CN104906007A - Method for extracting rose essential oil, pigment and flavone from roses simultaneously and application of extracts - Google Patents
Method for extracting rose essential oil, pigment and flavone from roses simultaneously and application of extracts Download PDFInfo
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- CN104906007A CN104906007A CN201510352612.1A CN201510352612A CN104906007A CN 104906007 A CN104906007 A CN 104906007A CN 201510352612 A CN201510352612 A CN 201510352612A CN 104906007 A CN104906007 A CN 104906007A
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- flos rosae
- rosae rugosae
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Abstract
The invention relates to a method for extracting rose essential oil, pigment and rose glucoside from roses simultaneously and application of extracts and belongs to the technical field of medicine and chemistry. According to the method, essential oil, flavone and red pigment are extracted from roses in the same production process by means of phytochemical separation so as to achieve the purpose of total-effect utilization; roses are preserved and fermented by NaCl, so that the guarantee period of the roses is prolonged, the fragrance is permanent, and the extraction ratio of rose essential oil is improved; and the rose essential oil, pigment and flavone extracted according to the method can be applied to various fields such as foods, household chemicals and health-care products, have a wide application range, are purely natural, can be eaten directly, have high safety and are easy to popularize and apply.
Description
Technical field
The invention belongs to pharmaceutical chemistry technical field, be specifically related to a kind ofly from Flos Rosae Rugosae, extract Flos Rosae Rugosae quintessence oil, pigment and the method for Flos Rosae Rugosae glycosides and the application of extract thereof simultaneously.
Background technology
Flos Rosae Rugosae (
rosa rugosathunb.), Rosaceae Rosa fallen leaves bush, its flower, color, perfume (or spice), shape are all beautiful, have high economic worth.Be described as " JINHUA ".Flos Rosae Rugosae quintessence oil is the hat of flower oil, has gracefulness, soft, fine and smooth, the fragrant and sweet Rose Essentielle overflowed as honey, fragrance.Fragrance is dense, and namely two can be made into highclass perfumes, and it is expensive, has the good reputation of " liquid golden ".Flos Rosae Rugosae quintessence oil is used for food, and wine brewing, smoked tea, allocate the aspects such as senior essence.The extracting method of Oleum Rosae Rugosae mainly contains steam distillation, extraction and supercritical fluid extraction.Flos Rosae Rugosae is soaked by the Sal with 10 ~ 15%, makes on the one hand that Flos Rosae Rugosae is unlikely to rot, and the oil in flower can be made to diffuse out on the other hand.
The good water solubility of rose-bengal pigment, in acid condition to various food additive as sodium ascorbate, V
e, sodium benzoate equistability is good.Rose-bengal pigment is that a kind of extraction process is simple, stable in properties, bright-colored, cheap and easy to get, sufficient natural pigment of originating, and can be used for coloured confection, food, fruit drink, tea beverage and drinks etc.
The main component of Flos Rosae Rugosae flavone is the flavone compounds such as Quercetin, rutin and luteolin, there is very strong antioxidant activity and antiinflammatory bacteriostatic activity, Zeng Youwei etc. once have studied the scavenging action of Flos Rosae Rugosae extract to DPPH, result shows that Flos Rosae Rugosae extract has significant Free-radical scavenging activity, can match in excellence or beauty with chemical antioxidants BHT, and its main component is exactly Flos Rosae Rugosae flavone, so Flos Rosae Rugosae flavone is an extract having very much Development volue.
2013, Flos Rosae Rugosae is decided to be new resource food by SFDA and health ministry, make the use of Flos Rosae Rugosae more extensive, but at present, the extraction of Flos Rosae Rugosae quintessence oil is only confined to about the research of Flos Rosae Rugosae and patent, the process of the residue after not extracting Flos Rosae Rugosae quintessence oil proposes constructive path, causes the loss of a lot of effective ingredient.Preparation method (CN102614099A) the proposition supercritical fluid extraction rose extract of a kind of SCF-CO 2 rose extract used for cosmetic announced for such as 2012, this lifting manipulation is unscientific, first supercritical extraction Oleum Rosae Rugosae is adopted material must to be carried out drying and crushing, and high temperature drying can cause the loss of Flos Rosae Rugosae quintessence oil and the change of fragrance, supercritical high cost in addition, at present, the enterprise having this equipment and technology is very few, is not suitable for extensive expanding production.Other patents mostly relate to the equipment that Flos Rosae Rugosae quintessence oil extracts, and the rosebud oven drying at low temperature announced for 2013, effective ingredient remanufacture technique and production equipment (CN103461556A) thereof are only introduced Flos Rosae Rugosae production equipment.How to utilize Flos Rosae Rugosae quintessence oil to extract residue, thus make the value of Flos Rosae Rugosae obtain maximum performance, reduce enterprise's production cost, improving the utilization rate of Flos Rosae Rugosae, is the problem that the present invention mainly solves.
