CN105647328A - Weather-proof high-strength and high-adhesive-force paint - Google Patents
Weather-proof high-strength and high-adhesive-force paint Download PDFInfo
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- CN105647328A CN105647328A CN201610077909.6A CN201610077909A CN105647328A CN 105647328 A CN105647328 A CN 105647328A CN 201610077909 A CN201610077909 A CN 201610077909A CN 105647328 A CN105647328 A CN 105647328A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
- C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
The invention discloses a weather-proof high-strength and high-adhesive-force paint. The weather-proof high-strength and high-adhesive-force paint is prepared from a modified styrene-acrylic emulsion, tri(4-isopropylphenyl)phosphate ammonium polyphosphate, ethylene cellulose, nano-silica, nano-titanium dioxide, carbon nano-tubes, nano-zinc oxide, nano aluminum hydroxide, modified kaolin, modified carbon nano-tubes, kieselguhr, dipentaerythritol, polyethylene glycol, glycol ether, melamine phosphate, a silane coupling agent, a plasticizer, a defoaming agent, a flatting agent, a wetting agent and water. The paint has excellent weather-proof performance, high strength and high adhesive force.
Description
Technical field
The present invention relates to paint field, particularly relate to a kind of weather-resistant and high-strength degree high adhesion paint.
Background technology
After coating is coated in building surface, having function attractive in appearance, coating is in the middle of application, and resistance to impact and adhesive force to coating propose significantly high requirement. Under atrocious weather, along with rainwater is continual, coating top layer being scrubbed, if paint adhesion is poor, coating can produce to fade, problems of crack. Resistance to impact is poor, along with fraction time and extend, the performance of coating also can change. Affect the normal function of coating. Need now to find a kind of coating with weather-resistant and high-strength degree and high adhesion force.
Summary of the invention
For solving the technical problem existed in background technology, the present invention proposes a kind of weather-resistant and high-strength degree high adhesion paint, has the weather resistance of excellence, has high intensity and high adhesion force simultaneously.
A kind of weather-resistant and high-strength degree high adhesion paint that the present invention proposes, its raw material includes by weight: modifying cinepazid emulsion 80-120 part, Tri-isopropylphenyl phosphate APP 60-80 part, ethyl cellulose 30-60 part, nano silicon 20-80 part, nano titanium oxide 10-40 part, CNT 5-15 part, nano zine oxide 2-6 part, nano-aluminum hydroxide 3-9 part, modified kaolin 4-8 part, modified carbon nano-tube 1-8 part, kieselguhr 1-6 part, Bis(pentaerythritol) 2-8 part, Polyethylene Glycol 4-8 part, ethylene glycol 2-6 part, melamine phosphate 4-8 part, silane coupler 3-9 part, plasticizer 2-4 part, defoamer 3-6 part, levelling agent 4-8 part, wetting agent 1-5 part, water 5-15 part.
Preferably, the raw material of modifying cinepazid emulsion includes by weight: styrene-acrylic emulsion 20-60 part, styrene 10-30 part, methyl methacrylate 5-15 part, butyl acrylate 1-6 part, 2-(Acryloyloxy)ethanol 3-9 part, deionized water 4-8 part, sodium bicarbonate 2-6 part, emulsifying agent 1-5 part, dodecafluoroheptyl methacrylate 2-8 part, initiator 1-8 part.
Preferably, the weight ratio of modifying cinepazid emulsion, Tri-isopropylphenyl phosphate APP and ethyl cellulose is 85-115:65-75:35-55.
Preferably, the weight ratio of Tri-isopropylphenyl phosphate APP, styrene-acrylic emulsion, styrene, methyl methacrylate, butyl acrylate, 2-(Acryloyloxy)ethanol, deionized water, sodium bicarbonate, emulsifying agent, dodecafluoroheptyl methacrylate and initiator is 65-75:25-55:15-25:8-12:2-5:4-8:5-7:3-5:2-4:3-7:2-7.
Preferably, modifying cinepazid emulsion, ethyl cellulose, nano silicon, nano titanium oxide, CNT, nano zine oxide, nano-aluminum hydroxide, modified kaolin, modified carbon nano-tube and diatomaceous weight ratio are 85-115:35-55:25-75:15-35:8-12:3-5:4-8:5-7:2-7:2-5.
