WO2010069097A1 - Ceramic material for purifying and activating water - Google Patents

Ceramic material for purifying and activating water Download PDF

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Publication number
WO2010069097A1
WO2010069097A1 PCT/CN2008/073503 CN2008073503W WO2010069097A1 WO 2010069097 A1 WO2010069097 A1 WO 2010069097A1 CN 2008073503 W CN2008073503 W CN 2008073503W WO 2010069097 A1 WO2010069097 A1 WO 2010069097A1
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Prior art keywords
ceramic material
purification
activation
health care
raw materials
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PCT/CN2008/073503
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French (fr)
Chinese (zh)
Inventor
方敬亮
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Fong King Leung
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Priority to PCT/CN2008/073503 priority Critical patent/WO2010069097A1/en
Publication of WO2010069097A1 publication Critical patent/WO2010069097A1/en

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/005Systems or processes based on supernatural or anthroposophic principles, cosmic or terrestrial radiation, geomancy or rhabdomancy
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/02Non-contaminated water, e.g. for industrial water supply
    • C02F2103/026Treating water for medical or cosmetic purposes

Definitions

  • the invention relates to a ceramic material, in particular to a ceramic material for purification, activation and health care.
  • the purified water is pure water, which has a good mouthfeel and does not contain any impurities. It is more suitable for brewing coffee, drinking tea, and patients with liver disease, kidney disease, cancer, and cancer.
  • Pure water does not contain beneficial minerals, and the pH value is not guaranteed. It is slightly alkaline; at the same time, pure water does not have vitality and is not suitable for long-term drinking water.
  • water molecules are associated together to form a macromolecular group.
  • the sun's rays can be roughly divided into visible light and invisible light.
  • the visible light passes through the prism and reflects the light (spectrum) of purple, blue, cyan, green, yellow, orange, and red colors.
  • the light outside the red light, in the spectrum from 0.76 to 400 microns, is called infrared light, also known as infrared light.
  • Infrared rays belong to the category of electromagnetic waves and are radiations with strong heat. Infrared has a wide wavelength range. Infrared rays of different wavelength ranges are divided into near-infrared, mid-infrared and far-infrared regions, and electromagnetic waves corresponding to wavelengths are called near-infrared, mid-infrared and far-infrared.
  • the technical problem to be solved by the present invention is to provide a ceramic material for purifying, activating and protecting health, which can provide trace elements, purify and activate water, has a simple manufacturing process, and is convenient to use.
  • a ceramic material for purifying and health care which is made of the following raw materials by weight: maifanite 23 ⁇ 50, diatomaceous earth 16 ⁇ 22, talc 6 ⁇ 16, tourmaline 25 ⁇ 48.
  • the ceramic material for purification and health care is preferably made of the following raw materials by weight: maifanite 30 ⁇ 40, diatomaceous earth 18 ⁇ 20, talc 8 ⁇ 12, tourmaline 38 ⁇ 36.
  • the ceramic material is prepared by pretreating the raw materials of maifanite, diatomaceous earth, talc and tourmaline to remove heavy metals and impurities, grinding, grinding, molding and firing.
  • the raw materials of the medical stone, diatomaceous earth, talc and tourmaline are pretreated by pickling, caustic washing, water washing, and then drying.
  • the acid selected for the pickling is hydrochloric acid or phosphoric acid.
  • the base selected for the alkaline washing is sodium hydroxide.
  • the fineness of the raw material medical stone, diatomaceous earth, talc and tourmaline is 80 to 200 turns.
  • the ball milling is to put the raw materials and water into a ball mill and ball-bonding, so that the raw materials are bonded together, and the ball milling time is 2 to 3 days.
  • the firing temperature is 1150 to 1280 ° C, and the firing time is 10 to 15 hours.
  • Medical stone is a biologically active mineral health medicine with the following health functions: 1.
  • the medical stone contains potassium, sodium, calcium, magnesium, phosphorus, titanium, manganese, strontium, cobalt, copper, zinc, lithium, More than 30 kinds of trace elements such as antimony, molybdenum, niobium, tantalum, tin, selenium, silicon and rare earth elements such as lanthanum, cerium, lanthanum and cerium.
  • trace elements such as antimony, molybdenum, niobium, tantalum, tin, selenium, silicon and rare earth elements such as lanthanum, cerium, lanthanum and cerium.
  • selenium, zinc and manganese are abundant, and the indispensable trace element minerals dissolved in the mineral water of medical stone can improve water quality.
  • the content of four trace elements (silicic acid, S r, Z n, F) in the maifan stone solution is close to or close to the national beverage mineral water standard, so it is a natural nutrient source.
  • maifan stone can release far infrared rays, far-infrared radiance at room temperature >0. 88 ⁇ 0. 92, antibacterial rate at room temperature (E. coli, Staphylococcus aureus) > 90%. Therefore, it can effectively inhibit bacterial growth, break the active bond of toxic substance structure, and exert a strong oxidative cleavage function. Decomposes carcinogenic organic molecules in contaminated water to prevent water from spoiling, resulting in high quality water. 3. Adjust the water quality.
  • Diatomaceous earth is an ancient seabed mineral, white sedimentary rock, light and porous. It is a diatom shell buried in the stratum. The minerals in the earth's crust are raised on the surface. The main chemical composition is oxides containing silicon, aluminum and iron. It is said to have a pore size of about 500 um, and the surface area is about 37.8 M 2 /g. The diatomaceous earth has excellent adsorption and good chemical inertness. The most important thing is that diatomaceous earth can release negative ions and release far infrared rays. .
