CN105062264A - Fireproof emulsion paint - Google Patents
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- CN105062264A CN105062264A CN201510474083.2A CN201510474083A CN105062264A CN 105062264 A CN105062264 A CN 105062264A CN 201510474083 A CN201510474083 A CN 201510474083A CN 105062264 A CN105062264 A CN 105062264A
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Abstract
The invention discloses fireproof emulsion paint. The fireproof emulsion paint comprises acrylic acid emulsion, polyurethane emulsion, epoxy resin, a fire retardant, expanded perlite, titanium dioxide, nanometer silica sol, silicon powder, nanometer titanium dioxide, zinc trifluoroacetylacetonate, dodecafluoroheptyl methacrylate, a film forming auxiliary agent, sorbitan monopalmitate, lauric acid, an antifoaming agent, hydroxyethyl cellulose, methyl ethyl ketone, N-phenyl-N'-cyclohexyl p-phenylenediamine, potassium citrate, dimethyldiallylammonium chloride and water. The fire retardant comprises dimethyl phosphite, methylvinyldichlorosilane, 3-aminopropyltriethoxysilane, 5-ethyl-5-butyl-2-chloro-1,3,2-dioxaphosphorinane, potassium tripolyphosphate, cetyl pyridinium bromide, decabromodiphenyl ethane, aluminum dihydrogen phosphate, calcium borate, melamine and cyanuric acid. The fireproof emulsion paint has excellent flame resistance, good fire retardancy, good adhesion to a base material and good decorative effects.
Description
Technical field
The present invention relates to emulsion paint technical field, particularly relate to a kind of fireproof emulsion paint.
Background technology
Emulsion paint is water-dispersible paint, and it take synthetic resin emulsion as base-material, and filler adds the coating that various auxiliary agent is refined after grinding distribution.Emulsion paint has possessed the many merits different from conventional wall coating materials, and as being easy to brushing, drying is rapid, paint film is water-fast, scrub resistance is good.Emulsion paint is of a great variety in the market; the production of fireproof emulsion paint has also had certain scale; but in the emulsion paint that numerous fireproof emulsion paint manufacturing enterprises produces; ubiquity flame retardant resistance is not enough; the shortcoming inadequate to the protectiveness of ground; easily come off in the process used, ornamental difference, thus make the application of emulsion paint receive certain restriction.
Summary of the invention
Based on the technical problem that background technology exists, the present invention proposes a kind of fireproof emulsion paint, its excellent fireproof performance, fire line is good, with the strong adhesion of ground, difficult drop-off in the process used is good to the protectiveness of ground.
A kind of fireproof emulsion paint that the present invention proposes, its raw material comprises following component by weight: ACRYLIC EMULSION 50-80 part, polyaminoester emulsion 20-40 part, epoxy resin 10-30 part, fire retardant 20-35 part, pearlstone 3-15 part, titanium dioxide 10-22 part, Nano silica sol 3-10 part, silica flour 8-15 part, nano titanium oxide 10-25 part, trifluoroacetylacetone zinc 3-8 part, dodecafluoroheptyl methacrylate 2-10 part, film coalescence aid 15-40 part, sorbitol anhydride monopalmitate 5-10 part, lauric acid 2-10 part, defoamer 1-3 part, Natvosol 1-2 part, methyl ethyl ketone 1-5 part, N-phenyl-N '-cyclohexyl Ursol D 0.3-2 part, Tripotassium Citrate 1-2 part, dimethyl diallyl ammonium chloride 2-10 part, water 60-100 part,
Wherein, described fire retardant is by dimethylphosphite, the methylvinyldichlorosilane of 10-25 weight part, the APTES of 3-12 weight part, the 5-ethyl-5-butyl-2-chloro-1 of 10-25 weight part of 20-30 weight part, the tricyanic acid composition of the TDE of the Potassium tripolyphosphate of 3,2-dioxaphosphorinane, 3-10 weight part, the bromide sixteen alkyls pyridine of 1-5 weight part, 5-12 weight part, the aluminium dihydrogen phosphate of 3-12 weight part, the lime borate of 5-20 weight part, the trimeric cyanamide of 3-15 weight part and 5-20 weight part.
