CN105084468A - Ceramal material for manufacturing hydrogen-enriched water and preparing method and application thereof - Google Patents
Ceramal material for manufacturing hydrogen-enriched water and preparing method and application thereof Download PDFInfo
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- CN105084468A CN105084468A CN201510456288.8A CN201510456288A CN105084468A CN 105084468 A CN105084468 A CN 105084468A CN 201510456288 A CN201510456288 A CN 201510456288A CN 105084468 A CN105084468 A CN 105084468A
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Abstract
The invention belongs to the technical field of new environment-friendly materials, and particularly relates to a ceramal material for manufacturing hydrogen-enriched water and the preparing method and application thereof. The ceramal material is prepared from, by weight, 30-85 parts of base material component, 20-60 parts of hydrogen-enriched component, 2-25 parts of anti-microbial component, and 3-30 parts of binder. The base material component is prepared from tourmaline, serpeggiante, silicon oxide, calcium oxide and zeolite. The hydrogen-enriched component is prepared from magnesium metal powder, magnesia powder and KDF alloy powder. The anti-microbial component is prepared from zinc oxide, titanium oxide and cerium oxide. The binder is prepared from one or more of high-purity distilled water, carboxypropyl cellulose and bentonite. The ceramal material can be used for manufacturing alkalescent water, negative-potential water and hydrogen-enriched water and also has an anti-microbial function and a water activating function. The invention further provides the preparing method and application of the ceramal material. The technology is simple and easy to realize. The ceramal material can be applied to products including water purifiers, water purifying kettles and cups.
Description
Technical field
The invention belongs to environmental friendly material technical field, be specifically related to rich hydrogen water alloy ceramic of a kind of manufacture and its preparation method and application.
Background technology
Medical research shows a lot of disease, and comprising aging is all that the free radical cannot removed in time due to cylinder accumulation causes.Free radical is the chemical substance that human body cell produces that in metabolic process a class is very active, have very strong oxidation, is also active oxygen.Free radical attacks life macromolecule can cause tissue cell insult, and being the basic reason causing body aging, is also the important cause of the malignant diseases such as induced tumor.Too much active oxygen radical can produce destruction, causes the damage of human normal cell and tissue, thus causes various diseases, as heart trouble, senile dementia, Parkinson's disease and tumour etc.In addition, the solar irradiation in external environment, atmospheric pollution, flue dust, agricultural chemicals etc. all can impel human body to produce more active oxygen radicals, and cause nucleic acid mutation, this is mankind aging and ill root.
And the glassware for drinking water of hydrogen has the effect removing biological interior free yl.Hydrogen is a kind of best antioxidant inherently, because hydrogen molecule is very fine, enters body interior energy rapid osmotic to whole body, and permeates cell membranes, be difficult to the pernicious active oxygen eliminated in the middle of taking away, its synthetic water excreted, and the running of other benign activity oxygen and body function can not be affected.The most important thing is destroyed and oxidized cell to be restored." hydrogen " in water has the strongest reducing power, most of antioxidant that we often eat, as vitamin b6 usp, and be not easy through cytolemma, and can not only pernicious active oxygen be eliminated pointedly, eat a large amount of vitamin b6 usp still more, be also difficult to store in body and absorb.According to the experimental analysis that Japanese Ohta Shigeo professor does, resistance of oxidation and the cell restorability of hydrogen are the most severe so far.
Rich hydrogen water, as the term suggests be exactly the water being rich in hydrogen, Japanese is " Shui Sushui ".Be rich in hydrionic water element water (HydrogenWater), be hydrogen reduction water, different from common water, by its reducing power, can the interior superfluous active oxygen (oxyradical) of purged body.Rich hydrogen water is not only clean, and have hydrogen to have energy, be all present small molecules running water group, also can purify the blood, make unobstructed blood, metabolism is vigorous, prevention of various diseases, promotes HUMAN HEALTH.In July, 2007, Japanese medical university scholar is at " Natural medicine " report, and the hydrogen of animal breath 2% just can effective scavenging free radicals.
It is that direct current brine electrolysis prepares hydrogen that current manufacture rich hydrogen water technology mainly contains following three kinds: one, and the hydrogen portion of generation is soluble in water becomes rich hydrogen water; Two is directly be filled with in water by hydrogen to be prepared into hydrogeneous rich hydrogen water; Three is that natural stupalith light electrolysis prepares hydrogen, the rich hydrogen water of hydrogen one-tenth soluble in water of generation.Above three kinds of methods respectively have relative merits, and wherein direct current electrolytic hydrogen production Technical comparing is ripe, but manufacturing cost is high, easily produce the shortcomings such as ozone peculiar smell, cause this produce market to be promoted slower.As patent 201510126957.5, a kind of portable rich hydrogen water tumbler; Patent 201410679373.6, a kind of rich hydrogen water rod; Patent 201280061730.1, water element water making device., there is manufacturing cost higher in the method introduced in these patents, and easily produces ozone while the rich hydrogen water of manufacture, causes peculiar smell in water comparatively large, lack trace element and weakly alkaline, be just reduced to the shortcomings such as ortho-water in the short period of time.But water electrolysis hydrogen production technology can prepare high concentration of hydrogen water, be suitable as treatment water, but drink rich hydrogen water keep healthy as daily, be unfavorable for healthy on the contrary.
