mixed by the magnesium hydroxide of 20 weight parts, the aluminium hydroxide of 4 weight parts, the pearlstone of 15 weight parts, the Nano silica sol of 2 weight parts, the asbestos powder of 15 weight parts, the nano titanium oxide of 10 weight parts, the red iron oxide of 10 weight parts;
Described aluminium hydroxide is nano-aluminum hydroxide, and the median size of described nano-aluminum hydroxide is 25nm; The median size of described Nano silica sol is 20nm; The median size of described nano titanium oxide is 15nm;
Embodiment 5
A kind of external wall dedicated high performance emulsion paint that the present invention proposes, its raw material comprises following component by weight: ACRYLIC EMULSION 53 parts, polyaminoester emulsion 30 parts, bisphenol A epoxide resin 27 parts, o-cresol formaldehyde type epoxy resin 18 parts, microencapsulated powder oil 6 parts, boric acid three (2, 3-dibromo) propyl ester 3 parts, boric acid 2 parts, diphenyl silanodiol 7 parts, 11 parts, γ-aminopropyl triethoxysilane polymkeric substance, filler 30 parts, dodecafluoroheptyl methacrylate 7 parts, polyvinylidene fluoride resin 6 parts, butyl glycol ether 22 parts, sorbitol anhydride monopalmitate 8 parts, lauric acid 6 parts, 4 parts, aminoresin, N-phenyl-N '-cyclohexyl Ursol D 1.6 parts, trolamine 2.3 parts, defoamer 1.8 parts, Natvosol 1.6 parts, Tripotassium Citrate 1.3 parts, P-hydroxybenzoic acid 2.6 parts, propylparaben 6 parts, Sodium.alpha.-hydroxypropionate 5 parts, 105 parts, water,
Wherein, described filler is mixed by the magnesium hydroxide of 16 weight parts, the aluminium hydroxide of 8 weight parts, the pearlstone of 7 weight parts, the Nano silica sol of 6 weight parts, the asbestos powder of 10 weight parts, the nano titanium oxide of 16 weight parts, the red iron oxide of 5 weight parts;
Described aluminium hydroxide is nano-aluminum hydroxide, and the median size of described nano-aluminum hydroxide is 19nm; The median size of described Nano silica sol is 17nm; The median size of described nano titanium oxide is 20nm.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (10)
1. an external wall dedicated high performance emulsion paint, it is characterized in that, its raw material comprises following component by weight: ACRYLIC EMULSION 40-60 part, polyaminoester emulsion 20-35 part, bisphenol A epoxide resin 10-30 part, o-cresol formaldehyde type epoxy resin 12-20 part, microencapsulated powder oil 1-10 part, boric acid three (2, 3-dibromo) propyl ester 1-5 part, boric acid 1-5 part, diphenyl silanodiol 3-10 part, γ-aminopropyl triethoxysilane polymkeric substance 4-15 part, filler 10-35 part, dodecafluoroheptyl methacrylate 2-10 part, polyvinylidene fluoride resin 3-10 part, film coalescence aid 15-35 part, sorbitol anhydride monopalmitate 5-10 part, lauric acid 2-10 part, aminoresin 1-5 part, N-phenyl-N '-cyclohexyl Ursol D 0.3-2 part, trolamine 1-3 part, defoamer 1-3 part, Natvosol 1-2 part, Tripotassium Citrate 1-2 part, P-hydroxybenzoic acid 1-4 part, propylparaben 2-8 part, Sodium.alpha.-hydroxypropionate 1-8 part, water 50-120 part.
2. external wall dedicated high performance emulsion paint according to claim 1, it is characterized in that, in its raw material, the weight ratio of ACRYLIC EMULSION, polyaminoester emulsion, bisphenol A epoxide resin, o-cresol formaldehyde type epoxy resin is 45-56:26-33:17-25:16-20.
