CN104970017A - Components and formula of attractant of tomicus minor hartig - Google Patents
Components and formula of attractant of tomicus minor hartig Download PDFInfo
- Publication number
- CN104970017A CN104970017A CN201410133308.3A CN201410133308A CN104970017A CN 104970017 A CN104970017 A CN 104970017A CN 201410133308 A CN201410133308 A CN 201410133308A CN 104970017 A CN104970017 A CN 104970017A
- Authority
- CN
- China
- Prior art keywords
- australene
- verbenol
- cis
- attractant
- myrtenol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005667 attractant Substances 0.000 title claims abstract description 60
- 230000031902 chemoattractant activity Effects 0.000 title claims abstract description 55
- 241000546230 Tomicus minor Species 0.000 title abstract 4
- WONIGEXYPVIKFS-UHFFFAOYSA-N (+)-cis-Verbenol Natural products CC1=CC(O)C2C(C)(C)C1C2 WONIGEXYPVIKFS-UHFFFAOYSA-N 0.000 claims abstract description 103
- WONIGEXYPVIKFS-YIZRAAEISA-N (1s,2s,5s)-4,6,6-trimethylbicyclo[3.1.1]hept-3-en-2-ol Chemical compound CC1=C[C@H](O)[C@@H]2C(C)(C)[C@H]1C2 WONIGEXYPVIKFS-YIZRAAEISA-N 0.000 claims abstract description 69
- RXBQNMWIQKOSCS-UHFFFAOYSA-N Myrthenol Natural products C1C2C(C)(C)C1CC=C2CO RXBQNMWIQKOSCS-UHFFFAOYSA-N 0.000 claims abstract description 39
- SLKPBCXNFNIJSV-HNNXBMFYSA-N Cuparene Chemical compound C1=CC(C)=CC=C1[C@@]1(C)C(C)(C)CCC1 SLKPBCXNFNIJSV-HNNXBMFYSA-N 0.000 claims abstract description 38
- YHQGMYUVUMAZJR-UHFFFAOYSA-N α-terpinene Chemical compound CC(C)C1=CC=C(C)CC1 YHQGMYUVUMAZJR-UHFFFAOYSA-N 0.000 claims abstract description 38
- RXBQNMWIQKOSCS-IUCAKERBSA-N [(1s,5r)-6,6-dimethyl-4-bicyclo[3.1.1]hept-3-enyl]methanol Chemical compound C1[C@@H]2C(C)(C)[C@H]1CC=C2CO RXBQNMWIQKOSCS-IUCAKERBSA-N 0.000 claims abstract description 37
- WONIGEXYPVIKFS-VGMNWLOBSA-N (1r,2s,5r)-4,6,6-trimethylbicyclo[3.1.1]hept-3-en-2-ol Chemical compound CC1=C[C@H](O)[C@H]2C(C)(C)[C@@H]1C2 WONIGEXYPVIKFS-VGMNWLOBSA-N 0.000 claims abstract description 34
- WSTYNZDAOAEEKG-UHFFFAOYSA-N Mayol Natural products CC1=C(O)C(=O)C=C2C(CCC3(C4CC(C(CC4(CCC33C)C)=O)C)C)(C)C3=CC=C21 WSTYNZDAOAEEKG-UHFFFAOYSA-N 0.000 claims abstract description 19
- SLKPBCXNFNIJSV-UHFFFAOYSA-N cuparene Natural products C1=CC(C)=CC=C1C1(C)C(C)(C)CCC1 SLKPBCXNFNIJSV-UHFFFAOYSA-N 0.000 claims abstract description 19
- WVRVMHCZDFFAFB-UHFFFAOYSA-N epsilon-Cuprenene Natural products C1=CC(C)=CCC1C1(C)C(C)(C)CCC1 WVRVMHCZDFFAFB-UHFFFAOYSA-N 0.000 claims abstract description 19
- HEVGGTGPGPKZHF-UHFFFAOYSA-N 1-(1,2-dimethyl-3-methylidenecyclopentyl)-4-methylbenzene Chemical compound CC1C(=C)CCC1(C)C1=CC=C(C)C=C1 HEVGGTGPGPKZHF-UHFFFAOYSA-N 0.000 claims description 70
- 238000005452 bending Methods 0.000 claims description 54
- 239000007787 solid Substances 0.000 claims description 21
- 150000001336 alkenes Chemical class 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 15
- WONIGEXYPVIKFS-HRDYMLBCSA-N (1r,2r,5r)-4,6,6-trimethylbicyclo[3.1.1]hept-3-en-2-ol Chemical compound CC1=C[C@@H](O)[C@H]2C(C)(C)[C@@H]1C2 WONIGEXYPVIKFS-HRDYMLBCSA-N 0.000 claims description 3
- BQOFWKZOCNGFEC-BDAKNGLRSA-N (+)-Delta3-carene Chemical compound C1C(C)=CC[C@H]2C(C)(C)[C@@H]12 BQOFWKZOCNGFEC-BDAKNGLRSA-N 0.000 claims 1
- 229930006713 (+)-car-3-ene Natural products 0.000 claims 1
- BQOFWKZOCNGFEC-UHFFFAOYSA-N Delta3-Carene Natural products C1C(C)=CCC2C(C)(C)C12 BQOFWKZOCNGFEC-UHFFFAOYSA-N 0.000 claims 1
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 abstract description 4
- XMGQYMWWDOXHJM-SNVBAGLBSA-N (-)-α-limonene Chemical compound CC(=C)[C@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-SNVBAGLBSA-N 0.000 abstract description 4
- UAHWPYUMFXYFJY-UHFFFAOYSA-N beta-myrcene Chemical compound CC(C)=CCCC(=C)C=C UAHWPYUMFXYFJY-UHFFFAOYSA-N 0.000 abstract description 4
- CRPUJAZIXJMDBK-UHFFFAOYSA-N Toxaphene Natural products C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 abstract description 3
- 229940099369 (+)- limonene Drugs 0.000 abstract description 2
- 229960003595 (-)- limonene Drugs 0.000 abstract description 2
- CRPUJAZIXJMDBK-BDAKNGLRSA-N (-)-camphene Chemical compound C1C[C@H]2C(=C)C(C)(C)[C@@H]1C2 CRPUJAZIXJMDBK-BDAKNGLRSA-N 0.000 abstract description 2
- 229930006714 (-)-camphene Natural products 0.000 abstract description 2