Hydrogen being filled with the rich hydrogen water prepared in water, there is problems such as storing difficulty and hydrogen volatilization, have certain limitation, can only sell for the preparation of becoming packed or filling hydrogen water.Such as, patent CN201410166247.0, a kind of preparation technology of rich hydrogen water, makes rich hydrogen water polo by composite mixture heating, loads in airtight retort, pass into degassed after pure water, stir obtained rich hydrogen water, fillingly after filtration to make.In the water made, hydrogen molecule content is 20 times of common alkaline ionized water.But the method can only carry out filling storage, hydrogen water can not be prepared whenever and wherever possible, and carry inconvenience.
The hydrogen manufacturing of natural stupalith light electrolysis, Material claddings such as general employing Tourmaline (tourmalinite), metal magnesium powder or directly adopt the ripple metal light electrolysis of living such as magnesium granules, magnesium rod to prepare hydrogen water, but there is poor in timeliness in above material, hydrogen manufacturing content is low, alkalescence is uncontrollable, and easily separate out the shortcomings such as throw out, have a strong impact on the mouthfeel of water.Meanwhile, the ripple metals of living such as magnesium granules and magnesium rod are very easily oxidized under air ambient, once substantially no longer work after oxidation, and the magnesium ion that easy stripping is excessive in water, cause magnesium ion in water to exceed standard.See with regard to existing market situation, above quality product is uneven, and functional effect is undesirable.Through inquiry, also do not find directly to adopt magnesium granules or magnesium rod to carry out the document of hydrogen manufacturing or patent document etc., have patent can manufacture negative potential water and alkaline small water.Such as patent CN201510008767.3, a kind of antibacterial negative potential ball and preparation method and application; Patent CN201010618600.6, composite antibacterial far infrared medical stone porous ceramic ball and preparation method; Patent 200910199142.4, a kind of can produce negative potential composition and preparation method and application.
How to apply natural mineral stupalith, producing the rich hydrogen water being conducive to HUMAN HEALTH becomes problem demanding prompt solution in prior art.
Summary of the invention
For the deficiencies in the prior art, the object of this invention is to provide the rich hydrogen water alloy ceramic of a kind of manufacture, have and manufacture week-base water, negative potential water and Fu Qing water three zones, also there is antibacterial and activated water effect; The present invention provides its preparation method and methods for using them simultaneously.
Manufacture of the present invention rich hydrogen water alloy ceramic, is made up of the raw material of following parts by weight: substrate component 30-85 part, hydrogen-rich component 20-60 part, antibacterial components 2-25 part and binding agent 3-30 part;
Wherein,
Substrate component is made up of tourmalinite, water unit stone, silicon oxide, calcium oxide and zeolite;
Hydrogen-rich component is made up of metal magnesium powder, magnesia powder and KDF powdered alloy;
Antibacterial components is made up of zinc oxide, titanium oxide and cerium oxide;
Binding agent is one or more in high-purity distilled water, carboxy-propyl cellulose or wilkinite.
Wherein:
Substrate component is made up of the raw material of following weight percentage:
Tourmalinite 20-45%, water unit stone 10-30%, silicon oxide 20-45%, calcium oxide 10-35% and zeolite 10-30%.
Hydrogen-rich component is made up of the raw material of following weight percentage:
Metal magnesium powder 20-60%, magnesia powder 20-60% and KDF powdered alloy 10-50%.The particle diameter of described metal magnesium powder, magnesia powder and KDF powdered alloy is 30-100 μm.
Antibacterial components is made up of the raw material of following weight percentage:
Zinc oxide 20-50%, titanium oxide 20-50% and cerium oxide 5-30%.
Binding agent is preferably made up of the raw material of following weight percentage:
High-purity distilled water 30-65%, carboxy-propyl cellulose 10-30% and wilkinite 20-50%.
The preparation method of described manufacture rich hydrogen water alloy ceramic, comprises the steps:
(1) pre-treatment:
By tourmalinite, water unit stone, silicon oxide, calcium oxide and zeolite mixed grinding 6-10h, to diameter of particle < 500 μm, obtain substrate component;
By zinc oxide, titanium oxide, cerium oxide mixed grinding 6-10h, to diameter of particle < 50 μm, obtain antibacterial components;
Metal magnesium powder, magnesia powder and KDF powdered alloy are mixed, obtains hydrogen-rich component;
High-purity distilled water, carboxy-propyl cellulose and wilkinite are mixed, obtains binding agent;
(2) batch mixing: substrate component, hydrogen-rich component and antibacterial components are added mixer by ratio of components, mixing 1-5 hour;
(3) shaping: the material of mixing step (2) prepared joins nodulizer or stamping machine is shaping, and moulding process constantly sprays binding agent;
(4) cure, screen: the shaping rear material that step (3) prepares is carried out curing, screening, obtain described manufacture rich hydrogen water alloy ceramic.
Wherein: stoving temperature is 150-480 DEG C, the time of curing is 0.5-2h.
Described manufacture rich hydrogen water alloy ceramic shape is granule type, wafer type, column type, diamond type, cast or cardioid.
The application of described manufacture rich hydrogen water alloy ceramic, is applied in water purifier, purifying kettle, water tumbler product, can also be used in deodorizing scrubbing, aquaculture, flower planting, health care and beauty treatment industry.