  • Talc silicate a natural hydrous magnesium silicate mineral containing silicon and magnesium, has a health care medicinal effect, odor: sweet, cold, non-toxic; Indications: vomiting, diarrhea, urinary dysfunction, skin eczema, etc. .
  • Efficacy Lee, soak, spleen and stomach.
  • Talc characteristics 1. It acts as a flux. 2. It makes the porcelain blank have high thermal shock resistance and high electrical resistance at high temperature, low dielectric loss and low power factor. 3. It reduces thermal expansion in high temperature or low temperature porcelain.
  • the basic structural unit of talc is composed of two layers of silicon atoms and oxygen atoms, which do not contain hydroxyl groups and active ions, and are sandwiched between magnesium ions. At a high temperature of 1000 fl C or more, ⁇ -hard pyroxene is formed, and its composition is unchanged. Magnesium silicate can change the taste of water and play a sweet and sweet effect.
  • Tourmaline also known as Tourmal ine, is called tourmaline because it is charged.
  • Tourmaline has the following characteristics: 1. Producing negative ions: Negative ions, also known as "air vitamins", have the effect of regulating the body's ion balance, relaxing the body and mind, activating cells, improving the natural cure rate, and inhibiting the body's oxidation or Aging, the modern environment has many factors that promote the formation of positive ions. The body is often in a state of tension. Therefore, negative ions are indispensable for modern people. In addition, negative ions also have deodorizing effects. 2.
  • Electrolyzed water After water electrolysis, the activity of the interface, the stabilization of chlorine, the passivation of iron (preventing red rust formation and red water), the reduction of water, and the removal of silica and binder ( Various effects such as microbial aggregates. When tourmaline reacts with water, it can handle problems that are difficult to handle with chemical lotions and chemicals. 3. Reducing water clusters: Water molecules will associate with each other to form molecular clusters. Smaller molecules of water can remove chlorine or impurities, taste good, and can improve the body's penetration. 4.
  • Far-infrared rays infrared rays with a wavelength of 4 to 14 microns
  • far-infrared rays can penetrate deep into the body, warm cells, promote blood circulation, and make metabolism smooth.
  • the far-infrared emissivity of tourmaline is nearly 100%, which is higher than other minerals. 5.
  • Far-infrared rays are the longest wavelength of infrared rays in the infrared range, and their wavelengths range from 5 to 100 ⁇ m. It is a kind of electromagnetic wave; it is invisible light, but it has all the characteristics of visible light. It has strong penetrating power and radiation force, has significant temperature control effect and resonance effect, and it is easily absorbed by objects. Converted into the internal energy of an object. detailed description
  • Preparation method 1. Pretreatment of the raw materials of the medical stone, diatomaceous earth, talc and tourmaline in the above table, that is, the raw materials are successively pickled, alkali washed, washed with water to remove metal impurities, and then dried for use.
  • the acid used for pickling is dilute hydrochloric acid with a concentration of 30% or phosphoric acid with a concentration of 85%, and alkali washing after pickling, the alkali selected for alkali washing is 96% sodium hydroxide, and 96% hydroxide for alkali washing.
  • Sodium is diluted with water, washed with alkali, washed with water, and the remaining alkali solution on the raw material is removed and dried.
  • the raw materials of maifanite, diatomaceous earth, talc and tourmaline are ground by a grinder.
  • the fineness after grinding is 80 ⁇ 200 mesh. The higher the fineness, the better, generally 120 mesh, then Mix each raw material evenly.
  • the ball mill After mixing the raw materials, perform ball milling.
  • the ball mill is used to put the raw materials of the above table and 10-20% of the weight of the raw materials into the ball mill.
  • the ball mill is equipped with a certain amount of high-aluminum balls, and then is driven by an electric ball mill to roll the raw materials and water with high-aluminum balls. Collision friction to bond, ball milling time is 2 to 3 days.
  • the blank is formed into a billet, and the billet can be made into a granular shape, a sheet shape, or the like as needed.
  • a block, cylindrical, mesh or other shape of the container and then left to dry, the blank is dried and placed in a furnace for firing, the firing temperature is 1150 ⁇ 1280 ° C, the firing time is 10 ⁇ 15 Hours, where the firing temperature is 1150 ° C, the firing time is 15 hours, the firing temperature is 1280 ° C, the firing time is slightly shorter than 10 hours, if the firing temperature is 1200 ° C, firing The time is 12 hours.
  • APHA American Public Health Association, American Water Works Association and Water Environment Federation, Standard Methods for the Examination of Water and Wastewater, APHA-AWWA-WEF, USA
  • test results were as follows:
  • the ceramic materials of the present invention are tested in three groups by smokers; the first group; 5 people in each group; smoking time 1-5 years, not completely addicted to cigarettes; test time is one month, test cigarette brands are not prescribed
  • Test method Put the cigarette into the cylindrical ceramic material of the present invention for about 1-10 seconds before smoking, depending on the feeling of each person, because the insertion time determines the concentration and the dilution of the cigarette, that is, the purity and the turbidity. Degree, the longer the time is put, the lighter the smoke. From the first group of people during the test period to compare feelings:
  • the cigarettes are close to the third party (non-smokers who smoke second-hand smoke:), they feel that the smoke smell is reduced by more than 60%; the others remain unchanged.
  • the second group 5 people in each group; smoking time 5-10 years, addicted to cigarettes, to a serious extent.
  • the test time, regulations, and methods are the same. The group feels the sum during the test; their feelings are the same as the first group, they add the fourth point, the cough is reduced and the sputum is reduced during the test; the third group; 5 people in each group; smoking People who are more than 10 years old and addicted to cigarettes are extremely addicted to cigarettes.
