CN104994834B - The sun-proof cosmetic preparation of aerosol type - Google Patents
The sun-proof cosmetic preparation of aerosol type Download PDFInfo
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- CN104994834B CN104994834B CN201480009099.XA CN201480009099A CN104994834B CN 104994834 B CN104994834 B CN 104994834B CN 201480009099 A CN201480009099 A CN 201480009099A CN 104994834 B CN104994834 B CN 104994834B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/4966—Triazines or their condensed derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/26—Optical properties
- A61K2800/262—Transparent; Translucent
Abstract
The problem of the present invention is to provide a kind of aerosol type suncream not tacky, the transparency is high, the aerosol type suncream is by the way that stably mixture has the ultra-violet absorber of the slightly solubility of high ultraviolet protection ability under conditions of being coexisted with liquid gas, so as to which ultraviolet protection effect is high, skin and hair can be equably sprayed to.There is provided a kind of aerosol type sun-proof cosmetic preparation, it is characterised in that it is the aerosol containing the stoste as water-in-oil emulsion and the liquid gas as propellant, and the water-in-oil emulsion contains following composition (a)~(c)：(a) the mass % of the mass % of Tinosorb S 1~3；(b) the mass % of the mass % of diester 5 that the aliphatic acid that propane diols and carbon number are 8~10 is formed~50；(c) the mass % of the mass % of ethylhexyl methoxy cinnamate 5~15, composition (a) and composition (b) and (c) mass ratio in above-mentioned water-in-oil emulsion are 1:10~1:20 scope.
Description
Technical field
The present invention relates to a kind of sun-proof cosmetic preparation of aerosol type, and it will contain double ethylhexyloxyphenol methoxyphenyls three
Piperazine and the water-in-oil emulsion of specific ester oil agent have used liquid gas as propellant as stoste；In more detail
Say, the present invention relates to a kind of sun-proof cosmetic preparation of aerosol type, its excellent in stability, thus in the absence of blocking, can equably spray
Mist has transparent and not tacky to skin and hair.
Background technology
The purpose of sun-proof cosmetic preparation in the ultraviolet in sunray is shielded, prevent skin by it is UV-induced not
Good influence, is developing a kind of sun-proof cosmetic preparation, and it passes through the metal oxides such as mixture zinc oxide, titanium dioxide and organic ultraviolet
Light absorbers, thus with high ultraviolet protection effect.But there can be following problems during a large amount of mixture metal oxides：
The astringent sense of powder is produced during use, the property completed is turned white, be unnatural；Etc., moreover, having with high ultraviolet protection effect
Machine ultra-violet absorber is mostly slightly solubility (being insoluble in water, be also insoluble in non-polar oil), right sometimes the problem of generation stability
This has carried out various researchs.(for example, with reference to patent document 1,2)
On the other hand, aerosol type cosmetic preparation is easy to be applied to the relative broad range of skin and hair, particularly for spraying
In the case of, will not get finger wet because of cosmetic preparation, but also can even spread to hand be difficult to the part that gets at, therefore use
Property is very good.So it can also carry out applying as sun-proof cosmetic preparation (for example, with reference to patent document 3,4).
Prior art literature
Patent document
Patent document 1：Japanese Unexamined Patent Publication 2010-100553 publications
Patent document 2：Japanese Unexamined Patent Publication 2011-236201 publications
Patent document 3：Japanese Unexamined Patent Application Publication 2008-543939 publications
Patent document 4：Japanese Unexamined Patent Publication 2010-270060 publications
The content of the invention
The invention problem to be solved
Aerosol type cosmetic preparation is that the warp coexisted with the liquid gas as propellant or compressed gas adds due to its environment
The particular surroundings of pressure, therefore, there is the ultra-violet absorber of the powders such as the metal oxide of ultraviolet protection effect or slightly solubility
Aggregation and crystallization can be caused in aerosol container, as a result, ultraviolet protection effect reduces, particularly in the situation for spraying
Under, there can be the problem of producing blocking, ejection is deteriorated, unevenly sprayed.In addition, during using liquid gas, can be formed
More tiny spraying granule.Therefore, it is sun-proof to be to provide a kind of aerosol type not tacky, that the transparency is high to problem of the invention
Frost, the aerosol type suncream is by the way that stably mixture has high ultraviolet protection ability under conditions of being coexisted with liquid gas
Slightly solubility ultra-violet absorber, thus ultraviolet protection effect is high, can equably be sprayed to skin and hair.