Summary of the invention
The object of the invention is to solve the deficiencies in the prior art, the present invention adopts phytochemistry separation means, by a production technology, extracts quintessence oil, flavone and red pigment from Flos Rosae Rugosae, reaches the object that full effect utilizes.
The technical solution used in the present invention is as follows:
The present invention unless otherwise stated, percentage sign representative be mass percent.
Concentration of alcohol all in the present invention is volumetric concentration.
From Flos Rosae Rugosae, extract a method for Flos Rosae Rugosae quintessence oil, pigment and flavone simultaneously, comprise the following steps:
Step (1), the preparation of Flos Rosae Rugosae quintessence oil:
In Flos Rosae Rugosae, add 10 ~ 50 quality mass concentration is doubly the saline solution of 10 ~ 15%, flood and adopt vapor distillation after 3 ~ 5 days, distillation temperature in the kettle is 100 ~ 105 DEG C, the condensed temperature of distillate is 28 ~ 36 DEG C, when distillate British plain spirits or when being occurred without oil droplet on a glass by condensing droplet, distillation can be stopped; Distillate cools, and layering, gets upper strata, is Flos Rosae Rugosae quintessence oil, and Flos Rosae Rugosae quintessence oil puts into 3 ~ 4 DEG C of refrigerator storage;
Step (2), the preparation of Flos Rosae Rugosae extractum:
Material in distillating still after step (1) being distilled filters, get filtering residue, carry out reflux, extract, with the hydrochloric acid of 0.1mol/L and the mixed liquor of 70% ethanol, in mixed liquor, the hydrochloric acid of 0.1mol/L and the volume ratio of 70% ethanol are 1:1000, Extracting temperature 50 ~ 60 DEG C, extraction time is 2 ~ 3h, and liquid ratio is 1:10 ~ 25(V:M, g/ml), extract 2 ~ 3 times, merge extractive liquid, then at 50 ~ 60 DEG C of concentrating under reduced pressure, obtains Flos Rosae Rugosae extractum;
Step (3), the preparation of Rose Pigment:
Flos Rosae Rugosae extractum distilled water step (2) obtained dissolves, make the solution that relative density is 0.9 ~ 1.2mg/mL, be 2 ~ 3 with hydrochloride adjusted solution pH, loading is in macroporous adsorptive resins, the quality of the Flos Rosae Rugosae extractum of loading is 1/10th of macroporous adsorbent resin quality, first use distilled water flushing 4 ~ 5 retention volumes, use 30% respectively again, the ethanol elution of 50% and 95%, each concentration eluting 4 ~ 5 retention volumes, elution speed is 0.8 ~ 1.0mL/min, collect by the part of 50% ethanol elution and the part with 95% ethanol elution, wherein use the part of 95% ethanol elution, concentrated, dry at 60 ~ 80 DEG C, obtain Rose Pigment,
Step (4), the preparation of Flos Rosae Rugosae flavone:
Step (3) is collected the part of use 50% ethanol elution obtained, concentrated, dry at 60 ~ 80 DEG C, obtain rose extract; By rose extract by polycaprolactam resin column purification, applied sample amount is 0.5 ~ 1g rose extract on polycaprolactam resin that 1ml is wet, during loading, adopt wet method loading, loading after rose extract is dissolved with distilled water, the solid-to-liquid ratio of rose extract and distilled water is 1:3(g:mL), be first eluant with distilled water after loading, eluting 4 ~ 5 retention volumes, change 80% ethanol elution again into, eluting 4 ~ 5 retention volumes, collect 80% ethanol distillate, concentrated, drying obtains Flos Rosae Rugosae flavone.
Further, the macroporous adsorbent resin preferably described in step (3) is AB-8 type.