  • the test time, regulations, and methods are the same as the first group; their group sleeps the next day after smoking every day. When you wake up, you must first spit out the throat in the throat. They feel the same as the second group. Add the fifth point. After about 8 days of testing, they wake up the next day and start to have no clots in the throat.
  • the ceramic material of the present invention is used to make a smoke filter, and the same is used for the comparison of the sea willow smoke filter sold in the market. After filtering 10 cigarettes, the middle tar of the cleaning filter is disassembled, and the tar in the ceramic material of the invention is found. More than 90% less than the willow filter.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Water Treatment By Sorption (AREA)
  • Physical Water Treatments (AREA)

Abstract

A ceramic material for purifying and activating water is prepared from raw materials consisting of (in weight parts): medical stone (maifan stone) 23-50, diatomite 16-22, talcum 6-16 and tourmaline 25-48.

Description

用于净化、 活化水的陶瓷材料  Ceramic material for purifying and activating water
技术领域 Technical field
本发明涉及一种陶瓷材料,尤其涉及一种用于净化、活化并保健的陶瓷材  The invention relates to a ceramic material, in particular to a ceramic material for purification, activation and health care.
 Say
料。 背景技术 书 净化后的水是纯净水, 水口感好, 不含任何杂质。 比较适用于冲咖啡、 饮 茶以及患有肝病、 肾病、 癌症、 肿瘤患者。 但还存在以下缺点: 纯净水多是能 满足没有污染, 无毒、 无害、 无异味的条件, 但是不符合人体生理需求, 纯净 水中不含有益的矿物质、 不能保证 PH值呈中性或微碱性等; 同时纯净水也不 具有生命活力, 不适合长期作为饮用水。 另外, 水分子之间缔合在一起形成大 分子团,大的水分子团在受到周遭环境污染时,大水分子团外吸附了有机物体, 形成水分子对生物体 (包括动物、 植物、 微生物和人类:)的生理功能的退化。 人 的衰老、 疾病、 尤其是慢性病增多, 均与水退化有关。 material. BACKGROUND OF THE INVENTION The purified water is pure water, which has a good mouthfeel and does not contain any impurities. It is more suitable for brewing coffee, drinking tea, and patients with liver disease, kidney disease, cancer, and cancer. However, the following shortcomings exist: Pure water is sufficient to meet the conditions of no pollution, non-toxic, harmless, and no odor, but it does not meet the physiological needs of the human body. Pure water does not contain beneficial minerals, and the pH value is not guaranteed. It is slightly alkaline; at the same time, pure water does not have vitality and is not suitable for long-term drinking water. In addition, water molecules are associated together to form a macromolecular group. When large water molecules are polluted by the surrounding environment, the large water molecules adsorb organic substances outside the group, forming water molecules to the organism (including animals, plants, microorganisms). And human:) the degradation of physiological functions. People's aging, disease, and especially chronic diseases are all related to water degradation.
太阳光线大致可分为可见光及不可见光。 可见光经三棱镜后会折射出紫、 蓝、 青、 绿、 黄、 橙、 红颜色的光线 (光谱) 。 红光外侧的光线, 在光谱中波 长自 0.76至 400微米的一段被称为红外光, 又称红外线。 红外线属于电磁波 的范畴, 是一种具有强热作用的放射线。 红外线的波长范围很宽, 人们将不同 波长范围的红外线分为近红外、 中红外和远红外区域,相对应波长的电磁波称 为近红外线、中红外线及远红外线。 自然界有无数的远红外放射源:宇宙星体、 太阳、 地球上的海洋、 山岭、 岩石、 土壤、 森林、 城市、 乡村、 以及人类生产 制造出来的各种物品, 凡在绝对零度(-273 °C ) 以上的环境, 无所不有地发射 出不同程度的红外线。现代物理学称之为热射线。 由能量守恒定律得知, 宇宙 的能量不能发生, 也不会消失, 只可以改变能量的方式。热能便是宇宙能量的 一种, 可以用放射 (辐射) 、 传导和对流的方式进行转换。 在放射的过程中, 便有一部份热能形成红外线。 发明内容 The sun's rays can be roughly divided into visible light and invisible light. The visible light passes through the prism and reflects the light (spectrum) of purple, blue, cyan, green, yellow, orange, and red colors. The light outside the red light, in the spectrum from 0.76 to 400 microns, is called infrared light, also known as infrared light. Infrared rays belong to the category of electromagnetic waves and are radiations with strong heat. Infrared has a wide wavelength range. Infrared rays of different wavelength ranges are divided into near-infrared, mid-infrared and far-infrared regions, and electromagnetic waves corresponding to wavelengths are called near-infrared, mid-infrared and far-infrared. There are countless far-infrared sources in nature: cosmic stars, The sun, the oceans of the earth, the mountains, rocks, soil, forests, cities, villages, and all kinds of objects produced by humans, all in an environment of absolute zero (-273 °C), are emitted in an all-encompassing way. Different levels of infrared. Modern physics is called heat ray. It is known from the law of conservation of energy that the energy of the universe cannot occur, it will not disappear, and only the way of energy can be changed. Thermal energy is a type of cosmic energy that can be converted by radiation (radiation), conduction, and convection. During the radiation process, a portion of the heat forms infrared light. Summary of the invention
本发明要解决的技术问题在于, 提供一种能提供微量元素、净化、活化水 质、 制造工艺简单、 使用方便的用于净化、 活化并保健的陶瓷材料。  The technical problem to be solved by the present invention is to provide a ceramic material for purifying, activating and protecting health, which can provide trace elements, purify and activate water, has a simple manufacturing process, and is convenient to use.
