CN105505109A - Fire-proof and anti-fouling epoxy finish paint - Google Patents

Fire-proof and anti-fouling epoxy finish paint Download PDF

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Publication number
CN105505109A
CN105505109A CN201510915317.2A CN201510915317A CN105505109A CN 105505109 A CN105505109 A CN 105505109A CN 201510915317 A CN201510915317 A CN 201510915317A CN 105505109 A CN105505109 A CN 105505109A
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CN
China
Prior art keywords
parts
epoxy
agent
organic
finish paint
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510915317.2A
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Chinese (zh)
Inventor
张卫中
焦丰娴
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NANJING CHANGJIANG PAINT CO Ltd
Original Assignee
NANJING CHANGJIANG PAINT CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NANJING CHANGJIANG PAINT CO Ltd filed Critical NANJING CHANGJIANG PAINT CO Ltd
Priority to CN201510915317.2A priority Critical patent/CN105505109A/en
Publication of CN105505109A publication Critical patent/CN105505109A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention provides fire-proof and anti-fouling epoxy finish paint. The fire-proof and anti-fouling epoxy finish paint is prepared from the following components in parts by weight: 100 parts of hydrogenated bisphenol A epoxy resin, 10 to 30 parts of water-borne epoxy resin, 10 to 20 parts of butyl titanate, 15 to 20 parts of fluorine/carbon-containing silane coupling agent, 10 to 20 parts of epoxy-containing silane coupling agent, 10 to 30 parts of other organosilicone precursors, 1 to 5 parts of dispersing agent, 1 to 5 parts of flatting agent, 2 to 5 parts of antifoaming agent, 1 to 2 parts of accelerating agent, 3 to 4 parts of water-borne additive, 10 to 15 parts of pigment and 50 to 150 parts of solvent, wherein the water-borne additive is a mixture of ethylene glycol, 2,2,4-trimethyl-1,3-pentanediolmono(2-methyl propanoate), the antifoaming agent and the flatting agent. The external wall epoxy finish paint provided by the invention is used as a decorative protection layer of a building wall body, not only conforms to all performance indexes of external wall elastic epoxy finish paint, but also has excellent flame resistance and excellent corrosion resistance.

Description

A kind of epoxy finish of resistant of preventing fires
Technical field
The present invention relates to decorating building technical field of coatings, particularly relate to a kind of exterior wall epoxy finish.
Background technology
The major function of exterior wall epoxy finish is decoration and architecture protection object plane, makes buildings appearance neat and artistic, thus reaches the object of beautifying urban environment, can play the effect of architecture protection beyond the region of objective existence wall simultaneously, extend its work-ing life.After dust in air and other materials stain coating, coating can lose original aesthetic, and thus exterior wall epoxy finish not easily must be stain or stain rear easy cleaning by these materials.Therefore the external wall elastic epoxy finish researching and developing contamination resistance excellence is needed.
On the other hand, fire protection flame retarding is the fire safety grade particularly the important point improving building.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of fire prevention resistant epoxy finish, and efficiency of preservation is strong and have good heatproof combustion resistance.
For solving the problems of the technologies described above, the invention provides a kind of fire prevention resistant epoxy finish, be made up of the component of following parts by weight: hydrogenated bisphenol A epoxy resin 100 parts, aqueous epoxy resins 10-30 part, butyl (tetra) titanate 10-20 part, fluorine-containing carbon silane coupling agent 15-25 part, containing epoxy silane coupling agent 10-16 part, other organosilane precursor 10-30 part, dispersion agent 1-5 part, flow agent 1-5 part, defoamer 2-5 part, promotor 1-2 part, filler ultra-fine barium sulfate 15-20 part, organosilicon flow agent 0.5-2.5 part, sanitas 10-15 part, aqueous promoter 3-4 part, pigment 10-15 part, solvent 50-150 part, described aqueous promoter is the mixture of ethylene glycol, Lauryl Alcohol ester, defoamer, flow agent.
As a preferred embodiment of the present invention, described pigment is that titanium dioxide, organic pale yellow, organic middle Huang, organic bright red, phthalocyanine blue, phthalein are dark green, one or more mixture in carbon black.
Beneficial effect of the present invention is: exterior wall epoxy finish of the present invention, as the decoration protective layer of building masonry wall, not only meets the property indices of external wall elastic epoxy finish, and has excellent flame retardant properties and antiseptic property.
Embodiment
In order to make the object of invention, technical scheme and advantage clearly understand, below in conjunction with embodiment, invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain invention, and be not used in restriction invention.
The invention provides a kind of fire prevention resistant epoxy finish, be made up of the component of following parts by weight: hydrogenated bisphenol A epoxy resin 100 parts, aqueous epoxy resins 10-30 part, butyl (tetra) titanate 10-20 part, fluorine-containing carbon silane coupling agent 15-25 part, containing epoxy silane coupling agent 10-16 part, other organosilane precursor 10-30 part, dispersion agent 1-5 part, flow agent 1-5 part, defoamer 2-5 part, promotor 1-2 part, filler ultra-fine barium sulfate 15-20 part, organosilicon flow agent 0.5-2.5 part, sanitas 10-15 part, aqueous promoter 3-4 part, pigment 10-15 part, solvent 50-150 part, described aqueous promoter is the mixture of ethylene glycol, Lauryl Alcohol ester, defoamer, flow agent.Pigment is that titanium dioxide, organic pale yellow, organic middle Huang, organic bright red, phthalocyanine blue, phthalein are dark green, one or more mixture in carbon black, and this is allocated according to color demand.
Embodiment one
The component of exterior wall epoxy finish consists of: hydrogenated bisphenol A epoxy resin 100 parts, aqueous epoxy resins 10 parts, butyl (tetra) titanate 20 parts, fluorine-containing carbon silane coupling agent 15 parts, containing epoxy silane coupling agent 16 parts, other organosilane precursor 10 parts, dispersion agent 5 parts, flow agent 1 part, defoamer 5 parts, promotor 1 part, filler ultra-fine barium sulfate 15 parts, organosilicon flow agent 2.5 parts, sanitas 10 parts, aqueous promoter 4 parts, pigment 10 parts, solvent 150 parts.
Embodiment two
The component of exterior wall epoxy finish consists of: hydrogenated bisphenol A epoxy resin 100 parts, aqueous epoxy resins 30 parts, butyl (tetra) titanate 10 parts, fluorine-containing carbon silane coupling agent 25 parts, containing epoxy silane coupling agent 10 parts, other organosilane precursor 30 parts, dispersion agent 1 part, flow agent 5 parts, defoamer 2 parts, promotor 2 parts, filler ultra-fine barium sulfate 20 parts, organosilicon flow agent 0.5 part, sanitas 15 parts, aqueous promoter 3 parts, pigment 15 parts, solvent 50 parts.
Embodiment three
The component of exterior wall epoxy finish consists of: hydrogenated bisphenol A epoxy resin 100 parts, aqueous epoxy resins 20 parts, butyl (tetra) titanate 15 parts, fluorine-containing carbon silane coupling agent 20 parts, containing epoxy silane coupling agent 14 parts, other organosilane precursor 20 parts, dispersion agent 3 parts, flow agent 3 parts, defoamer 4 parts, promotor 1.5 parts, filler ultra-fine barium sulfate 18 parts, organosilicon flow agent 2.0 parts, sanitas 13 parts, aqueous promoter 3.5 parts, pigment 12 parts, solvent 100 parts.
According to the inspecting standard of " finishing fire retardant paint " GB12441-2005, obtain following test result, reach the requirement of standard completely:
Consistency Sticking power Hardness Impact strength Snappiness Weathering resistance Non-corrosibility
Embodiment 1 Not stratified 1 grade 4h >50kg/cm 2 1mm 6Mpa 6Mpa
Embodiment 2 Not stratified 2 grades 3h >50kg/cm 2 1mm 7Mpa 6Mpa
Embodiment 3 Not stratified 1 grade 4h >50kg/cm 2 1mm 6Mpa 5Mpa
Be more than better embodiment of the present invention, but protection scope of the present invention is not limited thereto.Any those of ordinary skill in the art are in the technical scope disclosed by the present invention, and the conversion expected without creative work or replacement, all should be encompassed within protection scope of the present invention.Therefore the protection domain that protection scope of the present invention should limit with claim is as the criterion.

