CN104970017B - Components and formula of attractant of tomicus minor hartig - Google Patents
Components and formula of attractant of tomicus minor hartig Download PDFInfo
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- CN104970017B CN104970017B CN201410133308.3A CN201410133308A CN104970017B CN 104970017 B CN104970017 B CN 104970017B CN 201410133308 A CN201410133308 A CN 201410133308A CN 104970017 B CN104970017 B CN 104970017B
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- China
- Prior art keywords
- australene
- verbenol
- cis
- attractant
- myrcene
- Prior art date
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- 239000005667 attractant Substances 0.000 title claims abstract description 51
- 230000031902 chemoattractant activity Effects 0.000 title claims abstract description 49
- 241000546230 Tomicus minor Species 0.000 title abstract 4
- WONIGEXYPVIKFS-UHFFFAOYSA-N (+)-cis-Verbenol Natural products CC1=CC(O)C2C(C)(C)C1C2 WONIGEXYPVIKFS-UHFFFAOYSA-N 0.000 claims abstract description 77
- UAHWPYUMFXYFJY-UHFFFAOYSA-N beta-myrcene Chemical compound CC(C)=CCCC(=C)C=C UAHWPYUMFXYFJY-UHFFFAOYSA-N 0.000 claims abstract description 59
- WONIGEXYPVIKFS-YIZRAAEISA-N (1s,2s,5s)-4,6,6-trimethylbicyclo[3.1.1]hept-3-en-2-ol Chemical compound CC1=C[C@H](O)[C@@H]2C(C)(C)[C@H]1C2 WONIGEXYPVIKFS-YIZRAAEISA-N 0.000 claims abstract description 52
- VYBREYKSZAROCT-UHFFFAOYSA-N alpha-myrcene Natural products CC(=C)CCCC(=C)C=C VYBREYKSZAROCT-UHFFFAOYSA-N 0.000 claims abstract description 29
- RXBQNMWIQKOSCS-UHFFFAOYSA-N Myrthenol Natural products C1C2C(C)(C)C1CC=C2CO RXBQNMWIQKOSCS-UHFFFAOYSA-N 0.000 claims abstract description 25
- RXBQNMWIQKOSCS-IUCAKERBSA-N [(1s,5r)-6,6-dimethyl-4-bicyclo[3.1.1]hept-3-enyl]methanol Chemical compound C1[C@@H]2C(C)(C)[C@H]1CC=C2CO RXBQNMWIQKOSCS-IUCAKERBSA-N 0.000 claims abstract description 25
- WONIGEXYPVIKFS-VGMNWLOBSA-N (1r,2s,5r)-4,6,6-trimethylbicyclo[3.1.1]hept-3-en-2-ol Chemical compound CC1=C[C@H](O)[C@H]2C(C)(C)[C@@H]1C2 WONIGEXYPVIKFS-VGMNWLOBSA-N 0.000 claims abstract description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000005452 bending Methods 0.000 claims description 44
- 239000007787 solid Substances 0.000 claims description 20
- 150000001336 alkenes Chemical class 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 16
- 150000002085 enols Chemical class 0.000 claims description 5
- IRZWAJHUWGZMMT-UHFFFAOYSA-N Chrysanthenol Natural products CC1=CCC2C(C)(C)C1C2O IRZWAJHUWGZMMT-UHFFFAOYSA-N 0.000 claims 1
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 abstract description 20
- XMGQYMWWDOXHJM-SNVBAGLBSA-N (-)-α-limonene Chemical compound CC(=C)[C@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-SNVBAGLBSA-N 0.000 abstract description 20
- SLKPBCXNFNIJSV-HNNXBMFYSA-N Cuparene Chemical compound C1=CC(C)=CC=C1[C@@]1(C)C(C)(C)CCC1 SLKPBCXNFNIJSV-HNNXBMFYSA-N 0.000 abstract description 20
- YHQGMYUVUMAZJR-UHFFFAOYSA-N α-terpinene Chemical compound CC(C)C1=CC=C(C)CC1 YHQGMYUVUMAZJR-UHFFFAOYSA-N 0.000 abstract description 14
- 229940099369 (+)- limonene Drugs 0.000 abstract description 10
- 229960003595 (-)- limonene Drugs 0.000 abstract description 10
- CRPUJAZIXJMDBK-UHFFFAOYSA-N Toxaphene Natural products C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 abstract description 10
- SLKPBCXNFNIJSV-UHFFFAOYSA-N cuparene Natural products C1=CC(C)=CC=C1C1(C)C(C)(C)CCC1 SLKPBCXNFNIJSV-UHFFFAOYSA-N 0.000 abstract description 10
- WVRVMHCZDFFAFB-UHFFFAOYSA-N epsilon-Cuprenene Natural products C1=CC(C)=CCC1C1(C)C(C)(C)CCC1 WVRVMHCZDFFAFB-UHFFFAOYSA-N 0.000 abstract description 10
