CN106219693A - Special tourmaline ceramic filter element and preparation method thereof and the strong anti-oxidation obtained by its process, subset reductive water - Google Patents
Special tourmaline ceramic filter element and preparation method thereof and the strong anti-oxidation obtained by its process, subset reductive water Download PDFInfo
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- CN106219693A CN106219693A CN201610768342.7A CN201610768342A CN106219693A CN 106219693 A CN106219693 A CN 106219693A CN 201610768342 A CN201610768342 A CN 201610768342A CN 106219693 A CN106219693 A CN 106219693A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
- C02F1/4676—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electroreduction
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
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Abstract
The invention discloses special tourmaline ceramic filter element and preparation method thereof and processed strong anti-oxidation, the subset reductive water obtained by it, belong to the function water of health field, this special tourmaline ceramic filter element is prepared by following raw material, described raw material includes in parts by weight: by tourmaline powder 35～60 parts, dolomite 18～28 parts, crystal quartz 15～25 parts, clay 4～7 parts, potassium feldspar 3～5 parts, zeolite 2～4 parts, water 10～15 parts, through batch mixing, pulverize, refine base molding, sinter at a temperature of 1080～1200 DEG C, obtain finished product.After filter element processes water, obtain strong anti-oxidation, subset reductive water, useful health and rehabilitation.
Description
Technical field
The invention belongs to the function water of health field, be specifically related to a kind of special tourmaline ceramic filter element and preparation method thereof
With the strong anti-oxidation obtained by its process, subset reductive water.
Background technology
Hydrone (H2O) it is the most weak electrolyte, but it reversibility can ionize out hydrion (H at normal temperatures+) and hydroxyl
Ion (OH-), hydrion loses an electronics at anode, and in positive potential, hydroxide ion is nagative potential (equation at negative electrode
①)。
When electrically decomposing, under the effect of electric field, the hydrion of positively charged position face south Ghandler motion move, it is thus achieved that electronics becomes negative electricity
Reactive hydrogen (the i.e. negative hydrogen ion H that position reproducibility is extremely strong-), it is combined with each other as hydrogen (equation between part hydrogen atom therein
②)。
Hydroxide ion loses electronics under electric field action, on the sunny side Ghandler motion move, way in its part hydroxide ion with do not join
With the negative oxygen ion OH (H that the water molecules of electrolysis becomes to be referred to as natural complex2O), in alkalescence (equation is 3.).And
Additionally the hydroxide ion of part loses an electronics at anode, defines (OH) hydroxy radical.On general oxygen band one
Electronics has reformed into super oxygen (O2 -), carry two electronics to reform into hydrogen peroxide (H2O2) (equation is 4.), hydrogen peroxide once
Decompose and create (OH) hydroxy radical (also known as hydroxyl free radical) (equation is 5.) too.Super oxygen (O2 -), hydrogen peroxide
(H2O2), hydroxyl free radical be referred to as reactive oxygen free radical.
(OH) activity of hydroxy radical is the thousands of times of oxygen, extremely unstable.It can kill the erythrocyte in human body, fall
Solve DNA, cell membrane and multiple sugar compounds, it the disease states caused has: the early brain such as dementia from brain disease disease, parkinson
Illness, also cancer, coronary heart disease, essential hypertension, diabetes, arteriosclerosis, gout, various calculus, liver-kidney diseases, banding bleb
Hundreds of illness such as rash, Corii Bovis seu Bubali moss, cyst, fatty liver.(see The 2nd Army Medical College publish " electrolysis water-----life
Running water " book).The new book that People's Health Publisher publishes----" anticancer have new ideas, active oxygen of keeping under strict control " is write: " hydroxyl is freely
The oxidability of base is the strongest in known substance, and its carciongenic potency is the strongest in known 1,100 kinds of carcinogens simultaneously.……
Hydroxy radical is carcinogenic arch-criminal.”.
Human body is made up of countless cellular, internal unnecessary reactive oxygen free radical rob everywhere in organ cell electronics with
Making oneself to match, those have been ransacked of electronics and impaired cell just creates above-mentioned various chronic disease.And reproducibility is extremely strong
Reactive hydrogen obtain electronics at negative electrode and enter cell with small-micelle water, have in substantial amounts of reactive hydrogen gives damaged cell one
Individual electronics, makes normal cell.Have to one electronics of hydroxy radical of being detrimental to health, made harmless
Hydrone (equation is 6.).
Equation is 1.
