CN104989048A - Ultraviolet curing transfer-printing flat decoration plate and manufacturing method thereof - Google Patents

Ultraviolet curing transfer-printing flat decoration plate and manufacturing method thereof Download PDF

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Publication number
CN104989048A
CN104989048A CN201410849216.5A CN201410849216A CN104989048A CN 104989048 A CN104989048 A CN 104989048A CN 201410849216 A CN201410849216 A CN 201410849216A CN 104989048 A CN104989048 A CN 104989048A
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decorating board
ultraviolet light
carry out
decorative panel
ultra
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CN201410849216.5A
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CN104989048B (en
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赵金平
王弘书
冯小江
唐门辉
刘雪婧
高秀慧
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Beijing Tiangongju Technology Co.,Ltd.
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ZHONGGUANCUN HUMAN SETTLEMENT AND MATERIAL RESEARCH INSTITUTE
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Abstract

The invention provides an ultraviolet curing transfer-printing flat decoration plate and a manufacturing method thereof. The method includes: (1) forming a primer surface on the front surface of a decoration substrate; (2) performing sizing and transfer film-printing of the primer surface, performing ultraviolet curing, and removing the transfer-printing film; (3) performing roller painting of colored paints on the front surface of the decoration substrate and performing ultraviolet curing; and (4) performing roller painting of flat finishing paints on the cured colored paints and performing ultraviolet curing. The decoration plate manufactured by the method is advantaged by high-definition emulation, bright and saturated color, smooth and wear-resistant surface, light weight, and low cost.

Description

A kind of ultra-violet curing transfer zero diopter decorative panel and manufacture method thereof
Technical field
The present invention relates to a kind of decorative panel and manufacture method thereof, particularly relate to a kind of ultra-violet curing transfer zero diopter decorative panel and manufacture method thereof.
Background technology
Ultraviolet light (UV) solidification be utilize the photonasty of light trigger (sensitising agent), light-initiated formation excited ecological molecule under ultraviolet light irradiation, chemical reactions such as resolving into free radical or ion, make unsaturated compounds carry out being polymerized, connect skill, be crosslinked reaches the object of solidification.UV-curing technology has been applied in the manufacture of decorative panel.The base material of UV-curing technology is adopted to comprise cement pressure plate, multilayer solid wood board, density board, glass magnesium PLASTIC LAMINATED.But the ultraviolet light polymerization decorative panel being base material manufacture with the sheet material of mentioned kind can not meet at present to inexpensive, lightweight, the requirement that thickness is thin of decorative panel.
Summary of the invention
The present invention is intended to solve above-described problem.The object of this invention is to provide a kind of ultra-violet curing transfer zero diopter decorative panel and manufacture method thereof.
According to an aspect of the present invention, provide a kind of manufacture method of ultra-violet curing transfer zero diopter decorative panel, said method comprising the steps of:
(1) priming paint face is formed in the front of decorating board;
(2) applying glue on described priming paint face, cover transfer film, and carry out ultraviolet light polymerization, then remove described transfer film;
(3) be coated with colored paint in the face-side roll of described decorating board, and carry out ultraviolet light polymerization;
(4) roller coat zero diopter finish paint on the described colored paint through overcuring, and carry out ultraviolet light polymerization.
Wherein, before described step (1), also step is comprised:
Carry out dust removal process at the back side of described decorating board, then at the back side roller coat seal coat of described decorating board, and carry out ultraviolet light polymerization.
Wherein, described step (1) comprising:
(11) dust removal process is carried out in the front of described decorating board;
(12) be coated with adhesion primer in the face-side roll of described decorating board, and carry out ultraviolet light polymerization;
(13) washed ore light and dust removal process are carried out to the front of described decorating board;
(14) at the face-side roll coating white priming paint of described decorating board, and ultraviolet light polymerization is carried out;
(15) at the front roller coat seal coat of described decorating board, and ultraviolet light polymerization is carried out;
(16) sanding, infrared levelling and dust removal process are carried out to the front of described decorating board;
(17) be coated with attachment primer in the face-side roll of described decorating board, and carry out ultraviolet light polymerization, form priming paint face.
Wherein, after described step (4), also step is comprised:
Diaphragm is covered in the front of described decorating board.