- CRPUJAZIXJMDBK-BDAKNGLRSA-N (-)-camphene Chemical compound C1C[C@H]2C(=C)C(C)(C)[C@@H]1C2 CRPUJAZIXJMDBK-BDAKNGLRSA-N 0.000 abstract description 9
- 229930006714 (-)-camphene Natural products 0.000 abstract description 9
- WSTYNZDAOAEEKG-UHFFFAOYSA-N Mayol Natural products CC1=C(O)C(=O)C=C2C(CCC3(C4CC(C(CC4(CCC33C)C)=O)C)C)(C)C3=CC=C21 WSTYNZDAOAEEKG-UHFFFAOYSA-N 0.000 abstract description 7
- WTARULDDTDQWMU-UHFFFAOYSA-N Pseudopinene Natural products C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 abstract description 4
- WTARULDDTDQWMU-IUCAKERBSA-N (-)-β-pinene Chemical compound C1[C@@H]2C(C)(C)[C@H]1CCC2=C WTARULDDTDQWMU-IUCAKERBSA-N 0.000 abstract description 2
- -1 (+)-camphenee Chemical compound 0.000 abstract 2
- 229930003658 monoterpene Natural products 0.000 abstract 2
- 150000002773 monoterpene derivatives Chemical class 0.000 abstract 2
- 235000002577 monoterpenes Nutrition 0.000 abstract 2
- 238000000034 method Methods 0.000 description 15
- 239000000126 substance Substances 0.000 description 12
- 230000008569 process Effects 0.000 description 10
- 241000545593 Scolytinae Species 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 239000002023 wood Substances 0.000 description 7
- 241000238631 Hexapoda Species 0.000 description 6
- 230000002265 prevention Effects 0.000 description 6
- 241000607479 Yersinia pestis Species 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 150000003505 terpenes Chemical class 0.000 description 5
- 235000007586 terpenes Nutrition 0.000 description 5
- 235000011611 Pinus yunnanensis Nutrition 0.000 description 4
- 241000018652 Pinus yunnanensis Species 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- BQOFWKZOCNGFEC-BDAKNGLRSA-N (+)-Delta3-carene Chemical compound C1C(C)=CC[C@H]2C(C)(C)[C@@H]12 BQOFWKZOCNGFEC-BDAKNGLRSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 210000003750 lower gastrointestinal tract Anatomy 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000012544 monitoring process Methods 0.000 description 3
- 244000144977 poultry Species 0.000 description 3
- 229950010257 terpin Drugs 0.000 description 3
- CRPUJAZIXJMDBK-DTWKUNHWSA-N (+)-camphene Chemical compound C1C[C@@H]2C(=C)C(C)(C)[C@H]1C2 CRPUJAZIXJMDBK-DTWKUNHWSA-N 0.000 description 2
- 229930006720 (-)-alpha-pinene Natural products 0.000 description 2
- WONIGEXYPVIKFS-HRDYMLBCSA-N (1r,2r,5r)-4,6,6-trimethylbicyclo[3.1.1]hept-3-en-2-ol Chemical compound CC1=C[C@@H](O)[C@H]2C(C)(C)[C@@H]1C2 WONIGEXYPVIKFS-HRDYMLBCSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000004080 punching Methods 0.000 description 2
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 2
- 229930006713 (+)-car-3-ene Natural products 0.000 description 1
- 150000000015 (+)-car-3-ene derivatives Chemical class 0.000 description 1
- GRWFGVWFFZKLTI-RKDXNWHRSA-N (+)-α-pinene Chemical compound CC1=CC[C@H]2C(C)(C)[C@@H]1C2 GRWFGVWFFZKLTI-RKDXNWHRSA-N 0.000 description 1
- BAVONGHXFVOKBV-ZJUUUORDSA-N (-)-trans-carveol Chemical compound CC(=C)[C@@H]1CC=C(C)[C@@H](O)C1 BAVONGHXFVOKBV-ZJUUUORDSA-N 0.000 description 1
- WUOACPNHFRMFPN-VIFPVBQESA-N (R)-(+)-alpha-terpineol Chemical compound CC1=CC[C@H](C(C)(C)O)CC1 WUOACPNHFRMFPN-VIFPVBQESA-N 0.000 description 1
- VVFXXDIPJNSMPW-UHFFFAOYSA-N 1,1,4a-trimethyl-7-propan-2-yl-2,3,4,4b,5,6,8a,10a-octahydrophenanthrene Chemical compound C1=CC2C(C)(C)CCCC2(C)C2C1C=C(C(C)C)CC2 VVFXXDIPJNSMPW-UHFFFAOYSA-N 0.000 description 1
