CN104911921A - 一种户外鞋材用聚氨酯合成皮革 - Google Patents
一种户外鞋材用聚氨酯合成皮革 Download PDFInfo
- Publication number
- CN104911921A CN104911921A CN201510370813.4A CN201510370813A CN104911921A CN 104911921 A CN104911921 A CN 104911921A CN 201510370813 A CN201510370813 A CN 201510370813A CN 104911921 A CN104911921 A CN 104911921A
- Authority
- CN
- China
- Prior art keywords
- mass
- parts
- polyurethane
- component
- outdoor shoe
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920002635 polyurethane Polymers 0.000 title claims abstract description 154
- 239000004814 polyurethane Substances 0.000 title claims abstract description 154
- 239000000463 material Substances 0.000 title claims abstract description 74
- 239000002649 leather substitute Substances 0.000 title abstract description 7
- 239000010985 leather Substances 0.000 claims abstract description 58
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 31
- 239000011248 coating agent Substances 0.000 claims abstract description 5
- 238000000576 coating method Methods 0.000 claims abstract description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 39
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical class O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 36
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 34
- 238000002156 mixing Methods 0.000 claims description 30
- 229920001730 Moisture cure polyurethane Polymers 0.000 claims description 26
- 238000003756 stirring Methods 0.000 claims description 26
- 239000008367 deionised water Substances 0.000 claims description 22
- 229910021641 deionized water Inorganic materials 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 150000004985 diamines Chemical class 0.000 claims description 21
- HILAULICMJUOLK-UHFFFAOYSA-N 1,3-diethyl-5-methylbenzene Chemical compound CCC1=CC(C)=CC(CC)=C1 HILAULICMJUOLK-UHFFFAOYSA-N 0.000 claims description 16
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 14
- -1 polyoxypropylene Polymers 0.000 claims description 14
- 229920001451 polypropylene glycol Polymers 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 13
- IBOFVQJTBBUKMU-UHFFFAOYSA-N 4,4'-methylene-bis-(2-chloroaniline) Chemical compound C1=C(Cl)C(N)=CC=C1CC1=CC=C(N)C(Cl)=C1 IBOFVQJTBBUKMU-UHFFFAOYSA-N 0.000 claims description 12
- 241001112258 Moca Species 0.000 claims description 12
- 239000000853 adhesive Substances 0.000 claims description 12
- 230000001070 adhesive effect Effects 0.000 claims description 12
- 125000003118 aryl group Chemical group 0.000 claims description 12
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 claims description 12
- 239000000645 desinfectant Substances 0.000 claims description 12
- 229920005906 polyester polyol Polymers 0.000 claims description 12
- 239000002002 slurry Substances 0.000 claims description 12
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 11
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 10
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 claims description 8
- 239000003607 modifier Substances 0.000 claims description 8
- HEEACTTWORLLPM-UHFFFAOYSA-N 2-(1h-imidazol-5-yl)ethanol Chemical compound OCCC1=CNC=N1 HEEACTTWORLLPM-UHFFFAOYSA-N 0.000 claims description 7
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 claims description 7
- 229920003006 Polybutadiene acrylonitrile Polymers 0.000 claims description 6
