CN104995167B - 用于由合成气和二甲醚生产乙酸甲酯和甲醇的集成方法 - Google Patents

用于由合成气和二甲醚生产乙酸甲酯和甲醇的集成方法 Download PDF

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CN104995167B
CN104995167B CN201380073629.2A CN201380073629A CN104995167B CN 104995167 B CN104995167 B CN 104995167B CN 201380073629 A CN201380073629 A CN 201380073629A CN 104995167 B CN104995167 B CN 104995167B
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methanol
synthesis gas
carbonylation
product
synthesis
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Chinese (zh)
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CN104995167A (zh
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E.J.贝克
T.C.布里斯托夫
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Ineos Acetyls UK Ltd
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BP Chemicals Ltd
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/37—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by reaction of ethers with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1516—Multisteps
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1516—Multisteps
    • C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/04—Methanol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/12—Acetic acid esters
    • C07C69/14—Acetic acid esters of monohydroxylic compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201380073629.2A 2012-12-21 2013-12-19 用于由合成气和二甲醚生产乙酸甲酯和甲醇的集成方法 Active CN104995167B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12199092.3 2012-12-21
EP12199092 2012-12-21
PCT/EP2013/077473 WO2014096246A1 (en) 2012-12-21 2013-12-19 Integrated process for the production of methyl acetate and methanol from synthesis gas and dimethylether

Publications (2)

Publication Number Publication Date
CN104995167A CN104995167A (zh) 2015-10-21
CN104995167B true CN104995167B (zh) 2017-05-17

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CN201380073629.2A Active CN104995167B (zh) 2012-12-21 2013-12-19 用于由合成气和二甲醚生产乙酸甲酯和甲醇的集成方法

Country Status (12)

Country Link
US (1) US9505702B2 (enExample)
EP (1) EP2935195A1 (enExample)
JP (1) JP6161725B2 (enExample)
KR (1) KR20150099811A (enExample)
CN (1) CN104995167B (enExample)
BR (1) BR112015014994A2 (enExample)
CA (1) CA2894283A1 (enExample)
RU (1) RU2687234C2 (enExample)
SG (1) SG11201504646XA (enExample)
TW (1) TW201429941A (enExample)
UA (1) UA115579C2 (enExample)
WO (1) WO2014096246A1 (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10695756B2 (en) 2015-06-12 2020-06-30 Enerkem, Inc. Metal-loaded zeolite catalysts for the halogen-free conversion of dimethyl ether to methyl acetate
WO2018004992A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Conversion of methane to dimethyl ether
WO2018004994A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Fluidized bed membrane reactor
WO2018004993A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Reduction of greenhouse gas emission
GB201705882D0 (en) * 2017-04-12 2017-05-24 Bp Chem Int Ltd Process
CN111514940A (zh) * 2019-02-02 2020-08-11 中国科学院大连化学物理研究所 一种一步法制备丙酮的催化剂、其制备方法及其应用
CN111517948B (zh) * 2019-02-02 2021-07-27 中国科学院大连化学物理研究所 一种生产乙酸甲酯联产丙酮的方法
CN111517929A (zh) * 2019-02-02 2020-08-11 中国科学院大连化学物理研究所 生产丙酮的方法
CN115557829B (zh) * 2021-07-01 2024-08-13 高化学株式会社 一种由合成气联产甲醇与乙醇的方法
CN115845914B (zh) * 2022-11-21 2024-07-30 金宏气体股份有限公司 二氧化碳加氢制备甲醇的催化剂及其应用
CN118253262B (zh) * 2024-05-28 2024-07-30 安徽碳鑫科技有限公司 一种二甲醚羰基化制备乙酸甲酯的反应装置

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1306863A (en) * 1969-08-14 1973-02-14 Ajinomoto Kk Production of acetic acid
EP0566370A2 (en) * 1992-04-15 1993-10-20 Air Products And Chemicals, Inc. Integrated process for synthesizing oxygenated acetyl compounds from synthesis gas via dimethyl ether
CN101203479A (zh) * 2005-05-05 2008-06-18 加利福尼亚大学董事会 烷基醚羰基化方法
CN101687185A (zh) * 2007-04-26 2010-03-31 英国石油化学品有限公司 甲醚羰基化方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5502243A (en) * 1992-04-15 1996-03-26 Air Products And Chemicals, Inc. Hydrocarbonylation of dimethyl ether
DK40796A (da) * 1996-04-10 1997-10-11 Haldor Topsoe As Fremgangsmåde til fremstilling af eddikesyre
WO2001007393A1 (en) * 1999-07-23 2001-02-01 Union Carbide Chemicals & Plastics Processes for preparing oxygenates
CN1310826C (zh) * 2002-05-20 2007-04-18 埃塞泰克斯（塞浦路斯）有限公司 制造乙酸和甲醇的一体化方法
EP1985608A1 (en) * 2007-04-26 2008-10-29 BP Chemicals Limited Process for the carbonylation of dimethyl ether
EP2199272A1 (en) * 2008-11-27 2010-06-23 BP Chemicals Limited Carbonylation process

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1306863A (en) * 1969-08-14 1973-02-14 Ajinomoto Kk Production of acetic acid
EP0566370A2 (en) * 1992-04-15 1993-10-20 Air Products And Chemicals, Inc. Integrated process for synthesizing oxygenated acetyl compounds from synthesis gas via dimethyl ether
CN101203479A (zh) * 2005-05-05 2008-06-18 加利福尼亚大学董事会 烷基醚羰基化方法
CN101687185A (zh) * 2007-04-26 2010-03-31 英国石油化学品有限公司 甲醚羰基化方法

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Publication number Publication date
CA2894283A1 (en) 2014-06-26
BR112015014994A2 (pt) 2017-07-11
WO2014096246A1 (en) 2014-06-26
US20150329465A1 (en) 2015-11-19
EP2935195A1 (en) 2015-10-28
JP2016500378A (ja) 2016-01-12
JP6161725B2 (ja) 2017-07-12
US9505702B2 (en) 2016-11-29
RU2687234C2 (ru) 2019-05-08
UA115579C2 (uk) 2017-11-27
SG11201504646XA (en) 2015-07-30
CN104995167A (zh) 2015-10-21
TW201429941A (zh) 2014-08-01
KR20150099811A (ko) 2015-09-01
RU2015129643A (ru) 2017-01-30

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Effective date of registration: 20210915

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Patentee after: Ineos acetyl UK Ltd.

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Patentee before: BP Chemicals Ltd.