本发明解决其技术问题所采用的技术方案是:一种用于净化并保健的陶瓷 材料, 由以下重量份数的原料制成: 麦饭石 23〜50、硅藻土 16〜22、滑石 6〜16、 电气石 25〜48。  The technical solution adopted by the invention to solve the technical problem is: a ceramic material for purifying and health care, which is made of the following raw materials by weight: maifanite 23~50, diatomaceous earth 16~22, talc 6 ~16, tourmaline 25~48.
用于净化并保健的陶瓷材料优选由以下重量份数的原料制成: 麦饭石 30〜40、 硅藻土 18〜20、 滑石 8〜12、 电气石 38〜36。  The ceramic material for purification and health care is preferably made of the following raw materials by weight: maifanite 30~40, diatomaceous earth 18~20, talc 8~12, tourmaline 38~36.
所述陶瓷材料是将原料麦饭石、硅藻土、滑石、 电气石预处理去除重金属 及杂质后混合研磨, 球磨、 制作成型, 烧制而成。  The ceramic material is prepared by pretreating the raw materials of maifanite, diatomaceous earth, talc and tourmaline to remove heavy metals and impurities, grinding, grinding, molding and firing.
所述原料麦饭石、硅藻土、滑石、 电气石的预处理是将原料分别依次进行 酸洗、 碱洗、 水洗, 然后烘干备用。  The raw materials of the medical stone, diatomaceous earth, talc and tourmaline are pretreated by pickling, caustic washing, water washing, and then drying.
所述酸洗选用的酸为盐酸或磷酸。  The acid selected for the pickling is hydrochloric acid or phosphoric acid.
所述碱洗选用的碱为氢氧化钠。  The base selected for the alkaline washing is sodium hydroxide.
所述原料麦饭石、 硅藻土、 滑石、 电气石经研磨后的细度达到 80〜200 圈。 所述球磨是将原料及水放入球磨机内球磨,使原料粘合在一起,球磨时间 为 2〜3天。 The fineness of the raw material medical stone, diatomaceous earth, talc and tourmaline is 80 to 200 turns. The ball milling is to put the raw materials and water into a ball mill and ball-bonding, so that the raw materials are bonded together, and the ball milling time is 2 to 3 days.
所述烧制的温度为 1150〜1280°C, 烧制时间为 10〜15小时。  The firing temperature is 1150 to 1280 ° C, and the firing time is 10 to 15 hours.
球磨后成型制成粒状、 片状、 块状、 圆筒状、 网状或容器。  After ball milling, it is formed into a pellet, a sheet, a block, a cylinder, a mesh or a container.
麦饭石是一种具有生物活性的矿物保健药石, 具有以下保健功能: 1、 麦 饭石中含有钾、 钠、 钙、 镁、 磷、 钛、 锰、 钡、 钴、 铜、 锌、 锂、 锶、 钼、 铌、 锗、 锡、 硒、 硅及稀土元素镧、 铈、 钕、 钐等 30余种微量元素。 其中硒、 锌、 锰含量比较丰富,麦饭石的矿物水中溶出的人体不可缺少的微量元素矿物质可 以改善水质。 在通常条件下, 麦饭石溶出液中四种微量元素 (偏硅酸、 S r、 Z n、 F ) 含量达到或接近国家饮料矿泉水标准, 因此是一种天然营养源。 2、 麦饭石能释放远红外线, 常温下远红外线辐射率>0. 88〜0. 92, 常温下抑菌率 (大肠杆菌, 金黄色葡萄球菌)〉 90 %。 因此, 能够有效地抑制细菌生长,打破 有毒物质结构的活性键, 发挥较强的氧化裂解功能。分解被污染水中致癌性有 机分子, 防止水腐败, 从而得到优质水。 3、 调整水质。 以铁、 镁、 氟等矿物 质而论, 当水中不存在时它则溶出; 相反, 当水中存在过多时它则吸附, 这种 作用与 PH值有关。往水中投入麦饭石后, 可使水 ra值提高而接近中性。现代 科学分析证明,麦饭石富含多种元素,具有生物活性,能改善机体的生理功能, 起到双向调节酸碱度的作用。  Medical stone is a biologically active mineral health medicine with the following health functions: 1. The medical stone contains potassium, sodium, calcium, magnesium, phosphorus, titanium, manganese, strontium, cobalt, copper, zinc, lithium, More than 30 kinds of trace elements such as antimony, molybdenum, niobium, tantalum, tin, selenium, silicon and rare earth elements such as lanthanum, cerium, lanthanum and cerium. Among them, selenium, zinc and manganese are abundant, and the indispensable trace element minerals dissolved in the mineral water of medical stone can improve water quality. Under normal conditions, the content of four trace elements (silicic acid, S r, Z n, F) in the maifan stone solution is close to or close to the national beverage mineral water standard, so it is a natural nutrient source. 2, maifan stone can release far infrared rays, far-infrared radiance at room temperature >0. 88~0. 92, antibacterial rate at room temperature (E. coli, Staphylococcus aureus) > 90%. Therefore, it can effectively inhibit bacterial growth, break the active bond of toxic substance structure, and exert a strong oxidative cleavage function. Decomposes carcinogenic organic molecules in contaminated water to prevent water from spoiling, resulting in high quality water. 3. Adjust the water quality. In the case of minerals such as iron, magnesium, and fluorine, it dissolves when it is not present; on the contrary, it adsorbs when there is too much water, and this effect is related to pH. After putting the stone into the water, the water ra value can be increased to be close to neutral. Modern scientific analysis proves that medical stone is rich in various elements and has biological activity, which can improve the physiological function of the body and play a role of regulating pH in both directions.