- IAQORZCEBSUZRH-UHFFFAOYSA-N 3,3-dimethyl-2-methylidenebicyclo[2.2.1]heptane Chemical compound C1CC2C(=C)C(C)(C)C1C2.C1CC2C(=C)C(C)(C)C1C2 IAQORZCEBSUZRH-UHFFFAOYSA-N 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- BQOFWKZOCNGFEC-UHFFFAOYSA-N Delta3-Carene Natural products C1C(C)=CCC2C(C)(C)C12 BQOFWKZOCNGFEC-UHFFFAOYSA-N 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- 235000005205 Pinus Nutrition 0.000 description 1
- 241000218602 Pinus <genus> Species 0.000 description 1
- 241001074085 Scophthalmus aquosus Species 0.000 description 1
- 241000546225 Tomicus Species 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001712 car-3-ene derivatives Chemical class 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 230000027326 copulation Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000007831 electrophysiology Effects 0.000 description 1
- 238000002001 electrophysiology Methods 0.000 description 1
- BAVONGHXFVOKBV-UHFFFAOYSA-N exo-carveol Natural products CC(=C)C1CC=C(C)C(O)C1 BAVONGHXFVOKBV-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 238000010137 moulding (plastic) Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000001932 seasonal effect Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Abstract
The invention discloses application of monoterpene and monoterpene alcohol as attractants of tomicus minor hartig consi and an attractant of tomicus minor hartig. One or more of the following components act as the application of the attractant of tomicus minor hartig consi: S-(-)-alpha-pinene, IR-(+)-alpha-pinene, myrcene, (+)-camphenee, (-)-camphene, alpha-terpinene, (+)-3-carnene, (1s)-(-)-beta-pinene, (-)-limonene, (+)-limonene, (-)-Myrtenol, (s)-cis-verbenol, (-)-trans-verbenol and cuparene.
Description
Technical field
The present invention relates to terpenes and monoterpenol as ordinary bending attractant application and ordinary bending draw
The new component of lure and new formula.
Background technology
Ordinary bending (Tomicus.minor Hartig) is a kind of important trunk borer, and serious harm is Eurasian loose
Belong to multiple kinds.At present, research of the studies in China to ordinary bending is concentrated mainly on biology, hazard profile, informationization
Learn material and Prevention Technique etc..It is as follows in Yunnan prevention and control bark beetle major measure at present according to the investigation of applicant：1. inspection is strengthened
Epidemic disease, forbids allocation and transportation to harm wood.2. wood of harming is cleared up.To prevent insect pest from spreading, all aggrieved wood of woodland are felled, and in technology people
Under the supervision of member, carry out medicament fumigating or burn process.3. trap-tree trapping.In bark beetle Burst Regions, aggrieved trap-tree is randomly choosed
And cut down, woodland is placed in, bark beetle is lured, finally trap-tree is processed.4. chemical control.The method is mainly to per plant of aggrieved wood
Carry out punching moth medicine.
Cleaning wood of harming can leak and cut down and cause large batch of pinaster to be forced to cut down.The lasting effect of trap-tree trapping is poor, behaviour
Make constant, if bait wood is processed not in time, can also cause more harm.Punching moth medicine is time-consuming, and high cost, large area is prevented
Control difficulty.Environment is polluted in chemical control, destroys the balance of forest ecosystem；The Forest Tourism Resources very abundant in Yunnan, such as
What protects pinus yunnanensis faranch, and local government and forest department pay much attention to, but up to the present, never conjunction is compared in production
Reason, effectively monitoring and the method prevented and treated.