Equation 2. H+H → H2↑
Equation 3. OH+H2O→OH(H2O)
Equation 4. O2+e+2H→H2O2
Equation 5. H2O2+e→2(·OH)
Equation 6. OH+e+H → H2O
Electrolytic reduction water and health
" scientist is analyzed according to a large amount of tune amount results that world's longevity is regional all over the world, proposes high-quality and drinks
6 standards of water:
1, the physical property of harmful health, chemical and biologic contamination are not contained.
2, containing suitable useful health the mineral in ionic condition and trace element, it is suitable for absorption of human body.
3, the pH value of water is alkalescence, can neutralize the many spent acid element in human body.
4, water clusters is little, and dissolving power and penetration are strong.
5, in nagative potential, unnecessary free radical in human body can be eliminated.
6, containing appropriate oxygen (about 5mg/L).
Up to the present, only find that electrolytic reduction water can comply fully with above standard.Electrolytic reduction water is not only suitable for
Healthy People long-term drink, and because of it have significantly regulate gastrointestinal function, regulation blood refer to, antioxidation, fatigue-resisting function, because of
This also is adapted for sub-health population and patient drinks, and is the high-tech Drinking Water that 21 century can bring health to the mankind.”
------selects from military medicine Science Press " electrolysis water challenge subhealth state " pottery state pivot Zhang Huazhu.
Summary of the invention
First technical problem to be solved by this invention is to provide a kind of special tourmaline ceramic filter element, and this tourmaline is special
Kind of ceramic element raw material includes in parts by weight: tourmaline powder 35～60 parts, dolomite 18～28 parts, crystal quartz 15～
25 parts, clay 4～7 parts, potassium feldspar 3～5 parts, zeolite 2～4 parts, water 10～15 parts.
Wherein, in above-mentioned special tourmaline ceramic filter element, the particle diameter of described tourmaline powder is 0.035～0.06um.
Wherein, in above-mentioned special tourmaline ceramic filter element, the chemical composition of described tourmaline powder is wrapped by percentage to the quality
Include: SiO237～70%, CaO 15～22%, Al2O39～15%, MgO 2～11%, Fe2O31.5～3.5%, K2O
0.6～1.4%, Na2O 0.3～0.6%.
Wherein, in above-mentioned special tourmaline ceramic filter element, described clay is Kaolin, its Al2O3Mass content at least exists
More than 9%, SiO2Mass content is at least more than 58%.
Second technical problem to be solved by this invention is to provide the preparation method of above-mentioned special tourmaline ceramic filter element,
This preparation method comprises the following steps:
(1), by tourmaline powder 35～60 parts, dolomite 18～28 parts, crystal quartz 15～25 parts, clay 4～7 parts, potassium
Anhydrite 3～5 parts, zeolite 2～4 parts, mix homogeneously, obtain mixture；
(2), by said mixture being crushed to particle diameter is 0.035～0.01um, addition water 10～15 parts, refines after mix homogeneously
Become moulded pottery not yet put in a kiln to bake；
(3), treat that above-mentioned moulded pottery not yet put in a kiln to bake makes type at mould inner pressure, be dried, obtain shaping blank, by blank at 1080～1200 DEG C
At a temperature of sinter, be incubated 2～4h, make special tourmaline ceramic filter element after cooling.
Wherein, in the preparation method of above-mentioned special tourmaline ceramic filter element, the particle diameter of described tourmaline powder be 0.035～
0.06um。
Wherein, in the preparation method of above-mentioned special tourmaline ceramic filter element, the chemical composition of described tourmaline powder is with quality
Percentages includes: SiO237～70%, CaO 15～22%, Al2O39～15%, MgO 2～11%, Fe2O31.5～
3.5%, K2O 0.6～1.4%, Na2O 0.3～0.6%.
Wherein, in the preparation method of above-mentioned special tourmaline ceramic filter element, described clay is Kaolin, its Al2O3Quality contains
Measure at least more than 9%, SiO2Mass content is at least more than 58%.
3rd technical problem to be solved by this invention is to provide by above-mentioned special tourmaline ceramic filter element by micro-electricity
Solve strong anti-oxidation, subset reductive water that hydrone prepares.
The invention has the beneficial effects as follows: the tourmaline powder particle diameter preparing reductive water in the present invention only has 0.035～0.06um,
Substantially increase the contact area of tourmaline powder and hydrone, can fully produce the negative of removable free radical after light electrolysis effect
Hydrion and far infrared, and the macromolecular mass of water changed into the subset compared with the least several times of human body cell by far-infrared engergy
Water.And process the small-micelle water obtained through carrier ceramic element of the present invention, there is alkalescence, reproducibility and strong anti-oxidation energy
Power, more conducively human body cell absorb, and useful health and rehabilitation " are the high-tech that 21 century can bring health to the mankind
Drinking Water.”