Preferably, modifying cinepazid emulsion is prepared by following technique: styrene-acrylic emulsion, deionized water and sodium bicarbonate mix homogeneously are obtained material a; Styrene, methyl methacrylate, butyl acrylate and 2-(Acryloyloxy)ethanol mix homogeneously are obtained material b; By material a, material b, emulsifying agent, base dodecafluorhe-ptylacrylate and initiator mix homogeneously, then heat to 70-80 DEG C, be incubated 20-50min, be cooled to room temperature and obtain modifying cinepazid emulsion.
Preferably, its raw material includes by weight: modifying cinepazid emulsion 85-115 part, Tri-isopropylphenyl phosphate APP 65-75 part, ethyl cellulose 35-55 part, nano silicon 25-75 part, nano titanium oxide 15-35 part, CNT 8-12 part, nano zine oxide 3-5 part, nano-aluminum hydroxide 4-8 part, modified kaolin 5-7 part, modified carbon nano-tube 2-7 part, kieselguhr 2-5 part, Bis(pentaerythritol) 3-7 part, Polyethylene Glycol 5-7 part, ethylene glycol 3-5 part, melamine phosphate 5-7 part, silane coupler 4-8 part, plasticizer 2.5-3.5 part, defoamer 4-5 part, levelling agent 5-7 part, wetting agent 2-4 part, water 8-12 part.
Preferably, its raw material includes by weight: modifying cinepazid emulsion 100 parts, Tri-isopropylphenyl phosphate APP 70 parts, ethyl cellulose 45 parts, nano silicon 50 parts, nano titanium oxide 25 parts, CNT 10 parts, nano zine oxide 4 parts, nano-aluminum hydroxide 6 parts, modified kaolin 6 parts, modified carbon nano-tube 4.5 parts, 3.5 parts of kieselguhr, Bis(pentaerythritol) 5 parts, Polyethylene Glycol 6 parts, ethylene glycol 4 parts, melamine phosphate 6 parts, silane coupler 6 parts, plasticizer 3 parts, defoamer 4.5 parts, levelling agent 6 parts, wetting agent 3 parts, 10 parts of water.
A kind of weather-resistant and high-strength degree high adhesion paint of the present invention, its raw material includes modifying cinepazid emulsion, Tri-isopropylphenyl phosphate APP, ethyl cellulose, nano silicon, nano titanium oxide, CNT, nano zine oxide, nano-aluminum hydroxide, modified kaolin, modified carbon nano-tube, kieselguhr, Bis(pentaerythritol), Polyethylene Glycol, ethylene glycol, melamine phosphate, silane coupler, plasticizer, defoamer, levelling agent, wetting agent and water, by the modifying cinepazid emulsion major ingredient as coating of the present invention, the raw material of modifying cinepazid emulsion includes styrene-acrylic emulsion, styrene, methyl methacrylate, butyl acrylate, 2-(Acryloyloxy)ethanol, deionized water, sodium bicarbonate, emulsifying agent, dodecafluoroheptyl methacrylate and initiator, the dodecafluoroheptyl methacrylate wherein adopted introduces fluorine element, then through styrene, methyl methacrylate, butyl acrylate, 2-(Acryloyloxy)ethanol, deionized water, sodium bicarbonate, emulsifying agent and initiator modifiy further as auxiliary agent so that the weather resistance of modified styrene-acrylic emulsion is further enhanced, and then are effectively increased the weather resistance of coating of the present invention, while modifying cinepazid emulsion, the raw material of modifying cinepazid emulsion coordinates with Tri-isopropylphenyl phosphate APP, utilize the fluorine element introduced to further increase the weather resistance of Tri-isopropylphenyl phosphate APP, further increase weather resistance and the adhesion property of coating of the present invention,The ethyl cellulose, nano silicon, nano titanium oxide, CNT, nano zine oxide, nano-aluminum hydroxide, modified kaolin, modified carbon nano-tube and the kieselguhr that add coordinate with modifying cinepazid emulsion as filler, conservative control proportioning, it is effectively increased the toughness of styrene-acrylic emulsion, wear-resisting and fire resistance so that the coating good combination property of the present invention.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail; it is understood that; embodiment is served only for the present invention is described, rather than is used for limiting the invention, any make on basis of the present invention amendment, equivalent replacement etc. is all in protection scope of the present invention.
