CN104962002A - Preparation method for polyvinyl chloride material for medical mask - Google Patents
Preparation method for polyvinyl chloride material for medical mask Download PDFInfo
- Publication number
- CN104962002A CN104962002A CN201510370591.6A CN201510370591A CN104962002A CN 104962002 A CN104962002 A CN 104962002A CN 201510370591 A CN201510370591 A CN 201510370591A CN 104962002 A CN104962002 A CN 104962002A
- Authority
- CN
- China
- Prior art keywords
- preparation
- medical mask
- parts
- pvc material
- polyvinyl chloride
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Materials For Medical Uses (AREA)
Abstract
The invention discloses a preparation method for a polyvinyl chloride material for a medical mask. The method comprises the following steps that, firstly, all the components are thrown into a high speed stirring machine according to weight proportion, and stirring and mixing are carried out for 20-40 minutes; secondly, the evenly mixed materials are added to a double-screw extrusion machine to be melted, plasticized, extruded and pelletized to obtain the polyvinyl chloride material for the medical mask. The preparation method is short in procedure, easy to operate, low in cost, environmentally friendly and high in economic benefit. Compared with the prior art, the polyvinyl chloride material for the medical mask prepared through the method has excellent biocompatibility and safety, and the performance of the material is better than that of related products on the market.
Description
Technical field
The invention belongs to polymeric material field, relate to a kind of preparation method of medical mask pvc material.
Technical background
Plastics, as a kind of very important material, are widely applied at medicine and hygiene fields.It both can be made into disposable medical instrument as dropping bottle, syringe etc., can be used for again non-once medical facilities as gauger, surgery instrument etc., and medical plastic field is current plastics industry one of market having development potentiality most.
Along with the sustainable growth of population in the world quantity, particularly aging populations and the increase of number suffering from chronic disease, facilitate the sustainable growth of medical services market, special medical apparatus obtains widespread demand.Due to macromolecular material excellent specific property and also can reduce costs, at present, medical treatment product and apparatus are from large-scale diagnostic instrments, disposable medical article so that meticulous artificial organ all be unable to do without macromolecular material, and macromolecular material becomes one of important raw and processed materials of medical treatment product and apparatus gradually.And at present, in respiratory system field, the plastics relevant to respirator are that plastics apply one of the most concentrated field in medicine equipment, face shield uses one of maximum plastics in medical instruments field, and these goods are mostly prepared from by materials such as polyethylene, polyvinyl chloride, polypropylene, rubber.The product of this class is the easily-consumed products that quantity is larger, and China consumes the value of this series products every year at about several hundred million yuans, and market is very huge.Current China can autonomous production respirator and associated plastic goods thereof, but due to factors such as product finenesses, product is mainly used in small and medium-sized cities and vast Rural areas or outlet, and mainly apply as metropolitan markets such as Beijing-Tianjin Shanghai or external imported product, therefore the market space is still very large.Due to contact with liquid or and human contact, the basic demand of medical grade plastic materials has chemical stability and biological safety.In simple terms, the moiety in plastic material can not be separated out and enter liquid or human body, can not cause toxicity and the damage of histoorgan, is nontoxic to human body.For improving blood compatibility, the histocompatibility of goods, need the modifying surface to goods.The plastic tool anti-infection property of interposing catheter and life-time service is also one of research and development direction of current medical grade plastic materials.In sum, a kind of property separated out is low, security is high medical mask plastic material is badly in need of providing to be this area technical problem urgently to be resolved hurrily.
Summary of the invention
The object of the invention is to for the deficiencies in the prior art, a kind of preparation method of medical mask pvc material is provided.
The object of the invention is to be achieved through the following technical solutions: a kind of preparation method of medical mask pvc material, said method comprising the steps of: the 1st step, by weight, by polyvinyl chloride 80-90 part, polyacrylic rubber 50-60 part, polyvinylpyrrolidone 12-15 part, silicon rubber 20-30 part, isoprene-isobutylene rubber 20-30 part, acetyl citrate 4-14 part, magnesium borate crystal whisker 2-7 part, nucleator 4-12 part, antiseptic-germicide 4-8 part, straw powder 5-15 part, multipolymer 3-5 part of vinylbenzene and divinyl, calcium carbonate 2-4 part, fimbrin 3-8 part, 2-thiol group benzimidazolyl 3-7 part and toughner 10-14 part are dropped in homogenizer, be uniformly mixed 20 ~ 40 minutes, 2nd step, the material mixed joined melting in twin screw extruder, plastify, extrude, granulation, to obtain final product.