Detailed description of the invention
The invention provides a kind of special tourmaline ceramic filter element controlling the water circulation carrier, special tourmaline ceramic filter element, this is electric
Stone special cermacis filter element raw material includes in parts by weight: tourmaline powder 35～60 parts, dolomite 18～28 parts, crystal quartz
15～25 parts, clay 4～7 parts, potassium feldspar 3～5 parts, zeolite 2～4 parts, water 10～15 parts.
Wherein, in above-mentioned special tourmaline ceramic filter element, the particle diameter of described tourmaline powder is 0.035～0.06um, described
The chemical composition of tourmaline powder includes by percentage to the quality: SiO237～70%, CaO 15～22%, Al2O39～15%,
MgO 2～11%, Fe2O31.5～3.5%, K2O 0.6～1.4%, Na2O 0.3～0.6%.
Wherein, in above-mentioned special tourmaline ceramic filter element, described clay is Kaolin, its Al2O3Mass content at least exists
More than 9%, SiO2Mass content is at least more than 58%.
Further, present invention also offers the preparation method of above-mentioned special tourmaline ceramic filter element, this preparation method bag
Include following steps:
(1), by tourmaline powder 35～60 parts, dolomite 18～28 parts, crystal quartz 15～25 parts, clay 4～7 parts, potassium
Feldspar powder 3～5 parts, zeolite 2～4 parts, mix homogeneously, obtain mixture；
(2), by said mixture being crushed to particle diameter is 0.035～0.01um, addition water 10～15 parts, refines after mix homogeneously
Become moulded pottery not yet put in a kiln to bake；
(3), treat that above-mentioned moulded pottery not yet put in a kiln to bake makes type at mould inner pressure, be dried, obtain shaping blank, by blank at 1080～1200 DEG C
At a temperature of sinter, be incubated 2～4h, make special tourmaline ceramic filter element after cooling.
Wherein, in the preparation method of above-mentioned special tourmaline ceramic filter element, the particle diameter of described tourmaline powder be 0.035～
0.06um；Its chemical composition includes by percentage to the quality: SiO237～70%, CaO 15～22%, Al2O39～15%,
MgO 2～11%, Fe2O31.5～3.5%, K2O 0.6～1.4%, Na2O 0.3～0.6%.
Wherein, in the preparation method of above-mentioned special tourmaline ceramic filter element, described clay is Kaolin, its Al2O3Quality contains
Measure at least more than 9%, SiO2Mass content is at least more than 58%.
Further, present invention also offers and prepared by micro-electrolytic water molecule by above-mentioned special tourmaline ceramic filter element
The strong anti-oxidation that obtains, subset reductive water.
The present invention utilizes tourmaline light electrolysis principle, is smashed by tourmaline to particle diameter between 0.035～0.06um, significantly
Improve the contact area of tourmaline powder and hydrone, and by scientific matching raw material, fully have activated tourmaline inherent
Electrode produce electric field action and reduction, can fully produce after light electrolysis effect removable free radical negative hydrogen ion and
Far infrared, the water after filter element of the present invention processes has alkalescence, strong anti-oxidation, subset and reproducibility.Produce
Macromolecular mass water is changed into the small-micelle water compared with the least several times of human body cell by far-infrared engergy, and (subset is less than 0.1nm
Below), human body cell can be freely accessible to, allow cell refill vigor, utilize the reproducibility of water to remove oxygen-derived free radicals, and carry
Beneficial mineral matter and trace element enter cell (including damaged cell and cancerous cell), produce rehabilitation and suppression function, useful people
Body health and rehabilitation.Many medical experts praise for subset water spot, say that small-micelle water is that human health is with long-lived
Source, famous American scientist Peter Ah Gray say: boy divides a water to be freely accessible to cell membrane, is the answer to a riddle of Human Longevity.
Filter element of the present invention processes its small-micelle water of subset reductive water obtained and may diminish to one times of concentration reductive water
Pouring in the pure water of 100 times, moment can make 100 times of pure water all become antioxidation reductive water in 1 second, and one times concentrates also
Former water pours moment in the acid pure water of 400 times into all becomes alkalescent water, belongs to the most pioneering.
Below in conjunction with embodiment, the present invention is described in further detail, it should be appreciated that enforcement described herein
Example only in order to explain the present invention, is not intended to limit the present invention.
The chemical composition of tourmaline used in following embodiment includes by percentage to the quality: SiO252%, CaO
17%, Al2O313%, MgO 9%, Fe2O31.5%, K2O 0.9%, Na2O 0.4%；Al in Kaolin2O3Mass content exists
10%, SiO2Mass content is 60%.