Embodiment 1
A kind of weather-resistant and high-strength degree high adhesion paint that the present invention proposes, its raw material includes by weight: modifying cinepazid emulsion 100 parts, Tri-isopropylphenyl phosphate APP 70 parts, ethyl cellulose 45 parts, nano silicon 50 parts, nano titanium oxide 25 parts, CNT 10 parts, nano zine oxide 4 parts, nano-aluminum hydroxide 6 parts, modified kaolin 6 parts, modified carbon nano-tube 4.5 parts, 3.5 parts of kieselguhr, Bis(pentaerythritol) 5 parts, Polyethylene Glycol 6 parts, ethylene glycol 4 parts, melamine phosphate 6 parts, silane coupler 6 parts, plasticizer 3 parts, defoamer 4.5 parts, levelling agent 6 parts, wetting agent 3 parts, 10 parts of water.
Modifying cinepazid emulsion is prepared by following technique: by weight 40 parts of styrene-acrylic emulsions, 6 parts of deionized waters and 4 parts of sodium bicarbonate mix homogeneously are obtained material a; 20 parts of styrene, 10 parts of methyl methacrylates, 3.5 parts of butyl acrylate and 6 parts of 2-(Acryloyloxy)ethanol mix homogeneously are obtained material b; By material a, material b, 3 parts of emulsifying agents, 5 parts of base dodecafluorhe-ptylacrylates and 4.5 parts of initiator mix homogeneously, then heat to 75 DEG C, be incubated 35min, be cooled to room temperature and obtain modifying cinepazid emulsion.
Embodiment 2
A kind of weather-resistant and high-strength degree high adhesion paint that the present invention proposes, its raw material includes by weight: modifying cinepazid emulsion 80 parts, Tri-isopropylphenyl phosphate APP 80 parts, ethyl cellulose 30 parts, nano silicon 80 parts, nano titanium oxide 10 parts, CNT 15 parts, nano zine oxide 2 parts, nano-aluminum hydroxide 9 parts, modified kaolin 4 parts, modified carbon nano-tube 8 parts, 1 part of kieselguhr, Bis(pentaerythritol) 8 parts, Polyethylene Glycol 4 parts, ethylene glycol 6 parts, melamine phosphate 4 parts, silane coupler 9 parts, plasticizer 2 parts, defoamer 6 parts, levelling agent 4 parts, wetting agent 5 parts, 5 parts of water.
Modifying cinepazid emulsion is prepared by following technique: by weight 20 parts of styrene-acrylic emulsions, 8 parts of deionized waters and 2 parts of sodium bicarbonate mix homogeneously are obtained material a; 30 parts of styrene, 5 parts of methyl methacrylates, 6 parts of butyl acrylate and 3 parts of 2-(Acryloyloxy)ethanol mix homogeneously are obtained material b; By material a, material b, 5 parts of emulsifying agents, 2 parts of base dodecafluorhe-ptylacrylates and 8 parts of initiator mix homogeneously, then heat to 70 DEG C, be incubated 50min, be cooled to room temperature and obtain modifying cinepazid emulsion.
Embodiment 3
A kind of weather-resistant and high-strength degree high adhesion paint that the present invention proposes, its raw material includes by weight: modifying cinepazid emulsion 120 parts, Tri-isopropylphenyl phosphate APP 60 parts, ethyl cellulose 60 parts, nano silicon 20 parts, nano titanium oxide 40 parts, CNT 5 parts, nano zine oxide 6 parts, nano-aluminum hydroxide 3 parts, modified kaolin 8 parts, modified carbon nano-tube 1 part, 6 parts of kieselguhr, Bis(pentaerythritol) 2 parts, Polyethylene Glycol 8 parts, ethylene glycol 2 parts, melamine phosphate 8 parts, silane coupler 3 parts, plasticizer 4 parts, defoamer 3 parts, levelling agent 8 parts, wetting agent 1 part, 15 parts of water.
Modifying cinepazid emulsion is prepared by following technique: by weight 60 parts of styrene-acrylic emulsions, 4 parts of deionized waters and 6 parts of sodium bicarbonate mix homogeneously are obtained material a; 10 parts of styrene, 15 parts of methyl methacrylates, 1 part of butyl acrylate and 9 parts of 2-(Acryloyloxy)ethanol mix homogeneously are obtained material b; By material a, material b, 1 part of emulsifying agent, 8 parts of base dodecafluorhe-ptylacrylates and 1 part of initiator mix homogeneously, then heat to 80 DEG C, be incubated 20min, be cooled to room temperature and obtain modifying cinepazid emulsion.