For solving the scheme of problem
In view of the actual conditions, present inventor has performed further investigation, as a result finds：Contained by combining mixture and be used as
The water-in-oil emulsion of the Tinosorb S of slightly solubility ultra-violet absorber and specific ester oil
With liquid gas, so as to which ultraviolet protection effect is high, skin and hair can be equably sprayed to, is completed without tacky, transparent
The high aerosol type suncream of property.
That is, the present invention provides following technical scheme.
[1] the sun-proof cosmetic preparation of a kind of aerosol type, it is characterised in that it is to contain the stoste as water-in-oil emulsion
With the aerosol of the liquid gas as propellant, the water-in-oil emulsion contains following composition (a)~(c)：
(a) the mass % of the mass % of Tinosorb S 1~3；
(b) the mass % of the mass % of diester 5 that the aliphatic acid that propane diols and carbon number are 8~10 is formed~50；
(c) the mass % of the mass % of ethylhexyl methoxy cinnamate 5~15,
Composition (a) and composition (b) and (c) mass ratio in above-mentioned water-in-oil emulsion are 1:10~1:20 model
Enclose.
[2] the sun-proof cosmetic preparation of aerosol type as described in [1], it is characterised in that enter one in above-mentioned water-in-oil emulsion
Step contains composition (d) silicone oil.
[3] the sun-proof cosmetic preparation of aerosol type as described in [1] or [2], wherein, the oil bag in the sun-proof cosmetic preparation of aerosol type
The filling proportion of water type emulsion and liquid gas is the mass % of the mass % of water-in-oil emulsion 15~40 and liquid gas 60
The mass % of quality %~85%.
The effect of invention
The aerosol type suncream of the present invention is capable of the ultra-violet absorber of stably mixture slightly solubility, therefore with following
Advantage：Ultraviolet protection effect is high, also without it is tacky and after the completion of it is transparent, prolonged ejection is good, can equably spray
It is excellent to skin and hair, usability.
Embodiment
Below, the composition of the present invention is described in detail.It should be noted that with " X~Y " represents number in this specification
When being worth scope, its scope includes the value X and Y at both ends.
The sun-proof cosmetic preparation of aerosol type of the present invention is using as the stoste of water-in-oil emulsion and as propellant
Liquid gas fills what is formed into the container with resistance to pressure valve, and the water-in-oil emulsion contains composition (a)~(c).As
Aerosol, can be adjusted to spray (vaporific) according to application target, the form such as foam (blister), directly used after can spraying or
Person is sprawled and used with hand.In the present invention, from the aspect of it can equably be sprayed to skin and hair, the shape preferably sprayed
State.Therefore, the filling proportion of the water-in-oil emulsion in aerosol and liquid gas is preferably the matter of water-in-oil emulsion 15
Measure the mass % (hereinafter abbreviated as " % ") of %~40, more preferably liquid gas 60%~85%, water-in-oil emulsion 20%
~30%, liquid gas 70%~80% (water-in-oil emulsion and the total of liquid gas are set to 100%).This be because
For：If the scope, then separated out over time by also unconfirmed to crystallization, stability when aerosol type sun-proof cosmetic preparation is made
It is excellent, can equably spray.
(water-in-oil emulsion：Stoste)
The composition (a) used in the present invention is the ultra-violet absorber for being both insoluble in water or being insoluble in non-polar oil, as
Composition, it is double [{ 4- (2- ethyl hexyl oxies) -2- hydroxyls }-phenyl] -6- (4- the methoxyphenyls) -1,3,5-triazines of 2,4-.
INCI names (Intemational Nomenclature cosmetic material bookmark name) are Tinosorb S, as commercially available
Product, Tinosorb S (manufacture of BASF societies) can be enumerated.
The content of composition (a) in the water-in-oil emulsion of the present invention is 1%~3%.It is ultraviolet when content is less than 1%
Line protection effect reduces, and during more than 3%, spreadability becomes to have some setbacks when being sprawled with hand, is deteriorated in terms of sense of touch.
The composition (b) used in the present invention is diester of the propane diols with carbon number for 8~10 aliphatic acid formation, 25
DEG C be liquid ester oil.Specifically, didecyl acid propylene glycol ester, two sad propylene glycol esters, two (caprylic caprics) can be enumerated
Propylene glycol ester, it can use more than one or both of these.