With the fast development of chemical ecology, carry out prevention and control bark beetle using the infochemical of insecticide and obtained abroad
To confirmation well.The method, efficiently, environmental friendliness, positioning is strong.Foreign scholar ground to horizontal Hangzhoupro tangent epiderivative attractant
Study carefully.Kangas etc. (1970) has found that α-terpinol and genial trans- carveol in Volatiles of Pinus have attracting action to the worm.
Lanne etc. (1987) determines 3- carenes -10- alcohol, trans verbenol and Fructus Rhodomyrti alkene in its both sexes hindgut by GC-MS
Alcohol content is higher, and the content highest when brill moth is to the phloem-xylem interface for producing fat；When EAG is tested, trans Herba Verbenae
The activity of enol is most strong, next to that cis verbenol；In field test, what the juggle ratio for having female adult did not had can lure more
Bark beetle, show that female adult produces aggregation information, meanwhile, only with trans verbenol and (1S, 6R) -3- carene -10- alcohol
The juggle of process can just lure bark beetle；This show the worm be using host's volatile matter synthesis primary data usually lure it is of the same race its
Its bark beetle comes to assemble and copulation.
In January, 2010, it is little that applicant cuts the tip with the external special lure of ordinary bending introduced to China's woodland adit
Moth is traped, it is found that its effect is bad, not as trap-tree.Due to there is the ordinary bending environmental condition in China and host
Entirely different with foreign countries, its infochemical is also different, in addition external report some compositions (as (1S, 6R) -3- carenes -
10- alcohol) can't buy at home, and also do not find in we are to the analysis of Yunnan Province of China ordinary bending hindgut volatile matter same
The composition of sample, and the composition of external commodity lure is also underground.So what the present patent application person subsequently occurred for Yunnan Province of China
Ordinary bending has carried out the research such as chemical analyses of deep electro physiology, behavioristicss and infochemical, according to research
As a result the attractant new component and new formula for China's ordinary bending is developed.The following is the concrete interior of the attractant
Hold.
The content of the invention
It is an object of the invention to provide a kind of be related to terpenes and monoterpenol for Chinese ordinary bending development
The attractant new component of terpenes and the application of new formula.
It is a further object to provide it is a kind of have it is efficient, environmentally friendly, to person poultry safety, produce insect
The drug-fast ordinary bending attractant of life.
For achieving the above object, the present invention takes technical scheme below：
S- (-)-australene (S- (-)-α-pinene), 1R- (+)-australene (1R- (+)-α-pinene), myrcene
(myrcene), (+)-down alkene ((+)-camphene), (-)-camphene ((-)-camphene), α-terpinene (α-
Terpinene), (+) -3- carenes ((+) -3-carene), (1S)-(-)-nopinene ((1s)-(-)-β-pinene), (-)-lemon
Lemon alkene ((-)-limonene), (+)-limonene ((+)-limonene), (-)-myrtenol ((-)-Myrtenol), (S)-
Cis-verbenol (s)-cis-verbenol, (-)-trans-verbenol ((-)-trans-verbenol) and flower side
Application of one or more in cupressene (Cuparene) as ordinary bending attractant.
The present invention attracts in a large number a large amount of ordinary bendings using host and polypide volatile matter attractant so as to be gathered in one
Is killed again in fixed device, with low cost, efficiently, it is completely environmentally friendly, to person poultry safety, to produce insect anti-
The advantages of property of medicine so that in the past passive chemical prevention is changed into the Biological control of active, while can also be according to adit in trapper
Tangent epiderivative quantity number, reach monitoring and forecast forestry insect pest purpose.
A kind of ordinary bending attractant, the attractant by S- (-)-australene, 1R- (+)-australene, myrcene,
(+)-down alkene, (-)-camphene, α-terpinene, (1S)-(-)-nopinene, (-)-limonene, (+)-limonene, (-)-Fructus Rhodomyrti alkene
Alcohol and cuparene are constituted, S- (-)-australene, 1R- (+)-australene, myrcene, (+)-down alkene, (-)-camphene, α-terpene
The volume ratio of product alkene, (1S)-(-)-nopinene, (-)-limonene, (+)-limonene, (-)-myrtenol and cuparene
For：5-10∶1-3∶1-3∶1-3∶0.2-0.5∶0.05-0.1∶1-5∶0.01-0.1∶0.01-0.1∶0.01-0.1∶0.05-0.3.