硅藻土是古代海底矿物, 白色水成岩, 轻质、 多孔、 是硅藻属的壳埋没 堆积在地层, 经地壳变动隆起于地表的矿物, 其主要化学成份是含有硅、 铝和 铁等氧化物, 据称其孔径约为 500 um, 此表面积约达 37. 8 M2/g, 硅藻土具有 优异的吸附性和良好的化学惰性,最重要的是硅藻土能释放负离子并释放远红 外线。 滑石属硅酸盐类, 为含有硅、 镁的天然的含水硅酸镁矿物,具有保健药用 效果, 气味: 甘、 寒、 无毒; 主治: 呕吐、 泄泻、 小便不通、 皮肤湿疹病等。 功效: 利窍、 渗湿、 补脾胃等。 滑石特性: 1. 起到助熔的作用。 2.它使瓷坯 具有很高的耐热冲击强度以及高温下的电阻大、介电损耗低和功率因子小的功 能。 3. 无论在高温或低温瓷坯中, 它都使其热膨胀降低。 滑石基本结构单元 是两层由硅原子和氧原子的表面不包含羟基和活泼离子, 中间夹合镁离子组 成。 在高温 1000flC以上生成 β -顽火辉石,而其成份不变, 硅酸镁能改变水 质味道, 起到好饮甘甜作用。 Diatomaceous earth is an ancient seabed mineral, white sedimentary rock, light and porous. It is a diatom shell buried in the stratum. The minerals in the earth's crust are raised on the surface. The main chemical composition is oxides containing silicon, aluminum and iron. It is said to have a pore size of about 500 um, and the surface area is about 37.8 M 2 /g. The diatomaceous earth has excellent adsorption and good chemical inertness. The most important thing is that diatomaceous earth can release negative ions and release far infrared rays. . Talc silicate, a natural hydrous magnesium silicate mineral containing silicon and magnesium, has a health care medicinal effect, odor: sweet, cold, non-toxic; Indications: vomiting, diarrhea, urinary dysfunction, skin eczema, etc. . Efficacy: Lee, soak, spleen and stomach. Talc characteristics: 1. It acts as a flux. 2. It makes the porcelain blank have high thermal shock resistance and high electrical resistance at high temperature, low dielectric loss and low power factor. 3. It reduces thermal expansion in high temperature or low temperature porcelain. The basic structural unit of talc is composed of two layers of silicon atoms and oxygen atoms, which do not contain hydroxyl groups and active ions, and are sandwiched between magnesium ions. At a high temperature of 1000 fl C or more, β-hard pyroxene is formed, and its composition is unchanged. Magnesium silicate can change the taste of water and play a sweet and sweet effect.
电气石又名托玛琳 (Tourmal ine) , 是由于它带电而称谓电气石的。 电气石 具有以下特点: 1、 产生负离子: 负离子又称为 "空气的维生素",具有调节人 体离子平衡作用, 能使身心放松, 活化细胞, 提高自然治愈率等作用, 并能抑 制身体的氧化或老化,现代的环境具有许多促使正离子生成的要因, 身体经常 处于紧张状态, 因此, 负离子是现代人不可或缺的物质, 此外, 负离子也具有 除臭的功效。 2、 电解水: 水电解后, 能获得界面的活性作用、 氯的安定化、 铁的钝化(预防红色铁锈生成而发生红水) 、 水的还原化、 去除二氧化硅与粘 合物(微生物集合体)等各种效果。 电气石与水反应, 就能处理连化学洗剂和 化学物质都很难处理的问题。 3、 减小水分子团: 水分子之间会相互缔合, 形成分子团。分子团较小的水能去除氯或不纯物, 味道佳, 而且能够提高身体 的渗透力。 4、 放射远红外线 (波长 4〜14微米的红外线) , 远红外线能够渗 透到身体深层部位, 温暧细胞, 促进血液循环, 使新陈代谢顺畅。 电气石远红 外线发射率将近 100 %, 数值较其他矿物高。 5、 含有有效微量矿物质。 远红外线是红外线中波长最长的一段红外线其波长范围在 5— lOOum之间。 它是电磁波的一种; 它是不可见光, 但却具备可见光所具有的一切特性, 它可 有较强的渗透力和辐射力, 具有显著的温控效应和共振效应, 它易被物体吸收 并转化为物体的内能。 具体实施方式 Tourmaline, also known as Tourmal ine, is called tourmaline because it is charged. Tourmaline has the following characteristics: 1. Producing negative ions: Negative ions, also known as "air vitamins", have the effect of regulating the body's ion balance, relaxing the body and mind, activating cells, improving the natural cure rate, and inhibiting the body's oxidation or Aging, the modern environment has many factors that promote the formation of positive ions. The body is often in a state of tension. Therefore, negative ions are indispensable for modern people. In addition, negative ions also have deodorizing effects. 2. Electrolyzed water: After water electrolysis, the activity of the interface, the stabilization of chlorine, the passivation of iron (preventing red rust formation and red water), the reduction of water, and the removal of silica and binder ( Various effects such as microbial aggregates. When tourmaline reacts with water, it can handle problems that are difficult to handle with chemical lotions and chemicals. 3. Reducing water clusters: Water molecules will associate with each other to form molecular clusters. Smaller molecules of water can remove chlorine or impurities, taste good, and can improve the body's penetration. 4. Radiation far-infrared rays (infrared rays with a wavelength of 4 to 14 microns), far-infrared rays can penetrate deep into the body, warm cells, promote blood circulation, and make metabolism smooth. The far-infrared emissivity of tourmaline is nearly 100%, which is higher than other minerals. 5. Contains effective trace minerals. Far-infrared rays are the longest wavelength of infrared rays in the infrared range, and their wavelengths range from 5 to 100 μm. It is a kind of electromagnetic wave; it is invisible light, but it has all the characteristics of visible light. It has strong penetrating power and radiation force, has significant temperature control effect and resonance effect, and it is easily absorbed by objects. Converted into the internal energy of an object. detailed description