The content of composition (b) in the water-in-oil emulsion of the present invention is 5%~50%, more preferably 15%~
40%.When content is less than 5%, composition (a) through when separate out, it is possible to cause blocking, during more than 50%, use the oil of rear skin
Sense becomes strong, is deteriorated in terms of sense of touch.It in the case that content is 15%~40%, can equably spray, and also may be used in terms of sense of touch
With very excellent.
Composition (c) ethylhexyl methoxy cinnamate used in the present invention is in the ultraviolet radiation absorption that 25 DEG C are liquid
Agent.The content of composition (c) in water-in-oil emulsion is 5%~15%, more preferably 7%~12%.Content is less than 5%
When, composition (a) through when separate out, it is possible to cause blocking, during more than 15%, produce tacky, be deteriorated in terms of sense of touch.Content is
In the case of 7%~12%, can equably it spray, and can also be very excellent in terms of sense of touch.
In the water-in-oil emulsion of the present invention, composition (a) and composition (b) and the mass ratio (a) of (c):(b)+(c) is preferred
For 1:10~1:20th, it is more preferably 1:10~1:15.If the scope, then excellent in stability is can obtain, without tacky change
Makeup material.
Being capable of further compounding ingredients (d) silicone oil in the water-in-oil emulsion of the present invention.Composition (d) is not limited especially
It is fixed, preferably in the material that 25 DEG C are liquid, octamethylcy-clotetrasiloxane, decamethylcyclopentaandoxane, ten dimethyl can be enumerated
It is the siloxanes of ring six, HMDO, octamethyltrisiloxane, decamethyl tetrasiloxane, the poly- trimethicone of methyl, pungent
The poly- trimethicone of base, dimethyl polysiloxane, methyl phenyl silicone etc., they can use it is one or two kinds of with
On.In general, it is known that ultra-violet absorber is difficult to compatible with silicone oil mostly, and composition (a) is no exception, therefore preferably silicone oil
Content is as few as possible, if but be considered as the use feeling of sun-proof cosmetic preparation, preferably in water-in-oil emulsion mixture 1%~
20% or so.If the scope, then stability is good, can obtain salubrious use feeling.Gather from general as sense of touch regulator
The siloxanes such as methyl silsesquioxane powder, the siloxane surface processed material as the metal oxide of ultraviolet protection composition are closed
Used time it is stability-enhanced from the aspect of, it is also preferred that compounding ingredients (d) silicone oil.
In addition, in the water-in-oil emulsion of the present invention, in the range of the effect of the present invention is not damaged, as logical
The composition of mixture in normal cosmetic preparation, the oil components beyond compounding ingredients (b)~(d) can be taken the circumstances into consideration as needed, surface is lived
It is ultra-violet absorber, powder, water soluble polymer, NMF beyond property agent, water composition, composition (a), (c), anti-oxidant
Agent, colour fading preventing agent, preservative, effective component, stabilization agent, pigment, spices etc., to assign various effects.
As oil components, as long as the material for being generally used for cosmetic preparation in addition to composition (b)~(d) does not just limit especially
It is fixed, the solid oils of the origins such as animal oil, vegetable oil, artificial oil, semisolid oil, fluid oil, the character of ethereal oil are not limited to, can
Derived with enumerating hydro carbons, grease type, wax class, solidification oils, ester oil class, fatty acid, higher alcohols, fluorine system oils, lanolin
Species, oily gelling agent class, oil-soluble resin etc..