Wherein, the roller coat in described step (4), described step (12) and described step (15) adopts just against the mode of roller roller coat.
Wherein, in described step (13), adopt 240 order sand paper to carry out the process of washed ore light to the front of described decorating board, in described step (16), adopt 400 order sand paper to sand flat seal coat on the front of described decorating board.
Wherein, the time of carrying out ultraviolet light polymerization in each step is 3-10s, and ultraviolet light polymerization is 5 DEG C of-40 DEG C of normal temperature cures.
Wherein, in each step, the thickness of roll coat enamel is 0.05-0.12mm.
Wherein, described decorating board is gypsum plank.
According to another aspect of the present invention, a kind of ultra-violet curing transfer zero diopter decorative panel manufactured by above-mentioned manufacture method is provided.
Ultra-violet curing transfer zero diopter decorative panel of the present invention and manufacture method thereof can bring the lot of advantages relative to other kind substrates, and such as, cost is low, applied range etc.In addition, the material feature of said method and gypsum plank self combines, and is different from existing UV-curing technology.Adopt the decorative panel of said method manufacture to have better hardness and wiping properties, be more applicable for the dalle in building.Hardness of film >=the 2H of this decorative panel, and there is acid resistance, alkali resistance, the performance that solvent resistant wiping is >100 time.
Any pattern can be transferred on decorating board by ultra-violet curing transfer zero diopter decorative board production method according to the present invention, reach the similarity of 98%-99%, and the decorative panel manufactured have high definition emulation, saturated, smooth surface is wear-resisting, light weight is inexpensive feature bright in luster.Above-mentioned manufacture method curing rate is fast, production efficiency is high, Environmental Safety.
Read the following description for exemplary embodiment with reference to accompanying drawing, other property features of the present invention and advantage will become clear.
Accompanying drawing explanation
To be incorporated in manual and the accompanying drawing forming a part for manual shows embodiments of the invention, and together with the description for explaining principle of the present invention.In the drawings, similar Reference numeral is used for key element like representation class.Accompanying drawing in the following describes is some embodiments of the present invention, instead of whole embodiment.For those of ordinary skill in the art, under the prerequisite not paying creative work, other accompanying drawing can be obtained according to these accompanying drawings.
Fig. 1 schematically illustrates the flow chart according to ultra-violet curing transfer zero diopter decorative board production method of the present invention.
Detailed description of the invention
For making the object of the embodiment of the present invention, technical scheme and advantage clearly, below in conjunction with the accompanying drawing in the embodiment of the present invention, technical scheme in the embodiment of the present invention is clearly and completely described, obviously, described embodiment is the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.It should be noted that, when not conflicting, the embodiment in the application and the feature in embodiment can be combined mutually.
In existing UV-curing technology, according to the difference of base material, the technique of the ultraviolet light polymerization of employing is also different.Such as, when being applied to wood surface, need the characteristics such as the moisture content of consideration timber; When being applied to cement matrix, need the alkaline matrix considering cement.
At present, also UV-curing technology is not applied to gypsum plank.Due to gypsum plank self inexpensive, lightweight, thickness is thin, be that substrate applications UV-curing technology can bring huge economic benefit with gypsum plank, therefore, inventors performed a large amount of experiments, UV-curing technology is applied to gypsum plank.Inventor draws by experiment, when UV-curing technology is applied to gypsum plank, take into full account the particularity of gypsum plank material, adopt special production technology.Introduce the manufacture method according to ultra-violet curing transfer zero diopter decorative panel of the present invention below in detail.
Manufacture method according to ultra-violet curing transfer zero diopter decorative panel of the present invention comprises the following steps:
(1) priming paint face is formed in the front of decorating board.
(2) applying glue on described priming paint face, cover transfer film, and carry out ultraviolet light polymerization, then adopt automatic membrane removal machine to remove described transfer film.Wherein, transfer film there is pattern to be transferred, by transfer printing, the pattern on transfer film is formed on the front of decorating board.In this step, applying glue is to be attached on priming paint face by the pattern on transfer film, being then fixed on priming paint face by ultraviolet light polymerization.
(3) be coated with colored paint in the face-side roll of described decorating board, and carry out ultraviolet light polymerization.It should be noted that, in step (2) after removing transfer film, priming paint face forms the pattern of transfer printing, the pattern top roll then in priming paint face in step (3) is coated with colored paint.Wherein the object of roller coat colored paint established pattern transferring is played to the effect of protection.