The application of the Flos Rosae Rugosae quintessence oil that said method obtains in the natural light perfume of preparation Flos Rosae Rugosae, according to weight parts, the following component that the described natural light perfume of 100 portions of Flos Rosae Rugosaes comprises: dehydrated alcohol 60 ~ 80 parts, Fructus Citri Limoniae quintessence oil 0.01 ~ 0.05 part, Flos Rosae Rugosae quintessence oil 0.01 ~ 0.05 part, sandalwood essential oil 0.0008 ~ 0.012 part, deionized water surplus, mix homogeneously, to obtain final product.
The Flos Rosae Rugosae quintessence oil that said method obtains and rose-bengal pigment are preparing the application in natural lipstick, described lip pomade comprises the following component according to weight parts: Jojoba oil 20 ~ 30g, Semen pruni armeniacae oil 15 ~ 25g, shea butter 28 ~ 49g, Apis cerana Fabricius 20 ~ 30g, vitamin E 0.01 ~ 0.03g, Flos Rosae Rugosae quintessence oil 0.01 ~ 0.15g, sweet orange oil 0.01 ~ 0.15g, rose-bengal pigment 0.005 ~ 0.01g.The preparation method of natural lipstick is prepared according to the conventional method.
The application of the Flos Rosae Rugosae flavone that said method obtains in preparation Flos Rosae Rugosae toothpaste, described Flos Rosae Rugosae toothpaste comprises the following component according to weight parts: Flos Rosae Rugosae flavone 15 ~ 20 parts, calcium hydrogen phosphate 10 ~ 20 parts, sorbitol 1 ~ 5 part, sodium laurylsulfate 2 ~ 3 parts, sodium carboxymethyl cellulose 1 ~ 5 part, silicate hydrate 1 ~ 5 part, tetrasodium pyrophosphate 1 ~ 5 part, glycyrrhizin 1 ~ 3 part, natural antiseptic agent 1 ~ 3 part, its preparation method is prepared according to the conventional method.
compared with prior art, its beneficial effect is in the present invention:
(1) the invention provides the method for comprehensive utilization of a kind of Flos Rosae Rugosae, a production technology realizes the object simultaneously extracting the Multiple components such as Flos Rosae Rugosae quintessence oil, pigment, flavone;
(2) the present invention is not simply rough traditional extraction method, and each extract accomplishes pure extraction, obtains highly purified extract; Wherein Flos Rosae Rugosae quintessence oil purity reaches more than 95%, and Rose Pigment purity reaches more than 90%, and Flos Rosae Rugosae flavone purity reaches more than 80%;
(3) the present invention adopts NaCl to preserve and fermentation Flos Rosae Rugosae, and make the extended shelf-life 15 ~ 30 days of Flos Rosae Rugosae, fragrance permanency, makes the extraction rate reached of Flos Rosae Rugosae quintessence oil to 0.12%, and does not add extract with NaCl rate and be only 0.07%;
(4) the present invention obtains Flos Rosae Rugosae quintessence oil, pigment and flavone can be applied to the various fields such as food, daily chemical products, health product, applied range, pure natural, and direct-edible, safety is high;
(5) present invention process is simple, and not high to equipment requirements, whole process does not use toxic organic solvents, is more suitable for the demand of industrial mass production.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail.
It will be understood to those of skill in the art that the following example only for illustration of the present invention, and should not be considered as limiting scope of the present invention.Unreceipted concrete technology or condition person in embodiment, according to the technology described by the document in this area or condition or carry out according to product description.Agents useful for same or the unreceipted production firm person of instrument, being can by buying the conventional products obtained.
