CN105010348B - Composition pesticide containing fluorine azoles ring bacterium amine and fludioxonil and fluorine pyrrole furanone - Google Patents
Composition pesticide containing fluorine azoles ring bacterium amine and fludioxonil and fluorine pyrrole furanone Download PDFInfo
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- CN105010348B CN105010348B CN201510404438.0A CN201510404438A CN105010348B CN 105010348 B CN105010348 B CN 105010348B CN 201510404438 A CN201510404438 A CN 201510404438A CN 105010348 B CN105010348 B CN 105010348B
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Abstract
The invention discloses a kind of composition pesticide containing fluorine azoles ring bacterium amine and fludioxonil and fluorine pyrrole furanone, wherein, weight percent of the fluorine azoles ring bacterium amine in composition pesticide is 0.1%~40%, weight percent of the fludioxonil in composition pesticide is 0.1%~40%, and weight percent of the fluorine pyrrole furanone in composition pesticide is 0.1%~70%；Composition pesticide of the present invention can effectively prevent a variety of pest and disease damages on potato, have many advantages, such as that prevention spectrum is wide, resistance development is compared with slow, synergistic effect is notable low with cost accounting.
Description
Technical field
The present invention relates to composition pesticide and its application fields, specifically with fluorine azoles ring bacterium amine and fludioxonil and fluorine
Pyrrole furanone is the composition pesticide of active ingredient, is applied to the prevention of pest and disease damage on potato.
Background technology
Fluorine azoles ring bacterium amine (Sedaxane)：Main to inhibit mitochondria, to the significant effect of rhizoctonia, the lasting period is long, to it
It plants the prevention for passing and also having wide spectrum with soil-borne disease.
Fludioxonil (Fludioxonil)：For non-interior suction benzene pyroles contact killing type fungicide, pass through inhibition glucose phosphorylated
Related transfer, and inhibit the growth of fungal mycelium, germ death is eventually led to, the mechanism of action is unique, with existing fungicide
No interactions resistance.High-efficiency broad spectrum passes caused by many pathogens such as sac fungus, basidiomycetes, Fungi Imperfecti kinds and soil-borne disease has
Extraordinary preventive effect.
Fluorine pyrrole furanone (Flupyradifurone)：It is novel nicotinamide insecticide, acts on the central nervous system of insect
System, is the antagonist of insect nAChR.It is mainly effective to sucking pest, it is harmless to honeybee, not
By blooming, application is limited, to crop safety.
For being agriculturally also easy to produce the prevention and control of plant diseases, pest control of drug resistance, the pesticide different using the mechanism of action, prevention spectrum is different
It is a kind of best selection that kind, which carries out mixture,.If proportioning is reasonable, significant synergistic effect can be generated, field control is made
Significant effect is better than the effect of each single dose, expands prevention spectrum.The disease of big Tanaka and insect pest often mix generation, on potato
The pest and disease damages such as aphid, tar spot mix generation throughout the year, peasant needs while buying insecticide and fungicide, and the edge of a field mixes temporarily
It closes, arbitrariness is also big, is frequently not Use out of range, causes to waste, increases environmental pollution, is exactly dosage deficiency, influences to prevent matter
Amount.And part fungicide and insecticide are not appropriate for mixture and are used together due to chemical reaction etc., mixture is improper also easy
The problems such as causing control effect to decline.
Invention content
It is a kind of containing fluorine azoles ring bacterium amine and fludioxonil and fluorine the purpose of the present invention is in view of the above problems, providing
The composition pesticide of pyrrole furanone, for preventing a variety of pest and disease damages such as aphid on potato, grub, late blight and tar spot, one
Secondary medication can be controlled so that parasitosis is simultaneous, simplify farming, saved medicine cost, reduced environmental pollution, and prevention quality is improved.
Technical scheme of the present invention：A kind of pesticide combination containing fluorine azoles ring bacterium amine and fludioxonil and fluorine pyrrole furanone
Object, active ingredient are fluorine azoles ring bacterium amine, fludioxonil, fluorine pyrrole furanone, weight percent of the fluorine azoles ring bacterium amine in composition pesticide
Than being 0.1%~40%, weight percent of the fludioxonil in composition pesticide is 0.1%~40%, and fluorine pyrrole furanone is in agriculture
Weight percent in drug composition is herbal medicine 0.1%~70%.