(4) roller coat zero diopter finish paint on the colored paint through overcuring, and carry out ultraviolet light polymerization.Wherein the object of roller coat zero diopter finish paint is that the pattern transferring making roller coat cross colored paint reaches zero diopter effect.
Also step was comprised: carry out dust removal process at the back side of decorating board, then at the back side roller coat seal coat of decorating board, and carry out ultraviolet light polymerization before step (1).Ultraviolet light polymerization in this step adopts two mercury lamp curing to be cured.The above-mentioned step processed the back side of decorating board is to shield to substrate; due to the cure shrinkage that sheet material is very large can be caused after front surface coated multiple layers of cured coating; therefore apply the tension force that seal coat can offset sheet material two sides overleaf, prevent substrate deformation.
Above-mentioned steps (1) forms priming paint mask body and comprises in the front of decorating board:
(11) dust removal process is carried out in the front of decorating board.
(12) be coated with adhesion primer in the face-side roll of decorating board, and carry out ultraviolet light polymerization.Wherein the hardness of paint film of priming paint is high, and can improve the planeness in plate face.
(13) washed ore light and dust removal process are carried out to the front of decorating board.
(14) at the face-side roll coating white priming paint of decorating board, and ultraviolet light polymerization is carried out.Wherein the object of roller coat white primer be to improve after adhesive power, the fullness of coating in step, enable coating by uniform pickup.
(15) at the front roller coat seal coat of decorating board, and ultraviolet light polymerization is carried out.Wherein the object of roller coat seal coat makes the absorption of decorating board to upper coating become even, and effectively can prevent moisture, plays the effect of alkali resistant isolation.
(16) sanding, infrared levelling and dust removal process are carried out to the front of decorating board.
(17) be coated with attachment primer in the face-side roll of decorating board, and carry out ultraviolet light polymerization, form priming paint face.Wherein roller coat adheres to the adhesive power of coating in step after the object of primer is raising.
In above-mentioned steps (2), first applying glue on priming paint face, then covers transfer film, and carries out ultraviolet light polymerization on glue, make transfer film and glue hardening, the pattern simultaneously on transfer film is transferred on priming paint face.Then automatic membrane removal machine is utilized to be removed by transfer film.Because pattern is formed, glue is positioned at below pattern, therefore when removing transfer film, and the glue executed on priming paint face before can't removing.
Also step is comprised: cover diaphragm in the front of described decorating board after step (4).Thus form ultraviolet light polymerization zero diopter decorative panel.
Color according to coating in above-mentioned steps is different with function, selects the ultraviolet lamp of different wave length to be cured.Particularly, gallium gallium iron iron iron five lamp curing is adopted to be cured in above-mentioned steps (2), two gallium lamp curing is adopted to be cured in step (3), (12) and (14), adopt gallium gallium iron iron four lamp curing to be cured in step (4) and step (15), in step (17), adopt single mercury lamp curing to be cured.
In addition, the roller coat in step (4), step (12) and described step (15) adopts just against the mode of roller roller coat, to make paint even.Roller coat in other steps can adopt the mode of single roller roller coat.
In step (13), 240 order sand paper are adopted to carry out the process of washed ore light to the front of described decorating board.In step (16), adopt 400 order sand paper to sand flat seal coat on the front of described decorating board, and all need to carry out dust removal process after sanding and infrared levelling process.And in step (16), the object of infrared levelling is to raise system temperature, is convenient to the enforcement of later step.
The time of carrying out ultraviolet light polymerization in each step above-mentioned is 3-10s.The temperature of carrying out ultraviolet light polymerization in each step is normal temperature.Further, in each step, the thickness of roll coat enamel is 0.05-0.12mm.