- WTARULDDTDQWMU-IUCAKERBSA-N (-)-β-pinene Chemical compound C1[C@@H]2C(C)(C)[C@H]1CCC2=C WTARULDDTDQWMU-IUCAKERBSA-N 0.000 abstract description 2
- WTARULDDTDQWMU-UHFFFAOYSA-N Pseudopinene Natural products C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 abstract description 2
- VYBREYKSZAROCT-UHFFFAOYSA-N alpha-myrcene Natural products CC(=C)CCCC(=C)C=C VYBREYKSZAROCT-UHFFFAOYSA-N 0.000 abstract description 2
- -1 (+)-camphenee Chemical compound 0.000 abstract 2
- 229930003658 monoterpene Natural products 0.000 abstract 2
- 150000002773 monoterpene derivatives Chemical class 0.000 abstract 2
- 235000002577 monoterpenes Nutrition 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 description 18
- 230000008569 process Effects 0.000 description 13
- 239000000126 substance Substances 0.000 description 10
- 238000012360 testing method Methods 0.000 description 9
- 241000238631 Hexapoda Species 0.000 description 7
- 241000545593 Scolytinae Species 0.000 description 7
- 239000002023 wood Substances 0.000 description 7
- 239000003814 drug Substances 0.000 description 6
- 241000607479 Yersinia pestis Species 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 150000003505 terpenes Chemical class 0.000 description 5
- 235000007586 terpenes Nutrition 0.000 description 5
- 235000011611 Pinus yunnanensis Nutrition 0.000 description 4
- 241000018652 Pinus yunnanensis Species 0.000 description 4
- 230000002265 prevention Effects 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 230000036039 immunity Effects 0.000 description 3
- 210000003750 lower gastrointestinal tract Anatomy 0.000 description 3
- 244000144977 poultry Species 0.000 description 3
- CRPUJAZIXJMDBK-DTWKUNHWSA-N (+)-camphene Chemical compound C1C[C@@H]2C(=C)C(C)(C)[C@H]1C2 CRPUJAZIXJMDBK-DTWKUNHWSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 235000005205 Pinus Nutrition 0.000 description 2
- 241000218602 Pinus <genus> Species 0.000 description 2
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 2
- 235000011613 Pinus brutia Nutrition 0.000 description 2
- 241000018646 Pinus brutia Species 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 238000004080 punching Methods 0.000 description 2
- GRWFGVWFFZKLTI-RKDXNWHRSA-N (+)-α-pinene Chemical compound CC1=CC[C@H]2C(C)(C)[C@@H]1C2 GRWFGVWFFZKLTI-RKDXNWHRSA-N 0.000 description 1
- BAVONGHXFVOKBV-ZJUUUORDSA-N (-)-trans-carveol Chemical compound CC(=C)[C@@H]1CC=C(C)[C@@H](O)C1 BAVONGHXFVOKBV-ZJUUUORDSA-N 0.000 description 1
- WUOACPNHFRMFPN-SECBINFHSA-N (S)-(-)-alpha-terpineol Chemical compound CC1=CC[C@@H](C(C)(C)O)CC1 WUOACPNHFRMFPN-SECBINFHSA-N 0.000 description 1
- NVZULJTUMCKVQR-UHFFFAOYSA-N C1C(C)=CCC2C(C)(C)C12.C1C(C)=CCC2C(C)(C)C12 Chemical compound C1C(C)=CCC2C(C)(C)C12.C1C(C)=CCC2C(C)(C)C12 NVZULJTUMCKVQR-UHFFFAOYSA-N 0.000 description 1
- RXBQNMWIQKOSCS-RKDXNWHRSA-N Myrtenol Natural products C1[C@H]2C(C)(C)[C@@H]1CC=C2CO RXBQNMWIQKOSCS-RKDXNWHRSA-N 0.000 description 1
- 241000546225 Tomicus Species 0.000 description 1
- OVKDFILSBMEKLT-UHFFFAOYSA-N alpha-Terpineol Natural products CC(=C)C1(O)CCC(C)=CC1 OVKDFILSBMEKLT-UHFFFAOYSA-N 0.000 description 1
- 229940088601 alpha-terpineol Drugs 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000007831 electrophysiology Effects 0.000 description 1
- 238000002001 electrophysiology Methods 0.000 description 1
- BAVONGHXFVOKBV-UHFFFAOYSA-N exo-carveol Natural products CC(=C)C1CC=C(C)C(O)C1 BAVONGHXFVOKBV-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 238000010137 moulding (plastic) Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000001932 seasonal effect Effects 0.000 description 1
- 239000003620 semiochemical Substances 0.000 description 1
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Abstract
The invention discloses application of monoterpene and monoterpene alcohol as attractants of tomicus minor hartig consi and an attractant of tomicus minor hartig. One or more of the following components act as the application of the attractant of tomicus minor hartig consi: S-(-)-alpha-pinene, IR-(+)-alpha-pinene, myrcene, (+)-camphenee, (-)-camphene, alpha-terpinene, (+)-3-carnene, (1s)-(-)-beta-pinene, (-)-limonene, (+)-limonene, (-)-Myrtenol, (s)-cis-verbenol, (-)-trans-verbenol and cuparene.