In preparation method of the present invention, substrate component, hydrogen-rich component and antibacterial components separate batch mixing, avoid cause because particle diameter is inconsistent between each constituent materials less economical and merge the shortcomings such as insufficient.Because substrate component is mainly made with the grinding of natural crystal powder material batch mixing, require that particle diameter is less than 500 microns, mainly consider that this particle size range has functional and economy preferably.Hydrogen-rich component is made up of the material such as metal magnesium powder, magnesia powder, because MAGNESIUM METAL is inflammable, there is certain danger in conventional grinding, directly take to purchase commercially available magnesium powder, magnesia powder and KDF powdered alloy and carry out batch mixing compound, the situation such as uneven with other material batch mixing in substrate component can be avoided to occur.Antibacterial components each material requirements diameter of particle is the smaller the better, so antibacterial components raw material mixed grinding is less than 50 microns to particle diameter, and its better anti-microbial property of competence exertion.Consider according to each material property and economy like this, reaching required particle diameter by separating batch mixing grinding, then carrying out component compound, the function of each material can be played, having again good economy.
In the present invention, antibacterial components requires that batch mixing grinding particle diameter is less than 50 microns, is because zinc oxide, titanium oxide and cerium oxide will reach submicron or nano level just can better give play to antibiotic effect in component.
Substrate component of the present invention requires that batch mixing grinding particle diameter is less than 500 microns, is to consider based on the stability of composition each in component and economy.
Substrate component of the present invention with the addition of zeolite group mineral material, and mainly zeolite has natural microvoid structure, and specific surface area is very large.Zeolite and tourmalinite, water unit stone, silicon oxide and calcium oxide mix abundant after, then with hydrogen-rich component and antibacterial components batch mixing, the alloy ceramic made after low-temperature bake has more microvoid structure.Be dispersed with numerous micron order and nano level duct and micropore at the micropore framework of this material, increase the contact area of each function starting material and water, thus enhance alloy ceramic of the present invention carries out light electrolysis efficiency to water.More much than like product 50-100 times of the specific surface area of alloy ceramic.
Substrate component of the present invention adds tourmalinite and water unit stone mineral material, it is the activated water effect utilizing this material in water, himself self poling characteristic and large water clusters can be shaken into little water clusters by the red line energy wave far away discharged, thus realize the effect of activated water.Activated water has good seepage force and solvency power, to promotion body metabolism, strengthens body immunity and plays better effect.
Hydrogen-rich component of the present invention adds KDF powdered alloy, and KDF alloy is Copper-zinc alloy material, has and purifies waste water and micro-electrolytic water function.The technology of KDF alloy and product all comparative maturities.After KDF alloy mixes with MAGNESIUM METAL and magnesium oxide, each metal ion has higher potential difference in water, numerous galvanic effect can be formed, when contacting with water, each metal ion can synergy, produce numerous light electrolysis contact, thus the dynamics strengthened water light electrolysis, enhance the function manufacturing hydrogen molecule.
In antibacterial components material of the present invention, add rare-earth oxidation cerium material, mainly utilize the anti-microbial effect that cerium oxide is natural, also have cerium oxide can activate titanium oxide in alloy ceramic and zinc oxide material, the anti-microbial property of zine ion can be significantly improved, excite itself and water to produce the quantity of hydroxyl radical free radical, thus realize the object strengthening anti-microbial property.Antibacterial components material of the present invention does not adopt conventional silver metallic substance, mainly considers to add silver ions cost too high, also has the easy oxidation stain of silver ions, not only do not have anti-microbial effect, and in water, separate out silver ions on the contrary excessive, is unfavorable for healthy.
The present invention adopts baked and cured technology, instead of adopts low-firing technology, each constituent materials can be allowed fully to merge, be prepared into microvoid structure, increases the contact area with water, strengthens light electrolysis efficiency, can separate out trace element etc. by slowly-releasing simultaneously.
The advantages such as the present invention needs according to application the product being developed to different shape, has range of application wide, good in economic efficiency.
Constantly spray binding agent in moulding process of the present invention, can allow alloy ceramic in moulding process, form stratiform light electrolysis functional response layer, the specific surface area strengthening material simultaneously, improves the persistence of micro-electrolysis reaction, adds product life.
The rich hydrogen water alloy ceramic that the present invention prepares has following technical indicator:
Specific surface area: > 0.5 × 10
4cm
2/ g;
Density: 1.35 ~ 1.4g/cm
3;
Tap density: 1.15 ~ 1.22kg/cm
3.
Detect: detect through Shandong Center for Disease Control & Prevention, according to " Drinking Water transmission & distribution wetting system and protective material Hygienic safety evaluation specification " (2001), the method of inspection adopts " Drinking Water inspection specification " (2001), by spherical alloy stupalith soak time 24 ± 1h, soaking temperature 25 ± 5 DEG C.Result shows: color, opacity, the smelly and equal conformance with standard code requirement of index such as taste, naked eyes visible, pH, total dissolved solid, oxygen-consumption, arsenic, cadmium, lead, mercury, trichloromethane, volatile phenol.
Municipal tap water ORP value is 354mV, in mass ratio: 1 part of ceramal and 10 parts of water ratios, after adding described manufacture rich hydrogen water alloy ceramic immersion 5min, and reduction >=-150mV; Distilled water ORP value is 10mV, in mass ratio: 1 part of ceramal and 10 parts of water ratios, after adding described manufacture rich hydrogen water alloy ceramic immersion 5min, and reduction >=-150mV.