Embodiment 1
Special tourmaline ceramic filter element prepares according to following steps:
(1), by tourmaline powder (particle diameter 0.06um) 40 parts, dolomite 20 parts, crystal quartz 12 parts, feldspar in powder 3 parts, height
Ridge soil 5 parts, 2 parts of zeolite, mix homogeneously, obtain mixture；
(2), by said mixture being crushed to particle diameter is 0.06um, adds 12 parts of water, is smelt moulded pottery not yet put in a kiln to bake after mix homogeneously；
(3), treat that above-mentioned moulded pottery not yet put in a kiln to bake makes type at mould inner pressure, be dried, obtain shaping blank, by blank at a temperature of 1080 DEG C
Sintering, is incubated 4h, makes special tourmaline ceramic filter element after cooling.
The strong anti-oxidation, the subset reductive water that are obtained by the present embodiment ceramic element microelectrolysis processing are designated as sample 1.
Embodiment 2
Special tourmaline ceramic filter element prepares according to following steps:
(1), by tourmaline powder (particle diameter 0.05um) 48 parts, 14 parts of crystal quartz powder, feldspar in powder 9 parts, Kaolin 6 parts,
Zeolite powder 2 parts, zirconium oxide 4 parts, titanium oxide 4 parts, bismuth oxide 5 parts and silver oxide 5 parts, mix homogeneously, obtain mixture；
(2), by said mixture being crushed to particle diameter is 0.05um, adds 15 parts of water, is smelt moulded pottery not yet put in a kiln to bake after mix homogeneously；
(3), treat that above-mentioned moulded pottery not yet put in a kiln to bake makes type at mould inner pressure, be dried, obtain shaping blank, by blank at a temperature of 1150 DEG C
Sintering, is incubated 2.5h, makes tourmaline functional ceramic filter element after cooling.
The strong anti-oxidation, the subset reductive water that are obtained by the present embodiment ceramic element microelectrolysis processing are designated as sample 2.
Embodiment 3
According to " Drinking Water transmission & distribution wetting system and protective material wholesomeness value disciplines " (2001), to above-mentioned system
The sample 1 and the sample 2 that obtain carry out wholesomeness inspection.
Wherein, the method for inspection uses " the drinking water standard method of inspection " (GB/T5750-2006), sample treatment
Carrying out according to " Drinking Water transmission & distribution wetting system and protective material wholesomeness value disciplines " (2001) appendix A, sample soaks
Soaked employing appendix A 1.3.1 saves configuration, soak time 24h ± 1h, soaking temperature 25 DEG C ± 5 DEG C.Testing result is shown in Table 1 (table 1
Only list several important detection projects, other detection projects such as: color, smelly and taste, naked eyes visible, total dissolved solid, arsenic, six
The index of valency cadmium, aluminum, lead, hydrargyrum, volatile phenol, carbon tetrachloride, silver, nitrate ferrum, manganese, copper and zinc all meets hygienic practice and wants
Ask, differ herein and one list).
Table 1. tourmaline functional ceramic filter element soaks water water examination result
Embodiment 4 verification sample 1 (pure water, tap water, alkalescent water) and sample 2 (micro-electrolytic water of the present invention)
Strong anti-oxidation, small-micelle water and reproducibility
1, strong anti-oxidation:
Sample 1 and sample 2 totally four transparent cups will be poured identical strong oxidizer iodine tincture 3～5 (representative work respectively into
Property oxygen-derived free radicals) in above 3 cups, respectively pour the pure water of 1/3 quantity, tap water and alkalescent water respectively into, in these three cups
Dilute the brown red color to represent strong acid respectively, and after only the reductive water of 1/5 being poured in the 4th cup, at once by Strong oxdiative
The iodine tincture maroon of thing all removes the transparent true qualities becoming water.
2, small-micelle water:
(1), the Folium Camelliae sinensis that takes equivalent put in two transparent cups, pour the cold water (tap water) of equivalent and light electrolysis into simultaneously
Small-micelle water, micromolecular water at once just can by Folium Camelliae sinensis juice color penetration out, and tap water is then still true qualities, if by little
Molecule tea juice water is poured in another cup tap water again and is then also become Umber at once.
(2), one bottle of slime water puts into a small amount of carrier of the present invention (tourmaline micropowder) tighten bottle cap, rock 10 seconds
Slime water is sunk to bottle by the small-micelle water that clock light electrolysis produces at once at the bottom of, bottle top reaches water quality transparent clear.