Below provide specific embodiment.In following embodiment, be all applied to gypsum plank for this ultra-violet curing transfer zero diopter method.
embodiment one
Manufacture method according to ultra-violet curing transfer zero diopter decorative panel of the present invention comprises the following steps:
1) dust removal process is carried out to the back side of Thistle board;
2) adopt the mode of single roller roller coat at the thick seal coat of the backside coating 0.05mm of Thistle board, and adopt two mercury lamp curing to carry out the UV solidification of 3s;
3) turnover panel, and dust removal process is carried out to the front of Thistle board;
4) adopt just against the mode of roller roller coat at the thick adhesion primer of the front surface coated 0.05mm of Thistle board, and adopt two gallium lamp curing to carry out the UV solidification of 3s;
5), after having solidified, washed ore light and dust removal process are carried out to Thistle board surface;
6) white primer that single roller roller coat 0.05mm is thick, and adopt two gallium lamp curing to carry out the UV solidification of 3s;
7) adopt just against the seal coat that roller roller coat 0.05mm is thick, and adopt gallium gallium iron iron curing to carry out the UV solidification of 3s;
8) adopt 400 order sand paper to carry out sanding to the decorative panel completing primer coating, sand flat the seal coat on the front of described decorating board and carry out dust removal process, then carry out infrared levelling and dust removal process again;
9) the attachment primer that single roller roller coat 0.05mm is thick, and adopt single mercury lamp curing to carry out the UV solidification of 3s, form the priming paint face before transfer printing;
10) applying glue on priming paint face, cover transfer film, and carry out ultraviolet light polymerization, then adopt automatic membrane removal machine to remove described transfer film;
11) colored paint that single roller roller coat 0.05mm is thick on transfer film, and adopt two gallium lamp curing to carry out the UV solidification of 3s;
12) just against the zero diopter finish paint that roller roller coat 0.05mm is thick, and gallium gallium iron iron four lamp curing is adopted to carry out the UV solidification of 3s;
13) after having solidified, cover diaphragm at plaque surface, form UV and solidify zero diopter decorative panel.
Above-described UV solidification is all carried out under 5 DEG C of-40 DEG C of normal temperature conditions.
Hardness of film >=the 2H of the ultraviolet light polymerization zero diopter transfer decorative plate manufactured by said method, and there is acid resistance, alkali resistance, the performance that solvent resistant wiping is >100 time.
embodiment two
Manufacture method according to ultra-violet curing transfer zero diopter decorative panel of the present invention comprises the following steps:
1) dust removal process is carried out to the back side of Thistle board;
2) adopt the mode of single roller roller coat at the thick seal coat of the backside coating 0.08mm of Thistle board, and adopt two mercury lamp curing to carry out the UV solidification of 6s;
3) turnover panel, and dust removal process is carried out to the front of Thistle board;
4) adopt just against the mode of roller roller coat at the thick adhesion primer of the front surface coated 0.08mm of Thistle board, and adopt two gallium lamp curing to carry out the UV solidification of 6s;
5), after having solidified, washed ore light and dust removal process are carried out to Thistle board surface;
6) white primer that single roller roller coat 0.08mm is thick, and adopt two gallium lamp curing to carry out the UV solidification of 6s;
7) adopt just against the seal coat that roller roller coat 0.08mm is thick, and adopt gallium gallium iron iron curing to carry out the UV solidification of 6s;
8) adopt 400 order sand paper to carry out sanding to the decorative panel completing primer coating, sand flat the seal coat on the front of described decorating board and carry out dust removal process, then carry out infrared levelling and dust removal process again;
9) the attachment primer that single roller roller coat 0.08mm is thick, and adopt single mercury lamp curing to carry out the UV solidification of 6s, form the priming paint face before transfer printing;
10) applying glue on priming paint face, cover transfer film, and carry out ultraviolet light polymerization, then adopt automatic membrane removal machine to remove described transfer film;
11) colored paint that single roller roller coat 0.08mm is thick on transfer film, and adopt two gallium lamp curing to carry out the UV solidification of 6s;
12) just against the zero diopter finish paint that roller roller coat 0.08mm is thick, and gallium gallium iron iron four lamp curing is adopted to carry out the UV solidification of 6s;
13) after having solidified, cover diaphragm at plaque surface, form UV and solidify zero diopter decorative panel.
Above-described UV solidification is all carried out under 5 DEG C of-40 DEG C of normal temperature conditions.
