CN107573047B - Hydrogen water preparation ceramic material and preparation method and application thereof - Google Patents
Hydrogen water preparation ceramic material and preparation method and application thereof Download PDFInfo
- Publication number
- CN107573047B CN107573047B CN201710729360.9A CN201710729360A CN107573047B CN 107573047 B CN107573047 B CN 107573047B CN 201710729360 A CN201710729360 A CN 201710729360A CN 107573047 B CN107573047 B CN 107573047B
- Authority
- CN
- China
- Prior art keywords
- water
- hydrogen
- ceramic material
- mixture
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Cosmetics (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
Abstract
The invention discloses a hydrogen water-making ceramic material and a preparation method thereof, wherein the ceramic material is mainly prepared from the following raw materials in percentage by weight: 25-50% of tourmaline, 6-12% of medical stone, 5-10% of calcium oxide, 4-8% of calcium carbonate, 3-12% of diatomite, 8-18% of quartz sand, 4-8% of chitosan, 14-30% of metal magnesium powder, 1-5% of KDF alloy, 1-5% of antibacterial component and 4-10% of binder. The hydrogen water production ceramic material can be used for producing healthy water with integrated functions of hydrogen-rich water, alkalescent water, negative potential water, micromolecular water and the like, and also has the functions of sterilization and antibiosis. The ceramic material for preparing hydrogen and water can generate trace hydrogen and form micromolecular hydroxyl weak alkali ionized water by reacting with water. After the ceramic material for producing hydrogen water is put in water for 3 minutes, the content of hydrogen molecules in the water is more than or equal to 400ppb, and the pH value of the water is more than or equal to 7.4. The preparation method of the ceramic material for preparing hydrogen and water is simple in process and easy to realize.
Description
Technical Field
The invention relates to the technical field of new hydrogen production materials, in particular to a hydrogen production water ceramic material and a preparation method and application thereof.
Background
Generally, the hydrogen content of water meets certain criteria, known as hydrogen-rich water. The water containing hydrogen has the function of eliminating free radicals in organisms, and the hydrogen-rich water is not only clean, but also has energy, all presents small molecular active water groups, and can purify blood, lead the blood to be smooth, promote the metabolism, prevent various diseases and promote the health of human bodies. The hydrogen-rich water contains rich hydrogen, is real micromolecular water, negative potential water and weak alkaline water, and is a water body with excellent oxidation resistance and aging resistance. Further studies on hydrogen-rich water at home and abroad in recent years have shown that hydrogen-rich water has a significant effect in preventing and treating adult diseases such as cancer and diabetes. Through clinical verification and tracking of 10 years by the most authoritative Japan, the hydrogen-rich water is definitely determined to have medical prevention effect on human bodies, is a selective antioxidant substance, and has very wide application prospect.
At present, the technology of electrolyzing purified water by adopting an electrolysis principle to obtain hydrogen-rich water in China is difficult to popularize in a large range, and the key points of the traditional electrolysis structure are that a large amount of electric energy is consumed in the water electrolysis process, the ion exchange efficiency is low, the manufacturing cost is high, and the electrolysis equipment is large in size and cannot be carried; in addition, the electrolysis of water to produce hydrogen-rich water is easy to generate ozone, which causes the defects of large peculiar smell, trace element lack and weak alkalinity in water, and the water is reduced to common water in a short time. The natural ceramic material micro-electrolysis hydrogen production is generally prepared by compounding tourmaline, metal magnesium powder and other materials or directly preparing hydrogen water by micro-electrolysis of active metals such as magnesium particles, magnesium rods and the like, but the materials have the defects of poor timeliness, low hydrogen production content, uncontrollable alkalinity, easy precipitate separation and the like, and seriously affect the taste of water. Meanwhile, active metals such as magnesium particles, magnesium rods and the like are very easy to oxidize in the air environment, basically do not work once oxidized, and excessive magnesium ions are easily dissolved out in water, so that the magnesium ions in the water exceed the standard. How to use natural mineral ceramic materials to produce hydrogen-rich water which is beneficial to human health becomes a problem to be solved urgently in the prior art.
Disclosure of Invention
The invention provides a ceramic material for preparing hydrogen water, which solves the technical problems of high cost, poor timeliness, low hydrogen production content, uncontrollable alkalinity, easy precipitation of precipitates and easy oxidation of the existing technology for preparing hydrogen water.
The technical scheme adopted by the invention is as follows:
the invention provides a hydrogen water-making ceramic material which is mainly prepared from the following raw materials in percentage by weight: 25-50% of tourmaline, 6-12% of medical stone, 5-10% of calcium oxide, 4-8% of calcium carbonate, 3-12% of diatomite, 8-18% of quartz sand, 4-8% of chitosan, 14-30% of metal magnesium powder, 1-5% of KDF alloy, 1-5% of antibacterial component and 4-10% of binder.