Specifically, atoleine, saualane, vaseline, solid paraffin, hard wax (セ レ シ Application ワ ッ Network can be enumerated
ス), hydro carbons, the Japan such as microwax, ethylene propylene copolymer, lignite wax, Fischer-Tropsch wax, lightweight flowing isoparaffin, Permethyl 99A
The wax class such as grease type, beeswax, Brazil wax, candelila wax, the spermaceti such as wax, olive oil, castor oil, ermine oil, Hawaii kernel oil,
Jojoba oil (jojoba oil), isooctyl acid cetyl ester, isopropyl myristate, isopropyl palmitate, tetradecylic acid
Octyldodecyl, tricaprylin, the glyceride of two isostearic acid two, the glyceride of three isostearic acid two, tribehenin acid are sweet
Grease, two different stearyl ester of malic acid, neopentyl glycol two (thylhexoic acid) ester, different n-nonanoic acid tridecane base ester, the different tridecane of different n-nonanoic acid
Base ester, benzoic acid alkyl base ester, diisopropyl sebacate, decanedioic acid ethylhexyl, cholesterol fatty acid ester, N- lauroyl-L-
Esters, stearyl alcohol, hexadecanol, the bays such as glutamic acid two (cholesterol ester docosane base ester octyldodecyl)
The fluorine system finish such as higher alcohols, perfluoro decane, PFO, the PFPEs such as alcohol, oily enol, isooctadecanol, docosyl alcohol class, sheep
The lanolin derivatives such as hair fat, acetic acid lanolin, lanolin fatty isopropyl propionate, lanolin alcohol, sad dextrin, laurate paste
Essence, Dextrin palmitate, tetradecylic acid dextrin, stearic acid dextrin, behenic acid dextrin, coco-nut oil fatty acid dextrin, (palmitic acid/octanoic acid)
Oily gelling agent class, the hydrogenated rosins such as dextrin, sucrose fatty ester, starch aliphatic ester, 12- hydroxy stearic acids, calcium stearate
The oil-soluble resins such as sour pentaerythritol ester, specific acrylic acid alkyl methyl polysiloxane ester, etc..These oil components can be with
As needed using one or more, wherein different from stability aspect, preferably benzoic acid alkyl base ester, decanedioic acid two
Propyl diester, decanedioic acid ethylhexyl.
As surfactant, as long as surfactant can conventionally used in cosmetic preparation uses arbitrary thing
Matter, nonionic surface active agent, anionic surfactant, cationic surface active agent, amphoteric surface can be enumerated
Activating agent etc..Specifically, fatty acid glyceride and its alkylene glycol addition product, polyglyceryl fatty acid ester and its alkane can be enumerated
Support glycol adducts, sorbitan aliphatic ester and its alkylene glycol addition product, sucrose fatty ester, polyethylene glycol hydrogenated castor-oil plant
Oil, polyoxyalkylene alkyl common modified organopolysiloxane, polyether-modified organopolysiloxane etc..These surfactants can root
According to one or more are needed to use, in order to form water-in-oil emulsion, it is necessary to below mixture HLB7 nonionic table
Face activating agent.Wherein, from stability aspect, the nonionic table being preferably made up of the ester conjugate of poly- hydroxy stearic acid
Face activating agent, such as dimerization hydroxy stearic acid ester PEG-30；The poly- diformazan of lipophile silicone type surface active agent, such as PEG-9
Base siloxy ethyl dimethicone, lauryl PEG-9 poly dimethyl siloxy ethyl dimethicones etc..
As water composition, deionized water, distilled water, pure water, thermal water or rose water, lavender liquid can be enumerated
The so-called water such as the steam distillation water Deng plant origin, further, it is also possible to enumerate thing water-soluble and that solvent can be turned into
Matter, for example, the alcohols such as ethanol, isopropanol, propane diols, 1,2- pentanediols, 1,3-BDO, DPG, polyethylene glycol etc. two
The glycerols such as alcohols, glycerine, diglycerol, polyglycereol.
As ultra-violet absorber, such as benzophenone series, PABA systems, cinnamic acid system, salicylic acid system, silicon systems can be enumerated
Deng.Specifically, 2- [4- (diethylamino) -2- hydroxy benzoyls] hexyl-benzoate, oxybenzone, 4- tert-s can be enumerated
4 '-methoxy dibenzoylmethane, ESCALOL 567, salicylic acid -2- ethylhexyls, to dihydroxy third
Yl benzoic acid ethyl ester, dimethoxybenzylidenegroup group dioxoimidazolidin alkyl propionic acid -2- ethylhexyls, 2,2 '-di-2-ethylhexylphosphine oxide [6- (2H-
BTA -2- bases) -4- (1,1,3,3- tetramethyl butyls) phenol], double [{ 4- (the 2- ethyl hexyl oxygen of (1,3,5)-triazine -2,4-
Base) -2- hydroxyls-phenyl] -6- (4- methoxyphenyls) -1,3,5- triazines, benzal malonic acid salt polysiloxanes (ジ メ チ Us
ジ エ チ Le ベ Application ザ Le マ ロ ネ ー ト), BP-4 and its sodium salt, Dimethicodiethylbenzalmalonate
Deng.