Hardness of film >=the 2H of the ultraviolet light polymerization zero diopter transfer decorative plate manufactured by said method, and there is acid resistance, alkali resistance, the performance that solvent resistant wiping is >100 time.
embodiment three
Manufacture method according to ultra-violet curing transfer zero diopter decorative panel of the present invention comprises the following steps:
1) dust removal process is carried out to the back side of Thistle board;
2) adopt the mode of single roller roller coat at the thick seal coat of the backside coating 0.12mm of Thistle board, and adopt two mercury lamp curing to carry out the UV solidification of 10s;
3) turnover panel, and dust removal process is carried out to the front of Thistle board;
4) adopt just against the mode of roller roller coat at the thick adhesion primer of the front surface coated 0.12mm of Thistle board, and adopt two gallium lamp curing to carry out the UV solidification of 10s;
5), after having solidified, washed ore light and dust removal process are carried out to Thistle board surface;
6) white primer that single roller roller coat 0.12mm is thick, and adopt two gallium lamp curing to carry out the UV solidification of 10s;
7) adopt just against the seal coat that roller roller coat 0.12mm is thick, and adopt gallium gallium iron iron curing to carry out the UV solidification of 10s;
8) adopt 400 order sand paper to carry out sanding to the decorative panel completing primer coating, sand flat the seal coat on the front of described decorating board and carry out dust removal process, then carry out infrared levelling and dust removal process again;
9) the attachment primer that single roller roller coat 0.12mm is thick, and adopt single mercury lamp curing to carry out the UV solidification of 10s, form the priming paint face before transfer printing;
10) applying glue on priming paint face, cover transfer film, and carry out ultraviolet light polymerization, then adopt automatic membrane removal machine to remove described transfer film;
11) colored paint that single roller roller coat 0.12mm is thick on transfer film, and adopt two gallium lamp curing to carry out the UV solidification of 10s;
12) just against the zero diopter finish paint that roller roller coat 0.12mm is thick, and gallium gallium iron iron four lamp curing is adopted to carry out the UV solidification of 10s;
13) after having solidified, cover diaphragm at plaque surface, form UV and solidify zero diopter decorative panel.
Above-described UV solidification is all carried out under 5 DEG C of-40 DEG C of normal temperature conditions.
Hardness of film >=the 2H of the ultraviolet light polymerization zero diopter transfer decorative plate manufactured by said method, and there is acid resistance, alkali resistance, the performance that solvent resistant wiping is >100 time.
It should be noted that, current UV-curing technology is not all applied to gypsum plank, but due to gypsum plank self inexpensive, lightweight, thickness is thin, is that substrate applications UV-curing technology can bring huge economic benefit with gypsum plank.Therefore, take gypsum plank as the lot of advantages that decorating board can bring relative to other kind substrates, such as, cost be low, applied range etc.In addition, the material feature of said method and gypsum plank self combines, and is different from existing UV-curing technology.Adopt the decorative panel of said method manufacture to have better hardness and wiping properties, be more applicable for the dalle in building.
Any pattern can be transferred on decorating board by ultra-violet curing transfer zero diopter decorative board production method according to the present invention, reach the similarity of 98%-99%, and the decorative panel manufactured have high definition emulation, saturated, smooth surface is wear-resisting, light weight is inexpensive feature bright in luster.Above-mentioned manufacture method curing rate is fast, production efficiency is high, Environmental Safety.
Last it is noted that above embodiment is only in order to illustrate technical scheme of the present invention, be not intended to limit.Although with reference to previous embodiment to invention has been detailed description, those of ordinary skill in the art is to be understood that: it still can be modified to the technical scheme described in foregoing embodiments, or carries out equivalent replacement to wherein portion of techniques feature; And these amendments or replacement, do not make the essence of appropriate technical solution depart from the spirit and scope of various embodiments of the present invention technical scheme.

Claims (10)

1. a manufacture method for ultra-violet curing transfer zero diopter decorative panel, is characterized in that, said method comprising the steps of:
(1) priming paint face is formed in the front of decorating board;
(2) applying glue on described priming paint face, cover transfer film, and carry out ultraviolet light polymerization, then remove described transfer film;
(3) be coated with colored paint in the face-side roll of described decorating board, and carry out ultraviolet light polymerization;
(4) roller coat zero diopter finish paint on the described colored paint through overcuring, and carry out ultraviolet light polymerization.
2. the manufacture method of ultra-violet curing transfer zero diopter decorative panel as claimed in claim 1, is characterized in that, before described step (1), also comprise step:
Carry out dust removal process at the back side of described decorating board, then at the back side roller coat seal coat of described decorating board, and carry out ultraviolet light polymerization.