- 230000018044 dehydration Effects 0.000 claims description 6
- 238000006297 dehydration reaction Methods 0.000 claims description 6
- 150000002334 glycols Chemical class 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 238000003825 pressing Methods 0.000 claims description 6
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 4
- 238000012856 packing Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 abstract description 2
- 229920005749 polyurethane resin Polymers 0.000 abstract description 2
- 239000004744 fabric Substances 0.000 abstract 1
- 239000010410 layer Substances 0.000 abstract 1
- 239000002344 surface layer Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 19
- 238000002360 preparation method Methods 0.000 description 18
- 239000004721 Polyphenylene oxide Substances 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 229920000570 polyether Polymers 0.000 description 9
- 229920005862 polyol Polymers 0.000 description 9
- 150000003077 polyols Chemical class 0.000 description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 238000007599 discharging Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000004745 nonwoven fabric Substances 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 238000007789 sealing Methods 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 3
- 238000005452 bending Methods 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 2
- 229940008099 dimethicone Drugs 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- JZZIHCLFHIXETF-UHFFFAOYSA-N dimethylsilicon Chemical compound C[Si]C JZZIHCLFHIXETF-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 230000036632 reaction speed Effects 0.000 description 2
- 238000011109 contamination Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 238000013008 moisture curing Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
Landscapes
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Description
实施例3 | 实施例4 | 对比例3 | 对比例4 | 对比例5 | 对比例6 | |
拉伸负荷/N | ≥500 | ≥500 | ≥500 | ≥500 | ≥400 | ≥400 |
断裂伸长率/% | 58 | 60 | 35 | 32 | 51 | 47 |
撕裂负荷/N | ≥50 | ≥50 | ≥50 | ≥50 | ≥30 | ≥30 |
剥离负荷/N | ≥130 | ≥130 | ≥80 | ≥80 | ≥100 | ≥100 |
耐折牢度1 | 无裂口 | 无裂口 | 有裂口 | 有裂口 | 有裂口 | 有裂口 |
耐折牢度2 | 无裂口 | 无裂口 | 有裂口 | 有裂口 | 有裂口 | 有裂口 |
柔软度/mm | 2.0~4.0 | 2.0~4.0 | 2.0~4.0 | 2.0~4.0 | 2.0~4.0 | 2.0~4.0 |
耐水解性-水解后剥离强度/(N/3cm) | ≥115 | ≥115 | ≥50 | ≥50 | ≥70 | ≥70 |
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510370813.4A CN104911921B (zh) | 2015-06-30 | 2015-06-30 | 一种户外鞋材用聚氨酯合成皮革 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510370813.4A CN104911921B (zh) | 2015-06-30 | 2015-06-30 | 一种户外鞋材用聚氨酯合成皮革 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104911921A true CN104911921A (zh) | 2015-09-16 |
CN104911921B CN104911921B (zh) | 2016-08-31 |
Family
ID=54081329
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510370813.4A Active CN104911921B (zh) | 2015-06-30 | 2015-06-30 | 一种户外鞋材用聚氨酯合成皮革 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN104911921B (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106589900A (zh) * | 2016-11-29 | 2017-04-26 | 天长市良文运动器材有限公司 | 一种棒球用抗冲击耐紫外线合成革 |
CN111254233A (zh) * | 2020-03-25 | 2020-06-09 | 焦作隆丰皮草企业有限公司 | 无里衬包袋革的涂饰工艺 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102926220B (zh) * | 2012-10-09 | 2014-12-17 | 佛山威明塑胶有限公司 | 一种环保型pu合成革及其制备方法 |
