CN104927526A - Water-borne acrylic amino baking varnish special for intelligent ashtray metal shell - Google Patents
Water-borne acrylic amino baking varnish special for intelligent ashtray metal shell Download PDFInfo
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- CN104927526A CN104927526A CN201510396919.1A CN201510396919A CN104927526A CN 104927526 A CN104927526 A CN 104927526A CN 201510396919 A CN201510396919 A CN 201510396919A CN 104927526 A CN104927526 A CN 104927526A
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- water
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- borne acrylic
- metal shell
- baking vanish
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
Abstract
The invention relates to water-borne acrylic amino baking varnish special for an intelligent ashtray metal shell. The water-borne acrylic amino baking varnish comprises, by weight, 15-17 parts of water, 0.5-0.7 part of dispersing agents, 18-20 parts of organic pigments, 40-50 parts of water-borne acrylic resin, 4.0-5.5 parts of amino resin, 7-9 parts of propanediol butyl ether, 4-6 parts of isopropanol, 4.1-4.3 parts of catalyst, 0.2-0.4 part of defoamer, 0.4-0.6 part of flatting agents, 1.1-1.3 parts of adhesive force improver and 0.8-1.2 parts of PH modifier. The performance of the water-borne acrylic amino baking varnish is changed by adjusting the ratio between the water-borne acrylic resin and the amino resin, the prepared water-borne acrylic amino baking varnish special for the intelligent ashtray metal shell has a reasonable hardness value, good impact resistance, good flexibility, good water resistance and good alcohol resistance and large adhesive force, and therefore the service life of the water-borne acrylic amino baking varnish is prolonged.
Description
Technical field
The present invention relates to a kind of baking vanish, specifically the special-purpose aqueous acrylic-amino baking vanish of a kind of Intelligent ashtray metal shell.
Background technology
Baking vanish, be that one emerging in Furniture manufacture is sprayed paint making method (technique), its method is: in the substrate being polished to certain degree of roughness (normally high density plate material), sprays some layers of paint, and shapes through high bake.This technique is higher to paint requirements at present, and color developing is good.The furniture items such as baking finish process is widely used in moving door, cabinet desk, also start day by day to penetrate in other material surface complete processing.Baking vanish is divided into two large classes, and a class low temperature baking vanish solidification value is 90 °-100 °, and an other class is just called high temperature baking vanish, and its solidification value is 230 °-240 °.
Water soluble acrylic acid amino-stoving varnish owing to having high gloss, hardness, Bao Sebao light, the advantage such as heat-resisting become important industrial coating, be widely used in the goods industries such as automobile, household electrical appliances, pail pack, bike, sewing machine, stapler, bookshelf, play metal finishing and provide protection, a lot of Intelligent ashtray can be seen in existing market, what the metal shell above it sprayed is exactly water soluble acrylic acid amino-stoving varnish, but along with the continuous growth of duration of service, understand some above metal shell on Intelligent ashtray and impact print, and meet waterborne spray paint and easily come off, therefore existing water soluble acrylic acid amino-stoving varnish is in hardness, shock-resistance, snappiness, sticking power, Shortcomings in water tolerance and alcohol resistance, cause the existing water soluble acrylic acid amino-stoving varnish life-span shorter, and the proportioning of water-borne acrylic resin and aminoresin is the hardness affecting paint film, shock-resistance, snappiness, the basic reason of the multiple performance such as water tolerance and alcohol resistance.
Summary of the invention
For above-mentioned technical problem, the invention provides a kind of have good water-borne acrylic resin and aminoresin proportioning, preparation method is easy, the special-purpose aqueous acrylic-amino baking vanish of Intelligent ashtray metal shell that preparation technology is easy, there is rational hardness value, good shock-resistance, snappiness, water tolerance and alcohol resistance, higher sticking power, thus the work-ing life of improving Intelligent ashtray metal shell.