(3), in filling 1000 milliliters of acid pure water beakers, the concentration small-micelle water of 2 milliliters of present invention is only poured into,
By the acid water of 1:500 times within 1 second, all become and can change the alkalescent water that subhealth state human body is drunk.
3, reproducibility:
Instill in instant noodles with the iodine tincture of strong oxidizer, can see that instant noodles are oxidized into carbon black shape at once, will oxidation
After carbon black instant noodles be respectively put in two cups, then pour the reductive water of tap water and the present invention, reductive water after 2 minutes respectively into
Carbon black instant noodles Restore All is become white instant noodles, and the instant noodles in tap water are still that carbon black color.
The most several experiments all illustrate that micro-electrolytic water prepared by carrier of the present invention meets the strong anti-oxidation of the present invention, little molecule
The feature of group's reductive water.
Claims (9)
1. special tourmaline ceramic filter element, it is characterised in that described special tourmaline ceramic filter element raw material is in parts by weight
Including: tourmaline powder 35～60 parts, dolomite 18～28 parts, crystal quartz 15～25 parts, clay 4～7 parts, potassium feldspar 3～5
Part, zeolite 2～4 parts, water 10～15 parts.
Special tourmaline ceramic filter element the most according to claim 1, it is characterised in that the particle diameter of described tourmaline powder is
0.035～0.06um.
Special tourmaline ceramic filter element the most according to claim 1, it is characterised in that the chemical composition of described tourmaline powder
Include by percentage to the quality: SiO237～70%, CaO 15～22%, Al2O39～15%, MgO 2～11%, Fe2O3
1.5～3.5%, K2O 0.6～1.4%, Na2O 0.3～0.6%.
Special tourmaline ceramic filter element the most according to claim 1, it is characterised in that described clay is Kaolin, its
Al2O3Mass content at least more than 9%, SiO2Mass content is at least more than 58%.
5. the preparation method of special tourmaline ceramic filter element described in any one of Claims 1 to 4, it is characterised in that this preparation side
Method comprises the following steps:
(1), by tourmaline powder 35～60 parts, dolomite 18～28 parts, crystal quartz 15～25 parts, clay 4～7 parts, potassium feldspar 3
～5 parts, zeolite 2～4 parts, mix homogeneously, obtain mixture；
(2), by said mixture being crushed to particle diameter is 0.035～0.01um, addition water 10～15 parts, is smelt mud after mix homogeneously
Base；
(3), treat that above-mentioned moulded pottery not yet put in a kiln to bake makes type at mould inner pressure, be dried, obtain shaping blank, by blank 1080～1200 DEG C of temperature
Lower sintering, is incubated 2～4h, makes special tourmaline ceramic filter element after cooling.
The preparation method of special tourmaline ceramic filter element the most according to claim 5, it is characterised in that described tourmaline powder
Particle diameter is 0.035～0.06um.
The preparation method of special tourmaline ceramic filter element the most according to claim 5, it is characterised in that described tourmaline powder
Chemical composition includes by percentage to the quality: SiO237～70%, CaO 15～22%, Al2O39～15%, MgO 2～
11%, Fe2O31.5～3.5%, K2O 0.6～1.4%, Na2O 0.3～0.6%.
The preparation method of special tourmaline ceramic filter element the most according to claim 5, it is characterised in that described clay is kaolinite
Soil, its Al2O3Mass content at least more than 9%, SiO2Mass content is at least more than 58%.
9. a strong anti-oxidation, subset reductive water, it is characterised in that described reductive water is by electric described in Claims 1 to 4
Obtained by stone special cermacis filter element is by the preparation of micro-electrolytic water molecule.
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| CN106893645A (en) * | 2016-12-27 | 2017-06-27 | 广州舒泰生物技术有限公司 | A kind of method of electrolysis production small-micelle water and in household detergent application |
| CN108483803A (en) * | 2018-03-28 | 2018-09-04 | 广西金茂生物化工有限公司 | A method of handling cassava alcohol waste water using micro electrolysis tech |
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| CN106893645A (en) * | 2016-12-27 | 2017-06-27 | 广州舒泰生物技术有限公司 | A kind of method of electrolysis production small-micelle water and in household detergent application |
| CN108483803A (en) * | 2018-03-28 | 2018-09-04 | 广西金茂生物化工有限公司 | A method of handling cassava alcohol waste water using micro electrolysis tech |
| CN114249587A (en) * | 2021-12-20 | 2022-03-29 | 赵坚强 | Ceramic wafer for improving conductivity of pure water and manufacturing device thereof |
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Application publication date: 20161214 |