Preferably, S- (-)-australene, 1R- (+)-australene, myrcene, (+)-down alkene, (-)-camphene, α-terpin
The volume ratio of alkene, (1S)-(-)-nopinene, (-)-limonene, (+)-limonene, (-)-myrtenol and cuparene is：8
∶1∶1.5∶1.5∶0.3∶0.07∶3.75∶0.03∶0.07∶0.07∶0.13。
A kind of ordinary bending attractant, the attractant by S- (-)-australene, 1R- (+)-australene, myrcene,
(+)-down alkene, (-)-camphene, α-terpinene, (1S)-(-)-nopinene, (-)-limonene, (+)-limonene, (-)-Fructus Rhodomyrti alkene
Alcohol, (S)-cis-verbenol, (-)-trans-verbenol and cuparene composition, S- (-)-australene, 1R-
(+)-australene, myrcene, (+)-down alkene, (-)-camphene, α-terpinene, (1S)-(-)-nopinene, (-)-limonene, (+)-
The volume of limonene, (-)-myrtenol, (S)-cis-verbenol, (-)-trans-verbenol and cuparene
Than for：30-50∶10-20∶5-10∶1-3∶4-8∶1-5∶0.1-0.5∶0.01-0.1∶0.05-0.3∶0.05-0.3∶0.01-
0.05∶0.005-0.15∶0.01-0.05∶0.1-1；Wherein, S- (-)-australene, 1R- (+)-australene, myrcene, (+)-down
Alkene, (-)-camphene, α-terpinene, (1S)-(-)-nopinene, (-)-limonene, (+)-limonene, (-)-myrtenol,
(-)-trans-verbenol and cuparene are in units of ml, and (S)-cis-verbenol is solid, with cm3For
Unit.
Preferably, S- (-)-australene, 1R- (+)-australene, myrcene, (+)-down alkene, (-)-camphene, α-terpin
Alkene, (1S)-(-)-nopinene, (-)-limonene, (+)-limonene, (-)-myrtenol, (S)-cis-verbenol,
The volume ratio of (-)-trans-verbenol and cuparene is：39∶14∶9∶7∶3∶0.35∶0.05∶0.18∶0.16∶0.03∶
0.01∶0.03∶0.5；Wherein, S- (-)-australene, 1R- (+)-australene, myrcene, (+)-down alkene, (-)-camphene, α-terpin
Alkene, (1S)-(-)-nopinene, (-)-limonene, (+)-limonene, (-)-myrtenol, (-)-trans-verbenol and
Cuparene is in units of ml, and (S)-cis-verbenol is solid, with cm3For unit.
A kind of ordinary bending attractant, the attractant by S- (-)-australene, 1R- (+)-australene, myrcene,
(-)-myrtenol, (s)-cis-verbenol, (-)-trans-verbenol composition, S- (-)-australene,
1R- (+)-australene, myrcene, (-)-myrtenol, (s)-cis-verbenol, (-)-trans-verbenol
Volume ratio is 25-100: 25-100: 1-10: 0.1-1: 0.075-0.5: 0.075-0.5；Wherein, S- (-)-australene, 1R-
(+)-australene, myrcene, (-)-myrtenol, (-)-trans-verbenol in units of ml, and (S)-cis-
Verbenol is solid, with cm3For unit.
Preferably, S- (-)-australene, 1R- (+)-a- pinenes, myrcene, (-)-myrtenol, (s)-cis-
Verbenol, the volume ratio of (-)-trans-verbenol are 50: 50: 5: 0.5: 0.125: 0.125；；Wherein, S- (-)-
Australene, 1R- (+)-australene, myrcene, (-)-myrtenol, (-)-trans-verbenol in units of ml, and
(S)-cis-verbenol is solid, with cm3For unit.
A kind of ordinary bending attractant, the attractant is by (1S)-(-)-australene, myrcene and (s)-cis-horse
Whip oxalene alcohol is constituted, (1S)-(-)-australene, and the volume ratio of myrcene and (s)-cis-verbenol is 25-100:
1-10∶0.075-0.5；Wherein, (1S)-(-)-australene, myrcene is in units of ml, and (S)-cis-verbenol
For solid, with cm3For unit.
