CN104888704A - 桑杆活性炭/铁锰氧化物复合吸附剂的制备方法 - Google Patents
桑杆活性炭/铁锰氧化物复合吸附剂的制备方法 Download PDFInfo
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- CN104888704A CN104888704A CN201510262067.7A CN201510262067A CN104888704A CN 104888704 A CN104888704 A CN 104888704A CN 201510262067 A CN201510262067 A CN 201510262067A CN 104888704 A CN104888704 A CN 104888704A
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 45
- 235000008708 Morus alba Nutrition 0.000 title claims abstract description 36
- 240000000249 Morus alba Species 0.000 title claims abstract description 36
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 26
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 title claims abstract description 26
- 239000003463 adsorbent Substances 0.000 title claims abstract description 24
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000002131 composite material Substances 0.000 title abstract 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 12
- 238000001035 drying Methods 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims abstract description 9
- 229960002089 ferrous chloride Drugs 0.000 claims abstract description 4
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 claims abstract description 4
- 229910021642 ultra pure water Inorganic materials 0.000 claims abstract description 4
- 239000012498 ultrapure water Substances 0.000 claims abstract description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 24
- -1 manganese oxides compound Chemical class 0.000 claims description 21
- 239000011521 glass Substances 0.000 claims description 9
- 238000006424 Flood reaction Methods 0.000 claims description 6
- 238000013019 agitation Methods 0.000 claims description 6
- 239000004570 mortar (masonry) Substances 0.000 claims description 3
- 229910052785 arsenic Inorganic materials 0.000 abstract description 16
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 abstract description 15
- 238000000034 method Methods 0.000 abstract description 12
- 239000002351 wastewater Substances 0.000 abstract description 4
- 239000012286 potassium permanganate Substances 0.000 abstract description 2
- 238000007598 dipping method Methods 0.000 abstract 3
- 238000001914 filtration Methods 0.000 abstract 3
- 238000001816 cooling Methods 0.000 abstract 1
- 239000011363 dried mixture Substances 0.000 abstract 1
- 238000005242 forging Methods 0.000 abstract 1
- 238000000227 grinding Methods 0.000 abstract 1
- 238000007873 sieving Methods 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 10
- 238000010521 absorption reaction Methods 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 239000002028 Biomass Substances 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- 239000002154 agricultural waste Substances 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000000975 co-precipitation Methods 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 239000003651 drinking water Substances 0.000 description 2
- 235000020188 drinking water Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 206010012735 Diarrhoea Diseases 0.000 description 1
- 241000282412 Homo Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 206010047700 Vomiting Diseases 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000002156 adsorbate Substances 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 239000012620 biological material Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000002389 environmental scanning electron microscopy Methods 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 210000003734 kidney Anatomy 0.000 description 1
- 231100000636 lethal dose Toxicity 0.000 description 1
- 201000007270 liver cancer Diseases 0.000 description 1
- 208000014018 liver neoplasm Diseases 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000009366 sericulture Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 230000008673 vomiting Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
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CN201510262067.7A CN104888704B (zh) | 2015-05-21 | 2015-05-21 | 桑杆活性炭/铁锰氧化物复合吸附剂的制备方法 |