Further, the ceramic material for producing hydrogen and water is mainly prepared from the following raw materials in percentage by weight: 30% of tourmaline, 8% of medical stone, 6% of calcium oxide, 6% of calcium carbonate, 6% of diatomite, 12% of quartz sand, 4% of chitosan, 18% of metal magnesium powder, 2% of KDF alloy, 2% of antibacterial component and 6% of binder.
Further, the antibacterial component is one or more of silver, zinc oxide and titanium oxide.
Further, the binder is one or more of ethyl cellulose, methyl cellulose, kaolin, natural potassium feldspar and bentonite.
Furthermore, the grain sizes of the raw materials of the ceramic material for preparing hydrogen and water are all less than 20 microns.
According to another aspect of the present invention, there is also provided a method for preparing the ceramic material for hydrogen production, including the following steps:
(1) mixing tourmaline, medical stone, calcium oxide, calcium carbonate, diatomite, silicon oxide, chitosan, metal magnesium powder, KDF alloy and antibacterial components to obtain a mixture A; adding the binder into water or an organic solvent to dissolve to obtain a mixed solution;
(2) adding the mixture A prepared in the step (1) into the prepared mixed solution, and stirring to obtain a mixture B;
(3) and (3) baking the mixture B prepared in the step (2) in vacuum under the protection of hydrogen or inert gas to obtain the hydrogen water production ceramic material.
Further, the organic solvent in the step (1) is one or more of acetone, glycerol and absolute ethyl alcohol.
Further, the stirring in the step (2) is ultrasonic stirring, and the stirring time is 4-6 h.
Further, the baking temperature of the mixture B in the step (3) is 120-500 ℃, and the baking time is 0.2-3 h.
Further, in the step (3), the mixture B is granulated before baking, and then is subjected to dry pressing forming or plastic forming, and the shape of the obtained mixture B is a disc type, a cylinder type or a square type.
According to another aspect of the invention, the invention also provides an application of the hydrogen-water-making ceramic material, which is applied to water purifiers, water purifying kettles, water purifying cups and hydrogen-making rod products, and can also be used in bathing beauty and fruit and vegetable decontamination industries.
Compared with the prior art, the invention has the following beneficial effects:
(1) the ceramic material for producing hydrogen and water can produce healthy water with integrated functions of hydrogen-rich water, alkalescent water, negative potential water, small molecular water and the like, and also has the functions of sterilization and antibiosis. The ceramic material for preparing hydrogen and water can generate trace hydrogen and form micromolecular hydroxyl weak alkali ionized water by reacting with water. After the ceramic material for producing hydrogen water is put in water for 3 minutes, the content of hydrogen molecules in the water is more than or equal to 400ppb, and the pH value of the water is more than or equal to 7.4. The health water has effects of resisting oxidation and repairing cells, and can be rapidly absorbed by human body, regulating acid-base balance of human body, preventing diseases, strengthening body constitution, and prolonging life.
(2) The ceramic material for preparing hydrogen and water has low cost and simple use; is not easy to be oxidized, and does not generate precipitate when producing hydrogen.
(3) The preparation method of the ceramic material for preparing hydrogen and water is simple in process and easy to realize. Compared with the prior art, the method has the advantages that the cost for manufacturing the hydrogen-rich water is low, the ceramic material can be used in products such as a water purifier, a water purifying kettle, a water purifying cup and the like, the hydrogen production timeliness is good, and the carrying is convenient; ozone is avoided, and no peculiar smell is generated; the ceramic material is not oxidized in the preparation process and the use process, and does not generate precipitate.
In addition to the objects, features and advantages described above, other objects, features and advantages of the present invention are also provided. The present invention will be described in further detail below.
Detailed Description
It should be noted that the embodiments and features of the embodiments in the present application may be combined with each other without conflict. The invention will be described in detail below with reference to examples, but it can be implemented in many different ways as defined and covered by the claims.
Unless otherwise specified, the technical means used in the examples are conventional means well known to those skilled in the art.
The invention provides a hydrogen water preparation ceramic material which is mainly prepared from the following raw materials in percentage by weight: 25-50% of tourmaline, 6-12% of medical stone, 5-10% of calcium oxide, 4-8% of calcium carbonate, 3-12% of diatomite, 8-18% of quartz sand, 4-8% of chitosan, 14-30% of metal magnesium powder, 1-5% of KDF alloy, 1-5% of antibacterial component and 4-10% of binder. The ceramic material for producing hydrogen and water, which is prepared by combining the raw materials according to the proportion, has the functions of sterilization and bacteriostasis, can generate trace hydrogen and form micromolecular hydroxyl weak-base ionized water by reacting with the water, and can produce the healthy water integrating hydrogen-rich water, weak-base water, negative potential water and micromolecular water. The health water has effects of resisting oxidation and repairing cells, can be rapidly absorbed by human body, regulating acid-base balance of human body, preventing diseases, building body, and prolonging life.