Embodiment 1
From Flos Rosae Rugosae, extract a method for Flos Rosae Rugosae quintessence oil, pigment and flavone simultaneously, comprise the following steps:
Step (1), the preparation of Flos Rosae Rugosae quintessence oil:
In Flos Rosae Rugosae, add 10 quality mass concentration is doubly the saline solution of 10%, flood and adopt vapor distillation after 3 days, distillation temperature in the kettle is 100 ~ 105 DEG C, the condensed temperature of distillate is 28 ~ 30 DEG C, when distillate British plain spirits or when being occurred without oil droplet on a glass by condensing droplet, distillation can be stopped; Distillate cools, and layering, gets upper strata, is Flos Rosae Rugosae quintessence oil, and Flos Rosae Rugosae quintessence oil puts into 3 DEG C of refrigerator storage;
Step (2), the preparation of Flos Rosae Rugosae extractum:
Material in distillating still after step (1) being distilled filters, get filtering residue, carry out reflux, extract, with the hydrochloric acid of 0.1mol/L and the mixed liquor of 70% ethanol, in mixed liquor, the hydrochloric acid of 0.1mol/L and the volume ratio of 70% ethanol are 1:1000, Extracting temperature 50 DEG C, extraction time is 2h, and liquid ratio is 1:10(V:M, g/ml), extract 2 times, merge extractive liquid, then at 50 DEG C of concentrating under reduced pressure, obtains Flos Rosae Rugosae extractum;
Step (3), the preparation of Rose Pigment:
Flos Rosae Rugosae extractum distilled water step (2) obtained dissolves, make the solution that relative density is 0.9mg/mL, be 2 with hydrochloride adjusted solution pH, loading is in macroporous adsorptive resins, the quality of the Flos Rosae Rugosae extractum of loading is 1/10th of macroporous adsorbent resin quality, first use distilled water flushing 4 retention volumes, use 30% respectively again, the ethanol elution of 50% and 95%, each concentration eluting 4 retention volumes, elution speed is 0.8mL/min, collect by the part of 50% ethanol elution and the part with 95% ethanol elution, wherein use the part of 95% ethanol elution, concentrated, dry at 60 DEG C, obtain Rose Pigment, wherein said macroporous adsorbent resin is AB-8 type,
Step (4), the preparation of Flos Rosae Rugosae flavone:
Step (3) is collected the part of use 50% ethanol elution obtained, concentrated, dry at 60 DEG C, obtain rose extract; By rose extract by polycaprolactam resin column purification, applied sample amount is 0.6g rose extract on polycaprolactam resin that 1ml is wet, during loading, adopt wet method loading, loading after rose extract is dissolved with distilled water, the solid-to-liquid ratio of rose extract and distilled water is 1:3(g:mL), be first eluant with distilled water after loading, eluting 4 retention volumes, change 80% ethanol elution again into, eluting 4 retention volumes, collect 80% ethanol distillate, concentrated, drying obtains Flos Rosae Rugosae flavone.
Embodiment 2
From Flos Rosae Rugosae, extract a method for Flos Rosae Rugosae quintessence oil, pigment and flavone simultaneously, comprise the following steps:
Step (1), the preparation of Flos Rosae Rugosae quintessence oil:
In Flos Rosae Rugosae, add 50 quality mass concentration is doubly the saline solution of 15%, flood and adopt vapor distillation after 5 days, distillation temperature in the kettle is 100 ~ 105 DEG C, the condensed temperature of distillate is 34 ~ 36 DEG C, when distillate British plain spirits or when being occurred without oil droplet on a glass by condensing droplet, distillation can be stopped; Distillate cools, and layering, gets upper strata, is Flos Rosae Rugosae quintessence oil, and Flos Rosae Rugosae quintessence oil puts into 4 DEG C of refrigerator storage;
Step (2), the preparation of Flos Rosae Rugosae extractum:
Material in distillating still after step (1) being distilled filters, get filtering residue, carry out reflux, extract, with the hydrochloric acid of 0.1mol/L and the mixed liquor of 70% ethanol, in mixed liquor, the hydrochloric acid of 0.1mol/L and the volume ratio of 70% ethanol are 1:1000, Extracting temperature 60 DEG C, extraction time is 3h, and liquid ratio is 1:25(V:M, g/ml), extract 3 times, merge extractive liquid, then at 60 DEG C of concentrating under reduced pressure, obtains Flos Rosae Rugosae extractum;
Step (3), the preparation of Rose Pigment:
Flos Rosae Rugosae extractum distilled water step (2) obtained dissolves, make the solution that relative density is 1.2mg/mL, be 3 with hydrochloride adjusted solution pH, loading is in macroporous adsorptive resins, the quality of the Flos Rosae Rugosae extractum of loading is 1/10th of macroporous adsorbent resin quality, first use distilled water flushing 5 retention volumes, use 30% respectively again, the ethanol elution of 50% and 95%, each concentration eluting 5 retention volumes, elution speed is 1.0mL/min, collect by the part of 50% ethanol elution and the part with 95% ethanol elution, wherein use the part of 95% ethanol elution, concentrated, dry at 80 DEG C, obtain Rose Pigment, wherein said macroporous adsorbent resin is AB-8 type,
Step (4), the preparation of Flos Rosae Rugosae flavone:
Step (3) is collected the part of use 50% ethanol elution obtained, concentrated, dry at 80 DEG C, obtain rose extract; By rose extract by polycaprolactam resin column purification, applied sample amount is 1g rose extract on polycaprolactam resin that 1ml is wet, during loading, adopt wet method loading, loading after rose extract is dissolved with distilled water, the solid-to-liquid ratio of rose extract and distilled water is 1:3(g:mL), be first eluant with distilled water after loading, eluting 5 retention volumes, change 80% ethanol elution again into, eluting 5 retention volumes, collect 80% ethanol distillate, concentrated, drying obtains Flos Rosae Rugosae flavone.