As powder, as long as powder can conventionally used in cosmetic preparation uses arbitrary material, adjusted with sense of touch
Deng for the purpose of, such as siloxanes powder, talcum, sericite, silica, mica, kaolin, calcium carbonate, oxidation can be used
The powders such as aluminium, polyethylene end, polymethyl methacrylate, nylon powder., can be with addition, in order to assign ultraviolet protection effect
Using metal-oxide powder, such as zinc oxide, titanium dioxide, cerium oxide etc. can be enumerated, they can use one kind or will
It is used in combination.These powders can utilize known surface treatment method, such as silica-treated, at aluminum oxide
Reason, aluminium hydroxide processing, fluorine compounds processing, siloxane treated, organic siliconresin processing, side chain are handled, at silane coupler
Reason, titanium coupling agent processing, silane treatment, finish processing, N- be acylated lysine processing, polyacrylic acid processing, metallic soap processing,
The methods of acrylic resin processing, metal oxide treated, is surface-treated.Simply, in the present invention, if a large amount of mixture gold
Belong to oxide powder, then the transparency reduces sometimes, astringent sense strengthens sometimes, therefore its blend amount is in water-in-oil emulsion
In be preferably less than 10%, more preferably less than 5%.
As NMF, such as protein, mucopolysaccharide, collagen, elastin laminin, keratin etc. can be enumerated；As
Antioxidant, such as alpha-tocopherol, ascorbic acid etc. can be enumerated；As Cosmetic Ingredient, such as vitamins can be enumerated, disappeared
Scorching agent, Chinese herbal medicine etc.；As preservative, such as p-hydroxybenzoate, phenoxetol, 1,2- pentanediols etc. can be enumerated.
The manufacture method of the water-in-oil emulsion of the present invention is not particularly limited, can be using conventional method system
It is standby, for example, composition (a) is dissolved by heating in composition (b) and composition (c), mixed with other oil components and surfactant,
Water composition is emulsified and obtains above-mentioned water-in-oil emulsion.In addition, in the case of mixture powder, preferably fully divide in advance
Dissipate in oil components or water composition, emulsified afterwards.
The mass ratio (oil components) of oil components and water composition in the water-in-oil emulsion of the present invention：It is (water-based
Composition) it is different because of formula, such as preferably 1:3~3:1st, it is more preferably 1:2~2:1.In addition, the Water-In-Oil of the present invention
The content of emulsifying agent in type emulsion is that the amount of water composition, preferably Water-In-Oil can be stably emulsified in oil components
The 0.1%~5% of type emulsion.Because：It if such scope, then can stably emulsify, pass through over time
It is unconfirmed to be separated out to crystallization, thus when aerosol type sun-proof cosmetic preparation is made excellent in stability, can equably spray.
(propellant)
, can be by 1 in the hydrocarbon and dimethyl ether that carbon number is 2~5 as the liquid gas used in the present invention
Plant or two or more is applied in combination.It is 2~5 hydrocarbon as carbon number, such as ethane, propane, normal butane, isobutyl can be enumerated
Alkane, pentane, isopentane, neopentane etc..Among these, from passing through the outer oil with water-in-oil emulsion in aerosol container
It is mutually compatible come reduce with the interaction of interior aqueous phase, improve long-time stability in terms of set out, preferably using oil loving hydrocarbon.This
Outside, from the security aspect under high temperature, pressure at 20 DEG C is preferably adjusted to 0.15MPa compressed petroleum gas
(being designated as LPG0.15 below).
As the fill method of the aerosol of the present invention, it is not particularly limited, the above-mentioned oil that will be prepared using conventional method
Water-in type emulsion is filled into pressure vessel, after aerosol valve is fixed on into container, injects liquid gas by the valve.This
Outside, by the way that injecting-unit corresponding with purpose is attached into above-mentioned aerosol valve, so as to form aerosol product.In addition, according to
Viscosity of water-in-oil emulsion etc., for homogenizing in filling process, it can also fill respectively for forming water-in-oil type
The oil phase and aqueous phase of emulsion and powder etc., reinject liquid gas afterwards.
Embodiment
Below, embodiment is enumerated the present invention is described in more detail.It should be noted that but the present invention do not implemented by these
Any restriction of example.
Embodiment 1~6 and comparative example 1~8：
The sun-proof cosmetic preparation of aerosol type is prepared for using the composition shown in table 1 and following preparation methods.By following methods to institute
Obtained cosmetic preparation is evaluated, and result is shown in table 1 in the lump.
