CN105048028B - A kind of terahertz filter and preparation method thereof - Google Patents

A kind of terahertz filter and preparation method thereof Download PDF

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CN105048028B
CN105048028B CN201510439332.4A CN201510439332A CN105048028B CN 105048028 B CN105048028 B CN 105048028B CN 201510439332 A CN201510439332 A CN 201510439332A CN 105048028 B CN105048028 B CN 105048028B
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polymeric material
photoresist
metal
laminated structure
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CN105048028A (en
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李修函
徐征帅
朱王强
杨天阳
许巍
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Beijing Jiaotong University
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Abstract

The embodiment of the invention provides a kind of terahertz filters and preparation method thereof.It include: polymeric material layer and metal layer;The metal layer includes laminated structure, and the laminated structure includes horizontal stripe and taeniae;The laminated structure periodic distribution is in the polymeric material layer.Through the embodiment of the present invention, the filter range of filter is expanded, and is relatively beneficial to terahertz filter applied in other systems.

Description

A kind of terahertz filter and preparation method thereof
Technical field
The present invention relates to electromagnetic wave filtration arts more particularly to a kind of terahertz filter and preparation method thereof.
Background technique
Terahertz (THz) wave refers to electromagnetic wave of the frequency between 0.1~10THz (30 μm~3mm of corresponding wavelength), between Between visible light and microwave.THz wave has the unique physical characteristics such as transient state, low energy, strong penetrability, is allowed in width The band fields such as communication, image objects, environmental monitoring, medical diagnosis, safety inspection have wide practical use.In practical application In, the electromagnetic wave and noise for filtering out unwanted frequency range are generally required, to inhibit ambient noise, improves THz wave Performance.In order to solve this problem, the filtering to electromagnetic wave is realized generally by terahertz filter.
The prior art provides a kind of adjustable THz wave bandstop filter based on Meta Materials artificial structure, the filter Array is formed including several duplicate sub-wavelength resonance structures, and each resonance structure is by printable opening a pair of Mouthful contrary molten be combined together of metal U-shaped structure and formed.By change that the two fused structures mutually cover away from From, it can be achieved that stopband electromagnetic property linear frequency adjustability, the stopband of the bandstop filter is between 0.5-1.0THz.
But the filter filtering range is still relatively narrow, scalability is not strong, it is difficult to be applied to actual Terahertz system In, so urgent those skilled in the art are that how to expand the filter range of filter the technical issues of solution, to increase Terahertz filter is applied to the possibility in system.
Summary of the invention
The embodiment provides a kind of terahertz filter, the filter range of filter is expanded, and is increased too Hertz filter is applied to the possibility in system.
To achieve the goals above, this invention takes following technical solutions.
A kind of terahertz filter, comprising: polymeric material layer and metal layer;The metal layer includes laminated structure, institute Stating laminated structure includes horizontal stripe and taeniae;The laminated structure periodic distribution is in the polymeric material layer.
Preferably, the polymeric material layer is flexible polymeric material.
Preferably, the flexible polymeric material includes: Parylene, polymethyl methacrylate or polydimethylsiloxanes Alkane.
Preferably, the metal layer is multilayer, filling flexible polymeric material between the metal layer.
Preferably, the metal layer is two layers or three layers, and the distance between described adjacent metal is 1nm~100 μm.
Preferably, the laminated structure for belonging to same layer is identical;The laminated structure with a thickness of 1nm~100 μm;Institute The length for stating horizontal stripe is 1nm~1000 μm;The length of the taeniae is 1nm~1000 μm.
Preferably, the laminated structure is I type, II type or III type.
A kind of production method of terahertz filter, comprising:
Using double throwing silicon wafers as support substrate piece, by thermal oxidation process, in one layer of dioxy of the substrate slice Surface Creation SiClx insulating medium layer;
First layer polymeric material is formed in double silicon chip surface precipitating flexible polymer materials of throwing;
Using the first layer polymeric material as the first substrate, cleaning, and smear photoresist;
The photoresist smeared on the first layer polymeric material, the light of developed removal exposure area are exposed using mask plate Photoresist;
The first layer polymeric materials splash-proofing sputtering metal after exposure forms the first metal layer;
Removal photoresist is removed with acetone, the metal sputtered on the photoresist is removed together;
First layer polymeric materials precipitating flexible polymeric material after removing photoresist is as the second layers of polymer Material, the first layer polymeric material and the second layer polymeric material form polymeric material layer.