Embodiment 3
From Flos Rosae Rugosae, extract a method for Flos Rosae Rugosae quintessence oil, pigment and flavone simultaneously, comprise the following steps:
Step (1), the preparation of Flos Rosae Rugosae quintessence oil:
In Flos Rosae Rugosae, add 30 quality mass concentration is doubly the saline solution of 13%, flood and adopt vapor distillation after 34 days, distillation temperature in the kettle is 100 ~ 105 DEG C, the condensed temperature of distillate is 30-33 DEG C, when distillate British plain spirits or when being occurred without oil droplet on a glass by condensing droplet, distillation can be stopped; Distillate cools, and layering, gets upper strata, is Flos Rosae Rugosae quintessence oil, and Flos Rosae Rugosae quintessence oil puts into 3.5 DEG C of refrigerator storage;
Step (2), the preparation of Flos Rosae Rugosae extractum:
Material in distillating still after step (1) being distilled filters, get filtering residue, carry out reflux, extract, with the hydrochloric acid of 0.1mol/L and the mixed liquor of 70% ethanol, in mixed liquor, the hydrochloric acid of 0.1mol/L and the volume ratio of 70% ethanol are 1:1000, Extracting temperature 55 DEG C, extraction time is 2.5h, and liquid ratio is 1:18(V:M, g/ml), extract 2 times, merge extractive liquid, then at 58 DEG C of concentrating under reduced pressure, obtains Flos Rosae Rugosae extractum;
Step (3), the preparation of Rose Pigment:
Flos Rosae Rugosae extractum distilled water step (2) obtained dissolves, make the solution that relative density is 1.0mg/mL, be 2.5 with hydrochloride adjusted solution pH, loading is in macroporous adsorptive resins, the quality of the Flos Rosae Rugosae extractum of loading is 1/10th of macroporous adsorbent resin quality, first use distilled water flushing 4.5 retention volumes, use 30% respectively again, the ethanol elution of 50% and 95%, each concentration eluting 4.5 retention volumes, elution speed is 0.9mL/min, collect by the part of 50% ethanol elution and the part with 95% ethanol elution, wherein use the part of 95% ethanol elution, concentrated, dry at 70 DEG C, obtain Rose Pigment, wherein said macroporous adsorbent resin is AB-8 type,
Step (4), the preparation of Flos Rosae Rugosae flavone:
Step (3) is collected the part of use 50% ethanol elution obtained, concentrated, dry at 72 DEG C, obtain rose extract; By rose extract by polycaprolactam resin column purification, applied sample amount is 0.5g rose extract on polycaprolactam resin that 1ml is wet, during loading, adopt wet method loading, loading after rose extract is dissolved with distilled water, the solid-to-liquid ratio of rose extract and distilled water is 1:3(g:mL), be first eluant with distilled water after loading, eluting 4.5 retention volumes, change 80% ethanol elution again into, eluting 4.5 retention volumes, collect 80% ethanol distillate, concentrated, drying obtains Flos Rosae Rugosae flavone.
Application examples 1
In the natural light perfume of a kind of Flos Rosae Rugosae, according to weight parts, the following component that the described natural light perfume of 100 portions of Flos Rosae Rugosaes comprises: dehydrated alcohol 60 parts, Fructus Citri Limoniae quintessence oil 0.01 part, Flos Rosae Rugosae quintessence oil 0.01 part, sandalwood essential oil 0.0008 part, deionized water surplus, mix homogeneously, to obtain final product.