A：Composition (1)~(3) and (6)~(8) are dissolved by heating.
B：In A behind blending constituent (4)~(5) and (9), (10), it is uniformly dispersed (11).
C：Blending constituent (12)~(16), are emulsified added in B, obtain stoste.
D：After the stoste 9g obtained in C is filled into the pressure vessel of clear glass system and aluminum, standing valve, pass through valve
LPG0.15 21g are filled into pressure vessel, obtain the sun-proof cosmetic preparation of aerosol type.
(evaluation method 1：The precipitation of crystallization)
The aerosol composition of embodiment 1~6 and comparative example 1~8 is filled into the pressure vessel of clear glass, made
For the accelerated test of ageing stability, recover after being placed 2 weeks at -20 DEG C to 25 DEG C, confirm that sample has nodeless mesh by visual observation
Separate out.
[determinating reference]
(judgement)：(evaluation)
○：It is unconfirmed to be separated out to crystallization.
×：Crystallization is confirmed to separate out.
(evaluation method 2：Without blocking)
The aerosol composition of embodiment 1~6 and comparative example 1~8 is filled to the pressure vessel of aluminum (specification, bar：Directly
Footpath 0.4m, shell：0.8 × diameter 0.55mm, button：Diameter 0.5mm) in, preserved 1 month respectively at 5 DEG C and 40 DEG C, make the sample
Product recover to room temperature, are sprayed within 10 seconds at 25 DEG C of intervals and use is to last, according to following metewands to spraying now
Property is evaluated.
[determinating reference]
(judgement)：(evaluation)
○：Can be with state use of uniformly spraying to last.
×：Spraying state is uneven, and blocking is caused in way, can not use.
(evaluation method 3：The transparency)
The aerosol composition 30g of embodiment 1~6 and comparative example 1~8 is filled into the pressure vessel of aluminum, from away from
Position from 15cm is sprayed 3 seconds to 10cm black pieces, visually the completion status after observation just injection.
[determinating reference]
(judgement)：(evaluation)
○：Pellucidly complete.
×：Turn white obvious.
(evaluation method 4：Without tackiness)
Please 20 cosmetic evaluation expert groups by the aerosol composition of embodiment 1~6 and comparative example 1~8 to left forearm
Spraying 3 seconds, sprawled and used with hand afterwards, on from use to " without tackiness " after use, each according to following evaluations
Benchmark carries out 5 grade evaluations, and each sample is scored, and then the average mark of the scoring for whole judging panels, according to following
Determinating reference is judged.
[metewand]
(scoring)：(result)
5 points：It is very good
4 points：It is good
3 points：Commonly
2 points：It is slightly worse
1 point：Difference
[determinating reference]
(judgement)：(average mark of scoring)
◎：4.5 points~5.0 points
○：3.5 points~be less than 4.5 points
△：2.0 points~be less than 3.5 points
×：1.0 points~be less than 2.0 points
As shown in Table 1, the sun-proof cosmetic preparation of the aerosol type of embodiment 1~6 does not observe double ethyl hexyl oxies
The precipitation of phenol methoxyphenyl triazine, stability is excellent at low temperatures and high temperatures, and also without tacky in terms of sense of touch, usability is excellent
It is different.
On the other hand, instead of composition (B) in the mixture comparative example 1~3 of different ester oil, double ethyl hexyl oxygen are confirmed
The crystallization of base phenol methoxyphenyl triazine separates out, and problem in terms of stability be present, on (thylhexoic acid) ester of glycerine three and
Cetyl octanoate, sense of touch aspect are also poor.In the comparative example 4 of composition (B) more, exist tacky, sense of touch is wanting in.It is not compounded into
In the comparative example 5 of point (C), the precipitation of crystallization is confirmed, in the comparative example 6 of composition (C) more, sense of touch is wanting in.Composition (A):Into
In the case of the containing than deviation of point (B)+(C), the precipitation of crystallization is confirmed, problem be present in terms of stability.
Shown by result above, by combining each composition of the present invention, can obtain excellent in stability, without tacky aerosol
Type suncream.
Embodiment 7：Aerosol type suncream
(note 1) fine particulate titanium dioxide MTY-110M3S (manufacture of TAYCA Co., Ltd.)
(manufacture method)
A：Composition (8) is disperseed with appropriate composition (2) and composition (7).