Technical problem to be solved by this invention realizes by the following technical solutions:
The special-purpose aqueous acrylic-amino baking vanish of a kind of Intelligent ashtray metal shell, this baking vanish is made up of the component of following weight part: water 15-17 part, dispersion agent 0.5-0.7 part, pigment dyestuff 18-20 part, water-borne acrylic resin 40-50 part, aminoresin 4.0-5.5 part, propandiol butyl ether 7-9 part, Virahol 4-6 part, catalyzer 4.1-4.3 part, defoamer 0.2-0.4 part, flow agent 0.4-0.6 part, adhesion promoter 1.1-1.3 part and PH conditioning agent 0.8-1.2 part.
As a preferred embodiment of the present invention, described catalyzer is aqueous isopropanol.
A preparation method for the special-purpose aqueous acrylic-amino baking vanish of Intelligent ashtray metal shell, bag following steps:
(1), by the water of 40%, dispersion agent, 30% water-borne acrylic resin put into agitation vat successively, stirrer stir 5-15 minute;
(2), add pigment dyestuff, 35% defoamer, by sand mill, fineness is milled to less than 25 μm, obtained aqueous color paste;
(3), by the water-borne acrylic resin of 70%, aminoresin, propandiol butyl ether, Virahol, catalyzer, flow agent, adhesion promoter, 60% water and defoamer join in clean paint mixing cylinder successively, with high speed dispersor dispersion 5-10 minute, then add PH conditioning agent adjustment pH value;
(4), in paint mixing cylinder, add aqueous color paste obtained in step (2), high speed dispersor dispersion 15-25 minute, then obtains required baking vanish with after 180 order filter-cloth filterings.
The invention has the beneficial effects as follows: the present invention is by the performance by regulating the proportioning of water-borne acrylic resin and aminoresin to change water soluble acrylic acid amino-stoving varnish, the Intelligent ashtray metal shell special-purpose aqueous acrylic-amino baking vanish prepared has rational hardness value, good shock-resistance, snappiness, water tolerance and alcohol resistance, higher sticking power, thus the work-ing life of improving Intelligent ashtray metal shell.
Embodiment
The technique means realized to make the present invention and creation characteristic are easy to understand, and set forth further below to the present invention.
Embodiment one:
The special-purpose aqueous acrylic-amino baking vanish of a kind of Intelligent ashtray metal shell, this baking vanish is made up of the component of following weight part: 15 parts, water, dispersion agent 0.5 part, pigment dyestuff 18 parts, water-borne acrylic resin 40 parts, 5.5 parts, aminoresin, propandiol butyl ether 7 parts, Virahol 4 parts, catalyzer 4.1 parts, defoamer 0.2 part, flow agent 0.4 part, adhesion promoter 1.1 parts and PH conditioning agent 0.8 part.
Described catalyzer is aqueous isopropanol.
A preparation method for the special-purpose aqueous acrylic-amino baking vanish of Intelligent ashtray metal shell, bag following steps:
(1), by the water of 40%, dispersion agent, 30% water-borne acrylic resin put into agitation vat successively, stirrer stirs 5 minutes;
(2), add pigment dyestuff, 35% defoamer, by sand mill, fineness is milled to less than 25 μm, obtained aqueous color paste;
(3), by the water-borne acrylic resin of 70%, aminoresin, propandiol butyl ether, Virahol, catalyzer, flow agent, adhesion promoter, 60% water and defoamer join in clean paint mixing cylinder successively, disperse 5 minutes with high speed dispersor, then add PH conditioning agent adjustment pH value;
(4), in paint mixing cylinder, add aqueous color paste obtained in step (2), high speed dispersor disperses 15 minutes, then obtains required baking vanish with after 180 order filter-cloth filterings.
Embodiment two:
The special-purpose aqueous acrylic-amino baking vanish of a kind of Intelligent ashtray metal shell, this baking vanish is made up of the component of following weight part: 15.5 parts, water, dispersion agent 0.55 part, pigment dyestuff 18.5 parts, water-borne acrylic resin 44 parts, 5.0 parts, aminoresin, propandiol butyl ether 7.5 parts, Virahol 4.5 parts, catalyzer 4.15 parts, defoamer 0.25 part, flow agent 0.45 part, adhesion promoter 1.15 parts and PH conditioning agent 0.9 part.