The tourmaline which is added into the components of the invention can generate negative ions, has the function of adjusting the ion balance of human body, can relax body and mind, activate cells and inhibit the aging of the body; the surface of the device contains 0.06mA micro-current, can electrolyze water, and can supplement and regulate bioelectricity of a human body at any time to restore the pathological potential to normal, thereby playing the role of health care; can release far infrared rays (4-14 micron growing light rays) to permeate into deep parts of the body, so that capillaries are expanded, blood circulation is promoted, and metabolism is smooth; contains multiple effective trace minerals required by human body, and can regulate metabolism and maintain normal nutrition state and physiological function of organism; effectively block the harm of harmful electromagnetic waves, water pulses and other harmful radiation to human bodies. The far infrared energy wave released by the tourmaline can reduce water molecular beams, so that the tourmaline has strong permeability and good solubility and can be quickly absorbed by a human body; simultaneously releases a plurality of microelements beneficial to human body, and is beneficial to body health.
The components of the invention comprise medical stone materials, which contain clay minerals such as kaolinite and the like, have a special porous spongy structure and strong electrostatic attraction, have strong adsorption force on heavy metal ions and harmful toxins in water, can remove heavy metals such as mercury, lead, cadmium, arsenic, fluorine and the like and harmful substances such as chlorides, cyanides, residual pesticides, trimethyl alkane and the like in water, and can effectively purify water quality.
The diatomite material is added into the components, and mainly the diatomite has a natural micropore structure and can increase the specific surface area of the ceramic material, so that the contact area of each raw material and water is increased, and the speed of generating hydrogen is accelerated.
The composition of the invention also comprises chitosan, which can promote the reproduction of beneficial bacteria in the intestines and inhibit the growth of harmful bacteria. Meanwhile, the heavy metal in the body can be adsorbed and discharged.
The components of the invention contain calcium oxide, calcium carbonate and quartz sand, and the calcium oxide and the calcium carbonate can react with silicon dioxide in the quartz sand at high temperature to generate CaSiO3And the strength of the material is increased.
The invention uses KDF alloy powder material, which is a unique and novel water treatment medium meeting the environmental protection requirement, effectively reduces or removes chlorine and heavy metals in water through electrochemical oxidation-reduction reaction, and inhibits the growth and reproduction of microorganisms in water.
Preferably, the ceramic material for producing hydrogen and water is mainly prepared from the following raw materials in percentage by weight: 30% of tourmaline, 8% of medical stone, 6% of calcium oxide, 6% of calcium carbonate, 6% of diatomite, 12% of quartz sand, 4% of chitosan, 18% of metal magnesium powder, 2% of KDF alloy, 2% of antibacterial component and 6% of binder. The ceramic material for producing hydrogen and water, which is prepared by combining the raw materials according to the proportion, has the advantages of low baking temperature, good stability, high hydrogen production content, moderate water alkalinity and long service life, can better optimize the water quality, and is suitable for the requirements of human bodies.
Wherein, the preferred antibacterial component is one or more of silver, zinc oxide and titanium oxide. More preferably, the antimicrobial component is a mixture of silver, zinc oxide, titanium oxide. The metal silver material has an antibacterial function, improves the performance of antibacterial components, can form a microelectrode with Zn and Cu in KDF alloy, has positive influence on hydrogen production, and improves water quality.
Wherein, the preferred binder is one or more of ethyl cellulose, methyl cellulose, kaolin, natural potassium feldspar and bentonite. The above-mentioned binder enables a better shaping of the ceramic material.
Wherein, the grain size of the raw materials of the ceramic material for preparing hydrogen and water is preferably less than 20 microns. When the raw materials are purchased, all the raw materials are purchased with the grain diameter less than 20 microns, so that the raw materials can be mixed in the mixer at one time, the production procedures are reduced, and the production cost is reduced.
The invention also provides a preparation method of the hydrogen-water-making ceramic material, which comprises the following steps: (1) mixing tourmaline, medical stone, calcium oxide, calcium carbonate, diatomite, silicon oxide, chitosan, metal magnesium powder, KDF alloy and antibacterial components to obtain a mixture A; adding the binder into water or an organic solvent to dissolve to obtain a mixed solution; (2) adding the mixture A prepared in the step (1) into the prepared mixed solution, and stirring to obtain a mixture B; (3) and (3) baking the mixture B prepared in the step (2) in vacuum under the protection of hydrogen or inert gas to obtain the hydrogen water production ceramic material. In the preparation method, the mixture B is baked in vacuum or under the protection of hydrogen or inert gas to prepare the hydrogen water-making ceramic material, so that the metal magnesium powder can be protected from being oxidized in the baking process, and the service life of the hydrogen water-making ceramic material is prolonged.
Wherein, the organic solvent in the step (1) is preferably one or more of acetone, glycerol and absolute ethyl alcohol. The binder is dissolved in the organic solvent, so that the binding effect can be better exerted, and the structure of the ceramic material for preparing hydrogen and water is more stable.