B：Composition (1)~(3) are dissolved by heating.
C：Blending constituent (4)~(6) and B, make its dispersed in A.
D：Blending constituent (9)~(12), are emulsified added in C, obtain stoste.
E：After the stoste 6g obtained in D is filled into aluminum pressure vessel, standing valve, by valve by LPG0.15 24g
Filling obtains the sun-proof cosmetic preparation of aerosol type into pressure vessel.
In embodiment 7, the attachment portion that aerosol just can be seen after injection turns white, but transparence immediately, and unconfirmed
It is sun-proof without tacky aerosol type without blocking, sense of touch aspect to the precipitation of Tinosorb S
Frost.
Embodiment 8：Aerosol type suncream
(note 2) IPSE (Nippon Seika K.K.'s manufacture)
(note 3) FINEX-50S-LP2 (manufacture of Sakai chemistry society)
(manufacture method)
A：Composition (1)~(3) are dissolved by heating.
B：Blending constituent (4)~(10), make its dispersed in A.
C：Blending constituent (11)~(14), added in B, are emulsified.
D：After the stoste 9g obtained in C is filled into aluminum pressure vessel, standing valve, by valve by LPG0.15 21g
Filling obtains the sun-proof cosmetic preparation of aerosol type into pressure vessel.
Precipitation unconfirmed to Tinosorb S in embodiment 8 is sense of touch aspect without hair
Viscous aerosol type suncream.
Embodiment 9：Aerosol type suncream
(note 4) UVINUL A PLUS (manufacture of BASF societies)
(note 5) SH200C FLUID 6CS (manufacture of TorayDow Corning societies)
(note 6) Neosolue-EHS (Nippon Seika K.K.'s manufacture)
(manufacture method)
A：Composition (1)~(4) are dissolved by heating.
B：Blending constituent (5)~(8), make its dispersed in A.
C：Blending constituent (9)~(10), added in B, are emulsified.
D：After the stoste 9g obtained in C is filled into aluminum pressure vessel, standing valve, by valve by LPG0.15 15g
Filled with dimethyl ether 6g into pressure vessel, obtain aerosol type sun care preparations.
Precipitation unconfirmed to Tinosorb S in embodiment 9 is sense of touch aspect without hair
Viscous aerosol type suncream.
Embodiment 10：Aerosol type suncream
(manufacture method)
A：Composition (1)~(4) are dissolved by heating.
B：In A behind blending constituent (5)~(8), make (9) dispersed.
C：Blending constituent (10)~(12), are emulsified added in B, obtain stoste.
D：After the stoste 9g obtained in C is filled into the pressure vessel of clear glass system and aluminum, standing valve, pass through valve
LPG0.15 21g are filled into pressure vessel, obtain the sun-proof cosmetic preparation of aerosol type.
Precipitation unconfirmed to Tinosorb S in embodiment 10 is sense of touch aspect without hair
Viscous aerosol type suncream.
Claims (2)
- A kind of 1. sun-proof cosmetic preparation of aerosol type, it is characterised in thatIt is the aerosol containing the stoste as water-in-oil emulsion and the liquid gas as propellant, the water-in-oil type Emulsion contains following component (a)~(c)：(a) the mass % of the mass % of Tinosorb S 1~3；(b) the mass % of the mass % of diester 5 that the aliphatic acid that propane diols and carbon number are 8~10 is formed~50；(c) the mass % of the mass % of ethylhexyl methoxy cinnamate 5~15, composition (a) in the water-in-oil emulsion with Composition (b) and (c) mass ratio are 1:10~1:20 scope,The filling proportion of water-in-oil emulsion and liquid gas in the sun-proof cosmetic preparation of aerosol type is water-in-oil emulsion The mass % of the mass % and mass % of liquid gas 60 of 15 mass %~40~85%.