Description
Technical field
The present invention relates to terpenes and monoterpenol as the application of ordinary bending attractant and the new component of ordinary bending attractant and new formula.
Background technology
Ordinary bending (Tomicus.minor Hartig) is a kind of important trunk borer, the multiple kind of the Eurasian Pinus of serious harm.At present, the research of studies in China to ordinary bending mainly concentrates on biology, hazard profile, infochemical and Prevention Technique etc.According to the investigation of applicant, as follows in Yunnan prevention and control bark beetle major measure at present: 1. to strengthen quarantine, forbid allocation and transportation to harm wood.2. wood of harming is cleared up.For preventing insect pest from spreading, all for woodland wood of being injured being felled, and under the supervision of technical staff, carries out medicament fumigating or burn process.3. trap-tree trapping.In bark beetle Burst Regions, Stochastic choice is injured trap-tree cuting down, and is placed in woodland, lures bark beetle, finally process trap-tree.4. chemical control.The method mainly to every strain be injured wood carry out punching moth medicine.
Cleaning wood of harming can leak and cuts down and cause large batch of pine tree to be forced to cut down.The lasting effect of trap-tree trapping is poor, operates constant, if the process of bait wood not in time, also can cause more harm.Punching moth medicine is time-consuming, and cost is high, large area control difficulty.Chemical control contaminated environment, destroys the balance of forest ecosystem; The Forest Tourism Resources in Yunnan is very abundant, how to protect pinus yunnanensis, and local government and forest department pay much attention to, but up to the present, production never has the method for relatively reasonable, more effective Supervise prevention and cure.
Along with the fast development of chemiecology, utilize the infochemical of insect to carry out prevention and control bark beetle and well confirmed abroad.The method, efficiently, environmental friendliness, location is strong.Foreign scholar carried out research to horizontal Hangzhoupro tangent epiderivative attractant.α-terpineol in Kangas etc. (1970) discovery Volatiles of Pinus and genial trans-carveol have attracting action to this worm.Lanne etc. (1987) determine 3-carene-10-alcohol in its both sexes hindgut by GC-MS, trans verbenol and myrtenol content higher, and bore moth to product fat phloem-xylem interface time content the highest; When EAG tests, the activity of trans verbenol is the strongest, is secondly cis verbenol; In field test, there is the juggle of female worm than what do not have and can lure more bark beetle, show that female worm produces gathering information, meanwhile, only have and just can lure bark beetle with the juggle of trans verbenol and the process of (1S, 6R)-3-carene-10-alcohol; This shows that this worm utilizes host's volatile matter to synthesize primary data usually to lure other bark beetle of the same race to come to assemble and mating.
In January, 2010, applicant traps China's woodland ordinary bending with the external special core that lures of ordinary bending introduced, and finds that its effect is bad, not as trap-tree.Owing to occurring in the ordinary bending environmental condition of China and host from external completely different, its infochemical is also different, in addition some compositions of external report are (as (1S, 6R)-3-carene-10-alcohol) can't buy at home, and same composition is not found yet in we are to the analysis of Yunnan Province of China ordinary bending hindgut volatile matter, and external commodity lure the composition of core also underground.So the ordinary bending that the present patent application person occurs for Yunnan Province of China has subsequently carried out the researchs such as the chemical analysis of deep electro physiology, behaviouristics and infochemical, fill a prescription with new according to the attractant new component that result of study is developed for China's ordinary bending.It is below the particular content of this attractant.
Summary of the invention
The object of this invention is to provide the attractant new component relating to terpenes and monoterpenol terpenes that a kind of ordinary bending for China is developed and the application of newly filling a prescription.
Another object of the present invention be to provide a kind of have efficient, environmentally friendly, to person poultry safety, the ordinary bending attractant that do not make insect develop immunity to drugs.
For achieving the above object, the present invention takes following technical scheme:
S-(-)-australene (S-(-)-α-pinene), 1R-(+)-australene (1R-(+)-α-pinene), laurene (myrcene), (+)-down alkene ((+)-camphene), (-)-amphene ((-)-camphene), α-terpinene (α-terpinene), (+)-3-carene ((+)-3-carene), (1S)-(-)-nopinene ((1s)-(-)-β-pinene), (-)-citrene ((-)-limonene), (+)-citrene ((+)-limonene), (-)-myrtenol ((-)-Myrtenol), (S)-cis-verbenol (s)-cis-verbenol, one or more application as ordinary bending attractant in (-)-trans-verbenol ((-)-trans-verbenol) and cuparene (Cuparene).