CN104448233A (zh) * | 2013-09-12 | 2015-03-25 | 嘉兴禾欣化学工业有限公司 | 合成革中间层用高耐候性无溶剂型聚氨酯树脂 |
CN104153204B (zh) * | 2014-07-29 | 2016-06-01 | 上海揽胜绿色材料科技有限公司 | 一种无溶剂双组分聚氨酯合成革的滚涂式制备方法及设备和制备的合成革 |
-
2015
- 2015-06-30 CN CN201510370813.4A patent/CN104911921B/zh active Active
Non-Patent Citations (1)
Title |
---|
闫福安: "《水性树脂与水性涂料》", 31 January 2010 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106589900A (zh) * | 2016-11-29 | 2017-04-26 | 天长市良文运动器材有限公司 | 一种棒球用抗冲击耐紫外线合成革 |
CN111254233A (zh) * | 2020-03-25 | 2020-06-09 | 焦作隆丰皮草企业有限公司 | 无里衬包袋革的涂饰工艺 |
CN111254233B (zh) * | 2020-03-25 | 2022-02-01 | 焦作隆丰皮草企业有限公司 | 无里衬包袋革的涂饰工艺 |
Also Published As
Publication number | Publication date |
---|---|
CN104911921B (zh) | 2016-08-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP1731658B1 (en) | Process for producing leather-like sheet | |
CN104088161B (zh) | 一种无溶剂环保聚氨酯汽车革的制备方法 | |
CN101481579B (zh) | 一种防水透湿改性聚氨酯涂层胶及其制备方法 | |
CN101481580B (zh) | 一种防水、耐低温柔软、透湿涂层胶及其制备方法 | |
CN101591420B (zh) | 一种喷塑聚氨酯组合物、其制备方法及其应用 | |
KR101529152B1 (ko) | 폴리우레탄 발포 시트의 제조방법 및 그것을 사용한 피혁 유사 시트형상물 | |
KR20100057816A (ko) | 분산액 및 필름을 비롯한 수성 폴리우레탄우레아 조성물 | |
CN104153204A (zh) | 一种无溶剂双组分聚氨酯合成革的滚涂式制备方法及设备和制备的合成革 | |
CN106883592A (zh) | 一种超耐磨耐黄变易染色超纤革用聚氨酯树脂 | |
KR20180110538A (ko) | 텍스타일 스킨 코팅용 친수성 수분산 폴리우레탄 수지 및 이를 이용한 친수성 필름의 제조방법 | |
CN106220817A (zh) | 一种无溶剂型汽车内饰革用中间层聚氨酯树脂及其制备方法 | |
KR20110082572A (ko) | 분산액을 포함하는 수성 폴리우레탄우레아 조성물 및 필름 | |
CN107417874A (zh) | 一种封端型双组份无溶剂防水透湿聚氨酯树脂及其制备方法 | |
CN106496514A (zh) | 一种水性聚氨酯树脂 | |
CN105694701A (zh) | 一种防水高透湿、高抗紫外线的聚氨酯涂层胶 | |
TW202003614A (zh) | 聚胺酯預聚物、接著劑、及合成人造皮 | |
JP7123907B2 (ja) | 水性ポリウレタン分散体、プレポリマー、およびそれから作製された造形物品 | |
CN104911921A (zh) | 一种户外鞋材用聚氨酯合成皮革 | |
CN104018359A (zh) | 表面自消光人造革材料 | |
CN102418275A (zh) | 抗菌性聚氨酯pu涂饰剂的制备方法 | |
CN113881008A (zh) | 一种绒面超纤染色用溶剂型聚氨酯树脂及其制备方法 | |
KR20150081035A (ko) | 폴리우레탄 수지 조성물 및 그 제조 방법 | |
CN105297487A (zh) | 一种耐水洗型粘合剂及其制备方法 | |
CN107629670A (zh) | 一种无塑感无溶剂聚氨酯树脂及其制备方法与应用 | |
CN110922563A (zh) | 一种泳衣印花用水性聚氨酯胶浆乳液及制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20190410 Address after: 510000 Yingbin Avenue, Huadu District, Guangzhou City, Guangdong Province, 191 Patentee after: GUANGZHOU HONGGU LEATHER PRODUCTS Co.,Ltd. Address before: Room 2203, Building 6, Lanwan Peninsula, Zhongjun, Xingxia Road, Qidian Town, Jinjiang City, Fujian Province, 362000 Patentee before: JINJIANG CITY CHIDIAN TOWN JIAOPENG TRADE Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20230705 Address after: 528000 Room 2901, Building 1, Xinggang ISQUARE, Huangqi Jianshe Avenue, Dali Town, Nanhai District, Foshan, Guangdong Patentee after: Guangdong Aveni Brand management Co.,Ltd. Address before: 510000 Yingbin Avenue, Huadu District, Guangzhou City, Guangdong Province, 191 Patentee before: GUANGZHOU HONGGU LEATHER PRODUCTS Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20231226 Address after: No. 666 Donghong Road, Damian Street, Longquanyi District, Chengdu City, Sichuan Province, 610100, No. 7, 1st Floor, Zone C, 321 Creative Park Patentee after: Sichuan Gedingni Brand Management Co.,Ltd. Address before: 528000 Room 2901, Building 1, Xinggang ISQUARE, Huangqi Jianshe Avenue, Dali Town, Nanhai District, Foshan, Guangdong Patentee before: Guangdong Aveni Brand management Co.,Ltd. |