Preferably, the volume ratio of described (1S)-(-)-australene, myrcene and (s)-cis-verbenol is 50: 5:
0.125；Wherein, (1S)-(-)-australene, myrcene is in units of ml, and (S)-cis-verbenol is solid, with
cm3For unit.
A kind of ordinary bending attractant, the attractant by S- (-)-australene, 1R- (+)-australene, (s)-cis-
Verbenol is constituted, and S- (-)-australene, 1R- (+)-australene, the volume ratio of (s)-cis-verbenol are:
25-100∶25-100∶0.075-0.5；Wherein, S- (-)-australene, 1R- (+)-australene be in units of ml, and (S)-suitable
Formula-verbenol is solid, with cm3For unit.
Preferably, S- (-)-australene, 1R- (+)-australene, the volume ratio of (s)-cis-verbenol are：
50∶50∶0.125；Wherein, S- (-)-australene, 1R- (+)-australene are in units of ml, and (S)-cis-verbenol
For solid, with cm3For unit.
A kind of ordinary bending attractant, the attractant is by S- (-)-australene, (-)-myrtenol and (s)-suitable
The volume of formula-verbenol composition, S- (-)-australene, (-)-myrtenol and (s)-cis-verbenol
Than for 25-100: 0.1-1: 0.075-0.5；Wherein, S- (-)-australene, (-)-myrtenol be in units of ml, and
(S)-cis-verbenol is solid, with cm3For unit.
Preferably, the volume ratio of S- (-)-australene, (-)-myrtenol and (s)-cis-verbenol
For 50: 0.5: 0.125；Wherein, S- (-)-australene, (-)-myrtenol are in units of ml, and (S)-cis-Herba Verbenae
Enol is solid, with cm3For unit.
A kind of ordinary bending attractant, the attractant by S- (-)-australene, (s)-cis-verbenol,
(-)-trans-verbenol composition, S- (-)-australene, (s)-cis-verbenol, (-)-trans-Herba Verbenae
The volume ratio of enol is 25-100: 0.075-0.5: 0.075-0.5；Wherein, S- (-)-australene, (-)-trans-verbenene
Alcohol is in units of ml, and (S)-cis-verbenol is solid, with cm3For unit.
Preferably, S- (-)-australene, (s)-cis-verbenol, the volume of (-)-trans-verbenol
Than for 50: 0.125: 0.125；Wherein, S- (-)-australene, (-)-trans-verbenol be in units of ml, and (S)-suitable
Formula-verbenol is solid, with cm3For unit.
A kind of ordinary bending attractant, the attractant is by S- (-)-australene and (s)-cis-verbenol group
Into S- (-)-australene, cis-verbenol volume ratio are 25-100: 0.075-0.5；Wherein, S- (-)-australene
In units of ml, and (S)-cis-verbenol is solid, with cm3For unit.
Preferably, S- (-)-australene, the volume ratio of (s)-cis-verbenol are 50: 0.125: 0.125；
Wherein, S- (-)-australene is in units of ml, and (S)-cis-verbenol is solid, with cm3For unit.
The advantage of patent of the present invention is：
1st, with the infochemical of host and polypide ordinary bending is lured than traditional chemical pest control low cost
Much, terpenes preparation (the online quotation of domestic Production in Chemical Plant：7800 yuan/ton) more external low price, and 10ml terpenes (folding
Close 0.08 yuan or so) can continuously use 2 first quarter moons.The method economical and effective, can save substantial amounts of manpower and materials.
2nd, the use of attractant be not subject to seasonal restrictions and can life-time service, in Yunnan, ordinary bending is become a cadre the whole of harm
The individual time period can trapping pests, and chemical prevention and the killed wood of cleaning need to implement in a certain special time period, too early or mistake
Evening all impact effects.Therefore, invention is trying to explore and put into practice to frontier science and technology, with important scientific value and social valency
Value.
3rd, the present invention attracts in a large number Yunnan ordinary bending using containing host and polypide semiochemicalses so as to poly-
Collection killed again in certain device, with efficient, complete environmental friendliness, to person poultry safety, do not make insect produce drug resistance
Property the advantages of so that in the past passive chemical prevention is changed into the Biological control of active.
4 according in trapper ordinary bending quantity number, reach monitoring and forecast forestry insect pest purpose.