以下列举 8个实施例具体说明本发明, 8个实施例由以下重量份数的原料 制成:  The present invention is specifically illustrated by the following eight examples, and eight examples are made of the following parts by weight:
Figure imgf000006_0001
制备方法: 1、 将上述表格中份量的原料麦饭石、 硅藻土、 滑石、 电气石 的预处理, 即将原料分别依次进行酸洗、 碱洗、 水洗, 除去金属杂质, 然后烘 干备用。 其中, 酸洗选用的酸为浓度 30%的稀盐酸或浓度为 85%的磷酸, 酸 洗后进行碱洗, 碱洗选用的碱为浓度为 96%氢氧化钠, 碱洗时 96%氢氧化钠 中加水稀释, 碱洗后进行水洗, 清除原料上剩余的碱液, 烘干。
Figure imgf000006_0001
Preparation method: 1. Pretreatment of the raw materials of the medical stone, diatomaceous earth, talc and tourmaline in the above table, that is, the raw materials are successively pickled, alkali washed, washed with water to remove metal impurities, and then dried for use. Among them, the acid used for pickling is dilute hydrochloric acid with a concentration of 30% or phosphoric acid with a concentration of 85%, and alkali washing after pickling, the alkali selected for alkali washing is 96% sodium hydroxide, and 96% hydroxide for alkali washing. Sodium is diluted with water, washed with alkali, washed with water, and the remaining alkali solution on the raw material is removed and dried.
2、 分别将原料麦饭石、 硅藻土、 滑石、 电气石经研磨机研磨, 研磨后的 细度要达到 80〜200目, 细度是越高越好, 一般在 120目即可, 然后将各原料 混合均匀。  2. The raw materials of maifanite, diatomaceous earth, talc and tourmaline are ground by a grinder. The fineness after grinding is 80~200 mesh. The higher the fineness, the better, generally 120 mesh, then Mix each raw material evenly.
3、 原料混合后进行球磨。 球磨是将所上述表格的原料及占原料重量 10-20%的水放入球磨机内, 球磨机内装有一定量高铝球, 然后用电带动球磨 机滚动, 利用高铝球将所放入原材料和水进行碰撞磨擦使其粘合,球磨时间为 2〜3天。  3. After mixing the raw materials, perform ball milling. The ball mill is used to put the raw materials of the above table and 10-20% of the weight of the raw materials into the ball mill. The ball mill is equipped with a certain amount of high-aluminum balls, and then is driven by an electric ball mill to roll the raw materials and water with high-aluminum balls. Collision friction to bond, ball milling time is 2 to 3 days.
4、 成型烧制。球磨后成型制成坯料, 坯料根据需要可以制成粒状、 片状、 块状、 圆筒状、 网状或其他形状的容器, 然后静置晾干, 坯料晾干后放置在炉 中烧制, 烧制的温度为 1150〜1280°C, 烧制时间为 10〜15小时, 其中烧制温 度在 1150°C时, 烧制时间长为 15小时, 烧制温度在 1280°C时, 烧制时间稍短 为 10小时, 若烧制温度在 1200 °C时, 烧制时间为 12小时。 产品效果实验实例: 4. Forming and firing. After ball milling, the blank is formed into a billet, and the billet can be made into a granular shape, a sheet shape, or the like as needed. a block, cylindrical, mesh or other shape of the container, and then left to dry, the blank is dried and placed in a furnace for firing, the firing temperature is 1150~1280 ° C, the firing time is 10~15 Hours, where the firing temperature is 1150 ° C, the firing time is 15 hours, the firing temperature is 1280 ° C, the firing time is slightly shorter than 10 hours, if the firing temperature is 1200 ° C, firing The time is 12 hours. Product effect experiment example:
1、 水质检测实验: 本实验由香港的 SGS HONG KONG Ltd.进行的。  1. Water quality testing experiment: This experiment was carried out by SGS HONG KONG Ltd. of Hong Kong.
测试依据: APHA: American Public Health Association, American Water Works Association and Water Environment Federation, Standard Methods for the Examination of Water and Wastewater ,APHA-AWWA-WEF,USA  Test basis: APHA: American Public Health Association, American Water Works Association and Water Environment Federation, Standard Methods for the Examination of Water and Wastewater, APHA-AWWA-WEF, USA
USEPA: United States Environmental Protection Agency.  USEPA: United States Environmental Protection Agency.