The present invention utilizes host and polypide volatile matter attractant to attract a large amount of ordinary bending in a large number, make it be gathered in certain device to be killed again, have cost low, efficient, completely environmentally friendly, to person poultry safety, do not make the advantages such as insect develops immunity to drugs, in the past passive chemical control is made to become biological control initiatively, simultaneously can also according to ordinary bending quantity in trapper number, reach the object of monitoring and forecast forestry insect pest.
A kind of ordinary bending attractant, this attractant is by S-(-)-australene, 1R-(+)-australene, laurene, (+)-down alkene, (-)-amphene, α-terpinene, (1S)-(-)-nopinene, (-)-citrene, (+)-citrene, (-)-myrtenol and cuparene composition, described S-(-)-australene, 1R-(+)-australene, laurene, (+)-down alkene, (-)-amphene, α-terpinene, (1S)-(-)-nopinene, (-)-citrene, (+)-citrene, the volume ratio of (-)-myrtenol and cuparene is: 5-10: 1-3: 1-3: 1-3: 0.2-0.5: 0.05-0.1: 1-5: 0.01-0.1: 0.01-0.1: 0.01-0.1: 0.05-0.3.
Preferably, the volume ratio of described S-(-)-australene, 1R-(+)-australene, laurene, (+)-down alkene, (-)-amphene, α-terpinene, (1S)-(-)-nopinene, (-)-citrene, (+)-citrene, (-)-myrtenol and cuparene is: 8: 1: 1.5: 1.5: 0.3: 0.07: 3.75: 0.03: 0.07: 0.07: 0.13.
A kind of ordinary bending attractant, this attractant is by S-(-)-australene, 1R-(+)-australene, laurene, (+)-down alkene, (-)-amphene, α-terpinene, (1S)-(-)-nopinene, (-)-citrene, (+)-citrene, (-)-myrtenol, (S)-cis-verbenol, (-)-trans-verbenol and cuparene composition, described S-(-)-australene, 1R-(+)-australene, laurene, (+)-down alkene, (-)-amphene, α-terpinene, (1S)-(-)-nopinene, (-)-citrene, (+)-citrene, (-)-myrtenol, (S)-cis-verbenol, the volume ratio of (-)-trans-verbenol and cuparene is: 30-50: 10-20: 5-10: 1-3: 4-8: 1-5: 0.1-0.5: 0.01-0.1: 0.05-0.3: 0.05-0.3: 0.01-0.05: 0.005-0.15: 0.01-0.05: 0.1-1, wherein, S-(-)-australene, 1R-(+)-australene, laurene, (+)-down alkene, (-)-amphene, α-terpinene, (1S)-(-)-nopinene, (-)-citrene, (+)-citrene, (-)-myrtenol, (-)-trans-verbenol and cuparene are all in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
Preferably, the volume ratio of described S-(-)-australene, 1R-(+)-australene, laurene, (+)-down alkene, (-)-amphene, α-terpinene, (1S)-(-)-nopinene, (-)-citrene, (+)-citrene, (-)-myrtenol, (S)-cis-verbenol, (-)-trans-verbenol and cuparene is: 39: 14: 9: 7: 3: 0.35: 0.05: 0.18: 0.16: 0.03: 0.01: 0.03: 0.5; Wherein, S-(-)-australene, 1R-(+)-australene, laurene, (+)-down alkene, (-)-amphene, α-terpinene, (1S)-(-)-nopinene, (-)-citrene, (+)-citrene, (-)-myrtenol, (-)-trans-verbenol and cuparene are all in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
A kind of ordinary bending attractant, this attractant is made up of S-(-)-australene, 1R-(+)-australene, laurene, (-)-myrtenol, (s)-cis-verbenol, (-)-trans-verbenol, and the volume ratio of described S-(-)-australene, 1R-(+)-australene, laurene, (-)-myrtenol, (s)-cis-verbenol, (-)-trans-verbenol is 25-100: 25-100: 1-10: 0.1-1: 0.075-0.5: 0.075-0.5; Wherein, S-(-)-australene, 1R-(+)-australene, laurene, (-)-myrtenol, (-)-trans-verbenol are all in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
Preferably, described S-(-)-australene, 1R-(+)-a-firpene, laurene, (-)-myrtenol, the volume ratio of (s)-cis-verbenol, (-)-trans-verbenol is 50: 50: 5: 0.5: 0.125: 0.125; ; Wherein, S-(-)-australene, 1R-(+)-australene, laurene, (-)-myrtenol, (-)-trans-verbenol are all in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
A kind of ordinary bending attractant, this attractant is by (1S)-(-)-australene, laurene and (s)-cis-verbenol composition, described (1S)-(-)-australene, the volume ratio of laurene and (s)-cis-verbenol is 25-100: 1-10: 0.075-0.5; Wherein, (1S)-(-)-australene, laurene is all in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
Preferably, described (1S)-(-)-australene, the volume ratio of laurene and (s)-cis-verbenol is 50: 5: 0.125; Wherein, (1S)-(-)-australene, laurene is all in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
A kind of ordinary bending attractant, this attractant is made up of S-(-)-australene, 1R-(+)-australene, (s)-cis-verbenol, and the volume ratio of described S-(-)-australene, 1R-(+)-australene, (s)-cis-verbenol is: 25-100: 25-100: 0.075-0.5; Wherein, S-(-)-australene, 1R-(+)-australene are all in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
Preferably, the volume ratio of described S-(-)-australene, 1R-(+)-australene, (s)-cis-verbenol is: 50: 50: 0.125; Wherein, S-(-)-australene, 1R-(+)-australene are all in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
A kind of ordinary bending attractant, this attractant is made up of S-(-)-australene, (-)-myrtenol and (s)-cis-verbenol, and the volume ratio of described S-(-)-australene, (-)-myrtenol and (s)-cis-verbenol is 25-100: 0.1-1: 0.075-0.5; Wherein, S-(-)-australene, (-)-myrtenol are all in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