Description of the drawings
It is little that Fig. 1 cuts the tip for the different disposal (i.e. the process of A, B, C, D, E and F different formulations) of embodiment 1 to male and female adit
Moth-eaten average trapping value chart (in December, 2010 is in April, 2011, Yuxi).
Fig. 2 cuts the tip for the different disposal (i.e. the process of D, K, L, M, N, O and U different formulations) of embodiment 2 to male and female adit
The average trapping spirogram table (in December, 2011 to 2 months 2012, Yuxi) of bark beetle.Specific embodiment
The Yunnan ordinary bending attractant of the present invention was entered through continuous 2 years in North Mountain Forestry Center, Yuxi, Yunnan
The result of row testing experiment.The purity of compound used therefor and manufacturer are shown in Table 1.(wherein, the sample purity in table 1 is body
Product percentage ratio) (it is percent by volume that the numeral without percentage sign remains on expression behind numeral)
The mixed liquor of 40mL is loaded into the slow release bottle (the plastic molding and processing plant's production of three one-tenth of Shanxi province Taiyuan city Xiaodian District) of 100mL, should
Slow release bottle release rate of s- (-)-australene s- (-)-α-pinene at 20 DEG C is about 50mg/d.The high 81cm of cross trapper
Wide 37cm (middle prompt four directions, Beijing), bottom has a plastic collection bottle.Slow release bottle is fixed on trapper bottom.Trapper hangs over
Between the pinaster of woodland Yunnan, bottom is liftoff 1.5m is spaced 40m.
Embodiment 1：In December, 2010, field test test is carried out in Yuxi Beishan Mountain forest farm, according to aggrieved and for aggrieved
Pinus yunnanensis faranch volatile matter and ordinary bending hindgut chemical substance analysis and ordinary bending to different chemical substances
Electroantennogram response, is configured with 3 formula, as shown in the table.Wherein C is external ordinary bending commodity lure, and ABD is this
The formula of invention, the release rate of A process is doubled to obtain E, and F only hangs trapper and makees blank.The composition and ratio of each formula
It is shown in Table 2.Often process and be repeated 3 times, every investigation in 5 days once, and trapper is exchanged at random.
The sample purity of the main volatile standard substance of table 1 and manufacturer
The different disposal of the table field test of in December, 22010
Note：S the unit of ()-cis-verbenol is cm3, the unit of remaining compound is ml.Similarly hereinafter.
From on April 18,20 days to 2011 December in 2010, it is little that the test in Yuxi Beishan Mountain forest farm lures adit to cut the tip
Moth-eaten female adult 335 and male worm 287, the diversity between each process is shown in Fig. 2, female adult (F=50.241；Df=5,12；P=
0.0001)；Male worm (F=29.47；Df=5,12；P=0.0001).The present invention all formula trapping amount all apparently higher than
Control, has illustrated attracting action, and the ordinary bending that wherein D process is lured is significantly more than other and processes (see Fig. 1).
Embodiment 2：Carried out in Yuxi Beishan Mountain forest farm on 2 15th, 2012 in December, 2011, in test in 2010
On the basis of, by research, lure formula is further improved, 6 formula, respectively D, K, L, M, N and O are designed altogether, wherein D is
Formula better than external lure in 2010, additionally, U is shown in Table to cut down pinus yunnanensis faranch as control, other compositions for processing and ratio
2.Each processes and repeats to be 5 times.Other conditions are with embodiment 1.
The different disposal of the table field test of in December, 32011
Note：U is slight aggrieved pinus yunnanensis faranch, used as control.
In embodiment 2, ordinary bending female adult 315 and male worm 312, female adult (F=24.952 are lured；Df=6,
28, P=0.0001), male worm (F=21.247；Df=6,28；P=0.0001).As a result show, all new formula are with respect to 2010
The optimum formula and aggrieved trap-tree in year, attractant effect all increases, and wherein formula N is substantially better than formula K, L, M, formula O's
Attractant effect is preferably (see Fig. 2).
Claims (12)
1. a kind of ordinary bending attractant, it is characterised in that the attractant is by S- (-)-australene and (s)-cis-horse
Whip oxalene alcohol is constituted, and S- (-)-australene, (S)-cis-verbenol volume ratio are 25-100：0.075-0.5；Its
In, S- (-)-australene is in units of ml, and (S)-cis-verbenol is solid, with cm3For unit.