Preferably, the first layer polymeric material thickness is 1 μm~200 μm;The first metal layer with a thickness of 1nm~ 100μm。
Preferably, further includes:
Using the second layer polymeric material as the second substrate, cleaning, and smear photoresist;
It is exposed using the mask plate of laminated structure figure as described in claim 1 and is smeared on the second layer polymeric material Photoresist, it is developed removal exposure area photoresist;
The second layer polymeric materials splash-proofing sputtering metal after exposure forms second metal layer, with a thickness of 1nm~100 μm;
Removal photoresist is removed with acetone, the metal sputtered on the photoresist is removed together;
Second layer polymeric materials precipitating flexible polymeric material after removing photoresist is as third layers of polymer Material, the first layer polymeric material, the second layer polymeric material and third layer polymeric material form polymeric material layer;
And so on, until obtaining the terahertz filter with the metal layer for needing quantity.
As can be seen from the technical scheme provided by the above-mentioned embodiment of the present invention, the embodiment of the present invention is by setting metal layer Slabbing structure is counted, and periodic distribution forms terahertz filter in the polymeric material layer made of flexible polymeric material, it can Effectively to filter the THz wave of certain wavelength band, by the way that the size of laminated structure and each laminated structure is mutual The distance between, the adjusting to resistance band or peak value may be implemented;The embodiment of the present invention can also be arranged as needed At multilayered structure, a certain range of THz wave is filtered out with realizing, by adjusting the size of each lamellar structure, adjacent gold Belong to the distance between layer, or even the laminated structure on different metal layer is arranged to different sizes, may be implemented to difference too Hertz wave wave band filters out, wherein with the increase of laminated structure geometric dimension, the position of absorption peak is mobile to high frequency band;And With the increase of interfloor distance, stop-band frequency is mobile to low-frequency band.
The additional aspect of the present invention and advantage will be set forth in part in the description, these will become from the following description Obviously, or embodiment through the invention is recognized.
Detailed description of the invention
In order to illustrate the technical solution of the embodiments of the present invention more clearly, required use in being described below to embodiment Attached drawing be briefly described, it should be apparent that, drawings in the following description are only some embodiments of the invention, for this For the those of ordinary skill of field, without any creative labor, it can also be obtained according to these attached drawings other Attached drawing.
Fig. 1 is a kind of terahertz filter structural schematic diagram that the embodiment of the present invention one provides;
Fig. 2 is a kind of terahertz filter laminated structure schematic diagram that the embodiment of the present invention one provides;
Fig. 3 is single layer polymeric material terahertz filter absorbance curves figure;
Fig. 4 is a kind of multilayer terahertz filter structural schematic diagram that the embodiment of the present invention one provides;
Fig. 5 is a kind of multilayer terahertz filter Structure of cross section schematic diagram that the embodiment of the present invention one provides;
Fig. 6 is a kind of multiple layer of polymeric material terahertz filter absorbance curves figure that the embodiment of the present invention one provides;
Fig. 7 is a kind of multiple layer of polymeric material terahertz filter process flow chart provided by Embodiment 2 of the present invention;
It include: polymeric material layer 110, metal layer 120, laminated structure 121, horizontal stripe 122, taeniae 123 in above-mentioned attached drawing;Branch Support substrate slice 1, insulating medium layer 2, first layer polymeric material 111, photoresist 3, the first metal layer 4, second layer metal layer 5, the Three-layer metal layer 6, the Terahertz wide-band filter 100 comprising three-layer metal layer 120.
Specific embodiment
Embodiments of the present invention are described below in detail, the example of the embodiment is shown in the accompanying drawings, wherein from beginning Same or similar element or element with the same or similar functions are indicated to same or similar label eventually.Below by ginseng The embodiment for examining attached drawing description is exemplary, and for explaining only the invention, and is not construed as limiting the claims.
Those skilled in the art of the present technique are appreciated that unless expressly stated, singular " one " used herein, " one It is a ", " described " and "the" may also comprise plural form.It is to be further understood that being arranged used in specification of the invention Diction " comprising " refer to that there are the feature, integer, step, operation, element and/or component, but it is not excluded that in the presence of or addition Other one or more features, integer, step, operation, element, component and/or their group.It should be understood that when we claim member Part is " connected " or when " coupled " to another element, it can be directly connected or coupled to other elements, or there may also be Intermediary element.In addition, " connection " used herein or " coupling " may include being wirelessly connected or coupling.Wording used herein "and/or" includes one or more associated any cells for listing item and all combinations.
Those skilled in the art of the present technique are appreciated that unless otherwise defined, all terms used herein (including technology art Language and scientific term) there is meaning identical with the general understanding of those of ordinary skill in fields of the present invention.Should also Understand, those terms such as defined in the general dictionary, which should be understood that, to be had and the meaning in the context of the prior art The consistent meaning of justice, and unless defined as here, it will not be explained in an idealized or overly formal meaning.