Preferably, the volume ratio of described S-(-)-australene, (-)-myrtenol and (s)-cis-verbenol is 50: 0.5: 0.125; Wherein, S-(-)-australene, (-)-myrtenol are all in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
A kind of ordinary bending attractant, this attractant is made up of S-(-)-australene, (s)-cis-verbenol, (-)-trans-verbenol, and the volume ratio of described S-(-)-australene, (s)-cis-verbenol, (-)-trans-verbenol is 25-100: 0.075-0.5: 0.075-0.5; Wherein, S-(-)-australene, (-)-trans-verbenol are all in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
Preferably, the volume ratio of described S-(-)-australene, (s)-cis-verbenol, (-)-trans-verbenol is 50: 0.125: 0.125; Wherein, S-(-)-australene, (-)-trans-verbenol are all in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
A kind of ordinary bending attractant, this attractant is made up of S-(-)-australene and (s)-cis-verbenol, and described S-(-)-australene, cis-verbenol volume ratio is 25-100: 0.075-0.5; Wherein, S-(-)-australene is in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
Preferably, the volume ratio of described S-(-)-australene, (s)-cis-verbenol is 50: 0.125: 0.125; Wherein, S-(-)-australene is in units of ml, and (S)-cis-verbenol is solid, with cm
3for unit.
The advantage of patent of the present invention is:
1, lure ordinary bending more much lower than traditional chemical pest control cost with the infochemical of host and polypide, the terpenes preparation (offering on the net: 7800 yuan/ton) of domestic Production in Chemical Plant is comparatively at a low price external, and 10ml terpenes (amounting to about 0.08 yuan) can use 2 first quarter moons continuously.The method economical and effective, can save a large amount of manpower and materials.
2, the use of attractant is not subject to seasonal restrictions and energy Long-Time Service, become a cadre whole time period of harm at Yunnan ordinary bending can trapping pests, and chemical control and the killed wood of cleaning need to implement at a certain special time period, too early or cross all impact effects in evening.Therefore, invention is trying to explore and putting into practice frontier science and technology, has important scientific value and social value.
3, the present invention utilizes and attracts Yunnan ordinary bending in a large number containing host and polypide semiochemicals, make it be gathered in certain device to be killed again, there is efficient, complete environmental friendliness, to person poultry safety, do not make the advantages such as insect develops immunity to drugs, make in the past passive chemical control become biological control initiatively.
4, according to the number of ordinary bending quantity in trapper, reach the object of monitoring and forecast forestry insect pest.
Accompanying drawing explanation
Fig. 1 is the average trapping value chart (2010 year December to 2011 year April, Yuxi) of different disposal (i.e. the process of A, B, C, D, E and F different formulations) to male and female ordinary bending of embodiment 1.
Fig. 2 is the average trapping spirogram table (2011 year December to 2012 year February, Yuxi) of different disposal (i.e. the process of D, K, L, M, N, O and U different formulations) to male and female ordinary bending of embodiment 2.Embodiment
Yunnan of the present invention ordinary bending attractant is through continuous result of carrying out testing experiment for 2 years in North Mountain Forestry Center, Yuxi, Yunnan.The purity of compound used therefor and manufacturer are in table 1.(sample purity wherein, in table 1 is percent by volume) (not having the numeral of percentage sign also still to represent after numeral is percent by volume)
The mixed liquor of 40mL is loaded the slowly-releasing bottle (three one-tenth, Xiaodian District, Shanxi province Taiyuan city plastic molding and processing plant produces) of 100mL, the release rate of this slowly-releasing bottle s-(-)-australene s-(-)-α-pinene 20 DEG C time is about 50mg/d.The wide 37cm of cross trapper height 81cm (middle prompt four directions, Beijing), bottom has a plastic collection bottle.Slowly-releasing bottle is fixed on trapper bottom.Trapper hangs between the pine tree of woodland Yunnan, bottom is liftoff 1.5m, interval 40m.
Embodiment 1:2010 December, field test test is carried out in forest farm, the Beishan Mountain, Yuxi, according to to be injured and for the analysis of the pinus yunnanensis volatile matter of being injured and ordinary bending hindgut chemical substance and ordinary bending are to the Electroantennogram response of different chemical material, be configured with 3 formulas, as shown in the table.Wherein C is that external ordinary bending commodity lure core, and ABD is formula of the present invention, is doubled to obtain E by the release rate of A process, and F only hangs trapper and makes blank.The composition of each formula and ratio are in table 2.Often process repetition 3 times, every investigation in 5 days once, and trapper is exchanged at random.