The pH of municipal tap water is 7.0, in mass ratio: 1 part of ceramal and 10 parts of water ratios, after adding described manufacture rich hydrogen water alloy ceramic immersion 5min, and pH=8.2-8.8; The pH of distilled water is 5.5, in mass ratio: 1 part of ceramal and 10 parts of water ratios, after adding described manufacture rich hydrogen water alloy ceramic immersion 5min, and pH=7.8-8.0.
The TDS value of municipal tap water is 170, in mass ratio: 1 part of ceramal and 10 parts of water ratios, after adding described manufacture rich hydrogen water alloy ceramic immersion 5min, and TDS=260; Distilled water TDS value be 30, in mass ratio: 1 part of ceramal and 10 parts of water ratios, add described manufacture rich hydrogen water alloy ceramic and soak after 5min, TDS=150.
In sum, beneficial effect of the present invention is as follows:
(1) the present invention manufactures rich hydrogen water alloy ceramic, has and manufactures rich hydrogen water, week-base water and negative potential water three zones, also has antibacterial and activated water effect.After tested, in mass ratio: 1 part of ceramal and 10 parts of water ratios, in the rich hydrogen water of manufacture, the content of hydrogen molecule, can reach 300-800ppb; PH value is between 8-9.5; Redox potential ORP value is-150 to-300mV; Peak width at half height through nuclear magnetic resonance analyser test water oxygen 17 is distributed in 65-85 hertz; In rich hydrogen water, zinc, magnesium, calcium, metasilicic acid etc. are micro-abundant.So the water of alloy ceramic manufacture of the present invention integrates rich hydrogen, weak base, negative potential, subset and trace element.
(2) described alloy ceramic shape has spherical, sheet shape, column type etc., needs to prepare different shape according to application.May be used on, in the products such as water purifier, purifying kettle and water tumbler, manufacturing the healthy water of rich hydrogen, can improving product added value, improve healthy.Also can be used in the industries such as deodorizing scrubbing, aquaculture, flower planting and health and beauty.
(3) the present invention's tool compared with existing rich hydrogen water technology of preparing has the following advantages: compared with direct current brine electrolysis, it is low that alloy ceramic has cost, uses simple, can avoid producing the peculiar smell such as ozone, the rich hydrogen water produced is weakly alkaline, and trace element is abundant; Compared with being filled with water process for making hydrogen with hydrogen, alloy ceramic process for making hydrogen has and stores easily, avoids manufacturing hydrogen water function single, can manufacture and integrate rich hydrogen, negative potential water, small molecules, alkalescence and the advantage such as antibacterial; Compared with MAGNESIUM METAL material process for making hydrogen, alloy ceramic has and is not oxidized, not easily produces the advantage such as throw out, rich trace elements.
(4) preparation method of the present invention, has and is easy to the advantages such as suitability for industrialized production, good in economic efficiency, practical ranges is wide.
(5) preparation method of the present invention, can form stratiform functional layer and microvoid structure, adds the specific surface area of material, enhances light electrolysis hydrogen production efficiency.
Accompanying drawing explanation
Fig. 1 is the manufacture rich hydrogen water alloy ceramic appearance assumption diagram that the embodiment of the present invention 1 prepares;
Fig. 2 is the manufacture rich hydrogen water alloy ceramic appearance assumption diagram that the embodiment of the present invention 2 prepares;
Fig. 3 is the manufacture rich hydrogen water alloy ceramic appearance assumption diagram that the embodiment of the present invention 4 prepares;
Fig. 4 is the manufacture rich hydrogen water alloy ceramic appearance assumption diagram that the embodiment of the present invention 5 prepares.
Embodiment
Below in conjunction with embodiment, the present invention will be further described.
The all raw materials used in embodiment, except specified otherwise, are commercial.
Embodiment 1
Described manufacture rich hydrogen water alloy ceramic, be made up of the raw material of following parts by weight:
Substrate component 57 parts, hydrogen-rich component 40 parts, antibacterial components 13 parts and binding agent 16 parts;
Described substrate component is made up of the raw material of following weight percentage:
Tourmalinite 32%, water unit stone 20%, silicon oxide 28%, calcium oxide 10% and zeolite 10%.
Described hydrogen-rich component is made up of the raw material of following weight percentage:
Metal magnesium powder 30%, magnesia powder 20% and KDF powdered alloy 50%.
Described antibacterial components is made up of the raw material of following weight percentage:
Zinc oxide 20%, titanium oxide 50% and cerium oxide 30%.
Described binding agent is made up of the raw material of following weight percentage:
High-purity distilled water 30%, carboxy-propyl cellulose 30% and wilkinite 40%.
Described preparation method:
(1) pre-treatment:
By tourmalinite, water unit stone, silicon oxide, calcium oxide and zeolite mixed grinding 6h, to diameter of particle < 500 μm, obtain substrate component;
By zinc oxide, titanium oxide, cerium oxide mixed grinding 8h, to diameter of particle < 50 μm, obtain antibacterial components;
Metal magnesium powder, magnesia powder and KDF powdered alloy are mixed, obtains hydrogen-rich component;
High-purity distilled water, carboxy-propyl cellulose and wilkinite are mixed, obtains binding agent;
(2) batch mixing: substrate component, hydrogen-rich component and antibacterial components are added mixer by ratio of components, mixes 1 hour;
(3) shaping: it is shaping that the material of mixing step (2) prepared joins nodulizer, and moulding process constantly sprays binding agent;
(4) cure, screen: the shaping rear material that step (3) prepares is carried out curing, screening, obtain described manufacture rich hydrogen water alloy ceramic.