Application examples 2
In the natural light perfume of a kind of Flos Rosae Rugosae, according to weight parts, the following component that the described natural light perfume of 100 portions of Flos Rosae Rugosaes comprises: dehydrated alcohol 80 parts, Fructus Citri Limoniae quintessence oil 0.05 part, Flos Rosae Rugosae quintessence oil 0.05 part, sandalwood essential oil 0.012 part, deionized water surplus, mix homogeneously, to obtain final product.
Application examples 3
In the natural light perfume of a kind of Flos Rosae Rugosae, according to weight parts, the following component that the described natural light perfume of 100 portions of Flos Rosae Rugosaes comprises: dehydrated alcohol 70 parts, Fructus Citri Limoniae quintessence oil 0.03 part, Flos Rosae Rugosae quintessence oil 0.02 part, sandalwood essential oil 0.01 part, deionized water surplus, mix homogeneously, to obtain final product.
Application examples 4
In a kind of natural lipstick, described lip pomade comprises the following component according to weight parts: Jojoba oil 20g, Semen pruni armeniacae oil 15g, shea butter 28g, Apis cerana Fabricius 20g, vitamin E 0.01g, Flos Rosae Rugosae quintessence oil 0.01g, sweet orange oil 0.01g, rose-bengal pigment 0.005g.The preparation method of natural lipstick is prepared according to the conventional method.
Application examples 5
In a kind of natural lipstick, described lip pomade comprises the following component according to weight parts: Jojoba oil 30g, Semen pruni armeniacae oil 25g, shea butter 49g, Apis cerana Fabricius 30g, vitamin E 0.03g, Flos Rosae Rugosae quintessence oil 0.15g, sweet orange oil 0.15g, rose-bengal pigment 0.01g.The preparation method of natural lipstick is prepared according to the conventional method.
Application examples 6
In a kind of natural lipstick, described lip pomade comprises the following component according to weight parts: Jojoba oil 25g, Semen pruni armeniacae oil 22g, shea butter 36g, Apis cerana Fabricius 27g, vitamin E 0.02g, Flos Rosae Rugosae quintessence oil 0.1g, sweet orange oil 0.07g, rose-bengal pigment 0.008g.The preparation method of natural lipstick is prepared according to the conventional method.
Application examples 7
In a kind of Flos Rosae Rugosae toothpaste, described Flos Rosae Rugosae toothpaste comprises the following component according to weight parts: Flos Rosae Rugosae flavone 15 parts, calcium hydrogen phosphate 10 parts, sorbitol 1 part, sodium laurylsulfate 2 parts, sodium carboxymethyl cellulose 1 part, silicate hydrate 1 part, tetrasodium pyrophosphate 1 part, glycyrrhizin 1 part, natural antiseptic agent 1 part, its preparation method is prepared according to the conventional method.
Application examples 8
In a kind of Flos Rosae Rugosae toothpaste, described Flos Rosae Rugosae toothpaste comprises the following component according to weight parts: Flos Rosae Rugosae flavone 20 parts, calcium hydrogen phosphate 20 parts, sorbitol 5 parts, sodium laurylsulfate 3 parts, sodium carboxymethyl cellulose 5 parts, silicate hydrate 5 parts, tetrasodium pyrophosphate 5 parts, glycyrrhizin 3 parts, natural antiseptic agent 3 parts, its preparation method is prepared according to the conventional method.
Application examples 9
In a kind of Flos Rosae Rugosae toothpaste, described Flos Rosae Rugosae toothpaste comprises the following component according to weight parts: Flos Rosae Rugosae flavone 18 parts, calcium hydrogen phosphate 17 parts, sorbitol 3, sodium laurylsulfate 2.6 parts, sodium carboxymethyl cellulose 4 parts, silicate hydrate 3 parts, tetrasodium pyrophosphate 2 parts, glycyrrhizin 2 parts, natural antiseptic agent 2 parts, its preparation method is prepared according to the conventional method.