Preferably, the stirring in the step (2) is ultrasonic stirring, and the stirring time is 4-6 h. The mixture A and the mixed liquid can be fully and uniformly mixed by stirring according to the conditions, the bonding force among the components is strong, and the obtained hydrogen production water ceramic material is uniform in material and better in forming.
Preferably, the baking temperature of the mixture B in the step (3) is 120-500 ℃, and the baking time is 0.2-3 h. The mixture B is baked at low temperature according to the condition, the structure of the raw materials is not damaged, and the performance of each raw material is better exerted.
Preferably, when the binder is one or more of kaolin, natural potassium feldspar and bentonite, or the binder is a mixture of ethyl cellulose and one or more of the three binders, or a mixture of methyl cellulose and one or more of the three binders, the mixture B prepared in the step (2) is subjected to vacuum, hydrogen or inert gas protection, and baking or calcining can be selected to prepare the hydrogen-water ceramic material. When a calcination method is adopted, the calcination temperature of the mixture B prepared in the step (2) is 800-1200 ℃, and the calcination time is 0.5-10 h. The adoption of the calcination method with higher temperature can improve the hardness of the obtained hydrogen production ceramic material, can not generate dust after long-term use, can optimize the water quality for a long time, and promotes the health.
Preferably, the mixture B in the step (3) is granulated before baking, and then is subjected to dry pressing or plastic forming, and the shape of the obtained mixture B is a disc, cylinder or square. The finally obtained ceramic material for producing hydrogen and water is also in the shape of a circular sheet, a cylinder or a square, and can also be made into other different shapes so as to meet the requirements of different products and expand the application range.
The invention also provides application of the hydrogen production water ceramic material, which can be applied to water purifiers, water purifying kettles, water purifying cups and hydrogen production rod products, and can also be applied to bathing beauty and fruit and vegetable decontamination industries. The ceramic material for preparing hydrogen and water has wide application, the finished product is convenient to carry, and the timeliness of the preparation of hydrogen-rich water is improved.
Examples
All materials and equipment are commercially available in the following examples.
Example 1
The preferred embodiment of the invention provides a hydrogen water-making ceramic material which is mainly prepared from the following raw materials: 7.43g of tourmaline, 1.32g of medical stone, 1.06g of calcium oxide, 1.06g of calcium carbonate, 0.91g of diatomite, 1.93g of quartz sand, 1.23g of chitosan, 4.20g of metal magnesium powder, 0.38g of KDF alloy, 0.21g of titanium oxide, 0.21g of zinc oxide and 1.27g of ethyl cellulose.
The preferred embodiment of the present invention further provides a method for preparing the ceramic material for hydrogen production, which comprises the following steps:
(1) respectively weighing 7.43g of tourmaline, 1.32g of medical stone, 1.06g of calcium oxide, 1.06g of calcium carbonate, 0.91g of diatomite, 1.93g of quartz sand, 1.23g of chitosan, 4.20g of metal magnesium powder, 0.38g of KDF alloy, 0.21g of titanium oxide and 0.21g of zinc oxide, adding into a mixer, and mixing for 2 hours to obtain a mixture A; 1.27g of ethyl cellulose is weighed, added into 30ml of absolute ethyl alcohol, heated and fully stirred for 0.5h to obtain a mixed solution.
(2) And slowly adding the mixture A into the mixed solution, and carrying out ultrasonic stirring while adding, stirring for 4 hours until the mixture is uniformly mixed to obtain a mixture B.
(3) And placing the mixture B in an oven for baking for 5h at 50 ℃, then dry-pressing the mixture B into a cylinder, and placing the cylinder in a vacuum oven for baking at 200 ℃ for 2h to obtain the hydrogen water-making ceramic material.
Example 2
The preferred embodiment of the invention provides a hydrogen water-making ceramic material which is mainly prepared from the following raw materials: 6.03g of tourmaline, 2.69g of medical stone, 1.76g of calcium oxide, 1.02g of calcium carbonate, 1.39g of diatomite, 2.67g of quartz sand, 0.97g of chitosan, 3.43g of metal magnesium powder, 0.67g of KDF alloy, 0.36g of silver, 0.25g of zinc oxide, 0.18g of titanium oxide, 0.83g of methyl cellulose, 0.45g of natural potash feldspar and 0.38g of bentonite.
The preferred embodiment of the present invention further provides a method for preparing the ceramic material for hydrogen production, which comprises the following steps:
(1) respectively weighing 6.03g of tourmaline, 2.69g of medical stone, 1.76g of calcium oxide, 1.02g of calcium carbonate, 1.39g of diatomite, 2.67g of quartz sand, 0.97g of chitosan, 3.43g of metal magnesium powder, 0.67g of KDF alloy, 0.36g of silver, 0.25g of zinc oxide and 0.18g of titanium oxide, adding into a mixer, and mixing for 2 hours to obtain a mixture A; 0.83g of methylcellulose, 0.45g of natural potash feldspar and 0.38g of bentonite are weighed, added into 30ml of distilled water and fully stirred for 0.5h to obtain a mixed solution.