Preferably, in its raw material, the weight ratio of ACRYLIC EMULSION, polyaminoester emulsion, epoxy resin is 60-72:29-34:20-26.
Preferably, its raw material comprises following component by weight: ACRYLIC EMULSION 66-70 part, polyaminoester emulsion 30-33 part, epoxy resin 21-25 part, fire retardant 27-32 part, pearlstone 6-12 part, titanium dioxide 18-21 part, Nano silica sol 6-9 part, silica flour 10-14 part, nano titanium oxide 18-23 part, trifluoroacetylacetone zinc 5-7 part, dodecafluoroheptyl methacrylate 6-9 part, film coalescence aid 20-30 part, sorbitol anhydride monopalmitate 7-9 part, lauric acid 7-9 part, defoamer 2-2.6 part, Natvosol 1.3-1.8 part, methyl ethyl ketone 3-4.5 part, N-phenyl-N '-cyclohexyl Ursol D 1-1.6 part, Tripotassium Citrate 1.3-1.8 part, dimethyl diallyl ammonium chloride 6-9 part, water 80-87 part.
Preferably, its raw material comprises following component by weight: ACRYLIC EMULSION 68 parts, polyaminoester emulsion 32 parts, epoxy resin 25 parts, fire retardant 30 parts, pearlstone 10 parts, titanium dioxide 20 parts, Nano silica sol 7 parts, silica flour 12 parts, nano titanium oxide 20 parts, 6 parts, trifluoroacetylacetone zinc, dodecafluoroheptyl methacrylate 8 parts, film coalescence aid 23 parts, sorbitol anhydride monopalmitate 8 parts, lauric acid 7.8 parts, defoamer 2.3 parts, Natvosol 1.6 parts, methyl ethyl ketone 4 parts, N-phenyl-N '-cyclohexyl Ursol D 1.3 parts, Tripotassium Citrate 1.6 parts, dimethyl diallyl ammonium chloride 8 parts, 85 parts, water.
Preferably, described fire retardant is by dimethylphosphite, the methylvinyldichlorosilane of 17-21 weight part, the APTES of 7-10 weight part, the 5-ethyl-5-butyl-2-chloro-1 of 18-22 weight part of 23-28 weight part, the tricyanic acid composition of the TDE of the Potassium tripolyphosphate of 3,2-dioxaphosphorinane, 6-9 weight part, the bromide sixteen alkyls pyridine of 2-3.8 weight part, 7-11 weight part, the aluminium dihydrogen phosphate of 6-10 weight part, the lime borate of 10-16 weight part, the trimeric cyanamide of 9-12 weight part and 10-16 weight part.
Preferably, described fire retardant is by dimethylphosphite, the methylvinyldichlorosilane of 20 weight parts, the APTES of 9 weight parts, the 5-ethyl-5-butyl-2-chloro-1 of 20 weight parts of 26 weight parts, the tricyanic acid composition of the TDE of the Potassium tripolyphosphate of 3,2-dioxaphosphorinane, 7 weight parts, the bromide sixteen alkyls pyridine of 3 weight parts, 10 weight parts, the aluminium dihydrogen phosphate of 9 weight parts, the lime borate of 12 weight parts, the trimeric cyanamide of 10 weight parts and 13 weight parts.
Preferably, described ACRYLIC EMULSION is one or more the mixture in pure-acrylic emulsion, benzene emulsion, organosilicon crylic acid latex, acrylate and vinyl acetate emulsion.
Preferably, described epoxy resin is novolac epoxy, and the oxirane value of described novolac epoxy is 0.32-0.5.
Preferably, the median size of described Nano silica sol is 12-18nm; The median size of nano titanium oxide is 10-20nm.
Preferably, described film coalescence aid is one or more the mixture in propylene-glycol ethyl ether, butyl glycol ether, propandiol butyl ether, turps, kautschin, perhydronaphthalene, phenylcarbinol, diisopropyl ester amber acid, butyl carbitol acetate.
Fireproof emulsion paint of the present invention can emulsion paint preparation technology conveniently be prepared from.