The present invention adopts a production technology to realize extracting the object of the Multiple components such as Flos Rosae Rugosae quintessence oil, pigment, flavone simultaneously; The present invention adopts NaCl to preserve and fermentation Flos Rosae Rugosae, and make the extended shelf-life 15 ~ 30 days of Flos Rosae Rugosae, fragrance permanency, makes the extraction rate reached of Flos Rosae Rugosae quintessence oil to 0.12%, and does not add extract with NaCl rate and be only 0.07%.Wherein Flos Rosae Rugosae quintessence oil purity reaches more than 95%, and Rose Pigment purity reaches more than 90%, and Flos Rosae Rugosae flavone purity reaches more than 80%.
Rhodamine toner main body of oil prepared by the present invention is that β-citronellol (percentage contents is 63%), β-nerol (percentage contents is 11.23%), geraniol (percentage contents is 10.05%), linalool (percentage contents is 1.34%), eugenol (percentage contents is 0.74%), farnesol (percentage contents is 1.84%) and citronellol acetic acid fat (percentage contents is 4.65%) and the collocation of each composition are even, fragrance is plump full, fragrance is lasting, and quintessence oil taste is higher.
At present, commercially available aromatic mostly is synthetic, and the time is slightly long, and these strong artificial fragrance can bring out vertigo, and chemical substance also can stimulate human body olfactory sensation, also can cause skin allergy time serious, even carcinogenic etc.The Flos Rosae Rugosae quintessence oil, Rose Pigment and the Flos Rosae Rugosae flavone that adopt in the present invention's application are all natural extract, be prepared into the natural light perfume of Flos Rosae Rugosae, natural lipstick, natural toothpaste not containing chemical addition agent, chemistry essence, also human allergy, carcinogenic, effect sterilization can also be played, purifying air can not be caused.
The light perfume of the natural rose that the present invention obtains and perfume inferior more as shown in table 1.
The light perfume of table 1 natural rose and perfume inferior compare
Flos Rosae Rugosae lip pomade moistening effect prepared by the present invention is remarkable.Adopt external weight method to carry out moisture retention test to Flos Rosae Rugosae natural lipstick and commercially available common lip pomade, result is as shown in table 2.
Table 2 lip gloss is the moisturizing rate measurement result (%) of 60% at relative humidity
Flos Rosae Rugosae toothpaste prepared by the present invention, known by detecting, its Flos Rosae Rugosae flavones content is up to 15.3% of toothpaste gross mass, a pure-natural biological toothpaste with inhibiting bacteria and diminishing inflammation activity and health care, commercial toothpastes mostly is pure chemicals, certain harm can be caused to health if engulf because of carelessness, and this toothpaste adopts natural rose flavone to add as main component, also gingiva is taken into account while tooth-whitening, remove oral cavity bacterium, preventing the generation of oral inflammation, even if engulf also nontoxic, is the Flos Rosae Rugosae toothpaste of a high activity pure natural.
More than show and describe ultimate principle of the present invention, principal character and advantage of the present invention.The technical staff of the industry should understand; the present invention is not restricted to the described embodiments; what describe in above-described embodiment and description just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.Application claims protection domain is defined by appending claims and equivalent thereof.
Claims (5)
1. from Flos Rosae Rugosae, extract a method for Flos Rosae Rugosae quintessence oil, pigment and flavone simultaneously, it is characterized in that, comprise the following steps:
Step (1), the preparation of Flos Rosae Rugosae quintessence oil:
In Flos Rosae Rugosae, add 10 ~ 50 quality mass concentration is doubly the saline solution of 10 ~ 15%, flood and adopt vapor distillation after 3 ~ 5 days, distillation temperature in the kettle is 100 ~ 105 DEG C, the condensed temperature of distillate is 28 ~ 36 DEG C, when distillate British plain spirits or when being occurred without oil droplet on a glass by condensing droplet, distillation can be stopped; Distillate cools, and layering, gets upper strata, is Flos Rosae Rugosae quintessence oil, and Flos Rosae Rugosae quintessence oil puts into 3 ~ 4 DEG C of refrigerator storage;