(2) And slowly adding the mixture A into the mixed solution, and carrying out ultrasonic stirring while adding, stirring for 5 hours until the mixture is uniformly mixed to obtain a mixture B.
(3) And placing the mixture B in an oven to bake for 2 hours at 100 ℃, then forming the mixture B into a wafer shape by dry pressing, and placing the wafer shape in a high-temperature oven to bake under the protection of argon, wherein the baking temperature is 400 ℃, and the baking time is 0.5 hour, thus obtaining the hydrogen water-making ceramic material.
Example 3
The preferred embodiment of the invention provides a hydrogen water-making ceramic material which is mainly prepared from the following raw materials: 10.51g of tourmaline, 1.46g of medical stone, 1.02g of calcium oxide, 1.29g of calcium carbonate, 0.87g of diatomite, 2.00g of quartz sand, 0.97g of chitosan, 3.77g of metal magnesium powder, 0.31g of KDF alloy, 0.19g of zinc oxide, 0.23g of titanium oxide, 0.49g of kaolin and 0.45g of natural potash feldspar.
The preferred embodiment of the present invention further provides a method for preparing the ceramic material for hydrogen production, which comprises the following steps:
(1) respectively weighing 10.51g of tourmaline, 1.46g of medical stone, 1.02g of calcium oxide, 1.29g of calcium carbonate, 0.87g of diatomite, 2.00g of quartz sand, 0.97g of chitosan, 3.77g of metal magnesium powder, 0.31g of KDF alloy, 0.19g of zinc oxide and 0.23g of titanium oxide, adding into a mixer, and mixing for 2 hours to obtain a mixture A; 0.49g of kaolin and 0.45g of natural potash feldspar are weighed and added into 30ml of acetone, and the mixture is fully stirred for 0.5h to obtain a mixed solution.
(2) And slowly adding the mixture A into the mixed solution, and carrying out ultrasonic stirring while adding, stirring for 5 hours until the mixture is uniformly mixed to obtain a mixture B.
(3) And placing the mixture B in an oven for baking for 5h at 90 ℃, then dry-pressing the mixture B into a square shape, and placing the square shape in a high-temperature oven for baking under the protection of hydrogen at the baking temperature of 500 ℃ for 2h to obtain the hydrogen water-making ceramic material.
Example 4
The preferred embodiment of the invention provides a hydrogen water-making ceramic material which is mainly prepared from the following raw materials: 7.31g of tourmaline, 1.95g of medical stone, 1.13g of calcium oxide, 1.80g of calcium carbonate, 1.46g of diatomite, 2.93g of quartz sand, 0.98g of chitosan, 4.39g of metal magnesium powder, 0.49g of KDF alloy, 0.24g of silver, 0.12g of titanium oxide, 0.12g of zinc oxide and 1.46g of bentonite.
The preferred embodiment of the present invention further provides a method for preparing the ceramic material for hydrogen production, which comprises the following steps:
(1) respectively weighing 7.31g of tourmaline, 1.95g of medical stone, 1.13g of calcium oxide, 1.80g of calcium carbonate, 1.46g of diatomite, 2.93g of quartz sand, 0.98g of chitosan, 4.39g of metal magnesium powder, 0.49g of KDF alloy, 0.24g of silver, 0.12g of titanium oxide and 0.12g of zinc oxide, adding into a mixer, and mixing for 2 hours to obtain a mixture A; 1.46g of bentonite is weighed, added into 30ml of glycerol and fully stirred for 0.5h to obtain a mixed solution.
(2) And slowly adding the mixture A into the mixed solution, and carrying out ultrasonic stirring while adding, stirring for 6 hours until the mixture is uniformly mixed to obtain a mixture B.
(3) And placing the mixture B in an oven for baking for 5h at 90 ℃, then dry-pressing the mixture B into a cylinder shape, and placing the cylinder shape in a high-temperature furnace for baking under the protection of hydrogen, wherein the baking temperature is 500 ℃, and the baking time is 3h, so that the hydrogen water-making ceramic material is obtained.
Example 5
The preferred embodiment of the invention provides a hydrogen water-making ceramic material which is mainly prepared from the following raw materials: 11.98g of tourmaline, 1.44g of medical stone, 0.92g of calcium oxide, 1.24g of calcium carbonate, 0.72g of diatomite, 1.92g of quartz sand, 0.96g of chitosan, 3.35g of metal magnesium powder, 0.24g of KDF alloy, 0.12g of silver, 0.12g of zinc oxide and 0.96g of bentonite.
The preferred embodiment of the present invention further provides a method for preparing the ceramic material for hydrogen production, which comprises the following steps:
(1) respectively weighing 11.98g of tourmaline, 1.44g of medical stone, 0.92g of calcium oxide, 1.24g of calcium carbonate, 0.72g of diatomite, 1.92g of quartz sand, 0.96g of chitosan, 3.35g of metal magnesium powder, 0.24g of KDF alloy, 0.12g of silver and 0.12g of zinc oxide, and adding the materials into a mixer for mixing for 2 hours to obtain a mixture A; 0.96g of bentonite is weighed, added into 30ml of acetone and fully stirred for 0.5h to obtain a mixed solution.