2. ordinary bending attractant according to claim 1, it is characterised in that S- (-)-australene, (s)-suitable
The volume ratio of formula-verbenol is 50：0.125.
3. a kind of ordinary bending attractant, it is characterised in that the attractant is by S- (-)-australene, (s)-cis-horse
Whip oxalene alcohol, (-)-trans-verbenol composition, S- (-)-australene, (s)-cis-verbenol, (-)-anti-
The volume ratio of formula-verbenol is 25-100：0.075-0.5：0.075-0.5；Wherein, S- (-)-australene, (-)-trans-
Verbenol is in units of ml, and (S)-cis-verbenol is solid, with cm3For unit.
4. ordinary bending attractant according to claim 3, it is characterised in that S- (-)-australene, (s)-suitable
Formula-verbenol, the volume ratio of (-)-trans-verbenol are 50：0.125：0.125.
5. a kind of ordinary bending attractant, it is characterised in that the attractant is by S- (-)-australene, (-)-Fructus Rhodomyrti alkene
Alcohol and (s)-cis-verbenol composition, S- (-)-australene, (-)-myrtenol and (s)-cis-Herba Verbenae
The volume ratio of enol is 25-100：0.1-1：0.075-0.5；Wherein, S- (-)-australene, (-)-myrtenol are with ml
Unit, and (S)-cis-verbenol is solid, with cm3For unit.
6. ordinary bending attractant according to claim 5, it is characterised in that S- (-)-australene, (-)-Fructus Persicae
The volume ratio of golden ma's enol and (s)-cis-verbenol is 50：0.5：0.125.
7. a kind of ordinary bending attractant, it is characterised in that the attractant is by S- (-)-australene, 1R- (+)-australene
Alkene, (s)-cis-verbenol composition, S- (-)-australene, 1R- (+)-australene, (s)-cis-verbenol
Volume ratio be：25-100：25-100：0.075-0.5；Wherein, S- (-)-australene, 1R- (+)-australene are with ml as list
Position, and (S)-cis-verbenol is solid, with cm3For unit.
8. ordinary bending attractant according to claim 7, it is characterised in that S- (-)-australene, 1R- (+)-
Australene, the volume ratio of (s)-cis-verbenol are：50：50：0.125.
9. a kind of ordinary bending attractant, it is characterised in that the attractant by S- (-)-australene, myrcene and (s)-
Cis-verbenol is constituted, (1S)-(-)-australene, and the volume ratio of myrcene and (s)-cis-verbenol is
25-100：1-10：0.075-0.5；Wherein, (1S)-(-)-australene, myrcene is in units of ml, and (S)-cis-horsewhip
Oxalene alcohol is solid, with cm3For unit.
10. ordinary bending attractant according to claim 9, it is characterised in that S- (-)-australene, myrcene
(s) volume ratio of-cis-verbenol is 50：5：0.125.
11. a kind of ordinary bending attractants, it is characterised in that the attractant is by S- (-)-australene, 1R- (+)-australene
Alkene, myrcene, (-)-myrtenol, (s)-cis-verbenol, (-)-trans-verbenol composition, the S-
(-)-australene, 1R- (+)-australene, myrcene, (-)-myrtenol, (s)-cis-verbenol, (-)-trans-
The volume ratio of verbenol is 25-100：25-100：1-10：0.1-1：0.075-0.5：0.075-0.5；Wherein, S- (-)-
Australene, 1R- (+)-australene, myrcene, (-)-myrtenol, (-)-trans-verbenol in units of ml, and
(S)-cis-verbenol is solid, with cm3For unit.
12. according to claim 11 ordinary bending attractant, it is characterised in that S- (-)-australene, 1R-
(+)-a- pinenes, myrcene, (-)-myrtenol, (s)-cis-verbenol, the body of (-)-trans-verbenol
Product is than being 50ml：50ml：5ml：0.5ml：0.125cm3：0.125ml.
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| CN106070288A (en) * | 2016-06-03 | 2016-11-09 | 华南农业大学 | A kind of pine tumor is as attractant |
| CN109793013A (en) * | 2019-02-02 | 2019-05-24 | 杭州科森农化有限公司 | A kind of coleopteron attractant |
| CN116158427B (en) * | 2023-02-21 | 2023-08-15 | 黑龙江省森林保护研究所 | Plant source attractant for preventing and treating hazelnut real images, and preparation method and application thereof |
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