Composition pesticide of the present invention is including emulsifier, dispersant, antifreeze also containing the auxiliary element needed for pesticidal preparations
Agent, preservative, film forming agent, antifoaming agent, colorant etc. are all to commonly use in pesticidal preparations or allow the ingredient used, have no especially
Restriction, specific ingredient and dosage are according to recipe requirements by simply testing determination.
The composition pesticide of the present invention can be processed into suspension seed-coating agent according to well known to a person skilled in the art methods.
The production technology of the composition pesticide application forms belongs to existing known technology, and details are not described herein.
Composition pesticide of the present invention is suitable for prevention potato disease insect pest aphid, grub, late blight, tar spot.
Composition pesticide described in the invention can be provided in the form of finished product preparation, i.e., each substance has mixed in composition
Close, the ingredient of composition can also unit dose form provide, directly mixed in bucket or tank using preceding, be then diluted to needed for it is dense
Degree.
Composition pesticide provided by the invention, generally use dressing methods use, and can also use and agriculturally answer as needed
Other use technology.
Compared with the prior art, the advantages of the present invention are as follows：
1, fluorine azoles ring bacterium amine, fludioxonil and fluorine pyrrole furanone ternary built have significant synergistic function, compared with list
Agent or binary built expand prevention spectrum using the control effect significantly improved to pest and disease damage, accomplished a medicine control more,
And pest and disease damage is planted by Zhiduo County.
2, fluorine azoles ring bacterium amine, fludioxonil and fluorine pyrrole furanone ternary built, reduce Pesticide use amount, reduce use at
Originally the pollution to environment, is alleviated, delayed the generation of pest and disease damage drug resistance, extended the service life of pesticide.
Specific implementation mode
To better understand the essence of the present invention, present disclosure is described further with reference to embodiment,
But limitation of the present invention cannot be considered as, it is as described below to be only used for explaining the present invention, for without departing from spirit of that invention and principle
Modification, replacement or the improvement made, belong to the scope of protection of present invention.
Embodiment one
Following substance is weight percentage：Fluorine azoles ring bacterium amine 2%, fludioxonil 1%, fluorine pyrrole furanone 10%, agriculture breast 500
Number 10%, lignin sodium iodate 1.5%, sodium benzoate 1.5%, polyvinyl acetate 0.5%, silicone oil 1%, glycerine 1.5%,
Rosa Damascana 0.5%, adds water to complement to 100%.Each component is pre-mixed, adds in sand mill and grinds, is cut through height
Film forming agent and colorant allotment is added after cutting mixing, you can 13% fluorine azoles ring bacterium amine fludioxonil fluorine pyrrole furanone is made and suspends
Seed coat agent.
The embodiment is used to prevent aphid, grub, late blight and the tar spot on potato：13% fluorine azoles ring bacterium amine is coughed up
Bacterium nitrile fluorine pyrrole furanone suspension seed-coating agent presses 130g a.i./100kg seed Dressings, and after planting 40d is on potato
Aphid, grub, late blight and tar spot preventive effect be respectively 86.42%, 83.17%, 84.58%, 85.95%；30% fluorine azoles
20% fludioxonil suspension seed-coating agent of ring bacterium amine presses 40g a.i./100kg seed Dressings, and after planting 40d is on potato
Aphid, grub, late blight and tar spot preventive effect be respectively 0.84%, 0.92%, 51.37%, 57.89%；44% fluorine azoles ring
Bacterium amine suspension seed-coating agent presses 30g a.i./100kg seed Dressings, and after planting 40d is to the aphid on potato, grub, evening
The preventive effect of epidemic disease and tar spot is respectively 0.37%, 0.75%, 39.74%, 54.53%；25 grams per liter fludioxonil suspension seed-coating agents
By 20g a.i./100kg seed Dressings, after planting 40d is to the aphid on potato, grub, late blight and tar spot
Preventive effect is respectively 0.58%, 0.62%, 48.65%, 52.58%；50% fluorine pyrrole furanone suspension seed-coating agent by 150g a.i./
100kg seed Dressings, after planting 40d on potato aphid, grub, late blight and tar spot preventive effect be respectively
66.78%, 58.93%, 0.56%, 0.78%.As it can be seen that increasing after fluorine azoles ring bacterium amine, fludioxonil and fluorine pyrrole furanone ternary built
Effect effect is notable, and the lasting period is long, expands prevention spectrum, to pest and disease damages such as aphid, grub, late blight and tar spots on potato
Preventive effect be significantly better than single dose or binary built, the amount ratio single dose of active ingredient or binary built use in ternary built medicament
When significantly reduce, to alleviate carrying capacity of environment, reduce use cost, meanwhile, do not find ternary built during the test
Medicament germinates to seed potato and plant strain growth generates poisoning.
