CN104910586A - 一种电磁防护复合材料的制备方法 - Google Patents
一种电磁防护复合材料的制备方法 Download PDFInfo
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- CN104910586A CN104910586A CN201510323092.1A CN201510323092A CN104910586A CN 104910586 A CN104910586 A CN 104910586A CN 201510323092 A CN201510323092 A CN 201510323092A CN 104910586 A CN104910586 A CN 104910586A
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- knitted body
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- electromagnetic protection
- nickel
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- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 239000002131 composite material Substances 0.000 title abstract description 7
- 230000001681 protective effect Effects 0.000 title abstract description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 39
- 238000000034 method Methods 0.000 claims abstract description 25
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 20
- 239000004917 carbon fiber Substances 0.000 claims abstract description 20
- 239000000835 fiber Substances 0.000 claims abstract description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229920005989 resin Polymers 0.000 claims abstract description 18
- 239000011347 resin Substances 0.000 claims abstract description 18
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 17
- 238000007747 plating Methods 0.000 claims abstract description 17
- 229920006231 aramid fiber Polymers 0.000 claims abstract description 15
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 14
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract description 14
- 239000011159 matrix material Substances 0.000 claims description 37
- 239000000243 solution Substances 0.000 claims description 22
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 18
- 230000008569 process Effects 0.000 claims description 16
- 239000000126 substance Substances 0.000 claims description 16
- 239000003054 catalyst Substances 0.000 claims description 15
- 239000000377 silicon dioxide Substances 0.000 claims description 12
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 11
- 229910017604 nitric acid Inorganic materials 0.000 claims description 11
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 10
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 claims description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- 238000000151 deposition Methods 0.000 claims description 8
- 230000008021 deposition Effects 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 101150003085 Pdcl gene Proteins 0.000 claims description 6
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 229920006241 epoxy vinyl ester resin Polymers 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 5
- 235000019270 ammonium chloride Nutrition 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims description 5
- 239000000945 filler Substances 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 150000002815 nickel Chemical class 0.000 claims description 5
- 239000001509 sodium citrate Substances 0.000 claims description 5
- 239000001488 sodium phosphate Substances 0.000 claims description 5
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 5
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 5
- 229940038773 trisodium citrate Drugs 0.000 claims description 5
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 5
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 4
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 4
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 4
- 230000004913 activation Effects 0.000 claims description 4
- 125000002252 acyl group Chemical group 0.000 claims description 4
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 4
- 238000007654 immersion Methods 0.000 claims description 4
- 238000011417 postcuring Methods 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- 238000005229 chemical vapour deposition Methods 0.000 claims description 3
- 239000012298 atmosphere Substances 0.000 claims description 2
- 238000009954 braiding Methods 0.000 claims description 2
- 230000008878 coupling Effects 0.000 claims description 2
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- 238000012545 processing Methods 0.000 claims description 2
- 238000001947 vapour-phase growth Methods 0.000 claims description 2
- 239000003643 water by type Substances 0.000 claims description 2
- 238000006424 Flood reaction Methods 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 5
- 230000009977 dual effect Effects 0.000 abstract description 4