In the present invention, have selected ACRYLIC EMULSION, polyaminoester emulsion and epoxy resin and coordinate filmogen as emulsion paint according to a certain percentage, give the weathering resistance of emulsion paint excellence, water tolerance and erosion resistance, and improve the cohesive force of film, reduce the shrinking percentage of film, Nano silica sol has the ultraviolet performance of absorption, join in system, by a certain percentage with pearlstone, titanium dioxide, silica flour, nano titanium oxide, trifluoroacetylacetone zinc coordinates, the sticking power of emulsion paint can be improved, and have water-fast, the characteristic of resistant, further improve the weathering resistance of emulsion paint in addition, it also has heat insulation performance simultaneously, the flame retardant resistance of giving emulsion paint excellence is coordinated with fire retardant, particularly, in fire retardant, have selected dimethylphosphite, methylvinyldichlorosilane, APTES, 5-ethyl-5-butyl-2-chloro-1, 3, 2-dioxaphosphorinane, Potassium tripolyphosphate, bromide sixteen alkyls pyridine, TDE, aluminium dihydrogen phosphate, lime borate, trimeric cyanamide and tricyanic acid coordinate as fire retardant, the performance of each fire retardant is collaborative to be promoted, have heat insulation simultaneously, oxygen barrier, fire-retardant, press down the performance of cigarette, give the flame retardant resistance of emulsion paint excellence, can prevent fires, sorbitol anhydride monopalmitate, lauric acid and dimethyl diallyl ammonium chloride add in system, improve the emulsifying dispersivity of emulsion paint, improve the over-all properties of emulsion paint, and dimethyl diallyl ammonium chloride wherein can with ACRYLIC EMULSION effect, improve the consistency of each raw material, methyl ethyl ketone and N-phenyl-N '-cyclohexyl Ursol D add in system as solidifying agent, shorten the set time of emulsion paint, have age inhibiting effect simultaneously, improve the weathering resistance of emulsion paint, extend the work-ing life of emulsion paint.
Embodiment
In a particular embodiment, a kind of fireproof emulsion paint that the present invention proposes, in its raw material, the weight part of ACRYLIC EMULSION can be 50,53,54,56,58,59,59.3,62,64,67,67.8,69,72,75,78,78.6,79,79.3,80 parts; The weight part of polyaminoester emulsion can be 20,23,24,26,28,29,29.3,31,34,35,36,37,38,38.6,39,39.4,40 parts; The weight part of epoxy resin can be 10,12,15,16,18,18.9,21,24,25,26,27,28,28.6,29,29.3,30 parts; The weight part of fire retardant can be 20,23,24,25,26,28,29,31,32,34,34.6,35 parts; The weight part of pearlstone can be 3,4,5,6,6.3,7,8,9,9.3,10,10.3,11,11.3,12,13,14,15 parts; The weight part of titanium dioxide can be 10,12,13,15,16,18,18.6,19,19.4,20,21,21.3,22 parts; The weight part of Nano silica sol can be 3,4,5,6,6.3,7,7.8,8,8.6,9,9.3,10 parts; The weight part of silica flour can be 8,9,10,10.3,11,11.3,12,12.6,13,13.4,14,14.6,15 parts; The weight part of nano titanium oxide can be 10,12,13,15,16,18,19,19.3,21,23,23.4,24,24.6,25 parts; The weight part of trifluoroacetylacetone zinc can be 3,3.2,3.8,4,4.5,5,5.2,5.8,6,6.3,6.7,7,7.4,8 parts; The weight part of dodecafluoroheptyl methacrylate can be 2,3,4,5,5.6,6,6.3,7,8,8.6,9,9.3,10 parts; The weight part of film coalescence aid can be 15,16,17,18,19,21,23,25,26,28,29,29.3,31,32,34,35,37,38,38.6,39,39.4,40 parts; The weight part of sorbitol anhydride monopalmitate can be 5,6,7,7.5,8,8.6,9,9.3,10 parts; Lauric weight part can be 2,3,4,5,5.3,6,6.3,7,7.4,8,8.6,9,9.4,10 parts; The weight part of defoamer can be 1,1.2,1.8,2,2.3,2.6,2.68,2.8,2.9,2.94,3 part; The weight part of Natvosol can be 1,1.2,1.3,1.58,1.8,1.89,2 part; The weight part of methyl ethyl ketone can be 1,1.6,2,2.3,2.8,3,3.4,4,4.5,4.87,5 part; The weight part of N-phenyl-N '-cyclohexyl Ursol D can be 0.3,0.5,0.8,0.94,1,1.2,1.28,1.5,1.8,1.89,1.9,1.94,2 part; The weight part of Tripotassium Citrate can be 1,1.2,1.3,1.68,1.8,2 part; The weight part of dimethyl diallyl ammonium chloride can be 2,3,4,5,5.6,6,6.3,7,8,8.6,9,9.4,10 parts; The weight part of water can be 60,65,68,69,75,78,79,79.3,84,86,87,89,89.3,91,94,96,97,98.6,100 parts.