Embodiment two
Following substance is weight percentage：Fluorine azoles ring bacterium amine 3%, fludioxonil 1%, fluorine pyrrole furanone 30%, agriculture breast 400
Number 10%, lauryl sodium sulfate 1.5%, sodium benzoate 1.5%, polyvinyl acetate 0.5%, silicone oil 1%, glycerine
1.5%, rose-red 0.5% adds water to complement to 100%.Each component is pre-mixed, adds in sand mill and grinds, is passed through
Film forming agent and colorant allotment are added after high shear mixing, you can 34% fluorine azoles ring bacterium amine fludioxonil fluorine pyrrole furanone is made
Suspension seed-coating agent.
The embodiment is used to prevent aphid, grub, late blight and the tar spot on potato：34% fluorine azoles ring bacterium amine is coughed up
Bacterium nitrile fluorine pyrrole furanone suspension seed-coating agent presses 130g a.i./100kg seed Dressings, and after planting 40d is on potato
Aphid, grub, late blight and tar spot preventive effect be respectively 84.78%, 83.66%, 85.53%, 82.47%；30% fluorine azoles
20% fludioxonil suspension seed-coating agent of ring bacterium amine presses 40g a.i./100kg seed Dressings, and after planting 40d is on potato
Aphid, grub, late blight and tar spot preventive effect be respectively 0.93%, 0.77%, 50.75%, 58.17%；44% fluorine azoles ring
Bacterium amine suspension seed-coating agent presses 30g a.i./100kg seed Dressings, and after planting 40d is to the aphid on potato, grub, evening
The preventive effect of epidemic disease and tar spot is respectively 0.64%, 0.48%, 40.76%, 52.69%；25 grams per liter fludioxonil suspension seed-coating agents
By 20g a.i./100kg seed Dressings, after planting 40d is to the aphid on potato, grub, late blight and tar spot
Preventive effect is respectively 0.59%, 0.38%, 47.82%, 54.67%；50% fluorine pyrrole furanone suspension seed-coating agent by 150g a.i./
100kg seed Dressings, after planting 40d on potato aphid, grub, late blight and tar spot preventive effect be respectively
63.31%, 52.05%, 0.46%, 0.82%.As it can be seen that increasing after fluorine azoles ring bacterium amine, fludioxonil and fluorine pyrrole furanone ternary built
Effect effect is notable, and the lasting period is long, expands prevention spectrum, to pest and disease damages such as aphid, grub, late blight and tar spots on potato
Preventive effect be significantly better than single dose or binary built, the amount ratio single dose of active ingredient or binary built use in ternary built medicament
When significantly reduce, to alleviate carrying capacity of environment, reduce use cost, meanwhile, do not find ternary built during the test
Medicament germinates to seed potato and plant strain growth generates poisoning.
Embodiment three
Following substance is weight percentage：Fluorine azoles ring bacterium amine 1%, fludioxonil 1%, fluorine pyrrole furanone 20%, agriculture breast 400
Number 10%, aryl alkyl polyoxyethylene ether 1.5%, sodium benzoate 1.5%, polyvinyl alcohol 0.5%, silicone oil 1%, glycerine
1.5%, rose-red 0.5% adds water to complement to 100%.Each component is pre-mixed, adds in sand mill and grinds, is passed through
Film forming agent and colorant allotment are added after high shear mixing, you can 22% fluorine azoles ring bacterium amine fludioxonil fluorine pyrrole furanone is made
Suspension seed-coating agent.