Wherein, stoving temperature is 150 DEG C, and the time of curing is 2h.
Described manufacture rich hydrogen water alloy ceramic shape is granule type.
Embodiment 2
Described manufacture rich hydrogen water alloy ceramic, be made up of the raw material of following parts by weight:
Substrate component 60 parts, hydrogen-rich component 50 parts, antibacterial components 20 parts and binding agent 12 parts;
Described substrate component is made up of the raw material of following weight percentage:
Tourmalinite 25%, water unit stone 10%, silicon oxide 20%, calcium oxide 20% and zeolite 25%.
Described hydrogen-rich component is made up of the raw material of following weight percentage:
Metal magnesium powder 40%, magnesia powder 20% and KDF powdered alloy 40%.
Described antibacterial components is made up of the raw material of following weight percentage:
Zinc oxide 30%, titanium oxide 50% and cerium oxide 20%.
Described binding agent is made up of the raw material of following weight percentage:
High-purity distilled water 40%, carboxy-propyl cellulose 10% and wilkinite 50%.
Described preparation method:
(1) pre-treatment:
By tourmalinite, water unit stone, silicon oxide, calcium oxide and zeolite mixed grinding 7h, to diameter of particle < 500 μm, obtain substrate component;
By zinc oxide, titanium oxide, cerium oxide mixed grinding 6h, to diameter of particle < 50 μm, obtain antibacterial components;
Metal magnesium powder, magnesia powder and KDF powdered alloy are mixed, obtains hydrogen-rich component;
High-purity distilled water, carboxy-propyl cellulose and wilkinite are mixed, obtains binding agent;
(2) batch mixing: substrate component, hydrogen-rich component and antibacterial components are added mixer by ratio of components, mixes 2 hours;
(3) shaping: it is shaping that the material of mixing step (2) prepared joins nodulizer, and moulding process constantly sprays binding agent;
(4) cure, screen: the shaping rear material that step (3) prepares is carried out curing, screening, obtain described manufacture rich hydrogen water alloy ceramic.
Wherein, stoving temperature is 200 DEG C, and the time of curing is 1.5h.
Described manufacture rich hydrogen water alloy ceramic shape is granule type.
Embodiment 3
Described manufacture rich hydrogen water alloy ceramic, be made up of the raw material of following parts by weight:
Substrate component 40 parts, hydrogen-rich component 30 parts, antibacterial components 15 parts and binding agent 20 parts;
Described substrate component is made up of the raw material of following weight percentage:
Tourmalinite 20%, water unit stone 15%, silicon oxide 35%, calcium oxide 15% and zeolite 15%.
Described hydrogen-rich component is made up of the raw material of following weight percentage:
Metal magnesium powder 50%, magnesia powder 30% and KDF powdered alloy 20%.
Described antibacterial components is made up of the raw material of following weight percentage:
Zinc oxide 40%, titanium oxide 40% and cerium oxide 20%.
Described binding agent is made up of the raw material of following weight percentage:
High-purity distilled water 50%, carboxy-propyl cellulose 30% and wilkinite 20%.
Described preparation method:
(1) pre-treatment:
By tourmalinite, water unit stone, silicon oxide, calcium oxide and zeolite mixed grinding 8h, to diameter of particle < 500 μm, obtain substrate component;
By zinc oxide, titanium oxide, cerium oxide mixed grinding 7h, to diameter of particle < 50 μm, obtain antibacterial components;
Metal magnesium powder, magnesia powder and KDF powdered alloy are mixed, obtains hydrogen-rich component;
High-purity distilled water, carboxy-propyl cellulose and wilkinite are mixed, obtains binding agent;
(2) batch mixing: substrate component, hydrogen-rich component and antibacterial components are added mixer by ratio of components, mixes 3 hours;
(3) shaping: it is shaping that the material of mixing step (2) prepared joins nodulizer, and moulding process constantly sprays binding agent;
(4) cure, screen: the shaping rear material that step (3) prepares is carried out curing, screening, obtain described manufacture rich hydrogen water alloy ceramic.
Wherein, stoving temperature is 300 DEG C, and the time of curing is 1.5h.
Described manufacture rich hydrogen water alloy ceramic shape is granule type.
Embodiment 4
Described manufacture rich hydrogen water alloy ceramic, be made up of the raw material of following parts by weight:
Substrate component 85 parts, hydrogen-rich component 60 parts, antibacterial components 25 parts and binding agent 25 parts;
Described substrate component is made up of the raw material of following weight percentage:
Tourmalinite 40%, water unit stone 11%, silicon oxide 25%, calcium oxide 12% and zeolite 12%.
Described hydrogen-rich component is made up of the raw material of following weight percentage:
Metal magnesium powder 60%, magnesia powder 30% and KDF powdered alloy 10%.
Described antibacterial components is made up of the raw material of following weight percentage:
Zinc oxide 50%, titanium oxide 40% and cerium oxide 10%.
Described binding agent is made up of the raw material of following weight percentage:
High-purity distilled water 60%, carboxy-propyl cellulose 10% and wilkinite 30%.