Wherein, in described fire retardant, the weight part of dimethylphosphite can be 20,23,24,25,26,28,28.6,30 parts; The weight part of methylvinyldichlorosilane can be 10,12,13,15,16,18,19,19.3,21,23,23.4,24,24.6,25 parts; The weight part of APTES can be 3,4,5,6,6.3,7,8,8.6,9,9.3,10,10.3,11,11.6,12 parts; The weight part of chloro-1,3, the 2-dioxaphosphorinane of 5-ethyl-5-butyl-2-can be 10,12,13,14,15,16,18,18.6,19,19.3,21,23,24,24.6,25 parts; The weight part of Potassium tripolyphosphate can be 3,4,5,6,6.3,7,8,8.6,9,9.3,10 parts; The weight part of bromide sixteen alkyls pyridine can be 1,2,3,3.4,3.8,4,4.2,4.8,5 part; The weight part of TDE can be 5,6,7,8,8.6,9,9.3,10,10.6,11,11.3,12 parts; The weight part of aluminium dihydrogen phosphate can be 3,4,5,6,6.3,7,7.8,8,8.6,9,9.3,10,10.6,11,11.3,12 parts; The weight part of lime borate can be 5,6,7,8,8.6,9,9.3,10,10.6,11,11.3,12,15,16,18,18.6,19,19.3,20 parts; The weight part of trimeric cyanamide can be 3,4,5,6,6.3,7,7.8,8,8.6,9,9.3,10,10.3,11,11.6,12,13,13.5,14,14.6,15; The weight part of tricyanic acid can be 5,6,7,8,8.6,9,9.3,10,10.6,11,11.3,12,15,16,18,19,19.3,20.
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
A kind of fireproof emulsion paint that the present invention proposes, its raw material comprises following component by weight: ACRYLIC EMULSION 50 parts, polyaminoester emulsion 40 parts, epoxy resin 10 parts, fire retardant 35 parts, pearlstone 3 parts, titanium dioxide 22 parts, Nano silica sol 3 parts, silica flour 15 parts, nano titanium oxide 10 parts, 8 parts, trifluoroacetylacetone zinc, dodecafluoroheptyl methacrylate 2 parts, film coalescence aid 40 parts, sorbitol anhydride monopalmitate 5 parts, lauric acid 10 parts, defoamer 1 part, Natvosol 2 parts, methyl ethyl ketone 1 part, N-phenyl-N '-cyclohexyl Ursol D 2 parts, Tripotassium Citrate 1 part, dimethyl diallyl ammonium chloride 10 parts, 60 parts, water,
Wherein, described fire retardant is by methylvinyldichlorosilane, the APTES of 3 weight parts, the 5-ethyl-5-butyl-2-chloro-1 of 25 weight parts of 20 weight part dimethylphosphites, 25 weight parts, the tricyanic acid composition of the TDE of the Potassium tripolyphosphate of 3,2-dioxaphosphorinane, 3 weight parts, the bromide sixteen alkyls pyridine of 5 weight parts, 5 weight parts, the aluminium dihydrogen phosphate of 12 weight parts, the lime borate of 5 weight parts, the trimeric cyanamide of 15 weight parts and 5 weight parts.
Carry out Performance Detection to fireproof emulsion paint described in the present embodiment, detected result is as follows: surface drying time is 1.8h; The time of doing solid work is 11h; Sticking power is 1 grade; Snappiness is 2.5mm; Impact strength is 31kg.cm; 24h water tolerance, peels off without wrinkling, nothing; 48h humidity resistance, peels off without wrinkling, nothing; Resistance to combustion time 32min; Flame propagation ratio is 14; Mass loss is 2.9g; Char volume is 20cm
3; Scrub for resistance to 3400 times; Artificial weathering ageing resistance 900h passes through.