Described catalyzer is aqueous isopropanol.
A preparation method for the special-purpose aqueous acrylic-amino baking vanish of Intelligent ashtray metal shell, bag following steps:
(1), by the water of 40%, dispersion agent, 30% water-borne acrylic resin put into agitation vat successively, stirrer stirs 7 minutes;
(2), add pigment dyestuff, 35% defoamer, by sand mill, fineness is milled to less than 25 μm, obtained aqueous color paste;
(3), by the water-borne acrylic resin of 70%, aminoresin, propandiol butyl ether, Virahol, catalyzer, flow agent, adhesion promoter, 60% water and defoamer join in clean paint mixing cylinder successively, disperse 7 minutes with high speed dispersor, then add PH conditioning agent adjustment pH value;
(4), in paint mixing cylinder, add aqueous color paste obtained in step (2), high speed dispersor disperses 17 minutes, then obtains required baking vanish with after 180 order filter-cloth filterings.
Embodiment three:
The special-purpose aqueous acrylic-amino baking vanish of a kind of Intelligent ashtray metal shell, this baking vanish is made up of the component of following weight part: 16 parts, water, dispersion agent 0.6 part, pigment dyestuff 19 parts, water-borne acrylic resin 46 parts, 4.7 parts, aminoresin, propandiol butyl ether 8 parts, Virahol 8 parts, catalyzer 4.2 parts, defoamer 0.3 part, flow agent 0.5 part, adhesion promoter 1.2 parts and PH conditioning agent 1.0 parts.
Described catalyzer is aqueous isopropanol.
A preparation method for the special-purpose aqueous acrylic-amino baking vanish of Intelligent ashtray metal shell, bag following steps:
(1), by the water of 40%, dispersion agent, 30% water-borne acrylic resin put into agitation vat successively, stirrer stirs 9 minutes;
(2), add pigment dyestuff, 35% defoamer, by sand mill, fineness is milled to less than 25 μm, obtained aqueous color paste;
(3), by the water-borne acrylic resin of 70%, aminoresin, propandiol butyl ether, Virahol, catalyzer, flow agent, adhesion promoter, 60% water and defoamer join in clean paint mixing cylinder successively, disperse 8 minutes with high speed dispersor, then add PH conditioning agent adjustment pH value;
(4), in paint mixing cylinder, add aqueous color paste obtained in step (2), high speed dispersor disperses 20 minutes, then obtains required baking vanish with after 180 order filter-cloth filterings.
Embodiment four:
The special-purpose aqueous acrylic-amino baking vanish of a kind of Intelligent ashtray metal shell, this baking vanish is made up of the component of following weight part: water 15-17 part, dispersion agent 0.65 part, pigment dyestuff 19.5 parts, water-borne acrylic resin 48 parts, 4.3 parts, aminoresin, propandiol butyl ether 8.5 parts, Virahol 5.5 parts, catalyzer 4.25 parts, defoamer 0.35 part, flow agent 0.55 part, adhesion promoter 1.25 parts and PH conditioning agent 1.1 parts.
Described catalyzer is aqueous isopropanol.
A preparation method for the special-purpose aqueous acrylic-amino baking vanish of Intelligent ashtray metal shell, bag following steps:
(1), by the water of 40%, dispersion agent, 30% water-borne acrylic resin put into agitation vat successively, stirrer stirs 12 minutes;
(2), add pigment dyestuff, 35% defoamer, by sand mill, fineness is milled to less than 25 μm, obtained aqueous color paste;
(3), by the water-borne acrylic resin of 70%, aminoresin, propandiol butyl ether, Virahol, catalyzer, flow agent, adhesion promoter, 60% water and defoamer join in clean paint mixing cylinder successively, disperse 9 minutes with high speed dispersor, then add PH conditioning agent adjustment pH value;
(4), in paint mixing cylinder, add aqueous color paste obtained in step (2), high speed dispersor disperses 23 minutes, then obtains required baking vanish with after 180 order filter-cloth filterings.