The embodiment is used to prevent aphid, grub, late blight and the tar spot on potato：22% fluorine azoles ring bacterium amine is coughed up
Bacterium nitrile fluorine pyrrole furanone suspension seed-coating agent presses 130g a.i./100kg seed Dressings, and after planting 40d is on potato
Aphid, grub, late blight and tar spot preventive effect be respectively 81.32%, 80.25%, 81.64%, 83.06%；30% fluorine azoles
20% fludioxonil suspension seed-coating agent of ring bacterium amine presses 40g a.i./100kg seed Dressings, and after planting 40d is on potato
Aphid, grub, late blight and tar spot preventive effect be respectively 1.13%, 0.65%, 50.97%, 59.13%；44% fluorine azoles ring
Bacterium amine suspension seed-coating agent presses 30g a.i./100kg seed Dressings, and after planting 40d is to the aphid on potato, grub, evening
The preventive effect of epidemic disease and tar spot is respectively 0.29%, 0.47%, 43.21%, 55.64%；25 grams per liter fludioxonil suspension seed-coating agents
By 20g a.i./100kg seed Dressings, after planting 40d is to the aphid on potato, grub, late blight and tar spot
Preventive effect is respectively 0.83%, 0.36%, 47.53%, 53.66%；50% fluorine pyrrole furanone suspension seed-coating agent by 150g a.i./
100kg seed Dressings, after planting 40d on potato aphid, grub, late blight and tar spot preventive effect be respectively
65.52%, 56.78%, 0.49%, 0.71%.As it can be seen that increasing after fluorine azoles ring bacterium amine, fludioxonil and fluorine pyrrole furanone ternary built
Effect effect is notable, and the lasting period is long, expands prevention spectrum, to pest and disease damages such as aphid, grub, late blight and tar spots on potato
Preventive effect be significantly better than single dose or binary built, the amount ratio single dose of active ingredient or binary built use in ternary built medicament
When significantly reduce, to alleviate carrying capacity of environment, reduce use cost, meanwhile, do not find ternary built during the test
Medicament germinates to seed potato and plant strain growth generates poisoning.
Example IV
Following substance is weight percentage：Fluorine azoles ring bacterium amine 1%, fludioxonil 1%, fluorine pyrrole furanone 10%, agriculture breast 602
Number 10%, polycarboxylate 1.5%, benzyl alcohol 1.5%, polyvinyl alcohol 0.5%, silicone oil 1%, glycerine 1.5%, aqueous rose-red
0.5%, add water to complement to 100%.Each component is pre-mixed, adds in sand mill and grinds, after high shear mixing
Film forming agent and colorant allotment is added, you can 12% fluorine azoles ring bacterium amine fludioxonil fluorine pyrrole furanone suspension seed-coating agent is made.
The embodiment is used to prevent aphid, grub, late blight and the tar spot on potato：12% fluorine azoles ring bacterium amine is coughed up
Bacterium nitrile fluorine pyrrole furanone suspension seed-coating agent presses 130g a.i./100kg seed Dressings, and after planting 40d is on potato
Aphid, grub, late blight and tar spot preventive effect be respectively 83.86%, 81.14%, 80.96%, 82.33%；30% fluorine azoles
20% fludioxonil suspension seed-coating agent of ring bacterium amine presses 40g a.i./100kg seed Dressings, and after planting 40d is on potato
Aphid, grub, late blight and tar spot preventive effect be respectively 0.98%, 0.71%, 48.89%, 55.67%；44% fluorine azoles ring
Bacterium amine suspension seed-coating agent presses 30g a.i./100kg seed Dressings, and after planting 40d is to the aphid on potato, grub, evening
The preventive effect of epidemic disease and tar spot is respectively 0.52%, 0.49%, 41.38%, 50.25%；25 grams per liter fludioxonil suspension seed-coating agents
By 20g a.i./100kg seed Dressings, after planting 40d is to the aphid on potato, grub, late blight and tar spot
Preventive effect is respectively 0.65%, 0.58%, 46.61%, 53.48%；50% fluorine pyrrole furanone suspension seed-coating agent by 150g a.i./
100kg seed Dressings, after planting 40d on potato aphid, grub, late blight and tar spot preventive effect be respectively
67.64%, 58.32%, 0.39%, 0.42%.As it can be seen that increasing after fluorine azoles ring bacterium amine, fludioxonil and fluorine pyrrole furanone ternary built
Effect effect is notable, and the lasting period is long, expands prevention spectrum, to pest and disease damages such as aphid, grub, late blight and tar spots on potato
Preventive effect be significantly better than single dose or binary built, the amount ratio single dose of active ingredient or binary built use in ternary built medicament
When significantly reduce, to alleviate carrying capacity of environment, reduce use cost, meanwhile, do not find ternary built during the test
Medicament germinates to seed potato and plant strain growth generates poisoning.