Embodiment 2
A kind of fireproof emulsion paint that the present invention proposes, its raw material comprises following component by weight: acrylate and vinyl acetate emulsion 80 parts, polyaminoester emulsion 20 parts, novolac epoxy 30 parts, fire retardant 20 parts, pearlstone 15 parts, titanium dioxide 10 parts, Nano silica sol 10 parts, silica flour 8 parts, nano titanium oxide 25 parts, 3 parts, trifluoroacetylacetone zinc, dodecafluoroheptyl methacrylate 10 parts, propylene-glycol ethyl ether 3 parts, butyl glycol ether 1 part, propandiol butyl ether 2 parts, 1 part, turps, kautschin 0.6 part, perhydronaphthalene 0.4 part, phenylcarbinol 2 parts, diisopropyl ester amber acid 4 parts, butyl carbitol acetate 1 part, sorbitol anhydride monopalmitate 10 parts, lauric acid 2 parts, defoamer 3 parts, Natvosol 1 part, methyl ethyl ketone 5 parts, N-phenyl-N '-cyclohexyl Ursol D 0.3 part, Tripotassium Citrate 2 parts, dimethyl diallyl ammonium chloride 2 parts, 100 parts, water,
Wherein, the oxirane value of described novolac epoxy is 0.5; The median size of described Nano silica sol is 13nm; The median size of nano titanium oxide is 16nm;
Described fire retardant is by methylvinyldichlorosilane, the APTES of 12 weight parts, the 5-ethyl-5-butyl-2-chloro-1 of 10 weight parts of 30 weight part dimethylphosphites, 10 weight parts, the tricyanic acid composition of the TDE of the Potassium tripolyphosphate of 3,2-dioxaphosphorinane, 10 weight parts, the bromide sixteen alkyls pyridine of 1 weight part, 12 weight parts, the aluminium dihydrogen phosphate of 3 weight parts, the lime borate of 20 weight parts, the trimeric cyanamide of 3 weight parts and 20 weight parts.
Carry out Performance Detection to fireproof emulsion paint described in the present embodiment, detected result is as follows: surface drying time is 1.3h; The time of doing solid work is 8h; Sticking power is 1 grade; Snappiness is 3mm; Impact strength is 32kg.cm; 24h water tolerance, peels off without wrinkling, nothing; 48h humidity resistance, peels off without wrinkling, nothing; Resistance to combustion time 33min; Flame propagation ratio is 11; Mass loss is 3.5g; Char volume is 19cm
3; Scrub for resistance to 3500 times; Artificial weathering ageing resistance 1000h passes through.
Embodiment 3
A kind of fireproof emulsion paint that the present invention proposes, its raw material comprises following component by weight: pure-acrylic emulsion 20 parts, benzene emulsion 30 parts, organosilicon crylic acid latex 5 parts, acrylate and vinyl acetate emulsion 13 parts, polyaminoester emulsion 32 parts, novolac epoxy 25 parts, fire retardant 30 parts, pearlstone 10 parts, titanium dioxide 20 parts, Nano silica sol 7 parts, silica flour 12 parts, nano titanium oxide 20 parts, 6 parts, trifluoroacetylacetone zinc, dodecafluoroheptyl methacrylate 8 parts, 8 parts, turps, kautschin 3 parts, perhydronaphthalene 3 parts, phenylcarbinol 4 parts, diisopropyl ester amber acid 5 parts, sorbitol anhydride monopalmitate 8 parts, lauric acid 7.8 parts, defoamer 2.3 parts, Natvosol 1.6 parts, methyl ethyl ketone 4 parts, N-phenyl-N '-cyclohexyl Ursol D 1.3 parts, Tripotassium Citrate 1.6 parts, dimethyl diallyl ammonium chloride 8 parts, 85 parts, water,
Wherein, the oxirane value of described novolac epoxy is 0.32; The median size of described Nano silica sol is 12nm; The median size of nano titanium oxide is 20nm;
Described fire retardant is by dimethylphosphite, the methylvinyldichlorosilane of 20 weight parts, the APTES of 9 weight parts, the 5-ethyl-5-butyl-2-chloro-1 of 20 weight parts of 26 weight parts, the tricyanic acid composition of the TDE of the Potassium tripolyphosphate of 3,2-dioxaphosphorinane, 7 weight parts, the bromide sixteen alkyls pyridine of 3 weight parts, 10 weight parts, the aluminium dihydrogen phosphate of 9 weight parts, the lime borate of 12 weight parts, the trimeric cyanamide of 10 weight parts and 13 weight parts.