用水泵从蓄水池中抽取水样, 将样品水以 2L/min的速度从本发明的长筒 形陶瓷材料流过, 收集出口的水, 经检测结果如下:  A water sample was taken from the reservoir by a water pump, and the sample water was flowed through the long cylindrical ceramic material of the present invention at a rate of 2 L/min, and the water of the outlet was collected. The test results were as follows:
Figure imgf000007_0001
t驟
Figure imgf000007_0001
t
il m  Il m
亚硫酸盐 (mg/1) APHA20thed.3500-SO3 <2 <2 Sulfite (mg/1) APHA20 th ed.3500-SO 3 <2 <2
a a a a  a a a a
USEPA 6020 <0.001 0.006  USEPA 6020 <0.001 0.006
USEPA 6020 <0.001 <0.001  USEPA 6020 <0.001 <0.001
USEPA 6020 <0.01 0.026  USEPA 6020 <0.01 0.026
USEPA 6020 <0.001 0.002  USEPA 6020 <0.001 0.002
PH(21 °C) APHA21sted.4500 H+B 5.7 6.0 PH(21 °C) APHA21 st ed.4500 H + B 5.7 6.0
2、 使用实例: 在日常接触物质作简单对比试验; 主要有烟、 茶、 酒及水 试验的情况。 2. Examples of use: Simple comparison tests on daily contact materials; mainly in the case of smoke, tea, wine and water tests.
( 1 ) 首先将本发明的陶瓷材料分三组由吸烟人士测试; 第一组; 每组 5人; 吸烟时间 1-5年, 对香烟未完全上瘾;测试时间一个月, 测试香烟牌子不规定,测试方法:每次要在吸烟前将香烟放入本发明圆筒状陶瓷 材料内约 1-10秒,视各人感觉而定, 因为放入时间决定香烟浓度与稀度, 即纯 度与浊度, 放入时间越长烟味越淡。 从第一组人士在测试期间对比感受总结: (1) First, the ceramic materials of the present invention are tested in three groups by smokers; the first group; 5 people in each group; smoking time 1-5 years, not completely addicted to cigarettes; test time is one month, test cigarette brands are not prescribed Test method: Put the cigarette into the cylindrical ceramic material of the present invention for about 1-10 seconds before smoking, depending on the feeling of each person, because the insertion time determines the concentration and the dilution of the cigarette, that is, the purity and the turbidity. Degree, the longer the time is put, the lighter the smoke. From the first group of people during the test period to compare feelings:
A、 所吸香烟喉咙感觉不会干渴, A. The throat of the cigarette you smoke does not feel thirsty.
B、 所吸香烟纯度改变为清纯, B. The purity of the smoked cigarette is changed to pure.
C、 所吸香烟靠近第三者 (不吸烟二手烟人士:), 他们感觉烟浓味减少 60% 以上; 其它不变。 第二组; 每组 5人;吸烟时间 5-10年,对香烟以上瘾,程度严重。测试时间、 规定、 方法其它一样, 这组人士测试期间感受总结; 他们的感受同第一组, 他 们补充第四点, 测试期间咳嗽减少及痰液减少; 第三组; 每组 5人;吸烟时间 10年以上老烟瘾人士, 对香烟以上瘾程度极 严重。 测试时间、 规定、 方法同第一组; 他们这组人士每天吸烟后第二天睡 醒起床第一时间必定要先吐掉在喉咙内痰块, 他们感受同第二组, 增加第五点, 在测试约 8天以后, 他们第二天起床开始喉咙内没有痰块。 C. The cigarettes are close to the third party (non-smokers who smoke second-hand smoke:), they feel that the smoke smell is reduced by more than 60%; the others remain unchanged. The second group; 5 people in each group; smoking time 5-10 years, addicted to cigarettes, to a serious extent. The test time, regulations, and methods are the same. The group feels the sum during the test; their feelings are the same as the first group, they add the fourth point, the cough is reduced and the sputum is reduced during the test; the third group; 5 people in each group; smoking People who are more than 10 years old and addicted to cigarettes are extremely addicted to cigarettes. The test time, regulations, and methods are the same as the first group; their group sleeps the next day after smoking every day. When you wake up, you must first spit out the throat in the throat. They feel the same as the second group. Add the fifth point. After about 8 days of testing, they wake up the next day and start to have no clots in the throat.
另者, 本发明的陶瓷材料制作烟滤嘴, 将市面所售海柳烟滤嘴二者作相同 对比,在过滤 10支香烟后, 拆开清洗滤嘴中间焦油, 发觉本发明陶瓷材料内焦 油比海柳烟滤嘴减少 90%以上。  In addition, the ceramic material of the present invention is used to make a smoke filter, and the same is used for the comparison of the sea willow smoke filter sold in the market. After filtering 10 cigarettes, the middle tar of the cleaning filter is disassembled, and the tar in the ceramic material of the invention is found. More than 90% less than the willow filter.
( 2 ) 茶叶试验: 采用刚制成的茶叶 (如炒茶), 用二份相同份量的茶叶开 水冲泡,其中一份将本发明陶瓷材料放在茶叶上 2分钟, 结果是冲泡的茶水饮 时感受不同,与本发明陶瓷材料接触的茶水纯滑, 而另一份没有与本发明的陶 瓷材料接触的则苦涩难饮。  (2) Tea test: using freshly made tea leaves (such as fried tea), brewing with two equal portions of tea leaves, one of which puts the ceramic material of the invention on the tea for 2 minutes, and the result is brewed tea. When drinking, the tea that is in contact with the ceramic material of the present invention is pure and slippery, while the other one that is not in contact with the ceramic material of the present invention is bitter and difficult to drink.