(2) And slowly adding the mixture A into the mixed solution, and carrying out ultrasonic stirring while adding, stirring for 4 hours until the mixture is uniformly mixed to obtain a mixture B.
(3) And placing the mixture B in an oven to bake for 5 hours at 40 ℃, then dry-pressing the mixture B into a cylinder shape, and placing the cylinder shape in a high-temperature furnace to bake under the protection of hydrogen at 500 ℃ for 1 hour to obtain the hydrogen water-making ceramic material.
Example 6
The preferred embodiment of the invention provides a hydrogen water-making ceramic material which is mainly prepared from the following raw materials: 5.40g of tourmaline, 2.59g of medical stone, 1.12g of calcium oxide, 1.04g of calcium carbonate, 1.51g of diatomite, 1.73g of quartz sand, 1.73g of chitosan, 3.02g of metal magnesium powder, 1.08g of KDF alloy, 0.22g of silver and 2.16g of bentonite.
The preferred embodiment of the present invention further provides a method for preparing the ceramic material for hydrogen production, which comprises the following steps:
(1) respectively weighing 5.40g of tourmaline, 2.59g of medical stone, 1.12g of calcium oxide, 1.04g of calcium carbonate, 1.51g of diatomite, 1.73g of quartz sand, 1.73g of chitosan, 3.02g of metal magnesium powder, 1.08g of KDF alloy and 0.22g of silver, and adding the materials into a mixer to mix for 2 hours to obtain a mixture A; 2.16g of bentonite is weighed, added into 30ml of water and fully stirred for 0.5h to obtain a mixed solution.
(2) And slowly adding the mixture A into the mixed solution, and carrying out ultrasonic stirring while adding, stirring for 5 hours until the mixture is uniformly mixed to obtain a mixture B.
(3) And placing the mixture B in an oven to bake for 3h at 100 ℃, then dry-pressing the mixture B into a cylinder shape, and placing the cylinder shape in a high-temperature furnace to bake under the protection of hydrogen, wherein the baking temperature is 400 ℃, and the baking time is 1h, thus obtaining the hydrogen water-making ceramic material.
Example 7
The preferred embodiment of the invention provides a hydrogen water-making ceramic material which is mainly prepared from the following raw materials: 5.51g of tourmaline, 1.32g of medical stone, 3.01g of calcium oxide, 0.96g of calcium carbonate, 1.98g of diatomite, 3.97g of quartz sand, 0.88g of chitosan, 3.08g of metal magnesium powder, 0.22g of KDF alloy, 0.11g of titanium oxide, 0.11g of zinc oxide, 0.68g of ethyl cellulose and 0.20g of kaolin.
The preferred embodiment of the present invention further provides a method for preparing the ceramic material for hydrogen production, which comprises the following steps:
(1) respectively weighing 5.51g of tourmaline, 1.32g of medical stone, 3.01g of calcium oxide, 0.96g of calcium carbonate, 1.98g of diatomite, 3.97g of quartz sand, 0.88g of chitosan, 3.08g of metal magnesium powder, 0.22g of KDF alloy, 0.11g of titanium oxide and 0.11g of zinc oxide, adding into a mixer, and mixing for 2 hours to obtain a mixture A; 0.68g of ethyl cellulose and 0.20g of kaolin are weighed and added into 30ml of absolute ethyl alcohol, and the mixture is fully stirred for 0.5h to obtain a mixed solution.
(2) And slowly adding the mixture A into the mixed solution, and carrying out ultrasonic stirring while adding, stirring for 5 hours until the mixture is uniformly mixed to obtain a mixture B.
(3) And placing the mixture B in an oven to bake for 1h at 50 ℃, then dry-pressing the mixture B into a cylinder shape, and placing the cylinder shape in a high-temperature furnace to bake under the protection of hydrogen, wherein the baking temperature is 120 ℃, and the baking time is 1h, thus obtaining the hydrogen water-making ceramic material.
Example 8
The preferred embodiment of the invention provides a hydrogen water-making ceramic material which is mainly prepared from the following raw materials: 5.64g of tourmaline, 1.35g of medical stone, 1.11g of calcium oxide, 0.92g of calcium carbonate, 2.70g of diatomite, 1.80g of quartz sand, 0.90g of chitosan, 6.76g of metal magnesium powder, 0.23g of KDF alloy, 0.11g of titanium oxide, 0.11g of zinc oxide, 0.62g of methyl cellulose and 0.28g of bentonite.