The sample purity of table 1 main volatile standard items and manufacturer
The different disposal of table 22010 field test in year December
Note: the unit of (s)-cis-verbenol is cm
3, the unit of all the other compounds is ml.Lower same.
From on April 18,20 days to 2011 December in 2010, lure the female worm of ordinary bending 335 and male worm 287 in the test in forest farm, the Beishan Mountain, Yuxi, the otherness between each process is shown in Fig. 2, female worm (F=50.241; Df=5,12; P=0.0001); Male worm (F=29.47; Df=5,12; P=0.0001).The trapping amount of all formulas of the present invention, all apparently higher than contrast, has illustrated attracting action, and the ordinary bending that wherein D process is lured obviously processes (see Fig. 1) more than other.
Embodiment 2: carry out in forest farm, the Beishan Mountain, Yuxi 15, on February of in December, 2011 to 2012, on the basis of test in 2010, by research, further improvement lures core formula, designs 6 formulas altogether, is respectively D, K, L, M, N and O, wherein D is the formula being better than luring core for 2010 abroad, in addition, U is for cuting down pinus yunnanensis in contrast, and the composition of other process and ratio are in table 2.Each process repeats to be 5 times.Other condition is with embodiment 1.
The different disposal of table 32011 field test in year December
Note: U is the pinus yunnanensis be slightly injured, in contrast.
In embodiment 2, lure the female worm of ordinary bending 315 and male worm 312, female worm (F=24.952; Df=6,28, P=0.0001), male worm (F=21.247; Df=6,28; P=0.0001).Result shows, all new formulas optimum formula of relative 2010 and trap-tree of being injured, and attractant effect all increases, and the N that wherein fills a prescription obviously is better than fill a prescription K, L, M, the attractant effect best (see Fig. 2) of formula O.
Claims (17)
- One or more application as ordinary bending attractant in 1.S-(-)-australene, 1R-(+)-australene, laurene, (+)-down alkene, (-)-amphene, α-terpinene, (+)-3-carene, (1S)-(-)-nopinene, (-)-citrene, (+)-citrene, (-)-myrtenol, (S)-cis-verbenol, (-)-trans-verbenol and cuparene.
- 2. an ordinary bending attractant, it is characterized in that, described attractant is by S-(-)-australene, 1R-(+)-australene, laurene, (+)-down alkene, (-)-amphene, α-terpinene, (1S)-(-)-nopinene, (-)-citrene, (+)-citrene, (-)-myrtenol and cuparene composition, described S-(-)-australene, 1R-(+)-australene, laurene, (+)-down alkene, (-)-amphene, α-terpinene, (1S)-(-)-nopinene, (-)-citrene, (+)-citrene, the volume ratio of (-)-myrtenol and cuparene is: 5-10: 1-3: 1-3: 1-3: 0.2-0.5: 0.05-0.1: 1-5: 0.01-0.1: 0.01-0.1: 0.01-0.1: 0.05-0.3.
- 3. ordinary bending attractant according to claim 2, it is characterized in that, in described attractant, the volume ratio of S-(-)-australene, 1R-(+)-australene, laurene, (+)-down alkene, (-)-amphene, α-terpinene, (1S)-(-)-nopinene, (-)-citrene, (+)-citrene, (-)-myrtenol and cuparene is: 8: 1: 1.5: 1.5: 0.3: 0.07: 3.75: 0.03: 0.07: 0.07: 0.13.
- 4. an ordinary bending attractant, is characterized in that, described attractant is by S-(-)-australene, 1R-(+)-australene, laurene, (+)-down alkene, (-)-amphene, α-terpinene, (1S)-(-)-nopinene, (-)-citrene, (+)-citrene, (-)-myrtenol, (S)-cis-verbenol, (-)-trans-verbenol and cuparene composition, described S-(-)-australene, 1R-(+)-australene, laurene, (+)-down alkene, (-)-amphene, α-terpinene, (1S)-(-)-nopinene, (-)-citrene, (+)-citrene, (-)-myrtenol, (S)-cis-verbenol, the volume ratio of (-)-trans-verbenol and cuparene is: 30-50: 10-20: 5-10: 1-3: 4-8: 1-5: 0.1-0.5: 0.01-0.1: 0.05-0.3: 0.05-0.3: 0.01-0.05: 0.005-0.15: 0.01-0.05: 0.1-1, wherein, S-(-)-australene, 1R-(+)-australene, laurene, (+)-down alkene, (-)-amphene, α-terpinene, (1S)-(-)-nopinene, (-)-citrene, (+)-citrene, (-)-myrtenol, (-)-trans-verbenol and cuparene are all in units of ml, and (S)-cis-verbenol is solid, with cm 3for unit.
- 5. ordinary bending attractant according to claim 4, it is characterized in that, described S-(-)-australene, 1R-(+)-australene, laurene, (+)-down alkene, (-)-amphene, α-terpinene, (1S)-(-)-nopinene, (-)-citrene, (+)-citrene, (-)-myrtenol, (S)-cis-verbenol, the volume ratio of (-)-trans-verbenol and cuparene is: 39: 14: 9: 7: 3: 0.35: 0.05: 0.18: 0.16: 0.03: 0.01: 0.03: 0.5.