Embodiment five:
The special-purpose aqueous acrylic-amino baking vanish of a kind of Intelligent ashtray metal shell, this baking vanish is made up of the component of following weight part: 17 parts, water, dispersion agent 0.7 part, pigment dyestuff 20 parts, water-borne acrylic resin 50 parts, 4.0 parts, aminoresin, propandiol butyl ether 9 parts, Virahol 6 parts, catalyzer 4.3 parts, defoamer 0.4 part, flow agent 0.6 part, adhesion promoter 1.3 parts and PH conditioning agent 1.2 parts.
Described catalyzer is aqueous isopropanol.
A preparation method for the special-purpose aqueous acrylic-amino baking vanish of Intelligent ashtray metal shell, bag following steps:
(1), by the water of 40%, dispersion agent, 30% water-borne acrylic resin put into agitation vat successively, stirrer stirs 15 minutes;
(2), add pigment dyestuff, 35% defoamer, by sand mill, fineness is milled to less than 25 μm, obtained aqueous color paste;
(3), by the water-borne acrylic resin of 70%, aminoresin, propandiol butyl ether, Virahol, catalyzer, flow agent, adhesion promoter, 60% water and defoamer join in clean paint mixing cylinder successively, disperse 10 minutes with high speed dispersor, then add PH conditioning agent adjustment pH value;
(4), in paint mixing cylinder, add aqueous color paste obtained in step (2), high speed dispersor disperses 25 minutes, then obtains required baking vanish with after 180 order filter-cloth filterings.
The contrast of Intelligent ashtray metal shell special-purpose aqueous acrylic-amino baking vanish in each performance that above-described embodiment one, embodiment two, embodiment three, embodiment four and embodiment five prepare according to the material of each weight part is as shown in table 1.
Table 1
As known from Table 1, embodiment two, embodiment three, the special-purpose aqueous acrylic-amino baking vanish of the Intelligent ashtray metal shell that water-borne acrylic resin in embodiment four and aminoresin proportioning prepare, in hardness, shock-resistance, snappiness, sticking power, the performance such as water tolerance and alcohol resistance is obviously better than embodiment one, the special-purpose aqueous acrylic-amino baking vanish of the Intelligent ashtray metal shell that the water-borne acrylic resin of embodiment five and aminoresin proportioning prepare, water-borne acrylic resin wherein in embodiment two and aminoresin proportioning are 8.8/1, water-borne acrylic resin in embodiment four and aminoresin proportioning are 11.2/1, therefore, the special-purpose aqueous acrylic-amino baking vanish of the Intelligent ashtray metal shell that water-borne acrylic resin and aminoresin proportioning prepare between 8.8/1-11.2/1 is better in over-all properties, thus improve the work-ing life of Intelligent ashtray metal shell, reach object.
The technician of the industry should understand; the present invention is not restricted to the described embodiments; the just principle of the present invention described in above-described embodiment and specification sheets; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.Application claims protection domain is defined by appending claims and equivalent thereof.
Claims (3)
1. the special-purpose aqueous acrylic-amino baking vanish of Intelligent ashtray metal shell, is characterized in that: this baking vanish is made up of the component of following weight part: water 15-17 part, dispersion agent 0.5-0.7 part, pigment dyestuff 18-20 part, water-borne acrylic resin 40-50 part, aminoresin 4.0-5.5 part, propandiol butyl ether 7-9 part, Virahol 4-6 part, catalyzer 4.1-4.3 part, defoamer 0.2-0.4 part, flow agent 0.4-0.6 part, adhesion promoter 1.1-1.3 part and PH conditioning agent 0.8-1.2 part.
2. the special-purpose aqueous acrylic-amino baking vanish of a kind of Intelligent ashtray metal shell according to claim 1, is characterized in that: described catalyzer is aqueous isopropanol.