Embodiment 4
A kind of weather-resistant and high-strength degree high adhesion paint that the present invention proposes, its raw material includes by weight: property styrene-acrylic emulsion 85 parts, Tri-isopropylphenyl phosphate APP 75 parts, ethyl cellulose 35 parts, nano silicon 75 parts, nano titanium oxide 15 parts, CNT 12 parts, nano zine oxide 3 parts, nano-aluminum hydroxide 8 parts, modified kaolin 5 parts, modified carbon nano-tube 7 parts, 2 parts of kieselguhr, Bis(pentaerythritol) 7 parts, Polyethylene Glycol 5 parts, ethylene glycol 5 parts, melamine phosphate 5 parts, silane coupler 8 parts, plasticizer 2.5 parts, defoamer 5 parts, levelling agent 5 parts, wetting agent 4 parts, 8 parts of water.
Modifying cinepazid emulsion is prepared by following technique: by weight 25 parts of styrene-acrylic emulsions, 7 parts of deionized waters and 3 parts of sodium bicarbonate mix homogeneously are obtained material a; 25 parts of styrene, 8 parts of methyl methacrylates, 5 parts of butyl acrylate and 4 parts of 2-(Acryloyloxy)ethanol mix homogeneously are obtained material b; By material a, material b, 4 parts of emulsifying agents, 3 parts of base dodecafluorhe-ptylacrylates and 7 parts of initiator mix homogeneously, then heat to 72 DEG C, be incubated 45min, be cooled to room temperature and obtain modifying cinepazid emulsion.
Embodiment 5
A kind of weather-resistant and high-strength degree high adhesion paint that the present invention proposes, its raw material includes by weight: property styrene-acrylic emulsion 115 parts, Tri-isopropylphenyl phosphate APP 65 parts, ethyl cellulose 55 parts, nano silicon 25 parts, nano titanium oxide 35 parts, CNT 8 parts, nano zine oxide 5 parts, nano-aluminum hydroxide 4 parts, modified kaolin 7 parts, modified carbon nano-tube 2 parts, 5 parts of kieselguhr, Bis(pentaerythritol) 3 parts, Polyethylene Glycol 7 parts, ethylene glycol 3 parts, melamine phosphate 7 parts, silane coupler 4 parts, plasticizer 3.5 parts, defoamer 4 parts, levelling agent 7 parts, wetting agent 2 parts, 12 parts of water.
Modifying cinepazid emulsion is prepared by following technique: by weight 55 parts of styrene-acrylic emulsions, 5 parts of deionized waters and 5 parts of sodium bicarbonate mix homogeneously are obtained material a; 15 parts of styrene, 12 parts of methyl methacrylates, 2 parts of butyl acrylate and 8 parts of 2-(Acryloyloxy)ethanol mix homogeneously are obtained material b; By material a, material b, 2 parts of emulsifying agents, 7 parts of base dodecafluorhe-ptylacrylates and 2 parts of initiator mix homogeneously, then heat to 78 DEG C, be incubated 25min, be cooled to room temperature and obtain modifying cinepazid emulsion.
The above; it is only the present invention preferably detailed description of the invention; but protection scope of the present invention is not limited thereto; any those familiar with the art is in the technical scope that the invention discloses; it is equal to replacement according to technical scheme and inventive concept thereof or is changed, all should be encompassed within protection scope of the present invention.
Claims (8)
1. a weather-resistant and high-strength degree high adhesion paint, it is characterized in that, its raw material includes by weight: modifying cinepazid emulsion 80-120 part, Tri-isopropylphenyl phosphate APP 60-80 part, ethyl cellulose 30-60 part, nano silicon 20-80 part, nano titanium oxide 10-40 part, CNT 5-15 part, nano zine oxide 2-6 part, nano-aluminum hydroxide 3-9 part, modified kaolin 4-8 part, modified carbon nano-tube 1-8 part, kieselguhr 1-6 part, Bis(pentaerythritol) 2-8 part, Polyethylene Glycol 4-8 part, ethylene glycol 2-6 part, melamine phosphate 4-8 part, silane coupler 3-9 part, plasticizer 2-4 part, defoamer 3-6 part, levelling agent 4-8 part, wetting agent 1-5 part, water 5-15 part.