3. external wall dedicated high performance emulsion paint according to claim 1 or 2, it is characterized in that, its raw material comprises following component by weight: ACRYLIC EMULSION 50-54 part, polyaminoester emulsion 28-31 part, bisphenol A epoxide resin 19-23 part, o-cresol formaldehyde type epoxy resin 17-20 part, microencapsulated powder oil 6-10 part, boric acid three (2,3-dibromo) propyl ester 2-4 part, boric acid 3-4 part, diphenyl silanodiol 6-10 part, γ-aminopropyl triethoxysilane polymkeric substance 8-12 part, filler 20-30 part, dodecafluoroheptyl methacrylate 7-9 part, polyvinylidene fluoride resin 6-8 part, film coalescence aid 26-30 part, sorbitol anhydride monopalmitate 7-9 part, lauric acid 7-8 part, aminoresin 3-4.5 part, N-phenyl-N '-cyclohexyl Ursol D 1-1.4 part, trolamine 2-2.6 part, defoamer 2-2.3 part, Natvosol 1.3-1.7 part, Tripotassium Citrate 1.4-1.7 part, P-hydroxybenzoic acid 2-2.4 part, propylparaben 3-3.8 part, Sodium.alpha.-hydroxypropionate 4-4.6 part, water 89-94 part.
4. external wall dedicated high performance emulsion paint according to any one of claim 1-3, is characterized in that, described ACRYLIC EMULSION is one or more the combination in pure-acrylic emulsion, benzene emulsion, organosilicon crylic acid latex, acrylate and vinyl acetate emulsion.
5. external wall dedicated high performance emulsion paint according to any one of claim 1-4, it is characterized in that, described filler is mixed by the magnesium hydroxide of 10-20 weight part, the aluminium hydroxide of 4-15 weight part, the pearlstone of 5-15 weight part, the Nano silica sol of 2-10 weight part, the asbestos powder of 3-15 weight part, the nano titanium oxide of 10-25 weight part, the red iron oxide of 2-10 weight part.
6. external wall dedicated high performance emulsion paint according to any one of claim 1-5, it is characterized in that, described filler is mixed by the magnesium hydroxide of 16 weight parts, the aluminium hydroxide of 8 weight parts, the pearlstone of 7 weight parts, the Nano silica sol of 6 weight parts, the asbestos powder of 10 weight parts, the nano titanium oxide of 16 weight parts, the red iron oxide of 5 weight parts.
7. external wall dedicated high performance emulsion paint according to any one of claim 1-6, is characterized in that, described aluminium hydroxide is nano-aluminum hydroxide, and the median size of described nano-aluminum hydroxide is 15-25nm; The median size of described Nano silica sol is 10-20nm; The median size of described nano titanium oxide is 15-35nm.
8. external wall dedicated high performance emulsion paint according to any one of claim 1-7, it is characterized in that, described film coalescence aid is one or more the combination in ethylene glycol, propylene glycol, hexylene glycol, lauric acid alcohol, glycol ether, propylene-glycol ethyl ether, butyl glycol ether, propandiol butyl ether, ethylene glycol phenyl ether, turps, kautschin, perhydronaphthalene, phenylcarbinol, di-isopropyl succinate, butyl carbitol acetate.
9. external wall dedicated high performance emulsion paint according to any one of claim 1-8, it is characterized in that, described film coalescence aid is mixed by the ethylene glycol of 1-3 weight part, the lauric acid alcohol of 1-3 weight part, the glycol ether of 3-8 weight part, the propylene-glycol ethyl ether of 1-4 weight part, the butyl glycol ether of 2-6 weight part, the ethylene glycol phenyl ether of 3-10 weight part, the kautschin of 1-4 weight part, the perhydronaphthalene of 4-10 weight part, the di-isopropyl succinate of 1-3 weight part, the butyl carbitol acetate of 2-5 weight part.