Embodiment five
In order to further appreciate that fluorine azoles ring bacterium amine, fludioxonil and fluorine pyrrole furanone are the synergy class of active ingredient compounding
Type, the present inventor are that active ingredient compounding has carried out a large amount of indoor virulence to fluorine azoles ring bacterium amine, fludioxonil and fluorine pyrrole furanone
Measure experiment.
1, the Toxicity Determination of fluorine azoles ring bacterium amine, fludioxonil and fluorine pyrrole furanone compounding to Potato Aphid
It is for statistical analysis with DPS statistical analysis softwares, calculate the LC of each medicament50, and calculate the co-toxicity coefficient of mixture
(CTC)：Co-toxicity coefficient (CTC) >=120 shows as synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as antagonism；80 ＜ are total
Malicious coefficient (CTC) ＜ 120 shows as summation action.
Table 1, the The Toxicity Determination result to Potato Aphid
| Medicament | LC50 | ATI | TTI | CTC |
| Fluorine azoles ring bacterium amine (A) | 2569.82 | 100.00 | - | - |
| Fludioxonil (B) | 2177.97 | 117.99 | - | - |
| Fluorine pyrrole furanone (C) | 1.26 | 203953.97 | - | - |
| A:B:C(3:1:30) | 0.72 | 356919.44 | 179971.68 | 198.32 |
| A:B:C(3:1:20) | 0.93 | 276324.73 | 169979.06 | 162.56 |
| A:B:C(3:1:10) | 1.02 | 251943.14 | 145711.26 | 172.91 |
| A:B:C(2:1:30) | 0.94 | 273385.11 | 185422.33 | 147.44 |
| A:B:C(2:1:20) | 0.85 | 302331.76 | 177365.10 | 170.46 |
| A:B:C(2:1:10) | 0.79 | 325293.67 | 156912.13 | 207.31 |
| A:B:C(1:1:30) | 0.83 | 309616.87 | 191213.66 | 161.92 |
| A:B:C(1:1:20) | 0.77 | 333742.86 | 185422.61 | 179.99 |
| A:B:C(1:1:10) | 0.91 | 282397.80 | 169979.81 | 166.14 |
As it can be seen from table 1 when fluorine azoles ring bacterium amine, fludioxonil and fluorine pyrrole furanone compound in the range of certain proportion,
Co-toxicity coefficient (CTC) is all higher than 120, and synergistic function is shown to Potato Aphid；Especially with 2:1:10 (pressing quality)
Compounding, synergistic function is the most notable, and co-toxicity coefficient (CTC) is 207.31.As it can be seen that fluorine azoles ring bacterium amine, fludioxonil and fluorine pyrrole
Furanone compounding has reasonability and feasibility.
2, the Toxicity Determination of fluorine azoles ring bacterium amine, fludioxonil and fluorine pyrrole furanone compounding to black scurf of potato
It is for statistical analysis with DPS statistical analysis softwares, calculate the EC of each medicament50, and calculate the increasing of mixture interaction
Valid value (SR)：Synergism value (SR) ＜ 0.5, is antagonism；Synergism value (SR)=0.5~1.5, is addition；Synergism value
(SR) 1.5 ＞ are synergistic effects.
Table 2, the The Toxicity Determination result to black scurf of potato
| Medicament | EC50(ob) | EC50(th) | SR |
| Fluorine azoles ring bacterium amine (A) | 5.28 | - | - |
| Fludioxonil (B) | 7.96 | - | - |
| Fluorine pyrrole furanone (C) | 803.95 | - | - |
| A:B:C(3:1:30) | 17.42 | 46.50 | 2.67 |
| A:B:C(3:1:20) | 14.28 | 33.39 | 2.34 |
| A:B:C(3:1:10) | 11.67 | 19.82 | 1.70 |
| A:B:C(2:1:30) | 19.39 | 60.92 | 3.14 |
| A:B:C(2:1:20) | 23.94 | 43.45 | 1.82 |
| A:B:C(2:1:10) | 7.68 | 25.15 | 3.28 |
| A:B:C(1:1:30) | 38.46 | 90.82 | 2.36 |
| A:B:C(1:1:20) | 35.97 | 64.73 | 1.80 |
| A:B:C(1:1:10) | 16.79 | 36.65 | 2.18 |
From table 2 it can be seen that when fluorine azoles ring bacterium amine, fludioxonil and fluorine pyrrole furanone compound in the range of certain proportion,
Synergism value (SR) is all higher than 1.5, and synergistic function is shown to black scurf of potato；Especially with 2:1:10 (pressing quality) are multiple
Match, synergistic function is the most notable, and synergism value (SR) is 3.28.As it can be seen that fluorine azoles ring bacterium amine, fludioxonil and fluorine pyrrole furanone are multiple
With with reasonability and feasibility.