In order to facilitate understanding of embodiments of the present invention, it is done by taking several specific embodiments as an example below in conjunction with attached drawing further Explanation, and each embodiment does not constitute the restriction to the embodiment of the present invention.
Embodiment one
This embodiment offers a kind of terahertz filters, and specific implementation structure is as shown in Figure 1, Figure 2, Figure 3, Figure 4, can To include;
Polymeric material layer 110 and metal layer 120, wherein polymeric material layer be made of flexible polymeric material for example, Parylene (Parylene), PMMA (Polymethylmethacrylate, polymethyl methacrylate), PDMS Flexibilities such as (polydimethylsiloxane, dimethyl silicone polymers) and the excellent polymer material of translucency, such as Fig. 2 institute Show, metal layer 120 is that laminated structure 121 includes horizontal stripe 122 and taeniae 123;Metal layer can be by resistivity such as copper, aluminium, silver Low, good conductivity metal material is made;Laminated structure periodic distribution is in polymeric material layer 110.
The embodiment of the present invention in the specific implementation process, in order to realize the demand for filtering out different THz waves, metal layer 120 It can be set to one layer, may be set to be multilayer.
For the embodiment of the present invention with one layer of metal layer 120, by the periodic distance, the ruler that change laminated structure 121 It is very little etc., the different THz wave filter of available absorption peak;With the increasing of the geometric dimension of the laminated structure of metal layer Greatly, the position of absorption peak is mobile to high frequency band, for example, as shown in Fig. 2, (becoming laminated structure by the length b for adjusting horizontal stripe 122 121 width), the length a of the length c of taeniae 123 and/or laminated structure 121, and for multiple horizontal stripes 122 and/or Taeniae 123, the width between different horizontal stripes 122 and/or between different taeniaes 123 can also be adjusted, in turn, is realized to difference The absorption of the THz wave of peak value.Wherein, as shown in figure 3, Fig. 3 show metal layer of the embodiment of the present invention 120 be single layer when, to too The absorbance curves of Hertz wave, the embodiment of the present invention absorbs the Terahertz at 0.92THz close to perfection as seen from Figure 3 Wave, and reached within the scope of 0.8THz to 1THz 90% or more THz wave absorptivity.
In addition, as shown in Figure 4, Figure 5, Fig. 4 is the structural schematic diagram of three layers of THz wave filter, Fig. 5 is three layers of terahertz The hereby Structure of cross section schematic diagram of wave filter.For the embodiment of the present invention with more metal layers 120, can also pass through by Each layer is arranged to the periodic distance with various sizes of laminated structure 121 and each lamellar structure 121, between layers Distance, it is available absorb the continuous peak value of cluster THz wave filter.By to dielectric material thickness, dielectric constant Design, make Meta Materials absorption peak generate frequency displacement, so as to realize the movement of the filter passband in certain wavelength band And tuning.The embodiment of the present invention has been presented in Fig. 6 the absorbance curves that this filter is obtained by emulation, and stopband range exists 0.7 to 2.1THz wide frequency range, this programme are also extended to the integrated full Terahertz frequency of 2n (n >=1) a filter The filter that domain absorbs.
In practical applications, for the embodiment of the present invention with more metal layers 120 generally by adjacent metal 120 it Between distance be set as 1nm~100 μm, wherein distance be 10nm, 100nm, 10 μm when, the effect for inhaling THz wave is more preferable; 1nm~100 generally are set as by the thickness of laminated structure for the embodiment of the present invention with one layer or more metal layers 120 μm;The length of horizontal stripe 122 therein is set as 1nm~1000 μm, wherein effect becomes apparent from 10nm, 100nm, 100 μm;It is vertical The length of item is 1nm~1000 μm, wherein effect becomes apparent from 10nm, 100nm, 100 μm;It can either guarantee so adjacent Between metal layer while mutually insulated, and it can reasonably absorb the THz wave for needing to filter out;
Wherein, for the convenience on producing, implementing, the laminated structure 121 for belonging to same layer can be set into identical Size.
Laminated structure 121 in the specific implementation process, can be arranged to the shape of class Roman number by the embodiment of the present invention, Can specifically there are I type, II type or III type.Wherein Absorber Bandwidth of different shapes is also different, can be arranged according to actual needs.