3. the manufacture method of ultra-violet curing transfer zero diopter decorative panel as claimed in claim 1, it is characterized in that, described step (1) comprising:
(11) dust removal process is carried out in the front of described decorating board;
(12) be coated with adhesion primer in the face-side roll of described decorating board, and carry out ultraviolet light polymerization;
(13) washed ore light and dust removal process are carried out to the front of described decorating board;
(14) at the face-side roll coating white priming paint of described decorating board, and ultraviolet light polymerization is carried out;
(15) at the front roller coat seal coat of described decorating board, and ultraviolet light polymerization is carried out;
(16) sanding, infrared levelling and dust removal process are carried out to the front of described decorating board;
(17) be coated with attachment primer in the face-side roll of described decorating board, and carry out ultraviolet light polymerization, form priming paint face.
4. the manufacture method of ultra-violet curing transfer zero diopter decorative panel as claimed in claim 1, is characterized in that, after described step (4), also comprise step:
Diaphragm is covered in the front of described decorating board.
5. the manufacture method of ultra-violet curing transfer zero diopter decorative panel as claimed in claim 3, it is characterized in that, the roller coat in described step (4), described step (12) and described step (15) adopts just against the mode of roller roller coat.
6. the manufacture method of ultra-violet curing transfer zero diopter decorative panel as claimed in claim 3, it is characterized in that, in described step (13), 240 order sand paper are adopted to carry out the process of washed ore light to the front of described decorating board, in described step (16), 400 order sand paper are adopted to sand flat seal coat on the front of described decorating board.
7. the manufacture method of the ultra-violet curing transfer zero diopter decorative panel according to any one of claim 1-6, it is characterized in that, the time of carrying out ultraviolet light polymerization in each step is 3-10s, and ultraviolet light polymerization is 5 DEG C of-40 DEG C of normal temperature cures.
8. the manufacture method of the ultra-violet curing transfer zero diopter decorative panel according to any one of claim 1-6, it is characterized in that, in each step, the thickness of roll coat enamel is 0.05-0.12mm.
9. the manufacture method of the ultra-violet curing transfer zero diopter decorative panel according to any one of claim 1-6, it is characterized in that, described decorating board is gypsum plank.
10. according to the ultra-violet curing transfer zero diopter decorative panel that the manufacture method according to any one of claim 1-9 manufactures.
CN201410849216.5A 2014-12-29 2014-12-29 A kind of ultra-violet curing transfer zero diopter decorative panel and its manufacture method Active CN104989048B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105298059A (en) * 2015-10-22 2016-02-03 湖南邦弗特新材料技术有限公司 Wall decoration board, UV transfer printing and coating technology thereof, and applications thereof
CN106179907A (en) * 2016-06-30 2016-12-07 卓达新材料科技集团威海股份有限公司 A kind of photocuring overlay film glass magnesium trim panel preparation method
CN106863045A (en) * 2017-01-17 2017-06-20 优居优住家居装饰(北京)有限公司 Floor processing method is transferred without an aromatic plant metioned in ancient books mildew resistant moistureproof UV

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Publication number Priority date Publication date Assignee Title
JPH0679845B2 (en) * 1992-08-20 1994-10-12 大日本印刷株式会社 Veneer manufacturing method
KR20050106949A (en) * 2004-05-06 2005-11-11 한광수 UV-transfer paper coated with solvent-free type UV curable paint
CN101941339B (en) * 2009-07-06 2011-12-28 珠海东诚光固化材料有限公司 Ultraviolet light cured transfer printing film and preparation method and application thereof
CN202265971U (en) * 2011-10-20 2012-06-06 珠海东诚光固化材料有限公司 Ultraviolet curing colored decoration section bar

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105298059A (en) * 2015-10-22 2016-02-03 湖南邦弗特新材料技术有限公司 Wall decoration board, UV transfer printing and coating technology thereof, and applications thereof
CN106179907A (en) * 2016-06-30 2016-12-07 卓达新材料科技集团威海股份有限公司 A kind of photocuring overlay film glass magnesium trim panel preparation method
CN106863045A (en) * 2017-01-17 2017-06-20 优居优住家居装饰(北京)有限公司 Floor processing method is transferred without an aromatic plant metioned in ancient books mildew resistant moistureproof UV

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