The preferred embodiment of the present invention further provides a method for preparing the ceramic material for hydrogen production, which comprises the following steps:
(1) respectively weighing 5.64g of tourmaline, 1.35g of medical stone, 1.11g of calcium oxide, 0.92g of calcium carbonate, 2.70g of diatomite, 1.80g of quartz sand, 0.90g of chitosan, 6.76g of metal magnesium powder, 0.23g of KDF alloy, 0.11g of titanium oxide and 0.11g of zinc oxide, adding into a mixer, and mixing for 2 hours to obtain a mixture A; 0.62g of methylcellulose and 0.28g of bentonite are weighed and added into 30ml of distilled water, and the mixture is fully stirred for 0.5h to obtain a mixed solution.
(2) And slowly adding the mixture A into the mixed solution, and carrying out ultrasonic stirring while adding, stirring for 5 hours until the mixture is uniformly mixed to obtain a mixture B.
(3) And placing the mixture B into an oven to be baked for 2 hours at 100 ℃, then dry-pressing the mixture B into a cylinder shape, and placing the cylinder shape into a high-temperature furnace to be baked under the protection of hydrogen, wherein the baking temperature is 350 ℃, and the baking time is 1.5 hours, thus obtaining the hydrogen water-making ceramic material.
The hydrogen production water ceramic material prepared in the embodiments 1 to 8 is washed clean with distilled water, 20g is weighed and placed into a beaker, 200mL of purified water is poured, and the hydrogen molecular content, the pH value and the ORP value are respectively tested for 5 minutes, 60 minutes and 600 minutes, and the test results are shown in Table 1.
TABLE 1 test results of pure water with ceramic material for hydrogen production
From the above description, the ceramic material for producing hydrogen and water of the present embodiment has bactericidal and bacteriostatic effects, can produce trace hydrogen and form small molecular hydroxyl weak base ionized water by reacting with water, and can produce healthy water integrating hydrogen-rich water, weak base water, negative potential water and small molecular water. The health water has effects of resisting oxidation and repairing cells, can be rapidly absorbed by human body, regulating acid-base balance of human body, preventing diseases, building body, and prolonging life. The preparation method of the ceramic material for preparing hydrogen and water is simple in process and easy to implement.
The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention, and various modifications and changes may be made by those skilled in the art. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (3)
1. A method for preparing a hydrogen-making water ceramic material is characterized in that,
the hydrogen water-making ceramic material is mainly prepared from the following raw materials in percentage by weight:
30% of tourmaline, 8% of medical stone, 6% of calcium oxide, 6% of calcium carbonate, 6% of diatomite, 12% of quartz sand, 4% of chitosan, 18% of metal magnesium powder, 2% of KDF alloy, 2% of antibacterial component and 6% of binder;
the antibacterial component is silver;
the binder is one or more of ethyl cellulose, methyl cellulose, kaolin, natural potassium feldspar and bentonite;
the grain sizes of the raw materials of the ceramic material for producing hydrogen and water are all less than 20 microns;
the preparation method comprises the following steps:
(1) mixing tourmaline, medical stone, calcium oxide, calcium carbonate, diatomite, quartz sand, chitosan, metal magnesium powder, KDF alloy and antibacterial components to obtain a mixture A; adding the binder into water or an organic solvent to dissolve to obtain a mixed solution, wherein the organic solvent is one or more of acetone, glycerol and absolute ethyl alcohol;
(2) adding the mixture A prepared in the step (1) into the prepared mixed solution for ultrasonic stirring for 4-5 hours to obtain a mixture B;
(3) and (3) granulating the mixture B prepared in the step (2), and then carrying out dry pressing forming or plastic forming, wherein the obtained mixture B is in a shape of a circular sheet, a cylinder or a square, and then baking in vacuum under the protection of hydrogen or inert gas at the baking temperature of 120-500 ℃ for 0.2-3 h to obtain the hydrogen water production ceramic material.
2. The application of the ceramic material for producing hydrogen and water prepared by the preparation method in claim 1 is characterized by being applied to a water purifier, a water purifying kettle, a water purifying cup or a product of a hydrogen producing rod.