Some basic parameters that several laminated structures 121 are class Roman capitals terahertz filter are given in following table 1, with And different shape, different metal count the relationships with Absorber Bandwidth layer by layer:
Table 1
Embodiment two
This embodiment offers a kind of production process such as the terahertz filter in embodiment one as shown in fig. 7, comprises Following processing step:
Step S701, standby piece, using double throwing silicon wafers as the support substrate piece 1 of flexible structure, by the method for thermal oxide, Substrate surface grows layer of silicon dioxide as insulating medium layer 2, and the thickness of this layer of silica can be 300nm;
Step S702, in silicon chip surface precipitation polymers, the polymer be flexible polymer material (such as Parylene, The flexibilities such as PMMA, PDMS and the excellent polymer material of translucency), with a thickness of 5 μm~200 μm, form the first layers of polymer material Material 111;
Step S703, as the first substrate of filter, photoetching is smeared after routinely cleaning at first layer polymeric material Glue 3 is exposed using the mask plate of the laminated structure figure in such as embodiment one, and the photoresist of developed removal exposure area;
Step S704, first layer polymeric materials splash-proofing sputtering metal after exposure forms the first metal layer 4, and metal can be The resistivity such as copper, aluminium, silver are low, good conductivity metal material, and thickness can be 1nm~100 μm;
Step S705, removal photoresist is removed with acetone, sputters metal on a photoresist together as photoresist is by band It walks, has thus obtained the metal layer 120 such as the laminated structure figure in embodiment one;
Step S706, precipitation polymerization material is packaged device, and thickness can be 5 μm~200 μm, obtains single layer terahertz Hereby filter, the metal layer 120 in the filter are wrapped up by polymeric material layer 110;
By process above step, can obtain filtering such as the single-layer flexible Terahertz of the laminated structure in embodiment one Device.The performance of the embodiment of the present invention is emulated, is obtained too by CST (CST STUDIO SUITE, Electromagnetic Simulation) software The absorbance curves of hertz filter, as shown in figure 3, having reached perfect absorption at 0.92THz, and in 0.8THz to 1THz model 90% or more THz wave absorptivity is reached in enclosing.This characteristic provides foundation for the filtering of realization THz wave band.
The embodiment of the present invention in the specific implementation process, in order to manufacture the terahertz filter comprising more metal layers 120 Can also include:
Step S707, after conventional cleaning silicon chip, photoresist 3 is smeared, second of photoetching process is carried out, using such as embodiment one In laminated structure figure mask plate exposure, remove the photoresist of exposure area;
Step S708, substrate surface sputters second layer metal layer 5, metal can for the resistivity such as copper, aluminium, silver low, electric conductivity Good metal material, with a thickness of 1nm~100 μm;
Step S709, removal photoresist is removed with acetone, the metal sputtered on a photoresist is pulled away, thus obtains Such as the metal layer 120 of the laminated structure figure in embodiment one;
Step S710, precipitation polymerization material (such as Parylene, PMMA, the flexibilities such as PDMS and the excellent polymerization of translucency Object material), with a thickness of 5 μm~200 μm, at this point, can obtain metal layer 120 is double-deck THz wave filter.
It further, can also include: step S711, using double-deck THz wave filter as substrate, inorganic cleaning After silicon wafer, photoresist 3 is smeared, third time photoetching process is carried out, using the mask plate of the laminated structure figure in such as embodiment one Exposure, the photoresist of developed removal exposure area;
Step S712, substrate surface sputters third layer metal layer 6, metal can for the resistivity such as copper, aluminium, silver low, electric conductivity Good metal material, with a thickness of 1nm~100 μm;
Removal photoresist is removed with acetone, the metal layer sputtered on a photoresist is pulled away, and has thus been obtained as implemented The third layer metal structure of laminated structure figure in example one;
Step S713, precipitation polymerization material (such as Parylene, PMMA, the flexibilities such as PDMS and the excellent polymerization of translucency Object material) device is packaged, with a thickness of 1 μm~200 μm;
By above-mentioned processing step, can manufacture if the laminated structure figure in embodiment one is comprising three-layer metal layer 120 Terahertz wide-band filter 100.And so on, as needed, by that can be prepared in this approach as each in embodiment one Kind laminated structure and different layers of terahertz filters.The difference of absorption band can be shown in absorbance curves.
In conclusion the embodiment of the present invention is by being designed to laminated structure for metal layer, and periodic distribution is poly- in flexibility In polymeric material layer made of condensation material, form terahertz filter, can effectively your certain THz wave of filter bag, lead to The distance that the size of laminated structure and each laminated structure is mutual is crossed, may be implemented to resistance band or peak value Adjusting;The embodiment of the present invention can also be arranged to multilayered structure as needed, to realize to a certain range of Terahertz Wave filters out, by adjusting the size of each lamellar structure, the distance between adjacent metal, or even by the piece on different metal layer Shape structure setting may be implemented to filter out different THz wave wave bands, wherein with laminated structure geometry at different sizes The position of the increase of size, absorption peak is mobile to high frequency band;And with the increase of interfloor distance, stop-band frequency is moved to low-frequency band It is dynamic.