( 3 ) 酒试验: 将制成饼形状中间有小孔的本发明陶瓷材料放在杯中, 然 后将白酒或萄葡酒通过本发明陶瓷材料,用相同的未通过本发明陶瓷材料的酒 作对比, 各斟在小杯上,进行试饮或试闻, 经超过 600人次试闻或试饮,试饮人 士感觉是通过本发明陶瓷材料的酒饮时喉咙头不辣, 更香醇酒, 没有不舒服的 感觉。从闻酒的人士感觉, 通过本发明陶瓷材料的酒香味更醇厚, 口味便柔和、 醇香、 绵甜, 入口清凉。  (3) Wine test: The ceramic material of the present invention having a small hole in the middle of the shape of the cake is placed in a cup, and then the white wine or the wine is passed through the ceramic material of the present invention, and the same wine which does not pass the ceramic material of the present invention is used. In contrast, each cockroach is in a small cup for a tasting or test. After more than 600 test or tastings, the tasting person feels that the throat is not hot, but more mellow, through the ceramic material of the present invention. Uncomfortable feeling. From the smell of wine, the wine of the ceramic material of the present invention is more mellow, the taste is soft, mellow, sweet, and the mouth is cool.
(4 ) 用蒸馏水作对比试验: 将有通过所述产品及没有通过各斟二杯, 给 10人作比较, 结果 9人认为有通过所述产品饮时水比较润滑容易饮。  (4) Using distilled water as a comparative test: There will be a comparison between the product and the two cups that have not passed through each of the two cups, and the result is that the nine people think that the water is more lubricious and easy to drink when drinking through the product.

Claims

权 利 要 求 Rights request
1、 一种用于净化、 活化并保健的陶瓷材料, 其特征在于, 由以 下重量份数的原料制成: 麦饭石 23〜50、 硅藻土 16〜22、 滑石 6〜16 、 电气石 25〜48。 1. A ceramic material for purification, activation and health care, characterized in that it is made of the following raw materials by weight: maifanite 23~50, diatomaceous earth 16~22, talc 6~16, tourmaline 25~48.
2、 根据权利要求 1所述的用于净化、 活化并保健的陶瓷材料, 其特征在于, 由以下重量份数的原料制成: 麦饭石 30〜40、 硅藻土 18〜20、 滑石 8〜12、电气石 38-46  2. The ceramic material for purification, activation and health care according to claim 1, which is made of the following raw materials by weight: maifan stone 30 to 40, diatomaceous earth 18 to 20, talc 8 ~12, tourmaline 38-46
3、 根据权利要求 1或 2所述的用于净化、 活化并保健的陶瓷材 料, 其特征在于, 所述陶瓷材料是将原料麦饭石、 硅藻土、 滑石、 电 气石预处理去除重金属及杂质后混合研磨, 球磨、 制作成型, 烧制而 成。  The ceramic material for purification, activation and health care according to claim 1 or 2, wherein the ceramic material is prepared by pretreating raw materials of maifanite, diatomaceous earth, talc and tourmaline to remove heavy metals and The impurities are mixed and ground, ball milled, formed and fired.
4、 根据权利要求 3所述的用于净化、 活化并保健的陶瓷材料, 其特征在于, 所述原料麦饭石、 硅藻土、 滑石、 电气石的预处理是将 原料分别依次进行酸洗、 碱洗、 水洗, 然后烘干备用。  4. The ceramic material for purification, activation and health care according to claim 3, wherein the raw material of the medical stone, diatomaceous earth, talc, tourmaline is pretreated by pickling the raw materials separately. , alkaline washing, washing, and then drying for use.
5、 根据权利要求 4所述的用于净化、 活化并保健的陶瓷材料, 其特征在于, 所述酸洗选用的酸为盐酸或磷酸。  5. The ceramic material for purification, activation and health care according to claim 4, wherein the acid selected for the pickling is hydrochloric acid or phosphoric acid.
6、 根据权利要求 4所述的用于净化、 活化并保健的陶瓷材料, 其特征在于, 所述碱洗选用的碱为氢氧化钠。  6. The ceramic material for purification, activation and health care according to claim 4, wherein the alkali selected for the alkali washing is sodium hydroxide.
7、 根据权利要求 3所述的用于净化、 活化并保健的陶瓷材料, 其特征在于, 所述原料麦饭石、 硅藻土、 滑石、 电气石经研磨后的细 度达到 80〜200目。 The ceramic material for purification, activation and health care according to claim 3, wherein the raw materials of maifanite, diatomaceous earth, talc and tourmaline have a fineness of 80 to 200 mesh after grinding. .
8、 根据权利要求 3所述的用于净化、 活化并保健的陶瓷材料, 其特征在于, 所述球磨是将原料及水放入球磨机内球磨, 使原料粘合 在一起, 球磨时间为 2〜3天。 8. The ceramic material for purification, activation and health care according to claim 3, wherein the ball milling is performed by placing the raw material and water into a ball mill to bond the raw materials together, and the ball milling time is 2~ 3 days.
9、 根据权利要求 3所述的用于净化、 活化并保健的陶瓷材料, 其特征在于, 所述烧制的温度为 1150〜1280°C, 烧制时间为 10〜15 小时。  The ceramic material for purification, activation and health care according to claim 3, wherein the firing temperature is 1150 to 1280 ° C and the firing time is 10 to 15 hours.
10、 根据权利要求 3所述的用于净化、 活化并保健的陶瓷材料, 其特征在于, 球磨后成型制成粒状、 片状、 块状、 圆筒状、 网状或容 器。  10. A ceramic material for purification, activation and health care according to claim 3, characterized in that it is formed into a pellet, a sheet, a block, a cylinder, a mesh or a container after ball milling.
PCT/CN2008/073503 2008-12-15 2008-12-15 Ceramic material for purifying and activating water WO2010069097A1 (en)

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