Described preparation method:
(1) pre-treatment:
By tourmalinite, water unit stone, silicon oxide, calcium oxide and zeolite mixed grinding 9h, to diameter of particle < 500 μm, obtain substrate component;
By zinc oxide, titanium oxide, cerium oxide mixed grinding 10h, to diameter of particle < 50 μm, obtain antibacterial components;
Metal magnesium powder, magnesia powder and KDF powdered alloy are mixed, obtains hydrogen-rich component;
High-purity distilled water, carboxy-propyl cellulose and wilkinite are mixed, obtains binding agent;
(2) batch mixing: substrate component, hydrogen-rich component and antibacterial components are added mixer by ratio of components, mixes 4 hours;
(3) shaping: it is shaping that the material of mixing step (2) prepared joins stamping machine, and moulding process constantly sprays binding agent;
(4) cure, screen: the shaping rear material that step (3) prepares is carried out curing, screening, obtain described manufacture rich hydrogen water alloy ceramic.
Wherein, stoving temperature is 400 DEG C, and the time of curing is 1h.
Described manufacture rich hydrogen water alloy ceramic shape is wafer type.
Embodiment 5
Described manufacture rich hydrogen water alloy ceramic, be made up of the raw material of following parts by weight:
Substrate component 30 parts, hydrogen-rich component 50 parts, antibacterial components 10 parts and binding agent 20 parts;
Described substrate component is made up of the raw material of following weight percentage:
Tourmalinite 23%, water unit stone 14%, silicon oxide 22%, calcium oxide 11% and zeolite 30%.
Described hydrogen-rich component is made up of the raw material of following weight percentage:
Metal magnesium powder 30%, magnesia powder 40% and KDF powdered alloy 30%.
Described antibacterial components is made up of the raw material of following weight percentage:
Zinc oxide 50%, titanium oxide 20% and cerium oxide 30%.
Described binding agent is made up of the raw material of following weight percentage:
High-purity distilled water 40%, carboxy-propyl cellulose 50% and wilkinite 10%.
Described preparation method:
(1) pre-treatment:
By tourmalinite, water unit stone, silicon oxide, calcium oxide and zeolite mixed grinding 10h, to diameter of particle < 500 μm, obtain substrate component;
By zinc oxide, titanium oxide, cerium oxide mixed grinding 9h, to diameter of particle < 50 μm, obtain antibacterial components;
Metal magnesium powder, magnesia powder and KDF powdered alloy are mixed, obtains hydrogen-rich component;
High-purity distilled water, carboxy-propyl cellulose and wilkinite are mixed, obtains binding agent;
(2) batch mixing: substrate component, hydrogen-rich component and antibacterial components are added mixer by ratio of components, mixes 5 hours;
(3) shaping: it is shaping that the material of mixing step (2) prepared joins stamping machine, and moulding process constantly sprays binding agent;
(4) cure, screen: the shaping rear material that step (3) prepares is carried out curing, screening, obtain described manufacture rich hydrogen water alloy ceramic.
Wherein, stoving temperature is 480 DEG C, and the time of curing is 0.5h.
Described manufacture rich hydrogen water alloy ceramic shape is wafer type.
Embodiment 6
Described manufacture rich hydrogen water alloy ceramic, be made up of the raw material of following parts by weight:
Substrate component 70 parts, hydrogen-rich component 25 parts, antibacterial components 5 parts and binding agent 30 parts;
Described substrate component is made up of the raw material of following weight percentage:
Tourmalinite 20%, water unit stone 10%, silicon oxide 25%, calcium oxide 35% and zeolite 10%.
Described hydrogen-rich component is made up of the raw material of following weight percentage:
Metal magnesium powder 20%, magnesia powder 60% and KDF powdered alloy 20%.
Described antibacterial components is made up of the raw material of following weight percentage:
Zinc oxide 40%, titanium oxide 30% and cerium oxide 30%.
Described binding agent is made up of the raw material of following weight percentage:
High-purity distilled water 30%, carboxy-propyl cellulose 40% and wilkinite 30%.
Described preparation method:
(1) pre-treatment:
By tourmalinite, water unit stone, silicon oxide, calcium oxide and zeolite mixed grinding 8h, to diameter of particle < 500 μm, obtain substrate component;
By zinc oxide, titanium oxide, cerium oxide mixed grinding 8h, to diameter of particle < 50 μm, obtain antibacterial components;
Metal magnesium powder, magnesia powder and KDF powdered alloy are mixed, obtains hydrogen-rich component;
High-purity distilled water, carboxy-propyl cellulose and wilkinite are mixed, obtains binding agent;
(2) batch mixing: substrate component, hydrogen-rich component and antibacterial components are added mixer by ratio of components, mixes 4 hours;
(3) shaping: it is shaping that the material of mixing step (2) prepared joins stamping machine, and moulding process constantly sprays binding agent;
(4) cure, screen: the shaping rear material that step (3) prepares is carried out curing, screening, obtain described manufacture rich hydrogen water alloy ceramic.
Wherein, stoving temperature is 300 DEG C, and the time of curing is 1h.
Described manufacture rich hydrogen water alloy ceramic shape is diamond type.
Embodiment 7
Described manufacture rich hydrogen water alloy ceramic, be made up of the raw material of following parts by weight:
Substrate component 60 parts, hydrogen-rich component 50 parts, antibacterial components 20 parts and binding agent 12 parts;
Described substrate component is made up of the raw material of following weight percentage:
Tourmalinite 23%, water unit stone 14%, silicon oxide 22%, calcium oxide 11% and zeolite 30%.
Described hydrogen-rich component is made up of the raw material of following weight percentage:
Metal magnesium powder 20%, magnesia powder 60% and KDF powdered alloy 20%.