- 6. an ordinary bending attractant, it is characterized in that, described attractant is by S-(-)-australene, 1R-(+)-australene, laurene, (-)-myrtenol, (s)-cis-verbenol, (-)-trans-verbenol composition, described S-(-)-australene, 1R-(+)-australene, laurene, (-)-myrtenol, (s)-cis-verbenol, the volume ratio of (-)-trans-verbenol is 25-100: 25-100: 1-10: 0.1-1: 0.075-0.5: 0.075-0.5, wherein, S-(-)-australene, 1R-(+)-australene, laurene, (-)-myrtenol, (-)-trans-verbenol are all in units of ml, and (S)-cis-verbenol is solid, with cm 3for unit.
- 7. ordinary bending attractant according to claim 6, it is characterized in that, described S-(-)-australene, 1R-(+)-a-firpene, laurene, (-)-myrtenol, the volume ratio of (s)-cis-verbenol, (-)-trans-verbenol is 50ml: 50ml: 5ml: 0.5ml: 0.125cm 3: 0.125ml.
- 8. an ordinary bending attractant, it is characterized in that, described attractant is by (1S)-(-)-australene, laurene and (s)-cis-verbenol composition, described (1S)-(-)-australene, the volume ratio of laurene and (s)-cis-verbenol is 25-100: 1-10: 0.075-0.5; Wherein, (1S)-(-)-australene, laurene is all in units of ml, and (S)-cis-verbenol is solid, with cm 3for unit.
- 9. ordinary bending attractant according to claim 8, is characterized in that, described (1S)-(-)-australene, and the volume ratio of laurene and (s)-cis-verbenol is 50: 5: 0.125.
- 10. an ordinary bending attractant, it is characterized in that, described attractant is made up of S-(-)-australene, 1R-(+)-australene, (s)-cis-verbenol, and the volume ratio of described S-(-)-australene, 1R-(+)-australene, (s)-cis-verbenol is: 25-100: 25-100: 0.075-0.5; Wherein, S-(-)-australene, 1R-(+)-australene are all in units of ml, and (S)-cis-verbenol is solid, with cm 3for unit.
- 11. ordinary bending attractants according to claim 10, it is characterized in that, the volume ratio of described S-(-)-australene, 1R-(+)-australene, (s)-cis-verbenol is: 50: 50: 0.125.
- 12. 1 kinds of ordinary bending attractants, it is characterized in that, described attractant is made up of S-(-)-australene, (-)-myrtenol and (s)-cis-verbenol, and the volume ratio of described S-(-)-australene, (-)-myrtenol and (s)-cis-verbenol is 25-100: 0.1-1: 0.075-0.5; Wherein, S-(-)-australene, (-)-myrtenol are all in units of ml, and (S)-cis-verbenol is solid, with cm 3for unit.
- 13., according to ordinary bending attractant described in claim 12, is characterized in that, the volume ratio of described S-(-)-australene, (-)-myrtenol and (s)-cis-verbenol is 50: 0.5: 0.125.
- 14. 1 kinds of ordinary bending attractants, it is characterized in that, described attractant is made up of S-(-)-australene, (s)-cis-verbenol, (-)-trans-verbenol, and the volume ratio of described S-(-)-australene, (s)-cis-verbenol, (-)-trans-verbenol is 25-100: 0.075-0.5: 0.075-0.5; Wherein, S-(-)-australene, (-)-trans-verbenol are all in units of ml, and (S)-cis-verbenol is solid, with cm 3for unit.
- 15. according to ordinary bending attractant described in claim 14, it is characterized in that, the volume ratio of described S-(-)-australene, (s)-cis-verbenol, (-)-trans-verbenol is 50: 0.125: 0.125.
- 16. 1 kinds of ordinary bending attractants, it is characterized in that, described attractant is made up of S-(-)-australene and (s)-cis-verbenol, and described S-(-)-australene, cis-verbenol volume ratio is 25-100: 0.075-0.5; Wherein, S-(-)-australene is in units of ml, and (S)-cis-verbenol is solid, with cm 3for unit.