The embodiment of the present invention in the specific implementation process, can since the embodiment of the present invention is made of flexible polymeric material It is arranged on the interface for the receiving end that arbitrary shape is attached to Terahertz communication system with basis;By the way of multiple-layer stacked, It is even to be dispersed in flexible polymeric material, it is effectively prevent metal layer deformation fracture, improves reliability.Laminated structure, which uses, includes horizontal stripe The difficulty of preparation is reduced with the structure type of taeniae convenient for production.
Those of ordinary skill in the art will appreciate that: attached drawing is the schematic diagram of one embodiment, module in attached drawing or Process is not necessarily implemented necessary to the present invention.
All the embodiments in this specification are described in a progressive manner, same and similar portion between each embodiment Dividing may refer to each other, and each embodiment focuses on the differences from other embodiments.Especially for device or For system embodiment, since it is substantially similar to the method embodiment, so describing fairly simple, related place is referring to method The part of embodiment illustrates.Apparatus and system embodiment described above is only schematical, wherein the conduct The unit of separate part description may or may not be physically separated, component shown as a unit can be or Person may not be physical unit, it can and it is in one place, or may be distributed over multiple network units.It can root According to actual need that some or all of the modules therein is selected to achieve the purpose of the solution of this embodiment.Ordinary skill Personnel can understand and implement without creative efforts.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, In the technical scope disclosed by the present invention, any changes or substitutions that can be easily thought of by anyone skilled in the art, It should be covered by the protection scope of the present invention.Therefore, protection scope of the present invention should be with scope of protection of the claims Subject to.

Claims (5)

1. a kind of terahertz filter characterized by comprising polymeric material layer and metal layer;The metal layer includes piece Shape structure, the laminated structure include horizontal stripe and taeniae, and the both ends of the taeniae are vertically connected with the horizontal stripe, form II type Or III type structure;The laminated structure periodic distribution is in the polymeric material layer;The metal layer is multilayer, described adjacent The distance between metal layer is 1nm~100nm;The laminated structure size for belonging to same layer is identical;The laminated structure With a thickness of 1nm~100 μm;The length of the horizontal stripe is 1nm~100 μm;The length of the taeniae is 1nm~100 μm;It is described poly- Condensation material layer is flexible polymeric material.
2. terahertz filter according to claim 1, which is characterized in that the flexible polymeric material includes: poly- to two Toluene, polymethyl methacrylate or dimethyl silicone polymer.
3. a kind of production method of the terahertz filter as described in claim 1 to 2 any one characterized by comprising
Using double throwing silicon wafers as support substrate piece, by thermal oxidation process, in the substrate slice Surface Creation layer of silicon dioxide Insulating medium layer;
First layer polymeric material is formed in double silicon chip surface precipitating flexible polymer materials of throwing;
Using the first layer polymeric material as the first substrate, cleaning, and smear photoresist;
The photoetching smeared on the first layer polymeric material is exposed using mask plate corresponding with the figure of the laminated structure Glue, the photoresist of developed removal exposure area;
The first layer polymeric materials splash-proofing sputtering metal after exposure forms the first metal layer;
Removal photoresist is removed with acetone, the metal sputtered on the photoresist is removed together;
First layer polymeric materials precipitating flexible polymeric material after removing photoresist as second layer polymeric material, The first layer polymeric material and the second layer polymeric material form polymeric material layer.
4. the production method of terahertz filter according to claim 3, which is characterized in that the first layer polymeric material With a thickness of 1 μm~200 μm;The first metal layer is with a thickness of 1nm~100 μm.
5. the production method of terahertz filter according to claim 3 or 4, which is characterized in that further include:
Using the second layer polymeric material as the second substrate, cleaning, and smear photoresist;
The photoetching smeared on the second layer polymeric material is exposed using mask plate corresponding with the figure of the laminated structure Glue, the photoresist of developed removal exposure area;;
The second layer polymeric materials splash-proofing sputtering metal after exposure forms second metal layer, with a thickness of 1nm~100 μm;
Removal photoresist is removed with acetone, the metal sputtered on the photoresist is removed together;
Second layer polymeric materials precipitating flexible polymeric material after removing photoresist as third layer polymeric material, The first layer polymeric material, the second layer polymeric material and third layer polymeric material form polymeric material layer;
And so on, until obtaining the terahertz filter with the metal layer for needing quantity.
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