Claims (2)

1. the epoxy finish of a resistant of preventing fires, it is characterized in that, be made up of the component of following parts by weight: hydrogenated bisphenol A epoxy resin 100 parts, aqueous epoxy resins 10-30 part, butyl (tetra) titanate 10-20 part, fluorine-containing carbon silane coupling agent 15-25 part, containing epoxy silane coupling agent 10-16 part, other organosilane precursor 10-30 part, dispersion agent 1-5 part, flow agent 1-5 part, defoamer 2-5 part, promotor 1-2 part, filler ultra-fine barium sulfate 15-20 part, organosilicon flow agent 0.5-2.5 part, sanitas 10-15 part, aqueous promoter 3-4 part, pigment 10-15 part, solvent 50-150 part, described aqueous promoter is the mixture of ethylene glycol, Lauryl Alcohol ester, defoamer, flow agent.Pigment is that titanium dioxide, organic pale yellow, organic middle Huang, organic bright red, phthalocyanine blue, phthalein are dark green, one or more mixture in carbon black, and this is allocated according to color demand.
2. the epoxy finish of fire prevention resistant as claimed in claim 1, is characterized in that, described pigment be titanium dioxide, organic pale yellow, organic middle Huang, organic bright red, phthalocyanine blue, phthalein dark green, one or more mixture in carbon black.
CN201510915317.2A 2015-12-11 2015-12-11 Fire-proof and anti-fouling epoxy finish paint Pending CN105505109A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510915317.2A CN105505109A (en) 2015-12-11 2015-12-11 Fire-proof and anti-fouling epoxy finish paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510915317.2A CN105505109A (en) 2015-12-11 2015-12-11 Fire-proof and anti-fouling epoxy finish paint

Publications (1)

Publication Number Publication Date
CN105505109A true CN105505109A (en) 2016-04-20

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510915317.2A Pending CN105505109A (en) 2015-12-11 2015-12-11 Fire-proof and anti-fouling epoxy finish paint

Country Status (1)

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CN (1) CN105505109A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106634445A (en) * 2016-12-29 2017-05-10 四川省科学城新方舟安防科技有限责任公司 Elastic fire-retardant paint and preparation method thereof
CN109401530A (en) * 2018-09-12 2019-03-01 安徽康瑞高科新材料技术工程有限公司 A kind of epoxy finish and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106634445A (en) * 2016-12-29 2017-05-10 四川省科学城新方舟安防科技有限责任公司 Elastic fire-retardant paint and preparation method thereof
CN109401530A (en) * 2018-09-12 2019-03-01 安徽康瑞高科新材料技术工程有限公司 A kind of epoxy finish and preparation method thereof

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Application publication date: 20160420

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