- 230000001680 brushing effect Effects 0.000 abstract description 2
- 238000009940 knitting Methods 0.000 abstract 2
- 229910002666 PdCl2 Inorganic materials 0.000 abstract 1
- 230000002159 abnormal effect Effects 0.000 abstract 1
- 230000003213 activating effect Effects 0.000 abstract 1
- 239000004760 aramid Substances 0.000 abstract 1
- 230000005611 electricity Effects 0.000 abstract 1
- 238000007731 hot pressing Methods 0.000 abstract 1
- 230000005389 magnetism Effects 0.000 abstract 1
- 239000011241 protective layer Substances 0.000 abstract 1
- 239000010453 quartz Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 16
- 238000012360 testing method Methods 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 12
- 239000012153 distilled water Substances 0.000 description 8
- 230000007123 defense Effects 0.000 description 7
- 229910052786 argon Inorganic materials 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 239000007822 coupling agent Substances 0.000 description 5
- 238000010792 warming Methods 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- 230000002500 effect on skin Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
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- 238000004140 cleaning Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000007598 dipping method Methods 0.000 description 3
- 241000080590 Niso Species 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000007772 electroless plating Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000002444 silanisation Methods 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Reinforced Plastic Materials (AREA)
- Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
Abstract
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106770574A (zh) * | 2017-01-16 | 2017-05-31 | 华南理工大学 | 一种多壁碳纳米管修饰碳纤维微电极及其制备方法 |
CN106868855A (zh) * | 2017-01-12 | 2017-06-20 | 复旦大学 | 一种耐腐蚀电磁屏蔽织物的制备方法 |
CN111411352A (zh) * | 2020-04-15 | 2020-07-14 | 深圳市欣茂鑫实业有限公司 | 一种含有镀镍层的压铸铝框架及其制备方法 |
CN115559108A (zh) * | 2022-10-19 | 2023-01-03 | 杭州金州高分子科技有限公司 | 一种高耐磨性、高强度纤维复合材料及其制备方法 |
Citations (3)
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US20070056769A1 (en) * | 2005-09-12 | 2007-03-15 | Severance Christopher L | Composite polymeric material for EMI shielding |
CN101531804A (zh) * | 2009-04-13 | 2009-09-16 | 天津大学 | 三维编织镀镍碳纤维与环氧树脂电磁屏蔽复合材料及制备方法 |
CN104310372A (zh) * | 2014-09-30 | 2015-01-28 | 张映波 | 一种在纤维基底上直接生长碳纳米管阵列的方法 |
-
2015
- 2015-06-12 CN CN201510323092.1A patent/CN104910586B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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US20070056769A1 (en) * | 2005-09-12 | 2007-03-15 | Severance Christopher L | Composite polymeric material for EMI shielding |
CN101531804A (zh) * | 2009-04-13 | 2009-09-16 | 天津大学 | 三维编织镀镍碳纤维与环氧树脂电磁屏蔽复合材料及制备方法 |
CN104310372A (zh) * | 2014-09-30 | 2015-01-28 | 张映波 | 一种在纤维基底上直接生长碳纳米管阵列的方法 |
Non-Patent Citations (2)
Title |
---|
曲兆明等: "编织增强型电磁防护材料的等效模型与屏蔽性能", 《高电压技术》 * |
王富强等: "镀镍碳纤维复合材料的电磁脉冲屏蔽效能", 《强激光与粒子束》 * |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106868855A (zh) * | 2017-01-12 | 2017-06-20 | 复旦大学 | 一种耐腐蚀电磁屏蔽织物的制备方法 |
CN106770574A (zh) * | 2017-01-16 | 2017-05-31 | 华南理工大学 | 一种多壁碳纳米管修饰碳纤维微电极及其制备方法 |
CN106770574B (zh) * | 2017-01-16 | 2023-10-03 | 华南理工大学 | 一种多壁碳纳米管修饰碳纤维微电极及其制备方法 |
CN111411352A (zh) * | 2020-04-15 | 2020-07-14 | 深圳市欣茂鑫实业有限公司 | 一种含有镀镍层的压铸铝框架及其制备方法 |
CN111411352B (zh) * | 2020-04-15 | 2022-08-09 | 深圳市欣茂鑫实业有限公司 | 一种含有镀镍层的压铸铝框架及其制备方法 |
CN115559108A (zh) * | 2022-10-19 | 2023-01-03 | 杭州金州高分子科技有限公司 | 一种高耐磨性、高强度纤维复合材料及其制备方法 |
CN115559108B (zh) * | 2022-10-19 | 2024-03-01 | 杭州金州高分子科技有限公司 | 一种高耐磨性、高强度纤维复合材料及其制备方法 |
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Inventor after: Lei Yisan Inventor after: Zhang Ruigang Inventor after: Wang Fuqiang Inventor after: Qiao Miaojie Inventor after: Wang Qingguo Inventor after: Su Qinglin Inventor before: Lei Yisan Inventor before: Zhang Ruigang Inventor before: Wang Fuqiang Inventor before: Qiao Miaojie Inventor before: Wang Qingguo Inventor before: Su Qinglin |
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Effective date of registration: 20200927 Address after: 030006 No. 68 Changfeng street, Shanxi, Taiyuan Patentee after: NO.33 RESEARCH INSTITUTE OF CHINA ELECTRONICS TECHNOOGY Group Corp. Patentee after: ARMY ENGINEERING University OF PLA Address before: 030006 No. 68 Changfeng street, Shanxi, Taiyuan Patentee before: NO.33 RESEARCH INSTITUTE OF CHINA ELECTRONICS TECHNOOGY Group Corp. |
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