2. weather-resistant and high-strength degree high adhesion paint according to claim 1, it is characterized in that, the raw material of modifying cinepazid emulsion includes by weight: styrene-acrylic emulsion 20-60 part, styrene 10-30 part, methyl methacrylate 5-15 part, butyl acrylate 1-6 part, 2-(Acryloyloxy)ethanol 3-9 part, deionized water 4-8 part, sodium bicarbonate 2-6 part, emulsifying agent 1-5 part, dodecafluoroheptyl methacrylate 2-8 part, initiator 1-8 part.
3. weather-resistant and high-strength degree high adhesion paint according to claim 1 and 2, it is characterised in that the weight ratio of modifying cinepazid emulsion, Tri-isopropylphenyl phosphate APP and ethyl cellulose is 85-115:65-75:35-55.
4. the weather-resistant and high-strength degree high adhesion paint according to any one of claim 1-3, it is characterized in that, the weight ratio of Tri-isopropylphenyl phosphate APP, styrene-acrylic emulsion, styrene, methyl methacrylate, butyl acrylate, 2-(Acryloyloxy)ethanol, deionized water, sodium bicarbonate, emulsifying agent, dodecafluoroheptyl methacrylate and initiator is 65-75:25-55:15-25:8-12:2-5:4-8:5-7:3-5:2-4:3-7:2-7.
5. the weather-resistant and high-strength degree high adhesion paint according to any one of claim 1-4, it is characterized in that, modifying cinepazid emulsion, ethyl cellulose, nano silicon, nano titanium oxide, CNT, nano zine oxide, nano-aluminum hydroxide, modified kaolin, modified carbon nano-tube and diatomaceous weight ratio are 85-115:35-55:25-75:15-35:8-12:3-5:4-8:5-7:2-7:2-5.
6. the weather-resistant and high-strength degree high adhesion paint according to any one of claim 1-5, it is characterised in that modifying cinepazid emulsion is prepared by following technique: styrene-acrylic emulsion, deionized water and sodium bicarbonate mix homogeneously are obtained material a; Styrene, methyl methacrylate, butyl acrylate and 2-(Acryloyloxy)ethanol mix homogeneously are obtained material b; By material a, material b, emulsifying agent, base dodecafluorhe-ptylacrylate and initiator mix homogeneously, then heat to 70-80 DEG C, be incubated 20-50min, be cooled to room temperature and obtain modifying cinepazid emulsion.
7. the weather-resistant and high-strength degree high adhesion paint according to any one of claim 1-6, it is characterized in that, its raw material includes by weight: modifying cinepazid emulsion 85-115 part, Tri-isopropylphenyl phosphate APP 65-75 part, ethyl cellulose 35-55 part, nano silicon 25-75 part, nano titanium oxide 15-35 part, CNT 8-12 part, nano zine oxide 3-5 part, nano-aluminum hydroxide 4-8 part, modified kaolin 5-7 part, modified carbon nano-tube 2-7 part, kieselguhr 2-5 part, Bis(pentaerythritol) 3-7 part, Polyethylene Glycol 5-7 part, ethylene glycol 3-5 part, melamine phosphate 5-7 part, silane coupler 4-8 part, plasticizer 2.5-3.5 part, defoamer 4-5 part, levelling agent 5-7 part, wetting agent 2-4 part, water 8-12 part.
8. the weather-resistant and high-strength degree high adhesion paint according to any one of claim 1-7, it is characterized in that, its raw material includes by weight: modifying cinepazid emulsion 100 parts, Tri-isopropylphenyl phosphate APP 70 parts, ethyl cellulose 45 parts, nano silicon 50 parts, nano titanium oxide 25 parts, CNT 10 parts, nano zine oxide 4 parts, nano-aluminum hydroxide 6 parts, modified kaolin 6 parts, modified carbon nano-tube 4.5 parts, 3.5 parts of kieselguhr, Bis(pentaerythritol) 5 parts, Polyethylene Glycol 6 parts, ethylene glycol 4 parts, melamine phosphate 6 parts, silane coupler 6 parts, plasticizer 3 parts, defoamer 4.5 parts, levelling agent 6 parts, wetting agent 3 parts, 10 parts of water.
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| CN201610077909.6A CN105647328A (en) | 2016-02-02 | 2016-02-02 | Weather-proof high-strength and high-adhesive-force paint |
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| CN201610077909.6A CN105647328A (en) | 2016-02-02 | 2016-02-02 | Weather-proof high-strength and high-adhesive-force paint |
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