In conclusion the present invention uses the ternary that fluorine azoles ring bacterium amine, fludioxonil and fluorine pyrrole furanone compound for active ingredient
Compound, obvious synergy, a drug can parasitosis be simultaneous controls, and prevention spectrum is expanded, with existing single dose or binary
Complex preparation is compared, and prevents pest and disease damage raising with obvious effects, and the lasting period is long, to crop safety, is worth above pushing away in agricultural production
Wide application.
Claims (5)
1. a kind of composition pesticide containing fluorine azoles ring bacterium amine and fludioxonil and fluorine pyrrole furanone, it is characterised in that：Effectively at
Be divided into fluorine azoles ring bacterium amine, fludioxonil, fluorine pyrrole furanone, fluorine azoles ring bacterium amine, fludioxonil, fluorine pyrrole furanone weight ratio be 1-3:1:
10-30。
2. a kind of pesticide combination containing fluorine azoles ring bacterium amine and fludioxonil and fluorine pyrrole furanone according to claim 1
Object, it is characterised in that：Weight percent of the fluorine azoles ring bacterium amine in composition pesticide is 0.1%~40%, and fludioxonil is in pesticide
Weight percent in composition is 0.1%~40%, and weight percent of the fluorine pyrrole furanone in composition pesticide is 0.1%
~70%.
3. a kind of pesticide combination containing fluorine azoles ring bacterium amine and fludioxonil and fluorine pyrrole furanone according to claim 1
Object, it is characterised in that：The dosage form of the composition pesticide is suspension seed-coating agent.
4. a kind of composition pesticide containing fluorine azoles ring bacterium amine and fludioxonil and fluorine pyrrole furanone described in claim 1 is anti-
Control the application in potato disease insect pest.
5. a kind of composition pesticide containing fluorine azoles ring bacterium amine and fludioxonil and fluorine pyrrole furanone according to claim 4
Application in preventing potato disease insect pest, it is characterised in that：The potato disease insect pest is aphid, grub, late blight, black
Mole disease.
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| CN107771811B (en) * | 2017-08-24 | 2020-10-09 | 广东和利农种业股份有限公司 | Bitter gourd seed treating agent and method for treating bitter gourd seeds by using same |
| CN107467030A (en) * | 2017-08-30 | 2017-12-15 | 佛山市盈辉作物科学有限公司 | Seed treatment compositions containing fludioxonil, Metalaxyl-M and fluorine pyrrole furanone |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007045953A1 (en) * | 2007-09-26 | 2009-04-02 | Bayer Cropscience Ag | Active substance combination, useful for combating animal pest, treating seed, transgenic plant and seeds of transgenic plant, comprises a 5H-furan-2-one compound and other active agent comprising e.g. acrinathrin and alpha-cypermethrin |
| CN101466705A (en) * | 2006-03-31 | 2009-06-24 | 拜尔农作物科学股份公司 | Substituted enaminocarbonyl compounds |
| CN102365018A (en) * | 2009-03-25 | 2012-02-29 | 拜尔农作物科学股份公司 | Synergistic combinations of active ingredients |
| CN104719304A (en) * | 2013-12-20 | 2015-06-24 | 陕西美邦农药有限公司 | Sedaxane-containing bactericidal composition |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101466705A (en) * | 2006-03-31 | 2009-06-24 | 拜尔农作物科学股份公司 | Substituted enaminocarbonyl compounds |
| DE102007045953A1 (en) * | 2007-09-26 | 2009-04-02 | Bayer Cropscience Ag | Active substance combination, useful for combating animal pest, treating seed, transgenic plant and seeds of transgenic plant, comprises a 5H-furan-2-one compound and other active agent comprising e.g. acrinathrin and alpha-cypermethrin |
| CN102365018A (en) * | 2009-03-25 | 2012-02-29 | 拜尔农作物科学股份公司 | Synergistic combinations of active ingredients |
| CN104719304A (en) * | 2013-12-20 | 2015-06-24 | 陕西美邦农药有限公司 | Sedaxane-containing bactericidal composition |
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