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Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105080479A (zh) * | 2014-04-15 | 2015-11-25 | 中国石油化工股份有限公司 | 用于吸附轻烃尾气中挥发性氯化物的净化剂及其制备方法 |
CN106268646A (zh) * | 2016-10-13 | 2017-01-04 | 沈阳建筑大学 | 一种PAC‑Fe3O4/MnO2磁性活性炭及其制备方法 |
CN107537441A (zh) * | 2017-09-23 | 2018-01-05 | 湖南大学 | 一种纳米金属颗粒改性水热炭材料的制备和用途 |
CN107551998A (zh) * | 2017-09-23 | 2018-01-09 | 湖南大学 | 一种生物炭稳定化铁锰氧化物的制备方法和应用 |
CN108176362A (zh) * | 2017-11-13 | 2018-06-19 | 汝城县三鑫电化有限公司 | 一种稳定的铁锰氧化物制备方法 |
CN109092247A (zh) * | 2018-09-09 | 2018-12-28 | 桂林理工大学 | 改性桑杆生物质炭吸附剂的制备方法 |
CN109174958A (zh) * | 2018-10-15 | 2019-01-11 | 通化海汇龙洲化工有限公司 | 制备砷镉钝化剂的方法、由该方法制备的砷镉钝化剂及用途 |
CN109731548A (zh) * | 2019-02-23 | 2019-05-10 | 华南理工大学 | 一种活性炭/锆-锰氧化物复合材料及其制备方法与应用 |
CN109847698A (zh) * | 2019-02-02 | 2019-06-07 | 桂林理工大学 | 一种桑树杆生物质炭/铁锰氧化物复合吸附剂的制备方法 |
CN110433772A (zh) * | 2019-07-24 | 2019-11-12 | 桂林理工大学 | 一种桑树杆生物炭/Fe-Mn复合吸附剂的制备方法及应用 |
CN111530422A (zh) * | 2020-05-14 | 2020-08-14 | 合肥学院 | 一种利用含碳高分子工业废弃品制备改性碳复合吸附剂的方法 |
CN111530421A (zh) * | 2020-05-13 | 2020-08-14 | 内蒙古民族大学 | 一种用于重金属吸附的生物炭及其制备方法 |
CN114192564A (zh) * | 2021-12-01 | 2022-03-18 | 铜陵有色金属集团铜冠建筑安装股份有限公司 | 一种砷污染土壤异地异位修复方法 |
CN114349148A (zh) * | 2021-12-30 | 2022-04-15 | 江苏省环境工程技术有限公司 | 一种砷氧化吸附陶瓷膜处理剂及其制备方法和应用 |
CN114950358A (zh) * | 2022-04-22 | 2022-08-30 | 安徽晋煤中能化工股份有限公司 | 一种锰钛氧化物-生物质炭复合材料及其制备方法和应用 |
Citations (3)
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CN101024160A (zh) * | 2006-02-21 | 2007-08-29 | 中国科学院生态环境研究中心 | 一种铁锰复合氧化物/硅藻土吸附剂的制备、使用及再生方法 |
US20080119357A1 (en) * | 2002-10-30 | 2008-05-22 | The Regents Of The Univerisity Of California | Solid materials for removing arsenic and method thereof |
CN104587958A (zh) * | 2015-01-23 | 2015-05-06 | 中国科学院生态环境研究中心 | 负载铁氧化物的复合生物炭材料及其制备方法与应用 |
-
2015
- 2015-05-21 CN CN201510262067.7A patent/CN104888704B/zh active Active
Patent Citations (3)
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US20080119357A1 (en) * | 2002-10-30 | 2008-05-22 | The Regents Of The Univerisity Of California | Solid materials for removing arsenic and method thereof |
CN101024160A (zh) * | 2006-02-21 | 2007-08-29 | 中国科学院生态环境研究中心 | 一种铁锰复合氧化物/硅藻土吸附剂的制备、使用及再生方法 |
CN104587958A (zh) * | 2015-01-23 | 2015-05-06 | 中国科学院生态环境研究中心 | 负载铁氧化物的复合生物炭材料及其制备方法与应用 |
Non-Patent Citations (1)
Title |
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朱瑾等: ""铁锰氧化物/碳基复合材料的制备及其对水中砷的去除"", 《化学进展》 * |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105080479B (zh) * | 2014-04-15 | 2018-06-12 | 中国石油化工股份有限公司 | 用于吸附轻烃尾气中挥发性氯化物的净化剂及其制备方法 |
CN105080479A (zh) * | 2014-04-15 | 2015-11-25 | 中国石油化工股份有限公司 | 用于吸附轻烃尾气中挥发性氯化物的净化剂及其制备方法 |
CN106268646A (zh) * | 2016-10-13 | 2017-01-04 | 沈阳建筑大学 | 一种PAC‑Fe3O4/MnO2磁性活性炭及其制备方法 |
CN107537441A (zh) * | 2017-09-23 | 2018-01-05 | 湖南大学 | 一种纳米金属颗粒改性水热炭材料的制备和用途 |
CN107551998A (zh) * | 2017-09-23 | 2018-01-09 | 湖南大学 | 一种生物炭稳定化铁锰氧化物的制备方法和应用 |
CN108176362A (zh) * | 2017-11-13 | 2018-06-19 | 汝城县三鑫电化有限公司 | 一种稳定的铁锰氧化物制备方法 |
CN109092247A (zh) * | 2018-09-09 | 2018-12-28 | 桂林理工大学 | 改性桑杆生物质炭吸附剂的制备方法 |
CN109174958A (zh) * | 2018-10-15 | 2019-01-11 | 通化海汇龙洲化工有限公司 | 制备砷镉钝化剂的方法、由该方法制备的砷镉钝化剂及用途 |
CN109847698A (zh) * | 2019-02-02 | 2019-06-07 | 桂林理工大学 | 一种桑树杆生物质炭/铁锰氧化物复合吸附剂的制备方法 |
CN109731548B (zh) * | 2019-02-23 | 2021-01-19 | 华南理工大学 | 一种活性炭/锆-锰氧化物复合材料及其制备方法与应用 |
CN109731548A (zh) * | 2019-02-23 | 2019-05-10 | 华南理工大学 | 一种活性炭/锆-锰氧化物复合材料及其制备方法与应用 |
CN110433772A (zh) * | 2019-07-24 | 2019-11-12 | 桂林理工大学 | 一种桑树杆生物炭/Fe-Mn复合吸附剂的制备方法及应用 |
CN111530421A (zh) * | 2020-05-13 | 2020-08-14 | 内蒙古民族大学 | 一种用于重金属吸附的生物炭及其制备方法 |
CN111530422A (zh) * | 2020-05-14 | 2020-08-14 | 合肥学院 | 一种利用含碳高分子工业废弃品制备改性碳复合吸附剂的方法 |
CN111530422B (zh) * | 2020-05-14 | 2022-05-20 | 合肥学院 | 一种利用含碳高分子工业废弃品制备改性碳复合吸附剂的方法 |
CN114192564A (zh) * | 2021-12-01 | 2022-03-18 | 铜陵有色金属集团铜冠建筑安装股份有限公司 | 一种砷污染土壤异地异位修复方法 |
CN114349148A (zh) * | 2021-12-30 | 2022-04-15 | 江苏省环境工程技术有限公司 | 一种砷氧化吸附陶瓷膜处理剂及其制备方法和应用 |
CN114349148B (zh) * | 2021-12-30 | 2024-02-27 | 江苏省环境工程技术有限公司 | 一种砷氧化吸附陶瓷膜处理剂及其制备方法和应用 |
CN114950358A (zh) * | 2022-04-22 | 2022-08-30 | 安徽晋煤中能化工股份有限公司 | 一种锰钛氧化物-生物质炭复合材料及其制备方法和应用 |
CN114950358B (zh) * | 2022-04-22 | 2023-12-08 | 安徽晋煤中能化工股份有限公司 | 一种锰钛氧化物-生物质炭复合材料及其制备方法和应用 |
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