CN106010211A - UV radiation curable coating capable of recoating and use method thereof - Google Patents
UV radiation curable coating capable of recoating and use method thereof Download PDFInfo
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- CN106010211A CN106010211A CN201610258931.0A CN201610258931A CN106010211A CN 106010211 A CN106010211 A CN 106010211A CN 201610258931 A CN201610258931 A CN 201610258931A CN 106010211 A CN106010211 A CN 106010211A
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- Prior art keywords
- radiation curable
- curable coating
- recoated
- parts
- coating
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses a UV radiation curable coating capable of recoating; the prepared coating has excellent recoating adhesion powder, good cold-hot cycling and excellent weathering resistance, and also has the following advantages: 1, the operation process for coating and production of defective products can be simplified, polishing and other pretreatment are not required, the performance of the defective products is improved, and the production cost is reduced; and 2, the use scope under different climatic conditions is expanded, and the failure time of coated products used outdoors is substantially prolonged.
Description
Technical field
The present invention relates to technical field of coatings, be specifically related to a kind of UV radiation curable coating recoated and user thereof
Method.
Background technology
UV radiant light is coating material solidified has popularized use in an all-round way, and range is increasing, and its advantage is exactly, high richness,
High rigidity, high resistance to chemicals moral character, high-wearing feature, low voc energy-conserving and environment-protective odor profiles, low production efficiency significantly improve, shortcoming
It is exactly that the defective products produced aborning cannot be carried out reprocessing.The existing coating material solidified method that is widely used of UV radiant light is in car
The large-scale workpiece ready coatings such as class, household appliances, casing, big yet with workpiece, the little dirt pits of its part is difficult to avoid that, makes in production
The defective products become such as cannot reprocess at the reason, affects the control of production cost.
Research and develop at present and low viscosity UV bottom resin (for uncured type UV resin) has been introduced the solidification of UV radiant light
In coating, thus improve paint film adhesion, but experiment proves that its levelability, richness, hardness, chemical resistance, wearability all can
Causing declining, especially hardness, chemical resistance, wearability declines substantially.Also some manufacturer is comprehensive at it for meeting people
In the case of performance is constant, development & production is a kind of makes UV reprocess bottom water, and its technique is first defective products entirety to be polished, then
Bottom water is reprocessed in pre-spray one layer, then recoats UV radiation curable coating to improve the qualification rate of product.But bring not to production
Bother and waste a large amount of manpower and materials less, therefore the current coating material solidified direct recoating of UV radiant light still has suitable difficulty.
Summary of the invention
In view of this, the present invention discloses a kind of can directly reprocessing, without polishing, without making the UV radiation curing painting of bottom
Material.
The purpose of the present invention is achieved through the following technical solutions: a kind of UV radiation curable coating recoated, its raw material is pressed
Weight meter includes:
Monomer 1-3 part；
Acrylate oligomer 2-5 part；
Acetylbutyrylcellulose 2-5 part；
Modification acrylate 5-10 part；
Urethane acrylate 10-30 part；
Levelling agent 0.1-1 part；
Light trigger 1-3 part；
Solvent 50-80 part.
The described acrylate oligomer preferably ester oligomer Han solvent-type acrylic, can be selected for any one prior art real
Existing, such as the UA378 etc. of 6071,6070,6072 or thousand occasion materials of commercially available Changxing chemistry.Described acetylbutyrylcellulose is optional
Realizing by any one prior art, such as the CAB381-0.5 of Yi Shi Man of the U.S., its solid content is preferably 20wt%.Described poly-
Urethane acrylate can be selected for any one prior art and realizes.Described levelling agent, light trigger all can be selected for any one existing skill
Art realizes.Described modification acrylate can be methacrylate, Silicone modified acryl's ester, polyurethane-modified acrylic acid
The low-surface-energies such as ester, the prior art of high adhesion force realize.
The present invention selects acrylate oligomer, acetylbutyrylcellulose, modification acrylate, polyurethane acroleic acid especially
Ester, and its consumption is accurately allocated so that the coating of the present invention can directly recoat, and the most pre-without the most overall polishing
Spraying one layer of bottom water, adhesive strength is high.The coating of the present invention decreases spraying process, improves production efficiency, improves product qualified rate,
Decrease external coating energy consumption, reduce the voc discharge capacity that spraying application produces.There is hardness and the adhesive force of excellence simultaneously,
Improve the problem that prior art products causes wear resistance decrease because taking into account recoatability.Meanwhile, the coating that the present invention provides
Also having good application property, the gloss of spraying application is stable.The most appropriate acetylbutyrylcellulose and polyurethane propylene
Acid esters coordinates, and can be effectively improved the hardness of re-coating layer.
Further, described monomer is trimethylolpropane trimethacrylate；Described acrylate oligomer is saturated official
Energy base acrylate, its degree of functionality is 0 ~ 2.
Trimethylolpropane trimethacrylate molecular formula is (CH2=CHCOOCH2)3-CCH2CH3, it is mainly used in photocuring and is coated with
The aspects such as material, light-curable ink, photoresist, flexible printing product, solder resist, resist, paint, polymer modification, in the present invention
Middle as monomer existence, can be selected for any one prior art and realize, such as the EM231 in Changxing.Trimethylolpropane trimethacrylate
Jointly act on saturated functional group's acrylate that degree of functionality is 0 ~ 2, the coating of cured dope layer and recoating can be improved
The bond strength of layer, one is cured, and the dope layer of recoating is not easily stripped or comes off.
Further, described levelling agent is alkyl aralkyl silicone oil.
Described alkyl aralkyl silicone oil (aralkyl modified poly-methyl alkyl siloxane) also known as: C12 alkyl aralkyl changes
Property polydimethylsiloxane, can be selected for any one prior art realize.
Preferably, one during described solvent is white spirit, acetone, toluene, butyl acetate, propylene glycol methyl ether acetate or
Multiple.
Described white spirit is again chemical industry light oil, is the lightweight for industrial chemicals produced with crude oil or other Raw material processings
Oil, is mainly used as reforming and industrial chemicals.Described white spirit, acetone, toluene, butyl acetate, propylene glycol methyl ether acetate are equal
Can be selected for any one prior art to realize.
Preferably, described light trigger includes alpha-alcohol ketone.
Described alpha-alcohol ketone can be any one alpha-alcohol ketone.
Preferably, described light trigger also includes that quality is the benzimidazole of described alpha-alcohol ketone 0.11 times, the neighbour of 0.3 times
Phenylenediamine, the formic acid of 2 times and the trimethyl-phosphine of 0.7 times.
Described benzimidazole is a kind of chemical substance, and molecular formula is C7H6N2.Described o-phenylenediamine, is colourless list under room temperature
Oblique Crystal, darkens in air and daylight.It is slightly soluble in cold water, is dissolved in hot water, be soluble in ethanol, ether and chloroform.With nothing
Machine acid effect generates salt soluble in water.It it is the intermediate of dyestuff, pesticide, auxiliary agent, sensitive material etc..It itself it is dyestuff skin
The yellowish-brown M of hair.For manufacturing polyamide, polyurethane, carbendazim and thiophanate, vat scarlet GG, levelling agent, antioxidant MB, also use
In preparing developing agent, surfactant (surfactant) etc..Described trimethyl-phosphine chemical formula (CH3)3P, the alkyl that volume is minimum
Phosphine, has the symmetry of height and excellent spectral signature.In the present invention, o-phenylenediamine and benzimidazole synergistic, can be effective
Improve the smoothness of coating, reduce its skin-friction coefficient.Meanwhile, trimethyl-phosphine also contributes to the ageing resistance of coating
Can, it is allowed to be difficult to peel off because of aging, come off.
The present invention also provides for the using method of a kind of described UV radiation curable coating recoated, and comprises the steps:
The described UV radiation curable coating recoated is coated on plastic basis material；Levelling 1 ~ 2 minute, allows film fully sprawl, smooth
After, preheating 3 ~ 5 minutes under infrared lamp, preheating temperature is 50 DEG C ~ 60 DEG C, more UV radiation curing with UV, light radiation
Energy is 600 ~ 800mJ/cm2；The coating thickness of coating is 10-15 μm.
The present invention is directed to the above-mentioned characteristic recoating UV radiation curable coating, especially its construction technology etc. has been carried out excellent
Change, it is ensured that the dope layer that recoating obtains has higher hardness and adhesive force.
Described infrared lamps etc. all can be selected for prior art and realize.
Detailed description of the invention
The present invention is described in further detail below in conjunction with embodiment for the ease of it will be appreciated by those skilled in the art that:
Embodiment 1
The present embodiment provides a kind of UV radiation curable coating recoated, and its raw material includes by weight:
Monomer 2 parts；
Acrylate oligomer 3 parts；
Acetylbutyrylcellulose 4 parts；
Modification acrylate 7 parts；
Urethane acrylate 20 parts；
Levelling agent 0.7 part；
Light trigger 2 parts；
Solvent 60 parts.
Further, monomer described in this enforcement is trimethylolpropane trimethacrylate；Described acrylate oligomer
For Changxing chemistry 6071.
Further, described levelling agent is alkyl aralkyl silicone oil, China auxiliary agent HX3130 of preferable China chemical industry.
Further, mixing during described solvent is white spirit, acetone, toluene, butyl acetate, propylene glycol methyl ether acetate
Close.Mixed proportion is 2:1:1:1:1.
Preferably, described light trigger includes alpha-alcohol ketone.
Preferably, described light trigger also includes that quality is the benzimidazole of described alpha-alcohol ketone 0.11 times, the neighbour of 0.3 times
Phenylenediamine, the formic acid of 2 times and the trimethyl-phosphine of 0.7 times.
Embodiment 2
The present embodiment provides a kind of UV radiation curable coating recoated, and its raw material includes by weight:
Monomer 3 parts；
Acrylate oligomer 2 parts；
Acetylbutyrylcellulose 5 parts；
Modification acrylate 5 parts；
Urethane acrylate 30 parts；
Levelling agent 0.1 part；
Light trigger 3 parts；
Solvent 50 parts.
Further, described monomer is trimethylolpropane trimethacrylate；Described acrylate oligomer is long Xinghua
6070 learned.
Further, described levelling agent is alkyl aralkyl silicone oil.
Further, mixing during described solvent is white spirit, acetone, toluene, butyl acetate, propylene glycol methyl ether acetate
Close.Mass ratio is 2:1:0.9:0.8:1.2.
Preferably, described light trigger includes alpha-alcohol ketone.In the present embodiment, alpha-alcohol ketone selects BASF AG
184 products realize.
Preferably, described light trigger also includes that quality is the benzimidazole of described alpha-alcohol ketone 0.11 times, the neighbour of 0.3 times
Phenylenediamine, the formic acid of 2 times and the trimethyl-phosphine of 0.7 times.
Embodiment 3
The present embodiment provides a kind of UV radiation curable coating recoated, and its raw material includes by weight:
Monomer 1 part；
Acrylate oligomer 5 parts；
Acetylbutyrylcellulose 2 parts；
Modification acrylate 10 parts；
Urethane acrylate 10 parts；
Levelling agent 1 part；
Light trigger 1 part；
Solvent 80 parts.
Further, described monomer is trimethylolpropane trimethacrylate；Described acrylate oligomer is long Xinghua
6072 learned.
Further, described levelling agent is alkyl aralkyl silicone oil.
Further, mixing during described solvent is white spirit, acetone, toluene, butyl acetate, propylene glycol methyl ether acetate
Close.Mixing ratio is 1.5:0.7:1:0.9:1
Preferably, described light trigger includes alpha-alcohol ketone.
Preferably, described light trigger also includes that quality is the benzimidazole of described alpha-alcohol ketone 0.11 times, the neighbour of 0.3 times
Phenylenediamine, the formic acid of 2 times and the trimethyl-phosphine of 0.7 times.
Embodiment 4
The present embodiment provides a kind of UV radiation curable coating recoated, and its raw material includes by weight:
Monomer 2.5 parts；
Acrylate oligomer 4 parts；
Acetylbutyrylcellulose 3 parts；
Modification acrylate 8 parts；
Urethane acrylate 15 parts；
Levelling agent 0.4 part；
Light trigger 2 parts；
Solvent 65 parts.
Further, described monomer is trimethylolpropane trimethacrylate；Described acrylate oligomer is special official
Can base acrylate.
Further, described levelling agent is alkyl aralkyl silicone oil.
Further, mixing during described solvent is white spirit, acetone, toluene, butyl acetate, propylene glycol methyl ether acetate
Close.Mass ratio is 2:0.9:1.3:0.7:1
Preferably, described light trigger includes alpha-alcohol ketone.
Preferably, described light trigger also includes that quality is the benzimidazole of described alpha-alcohol ketone 0.11 times, the neighbour of 0.3 times
Phenylenediamine, the formic acid of 2 times and the trimethyl-phosphine of 0.7 times.
Embodiment 5
The present embodiment provides a kind of UV radiation curable coating recoated, and its raw material includes by weight:
Monomer 3 parts；
Acrylate oligomer 3 parts；
Acetylbutyrylcellulose 3 parts；
Modification acrylate 9 parts；
Urethane acrylate 12 parts；
Levelling agent 0.2 part；
Light trigger 1.5 parts；
Solvent 55 parts.
Further, described monomer is trimethylolpropane trimethacrylate；Described acrylate oligomer is special official
Can base acrylate.
Further, described levelling agent is alkyl aralkyl silicone oil.
Further, the mixing during described solvent is white spirit, acetone, butyl acetate, propylene glycol methyl ether acetate.Matter
Amount ratio is 2:1:1:1
Preferably, described light trigger includes alpha-alcohol ketone.
Embodiment 6
The present embodiment provides a kind of UV radiation curable coating recoated, and its raw material includes by weight:
Monomer 2 parts；
Acrylate oligomer 3 parts；
Acetylbutyrylcellulose 4 parts；
Modification acrylate 7 parts；
Urethane acrylate 20 parts；
Levelling agent 0.7 part；
Light trigger 2 parts；
Solvent 60 parts.
Further, monomer described in this enforcement is trimethylolpropane trimethacrylate；Described acrylate oligomer
For Changxing chemistry 6071.
Further, described levelling agent is alkyl aralkyl silicone oil, China auxiliary agent HX3130 of preferable China chemical industry.
Further, mixing during described solvent is white spirit, acetone, toluene, butyl acetate, propylene glycol methyl ether acetate
Close.Mixed proportion is 2:1:1:1:1.
Preferably, described light trigger includes alpha-alcohol ketone.
Preferably, described light trigger also includes that quality is the benzimidazole of described alpha-alcohol ketone 0.11 times, the formic acid of 2 times
And the trimethyl-phosphine of 0.7 times.
Embodiment 7
The present embodiment provides a kind of UV radiation curable coating recoated, and its raw material includes by weight:
Monomer 2 parts；
Acrylate oligomer 3 parts；
Acetylbutyrylcellulose 4 parts；
Modification acrylate 7 parts；
Urethane acrylate 20 parts；
Levelling agent 0.7 part；
Light trigger 2 parts；
Solvent 60 parts.
Further, monomer described in this enforcement is trimethylolpropane trimethacrylate；Described acrylate oligomer
For Changxing chemistry 6071.
Further, described levelling agent is alkyl aralkyl silicone oil, China auxiliary agent HX3130 of preferable China chemical industry.
Further, mixing during described solvent is white spirit, acetone, toluene, butyl acetate, propylene glycol methyl ether acetate
Close.Mixed proportion is 2:1:1:1:1.
Preferably, described light trigger includes alpha-alcohol ketone.
Preferably, described light trigger also includes that quality is the o-phenylenediamine of described alpha-alcohol ketone 0.3 times, the formic acid of 2 times.
Comparative example 1
This comparative example provides a kind of UV radiation curable coating recoated, and its raw material includes by weight:
Monomer 2 parts；
Acrylate oligomer 3 parts；
Modification acrylate 7 parts；
Urethane acrylate 20 parts；
Levelling agent 0.7 part；
Light trigger 2 parts；
Solvent 60 parts.
Further, monomer described in this enforcement is trimethylolpropane trimethacrylate；Described acrylate oligomer
For Changxing chemistry 6071.
Further, described levelling agent is alkyl aralkyl silicone oil, China auxiliary agent HX3130 of preferable China chemical industry.
Further, mixing during described solvent is white spirit, acetone, toluene, butyl acetate, propylene glycol methyl ether acetate
Close.Mixed proportion is 2:1:1:1:1.
Preferably, described light trigger includes alpha-alcohol ketone.
Comparative example 2
This comparative example provides a kind of UV radiation curable coating recoated, and its raw material includes by weight:
Monomer 2 parts；
Acrylate oligomer 3 parts；
Acetylbutyrylcellulose 4 parts；
Modification acrylate 7 parts；
Urethane acrylate 20 parts；
Levelling agent 0.7 part；
Light trigger 2 parts；
Solvent 60 parts.
Further, monomer described in this enforcement is methyl methacrylate；Described acrylate oligomer is long Xinghua
6071 learned.
Further, described levelling agent is alkyl aralkyl silicone oil, China auxiliary agent HX3130 of preferable China chemical industry.
Further, mixing during described solvent is white spirit, acetone, toluene, butyl acetate, propylene glycol methyl ether acetate
Close.Mixed proportion is 2:1:1:1:1.
Preferably, described light trigger includes alpha-alcohol ketone.
The sample A1-A7 preparing embodiment 1-7, comparative example 1-2 is prepared into sample B1-B2, is coated with by sample
On plastic basis material；Levelling 1 ~ 2 minute, allow film fully sprawl, smooth after, under infrared lamp preheat 3 ~ 5 minutes, preheating
Temperature is 50 DEG C ~ 60 DEG C, then (80w/cm2, high voltage mercury lamp N prop up, and lamp, away from workpiece 15cm, solidifies speed 10m/ with UV ultraviolet
Min) irradiating solidification, optical radiation energy is 600 ~ 800mJ/cm2；The coating thickness of coating is 10-15 μm.It is coated with after it is solidified
Material coating performance checks, checks result as shown in Table 1 and Table 2:
Table 1.
Table 2.
Testing the coefficient of kinetic friction and the specific wear amount (method ASTMD4060) of above-mentioned sample, its result is as shown in table 3.
Being more than the wherein specific implementation of the present invention, it describes more concrete and detailed, but can not therefore be interpreted as
Restriction to the scope of the claims of the present invention.It should be pointed out that, for the person of ordinary skill of the art, without departing from this
On the premise of bright design, it is also possible to make some deformation and improvement, these obvious alternative forms belong to the present invention's
Protection domain.
Claims (7)
1. the UV radiation curable coating that can recoat, its raw material includes by weight:
Monomer 1-3 part；
Acrylate oligomer 2-5 part；
Acetylbutyrylcellulose 2-5 part；
Modification acrylate 5-10 part；
Urethane acrylate 10-30 part；
Levelling agent 0.1-1 part；
Light trigger 1-3 part；
Solvent 50-80 part.
The UV radiation curable coating recoated the most according to claim 1, it is characterised in that: described monomer is trihydroxy methyl
Propane triacrylate；Described acrylate oligomer is saturated functional group's acrylate, and its degree of functionality is 0 ~ 2.
The UV radiation curable coating recoated the most according to claim 2, it is characterised in that: described levelling agent is alkyl virtue
Alkyl-silicone oil.
4. according to the UV radiation curable coating recoated described in any one of claim 1-3, it is characterised in that: described solvent is
One or more in white spirit, acetone, toluene, butyl acetate, propylene glycol methyl ether acetate.
5. according to the UV radiation curable coating recoated described in any one of claim 1-3, it is characterised in that: described light-initiated
Agent includes alpha-alcohol ketone.
The UV radiation curable coating recoated the most according to claim 5, it is characterised in that: described light trigger also includes
Quality is the benzimidazole of described alpha-alcohol ketone 0.11 times, the o-phenylenediamine of 0.3 times, the formic acid of 2 times and the trimethyl of 0.7 times
Phosphine.
7. a using method for the UV radiation curable coating recoated as described in any one of claim 1-6, including as follows
Step: the described UV radiation curable coating recoated is coated on plastic basis material；Levelling 1 ~ 2 minute, allows film fully spread
Exhibition, smooth after, preheat 3 ~ 5 minutes under infrared lamp, preheating temperature is 50 DEG C ~ 60 DEG C, then irradiates admittedly with UV ultraviolet
Changing, optical radiation energy is 600 ~ 800mJ/cm2；The coating thickness of coating is 10-15 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610258931.0A CN106010211A (en) | 2016-04-25 | 2016-04-25 | UV radiation curable coating capable of recoating and use method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610258931.0A CN106010211A (en) | 2016-04-25 | 2016-04-25 | UV radiation curable coating capable of recoating and use method thereof |
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| CN106010211A true CN106010211A (en) | 2016-10-12 |
Family
ID=57081199
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| CN201610258931.0A Pending CN106010211A (en) | 2016-04-25 | 2016-04-25 | UV radiation curable coating capable of recoating and use method thereof |
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Cited By (2)
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| CN106675219A (en) * | 2016-12-25 | 2017-05-17 | 合肥乐凯科技产业有限公司 | Transparent hardening composition, TAC glasses film and preparation method of TAC glasses film |
| CN106750274A (en) * | 2016-11-25 | 2017-05-31 | 上海展辰涂料有限公司 | A kind of non-isocyanate polyurethane |
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| CN106750274A (en) * | 2016-11-25 | 2017-05-31 | 上海展辰涂料有限公司 | A kind of non-isocyanate polyurethane |
| CN106675219A (en) * | 2016-12-25 | 2017-05-17 | 合肥乐凯科技产业有限公司 | Transparent hardening composition, TAC glasses film and preparation method of TAC glasses film |
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Application publication date: 20161012 |