3. The application of the ceramic material for producing hydrogen and water prepared by the preparation method in claim 1 is characterized by being used in bath beauty and fruit and vegetable decontamination industries.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710729360.9A CN107573047B (en) | 2017-08-22 | 2017-08-22 | Hydrogen water preparation ceramic material and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710729360.9A CN107573047B (en) | 2017-08-22 | 2017-08-22 | Hydrogen water preparation ceramic material and preparation method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107573047A CN107573047A (en) | 2018-01-12 |
| CN107573047B true CN107573047B (en) | 2020-06-19 |
Family
ID=61035943
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710729360.9A Active CN107573047B (en) | 2017-08-22 | 2017-08-22 | Hydrogen water preparation ceramic material and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107573047B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110872183A (en) * | 2018-09-03 | 2020-03-10 | 上海安娜奥环境科技有限公司 | Ceramic ball capable of rapidly producing hydrogen in water without external force and preparation method thereof |
| CN109179620B (en) * | 2018-10-12 | 2020-07-28 | 北京慧博源生物科技有限公司 | Combined multifunctional health-preserving hydrogen-rich water sheet |
| CN112723740A (en) * | 2020-12-29 | 2021-04-30 | 潮州市智信新材料科技有限公司 | Functional glaze for promoting water molecules to be in oxygen-enriched state and preparation method thereof |
| CN112980320A (en) * | 2021-02-23 | 2021-06-18 | 佛山市藻晨科技有限公司 | Micro-electrolysis inorganic ceramic coating, preparation method and application thereof |
| CN113998988A (en) * | 2021-11-09 | 2022-02-01 | 上海超高环保科技股份有限公司 | Method for manufacturing sheet, block, tubular and special-shaped material for hydrogen storage |
| CN114314793A (en) * | 2022-01-06 | 2022-04-12 | 青岛诺康新氢源研究院有限公司 | Hydrogen production particle capable of generating porous structure on site and preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101497522A (en) * | 2008-12-12 | 2009-08-05 | 方敬亮 | Ceramic material for purification, activation and healthcare |
| CN102219498A (en) * | 2011-03-31 | 2011-10-19 | 厦门建霖工业有限公司 | Water purification ceramic material and preparation method thereof |
| CN104072106A (en) * | 2014-07-15 | 2014-10-01 | 任新年 | Water element stone ceramic ball and preparing method thereof |
| CN105084468A (en) * | 2015-07-30 | 2015-11-25 | 济南木齐健康科技有限公司 | Ceramal material for manufacturing hydrogen-enriched water and preparing method and application thereof |
| CN105905426A (en) * | 2016-05-19 | 2016-08-31 | 蒋亚熙 | Beverage bottle capable of generating healthy water |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102180676B (en) * | 2011-01-04 | 2013-07-17 | 厦门建霖工业有限公司 | Preparation method of ceramic balls loaded with nano copper-zinc-silver |
-
2017
- 2017-08-22 CN CN201710729360.9A patent/CN107573047B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101497522A (en) * | 2008-12-12 | 2009-08-05 | 方敬亮 | Ceramic material for purification, activation and healthcare |
| CN102219498A (en) * | 2011-03-31 | 2011-10-19 | 厦门建霖工业有限公司 | Water purification ceramic material and preparation method thereof |
| CN104072106A (en) * | 2014-07-15 | 2014-10-01 | 任新年 | Water element stone ceramic ball and preparing method thereof |
| CN105084468A (en) * | 2015-07-30 | 2015-11-25 | 济南木齐健康科技有限公司 | Ceramal material for manufacturing hydrogen-enriched water and preparing method and application thereof |
| CN105905426A (en) * | 2016-05-19 | 2016-08-31 | 蒋亚熙 | Beverage bottle capable of generating healthy water |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107573047A (en) | 2018-01-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107573047B (en) | Hydrogen water preparation ceramic material and preparation method and application thereof | |
| CN105084468B (en) | Manufacture hydrogen rich water alloy ceramic and its preparation method and application | |
| CN108727007A (en) | More effect water purification ceramic materials and its preparation method and application | |
| CN108623224B (en) | Reduction antibacterial material and preparation method thereof | |
| CN102219498B (en) | Water purification ceramic material and preparation method thereof | |
| CN101693631B (en) | Porous ceramicite and preparation method and application thereof | |
| JP2018193292A (en) | Composite ceramic and method of production and method of application thereof | |
| CN106115621B (en) | Graphene activates hydrogen manufacturing material and its preparation method and application | |
| CN108715556A (en) | Multifunctional ceramic material and its preparation method and application | |
| CN102795737A (en) | Preparation method of weakly alkaline drinking water | |
| CN108059480A (en) | A kind of illite function haydite and preparation method thereof | |
| CN102805973A (en) | Water filter material, producing process of water filter material and corresponding water filter device | |
| CN102992741A (en) | Special biological source organic-inorganic antibacterial ceramic tea set | |
| CN113105221B (en) | Negative hydrogen ion water activating material and its producing method | |
| CN106219693A (en) | Special tourmaline ceramic filter element and preparation method thereof and the strong anti-oxidation obtained by its process, subset reductive water | |
| JP6010834B2 (en) | Antibacterial ceramic body | |
| CN101134112B (en) | Silver-carrying active aluminum oxide antimicrobials and method for preparing the same | |
| CN101531499A (en) | Far-infrared functional ceramic ball and manufacturing method thereof | |
| CN1557728A (en) | Antimicrobial compound for anion water purifying and activating, its pelletized product and preparation method | |
| CN109179620B (en) | Combined multifunctional health-preserving hydrogen-rich water sheet | |
| KR100740860B1 (en) | Water treating material and method for production of alkaline reducing water using the same | |
| KR101102429B1 (en) | Sericite exchanged metal ion having anti-bacteria and preparing methods for thereof | |
| CN105985141A (en) | Method for preparing modified nano catalytic zinc oxide antimicrobial ceramic | |
| CN106673632B (en) | Special water treatment functional ceramic for cosmetics | |
| KR100907911B1 (en) | Water purifier with reduction function |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |