CN103205146A - Ultraviolet-curable PET film surface treatment bottom sizing agent and preparing method and application thereof - Google Patents
Ultraviolet-curable PET film surface treatment bottom sizing agent and preparing method and application thereof Download PDFInfo
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- CN103205146A CN103205146A CN2013101025393A CN201310102539A CN103205146A CN 103205146 A CN103205146 A CN 103205146A CN 2013101025393 A CN2013101025393 A CN 2013101025393A CN 201310102539 A CN201310102539 A CN 201310102539A CN 103205146 A CN103205146 A CN 103205146A
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Abstract
The present invention discloses an ultraviolet-curable PET film surface treatment bottom sizing agent and a preparing method and an application thereof. The ultraviolet-curable PET film surface treatment bottom sizing agent is characterized by comprising, based on the mass percentage of 100%, 45% -55% of difunctional aliphatic carbamate-acrylate oligomers; 15% -20% of a trifunctional reactive diluent of trihydroxymethylpropyl trimethylacrylate; 15% -20% of a bifunctional reactive diluent of tripropylene glycol diacrylate; 1.5%-2.5% of a photo initiator of 2-hydroxy-2-methyl -1-phenyl acetone; 1.5% -2.5% of a photo initiator of 1-hydroxy cyclohexyl phenyl ketone and 5% -15% of ethyl acetate. The ultraviolet-curable PET film surface treatment bottom sizing agent of the invention can be applied to PET decoration materials, label materials and PET protective film surface treatment, and can improve adhesive force of UV ink and coatings.
Description
Technical field
The invention belongs to environmentally friendly coated material technical field, be specifically related to a kind of ultraviolet curing type PET film surface treatment silane coupling agent and its preparation method and application.
Background technology
PET film good heat resistance, transparency and intensity height are not easy to stretch, and tension control requires lower than other films, uses more and more widely in fields such as label, thin film switch, protective membranes.Because the PET macromolecular chain structure is regular, degree of crystallinity is higher, so its surperficial affinity, printing and printing ink attachment fastness are relatively poor.UV coating, the general weather resistance of UV printing ink, solvent resistance are good, has the environmental protection and energy saving feature, share of market improves constantly in recent years, and is generally undesirable but this class has printing ink, coating sticking power on the PET film of good durability, often is difficult to reach application requiring.Improving UV coating and printing ink sticking power on the PET film is a difficult problem of running in covering with paint or the printing practice.
PET film surface treatment method commonly used has corona method and coating.Corona method has ageing, and treatment effect can produce decay in various degree with the difference of storage environment humiture and shelf-time, and in addition to UV printing ink, coating, even through corona, attachment fastness is still not ideal enough usually.The advantage of coating is that film surface tension force can be along with storage environment temperature and shelf-time and decay.The pet sheet face is handled coating, and at first needing itself has powerful sticking power with the PET film, and gloss oil, the printing ink with surface printing has good ply adhesion simultaneously, and undercoat itself is also answered good durability, solvent resistance in addition.Present existing PET film surface treatment silane coupling agent, mainly contain solvent borne polyurethane, solvent-borne type saturated polyester resin class two classes, be generally two component thermoset silane coupling agents, it is no problem to the sticking power of PET material own, the deficiency that exists mainly contains: the one, and to part UV printing ink, UV coating, still very poor to hardness bigger UV printing ink, paint adhesion with high functionality epoxy-modified acrylic acid oligopolymer or the preparation of high-functionality polyurethane modified propylene acid oligomer especially; The 2nd, the existing silane coupling agent heated drying time is long, and energy consumption is big, and general coating machinery is difficult to adapt to; The 3rd, existing silane coupling agent constructing operation discharges a large amount of volatile organic matters (VOC).
For overcoming the currently available products deficiency, need that further exploitation is UV coating, ink adhesion better effects if, that suitability is wider to improving, dry solidification PET film surface treatment silane coupling agent easily.
Summary of the invention
The purpose of this invention is to provide ultraviolet curing type PET film surface treatment silane coupling agent a kind of ultraviolet curing type, that adaptability is extensive and its preparation method and application.Ultraviolet curing type PET film surface treatment silane coupling agent of the present invention can be applicable to PET finishing material, label material, the surface treatment of PET protective membrane, is used for improving UV printing ink, paint adhesion.
Ultraviolet curing type PET film surface treatment silane coupling agent of the present invention is characterized in that, by massfraction 100%, comprising:
A) two functionality aliphatic carbamate-acrylate type oligopolymer 45%～55%;
B) trifunctional reactive thinner Viscoat 295 (TMPTA) 15%～20%
C) bifunctional reactive thinner tripropylene glycol diacrylate (TPGDA) 15%～20%;
D) light trigger 2-hydroxy-2-methyl-1-phenyl-acetone (Switzerland Ciba Dorocure-1173) 1.5%～2.5%;
F) light trigger 1-hydroxy cyclohexyl phenylketone (Switzerland Ciba Irgacure-184) 1.5%～2.5%
G) ethyl acetate 5%～15%.
Preferably, described ultraviolet curing type PET film surface treatment silane coupling agent by massfraction 100%, comprising:
Two functionality aliphatic carbamate-acrylate type oligopolymer 45%;
Trifunctional reactive thinner Viscoat 295 20%;
Bifunctional reactive thinner tripropylene glycol diacrylate 20%;
Light trigger 2-hydroxy-2-methyl-1-phenyl-acetone 1.5%;
Light trigger 1-hydroxy cyclohexyl phenylketone 2.5%;
Ethyl acetate 11%.
The preparation method of ultraviolet curing type PET film surface treatment silane coupling agent of the present invention is: with two functionality aliphatic carbamate-acrylate type oligopolymer, trifunctional reactive thinner Viscoat 295, bifunctional reactive thinner tripropylene glycol diacrylate, light trigger 2-hydroxy-2-methyl-1-phenyl-acetone and light trigger 1-hydroxy cyclohexyl phenylketone, mix according to proportioning, as add barrel, disperse 3min under the 800rpm, and then add ethyl acetate and regulate viscosity 20-25 second/be coated with-4 glasss, stir, as stir 1min, be ultraviolet curing type PET film surface treatment silane coupling agent after the filtration.
The using method of ultraviolet curing type PET film surface treatment silane coupling agent of the present invention is: adopt line rod spreader, ultraviolet curing type PET film surface treatment silane coupling agent evenly is coated on the PET film, 80 ℃ are dried by the fire 20-30 second down, under UV cure lamp, carry out UV then and solidify condition of cure 1500-2000mJ/cm
2, make PET photocuring undercoat.Ultraviolet curing type PET film surface treatment silane coupling agent was placed 7 days after handling and solidifying, and applied UV gloss oil, coating or UV printing ink again and got final product.
Two functionality aliphatic carbamate of the present invention-acrylate type oligopolymer is the aliphatic carbamate modification, and origoester acrylate has two functionality, belongs to material of the prior art.
Ultraviolet curing type PET film surface treatment silane coupling agent of the present invention is than silane coupling agent of the prior art, and it has following beneficial effect:
(a) ultraviolet curing type PET film surface treatment silane coupling agent of the present invention can be used for PET label material, finishing material, protective membrane surface treatment, can effectively improve UV printing ink, paint adhesion.
(b) ultraviolet curing type PET film surface treatment silane coupling agent of the present invention, its dry solidification time is short, energy efficient.Ultraviolet curing type PET film surface treatment silane coupling agent of the present invention, it only contains the amount of ethyl acetate solvent, compares with the solvent-borne type silane coupling agent, and the quantity of solvent of coating process volatilization is little, is environment-friendly type coating.
Embodiment:
Following examples are to further specify of the present invention, rather than limitation of the present invention.
Two functionality aliphatic carbamate-acrylate type oligopolymer in following examples is available from the diligent Industry Co.,Ltd of power, name of product: two functionality aliphatic carbamate-acrylate type oligopolymer, model: UA1239.
Embodiment 1
A) ultraviolet curing type PET film surface treatment silane coupling agent prescription (weight ratio)
Two functionality aliphatic carbamate-acrylate type oligopolymer: 500 grams;
Trifunctional reactive thinner Viscoat 295 (TMPTA): 200 grams;
Bifunctional reactive thinner tripropylene glycol diacrylate (TPGDA): 150 grams;
Light trigger 2-hydroxy-2-methyl-1-phenyl-acetone (Switzerland Ciba Dorocure-1173): 25 grams;
Light trigger 1-hydroxy cyclohexyl phenylketone (Switzerland Ciba Irgacure-184): 15 grams;
Ethyl acetate: 110 grams;
Add up to 1000 grams.
B) preparation and the application method of ultraviolet curing type PET film surface treatment silane coupling agent:
With two functionality aliphatic carbamate-acrylate type oligopolymer, reactive thinner (TMPTA, TPGDA), light trigger (Dorocure-1173, Irgacure-184), by above proportioning weighing, add barrel, disperse 3min under the 800rpm, add ethyl acetate again and regulate viscosity, stir 1min, be ultraviolet curing type PET film surface treatment silane coupling agent after the filtration.Ultraviolet curing type PET film surface treatment silane coupling agent viscosity 21 seconds/be coated with-4 glasss.Adopt line rod spreader, ultraviolet curing type PET film surface treatment silane coupling agent evenly is coated on the PET film of corona treatment, 80 ℃ of bakings 30 seconds are down carried out UV then and are solidified condition of cure 2000mJ/cm under UV cure lamp
2, make PET photocuring undercoat.PET photocuring undercoat is placed after 7 days after solidifying, and applies UV gloss oil (be varnish, the good good omen chemical industry in Shenzhen company limited provides, and model HCT902 is by the preparation of high-functionality polyurethane modified propylene acid oligomer).
C) effect of ultraviolet curing type PET film surface treatment silane coupling agent
The effect of embodiment 1 sees Table 1.
The implementation result of table 1: embodiment 1
(contrast of table empty is PET corona film; Sticking power is tested by the GB9286-1998 standard in the table; Hardness is tested by the GB/T6739-2006 standard; Anti-solvent wiping is tested by the GB/T23989-2009 standard.）
As seen from Table 1, the PET film brings up to 95% to the sticking power of HCT902 gloss oil from 60% after ultraviolet curing type PET film surface treatment silane coupling agent of the present invention is handled, can satisfy application request.
Embodiment 2
A) ultraviolet curing type PET film surface treatment silane coupling agent prescription (weight ratio)
Two functionality aliphatic carbamate-acrylate type oligopolymer: 450 grams;
Trifunctional reactive thinner (Viscoat 295 (TMPTA): 200 grams;
Bifunctional reactive thinner tripropylene glycol diacrylate (TPGDA): 200 grams;
Light trigger 2-hydroxy-2-methyl-1-phenyl-acetone (Switzerland Ciba Dorocure-1173): 15 grams;
Light trigger 1-hydroxy cyclohexyl phenylketone (Switzerland Ciba Irgacure-184): 25 grams;
Ethyl acetate: 110 grams;
Add up to 1000 grams.
B) preparation and the application method of ultraviolet curing type PET film surface treatment silane coupling agent:
With two functionality aliphatic carbamate-acrylate type oligopolymer, reactive thinner (TMPTA, TPGDA), light trigger (Dorocure-1173, Irgacure-184), by above proportioning weighing, add barrel, disperse 3min under the 800rpm, add ethyl acetate again and regulate viscosity, stir 1min, be ultraviolet curing type PET film surface treatment silane coupling agent after the filtration.Ultraviolet curing type PET film surface treatment silane coupling agent viscosity 20 seconds/be coated with-4 glasss.Adopt line rod spreader, ultraviolet curing type PET film surface treatment silane coupling agent evenly is coated on the PET film of corona treatment, 80 ℃ of bakings 30 seconds are down carried out UV then and are solidified condition of cure 2000mJ/cm under UV cure lamp
2, make PET photocuring undercoat.PET photocuring undercoat is placed after 7 days after solidifying, and applies UV gloss oil (be varnish, company limited provides model HCT903 by the good good omen chemical industry in Shenzhen, prepares the UV gloss oil by high-functionality polyurethane modified propylene acid oligomer).
C) effect of ultraviolet curing type PET film surface treatment silane coupling agent
The effect of embodiment 2 sees Table 2.
The implementation result of table 2: embodiment 2
(contrast of table empty is PET corona film; Sticking power is tested by the GB9286-1998 standard in the table; Hardness is tested by the GB/T6739-2006 standard; Anti-solvent wiping is tested by the GB/T23989-2009 standard.）
As seen from Table 2, the PET film brings up to 100% to the sticking power of HCT903 gloss oil from 50% after the ultraviolet curing type PET of present embodiment film surface treatment silane coupling agent is handled, can satisfy application request.
Embodiment 3
A) ultraviolet curing type PET film surface treatment silane coupling agent prescription (weight ratio)
Two functionality aliphatic carbamate-acrylate type oligopolymer: 550 grams;
Trifunctional reactive thinner (Viscoat 295 (TMPTA): 150 grams;
Bifunctional reactive thinner tripropylene glycol diacrylate (TPGDA): 200 grams;
Light trigger 2-hydroxy-2-methyl-1-phenyl-acetone (Switzerland Ciba Dorocure-1173): 20 grams;
Light trigger 1-hydroxy cyclohexyl phenylketone (Switzerland Ciba Irgacure-184): 15 grams;
Ethyl acetate: 65 grams;
Add up to 1000 grams.
B) preparation and the application method of ultraviolet curing type PET film surface treatment silane coupling agent:
With two functionality aliphatic carbamate-acrylate type oligopolymer, reactive thinner (TMPTA, TPGDA), light trigger (Dorocure-1173, Irgacure-184), by above proportioning weighing, add barrel, disperse 3min under the 800rpm, add ethyl acetate again and regulate viscosity, stir 1min, be ultraviolet curing type PET film surface treatment silane coupling agent after the filtration.Ultraviolet curing type PET film surface treatment silane coupling agent viscosity 25 seconds/be coated with-4 glasss.Adopt line rod spreader, ultraviolet curing type PET film surface treatment silane coupling agent evenly is coated on the PET film of corona treatment, 80 ℃ of bakings 30 seconds are down carried out UV then and are solidified condition of cure 2000mJ/cm under UV cure lamp
2, make PET photocuring undercoat.PET photocuring undercoat is placed after 7 days printing UV printing ink (UV ink types UB-2 is provided by Japanese Jujo Chemical Co, Ltd.) after solidifying.
C) effect of ultraviolet curing type PET film surface treatment silane coupling agent
The effect of embodiment 3 sees Table 3.
The implementation result of table 3: embodiment 3
(contrast of table empty is PET corona film; Sticking power is tested by the GB9286-1998 standard in the table; Hardness is tested by the GB/T6739-2006 standard; Anti-solvent wiping is tested by the GB/T23989-2009 standard.）
As seen from Table 3, the PET film brings up to 98% to the sticking power of UB-2 printing ink from 30% after the ultraviolet curing type PET of present embodiment film surface treatment silane coupling agent is handled, can satisfy application request.
Embodiment 4
A) ultraviolet curing type PET film surface treatment silane coupling agent prescription (weight ratio)
Two functionality aliphatic carbamate-acrylate type oligopolymer: 500 grams;
Trifunctional reactive thinner Viscoat 295 (TMPTA): 160 grams;
Bifunctional reactive thinner tripropylene glycol diacrylate (TPGDA): 150 grams;
Light trigger 2-hydroxy-2-methyl-1-phenyl-acetone (Switzerland Ciba Dorocure-1173): 25 grams;
Light trigger 1-hydroxy cyclohexyl phenylketone (Switzerland Ciba Irgacure-184): 15 grams;
Ethyl acetate: 150 grams;
Add up to 1000 grams.
B) preparation and the application method of ultraviolet curing type PET film surface treatment silane coupling agent:
With two functionality aliphatic carbamate-acrylate type oligopolymer, reactive thinner (TMPTA, TPGDA), light trigger (Dorocure-1173, Irgacure-184), by above proportioning weighing, add barrel, disperse 3min under the 800rpm, add ethyl acetate again and regulate viscosity, stir 1min, be ultraviolet curing type PET film surface treatment silane coupling agent after the filtration.Ultraviolet curing type PET film surface treatment silane coupling agent viscosity 21 seconds/be coated with-4 glasss.Adopt line rod spreader, ultraviolet curing type PET film surface treatment silane coupling agent evenly is coated on the PET film of corona treatment, 80 ℃ of bakings 20 seconds are down carried out UV then and are solidified condition of cure 1500mJ/cm under UV cure lamp
2, make PET photocuring undercoat.PET photocuring undercoat is placed after 7 days after solidifying, and applies UV gloss oil (be varnish, the good good omen chemical industry in Shenzhen company limited provides, and model HCT902 is by the preparation of high-functionality polyurethane modified propylene acid oligomer).
C) effect of ultraviolet curing type PET film surface treatment silane coupling agent
The effect of embodiment 4 sees Table 4.
The implementation result of table 4: embodiment 4
(contrast of table empty is PET corona film; Sticking power is tested by the GB9286-1998 standard in the table; Hardness is tested by the GB/T6739-2006 standard; Anti-solvent wiping is tested by the GB/T23989-2009 standard.）
As seen from Table 4, the PET film brings up to 98% to the sticking power of HCT902 gloss oil from 50% after ultraviolet curing type PET film surface treatment silane coupling agent of the present invention is handled, can satisfy application request.
Embodiment 5
A) ultraviolet curing type PET film surface treatment silane coupling agent prescription (weight ratio)
Two functionality aliphatic carbamate-acrylate type oligopolymer: 550 grams;
Trifunctional reactive thinner Viscoat 295 (TMPTA): 160 grams;
Bifunctional reactive thinner tripropylene glycol diacrylate (TPGDA): 200 grams;
Light trigger 2-hydroxy-2-methyl-1-phenyl-acetone (Switzerland Ciba Dorocure-1173): 25 grams;
Light trigger 1-hydroxy cyclohexyl phenylketone (Switzerland Ciba Irgacure-184): 15 grams;
Ethyl acetate: 50 grams;
Add up to 1000 grams.
B) preparation and the application method of ultraviolet curing type PET film surface treatment silane coupling agent:
With two functionality aliphatic carbamate-acrylate type oligopolymer, reactive thinner (TMPTA, TPGDA), light trigger (Dorocure-1173, Irgacure-184), by above proportioning weighing, add barrel, disperse 3min under the 800rpm, add ethyl acetate again and regulate viscosity, stir 1min, be ultraviolet curing type PET film surface treatment silane coupling agent after the filtration.Ultraviolet curing type PET film surface treatment silane coupling agent viscosity 21 seconds/be coated with-4 glasss.Adopt line rod spreader, ultraviolet curing type PET film surface treatment silane coupling agent evenly is coated on the PET film of corona treatment, 80 ℃ of bakings 20 seconds are down carried out UV then and are solidified condition of cure 1500mJ/cm under UV cure lamp
2, make PET photocuring undercoat.PET photocuring undercoat is placed after 7 days after solidifying, coating UV gloss oil (be varnish, the good good omen chemical industry in Shenzhen company limited provides, model HCT902,
By the preparation of high-functionality polyurethane modified propylene acid oligomer).
C) effect of ultraviolet curing type PET film surface treatment silane coupling agent
The effect of embodiment 5 sees Table 5.
The implementation result of table 5: embodiment 5
(contrast of table empty is PET corona film; Sticking power is tested by the GB9286-1998 standard in the table; Hardness is tested by the GB/T6739-2006 standard; Anti-solvent wiping is tested by the GB/T23989-2009 standard.）
As seen from Table 5, the PET film brings up to 95% to the sticking power of HCT902 gloss oil from 60% after ultraviolet curing type PET film surface treatment silane coupling agent of the present invention is handled, can satisfy application request.
Claims (4)
1. a ultraviolet curing type PET film surface treatment silane coupling agent is characterized in that, by massfraction 100%, comprising:
A) two functionality aliphatic carbamate-acrylate type oligopolymer 45%～55%;
B) trifunctional reactive thinner Viscoat 295 15%～20%
C) bifunctional reactive thinner tripropylene glycol diacrylate 15%～20%;
D) light trigger 2-hydroxy-2-methyl-1-phenyl-acetone 1.5%～2.5%;
F) light trigger 1-hydroxy cyclohexyl phenylketone 1.5%～2.5%;
G) ethyl acetate 5%～15%.
2. ultraviolet curing type PET film surface treatment silane coupling agent according to claim 1 is characterized in that, by massfraction 100%, comprising:
Two functionality aliphatic carbamate-acrylate type oligopolymer 45%;
Trifunctional reactive thinner Viscoat 295 20%;
Bifunctional reactive thinner tripropylene glycol diacrylate 20%;
Light trigger 2-hydroxy-2-methyl-1-phenyl-acetone 1.5%;
Light trigger 1-hydroxy cyclohexyl phenylketone 2.5%;
Ethyl acetate 11%.
3. the preparation method of the described ultraviolet curing type PET of claim 1 a film surface treatment silane coupling agent, it is characterized in that, with two functionality aliphatic carbamate-acrylate type oligopolymer, trifunctional reactive thinner Viscoat 295, bifunctional reactive thinner tripropylene glycol diacrylate, light trigger 2-hydroxy-2-methyl-1-phenyl-acetone and light trigger 1-hydroxy cyclohexyl phenylketone, mix according to proportioning, and then add ethyl acetate and regulate viscosity 20-25 second/be coated with-4 glasss, stir, be ultraviolet curing type PET film surface treatment silane coupling agent after the filtration.
4. the using method of the described ultraviolet curing type PET of claim 1 a film surface treatment silane coupling agent, it is characterized in that, adopt line rod spreader, the described ultraviolet curing type PET of claim 1 film surface treatment silane coupling agent evenly is coated on the PET film, 80 ℃ are dried by the fire 20-30 second down, under UV cure lamp, carry out UV then and solidify condition of cure 1500-2000mJ/cm
2, make PET photocuring undercoat.
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| CN105882172A (en) * | 2016-05-10 | 2016-08-24 | 深圳市睿同科技有限公司 | Novel flexographic printing method |
| CN107523207A (en) * | 2017-08-31 | 2017-12-29 | 安徽骏飞标识设计制作有限公司 | Suitable for feature primary coat, its preparation method and the application method of UV printings |
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| CN103408782A (en) * | 2013-08-05 | 2013-11-27 | 江苏华信塑业发展有限公司 | Exclusive digital printing sheet base material and preparation method thereof |
| CN105882172A (en) * | 2016-05-10 | 2016-08-24 | 深圳市睿同科技有限公司 | Novel flexographic printing method |
| CN108070299A (en) * | 2017-06-30 | 2018-05-25 | 施莹莺 | For the functional ink and preparation method and application of inkjet printing |
| CN107523207A (en) * | 2017-08-31 | 2017-12-29 | 安徽骏飞标识设计制作有限公司 | Suitable for feature primary coat, its preparation method and the application method of UV printings |
| WO2019095625A1 (en) * | 2017-11-15 | 2019-05-23 | 洛阳尖端技术研究院 | Ultraviolet curable ink and preparation method therefor |
| CN108250925A (en) * | 2017-12-20 | 2018-07-06 | 宁波激智科技股份有限公司 | A kind of silane coupling agent and preparation method thereof, a kind of polyester film and preparation method thereof |
| RU2718756C2 (en) * | 2018-09-28 | 2020-04-14 | Владислав Юрьевич Мирчев | Adhesive for jet printing and method for production thereof |
| CN109735221A (en) * | 2018-12-29 | 2019-05-10 | 中山市柏顿涂料有限公司 | A kind of priming paint and preparation method thereof with excellent UV ink adhesion |
| CN111423754A (en) * | 2020-04-29 | 2020-07-17 | 传美讯电子科技（珠海）有限公司 | Coating liquid for promoting UV ink adhesion and preparation method thereof |
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