- 2. the sun-proof cosmetic preparation of aerosol type as claimed in claim 1, it is characterised in that enter one in the water-in-oil emulsion Step contains composition (d) silicone oil.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013-031162 | 2013-02-20 | ||
| JP2013031162 | 2013-02-20 | ||
| PCT/JP2014/053857 WO2014129484A1 (en) | 2013-02-20 | 2014-02-19 | Aerosol-type sunscreen cosmetic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104994834A CN104994834A (en) | 2015-10-21 |
| CN104994834B true CN104994834B (en) | 2018-04-06 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480009099.XA Active CN104994834B (en) | 2013-02-20 | 2014-02-19 | The sun-proof cosmetic preparation of aerosol type |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JP6255004B2 (en) |
| KR (1) | KR102099493B1 (en) |
| CN (1) | CN104994834B (en) |
| HK (1) | HK1210051A1 (en) |
| TW (1) | TWI597067B (en) |
| WO (1) | WO2014129484A1 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6750016B2 (en) * | 2015-12-17 | 2020-09-02 | ロレアル | Water-in-oil emulsion with a moisturizing effect containing a hydrophobically coated pigment and a high content of water phase |
| JP6894781B2 (en) * | 2016-06-30 | 2021-06-30 | 株式会社コーセー | Aerosol type cosmetics |
| US10344194B2 (en) * | 2017-09-27 | 2019-07-09 | Momentive Performance Materials Inc. | Thermal interface composition comprising ionically modified siloxane |
| CN114845697A (en) * | 2019-12-25 | 2022-08-02 | 花王株式会社 | Water-in-oil type emulsified sunscreen cosmetic |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050142080A1 (en) * | 2001-12-20 | 2005-06-30 | Beiersdorf Ag | Cosmetic or dermatological light protection formulation with a benzoxazole derivative |
| CN101011332A (en) * | 2006-01-19 | 2007-08-08 | 莱雅公司 | Aqueous fluid photoprotective composition based on an ester-terminated poly(ester amide) polymer |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10162840A1 (en) * | 2001-12-20 | 2003-07-03 | Beiersdorf Ag | Cosmetic and dermatological light protection formulations containing water-soluble UV filter substances and benzoxazole derivatives |
| DE10162841A1 (en) * | 2001-12-20 | 2003-07-03 | Beiersdorf Ag | Cosmetic and dermatological light protection formulations containing benzoxazole derivatives |
| DE102005028388A1 (en) | 2005-06-20 | 2007-01-04 | Wella Ag | Product delivery system for spraying hair or skin cosmetic compositions containing UV filters |
| JP5378753B2 (en) * | 2008-10-22 | 2013-12-25 | 株式会社 資生堂 | Emulsified composition |
| JP5566016B2 (en) * | 2008-11-18 | 2014-08-06 | 花王株式会社 | Aerosol type sunscreen cosmetics |
| JP5503175B2 (en) * | 2009-03-30 | 2014-05-28 | 株式会社コーセー | Cracking aerosol composition |
| JP6022140B2 (en) | 2009-05-21 | 2016-11-09 | 株式会社ダイゾー | Aerosol composition |
| JP5058352B2 (en) | 2010-04-13 | 2012-10-24 | 株式会社 資生堂 | Water-in-oil emulsion composition |
| JP6727820B2 (en) * | 2016-01-28 | 2020-07-22 | 株式会社コーセー | Cosmetic composition |
-
2014
- 2014-02-19 CN CN201480009099.XA patent/CN104994834B/en active Active
- 2014-02-19 KR KR1020157025267A patent/KR102099493B1/en active IP Right Grant
- 2014-02-19 WO PCT/JP2014/053857 patent/WO2014129484A1/en active Application Filing
- 2014-02-19 JP JP2015501469A patent/JP6255004B2/en active Active
- 2014-02-20 TW TW103105644A patent/TWI597067B/en active
-
2015
- 2015-11-06 HK HK15110995.7A patent/HK1210051A1/en unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050142080A1 (en) * | 2001-12-20 | 2005-06-30 | Beiersdorf Ag | Cosmetic or dermatological light protection formulation with a benzoxazole derivative |
| CN101011332A (en) * | 2006-01-19 | 2007-08-08 | 莱雅公司 | Aqueous fluid photoprotective composition based on an ester-terminated poly(ester amide) polymer |
Also Published As
| Publication number | Publication date |
|---|---|
| JP6255004B2 (en) | 2017-12-27 |
| KR102099493B1 (en) | 2020-04-09 |
| WO2014129484A1 (en) | 2014-08-28 |
| TW201442731A (en) | 2014-11-16 |
| TWI597067B (en) | 2017-09-01 |
| CN104994834A (en) | 2015-10-21 |
| KR20150120431A (en) | 2015-10-27 |
| HK1210051A1 (en) | 2016-04-15 |
| JPWO2014129484A1 (en) | 2017-02-02 |
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