Embodiment 4
A kind of fireproof emulsion paint that the present invention proposes, its raw material comprises following component by weight: pure-acrylic emulsion 66 parts, polyaminoester emulsion 33 parts, novolac epoxy 21 parts, fire retardant 32 parts, pearlstone 6 parts, titanium dioxide 21 parts, Nano silica sol 6 parts, silica flour 14 parts, nano titanium oxide 18 parts, 7 parts, trifluoroacetylacetone zinc, dodecafluoroheptyl methacrylate 6 parts, butyl glycol ether 20 parts, propandiol butyl ether 10 parts, sorbitol anhydride monopalmitate 7 parts, lauric acid 9 parts, defoamer 2 parts, Natvosol 1.8 parts, methyl ethyl ketone 3 parts, N-phenyl-N '-cyclohexyl Ursol D 1.6 parts, Tripotassium Citrate 1.3 parts, dimethyl diallyl ammonium chloride 9 parts, 80 parts, water,
Wherein, the oxirane value of described novolac epoxy is 0.42; The median size of described Nano silica sol is 18nm; The median size of nano titanium oxide is 10nm;
Described fire retardant is by dimethylphosphite, the methylvinyldichlorosilane of 22 weight parts, the APTES of 5 weight parts, the 5-ethyl-5-butyl-2-chloro-1 of 20 weight parts of 23 weight parts, the tricyanic acid composition of the TDE of the Potassium tripolyphosphate of 3,2-dioxaphosphorinane, 6 weight parts, the bromide sixteen alkyls pyridine of 3 weight parts, 8 weight parts, the aluminium dihydrogen phosphate of 10 weight parts, the lime borate of 8 weight parts, the trimeric cyanamide of 6 weight parts and 18 weight parts.
Embodiment 5
A kind of fireproof emulsion paint that the present invention proposes, its raw material comprises following component by weight: benzene emulsion 40 parts, organosilicon crylic acid latex 30 parts, polyaminoester emulsion 30 parts, epoxy resin 25 parts, fire retardant 27 parts, pearlstone 12 parts, titanium dioxide 18 parts, Nano silica sol 9 parts, silica flour 10 parts, nano titanium oxide 23 parts, 5 parts, trifluoroacetylacetone zinc, dodecafluoroheptyl methacrylate 9 parts, propylene-glycol ethyl ether 20 parts, sorbitol anhydride monopalmitate 9 parts, lauric acid 7 parts, defoamer 2.6 parts, Natvosol 1.3 parts, methyl ethyl ketone 4.5 parts, N-phenyl-N '-cyclohexyl Ursol D 1 part, Tripotassium Citrate 1.8 parts, dimethyl diallyl ammonium chloride 6 parts, 87 parts, water,
Wherein, described fire retardant is by dimethylphosphite, the methylvinyldichlorosilane of 17 weight parts, the APTES of 10 weight parts, the 5-ethyl-5-butyl-2-chloro-1 of 16 weight parts of 28 weight parts, the tricyanic acid composition of the TDE of the Potassium tripolyphosphate of 3,2-dioxaphosphorinane, 8 weight parts, the bromide sixteen alkyls pyridine of 4 weight parts, 11 weight parts, the aluminium dihydrogen phosphate of 6 weight parts, the lime borate of 17 weight parts, the trimeric cyanamide of 11 weight parts and 10 weight parts.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (10)
1. a fireproof emulsion paint, it is characterized in that, its raw material comprises following component by weight: ACRYLIC EMULSION 50-80 part, polyaminoester emulsion 20-40 part, epoxy resin 10-30 part, fire retardant 20-35 part, pearlstone 3-15 part, titanium dioxide 10-22 part, Nano silica sol 3-10 part, silica flour 8-15 part, nano titanium oxide 10-25 part, trifluoroacetylacetone zinc 3-8 part, dodecafluoroheptyl methacrylate 2-10 part, film coalescence aid 15-40 part, sorbitol anhydride monopalmitate 5-10 part, lauric acid 2-10 part, defoamer 1-3 part, Natvosol 1-2 part, methyl ethyl ketone 1-5 part, N-phenyl-N '-cyclohexyl Ursol D 0.3-2 part, Tripotassium Citrate 1-2 part, dimethyl diallyl ammonium chloride 2-10 part, water 60-100 part,
Wherein, described fire retardant is by dimethylphosphite, the methylvinyldichlorosilane of 10-25 weight part, the APTES of 3-12 weight part, the 5-ethyl-5-butyl-2-chloro-1 of 10-25 weight part of 20-30 weight part, the tricyanic acid composition of the TDE of the Potassium tripolyphosphate of 3,2-dioxaphosphorinane, 3-10 weight part, the bromide sixteen alkyls pyridine of 1-5 weight part, 5-12 weight part, the aluminium dihydrogen phosphate of 3-12 weight part, the lime borate of 5-20 weight part, the trimeric cyanamide of 3-15 weight part and 5-20 weight part.