- 17., according to ordinary bending attractant described in claim 16, is characterized in that, the volume ratio of described S-(-)-australene, (s)-cis-verbenol is 50: 0.125.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410133308.3A CN104970017B (en) | 2014-04-03 | 2014-04-03 | Components and formula of attractant of tomicus minor hartig |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410133308.3A CN104970017B (en) | 2014-04-03 | 2014-04-03 | Components and formula of attractant of tomicus minor hartig |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104970017A true CN104970017A (en) | 2015-10-14 |
| CN104970017B CN104970017B (en) | 2017-04-12 |
Family
ID=54267447
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410133308.3A Expired - Fee Related CN104970017B (en) | 2014-04-03 | 2014-04-03 | Components and formula of attractant of tomicus minor hartig |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104970017B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106070288A (en) * | 2016-06-03 | 2016-11-09 | 华南农业大学 | A kind of pine tumor is as attractant |
| CN109793013A (en) * | 2019-02-02 | 2019-05-24 | 杭州科森农化有限公司 | A kind of coleopteron attractant |
| CN116158427A (en) * | 2023-02-21 | 2023-05-26 | 黑龙江省森林保护研究所 | Plant source attractant for preventing and treating hazelnut real images, and preparation method and application thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0175141A2 (en) * | 1984-08-17 | 1986-03-26 | Shell Internationale Researchmaatschappij B.V. | Insect attractant |
| US6203786B1 (en) * | 1998-07-10 | 2001-03-20 | The Research Foundation Of State University Of New York | Pine shoot beetle attractant compositions |
| US20060198860A1 (en) * | 2005-03-07 | 2006-09-07 | Phero Tech Inc. | Synergistic blends of monoterpenes for mountain pine beetle pheromones |
| CN101069503A (en) * | 2006-05-11 | 2007-11-14 | 中国科学院动物研究所 | Luring agent for luring and collecting Dendroctonus valens |
| CN101390514A (en) * | 2008-11-12 | 2009-03-25 | 青海省森林病虫害防治检疫总站 | Aggregation pheromone attractant for attracting shangrila dentate bark beetle |
| CN101611709A (en) * | 2009-07-30 | 2009-12-30 | 孙晓玲 | A kind of attractant that is used for attracting ips typographus together |
| CN101863750A (en) * | 2010-06-08 | 2010-10-20 | 中国科学院长春应用化学研究所 | Synthesis method of oxygen-containing derivative bark beetle pheromone verbena ketene of alpha-pinene and verbenol |
-
2014
- 2014-04-03 CN CN201410133308.3A patent/CN104970017B/en not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0175141A2 (en) * | 1984-08-17 | 1986-03-26 | Shell Internationale Researchmaatschappij B.V. | Insect attractant |
| US6203786B1 (en) * | 1998-07-10 | 2001-03-20 | The Research Foundation Of State University Of New York | Pine shoot beetle attractant compositions |
| US20060198860A1 (en) * | 2005-03-07 | 2006-09-07 | Phero Tech Inc. | Synergistic blends of monoterpenes for mountain pine beetle pheromones |
| CN101069503A (en) * | 2006-05-11 | 2007-11-14 | 中国科学院动物研究所 | Luring agent for luring and collecting Dendroctonus valens |
| CN101390514A (en) * | 2008-11-12 | 2009-03-25 | 青海省森林病虫害防治检疫总站 | Aggregation pheromone attractant for attracting shangrila dentate bark beetle |
| CN101611709A (en) * | 2009-07-30 | 2009-12-30 | 孙晓玲 | A kind of attractant that is used for attracting ips typographus together |
| CN101863750A (en) * | 2010-06-08 | 2010-10-20 | 中国科学院长春应用化学研究所 | Synthesis method of oxygen-containing derivative bark beetle pheromone verbena ketene of alpha-pinene and verbenol |
Non-Patent Citations (1)
| Title |
|---|
| 王红伟等: "横坑切梢小蠹对植物挥发物的电生理和行为反应", 《生态学杂志》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106070288A (en) * | 2016-06-03 | 2016-11-09 | 华南农业大学 | A kind of pine tumor is as attractant |
| CN109793013A (en) * | 2019-02-02 | 2019-05-24 | 杭州科森农化有限公司 | A kind of coleopteron attractant |
| CN116158427A (en) * | 2023-02-21 | 2023-05-26 | 黑龙江省森林保护研究所 | Plant source attractant for preventing and treating hazelnut real images, and preparation method and application thereof |
| CN116158427B (en) * | 2023-02-21 | 2023-08-15 | 黑龙江省森林保护研究所 | Plant source attractant for preventing and treating hazelnut real images, and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104970017B (en) | 2017-04-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103563896B (en) | Monochamus alternatus hope attractant and application thereof | |
| CN102027901B (en) | Adult monochamus alternatus hope attractant | |
| CN106900704B (en) | Sex attractant core for fruit tree pest oriental fruit moth | |
| Fettig et al. | The effects of mechanical fuel reduction treatments on the activity of bark beetles (Coleoptera: Scolytidae) infesting ponderosa pine | |
| CN100425138C (en) | Luring agent for luring and collecting Dendroctonus valens | |
| CN104970017A (en) | Components and formula of attractant of tomicus minor hartig | |
| CN113068695A (en) | Sex attractant for oriental fruit moth, lure and preparation method and application thereof | |
| JP2013177359A (en) | Sex pheromone composition of peach fruit moth and attractant comprising the same | |
| CN101822246B (en) | Yunnan Pissodes radiatae Hopkins attractant | |
| KR101786830B1 (en) | Dispenser of aggregation pheromones and composition comprising it for luring Hemiptera | |
| CN104970016B (en) | Attractant of tomicus yunnanensis | |
| CN105145557B (en) | A kind of citrus fruit fly sex pheromone | |
| CN104996422A (en) | Othaga achatina butler sex attractant composition and application thereof | |
| CN101926326B (en) | Pissodes punctatus attractant | |
| CN105746511B (en) | A kind of attractant of ips typographus | |
| CN101406180B (en) | Method for attracting Ips typographus using pheromone | |
| CN106614578A (en) | Ips attractant | |
| CN103004903B (en) | Phyllo treta striolata attractant | |
| CN105052924B (en) | Caragana microphylla looper gyplure | |
| CN104814009B (en) | Larch bark bcetle worm repellant and lure and preparation method thereof | |
| CN105052927A (en) | Tea geometrid male adult attractant based on tea plant volatile matter | |
| CN100438759C (en) | Use of verbenote repellent | |
| CN105325463A (en) | Insecticidal composition | |
| CN103392700A (en) | Adelphocoris suturalis sex attractant and application thereof | |
| CN105494336A (en) | Botanical attractant composition for isoceras sibirica and application method of botanical attractant composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170412 |