Described extrusion temperature is 140 ~ 160 DEG C.Described nucleator is (3,4-dimethyl two benzal) sorbyl alcohol or methylene-bis (2,4-di-tert-butyl-phenyl) phosphoric acid ester oxyaluminum salt.
Described toughner is grafting maleic anhydride with ethylene propylene terpolymer.
Described antiseptic-germicide is nano silver inorganic antimicrobial agent or primary ammonium phosphate.
The present invention has following beneficial effect: preparation method's flow process of the present invention is shorter, simple to operate, and cost is low, environmentally friendly, high financial profit.Compared with prior art, the medical mask pvc material that the method for the invention provides is prepared has excellent biocompatibility and security, be all better than the performance of existing related products on the market, and its intensity is high, good mechanical property.
Embodiment
embodiment 1
A kind of preparation method of medical mask pvc material, said method comprising the steps of: by the 1st step, by weight, by in the multipolymer 3 parts of polyvinyl chloride 80 parts, polyacrylic rubber 50 parts, polyvinylpyrrolidone 12 parts, 20 parts, silicon rubber, isoprene-isobutylene rubber 20 parts, acetyl citrate 4 parts, magnesium borate crystal whisker 2 parts, nucleator 4 parts, antiseptic-germicide 4 parts, straw powder 5 parts, vinylbenzene and divinyl, 2 parts, calcium carbonate, fimbrin 3 parts, 2-thiol group benzimidazolyl 3 parts and toughner 10 parts of input homogenizers, be uniformly mixed 20 ~ 40 minutes; 2nd step, the material mixed joined melting in twin screw extruder, plastify, extrude, granulation, to obtain final product.
Described extrusion temperature is 140 ~ 160 DEG C.Described nucleator is (3,4-dimethyl two benzal) sorbyl alcohol or methylene-bis (2,4-di-tert-butyl-phenyl) phosphoric acid ester oxyaluminum salt.
Described toughner is grafting maleic anhydride with ethylene propylene terpolymer.
Described antiseptic-germicide is nano silver inorganic antimicrobial agent or primary ammonium phosphate.
embodiment 2
A kind of preparation method of medical mask pvc material, said method comprising the steps of: the 1st step, by weight, by in the multipolymer 5 parts of polyvinyl chloride 90 parts, polyacrylic rubber 60 parts, polyvinylpyrrolidone 15 parts, 30 parts, silicon rubber, isoprene-isobutylene rubber 30 parts, acetyl citrate 14 parts, magnesium borate crystal whisker 7 parts, nucleator 12 parts, antiseptic-germicide 8 parts, straw powder 15 parts, vinylbenzene and divinyl, 4 parts, calcium carbonate, fimbrin 8 parts, 2-thiol group benzimidazolyl 7 parts and toughner 14 parts of input homogenizers, be uniformly mixed 20 ~ 40 minutes; 2nd step, the material mixed joined melting in twin screw extruder, plastify, extrude, granulation, to obtain final product.Described extrusion temperature is 140 ~ 160 DEG C.Described nucleator is (3,4-dimethyl two benzal) sorbyl alcohol or methylene-bis (2,4-di-tert-butyl-phenyl) phosphoric acid ester oxyaluminum salt.
Described toughner is grafting maleic anhydride with ethylene propylene terpolymer.
Described antiseptic-germicide is nano silver inorganic antimicrobial agent or primary ammonium phosphate.
embodiment 3
A kind of preparation method of medical mask pvc material, said method comprising the steps of: the 1st step, by weight, by in the multipolymer 4 parts of polyvinyl chloride 85 parts, polyacrylic rubber 55 parts, polyvinylpyrrolidone 14 parts, 25 parts, silicon rubber, isoprene-isobutylene rubber 25 parts, acetyl citrate 7 parts, magnesium borate crystal whisker 4 parts, nucleator 6 parts, antiseptic-germicide 6 parts, straw powder 10 parts, vinylbenzene and divinyl, 3 parts, calcium carbonate, fimbrin 6 parts, 2-thiol group benzimidazolyl 5 parts and toughner 12 parts of input homogenizers, be uniformly mixed 20 ~ 40 minutes; 2nd step, the material mixed joined melting in twin screw extruder, plastify, extrude, granulation, to obtain final product.