Step (2), the preparation of Flos Rosae Rugosae extractum:
Material in distillating still after step (1) being distilled filters, get filtering residue, carry out reflux, extract, with the hydrochloric acid of 0.1mol/L and the mixed liquor of 70% ethanol, in mixed liquor, the hydrochloric acid of 0.1mol/L and the volume ratio of 70% ethanol are 1:1000, Extracting temperature 50 ~ 60 DEG C, extraction time is 2 ~ 3h, liquid ratio is 1:10 ~ 25(V:M), extract 2 ~ 3 times, merge extractive liquid, then at 50 ~ 60 DEG C of concentrating under reduced pressure, Flos Rosae Rugosae extractum is obtained;
Step (3), the preparation of Rose Pigment:
Flos Rosae Rugosae extractum distilled water step (2) obtained dissolves, make the solution that relative density is 0.9 ~ 1.2mg/mL, be 2 ~ 3 with hydrochloride adjusted solution pH, loading is in macroporous adsorptive resins, the quality of the Flos Rosae Rugosae extractum of loading is 1/10th of macroporous adsorbent resin quality, first use distilled water flushing 4 ~ 5 retention volumes, use 30% respectively again, the ethanol elution of 50% and 95%, each concentration eluting 4 ~ 5 retention volumes, elution speed is 0.8 ~ 1.0mL/min, collect by the part of 50% ethanol elution and the part with 95% ethanol elution, wherein use the part of 95% ethanol elution, concentrated, dry at 60 ~ 80 DEG C, obtain Rose Pigment,
Step (4), the preparation of Flos Rosae Rugosae flavone:
Step (3) is collected the part of use 50% ethanol elution obtained, concentrated, dry at 60 ~ 80 DEG C, obtain rose extract; By rose extract by polycaprolactam resin column purification, applied sample amount is 0.5 ~ 1g rose extract on polycaprolactam resin that 1ml is wet, during loading, adopt wet method loading, loading after rose extract is dissolved with distilled water, the solid-to-liquid ratio of rose extract and distilled water is 1:3(g:mL), be first eluant with distilled water after loading, eluting 4 ~ 5 retention volumes, change 80% ethanol elution again into, eluting 4 ~ 5 retention volumes, collect 80% ethanol distillate, concentrated, drying obtains Flos Rosae Rugosae flavone.
2. the method simultaneously extracting Flos Rosae Rugosae quintessence oil, pigment and flavone from Flos Rosae Rugosae according to claim 1, is characterized in that, the macroporous adsorbent resin described in step (3) is AB-8 type.
3. the application of the Flos Rosae Rugosae quintessence oil that the method that claim 1 extracts Flos Rosae Rugosae quintessence oil, pigment and flavone from Flos Rosae Rugosae simultaneously obtains in the natural light perfume of preparation, it is characterized in that: according to weight parts, the following component that 100 parts of described light perfume comprise: dehydrated alcohol 60 ~ 80 parts, Fructus Citri Limoniae quintessence oil 0.01 ~ 0.05 part, Flos Rosae Rugosae quintessence oil 0.01 ~ 0.05 part, sandalwood essential oil 0.0008 ~ 0.012 part, deionized water surplus, mix homogeneously, to obtain final product.
4. the Flos Rosae Rugosae quintessence oil that the method that claim 1 extracts Flos Rosae Rugosae quintessence oil, pigment and flavone from Flos Rosae Rugosae simultaneously obtains and rose-bengal pigment are preparing the application in natural lipstick, it is characterized in that, described lip pomade comprises the following component according to weight parts: Jojoba oil 20 ~ 30g, Semen pruni armeniacae oil 15 ~ 25g, shea butter 28 ~ 49g, Apis cerana Fabricius 20 ~ 30g, vitamin E 0.01 ~ 0.03g, Flos Rosae Rugosae quintessence oil 0.01 ~ 0.15g, sweet orange oil 0.01 ~ 0.15g, rose-bengal pigment 0.005 ~ 0.01g.
5. the application of the Flos Rosae Rugosae flavone that the method that claim 1 extracts Flos Rosae Rugosae quintessence oil, pigment and flavone from Flos Rosae Rugosae simultaneously obtains in preparation Flos Rosae Rugosae toothpaste, it is characterized in that, described toothpaste comprises the following component according to weight parts: Flos Rosae Rugosae flavone 15 ~ 20 parts, calcium hydrogen phosphate 10 ~ 20 parts, sorbitol 1 ~ 5 part, sodium laurylsulfate 2 ~ 3 parts, sodium carboxymethyl cellulose 1 ~ 5 part, silicate hydrate 1 ~ 5 part, tetrasodium pyrophosphate 1 ~ 5 part, glycyrrhizin 1 ~ 3 part, natural antiseptic agent 1 ~ 3 part.
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