3. the preparation method of the special-purpose aqueous acrylic-amino baking vanish of a kind of Intelligent ashtray metal shell according to claim 1 and 2, is characterized in that: bag following steps:
(1), by the water of 40%, dispersion agent, 30% water-borne acrylic resin put into agitation vat successively, stirrer stir 5-15 minute;
(2), add pigment dyestuff, 35% defoamer, by sand mill, fineness is milled to less than 25 μm, obtained aqueous color paste;
(3), by the water-borne acrylic resin of 70%, aminoresin, propandiol butyl ether, Virahol, catalyzer, flow agent, adhesion promoter, 60% water and defoamer join in clean paint mixing cylinder successively, with high speed dispersor dispersion 5-10 minute, then add PH conditioning agent adjustment pH value;
(4), in paint mixing cylinder, add aqueous color paste obtained in step (2), high speed dispersor dispersion 15-25 minute, then obtains required baking vanish with after 180 order filter-cloth filterings.
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106147443A (en) * | 2016-07-01 | 2016-11-23 | 太仓市金新涂料有限公司 | A kind of luster, high-hardness and high modification acrylic acrylic acid baking vanish and preparation method thereof |
CN106243873A (en) * | 2016-08-30 | 2016-12-21 | 河北晨阳工贸集团有限公司 | A kind of aqueous tape measure dip-coating baking vanish and preparation method thereof |
CN106609053A (en) * | 2015-10-26 | 2017-05-03 | 天津市新丽华色材有限责任公司 | Water-based baking varnish |
CN106675271A (en) * | 2017-01-16 | 2017-05-17 | 广东四方威凯新材料有限公司 | Bake type single-layer waterborne flashing paint for aluminum alloy hub and preparation method of waterborne flashing paint |
CN109251606A (en) * | 2018-08-21 | 2019-01-22 | 河北晨阳工贸集团有限公司 | A kind of water soluble acrylic acid amino-stoving varnish for three-wheel wheel hub |
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CN102585630A (en) * | 2011-12-19 | 2012-07-18 | 青岛爱尔家佳新材料有限公司 | Water-based glass baking paint and preparation method thereof |
CN104164145A (en) * | 2014-07-15 | 2014-11-26 | 合肥科润节能建材有限公司 | Water-based baked industrial paint |
CN104263145A (en) * | 2014-08-29 | 2015-01-07 | 湖南新力华纳米科技有限公司 | Water-based thermosetting glass winebottle stoving varnish and preparation method thereof |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102585630A (en) * | 2011-12-19 | 2012-07-18 | 青岛爱尔家佳新材料有限公司 | Water-based glass baking paint and preparation method thereof |
CN104164145A (en) * | 2014-07-15 | 2014-11-26 | 合肥科润节能建材有限公司 | Water-based baked industrial paint |
CN104263145A (en) * | 2014-08-29 | 2015-01-07 | 湖南新力华纳米科技有限公司 | Water-based thermosetting glass winebottle stoving varnish and preparation method thereof |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106609053A (en) * | 2015-10-26 | 2017-05-03 | 天津市新丽华色材有限责任公司 | Water-based baking varnish |
CN106147443A (en) * | 2016-07-01 | 2016-11-23 | 太仓市金新涂料有限公司 | A kind of luster, high-hardness and high modification acrylic acrylic acid baking vanish and preparation method thereof |
CN106243873A (en) * | 2016-08-30 | 2016-12-21 | 河北晨阳工贸集团有限公司 | A kind of aqueous tape measure dip-coating baking vanish and preparation method thereof |
CN106675271A (en) * | 2017-01-16 | 2017-05-17 | 广东四方威凯新材料有限公司 | Bake type single-layer waterborne flashing paint for aluminum alloy hub and preparation method of waterborne flashing paint |
CN106675271B (en) * | 2017-01-16 | 2019-06-07 | 广东四方威凯新材料有限公司 | A kind of aluminium alloy wheel hub aqueous metallic finishe of baking-type single layer and preparation method thereof |
CN109251606A (en) * | 2018-08-21 | 2019-01-22 | 河北晨阳工贸集团有限公司 | A kind of water soluble acrylic acid amino-stoving varnish for three-wheel wheel hub |
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Application publication date: 20150923 |