10. external wall dedicated high performance emulsion paint according to any one of claim 1-9, it is characterized in that, described film coalescence aid is mixed by the ethylene glycol of 1.7 weight parts, the lauric acid alcohol of 2 weight parts, the glycol ether of 5 weight parts, the propylene-glycol ethyl ether of 1 weight part, the butyl glycol ether of 3 weight parts, the ethylene glycol phenyl ether of 5 weight parts, the kautschin of 4 weight parts, the perhydronaphthalene of 8 weight parts, the di-isopropyl succinate of 2 weight parts, the butyl carbitol acetate of 3.7 weight parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510472911.9A CN105086536A (en) | 2015-08-05 | 2015-08-05 | Special high-performance emulsion paint for building external wall |
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| CN105838212A (en) * | 2016-04-11 | 2016-08-10 | 江苏建筑职业技术学院 | Water-proof anticorrosive coating |
| CN106221354A (en) * | 2016-08-19 | 2016-12-14 | 袁中良 | A kind of multi-functional coalescents and preparation method and application |
| CN106590295A (en) * | 2016-11-07 | 2017-04-26 | 芜湖市鸿坤汽车零部件有限公司 | Silane modified antibacterial leather coating and preparation method thereof |
| CN107892847A (en) * | 2017-12-05 | 2018-04-10 | 安徽建邦建材有限公司 | A kind of exterior wall acrylic coating not easy to crack |
| CN107903744A (en) * | 2017-12-12 | 2018-04-13 | 佛山早稻田科技服务有限公司 | A kind of environment friendly emulsion paint |
| CN108929601A (en) * | 2018-06-19 | 2018-12-04 | 佛山市高明区首邦化工有限公司 | A kind of preparation method of antibiotic emulsion paint |
| CN109111836A (en) * | 2018-07-13 | 2019-01-01 | 贵州紫云月华新材料有限公司 | A kind of production method of modified internal and external wall coating |
| CN110845953A (en) * | 2019-10-31 | 2020-02-28 | 青川源泰建材科技有限公司 | Exterior wall environment-friendly coating and preparation method thereof |
| CN111466418A (en) * | 2020-04-30 | 2020-07-31 | 国网河南省电力公司镇平县供电公司 | Reflective slow-release bird repellent composition and preparation method thereof |
| CN113683928A (en) * | 2021-08-24 | 2021-11-23 | 广东美涂士建材股份有限公司 | High-strength primer for building exterior wall |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105838212A (en) * | 2016-04-11 | 2016-08-10 | 江苏建筑职业技术学院 | Water-proof anticorrosive coating |
| CN106221354A (en) * | 2016-08-19 | 2016-12-14 | 袁中良 | A kind of multi-functional coalescents and preparation method and application |
| CN106590295A (en) * | 2016-11-07 | 2017-04-26 | 芜湖市鸿坤汽车零部件有限公司 | Silane modified antibacterial leather coating and preparation method thereof |
| CN107892847A (en) * | 2017-12-05 | 2018-04-10 | 安徽建邦建材有限公司 | A kind of exterior wall acrylic coating not easy to crack |
| CN107903744A (en) * | 2017-12-12 | 2018-04-13 | 佛山早稻田科技服务有限公司 | A kind of environment friendly emulsion paint |
| CN108929601A (en) * | 2018-06-19 | 2018-12-04 | 佛山市高明区首邦化工有限公司 | A kind of preparation method of antibiotic emulsion paint |
| CN109111836A (en) * | 2018-07-13 | 2019-01-01 | 贵州紫云月华新材料有限公司 | A kind of production method of modified internal and external wall coating |
| CN110845953A (en) * | 2019-10-31 | 2020-02-28 | 青川源泰建材科技有限公司 | Exterior wall environment-friendly coating and preparation method thereof |
| CN111466418A (en) * | 2020-04-30 | 2020-07-31 | 国网河南省电力公司镇平县供电公司 | Reflective slow-release bird repellent composition and preparation method thereof |
| CN111466418B (en) * | 2020-04-30 | 2021-09-24 | 国网河南省电力公司镇平县供电公司 | Reflective slow-release bird repellent composition and preparation method thereof |
| CN113683928A (en) * | 2021-08-24 | 2021-11-23 | 广东美涂士建材股份有限公司 | High-strength primer for building exterior wall |
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Application publication date: 20151125 |