2. fireproof emulsion paint according to claim 1, it is characterized in that, in its raw material, the weight ratio of ACRYLIC EMULSION, polyaminoester emulsion, epoxy resin is 60-72:29-34:20-26.
3. fireproof emulsion paint according to claim 1 or 2, it is characterized in that, its raw material comprises following component by weight: ACRYLIC EMULSION 66-70 part, polyaminoester emulsion 30-33 part, epoxy resin 21-25 part, fire retardant 27-32 part, pearlstone 6-12 part, titanium dioxide 18-21 part, Nano silica sol 6-9 part, silica flour 10-14 part, nano titanium oxide 18-23 part, trifluoroacetylacetone zinc 5-7 part, dodecafluoroheptyl methacrylate 6-9 part, film coalescence aid 20-30 part, sorbitol anhydride monopalmitate 7-9 part, lauric acid 7-9 part, defoamer 2-2.6 part, Natvosol 1.3-1.8 part, methyl ethyl ketone 3-4.5 part, N-phenyl-N '-cyclohexyl Ursol D 1-1.6 part, Tripotassium Citrate 1.3-1.8 part, dimethyl diallyl ammonium chloride 6-9 part, water 80-87 part.
4. fireproof emulsion paint according to any one of claim 1-3, it is characterized in that, its raw material comprises following component by weight: ACRYLIC EMULSION 68 parts, polyaminoester emulsion 32 parts, epoxy resin 25 parts, fire retardant 30 parts, pearlstone 10 parts, titanium dioxide 20 parts, Nano silica sol 7 parts, silica flour 12 parts, nano titanium oxide 20 parts, 6 parts, trifluoroacetylacetone zinc, dodecafluoroheptyl methacrylate 8 parts, film coalescence aid 23 parts, sorbitol anhydride monopalmitate 8 parts, lauric acid 7.8 parts, defoamer 2.3 parts, Natvosol 1.6 parts, methyl ethyl ketone 4 parts, N-phenyl-N '-cyclohexyl Ursol D 1.3 parts, Tripotassium Citrate 1.6 parts, dimethyl diallyl ammonium chloride 8 parts, 85 parts, water.
5. fireproof emulsion paint according to any one of claim 1-4, it is characterized in that, described fire retardant is by the dimethylphosphite of 23-28 weight part, the methylvinyldichlorosilane of 17-21 weight part, the APTES of 7-10 weight part, 5-ethyl-5-butyl-the 2-chloro-1 of 18-22 weight part, 3, 2-dioxaphosphorinane, the Potassium tripolyphosphate of 6-9 weight part, 2-3.8 the bromide sixteen alkyls pyridine of weight part, the TDE of 7-11 weight part, the aluminium dihydrogen phosphate of 6-10 weight part, the lime borate of 10-16 weight part, the trimeric cyanamide of 9-12 weight part and the tricyanic acid composition of 10-16 weight part.