Described antibacterial components is made up of the raw material of following weight percentage:
Zinc oxide 40%, titanium oxide 40% and cerium oxide 20%.
Described binding agent is carboxy-propyl cellulose.
Described preparation method:
(1) pre-treatment:
By tourmalinite, water unit stone, silicon oxide, calcium oxide and zeolite mixed grinding 8h, to diameter of particle < 500 μm, obtain substrate component;
By zinc oxide, titanium oxide, cerium oxide mixed grinding 7h, to diameter of particle < 50 μm, obtain antibacterial components;
Metal magnesium powder, magnesia powder and KDF powdered alloy are mixed, obtains hydrogen-rich component;
(2) batch mixing: substrate component, hydrogen-rich component and antibacterial components are added mixer by ratio of components, mixes 3 hours;
(3) shaping: it is shaping that the material of mixing step (2) prepared joins nodulizer, and moulding process constantly sprays binding agent;
(4) cure, screen: the shaping rear material that step (3) prepares is carried out curing, screening, obtain described manufacture rich hydrogen water alloy ceramic.
Wherein, stoving temperature is 250 DEG C, and the time of curing is 2h.
Described manufacture rich hydrogen water alloy ceramic shape is granule type.
Manufacture embodiment 3 prepared rich hydrogen water alloy ceramic deionized water rinsing is clean.50 grams of alloy ceramsite materials are put into beaker, pours 200mL pure water into, test the hydrogen richness of 5 minutes, 10 minutes, 60 minutes and 720 minutes, pH value, TDS value and ORP value respectively, test result is in table 1.
Hydrogen richness detects and adopts U.S.'s Honeywell HoneywellXP-H2 hydrogen detector; PH detects and adopts high precision band temperature compensation pH potential of hydrogen test pen acidometer p-II; TDS detects and adopts conductive solid particles TDS tester (Korean company production); ORP detects and adopts Shenzhen to produce MT-8050 type pen type ORP (redox potential).
The test result after the manufacture rich hydrogen water alloy ceramic that embodiment 3 prepares is added in table 1 pure water
| 5 minutes | 10 minutes | 60 minutes | 720 minutes | |
| Hydrogen richness (ppb) | 560 | 650 | 850 | 1050 |
| PH value | 8.3 | 8.5 | 8.8 | 9.2 |
| TDS value (ppm) | 163 | 173 | 182 | 214 |
| ORP value (mV) | -87 | -123 | -155 | -255 |
The manufacture prepared by embodiment 1-7 rich hydrogen water alloy ceramic is used for manufacturing rich hydrogen water in water tumbler, and carries out a series of test to the rich hydrogen water generated.
(1) pH value of rich hydrogen water and pure water is tested
Pure water and each one glass of Fu Qing water, respectively put in a cup with precise chemical reagents paper and shake (or instillation pH value reagent).Test-results: the chemical reagent paper color in pure water is yellow, and pH value is 5.5; Chemical reagent paper in rich hydrogen water is blue (becoming small-micelle water) pH value is 8.2-9.5.
(2) comparison of tap water and Fu Qing bubble green tea, milk powder, bean powder is tested
To have made tea bitter taste and chlorinated lime taste with tap water, bubble bean powder indissoluble solution, making milk powder indissoluble also has fishy smell.Obviously reduce with rich hydrogen bubble tea or there is no bitter taste, tea flavour fragrance; Bean powder, milk powder are just washed open quickly, and pleasant aroma.
(3) the little tomato of rich hydrogen water soaking is tested
Rich hydrogen water and tap water or each one glass of pure water, respectively put into several little tomatoes and soak 5-10 minute, the tomato soaking rich hydrogen water overworked small bubbles, has touched texture comparatively hard, taste taste more fragrant with hand; Soak the little tomato of tap water or pure water without any change.
(4) rich hydrogen water cola experiment
Pour rich hydrogen water in glass cylinder (1/10), instillation 2-3 drips pH reagent, and display is blue, illustrates that rich hydrogen water is weakly alkaline (representing the environment of healthy body); Pour a little cola into glass cylinder, the color table that reddens shows laughable for acid, illustrates that drinking laughable rear internal milieu is strongly-acid.Injected by rich hydrogen water and laughable glass cylinder is housed, color becomes blueness, represents that rich hydrogen water can neutralize laughable acidity.
(5) experiment of rich hydrogen water and glucose
Glucose implantation glass cup (1/5), instillation 2-3 are dripped pH reagent, becomes red and represent that glucose is strongly-acid (representing that diabetics is for acidic constitution with this).Rich hydrogen water is injected the glass cylinder that glucose is housed, color becomes blueness, represent rich hydrogen water can in and the acidity of glucose.
(6) rich hydrogen water soluble oil experiment
Required article: transparent water cup 5-6, pH reagent one bottle, pH value contrast table one, edible oil one bottle, chopsticks a pair of.
Get the oil (1/3 glass) that two water tumblers add equivalent respectively, then one glass of rich hydrogen water of access, one glass of access tap water, stirs with chopsticks, respectively until the water tumbler of rich hydrogen water cannot see water.The oil poured in cup represents fat unnecessary in human body and oily substance, and the molecular grouping of rich hydrogen water is little, and active strong, dissolving power is strong, can dissolve emulsified fat, and tap water belongs to macromolecular mass water, does not decompose emulsifying effect.