Described extrusion temperature is 140 ~ 160 DEG C.Described nucleator is (3,4-dimethyl two benzal) sorbyl alcohol or methylene-bis (2,4-di-tert-butyl-phenyl) phosphoric acid ester oxyaluminum salt.
Described toughner is grafting maleic anhydride with ethylene propylene terpolymer.
Described antiseptic-germicide is nano silver inorganic antimicrobial agent or primary ammonium phosphate.
The above, it is only preferred embodiment of the present invention, not any pro forma restriction is done to the present invention, although the present invention discloses as above with preferred embodiment, but and be not used to limit the present invention, any those skilled in the art, do not departing within the scope of technical solution of the present invention, make a little change when the technology contents of above-mentioned announcement can be utilized or be modified to the Equivalent embodiments of equivalent variations, in every case be the content not departing from technical solution of the present invention, according to any simple modification that technical spirit of the present invention is done above embodiment, equivalent variations and modification, all still belong in the scope of technical solution of the present invention.
Claims (5)
1. the preparation method of a medical mask pvc material, it is characterized in that, said method comprising the steps of: the 1st step, by weight, by polyvinyl chloride 80-90 part, polyacrylic rubber 50-60 part, polyvinylpyrrolidone 12-15 part, silicon rubber 20-30 part, isoprene-isobutylene rubber 20-30 part, acetyl citrate 4-14 part, magnesium borate crystal whisker 2-7 part, nucleator 4-12 part, antiseptic-germicide 4-8 part, straw powder 5-15 part, multipolymer 3-5 part of vinylbenzene and divinyl, calcium carbonate 2-4 part, fimbrin 3-8 part, 2-thiol group benzimidazolyl 3-7 part and toughner 10-14 part are dropped in homogenizer, be uniformly mixed 20 ~ 40 minutes, 2nd step, the material mixed joined melting in twin screw extruder, plastify, extrude, granulation, to obtain final product.
2. the preparation method of a kind of medical mask pvc material according to claim 1, is characterized in that, described extrusion temperature is 140 ~ 160 DEG C.
3. the preparation method of a kind of medical mask pvc material according to claim 1, it is characterized in that, described nucleator is (3,4-dimethyl two benzal) sorbyl alcohol or methylene-bis (2,4-di-tert-butyl-phenyl) phosphoric acid ester oxyaluminum salt.
4. the preparation method of a kind of medical mask pvc material according to claim 1, it is characterized in that, described toughner is grafting maleic anhydride with ethylene propylene terpolymer.
5. the preparation method of a kind of medical mask pvc material according to claim 1, is characterized in that, described antiseptic-germicide is nano silver inorganic antimicrobial agent or primary ammonium phosphate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510370591.6A CN104962002A (en) | 2015-06-30 | 2015-06-30 | Preparation method for polyvinyl chloride material for medical mask |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510370591.6A CN104962002A (en) | 2015-06-30 | 2015-06-30 | Preparation method for polyvinyl chloride material for medical mask |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104962002A true CN104962002A (en) | 2015-10-07 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510370591.6A Pending CN104962002A (en) | 2015-06-30 | 2015-06-30 | Preparation method for polyvinyl chloride material for medical mask |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104962002A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106280342A (en) * | 2016-08-30 | 2017-01-04 | 胡何辉 | A kind of PP composite material being applicable to medical infusion bags and preparation method thereof |
| CN106519512A (en) * | 2016-11-25 | 2017-03-22 | 安徽美翔塑业有限公司 | Rubber material and preparation method thereof |
| CN111154202A (en) * | 2020-03-10 | 2020-05-15 | 奥特路（漳州）光学科技有限公司 | Anti-ultraviolet antibacterial environment-friendly medical eye patch main frame material and manufacturing method thereof |
-
2015
- 2015-06-30 CN CN201510370591.6A patent/CN104962002A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106280342A (en) * | 2016-08-30 | 2017-01-04 | 胡何辉 | A kind of PP composite material being applicable to medical infusion bags and preparation method thereof |
| CN106519512A (en) * | 2016-11-25 | 2017-03-22 | 安徽美翔塑业有限公司 | Rubber material and preparation method thereof |
| CN111154202A (en) * | 2020-03-10 | 2020-05-15 | 奥特路（漳州）光学科技有限公司 | Anti-ultraviolet antibacterial environment-friendly medical eye patch main frame material and manufacturing method thereof |
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| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20151007 |