6. fireproof emulsion paint according to any one of claim 1-5, it is characterized in that, described fire retardant is by the dimethylphosphite of 26 weight parts, the methylvinyldichlorosilane of 20 weight parts, the APTES of 9 weight parts, 5-ethyl-5-butyl-the 2-chloro-1 of 20 weight parts, 3, 2-dioxaphosphorinane, the Potassium tripolyphosphate of 7 weight parts, the bromide sixteen alkyls pyridine of 3 weight parts, the TDE of 10 weight parts, the aluminium dihydrogen phosphate of 9 weight parts, the lime borate of 12 weight parts, the trimeric cyanamide of 10 weight parts and the tricyanic acid composition of 13 weight parts.
7. fireproof emulsion paint according to any one of claim 1-6, is characterized in that, described ACRYLIC EMULSION is one or more the mixture in pure-acrylic emulsion, benzene emulsion, organosilicon crylic acid latex, acrylate and vinyl acetate emulsion.
8. fireproof emulsion paint according to any one of claim 1-7, is characterized in that, described epoxy resin is novolac epoxy, and the oxirane value of described novolac epoxy is 0.32-0.5.
9. fireproof emulsion paint according to any one of claim 1-8, is characterized in that, the median size of described Nano silica sol is 12-18nm; The median size of nano titanium oxide is 10-20nm.
10. fireproof emulsion paint according to any one of claim 1-9, it is characterized in that, described film coalescence aid is one or more the mixture in propylene-glycol ethyl ether, butyl glycol ether, propandiol butyl ether, turps, kautschin, perhydronaphthalene, phenylcarbinol, diisopropyl ester amber acid, butyl carbitol acetate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510474083.2A CN105062264A (en) | 2015-08-05 | 2015-08-05 | Fireproof emulsion paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510474083.2A CN105062264A (en) | 2015-08-05 | 2015-08-05 | Fireproof emulsion paint |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105567043A (en) * | 2016-02-19 | 2016-05-11 | 徐冉 | Fireproof paint and preparing method thereof |
| CN105969184A (en) * | 2016-05-26 | 2016-09-28 | 合肥市田源精铸有限公司 | Low-corrosivity automobile antirust wax |
| CN106280953A (en) * | 2016-08-27 | 2017-01-04 | 安徽省金盾涂料有限责任公司 | A kind of inflaming-retarding antifouling polyurethane coating |
| CN106366740A (en) * | 2016-08-27 | 2017-02-01 | 安徽省金盾涂料有限责任公司 | High-flame-retardancy paint |
| CN106497186A (en) * | 2016-11-29 | 2017-03-15 | 青岛海之星生物科技有限公司 | A kind of flame-proof environmental protection interiro wall latex paint and preparation method thereof |
| CN108102533A (en) * | 2017-12-26 | 2018-06-01 | 龙口德源高分子科技有限公司 | A kind of high performance water proof anti-corrosive paint and preparation method thereof |
| CN109666189A (en) * | 2018-11-14 | 2019-04-23 | 芜湖市元奎新材料科技有限公司 | A kind of preparation process of flame-resistant resin material |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105567043A (en) * | 2016-02-19 | 2016-05-11 | 徐冉 | Fireproof paint and preparing method thereof |
| CN105969184A (en) * | 2016-05-26 | 2016-09-28 | 合肥市田源精铸有限公司 | Low-corrosivity automobile antirust wax |
| CN106280953A (en) * | 2016-08-27 | 2017-01-04 | 安徽省金盾涂料有限责任公司 | A kind of inflaming-retarding antifouling polyurethane coating |
| CN106366740A (en) * | 2016-08-27 | 2017-02-01 | 安徽省金盾涂料有限责任公司 | High-flame-retardancy paint |
| CN106497186A (en) * | 2016-11-29 | 2017-03-15 | 青岛海之星生物科技有限公司 | A kind of flame-proof environmental protection interiro wall latex paint and preparation method thereof |
| CN108102533A (en) * | 2017-12-26 | 2018-06-01 | 龙口德源高分子科技有限公司 | A kind of high performance water proof anti-corrosive paint and preparation method thereof |
| CN109666189A (en) * | 2018-11-14 | 2019-04-23 | 芜湖市元奎新材料科技有限公司 | A kind of preparation process of flame-resistant resin material |
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Application publication date: 20151118 |
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