(7) Fu Qing is hydrolyzed tea experiment
Required article: transparent water cup 5-6, pH reagent one bottle, pH value contrast table one, tealeaves (Iron Guanyin, can not be too dry, and coarse tealeaves effect is best) one bag.Get the tealeaves that two water tumblers put into equivalent respectively, one glass of rich hydrogen water of access, one glass of access tap water, when can find that the color of rich hydrogen water has dark brown, tap water or colourless.The water clusters of rich hydrogen water is little, and by force, be easy to the composition in tea to bubble out, and the water clusters of tap water is large, seepage force is poor, so tea does not become color for decomposition, penetrating power.
(8) tincture of iodine reduction experiment
Required article: transparent water cup 5-6, pH reagent one bottle, pH value contrast table one, one bottle, the tincture of iodine, rice, chopsticks a pair of.Two water tumblers put into respectively by the rice taken a morsel, add a small amount of tap water (covering rice), then add 3-4 and drip the tincture of iodine, stir, at this moment water and rice all blackening; Then, one glass adds rich hydrogen water, one glass of tap water adding equivalent, at this moment: the cup water adding rich hydrogen water has become clear, meter Bian Bai, and the not change of water base of the cup adding tap water.
(9) conduction experiment
Required article: transparent large water tumbler 5-6, pH reagent one bottle, pH value contrast table one, pure water one bottle, band plug electric wire (about 2 meters) one end connect socket and bulb, will wherein disconnect by a strand from centre.Get rich hydrogen water and pure water that two cups add equivalent respectively, first connected by the electric wire of disconnection, plug in, bulb is light, illustrates that bulb is good; Opened by the line connected, put into pure water, bulb does not work, and pure water is described not containing mineral substance and trace element; Put into the bright horse back of rich hydrogen water lamp more light, the mineral substance of rich hydrogen water containing abundant ion like is described.
Claims (10)
1. manufacture a rich hydrogen water alloy ceramic, it is characterized in that: be made up of the raw material of following parts by weight: substrate component 30-85 part, hydrogen-rich component 20-60 part, antibacterial components 2-25 part and binding agent 3-30 part;
Wherein,
Substrate component is made up of tourmalinite, water unit stone, silicon oxide, calcium oxide and zeolite;
Hydrogen-rich component is made up of metal magnesium powder, magnesia powder and KDF powdered alloy;
Antibacterial components is made up of zinc oxide, titanium oxide and cerium oxide;
Binding agent is one or more in high-purity distilled water, carboxy-propyl cellulose or wilkinite.
2. manufacture according to claim 1 rich hydrogen water alloy ceramic, is characterized in that: substrate component is made up of the raw material of following weight percentage:
Tourmalinite 20-45%, water unit stone 10-30%, silicon oxide 20-45%, calcium oxide 10-35% and zeolite 10-30%.
3. manufacture according to claim 1 rich hydrogen water alloy ceramic, is characterized in that: hydrogen-rich component is made up of the raw material of following weight percentage:
Metal magnesium powder 20-60%, magnesia powder 20-60% and KDF powdered alloy 10-50%.
4. manufacture according to claim 3 rich hydrogen water alloy ceramic, is characterized in that: the particle diameter of metal magnesium powder, magnesia powder and KDF powdered alloy is 30-100 μm.
5. manufacture according to claim 1 rich hydrogen water alloy ceramic, is characterized in that: antibacterial components is made up of the raw material of following weight percentage:
Zinc oxide 20-50%, titanium oxide 20-50% and cerium oxide 5-30%.
6. manufacture according to claim 1 rich hydrogen water alloy ceramic, is characterized in that: binding agent is made up of the raw material of following weight percentage:
High-purity distilled water 30-65%, carboxy-propyl cellulose 10-30% and wilkinite 20-50%.
7. a preparation method for the arbitrary described manufacture of claim 1-6 rich hydrogen water alloy ceramic, is characterized in that: comprise the steps:
(1) pre-treatment:
By tourmalinite, water unit stone, silicon oxide, calcium oxide and zeolite mixed grinding 6-10h, to diameter of particle < 500 μm, obtain substrate component;
By zinc oxide, titanium oxide, cerium oxide mixed grinding 6-10h, to diameter of particle < 50 μm, obtain antibacterial components;
Metal magnesium powder, magnesia powder and KDF powdered alloy are mixed, obtains hydrogen-rich component;
High-purity distilled water, carboxy-propyl cellulose and wilkinite are mixed, obtains binding agent;
(2) batch mixing: substrate component, hydrogen-rich component and antibacterial components are added mixer by ratio of components, mixing 1-5 hour;
(3) shaping: the material of mixing step (2) prepared joins nodulizer or stamping machine is shaping, and moulding process constantly sprays binding agent;
(4) cure, screen: the shaping rear material that step (3) prepares is carried out curing, screening, obtain described manufacture rich hydrogen water alloy ceramic.
8. the preparation method of manufacture according to claim 7 rich hydrogen water alloy ceramic, is characterized in that: stoving temperature is 150-480 DEG C, and the time of curing is 0.5-2h.
9. the preparation method of manufacture according to claim 7 rich hydrogen water alloy ceramic, is characterized in that: described manufacture rich hydrogen water alloy ceramic shape is granule type, wafer type, column type, diamond type, cast or cardioid.
10. the application of a manufacture according to claim 1 rich hydrogen water alloy ceramic, it is characterized in that: be applied in water purifier, purifying kettle, water tumbler and humidifier product, can also be used in deodorizing scrubbing, aquaculture, flower planting, health care and beauty treatment industry.
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